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BUILOIUtt a BBTTMH WOKID
April 15,2009
Ms. Diana Engeman ^ ^ P F R F I If Remedial Project Manager ^ ' O / V O O / I / Z ^ / D A ;
Superfund Division ' ^ ' U l \ j United States Environmental Protection Agency, Region Vll 901 North Fifth Street Kansas City, KS 66101 MWH #1914390.0102
RE: Focused Remedial Investigation Report Addendum Former Manufactured Gas Plant Site Clinton, Iowa Docket No. CERCLA-07-2004-0307
Dear Ms. Engeman:
On behalf of Interstate Power and Light Company (IPL), MWH has prepared this Addendum to the February 2006 Focused Remedial Investigation Report to present results of the vapor intrusion investigation activities conducted in accordance with the December 2008 Focused Remedial Investigation (Rl) Work Plan Addendum (2008 Focused Rl Work Plan Addendum) for the former manufactured gas plant site in Clinton, Iowa (site).
INTRODUCTION
The 2008 Focused Rl Work Plan Addendum was prepared to investigate potential vapor intrusion in the site vicinity, in order to complete the Focused Rl objective of determining the associated risk to public health and the environment as discussed in the United States Environmental Protection Agency (USEPA) June 19, 2007 letter to IPL. An addendum to the April 2005 Focused Remedial Investigation/Feasibility Study (RI/FS) Sampling and Analysis Plan (2008 SAP Addendum) and a revised site-specific Health and Safety Plan Addendum were prepared to address vapor intrusion investigation activities and included as Appendices A and B, respectively, of the 2008 Focused Rl Work Plan Addendum.
FOCUSED Ri ACTIVITIES
To evaluate the potential for vapor intrusion of site impacts in the site vicinity, indoor air field screening; sump water, subslab soil gas, and soil gas sample collection; and laboratory analysis were conducted as specified in Sections 2 and 5 of the 2008 SAP Addendum. Data collection activities were conducted by MWH in the four target buildings identified in the 2008 Focused Rl Work Plan Addendum. For anonymity, the target buildings are referred to as Building 1, Building 2, Building 3, and Building 4 in this Focused Rl Report Addendum.
11153 Aurora Avenue TEL 51525308.50 Des Moines, IA 50322-7904 FA> 515 253 9592
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Ms. Diana Engeman Page 2 April 15, 2009
Indoor Air Field Screening
Indoor air conditions (percent lower explosive limit [LEL] and concentrations of volatile organic compounds [VOCs], carbon monoxide, hydrogen sulfide, and oxygen) of the lowest level in each target building were surveyed with a calibrated RAE Systems, Inc. Entry RAE PGM-3000 multi-gas monitor and recorded to identify potentially acute or emergency hazards.
The indoor air field screening data are presented in Table 1. VOCs, carbon monoxide, and hydrogen sulfide were not detected in indoor air monitored in the four target buildings. The LEL did not exceed zero percent in indoor air monitored in the four target buildings. Oxygen was detected at concentrations between 20.3 and 22.7 percent by volume in indoor air monitored in the four target buildings. The indoor air field screening results indicate potentially acute or emergency indoor air hazards resulting from the potential vapor intrusion pathway do not exist in Buildings 1 through 4. Therefore, the Focused Rl activities proceeded to evaluation of building sumps.
Sump Water Sampie Coiiection
Sumps were encountered in two of the four target buildings. Water samples were collected from the sump in Building 1 on September 10, 2008 and from the sump in Building 2 on October 8, 2008.
Prior to sample collection, the water level in each sump was measured to the nearest 0.01 foot from the top of the sump using a Solinst Model 101 electronic water level indicator; the total depth of each sump was measured to the nearest 0.01 foot from the top of the sump using a graduated, weighted, stainless steel tape; and the diameter or length and width of the sump were measured to the nearest 0.1 foot with a measuring tape. The sump measurements are presented in Table 2.
Vertically-integrated water samples were collected using dedicated disposable high density polyethylene (HDPE) 0.75-inch outer-diameter (OD) bailers prior to manual evacuation of each sump. Water samples were transferred from each bailer into laboratory supplied and preserved sample containers using dedicated disposable HDPE VOC sampling altaehments. After collecting the initial static water sample from each sump, an attempt was made to evacuate the sump in order to potentially collect a more representative water sample if sufficient groundwater recharge into the sump was observed.
Following initial sample collection, the sump in Building 1 was partially evacuated to the extent possible with the installed sump pump. However, the sump pump did not have a check valve and water drained back into the sump after deactivating the pump. Approximately 11 gallons of water were removed from the Building 1 sump with a 5-gallon bucket liner. Groundwater
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recharge into the Building 1 sump was observed to be very slow. Due to slow groundwater recharge, agitation from pump back flow, and dilution effects of sump water not evacuated, a post-sump evacuation water sample was not collected from Building 1.
In Building 2, condensate and melt water from an icemaker are directed into the sump. According to the property owner, the sump is used to remove water created by the icemaker from the building and the sump does not collect groundwater. After initial water sample collection, the Building 2 sump was partially evacuated to the extent possible with the installed sump pump and the condensate and melt water drainage lines were removed from the sump and redirected into a bucket. After ten minutes, the measured depth to water in the sump recovered 0.01 foot and approximately two liters of condensate and melt water were collected in the bucket. A post-evacuation water sample was not collected from the Building 2 sump.
Collected sump water samples were submitted to Keystone Laboratories, Inc. of Newton, Iowa (Keystone) in iced coolers under chain-of-custody documentation for laboraiory analysis of the contaminants of potential concern (COPCs) benzene, ethylbenzene, toluene, total xylenes (BETX) and naphthalene by USEPA method SW-846 8260. The analytical data for the water samples collected from the Building 1 and Building 2 sumps are presented in Table 3. The COPCs, BETX and naphthalene, were not detected in the sump water samples collected from Buildings 1 and 2. Based on these results, there does not appear to be a completed COPC migration pathway of direct volatilization from groundwater to indoor air through sumps in these buildings. Therefore, the Focused Rl activities proceeded to subslab soil gas or soil gas sample collection.
Subslab Soil Gas Sample Collection
Foundation slabs were found to be present in three of the four target buildings. Subslab soil gas sampling was conducted in the three target buildings with foundation slabs (Buildings 2 through 4) during the week of January 26, 2009 to evaluate the potential vapor intrusion pathway during winter conditions, when minimum air exchange rates and maximum stack effects are expected.
Details of subslab soil gas probe installation, field measurements, weather conditions, tightness tests, leak tests, purging, and sampling are documented on the individual Subslab Soil Gas Sample Collection Records included as Attachment A. A schematic drawing of the subslab soil gas sample collection apparatus is included as Figure 1.
Subslab Soil Gas Probe Installation
Two subslab soil gas probes were installed in each of the three target buildings with foundation slabs. Subslab soil gas probes were constructed of the following materials before drilling probe holes to minimize exposure time of subslab soil to indoor air:
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Swagelok® Vi-inch-OD stainless steel tubing (SS-T4-S-049-20), Swagelok® stainless steel compression fitting (SS-400-1-2ST Body), and Swagelok® stainless steel hex plug with o-ring (SS-2-HPST).
A rotary hammer drill with a 1 ys-inch-OD bit was used to advance each outer probe hole to a depth of approximately 1 V inch below the top of slab. A rotary hammer drill with a V4-inch-0D bit was used to advance each inner hole from the bottom of the center of each outer hole through the slab and penetrating, at a minimum, approximately 2 inches into the subslab material. A wet/dry vacuum with a high efficiency particulate air (HEPA) filter was used to control dust during slab drilling. Each outer hole was cleaned wilh a microfiber cloth and laboratory-supplied distilled and deionized (Dl) water.
A subslab soil gas probe was inserted into each probe hole with the tubing extending into the inner hole and the bottom of the compression fitting resting on the bottom of the outer hole. The annular space between each probe and outer hole was sealed with quick-drying, expanding Quickrete® anchoring cement mixed with laboratory-supplied Dl water. The subslab soil gas probe hole construction details are presented in Table 4.
Pressure Differential Measurement
The pressure differential between the subslab and indoor air was measured with an Omniguard III Differential Pressure Recorder and recorded at each subslab soil gas probe after a minimum of 24 hours following probe installation to allow for pressure equilibration. The negative port of the differential pressure recorder was connected to each subslab soil gas port with dedicated disposable V4-inch-0D nylon tubing with a dedicated Swagelok® stainless steel compression fitting tubing connector (SS-400-1-2ST). The positive port of the differential pressure recorder was open to ambient indoor air. The differential pressure measurements are presented in Table 5.
Sample Manifold Construction
Dedicated "T"-configured sample manifolds, each comprised of stainless steel tubing, stainless steel compression fittings, a particulate filter, a flow controller (restricting flow rate to less than 200 milliliters per minute), two analog vacuum gauges, and a manifold valve, were constructed by Air Toxics, Ltd. of Folsom, California (ATL) to facilitate subslab soil gas sampling. The probe fitting connects one end of the sample manifold to sample tubing leading to the subslab soil gas probe. The canister fitting connects the central portion of the sample manifold to the sample canister. The purge fitting connects the sample manifold end opposite to the probe fitting to purge tubing leading to a 60-cubic centimeter (cc) syringe. Each sample manifold was paired with a sample canister and certified by ATL to contain BETX and naphthalene concentrations less than method reporting limits.
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I I I I I
Tightness Testing
Evacuated 6-liter stainless steel Summa canisters were selected for subslab soil gas sample collection to achieve reporting limits near the screening levels. The initial vacuum of each canister was measured with a Dwyer DPGW-00 digital vacuum gauge and recorded prior to mobilization to the site and prior to connection to the sample manifold. Each canister was found to have sufficient vacuum (greater than 25 inches mercury).
After each sample manifold was connected to the paired closed sample canister, the probe fitting was securely capped and an apparatus tightness test was performed. The tightness test consisted of applying a vacuum across each sample manifold with a syringe and nylon tubing connected to the purge fitting of the manifold, closing the manifold valve, and observing and recording the vacuum readings on the manifold analog vacuum gauges.
Subslab Soil Gas Purging
Prior to sample collection, a minimum of three system volumes were purged from each sample system to remove indoor air introduced during installation. A system volume consists of the internal volume of the purge tubing, sample manifold, dedicated sample tubing and fittings, subslab soil gas probe, open inner hole in the slab, and the cavity created in the subslab material during drilling. Each sample system was purged by opening the sample manifold valve and using a 60-cc synnge with a three-way valve connected to dedicated %-inch-OD nylon tubing to the purge fitting of the sample manifold to draw air through the system. The sample manifold valve was closed immediately after system purging was completed at each location.
Leak Testing
Dunng each system purging, a leak test was conducted with helium as a tracer gas. A glove box shroud was placed over each entire sample system including lhe subslab soil gas probe, sample manifold, and sample canister. Helium gas (99.999% purity) was introduced into the shroud through polytetrafluoroethylene (PTFE) lubing inserted through a hole near the bottom of the shroud. A Dielectric Technologies Model MGD-2002 portable helium detector was used to monitor the concentration of helium near the bottom of the shroud. A minimum helium concentration of 10 percent by volume, as measured at the bottom of the shroud, was maintained inside the shroud.
The air purged from each sample system was collected in a dedicated laboratory-supplied 1-liter Tedlar® bag using a three-way valve on the syringe. The
Ms. Diana Engeman Page 6 April 15, 2009
purged air in each Tedlar bag was monitored for helium with the portable helium detector to evaluate potential leaks into the sample system. If helium was detected during the initial leak test, the system fittings were inspected and adjusted and another leak test was conducted. If several attempts to adjust fittings were unsuccessful in preventing helium detection in the purged air, the conditions and actions taken were documented before proceeding to sample collection.
Sample Collection
After system purging and leak tests were completed at each location, sample collection was initiated by opening the sample canister valve. Time-integrated samples were passively collected as the evacuated canister drew in air from the subslab at a rate less than 200 milliliters per minute. Sampling progress was monitored by the canister vacuum indicated on the manifold analog vacuum gauge located near the canister. Any vacuum drawn on the subslab was monitored and recorded from the analog vacuum gauge located near the probe fitting of the sample manifold. Sample collection was completed by closing the canister valve when the analog vacuum gauge indicated a vacuum between two and five inches mercury remained in the sample canister. The final vacuum of each sample canister was measured with a digital vacuum gauge after sample collection and recorded on the chain-of-custody forms accompanying the canisters to evaluate the potential for leaks during transport to the laboratory.
Laboratorv Analvsis
Collected subslab soil gas were submitted to ATL under chain-of-custody documentation for laboratory analysis of COPCs, BETX and naphthalene, by ATL Modified USEPA TO-15 and leak test tracer gas helium by ATL Modified American Society for Testing Materials (ASTM) D-1945.
Soil Gas Sample Collection
A foundation slab was not present in one of the four target buildings. The basement floor of Building 1 was constructed of brick, which precluded the collection of subslab soil gas samples in Building 1. Therefore, soil gas samples were collected from two temporary soil gas points installed near the target building to evaluate the potential vapor intrusion pathway.
Details of temporary soil gas sample point installation, field measurements, weather conditions, tightness tests, leak tests, purging, and sampling are documented on the individual Soil Gas Sample Collection Records included as Attachment B.
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Soil Gas Sample Point Installation
Below Ground Surface, Inc. of Lawrence, Kansas (BGS), a State of Iowa-licensed well driller, was contracted to install two temporary soil gas sample points near Building 1, one to the south (BLOI S) and one to the east (BLOI E) of the building, with direct-push rods and post-run tubing systems. A joint meet utility locate coordinated through Iowa One Call identified underground gas and sewer utilities and overhead electric lines near the east side of Building 1. The proposed location of BLOI E east of the building was adjusted south to 6 feet southeast of the southeast corner of Building 1 to avoid the identified utilities.
Depth to water, approximately 12 and 13.5 feet below ground surface (bgs), was measured by MWH in two site monitoring wells located near Building 1. Direct-push probe rods were advanced by BGS to 11 feet bgs and then retracted to 10.5 feet bgs at temporary soil gas sample points BLOI E and BLOI S to disengage an expendable drive point and expose the soil interval between 11 and 10.5 feet bgs for sample collection. At each soil gas sample point, a dedicated stainless steel adapter was connected to dedicated %-inch-OD PTFE tubing, inserted through the probe rods, and connected to the expendable point holder to complete the discreet-depth soil gas sample point.
Pressure Differential Measurement
The pressure differential between subsurface and outdoor air was measured with an Omniguard III Differential Pressure Recorder and recorded at each soil gas sample point after post-run tubing installation. The negative port of the differential pressure recorder was connected to the Vi-inch-OD PTFE sample tubing. The positive port of the differential pressure recorder was open to ambient outdoor air. The differential pressure measurements are presented in Table 5.
Sample Manifold Construction
Dedicated "T"-configured sample manifolds identical to the sample manifolds used for subslab soil gas sampling were constructed by ATL to facilitate soil gas sampling. Each sample manifold was paired with a sample canister and certified by ATL to contain BETX and naphthalene concentrations less than method reporting limits.
Tightness Testing
Evacuated 6-liter stainless steel Summa canisters were selected for soil gas sample collection to achieve reporting limits near the screening levels. The initial vacuum of each canister was measured with a Dwyer DPGW-00 digital vacuum gauge and
Ms. Diana Engeman Page 8 April 15, 2009
recorded prior to mobilization to the site and prior to connection to the sample manifold. Each canister was found to have sufficient vacuum (greater than 25 inches mercury).
After each sample manifold was connected to the paired closed sample canister, the probe fitting was securely capped and an apparatus tightness test was performed. The tightness test consisted of applying a vacuum across each sample manifold with a syringe and nylon tubing connected to the purge fitting of the manifold, closing the manifold valve, and observing and recording the vacuum readings on the manilold analog vacuum gauges.
Soil Gas Purging
Prior to sample collection, a minimum of three system volumes were purged from each sample system to remove air introduced during installation. A system volume consists of the internal volume of the purge tubing, sample manifold, dedicated sample tubing and fittings, and the cavity created in the subsurface material after retracting the direct-push rods. Each sample system was purged by opening the sample manifold valve and using a 60-cc syringe with a three-way valve connected to dedicated V4-inch-OD nylon tubing connected to the purge fitting of the sample manifold to draw air through the system. The sample manifold valve was closed immediately after system purging was completed at each location.
Leak Testing
During system purging at each soil gas sample point, a leak test was conducted using helium as a tracer gas. A glove box shroud was placed over the sample system, encompassing the temporary soil gas sample point, sample manifold, and sample canister. Helium gas (99.999% purity) was introduced into the shroud through %-inch-OD PTFE tubing inserted through a hole near the bottom of the shroud. A Dielectric Technologies Model MGD-2002 portable helium detector was used to monitor the concentration of helium near the bottom of the inside of the shroud. A minimum helium concentration of 10 percent by volume, as measured near the bottom of the shroud, was maintained inside the shroud.
The last 240 to 300 cc of air purged from the sample system at each soil gas sample point was collected in a dedicated laboratory-supplied 1-liter Tedlar® bag using a three-way valve on the syringe. The purged air in each Tedlar® bag was monitored for helium with the portable helium detector to evaluate potential leaks into the sample system. It helium was detected during the initial leak test, the system fittings were inspected and adjusted and another leak test was conducted. If several attempts to adjust fittings were unsuccessful in preventing helium detection in the purged air, the
Ms. Diana Engeman Page 9 April 15, 2009
observed conditions and actions taken were documented before proceeding to sample collection.
Sample Collection
After system purging and leak tests were completed at each location, sample collection was initiated by opening the sample canister valve. Time-integrated samples were passively collected as the evacuated canister drew in air from the subslab at a rate less than 200 milliliters per minute. Sampling progress was monitored by the canister vacuum indicated on the manifold analog vacuum gauge located near the canister. Any vacuum drawn on the subslab was monitored and recorded from the analog vacuum gauge located near the probe fitting of the sample manifold. Sample collection was completed by closing the canister valve when the analog vacuum gauge indicated a vacuum between two and five inches mercury remained in the sample canister. The final vacuum of each sample canister was measured with a digital vacuum gauge after sample collection and recorded on the chain-of-custody forms accompanying the canisters to evaluate the potential for leaks during transport to the laboratory.
Ten minutes after initiating sample collection from BLOI E, the sample manifold vacuum gauge indicated the vacuum drawn on the subslab increased from 0 to 20 inches mercury and water was observed in the sample tubing. The sample canister valve was closed to prevent water from entering the sample canister. The brief sample collection resulted in a decrease in canister vacuum of 3.70 inches mercury. Based on inspection of the sample manifold and canister, water did not appear to pass through the particulate filter. After raising the direct-push probes to 9.5 feet bgs, replacing the sample tubing with new dedicated Vi-inch-OD PTFE tubing, reassembling the sample system, purging three system volumes, and conducting a leak test, the remainder of the BL01 E soil gas sample was collected.
Due to the water encountered at BLOI E, the direct-push rods were raised from 10.5 to 9.5 feet bgs at BLOI S prior to system purging, leak testing, and sample collection. Nine minutes after initiating sample collection from BL01 S, water was observed in the sample tubing near the sample manifold and the canister valve was closed to prevent water from entering the sample canister. The brief sample collection resulted in a decrease in canister vacuum of 6.81 inches mercury. Based on inspection of the sample manifold and canister, water did not appear to pass through the particulate filter. According to ATL, sufficient sample volume had been collected for analysis. The limited sample volume would result in method reporting limits elevated approximately by a factor of 6.
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Soil Gas Sample Point Abandonment
Following soil gas sample collection, BGS discarded the sample tubing, removed the direct-push rods, and filled the temporary soil gas sample points with bentonite. MWH measured the soil gas sample point locations to Building 1 features.
Laboratorv Analvsis
Collected soil gas samples were submitted to ATL under chain-of-custody documentation for laboratory analysis of COPCs, BETX and naphthalene, by ATL Modified USEPA TO-15 and leak test tracer gas helium by ATL Modified ASTM D-1945.
Investigation-Derived Waste Disposal
Disposable personal protective equipment (PPE) and other solid waste (i.e., paper towels, bailers, tubing, etc.) generated during sampling activities were containerized in garbage bags and placed in an IPL dumpster for disposal with other general municipal waste generated by the IPL facility. Sample collection activities did not generate investigation-derived waste soil or water.
RESULTS
Laboratory analytical reports for the sump water, subslab soil gas, and soil gas samples are provided in Attachment C. The definitive analytical data were validated as described in the 2008 SAP Addendum by MWH. The data validation evaluations and results are presented in Attachment D. Data qualifiers resulting from data validation were added to the project database. Subslab soil gas and soil gas analytical results are discussed in the following paragraphs.
Subslab Soil Gas Data
COPC analytical data for the subslab soil gas samples collected at Buildings 2, 3, and 4 are presented in Table 6 with corresponding COPC screening values and helium tracer gas analytical data. At least one COPC was detected in each of the six subslab soil gas samples collected.
Detected COPC concentrations were compared to COPC screening levels. The COPC screening levels are the target indoor air concentrations complying with the prescribed cancer risk of IE-06 (1 in 1,000,000) and noncancer target hazard index of 1 for the residential inhalation exposure, as provided in the Residential Air Supporting Table in the September 12, 2008 version of the USEPA Regional Screening Levels for Chemical Contaminants at
Ms. Diana Engeman Page 11 April 15,2009
Superfunci Sites. Detected subslab soil gas sample COPC concentrations exceeding respective screening levels are indicated in bold font in Table 6.
Building 2
In the subslab soil gas sample collected from the eastern probe (BL02 E), elevated concentrations of nontarget species (compounds other than BETX and naphthalene) resulted in elevated reporting limits. Ethylbenzene (1,100 J micrograms per cubic meter [//g/m^]) and total xylenes (6,900 J //g/m^) were detected at concentrations exceeding the respective screening levels. Toluene was detected at a concentration below the screening level. Benzene and naphthalene were not detected at concentrations above the elevated reporting limits. Less than 0.1 percent helium was detected in the subslab soil gas sample.
In the subslab soil gas sample collected from the western probe (BL02 W), benzene (0.45 B /yg/m^) and naphthalene (0.21 J,UB fjg/m^) were detected at concentrations above the respective screening levels. However, naphthalene is not considered detected in the sample because naphthalene was detected in the associated method blank at a similar concentration. Benzene was detected in the associated method blank at a concentration less than 20 percent of the detected concentration in the sample. Ethylbenzene, toluene, and total xylenes were detected at concentrations below the respective screening levels. Less than 0.1 percent helium was detected in the subslab soil gas sample.
Buildings
In the subslab soil gas sample collected from the eastern probe (BL03 E), benzene (0.33 B /vg/m^) and naphthalene (3.7 J,UB /yg/m^) were detected at concentrations above the respective screening levels. However, naphthalene is not considered detected in the sample because naphthalene was detected in the associated meihod blank at a similar concentration. Benzene was detected in the associated method blank at a concentration less than 20 percent of the detected concentration in the sample. Ethylbenzene, toluene, and total xylenes were detected at concentrations below the respective screening levels. Less than 0.5 percent helium was detected in the subslab soil gas sample.
In the subslab soil gas sample collected from the westem probe (BL03 W), naphthalene (0.30 J,UB /yg/m^) was detected at a concentration above the respective screening level. However, naphthalene is not considered detected in the sample because naphthalene was detected in the associated method blank at a similar concentration. BETX were detected at concentrations below the respective screening levels. Less than 0.1 percent helium was detected in the subslab soil gas sample.
I I I I I I I I
Ms. Diana Engeman Page 12 April 15, 2009
Building 4
In the subslab soil gas sample collected from the eastern probe (BL04 E), naphthalene (0.27 J,UB fjg/m^) was detected at a concentration above the respective screening level. However, naphthalene is not considered detected in the sample because naphthalene was detected in the associated method blank at a similar concentration. BETX were detected at concentrations below the respective screening levels. Less than 0.5 percent helium was detected in the subslab soil gas sample.
In the subslab soil gas sample collected from the western probe (BL04 W), naphthalene (0.39 J,UB fjg/m^) was detected at a concentration above the respective screening level. However, naphthalene is not considered detected in the sample because naphthalene was detected in the associated method blank at a similar concentration. BETX were detected at concentrations below the respective screening levels. Less than 0.5 percent helium was detected in the subslab soil gas sample.
Soii Gas Data
COPC analytical data for the soil gas samples collected near Building 1 are presented in Table 7 with corresponding COPC screening values and helium tracer gas analytical data. At least one COPC was detected in each of the two soil gas samples collected.
Detected COPC concentrations were compared to COPC screening levels. The COPC screening levels are the target indoor air concentrations complying with the prescribed cancer risk of IE-06 (1 in 1,000,000) and noncancer target hazard index of 1 for the residential inhalation exposure, as provided in the Residential Air Supporting Table in the September 12, 2008 version of the USEPA Regional Screening Levels for Chemical Contaminants at Superfund Sites. Detected soil gas sample COPC concentrations exceeding the respective screening levels are indicated in bold font in Table 7.
In the soil gas sample collected from the eastern temporary soil gas sample point (BLOI E), elevated concentrations of nontarget species (compounds other than BTEX and naphthalene) resulted in elevated reporting limits. Benzene (47,000 /ug/m^), ethylbenzene (110,000 J fjg/m^), toluene (220,000 //g/m^), and total xylenes (630,000 J /vg/m^) were detected at concentrations above the respective screening levels. Naphthalene was not detected at a concentration above the elevated reporting limit. Helium was detected at a concentration of 20 percent in the soil gas sample.
In the soil gas sample collected from the southern temporary soil gas sample point (BLOI S), elevated concentrations of nontarget species (compounds other than BTEX and naphthalene) resulted in elevated reporting limits. Total xylenes (18,200 J yi/g/m ) were detected at a
Ms. Diana Engeman Page 13 April 15,2009
concentration above the respective screening level. Toluene was detected at a concentration below the respective screening level. Benzene, ethylbenzene, and naphthalene were not detected at concentrations above the elevated reporting limits. Helium was detected at a concentration of 58 percent in the soil gas sample.
ESTIMATED INDOOR AIR CONCENTRATIONS
Potential COPC indoor air concentrations resulting from vapor intrusion of detected subslab soil gas concentrations were estimated based on subslab soil gas-to-indoor air attenuation factors of 1, 0.1, 0.01, 0.001, and 0.0001, which represent a 0-, 1-, 2-, 3-, and 4-order of magnitude decrease in concentration from subslab soil gas indoor air. The estimated COPC indoor air concentrations at each subslab soil gas probe are presented in Tables 8.
Potential COPC indoor air concentrations resulting from vapor intrusion of detected soil gas concentrations were estimated based on soil gas-to-indoor air attenuation factors of 1, through 0.000001, which represent a 0-order through a 6-order of magnitude decrease in concentration from soil gas indoor air. The estimated COPC indoor air concentrations at each temporary soil gas sample point are presented in Tables 9.
Subslab Soil Gas-to-lndoor Air Attenuation
As indicated in Table 8, a subslab soil gas-to-indoor air attenuation factor of 0.1 (a 1-order of magnitude decrease) would result in indoor air concentrations below target residential indoor air concentrations at the following subslab soil gas probe locations: BL02 W, BL03 W, BL04 E, and BL04 W. A subslab soil gas-to-indoor attenuation factor of 0.01 (a 2-order of magnitude decrease) at BL03 E would result in indoor air concentrations below target residential indoor air concentrations. A subslab soil gas-to-indoor attenuation factor of 0.0001 (a 4-order of magnitude decrease) at BL02 E would result in indoor air concentrations below target residential indoor air concentrations. Subslab soil gas-to-indoor air attenuation factors based on empirical data for residential buildings generally range from 0.1 to 0.01 (Interstate Technical Regulatory Council [ITRC], 2007).
Soil Gas-to-lndoor Air Attenuation
As indicated in Table 9, a soil gas-to-indoor air attenuation factor of 0.001 (a 3-order magnitude decrease) would result in COPC indoor air concentrations below target residential indoor air concentrations in Building 1 near BLOI S. A soil gas-to-indoor air attenuation factor of 0.000001 (a 6-order magnitude decrease) would result in COPC indoor air concentrations below target residential indoor air concentrations in Building 1 near BLOI E. Soil gas-to-indoor air attenuation factors based on empincal and modeled data for residential buildings generally range from 0.1 to 0.002 (ITRC, 2007).
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DISCUSSION
COPC concentrations detected above screening levels (benzene and/or naphthalene) in subslab soil gas samples collected in Building 3, Building 4, and from BL02 W in Building 2, are near or below method reporting limits and are associated with method blanks that have benzene and naphthalene concentrations detected below the method reporting limits. Therefore, actual COPC subslab soil gas concentrations may be below screening levels at BL02 W, BL03 E, BL03 W, BL04 E, and BL04 W.
The vacuum drawn on the subsurface and water in sample tubing observed during sample collection, and the elevated helium concentrations detected in the soil gas samples indicate the soil gas sample results may not be representative of COPC soil gas concentrations in the vicinity of Building 1. These observations also indicate low permeability soil in the vadose zone near Building 1, which likely resulted in breakthrough of outdoor air and, therefore, elevated helium concentrations detected in both soil gas samples
SUMMARY AND CONCLUSIONS
Based on the Focused Rl activities conducted in September and October 2008 and January 2009:
Acute or emergency indoor air hazards resulting from the potential vapor intrusion pathway do not exist in Buildings 1 through 4.
Sumps do not appear to be a source of COPCs from groundwater to indoor air in Buildings 1 and 2.
Differential pressure values measured at subslab soil gas probes indicated neutral or upward pressure gradients during the January 2009 data collection activities.
COPCs were detected in subslab soil gas samples collected from Buildings 2, 3, and 4 and soil gas samples collected near Building 1.
Little spatial variability was observed in COPC concentrations detected in subslab soil gas samples collected from Buildings 3 and 4.
Concentrations of COPCs detected in the two subslab soil gas samples collected from Building 2 varied by four orders of magnitude.
Additional subslab soil gas samples will be collected from existing subslab soil gas probes installed in Buildings 2, 3, and 4, and additional soil gas samples will be collected from temporary soil gas sample points near Building 1 during the summer of 2009 to evaluate temporal variability.
Ms. Diana Engeman Page 15 April 15,2009
If you have any questions regarding the site, please contact Mr. Dean Hargens of IPL at 319-789-4658 or me at 515-253-0830.
Sincerely,
Randy J. Kroneman, P.G. Project Manager
/khw:hls:vas Enclosures cc: Dean Hargens, IPL
Matt Culp, Iowa Department of Natural Resources
Attachments: Table 1 - Indoor Air Field Screening Measurements Table 2 - Sump Measurements Table 3 - Sump Water Sample Analytical Data Table 4 - Subslab Soil Gas Probe Dimensions Table 5 - Differential Pressure Measurements Table 6 - Subslab Soil Gas Sample Analytical Data Table 7 - Soil Gas Sample Analytical Data Table 8 - Estimated Indoor Air Concentrations Based on Varying
Subslab Soil Gas-to-lndoor Air Attenuation Factors Table 9 - Estimated Indoor Air Concentrations Based on Varying
Soil Gas-to-lndoor Air Attenuation Factors
Figure 1 - Schematic Drawing of Subslab Soil Gas Sample Collection Apparatus
Attachment A - Subslab Soil Gas Sample Collection Records Attachment B - Soil Gas Sample Collection Records Attachment C - Laboratory Analytical Reports Attachment D - Quality Assurance Report
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TABLE 1
INDOOR AIR FIELD SCREENING MEASUREMENTS FOCUSED REMEDIAL INVESTIGATION
FORMER MANUFACTURED GAS PLANT SITE - CLINTON, IOWA
Building Date Time Volatile Organic Compounds Lower Explosive Limit Carbon Monoxide Hydrogen Sulfide Oxygen
(part[s] per million) (percent) (part[s] per million) (part[s] per million) (percent)
1 9/10/2008 Approximately 11:45 a m.
2 1/26/2009 3:49 p.m.
3 1/26/2009 1:57 p.m.
3 1/27/2009 12:51 p.m.
4 1/27/2009 8:15 a.m.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
20.9
22.7
22.5
22.3
20 3
Page 1 of 1
TABLE 2
SUMP MEASUREMENTS FOCUSED REMEDIAL INVESTIGATION
FORMER MANUFACTURED GAS PLANT SITE - CLINTON, IOWA
Sump Depth Sump Diameter Sump Length Sump Width Depth to Water Volume of Water Building Date Sump Shape (feet) (feet) (feet) (feet) (feet) (gallons)
1 9/10/2008 Cylinder 160 2.0 Not applicable Not applicable 0.65 22.3
2 10/8/2008 Box 177 Not applicable 1.55 155 136 7.37
Pagel of 1
TABLE 3
SUMP WATER SAMPLE ANALYTICAL DATA FOCUSED REMEDIAL INVESTIGATION
FORMER MANUFACTURED GAS PLANT SITE - CLINTON, IOWA
Analyte
Benzene Ethylbenzene Toluene Xylenes, Total Naphthalene
Building: Sample
Sample Sample
Units
lig/L ng/L ng/L ng/L ng/L
Mame: Date: Time:
1 BL01-SW-1001
9/10/2008 11:50 AM
l.OU l.OU l.OU 2.0 U l.OU
2 BL02-SW-1001
10/8/2008 10:15 AM
l.OU 1 o u 1 ou 2 0U 1 OU
Notes: \ig/L = Mlcrogram(s) per liter. U = The analyte was analyzed for, but not detected.
The associated numberical value is at or below the method detection limit.
I I I Page 1 of 1
TABLE 4
SUBSLAB SOIL GAS PROBE DIMENSIONS FOCUSED REMEDIAL INVESTIGATION
FORMER MANUFACTURED GAS PLANT SITE - CLINTON, IOWA
BL02E BL02W BL03E BL03W BL04E BL04W
Building
Installation Date
Installation Time
Slab Thickness (inches)
Diameter of Slab Outer Hole (inches)
Lenglh of Slab Outer Hole (inches)
Diameter of Slab Inner Hole (inch)
Length of Slab Inner Hole (inches) Diameter of Hole in Subslab Matenal (inch) Length of Hole in Subslab Matenal (inches)
Length of Compression Fitting (inches)
Outer Diameter of Tubing (inch)
Length of Tubing (inches)
2
1/26/2009
4:20 PM
4
1 3/8
1 3/4
1/4
2 1/4 1/4
3 5/8
1 3/8
1/4
1 3/4
2
1/26/2009
4:40 PM
7
1 3/8
1 1/2
1/4
5 1/2 1/4
3 1/8
1 3/8
1/4
2 15/16
3
1/26/2009
2:58 PM
3 3/8
1 3/8
1 1/2
1/4
17/8 1/4
2 1/2
1 3/8
1/4
1 1/8
3
1/26/2009
3:20 PM
3 3/8
13/8
1 1/2
1/4
1 7/8 1/4
2 7/8
1 3/8
1/4
1 3/16
4
1/27/2009
8:49 AM
5 3/8
1 3/8
1 1/2
1/4
3 7/8 1/4 2
1 3/8
1/4
2 3/4
4
1/27/2009
9:49 AM
4 3/8
1 3/8
1 1/2
1/4
2 7/8 1/4
1 3/4
1 3/8
1/4
1 5/8
Page 1 of 1
TABLE 5
DIFFERENTIAL PRESSURE MEASUREMENTS FOCUSED REMEDIAL INVESTIGATION
FORMER MANUFACTURED GAS PLANT SITE - CLINTON, IOWA
Measurement Measurement Building Location Date Time
Differential Pressure * (Inches Water) Direction of Pressure Gradient
BLOI E 1/28/2009
BL01 S 1/28/2009
9:43 AM
10 03 AM
+ 0010
+ 0.008
Upward (Subsurface to Outdoor)
Upward (Subsurface to Outdoor)
BL02 E 1/29/2009 2:44 PM Vaned from -0.009 to +0.042, predominantly positive Predominantly Upward (Subslab to Indoor)
BL02W 1/29/2009 4:30 PM Varied from-0.017 to + 0.030, predominantly positive Predominantly Upward (Subslab to Indoor)
BL03 E 1/27/2009
BL03W 1/27/2009
1.17PM
2:08 PM
+ 0.007
+ 0 001
Upward (Subslab to Indoor)
Upward (Subslab to Indoor)
BL04 E 1/29/2009 8:45 AM 0.000 No pressure gradient
BL04W 1/29/2009 10:27 AM + 0.002 Upward (Subslab to Indoor)
Notes:
' = Negative port of differential pressure recorded connected to subslab soil gas or soil gas probe and the positive port is connected to ambient indoor or outdoor air.
Page 1 of 1
TABLE 6 SUBSLAB SOIL GAS SAMPLE ANALYTICAL DATA
FOCUSED REMEDIAL INVESTIGATION FORMER MANUFACTURED GAS PLANT SITE - CLINTON, IOWA
I Analvtical Parameter
Benzene Ethylbenzene
Toluene Naphthalene m.p-Xylene o-Xylene Xylenes, Total"
Tracer Gas Helium
Screening Value
0.31' 0.97'
5,200' 0.072/7.2"
NA NA
100'
Not appllcable
Building: Sample Name: Sample Date: Sample Type:
Units
pg/m^
pg/m^ pg/m^ pg/m^
ng/m^ ng/m^ pg/m^
percent
2 BL02-SS-E001
1/28/2009 Subslab Soil Gas
2,300 U 1,100 J 2,200 J
15,000 U
5,300 1,600 J 6,900 J
0.056 J
2 BL02-SS-W001
1/28/2009 Subslab Soil Gas
0.45 B 0.22 B 0.74 B
0.21 J. UB 0.55 B
0.21 B
0.76 B
0.091
3 BL03-SS-E001
1/28/2009 Subslab Soil Gas
0.38 B 0 18 B 0.79 B
3.7 J, UB
0.45 B 0 20 B
0.65 B
0.31
3 BL03-SS-W001
1/28/2009 Subslab Soil Gas
0.22 J. UB 0.13 J, B 0.47 B
0.30 J, UB
0.22 J, B 0.11 J, UB 0.33 J, UB
0.079 J
4 BL04-SS-E001
1/28/2009 Subslab Soil Gas
0.21 J, UE
0.069 J, B 0.21 B 0.27 J, UB 0.13 J.B
0.057 J, B
0.187 J, B
0.43
4 BL04-SS-W001
1/28/2009 Subslab Soil Gas
0.24 J, UB
0.083 J. B 0 33B
0.39 J, UB 0.18 J, B
0.082 J, B 0.262 J, B
0.32
Notes: jig/m' = Microgram(s) per cubic meter. ' = Target indoor air concentration complying with prescnbed cancer risk of 1 E-06 and noncancer target hazard index of 1 for residential inhalation exposure scenario, as provided in the Residenti
Supporting Table in the Sepember 12, 2008 version of Regional Screening Levels for Chemical Contaminants at Superfund Sites.
" = The target indoor air concentration for naphthalene corresponding to 1 E-06 cancer risk (0 07i! Mg/m ) is two orders of magnitude smaller than the laboratory method reporting limit for naphthali Modified TO-15 Low Level (2.62 pg/m^). Therefore, 7.2 \iglm^, which corresponds to a cancer risk of 1 E-04, will be used as a screening level for subslab soil gas, indoor .jir, and outdoor air naphthalene concentrations during this vapor intrusion investigation.
" = The reported o-xylene and m,p-xylene isomer results were summed to calculate total xylene concentrations.
B = The analyte was detected in an associated method blank as well as in the sample. The concentration detected in the sample is equal to or greater than 5 times the concjntration detected in t UB = The analyte is considered not detected; the concentration detected in the sample is less than 5 times the concentration detected in an associated method blank. J = The analyte was positively identified; the quantitation is an estimation. U = The analyte was analyzed for, but not detected. The associated numberical value is at or below the method detection limit.
I I I I
Page 1 of 1
TABLE 7
SOIL GAS SAMPLE ANALYTICAL DATA FOCUSED REMEDIAL INVESTIGATION
FORMER MANUFACTURED GAS PLANT SITE - CLINTON, IOWA
Analvtical Parameter
Benzene Ethylbenzene Toluene
Naphthalene
m.p-Xylene o-Xylene Xylenes, Total"
Tracer Gas Helium
Screenina Value
0.31' 0.97' 5,200'
0.072/7.2"
NA NA
100'
Not appllcable
Building: Sample Name: Sample Date: Sample Type:
Units
ng/m^ ng/m^ ng/m^ pg/m^
ng/m^ pg/m^
pg/m^
perceni
1 BLOl-SG-EOOl
1/28/2009 Soil Gas
47,000 J 110,000 J
220,000
750,000 U 510,000
120,000 J
630,000
20
1 BLOl-SG-SOOl
1/28/2009 Soil Gas
9,900 U 13,000 U
4,600 J
65,000 U
14.000
4,200 J 18,200
58
Notes: pg/m^ = Microgram(s) per cubic meter. ' = Target indoor air concentration complying with prescribed cancer nsk of 1E-06 and noncancer
target hazard index of 1 for residential inhalation exposure scenano, as provided in the Residential Air Supporting Table in the Sepember 12. 2008 version of Regionai Screening Levels for Chemical Contaminants at Superfund Sites.
" = The target indoor air concentration for naphthalene corresponding to 1 E-06 cancer nsk (0.072 pg/m3) is two orders of magnitude smaller than the laboratory method reporting limit for naphthalene by Modified TO-15 Low Level (2.62 pg/m3). Therefore, 7.2 pg/mS. which corresponds to a cancer risk of 1E-04. will be used as a screening level for subslab soil gas, indoor air, and outdoor air naphthalene concentrations dunng this vapor intrusion investigation.
" = The reported o-xylene and m,p-xylene isomer resulls were summed to calculate total xylene concentrations
B = The analyte was detected in an associated method blank as well as in the sample. The concentration detected in the sample is equal to or greater than 5 times the concentration delected in the blank.
UB = The analyte is considered not detected; the concentration detected in the sample is less than 5 times the concentration detected in an associated method blank.
J = The analyte was positively identified; the quantitation is an estimation. U = The analyte was analyzed for, but not detected.
The associated numberical value is at or below the method detection limit
Page 1 of 1
TABLE 8
ESTIMATED INDOOR AIR CONCENTRATIONS BASED ON VARYING SUBSLAB SOIL GAS-TO-INDOOR AIR ATTENUATION FACTORS
FOCUSED REMEDIAL INVESTIGATION FORMER MANUFACTURED GAS PLANT SITE - CLINTON, IOWA
Building: Location:
Subslab Soil Gas-to-lndoor Air Attenuation Factor (a): 0.1
2 BL02E 0.01 0.001 0.0001 0.1
2 BL02W
0.01 0.001 0.0001 0.1
3 BL03E
0.01 0.001 0.0001 0.1
3 BL03W
0.01 0.001 0.0001 0.1
4 BL04E
0.01 0.001 0.0001 0.1
4 BL04W
0.01 0.001 0.0001
COPC
Benzene
Ethylbenzene
Toluene
Naphthalene
Xylenes, Total
Units
|jg/m'
(jg/m^
gg/m'
ug/m'' pg/m^
Screenina Value
0.31*
0 97'
5.200*
0 072/7 -^
100'
ND NC NC NC NC 1,100 110 11 1.1 O i l 2,200 220 22 2 2 0 22 ND NC NC NC NC
6,900 690 69 6 9 0 69
0.45 0 045 0 0045 0 22 0 022 0 0022 0 74 0 074 0 0074 0.21 0 021 0.0021 0 76 0 076 0 0076 0 0007B 0 000076 0 65 0 065 0 006" 0.00065 0 000065 0 33 0 033 0 0033 0.00033 0 000033 0 187 0 019 0 0019 0 00019 0 000019 0 262 0 026 0 0026 0 00026 0 000026
0 00045
0 00022
0 00074
0 00021
0 000045
0 000022
0 000074
0 000021
0.38
018
0 79
3.7
0 038
0 018
0 079
0.370
0 0038
0 0018
0 0079
0 0370
0 00038
0 00018
0 00079
0 00370
0 000038
0 000018
0 000079
0 000370
0 22
0 13
0 47
0.30
0 022
0 013
0 047
0 030
0 0022
0 0013
0 0047
0.0030
0 00022
0 00013
0 00047
0 00030
0 000022
0 000013
0 000047
0 000030
0 21
0 069
0 21
0.27
0 021
0 007
0 021
0 027
0 0021
0 0007
0 0021
0 0027
0 00021
0 00007
0 00021
0 00027
0 000021
0 000007
0 000021
0.000027
0 24
0 083
0 33
0.39
0 024
0 008
0 033
0 039
0 0024
0 0008
0 0033
0 0039
0 00024
0 00008
0 00033
0 00039
0 000024
0 000008
0 000033
0 000039
Notes: pg/m' = Microgram(s) per cubic meter ' = Target indoor air concentration complying with prescnt)ed cancer nsk of IE-06 and noncancer target hazard index of 1 for residential inhalation exposure scenario, as provided in the Residential Air Supporting Table in the Sepember 12, 2008 version of Regional Screening Levels for Chemical Contaminants at Superfund Sites
' = The target indoor air concentration for naphthalene corresponding to IE-06 cancer nsk (0 072 jjg/m') is two orders of magnitude smaller than the laboratory method reporting limit for naphthalene by Modified TO-15 Low Level (2 62 pg/m3) Therefore, 7 2 p3/m3, whicn corresponds to a cancer nsk of 1E-04, may be used as a screening level for subslab soil gas, indoor air, and outdoor air naphthalene concentrations dunng this vapor intrusion investigation
NC = Not calculated NO = Not detected at elevated reporting limit Subslab soil gas-lo-indoor air attenuation factor = Concentration in indoor air/Concentration in subslab soil gas
Page 1 of 1
TABLE 9
ESTIMATED INDOOR AIR CONCENTRATIONS BASED ON VARYING SOIL GAS-TO-INDOOR AIR ATTENUATION FACTORS
FOCUSED REMEDIAL INVESTIGATION FORMER MANUFACTURED GAS PLANT SITE - CLINTON, IOWA
Building: Location:
Soil Gas-to-lndoor Air Attenuation Factor (o):
COPC Units
Benzene \iglm Ethylbenzene uglrri^ Toluene MQ/nn Naphthalene pgirri^ Xylenes, Total MQ/m
Screenina Value
0 31 ' 0 97' 5,200'
0 072/7 2" 100'
1
47,000 110,000 220,000
ND 630.000
0.1
4,700 11,000 22,000
NC 63,000
0.01
470 1.100 2,200 NC
6.300
1 BL01E
0.001
47 110 220 NC 630
0.0001
4.7 11 22 NC 63
0.00001
0.47 1.1 22 NC 63
0.000001
0 047 0.11 0 22 NC 0 63
1
ND ND
4,600 ND
18,200
0.1
NC NC 460 NC
1,820
0.01
NC NC 46 NC 182
1 BL01 S
0.001
NC NC 46 NC 182
0.0001
NC NC 0.46 NC 1 82
0.00001
NC NC
0 046 NC
0 182
0.000001
NC NC
0 0046 NC
0 0182
Notes: ' = Target indoor air concentration complying with prescribed cancer risk of 1 E-06 and noncancer target hazard index of 1 for residential inhalation exposure scenano, as provided in the
Residential Air Supporting Table in the Sepember 12, 2008 version of Regionai Screening Levels for Chemical Contaminants at Superfund Sites
^ = The target indoor air concentration for naphthalene corresponding to 1 E-06 cancer nsk (0 072 pg/m'') is two orders of magnitude smaller than the laboratory method reporting limit for naphthalene by Modified TO-15 Low Level (2 62 pg/m^) Therefore. 7 2 pg/m'', which corresponds to a cancer nsk of 1E-04, may be used as a screening level for subslab soil gas, indoor air, and outdoor air naphthalene concentrations during this vapor intrusion investigation.
pg/m^ = Microgram(s) per cubic meter. NC = Not calculated ND = Not detected at elevated reporting limit. Son gas-to-indoor air attenuation factor = Concentration in indoor dir/Concentration msoil gas.
Page 1 of 1
FIGURE
^ M W H J
CLEAR PLASTIC STORAGE BOX
1/4" ss SWAGELOCK UNION
1/4" ss NUT & FERRULE
I B
1=111=111—111-
- TEDLAR BAG (FIELD TEST FOR HEUUM)
NOT TO SCALE
CUEHT REFEREhCE NC
lEs iONEogr
JRAWMBr
CHECISDBV
A n K » E D B V
• n O E C i n u m O E R
a.Ktn urmviiL
K M W WILHELM
NOW M Y
R A N D n W O W I U H
IMUGINGC^^XE DES MOINES, IOWA
INTERSTATE POWER AND LIGHT COMPANY ^ MWH
SCHEMATIC DRAWING OF SUBSLAB SOIL GAS SAMPLE
COLLECTION APPARATUS
ATTACHMENT A
Q M W H
(^MWH 1 Building ID
2 Probe Location ID
3 Sample ID
4
5
6
11
12
SUBSLAB SOIL GAS SAMPLE COLLECTION RECORD
BL02
BL02-SS-E001
Interstate Power and Light Company Client Project Clinton FMGP -Focused Remedial Investigation Project Nuinber 1914390.0102
Subslab Probe Installation 01/26/09 1620 4 inches Date Time Slab Thickness
Sample Container Summa 6-liter 4374 4374
Soil Gas Sample Coiiection Type Volume
01/29/09 Container Laboratory ID Manifold Lxiboratory ID
15:28:12 01/29/09 16:18:15 Begin
Measurement
Indoor Volatile Organic Compounds (ppm) Indoor Lower Explosive Limit (%) Indoor Caitxxi Monoxide (ppm) Indoor Hydrogen Sulfide (ppm) Indoor Oxygen (%) Initial Sample Canister Vacuum (in Hg) Tightness Test (Vacuum held yes/no?) Differential Pressure (neg port to subsurface) (in HzO) Volume Purged from Sample System (mL) Leak Test Helium Concentration in Shroud (%) Leak Test Helium Concentration in Tedlar Bag (ppm) Draw on Subsurface (in Hg) Final Sample Canister Vacuum (in Hg)
Date
Result
0 0 0 0
22.7 -29.11 Yes
Variable' 480" 11.0
3.550 0
-23.47
Begin Time
Date
01/26A)9 01/26/09 01/26/09 01/26/09 01/26/09 01/28/09 01/29/09 01/29/09 01/29/09 01/29A)9 01/29A)9 01/29/09 01/2gA)9
Time
1549 1549 1549 1549 1549 1811 0751 1444 1519 1519 1519 1528 1850
End Date End Time
Equipment Used RAE Systems Entry RAE PGM-3000 Multi-Gas Monitor RAE Systems Entry RAE PGM-3000 Multi-Gas Monitor RAE Systems Entry RAE PGM-3000 MuHi-Gas Monitor RAE Systems Entry RAE PGM-3000 Multi-Gas Monitor RAE Systems Entry RAE PGM-3000 Mulb-Gas Monitor
Dwyer Instruments Model DPGW-00 digital pressure gauge Canister, manifokl, synnge, nylon tubing, analog vacuum gauge
Omniguard III Differential Pressure Recorder 60 cc syringe, nyk>n tubing, 3 way valve, Tedlar bag
Dielectric Tectinologies Model MGO-2002 helium detector Dielectric Technobgies Model MGD-2002 helium detector
Analog vacuun gauge (}wyer Instmrnents Model OPGW-00 digital pressure gauge
Analyte
Benzene Ethylbenzene Toluene Xylenes, Total Naphthalene Helium
Method
Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Leve! with SIM Modified EPA TO-15 High/Low Level with Low Level Modified ASTM D-1945
Laboratory
AirToxics, Inc. AirToxics, Inc. AirToxics, Inc. AirToxics, Inc. AirToxics. Inc. AirToxics, Inc.
Hold Time
30 days 30 days 30 days 30 days 30 days 30 days
Component
Open Slab Hole Subslab Probe Sample Tubing Sampling Manifold Purge Tubing 3 System Volumes
Volume
3.3 mL 1.4 mL 10.8 mL 14.5 mL 18.5 mL 146 mL
10 Weattier Conditions Temperature = 21.2 °F, Dew Point = 10.4 °F, Humidtty = 63%. Sea Level Pressure = 30.00 in Hg and rising, Wind = 20.7 mph WNW. Precipitation = None, Sky = Clear (Clinton Municipal Airport at 15:35).
Comments/Observations Black top patch, heavy duty degreaser, and other cleaning solutions observed in basement near probe. *Differential pressure varied from -0.009 to +0.042 in HgO. "240mL were purged at 1501. additional 240mL purged due to helium in bag.
Sampler Signature(^ Karin H. Wilhelm / Randy J. Kroneman
Sampler Name(8)
Q M W H SUBSLAB SOIL CSAS SAMPLE COLLECTION RECORD
1
2
3
4
5
6
Building ID
Probe Location ID
Sample ID
Subslab Probe Installation
Sample Container
Soil Gas Sample Collection
BL02
W
BL02-SS-W001
01/26/09 Date
Summa 6-llter Type Volume
01/29/09
Interstate Power and Light Company Client Project Clinton FMGP -Focused Remedial Investigation Project Number 1914390.0102
1640 7 inches Time Slab Thickness
35269 35269 Container Laboratory ID Manifold Laboratory ID
16:50:25 01/29/09 18:16:45 Begin Date
Measurement Indoor Volatile Organic Compounds (ppm) Indoor Lower Explosive Umit (%) Indoor Cartxm Monoxide (ppm) Indoor Hydrogen Sulfide (ppm) Indoor Oxygen (%) Initial Sample Canister Vacuum (in Hg) Tightness Test (Vacuum held yes/no?) Differential Pressure (neg port to subsurface) (in H2O) Volume Purged from Sample System (mL) Leak Test Helium Concentration in Shroud (%) Leak Test Helium Concentration in Tedlar Bag (ppm) Draw on Subsurface (in Hg) Rnal Sample Canister Vacuum (in Hg)
Result
0 0 0 0
22.7 -29.35 Yes
Variable * 240 25.0 200
0 -1.75
Begin Time
Date 01/26/09 01/26/09 01/26A)9 01/26A)9 01/26/09 01/28A)9 01/28A)9 01/29/09 01/29/09 01/29/09 01/29A)9 01/29/09 01/29/09
Time 1549 1549 1549 1549 1549 1808 1853 1630 1639 1639 1648 1528 1850
End Date End Time
Equipment Used RAE Systems Entry RAE PQM-3000 MulthGas Monitor RAE Systems Entry RAE PGM-3000 Multi-Gas Monitor RAE Systems Entiy RAE PGM-3000 Multi-Gas Monitor RAE Systems Entry RAE PGM-3000 Multi-Gas Monitor RAE Systems Entry RAE PGM-3000 Multi-Gas Monitor
Dwyer Instruments Model DPQW-00 digital pressure gauge Canister, manifoM, syringe, nylon tubing, analog vacuion gauge
Omniguard III Differential Pressure Recorder 60 cc syringe, nykxi tubing, 3 way valve. Tedlar bag
Dielectric Technologies Model MGD-2002 helium detector Dielectric Technologies Model MGD-2002 helium detector
Analog vacuum gauge Dwyer Instnanents Model DPGW-00 digital pressure gauge
Analyte
Benzene Ethylbenzene Toluene Xylenes, Total Naphthalene Helium
Method
Modified EPA TO-15 HighAx)w Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with Low Level Modified ASTM D-1945
Laboratory
AirToxics, Inc. AirToxics, Inc. AirToxics, Inc. AirToxics, Inc. AirToxics, Inc. /kirToxics, Inc.
Hold Time
30 days 30 days 30 days 30 days 30 days 30 days
Component
Open Slab Hole Subslab Probe Sample Tubing Sampling Manifold Purge Tubing 3 System Volumes
Volume
3.3 mL 1.4 mL 10.8 mL 14.5 mL 18.5 mL 146 mL
10 Weather Conditions Temperature = 19.4 °F, Dew Point = 8.6 °F, Humidity = 63%, Sea Level Pressure = 30.02 in Hg and rising, Wind g 24.2 mph W, Precipitation = None, Sky = Clear (Clinton Municipal Airport at 16:55).
11 Comments/Observations 'Differential pressure varied from -0.017 to -K).030 in HgO. Draw on subslab at end of sample collection was -1 in Hg.
12 Karin H. Wilhelm / Randy J. Kroneman Sampler Name(s) Sampler Slgnature(«)
1 Building ID
2 Probe Location ID
3 Sample ID
4
5
6
10
SUBSLAB SOIL GAS SAMPLE COLLECTION RECORD
BL03
BL03-SS-E001
Client Project Project Number
Interstate Power and Light Company Clinton FMGP -Focused Remedial Investigation 1914390.0102
Subslab Probe Installation 01/26/09 1458 3 3/8 inches Date Time Slab Thickness
Sample Container Summa 6-liter 25315 25315
Soil Gas Sample Collection Type Volume
01/27/09 Container Laboratory ID Manifold Laboratory ID
15:03:39 01/27/09 15:46:38 Begin
Measurement
Indoor Volatile Organic Compounds (ppm) Indoor Lower Explosive Limit (%) Indoor CartMn Monoxide (ppm) Indoor Hydrogen Sulfide (ppm) Indoor Oxygen (%) Initial Sample Canister Vacuum (in Hg) Tightness Test (Vacuum held yes/no?) Differential Pressure (neg port to subsurface) (in HzO) Volume Purged from Sample System (mL) Leak Test Helium Concentration in Shroud (%) Leak Test Helium Concentration in Tedlar Bag (ppm) Draw on Subsurface (in Hg) Final Sample Canister Vacuum (in Hg)
Date
Result
0 0 0 0
22.7 -29.70
No' +0.007
180 17.5
0 -2
-6.81
Begin Time
Date
01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/27A)9 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09
Time
1251 1251 1251 1251 1251 1312 1429 1317 1457 1458 1459
1555
End Date End Time
Equipment Used RAE Systems Entry RAE PGM-3000 Mufti-Gas Monitor RAE Systems Entry RAE PGM-3000 Mutti-Gas Monitor RAE Systems Entiy RAE PGM-3000 Mutti-Gas Monitor RAE Systems Entiy RAE PGM-3000 Mutti-Gas Monttor RAE Systems Entry RAE PGM-3000 Multi-Gas Monitor
Dwyer Instniments Modal DPGW-00 digital pressure gauge Canister, manitoki, synnge, nylon tubing, anatog vacuum gauge
Omniguard III Differential Pressure Recorder 60 cc syringe, nylon tubing, 3 way valve. Tedlar bag
Dielectric Technologies Model MGO-2002 helium detector Dielectric Technologies Model MGD-2002 helium detector
Anatog vacuum gauge Dwyer Instruments Model OPGW-00 digital pressure gauge
Analyte
Benzene Ethylbenzene Toluene Xylenes, Tota! Naphthalene Helium
Method
Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with Low Level Modified ASTM D-1945
Laboratory
AirToxics, Inc. AirToxics, inc. /AirToxics, Inc. AirToxics, Inc. AirToxKS, Inc. AirToxics, Inc.
Hold Time
30 days 30 days 30 days 30 days 30 days 30 days
Component
Open Slab Hole Subslab Probe Sample Tubing Sampiing Manifold Purge Tubing 3 System Volumes
Volume
2.6 mL 1.1 mL 9.5 mL 14.5 mL 18.5 mL 139 mL
Weather Conditions Temperature = 10.4 "F, Dew Point = 5.0 °F, Humidity = 85%, Sea Level Pressure = 30.32 in Hg and falling. Wind = 4.6 mph NNE, Precipitation = None. Sky = Overcast (Clinton Municipal /Airport at 15:15).
11 Comments/Observations 'Applied vacuum dropped from -18.5 to -18.0 in Hg from 1418 to 1428. An attempt was made to tighten fittings.
12 Karin H. Wilhelm / Randy J. Kroneman Sampler Name(s)
>^U^/V^ /<yx.l/rjl^l / ^ ^ ^ / ^ ^ ^ ' " ^ ^ Sampler Signature(s) -^
® MWH SUBSLAB SOIL GAS SAMPLE COLLECTION RECORD
1
2
3
4
5
6
Building ID
Probe Location ID
Sample ID
Subslab Probe Installation
Sample Container 1
Soil Gas Sample Collection
BL03
W
BL03-SS-W001
01/26/09 Date
Summa 6-liter Type Volume
01/27/09
10
11
12
Client Project Project Number
Interstate Power and Light Company Clinton FMGP -Focused Remedial Investigation 1914390.0102
1520 3 3/8 inches Time Slab Thickness
33962 33962 Container Laboratory ID Manifold Laboratory ID
17:53:13 01/27/09 18:37:16 Begin
Measurement Indoor Volatile Organic Compounds (ppm) Indoor Lower Explosive Limit (%) Indoor Carbon Monoxide (ppm) Indoor Hydrogen SuifMe (ppm) Indoor Oxygen (%) Initial Sample Canister Vacuum (in Hg) Tightness Test (Vacuum held yes/no?) Differential Pressure (neg port to subsurface) (in HjO) Volume Purged from Sample System (mL) Leak Test Helium Concentration in Shroud (%) Leak Test Helium Concentration in Tedlar Bag (ppm) Draw on Subsurface (in Hg) Final Sample Canister Vacuum (in Hg)
Date
Result
0 0 0 0
22.7 -29.58
No' -tO.001 720" 12.4 75 0
-5.47
Begin Time
Date 01/27/09 01/27/09 01/27A)9 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09
Time 1251 1251 1251 1251 1251 1353 1725 1408 1742 1742 1745
1840
End Date End Time
Equipment Used RAE Systems Entry RAE PGM-3000 Multi-Gas Monitor RAE Systems Entiy RAE PGM-3000 Mutti-Gas Monttor RAE Systems Entry RAE PGM-3000 Mutti-Gas Monitor RAE Systems Entiy RAE PGM-3000 Mutti-Gas Monttor RAE Systems Entry RAE PGM-3000 Mutti-Gas Monttor
Dwyer Instruments Model OPGW-00 digital pressure gauge Canister, manltold, syringe, nykxi tubing. anak>g vacuum gauge
Omniguard III Differential Pressure Recorder 60 cc syringe, nykxi tubing, 3 way valve. Tedlar bag
Oietectnc Technotogles Model MGD-2002 helium detector Dielectric Technotogles Model MGO-2002 helium detector
Anatog vacuum gauge Dwyer Instrments Model DPGW-00 digttal pressure gauge
Analyte
Benzene Ethylbenzene Toluene Xylenes, Total Naphthalene Helium
Method
Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 Hiqh/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with Low Level Modified ASTM D-1945
Laboratory
AirToxics, inc. AirToxics, Inc. AirToxkss. Inc. AirToxics, Inc. AirToxics. Inc. AirToxics, Inc.
Hold Time
30 days 30 days 30 days 30 days 30 days 30 days
Component
Open Slab Hole Subslab Probe Sample Tubing Sampling Manifold Purge Tubing 3 System Volumes
Volume
2.9 mL 1.2 mL 9.5 mL 14.5 mL 18.5 mL 140 mL
Weather Conditions Temperature = 12.2 °F, Dew Point = 5.0 "F, Humklity = 73%. Sea Level Pressure = 30.26 in Hg and falling, Wind = 4.6 mph NNE, Precipitation = None. Sky = Overcast (Clinton Municipal Airport at 17:55).
Comments/Observations */Wer several attempts to tighten fittings and replace sample tubing ferrule, the applied vacuum decreased from -20.8 in Hg at 1718 to -20.4 in Hg at 1723 to -20.2 in Hg at 1725. Purged 180mL 4 times, each time after trying to tighten fittings.
Sampler Signature(tf) Karin H. Wilhelm / Randy J. Kroneman
Sampler Name(s)
1 Building ID
2 Probe Location ID
3 Sample ID
4
5
6
10
SUBSLAB SOIL GAS SAMPLE COLLECTION RECORD
BL04
BL04-SS-E001
Client Project Project Number
Interstate Power and Ught Company Clinton FMGP -Focused Remedial Investigation 1914390.0102
Subslab Probe Installation 01/27/09 0849 5 3/8 inches Date Time
Sample Container Summa Slab Thk:kness
6-liter 34377 34377
Soil Gas Sample Coiiection Type Volume
01/29/09 Container Laboratory ID Manifold Laboratory ID
09:14:48 01/29/09 10:15:45 Begin
Measurement
Indoor Volatile Organic Compounds (ppm) Indoor Lower Explosive Limit (%) Indoor Cartxm Monoxkle (ppm) Indoor Hydrogen Sulfide (ppm) Indoor Oxygen (%) Initial Sample Canister Vacuum (in Hg) Tightness Test (Vacuum hekl yes/no?) Differential Pressure (neg port to subsurface) (in HzO) Volume Purged from Sample System (mL) Leak Test Helium Concentration in Shroud (%) Leak Test Helium Concentratton in Tedlar Bag (ppm) Draw on Subsurface (in Hg) Final Sample Canister Vacuum (in Hg)
Date
Result
0 0 0 0
20.3 -29.47
Yes 0.000 240 33.3
0 -6*
-5.12
Begin Time
Date
01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/28A)9 01/28/09 01/29A)9 01/29/09 01/29rt)9 01/29/09 01/29/09 01/29/09
Time
0815 0815 0815 0815 0815 1817 1855 0845 0910 0910 0911 0914 1420
End Date End Time
Equipment Used
RAE Systems Entiy RAE PGM-3000 Mutti-Gas Monitor RAE Systems Entry RAE PGM-3000 Mutti-Gas Monttor RAE Systems Entiy RAE PGM-3000 Mutti-Gas Monitor RAE Systems Entry RAE PGM-3000 Mutti-Gas Monitor RAE Systems Entry RAE PGM-3000 Multi-Gas Monitor
Dwyer Instruments Model DPGW-00 digttal pressure gauge Canister, manifold, syringe, nyton tubing, anatog vacuum gauge
Omniguard III Differential Pressure Recorder 60 cc syringe, nylon tut>ing, 3 way valve, Tedlar bag
Dielectnc Technotogles Model MGO-2002 helium detector Oielectnc Technologies Model MGD-2002 helium detector
Anatog vacuum gauge Dwyer Instalments Model DPGW-00 digital pressure gauge
Analyte
Benzene Ethylbenzene Toluene Xylenes, Total Naphthalene Helium
Method
Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 Hkjh/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with Low Level Modified ASTM D-1945
Laboratory
AirToxk», Inc. AirToxics. Inc. AirToxics. Inc. AirToxics, Inc. AirToxics, Inc. AirToxics, Inc.
Hold T ime
30 days 30 days 30 days 30 days 30 days 30 days
Component
Open Stab Hole Subslab Probe Sample Tubing Sampling Manifold Purge Tubing 3 System Volumes
Volume
2.7 mL 1.9 mL 9.5 mL 14.5 mL 18.5 mL 140 mL
Weather Conditions Temperature = 23.0 °F. Dew Point = 17.6 °F. HumkJity = 80%, Sea Level Pressure = 29.93 in Hg and rising, Wind = 16.1 mph W, Precipitation = None, Sky = Clear (Clinton Municipal Airport at 09:15).
11 Comments/Observations 'Draw on subslab gradually decreased when canister vacuum reached - 24 in Hg. Draw on subslab reached 0 in Hg when canister vacuum reached -15.5 in Hg at 0938.
12 Karin H. Wilhelm / Randy J. Kroneman Sampler Name(s) Sampler Signature(a)
® MWH SUBSLAB SOIL GAS SAMPLE COLLECTION RECORD
1
2
3
4
5
6
Building ID
Probe Location ID
Sample ID
Subslab Probe installation
Sample Container
Soil Gas Sample Collection
BL04
W
BL04-SS-W001
01/27/09 Date
Summa 6-liter Type Volume
01/291/09
10
Client Project Project Number
Interstate Power and Light Company Clinton FMGP -Focused Remedial Investigation 1914390.0102
0949 4 3/8 inches Time Slab Thickness
34022 34022 Container Laboratory ID Manifold Laboratory ID
11:46:01 01/29/09 12:37:31 Begin Date
Measurement Indoor Volatile Organk: Compounds (ppm) Indoor Lower Explosive Limit (%) Indoor Cattion Monoxide (ppm) Indoor Hydrogen Sulfide (ppm) Indoor Oxygen (%) Initial Sample Canister Vacuum (in Hg) Tightness Test (Vacuum held yes^o?) Differential Pressure (neg port to subsurface) (in HzO) Volume Purged from Sample System (mL) Leak Test Helium Concentration in Shroud (%) Leak Test Helium Concentration in Tedlar Bag (ppm) Draw on Subsurface (in Hg) Final Sample Canister Vacuum (in Hg)
Result 0 0 0 0
20.3 -29.26 Yes
•tO.002 720* 23.8 1,400
-1 -3.83
Begin Time
Date 01/27/09 01/27/09 01/27/09 01/27/09 01/27/09 01/28A)9 01/28/09 01/29/09 01/29/09 01/29A)9 01/29A)9 01/29/09 01/29/09
Time 0815 0815 0815 0815 0815 1814 1853 1027 1141 1141 1142 1146 1424
End Date End Time
Equipment Used RAE Systems Entry RAE PGM-3000 Mutti-Gas Monitor RAE Systems Entry RAE PGM-3000 Mutti-Gas Monttor RAE Systems Entiy RAE PGM-3000 Mutti-Gas Monttor RAE Systems Entry RAE PGM-3000 Mult i^as Monitor RAE Systems Entiy FtAE PGM-3000 Multi-Gas Monttor
Dwyer Instruments Model DPGW-00 digital pressure gauge Canister, manifold, syringe, nyton tubing, anatog vacuum gauge
Omniguard III Differential Pressure Recorder 60 cc syringe, nyton tubing. 3 way valve, Tedlar bag
Dielectric Technologies Utodel MGD-2002 helium detector Oielectrto Technologies Model MGD-2002 helium detector
Anatog vacuum gauge Dwyer Instmments Model DPGW-00 digttal pressure gauge
Analyte
Benzene Ethylbenzene Toluene Xylenes, Total Naphthalene Helium
Method
Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 Hiqh/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with Low Level Modified ASTM D-1945
Laboratory
AirToxics, Inc. AirToxics, inc. AirToxics, Inc. /MrToxics, Inc. AirToxics, Inc. AirToxics, Inc.
Hold Time
30 days 30 days 30 days 30 days 30 days 30 days
Component
Open Slab Hole Subslab Probe Sample Tubing Sampling Manifold Purge Tubing 3 System Volumes
Volume
2.4 mL 1.4 mL 10.8 mL 14.5 mL 18.5 mL 143 mL
Weather Conditions ' Temperature = 23.0 °F, Dew Point = 14.0 °F, Humidity = 68%, Sea Level Pressure = 29.96 in Hg and rising. Wind = 24.2 mph WNW, Precipitation = None, Sky = Clear (Clinton Municipal Airport at 11:55).
11 Comments/Observations 'Purged 240mL, He in bag = 625 ppm at 1053. Checked and tightened fittings. Purged additional 240mL. He in bag = 1,625 ppm atl 110. Disconnected sample tubing, checked ferrules, passed new tightness test, purged 240mL, He in bag = 1,400ppm at 1142.
12 Karin H. Wilhelm / Randy J. Kroneman Sampler Name(8) Sampler Signature(^
I I I I I I I I I I I I I I I I I n I
ATTACHMENT B
Q M W H
1 Building ID
2 Probe Location ID
3 Sample ID
4
5
6
SOIL GAS SAMPLE COLLECTION RECORD
BLOI
BLOl-SG-SOOl
Client Project Project Number
Interstate Power and Light Company Clinton FMGP -Focused Remedial Investigation 1914390.0102
Soil Gas Probe installation 01/28/09 0947 9.5 feet
Sample Container Summa Date Time
6-liter 4138 Depth Below Surface
4138
- 12.5 feet bgs Depth to Water
Soil Gas Sample Collection Type Volume
01/28/09 Container Laboratory ID Manifold Laboratory ID
16:28:35 01/28/09 1637 Begin
Measurement
Initial Sampte Canister Vacuum (in Hg) Tightness Test (Vacuum held yes/no?) Differential Pressure (neg port to subsurface) (in HzO) Volume Purged from Sample System (mL) Leak Test Helium Concentration in Shroud (%) Leak Test Helium Concentratkm in Tedlar Bag (%) Draw on Subsurface (in Hg) Final Sample Canister Vacuum (in Hg)
Date
Result
-30.42 Yes
-fO.008 1,860 16.7 25.1 -3.25 -2.14
Begin Time
Date
01/28A)9 01/28^)9 01/28/09 01/28/09 01/28/09 01/28A)9 0M2Bm 01/28A)9
Time
0826 0859 1003 1618 1623 1626 1628 1755
End Date End Time
Equipment Used
Dwyer Instruments Model DPGW-00 digital pressure gauge Canister, manifokl, syringe, nyton tubing, anatog vacuum gauge
Omniguard III Differential Pressure Recorder 60 cc syringe, nyton tubing. 3 way valve, Tedlar bag
Dielectnc Technotogles Model MGO-2002 helium detector Oietoctric Technologies Model MGD-2002 helium detector
Anatog vacuum gauge Dwyer Instruments Model DPGW-00 digital pressure gauge
Analyte
Benzene Ethylt>enzene Toluene Xylenes, Total Naphthalene Helium
Method
Modified EPA TO-15 Hiqh/Low Level with SIM Modified EPA TO-15 Hiqh/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with Low Level Modified ASTM D-1945
Laboratory
AirToxics, Inc. AirToxics, Inc. AirToxics, Inc. AirToxics, Inc. /MrToxics, Inc. AirToxics, Inc.
Hold Time
30 days 30 days 30 days 30 days 30 days 30 days
Component
Sample Tubing Sampling Manifold Purge Tubing Cavity Total 3 System Volumes
Volume
69 mL 14.5 mL 18.5mL 522 mL 624 mL 1.872 mL
10 Weather Conditions Temperature = 15.8 °F. Dew Point = 8.6 °F, Humidity = 73%. Sea Level Pressure = 29.93 in Hg and falling. Wind = 8.1 mph SSW, Precipitation = None, Sky = Clear (Clinton Munkiipal Airport at 16:35).
11 Comments/Observations Raised sample depth from 10.5 to 9.5 ft bgs before sample collection. Stopped sampling early due to water in sample tubing. Per Air Toxics, suffk;ient sample volume for analysis, but will have reporting limits elevated - 6.19 times.
12 Karin H. Wilhelm / Randy J. Kroneman Sampler Name(s) Sampler Signaturo(iq
Q M W H 1 Building ID
2 Probe Location ID
3 Sample ID
4
5
6
SOIL GAS SAMPLE COLLECTION RECORD
BLOI
BLOl-SG-EOOl
Client Project Project Numk>er
Interstate Power and Light Company Clinton FMGP -Focused Remedial Investigation 1914390.0102
Soil Gas Probe installation 01/28/09 0947 9.5 feet Date Time
Sample Container Summa 6-liter 931 Depth Below Surface
12.5 feet bgs Depth to Water
931
Soil Gas Sample Coiiection Type Volume
01/28/09 Container t.at>oratory ID Manifold Laboratory ID
11:09:16 01/28/09 15:35:30 Begin
Measurement
Initial Sample Canister Vacuum (in Hg) Tightness Test (Vacuum held yes/no?) Differential Pressure (neg port to subsurface) (in HzO) Volume Purged from Sample System (mL) Leak Test Helium Concentratk>n in Shroud (%) Leak Test Helium Concentration in Tedlar Bag (ppm) Draw on Subsurtace (in Hg) Volume Purged from Sample System (mL) Leak Test Helium Concentration in Shroud (%) Leak Test Helium Concentration in Tedlar Bag (ppm) Draw on Subsurface (in Hg) Final Sample Canister Vacuum (in Hg)
Date
Result
-30.65 Yes
-fO.010 660 20.0
0 0
1,980 13.6
11,925 0
-2.14
Begin Time
Date
01/28A)9 01/28/09 01/28«)9 01/28«)9 01/28A)9 0M2Qm 01/28/09 01/28/09 01/28/09 01/28/09 01/28/09 01/28A)9
Time
0829 0859 0943 1103 1103 1107 1109 1438 1438 1444 1450 1755
End Date End Time
Equipment Used Dwyer Instruments Model DPQW-00 digttal pressure gauge
Canister, manifold, synnge. nylon tubing, anatog vacuum gauge Omniguard III Dttferential Pressure Recorder
60 cc syringe, nyton tubing, 3 way valve, Tedlar bag Dielectric Technologies Model MGD-2002 helium detector OielecUk; Technologies Model MGD-2002 helium detector
Anatog vacuum gauge 60 oc synnge. nylon tubing, 3 way valve, Tedlar bag
Dielectric Technologies Model MGD-2002 heUum detector Dielectric Teohnokigies Model MQ[}-2002 heUum detector Dielectrk: Technotogles Model MGD-2002 helium detector
Dwyer Instruments Model DPGW-00 digital pressure gauge
Analyte
Benzene Ethylbenzene Toluene Xylenes, Total Naphthalene Helium
Method
Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 High/Low Level with SIM Modified EPA TO-15 HighA.ow Level with Low Level Modified ASTM D-1945
Laboratory
AirToxics, Inc. AirToxics, inc. AirToxics, Inc. AirToxics, Inc. AirToxics, Inc. AirToxics, Inc.
Hold Time
30 days 30 days 30 days 30 days 30 days 30 days
9 Component
Sample Tubing Sampling Manifold Purge Tubing Cavity Total 3 System Volumes
Volume
66 mL 14.5 mL 18.5mL 522 mL 621 mL 1,863 mL
10 Weather Conditions Temperature = 15.8 °F, Dew Point = 10.4 °F, Humidity = 68%, Sea Level Pressure = 29.94 in Hg and falling. Wind = 8.1 mph SSW, Precipitation = None, Sky = Clear (Clinton Municipal Airport at 14:55).
11 Comments/Observations Original sample depth = 10.5 ft bgs. Stopped sampling at 11 ;25:50 due to water in sample tubing. Raised sample point to 9.5 ft bgs. Restarted sample collection at 14:50:30.
12 Karin H. Wilhelm / Randy J. Kroneman Sampler Name(s) Sampler S fgnature(^
I I I I I I I I I I 6 II H B i ATTACHMENT C B
B
»
• I V QMWH
I ^ H I
fl Keystone Laboratories, Inc. - Newton I SDG: 18J0485
CLASS: GCMS I METHOD: EPA 8260B
H B I I I I I I 1 I I I I I I I Page 1 of I
ANALYSES DATA PACKAGE COVER PAGE EPA 8260B
Laboratory: Keystone Laboratories, Inc - Newton
Client: MWH Americas, Inc.-IA
SDG: 18J0485
Project- IPL-Clinton FMGP Site
Client Sample Id:
PZOl-GW-009
PZ02-GW-009
PZ03-GW-009
PZ4R-GW-009
PZ05-GW-009
MW32-GW-009
MW66-GW-009
PZOl-GW-901
BL02-SW-I001
Lab Sample Id:
18J0485-01
18J0485-02
18J0485-03
18J0485-04
18J0485-05
18J0485-06
18J0485-07
18J0485-08
18J0485-09
I certify that this data package is in compliance with the terms and conditions ofthe contract, both technically and for completeness, for other than the conditions detailed above. Release ofthe data contained in this hardcopy data package and in computer-readable data submitted on diskette has been autonzed by the Laboratory Manager or the Manager's designee, as venfied by the following signatures.
Signature Name: Jeffrey King, Ph.D.
Date: February 06, 2009 Title: Laboratory Director
Page I of 1
METHOD DETECTION AND REPORTING LIMITS EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Amencas. Inc.-IA
Matrix: Water
SDG: I8J0485
Project: IPL-Clinlon FMGP Site
Instrument: MS #1
Analyte
Chioromethane
Vinyl Chlonde
Bromomethane
Chloroethane
Tnchlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chlorofonn
1,1,1 -Tnchloroethane
Carbon Tetrachloride
Benzene
1.2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dlbromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromofonn
1,1,2,2-Tetrachloroethane
MDL
06
08
0.5
0.6
0.7
0.4
1 7
1.0
3.9
02
08
03
0.2
0.4
0.4
0.2
0.2
0.3
02
02
0.2
03
0.2
0.3
0.4
01
0.2
02
02
05
02
0.3
MRL
1.0
1.0
10
1.0
1.0
1.0
10.0
1.0
5.0
10
20
1.0
10
1.0
10
1.0
1.0
10
1.0
1.0
1.0
I 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
1 0
Units
ug/l
ug/l
ug/l
ug/'l
ug/l
ug/l
ug'I
ug/l
ug/I
ug/l
ug/l
ug/l
ug/l
ug'I
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Page 1 of 1
ORGANIC ANALYSIS DATA SHEET EPA 8260B
PZOl-GW-009
Laboratory. Kevstone Laboratories. Inc. - Newton
Client: MWH Amencas. Inc.-lA
Matrix: Water Laboratory ID:
Sampled: 10/07/08 17 50 Prepared:
Solids: Preparation:
Batch: IJ8I413 Sequence 18J1413
SDG:
Project:
18J0485-01
10/14/08 00 00
EPA 5030B
Calibration-
18J0485
IPL-Clinton FMGP Site
File ID: 1V015.D
Analyzed: 10/14/08 21:57
Initial/Final: 5 ml / 5 ml
18J110I Instrument: MS#1
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
108-88-3
10061-02-6
79-00-5
127-18-4
124-48-1
106-93-4
108-90-7
100-41-4
1330-20-7
75-25-2
79-34-5
COMPOUND
Chioromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Mcthyl-t-butyl Ether (MTBE)
1,1 -Dichloroethane
Chloroform
1,1,1-Trichloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dlbromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromoform
1,1,2,2-Tetrachloroethane
DILUTION CONC. (ug/l)
1.0
1.0
1.0
1.0
1 0
1.0
10.0
1 0
50
1.0
2.0
1.0
1.0
1.0
1.0
1 0
1.0
10
1.0
1.0
1 0
10
1 0
1.0
1.0
10
1.0
1.0
1.0
2.0
1.0
1.0
Q
u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u
SYSTEM MONITORING COMPOLTND
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
ADDED (ug/l)
50.0000
50 OOOO
50 OOOO
50.0000
CONC (ug/l)
55.8
49.6
51.2
47 3
% REC
112
99 2
102
94.7
QC LIMITS
7 4 - 132
7 4 - 1 3 3
8 5 - 1 1 5
7 7 - 122
Q
* Values outside of QC limits
Page 1 o f 9
B ORGANIC ANALYSIS DATA SHEET EPA 8260B
PZ02-G\V-009
Laboratory Kevstone Laboratones. Inc. - Newton
Client. MWH Amencas. Inc.-IA
Matri,x: Water Laborator
Sampled: 10/07/08 13:30 Prepared.
I Solids: Preparation
' Batch: 1J81413 Sequence:
rylD:
an:
18J1413
SDG:
Project-
18J0485-02
10/14/08 00 00
EPA 5030B
Calibration.
18J0485
IPL-Clinton FMGP Site
File ID:
Analyzed:
Initial/Final:
I8J1101
1V012.D
10/14/08 20:02
5 ml /5 ml
Instrument. MS#I
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67 64-1
75 15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
lOS-88-3
10061-02-6
79-00-5
127-18-4
124-48-1
106-93-4
108-90-7
100-41-4
1330-20-7
75-25-2
79-34-5
COMPOUND
Chioromethane
Vinyl Chlonde
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chloroform
1,1,1-Trichloroethane
Carbon Tetrachlonde
Benzene
1,2-Dichloroethane
Tnchloroethylene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dlbromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromofonn
1,1,2,2-Tetrachloroethane
DILUTION
1
CONC. (ug/l)
1 0
1.0
1 0
1 0
l.O
1.0
10.0
1.0
5.0
1.0
2.0
1.0
1.0
1 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1 0
1 0
10
I 0
1.0
1.0
1.0
20
1 0
1.0
Q
u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u
SYSTEM MONITORING COMPOUND
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromonuorobenzene
ADDED (ug/l)
50.0000
50.0000
50.0000
50.0000
CONC (ug/l)
57 6
51.0
50.5
48.5
% REC
115
102
101
96 9
QC LIMITS
74- 132
74- 133
85-115
77- 122
Q
• Values outside of QC limits
Page 2 of9
ORGANIC ANALYSIS DATA SHEET EPA 8260B
PZ03-GW-009
Laboratory: Kevstone Laboratories. Inc. - Newton
Client; MWH Amencas. Inc.-IA
Matnx: Water Laboratory ID:
Sampled: 10/07/08 15:25 Prepared:
Solids: Preparation-
Batch. 1J81413 Sequence. 18J1413
SDG:
Project:
18J0485-03
10/14/08 00-00
EPA 5030B
Calibration:
18J0485
IPL-Clinton FMGP Site
File ID: 1V0I3.D
Analyzed: 10/14/08 20:40
Initial/Final: 5 ml / 5 ml
18J1101 Insttument: MS#1
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
108-88-3
10061-02-6
79-00-5
127-18-4
124^8-1
106-93-4
108-90-7
100-41-4
1330-20-7
75-25-2
79-34-5
COMPOUND
Chioromethane
Vinyl Chlonde
Bromomethane
Chloroethane
Tnchlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chlonde
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1 -Dichloroethane
Chloroform
1,1,1 -Trichloroethane
Carbon Tetrachlonde
Benzene
1,2-Dichloroethane
Tnchloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Tnchloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromoform
1,1,2,2-Tetrachloroethane
DILUTION CONC. (ug/l)
1 0
1.0
1.0
1.0
1.0
1.0
10.0
1.0
5.0
10
2.0
1 0
1.0
1.0
1.0
7.0
1.0
1.0
1.0
10
1.0
1 0
10
1 0
10
1.0
1.0
1.0
9.6
167
1.0
1.0
Q
u u u u u u u u u u u u u u u
u u u u u
u u u u u u
u u
SYSTEM MONITORING COMPOUND
Dibromofl uoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
ADDED (ug/l)
50.0000
50 OOOO
50 OOOO
50.0000
CONC (ug/l)
57 6
51.5
51.6
50.0
% R E C
115
103
103
100
QC LIMITS
7 4 - 132
7 4 - 1 3 3
8 5 - 1 1 5
7 7 - 122
Q
* Values outside of QC limits
Page 3 of 9
B ORGANIC ANALYSIS DATA SHEET EPA 8260B
PZ4R-GW-009
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Amencas. Inc.-lA
I Matrix. Water Laboratoi
Sampled 10/08/08 09:25 Prepared.
I Solids Preparation
Batch. 1J8I413 Sequence:
rylD.
on:
I8JI413
SDG-
Project:
18J0485-04
10/14/08 00:00
EPA 5030B
Calibration:
I8J0485
IPL-Clinton FMGP Site
Flic ID:
Analyzed:
Initial/Final:
18J1I0I
1V025D
10/15/08 04 22
5 ml / 5 ml
Instrument: MS#1
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
7901-6
78-87-5
75 27-4
10061-01-5
108-88-3
10061-02-6
79-00-5
127-18-4
124-48-1
106-93-4
108-90-7
100-41-4
1330-20-7
75-25-2
79-34-5
COMPOUND
Chioromethane
Vinyl Chlonde
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulflde
Methylene Chlonde
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chloroform
1,1,1-Tnchloroethane
Carbon Tetrachlonde
Benzene
1,2-Dichlorocthane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromofonn
1,1,2,2-Tetrachloroethane
DILUTION
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
CONC (ug/l)
10 0
10.0
100
IOO
10.0
10.0
100
10.0
50 0
10 0
20.0
10.0
10.0
10.0
10.0
108
10 0
10 0
10.0
10 0
10.0
157
10.0
10.0
10.0
10.0
10.0
10.0
126
417
10.0
10.0
Q
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
D
DU
DU
DU
DU
DU
D
DU
DU
DU
DU
DU
DU
D
D
DU
DU
SYSTEM MONITORING COMPOUND
Dibiomofluoromethane
l,2-Dichlorocthane-d4
Toluene-d8
4- Brornofl uorobenzene
ADDED (ug/l)
50.0000
50.0000
50.0000
50 OOOO
CONC (ug/l)
54 5
50.7
52.2
48 3
% REC
109
101
104
96.6
QC LIMITS
7 4 - 132
7 4 - 1 3 3
8 5 - 1 1 5
7 7 - 122
Q
Values outside of QC limits
Page 4 of 9
ORGANIC ANALYSIS DATA SHEET EPA 8260B
PZ05-GW-009
Laboratory Kevstone Laboratories. Inc. - Newton
Client: MWH Amencas. Inc.-IA
Matrix- Water Laboratory ID-
Sampled: 10/07/08 1630 Prepared:
Solids- Preparation:
Batch. 1J81413 Sequence: 18J1413
SDG.
Project.
18J0485-05
10/14/08 00:00
EPA 5030B
Calibration-
18J0485
IPL-Clinton FMGP Site
File ID- 1V014.D
Analyzed: 10/14/08 21:19
Initial/Final: 5 ml / 5 ml
18J1101 Instmment: MS#I
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
108-88-3
10061-02-6
79-00-5
127-18-4
124-48-1
106-93-4
108-90-7
100-41-4
1330-20-7
75-25-2
79-34-5
COMPOUND
Chioromethane
Vinyl Chlonde
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1 -Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chloroform
1,1,1-Trichloroethane
Carbon Tetrachlonde
Benzene
1,2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Tnchloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dlbromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromofonn
1,1.2,2-Tetrachloroethane
DILUTION CONC. (ug/l)
10
10
I.O
1.0
10
1.0
IOO
1.0
5.0
1.0
20
1.0
10
1 0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
1.0
10
1 0
20
1.0
1.0
Q
u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u
SYSTEM MONITORING COMPOUND
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4- Bromofluorobenzene
ADDED (ug/l)
50.0000
50.0000
50.0000
50.0000
CONC (ug/l)
55.0
50.8
53.4
50.0
%R£C
no 102
107
IOO
QC LIMITS
74- 132
74 - 133
85-115
77- 122
Q
* Values outside of QC limits
Page 5 of 9
B I I
ORGANIC ANALYSIS DATA SHEET EPA 8260B
MW32-GW-009
Laboratory. Kevstone Laboratories. Inc. - Newton
Client: MWH Amencas. Inc.-lA
Matnx: Water Laborator
Sampled. 10/08/08 12.00 Prepared.
Solids- Preparation:
Batch: 1J8I413 Sequence:
rylD-
on:
18J1413
SDG.
Project.
18J0485-06
10/14/08 00 00
EPA 5030B
Calibration:
I8J0485
IPL-Climon FMGP Site
File ID:
Analyzed-
Initial/Final:
18J1101
1V033.D
10/15/08 09.39
5 m l / 5 m l
Instrument- MS#1
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
108-88-3
10061-02-6
79-00-5
127-18-4
124-48-1
106-93-4
108-90-7
100-41-4
1330-20-7
75-25-2
79-34-5
COMPOUND
Chioromethane
Vinyl Chlonde
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chlorofonn
1,1,1-Trichloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Tnchloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropcne
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromoform
1,1,2,2-Tetrachloroethane
DILUTION
10
10
10
10
10
10
50
50
10
10
50
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
CONC. (ug/l)
10 0
10.0
10.0
10.0
10.0
10.0
500
50.0
50.0
10.0
100
10.0
10.0
10.0
10 0
168
10.0
10.0
10 0
10.0
10 0
477
10 0
10.0
10.0
10.0
10.0
10.0
255
670
10.0
ID.O
Q
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
DU
D
DU
DU
DU
DU
DU
D
DU
DU
DU
DU
DU
DU
D
D
DU
DU
SYSTEM MONITORING COMPOUND
Dibromofluoromethane
l,2-Dichloroethane-d4
Toluene-d8
4-Bromofl uorobenzene
ADDED (ug/l)
50.0000
50.0000
50.0000
50.0000
CONC (ug/l)
54.3
49.8
53.8
49 7
% REC
109
99.5
108
99.4
QC LIMITS
7 4 - 1 3 2
7 4 - 1 3 3
8 5 - 1 1 5
7 7 - 122
Q
* Values outside of QC limits
Page 6 of 9
ORGANIC ANALYSIS DATA SHEET EPA 8260B
MW66-GW-009
Laboratory: Kevstone Laboratories. Inc - Newton
Client. MWH Americas. Inc.-IA
Matnx: Water Laboratory ID.
Sampled: 10/08/08 09:02 Prepared:
Solids: Preparation-
Batch: IJ8I413 Sequence- 18J1413
SDG:
Project:
18J0485-07
10/14/08 00 00
EPA 5030B
Calibration:
18J0485
IPL-Clinton FMGP Site
File ID: 1V024.D
Analyzed: 10/15/08 03:44
Initial/Final- 5 ml / 5 ml
18J1101 Instmment: MS#1
CAS NO
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
108-88-3
10061-02-6
79-00-5
127-18-4
124^8-1
106-93-4
108-90-7
100-41-4
1330-20-7
75-25-2
79-34-5
COMPOUND
Chioromethane
Vinyl Chloride
Bromomethane
Chloroethane
Tnchlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chlonde
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chloroform
1,1,1 -Trichloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Tnchloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dlbromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromofonn
1,1,2,2-Tetrachloroethane
DILUTION CONC. (ug/l)
1.0
1.0
1.0
1.0
1.0
1.0
10.0
10
5.0
1.0
20
1.0
1.0
1.0
1.0
57.5
1.0
1 0
1.0
1.0
1.0
28.2
1.0
10
1.0
1.0
1.0
1.0
9.6
37 1
1.0
1.0
Q
u u u u u u u u u u u u u u u
u u u u u
u u u u u u
u u
SYSTEM MONITORING COMPOUND
Dibromofluoromethane
1,2-Dich)oroethane-d4
Toluene-d8
4-Bromofluorobenzene
ADDED (ug/l)
50.0000
50.0000
50.0000
50.0000
CONC (ug/l)
57 6
52.5
51.7
49.3
%REC
115
105
103
98.5
QC LIMITS
74-132
74- 133
85-115
77- 122
Q
' Values outside of QC limits
Page 7 of 9
ORGANIC ANALYSIS DATA SHEET EPA 8260B
PZOI-GW-901
Laboratory Kevstone Laboratones. Inc. - Newton
Client- MWH Amencas. Inc -IA
Matnx Water Laborato
Sampled: 10/07/08 08-00 Prepared
Solids: Preparation
Batch. 1J8I413 Sequence.
rylD:
on.
18J1413
SDG.
Project.
18J0485-08
10/14/08 00-00
EPA 5030B
Calibration
18J0485
IPL-Clinton FMGP Site
File ID-
Analyzed.
Initial/Final-
18J1101
1V017.D
10/14/08 23:14
5 ml /5 ml
Instrument MS#1
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
108-88-3
10061-02-6
79-00-5
127-18-4
124-48-1
106-93-4
108-90-7
100-41-4
1330-20-7
75-25-2
79-34-5
COMPOUND
Chioromethane
Vinyl Chloride
Bromomethane
Chloroethane
Tnchlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chloroform
1,1,1-Tnchloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromoform
1,1,2,2-Tetrachloroethane
DILUTION CONC. (ug/l)
1.0
1.0
1 0
1 0
1.0
I.O
10.0
1.0
5.0
1.0
2.0
1.0
1 0
10
1.0
1.0
10
1.0
1.0
1.0
10
10
1.0
1 0
1.0
1 4
10
1.0
10
2.0
1.7
1 0
Q
u u u u u u u u u u u u u u u u u u u u u u u u u
u u u u
u
SYSTEM MONITORING COMPOUND
Dibromofl uoromethane
1,2-Dichloroeihane-d4
ToIuene-d8
4- B romofl uorobenzene
ADDED (ug/l)
50.0000
50 OOOO
50.0000
50 OOOO
CONC (ug/l)
55.6
51.4
51.0
46 4
% REC
111
103
102
92.7
QC LIMITS
7 4 - 132
7 4 - 1 3 3
8 5 - 1 1 5
7 7 - 122
Q
' Values outside of QC limits
Page 8 of 9
ORGANIC ANALYSIS DATA SHEET EPA 8260B
BL02-SW-I001
Laboratory: Kevstone Laboratones. Inc. - Newton
Client- MWH Americas. Inc.-IA
Matrix. Water Laboratory ID-
Sampled: 10/08/08 10:15 Prepared
Solids: Preparation:
Batch: IJ8I413 Sequence: 18J14I3
SDG:
Project:
18J0485-09
10/14/08 00.-00
EPA 5030B
Calibration-
18J0485
IPL-Clinton FMGP Site
File ID. IVOII D
Analyzed: 10/14/08 19:24
Initial/Final. 5 ml / 5 ml
18J1101 Instmment: M S # I
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
108-88-3
10061-02-6
79-00-5
127-18-4
124-48-1
106-93-4
108-90-7
100-41-4
1330-20-7
75-25-2
79-34-5
COMPOUND
Chioromethane
Vinyl Chloride
Bromomethane
Chloroelhane
Tnchlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1.1-Dichloroethane
Chloroform
1,1,1 -Tnchloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Tnchloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromofonn
1,1,2,2-Tetrachloroethane
DILUTION CONC (ug/l)
10
1.0
1 0
1.0
1.0
10
10.0
1.0
5.0
10
2.0
1.0
1.0
10
1.0
1.0
1 0
1 0
1.0
1 0
1.0
1.0
1 0
1.0
10
1.0
1.0
1.0
1.0
2.0
1.0
1.0
Q
u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u
SYSTEM MONITORING COMPOUND
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
ADDED (ug/l)
50.0000
50.0000
50.0000
50 OOOO
CONC (ug/l)
56.4
51.6
50.7
49.8
% REC
113
103
101
99.6
QC LIMITS
7 4 - 132
7 4 - 133
8 5 - 1 1 5
7 7 - 1 2 2
Q
* Values outside of QC limits
Page 9 o f 9
I I I
PREPARATION BATCH SUMMARY EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Amencas. Inc.-IA
Batch: 1J81413 Batch Matnx Water
SDG:
Project:
Preparation:
18J0485
IPL-Clinton FMGP Site
EPA 5030B
SAMPLE NAME
PZOl-GW-009
PZOl-GW-009
PZ02-GW-009
PZ02-GW-009
PZ03-GW-009
PZ03-GW-009
PZ4R-GW-009
PZ4R-GW-009
PZ05-GW-009
PZ05-GW-009
MW32-GW-009
MW32-GW-009
MW66-GW-009
MW66-GW-009
PZOl-GW-901
PZOl-GW-901
BL02-SW-1001
BL02-SW-1001
Blank
LCS
PZOl-GW-009
PZOl-GW-009
LAB SAMPLE ID
18J0485-01
18J0485-01
18J0485-02
18J0485-02
18J0485-03
18J0485-03
18J0485-04
18J0485-04
18J0485-05
18J0485-05
18J0485-06
18J0485-06
I8J0485-07
18J0485-07
18J0485-08
18J0485-08
18J0485-09
18J0485-09
1J81413-BLK1
1J8I413-BS1
1J81413-MS1
IJ81413-MSDI
LAB FILE ID
IV015.D
1V015.D
1V012.D
1V012.D
1V013.D
1V013D
1V025.D
1V025D
IV014D
1V014.D
1V026D
1V033.D
1V024D
1V024D
1V017.D
IV0I7.D
IVOll D
IVOll D
1V009.D
1V004.D
1V005.D
1V006.D
DATE PREPARED
10/14/08 00:00
10/14/08 00:00
10/14/08 00:00
10/14/08 00:00
10/14/08 00:00
10/14/08 00.00
10/14/08 00:00
10/14/08 00.00
10/14/08 00.00
10/14/08 00:00
10/14/08 00.00
10/14/08 00-00
10/14/08 00:00
10/14/08 00:00
10/14/08 00:00
10/14/08 00:00
10/14/08 00:00
10/14/08 00:00
10/14/08 00-00
10/14/08 00:00
10/14/08 00:00
10/14/08 00-00
OBSERVATIONS
CLP Level 4 QC
CLP Level 4 QC
CLP Level 4 QC
CLP Level 4 QC
CLP Level 4 QC
CLP Level 4 QC
CLP Level 4 QC
CLP Level 4 QC
CLP Level 4 QC
I I B I I I Page 1 of 1
METHOD BLANK DATA SHEET EPA 8260B
Laboratory.
Client-
Matrix.
Prepared:
Analyzed:
Batch
Kevstone Laboratories
MWH Americas,
Water
10/14/08 00:00
10/14/08 18 07
1J81413
Inc-
, Inc.
[A
- Newton
Laboratory
Preparation:
Instmment:
Sequence:
ID.
SDG:
Project:
1J81413-BLK1
EPA 5030B
MS#1
18J1413
18J0485
IPL-CIinton FMGP Site
File ID:
Initial/Final:
Calibration:
IV009.D
5 ml / 5 ml
18J1101
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
108-88-3
10061-02-6
79-00-5
127-18-4
124-48-1
106-93-4
108-90-7
100-41-4
1330-20-7
COMPOUND
Chioromethane
Vinyl Chlonde
Bromoinethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chloroform
1,1,1-Tnchloroethane
Carbon Tetrachlonde
Benzene
1,2-Dichloroethane
Tnchloroethylene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibroinoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
CONC. (ug/l)
10
10
1.0
1.0
10
1.0
10.0
1 0
5.0
1.0
2.0
1.0
1.0
10
10
1 0
1.0
1.0
1.0
1.0
1.0
I.O
I.O
1.0
10
1.0
1.0
1.0
1.0
2.0
Q
u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u
Page 1 of 5
I METHOD BLANK DATA SHEET EPA 8260B
Laboratory: Kevstone Laboratones. Inc. - Newton SDG
Client: MWH Amencas. Inc.-IA Project:
Matnx: Water Laboratory ID: 1J81413-BLKI
Prepared: 10/14/08 00:00 Preparation: EPA 5030B
Analyzed. 10/14/08 18.07 Instmment MS#1
Batch: IJ81413 Sequence 18J14I3
18J0485
IPL-Clinton FMGP Site
Flic ID- 1 V009.D
Initial/Final- 5 ml /5 ml
Calibration: 18J1101
CAS NO.
75-25-2
79-34-5
COMPOUND
Bromofonn
1,1,2,2-Tetrachlorocthane
CONC. (ug/l)
1.0
1 0
Q
u u
SYSTEM MONITORING COMPOUND
Dibrornofluoroinethane
1.2-Dichloroethane-d4
Toluene-d8
4- B roino fl uorobenzene
ADDED (ug/l)
50.0000
50.0000
50.0000
50.0000
CONC (ug/l)
55.3
52 0
50.8
50.1
% REC
ni
104
102
100
QC LIMITS
74- 132
74- 133
85-115
77-122
Q
Page 2 of 5
EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Americas. Inc.-IA
Matnx: Water
Batch: IJ8I413
Preparation: EPA 5030B
:ATE RECOVERY
SDG:
Project:
Laboratory ID:
Initial/Final:
PZOl-GW-009
18J0485
IPL-Clinton FMQP Site
IJ8I4I3-MS1
5 ml / 5 ml
Source Sample Name. PZOl-GW-009
COMPOUND
Chioromethane
Vinyl Chlonde
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1 -Dichloroethylene
Acetone
Carbon Disulflde
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chloroform
1,1,1-Tnchloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropcne
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromoform
1,1,2,2-Tetrachloroethane
SPIKE ADDED
(ug/l)
1065 50
1010.00
1095.50
1036.00
1021 00
500.000
1648.00
1160 00
500.000
500 000
1144.00
500.000
500 000
500.000
500 000
500.000
500.000
500 000
500.000
500.000
500 000
500.000
500.000
500.000
500.000
500.000
500.000
500.000
500.000
1500.00
500 000
500 000
SAMPLE CONCENTRATION
(ug/l)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
MS CONCENTRATION
(ug/l)
930 8
1055
915.3
974 0
1304
508.5
1060
1093
530.4
493 1
995 4
484.9
488.2
476.3
486.9
495.1
463.7
488.4
485 1
490 4
473.7
476 6
464 3
447 3
460.8
457.4
442 5
465.2
470 0
1391
418.8
444 5
MS %
REC.#
87 4
104
83.6
94 0
128
102
64 3
94.2
106
98.6
87.0
97.0
97.6
95.3
97.4
99 0
92.7
97.7
97.0
98.1
94.7
95.3
92 9
89 5
92.2
91.5
88.5
93.0
94.0
92 7
83 8
88.9
QC LIMITS
REC.
60- 140
79 - 140
60-140
67 - 140
90-140
81 - 140
60- 134
66- 133
65-127
76- 132
60- 140
72-137
78 - 124
84- 126
83-129
62 - 140
63-138
82- 125
82-121
84-116
70-128
76-138
72-122
81-117
84-122
76-121
60 - 140
84-116
65-140
61 - 137
62-121
76- 122
Page 3 of 5
MATRIX SPIKE / MATRIX SPIKE DUPLICATE RECOVERY EPA 8260B
PZOl-CW-009
Laboratory: Kevstone Laboratories. Inc - Newton
Client: MWH Americas. Inc.-IA
Matrix: Water
Batch: 1J81413
Preparation: EPA 5030B
SDG.
Project.
Laboratory ID-
Initial/Final:
I8J0485
IPL-Clinton FMGP Site
1J81413-MSI
5 ml / 5 ml
Source Sample Name: PZOl-GW-009
COMPOUND
Chioromethane
Vinyl Chlonde
Bromomethane
Chloroethane
Tnchloro fl uoromethane
1,1 -Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
Chloroform
1.1,1-Tnchloroethane
Carbon Tetrachloride
Benzene
1.2-Dichloroethane
Tnchloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1 ,:i-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Tnchloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromoform
1.1,2,2-Tetrachloroethane
SPIKE ADDED
(ug/l)
1065.50
1010.00
1095.50
1036.00
1021.00
500.000
1648 00
1160.00
500.000
500 000
1144.00
500.000
500.000
500.000
500.000
500 000
500 000
500.000
500.000
500.000
500.000
500.000
500.000
500 000
500.000
500 000
500 000
500.000
500.000
1500.00
500.000
500 000
MSD CONCENTRATION
(ug/l)
1033
1190
lOII
1104
1444
555.3
1185
1219
590.8
541.3
1112
534.1
541.9
527.3
536 9
530 0
480.8
536.3
517.1
518 1
505.2
491 8
491 7
466.5
521.0
495.6
477.5
492.4
514.7
1498
443.8
484.3
MSD %
REC n
97 0
118
92.3
107
141 •
111
71.9
105
118
108
97.2
107
108
105
107
106
96 2
107
103
104
101
98.4
98.3
93.3
104
99.1
95 5
98.5
103
99.9
88.8
96.9
% RPD#
10.4
12.0
9.91
12.5
102 *
8 80
11 1
10 9
108
9 32
11.1
9.66
104
10.2
9.77
681
3.62
9 35
6.39
5.49
644
3 14
5.73
4.20
12.3
8.02
7.61
5 68
9 08
7.43
5.80
8.57
QC
RPD
18
21
26
23
10
15
19
20
22
16
13
14
14
15
16
20
17
17
20
23
23
18
21
25
14
18
19
14
13
13
22
17
LIMITS
REC
60-140
79-140
60- 140
67- 140
90- 140
81 - 140
60-134
66- 133
65- 127
76- 132
60-140
72- 137
78-124
84- 126
83- 129
62-140
63- 138
82- 125
82- 121
84-116
70-128
76- 138
72- 122
81 -117
84-122
76- 121
60-140
84-116
65 - 140
61 -137
62-121
76- 122
Page 4 of 5
# Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
Page 5 of 5
I I I I i I I I I I I I i I I I I i I
LCS / LCS DUPLICATE RECOVERY EPA 8260B
Laboratory:
Client-
Matnx:
Batch:
Preparation:
Kevstone Laboratories. Inc. - Newton
MWH Americas. Inc -IA
Water
1J81413
EPA 5030B
SDG:
Project:
Laboratory ID:
Initial/Final:
18J0485
IPL-Clinton FMGP Site
1J81413-BS1
5 ml / 5 ml
COMPOUND
Chioromethane
Vinyl Chloride
Bromomethane
Chloroethane
Tnchlorofluoromethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chlonde
trans-1,2-Dichloroethylene
Mcthyl-t-butyl Ether (MTBE)
Ul-Dichloroethane
Chlorofonn
1.1,1-Tnchlorocthane
Carbon Tetrachloride
Benzene
1.2-Dichloroethanc
Trichloroethylene"
1,2-Dichloropropane
Bromodichloromethane
CIS-1, j-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Tnchloroethane
Tetrai-hloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
SPIKE
ADDED
(ug/l)
106.550
101.000
109.550
103.600
102.100
50.0000
164.800
116.000
50.0000
50 0000
114.400
50.0000
50.0000
50.0000
50.0000
50 OOOO
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50 OOOO
50.0000
50.0000
50.0000
50.0000
150.000
LCS
CONCENTRATION
(ug/l)
99.08
110.2
97.93
103.8
134.8
52 63
132.0
114.1
48.06
51.25
106,5
51.34
50.87
49 23
51 26
50.99
47.93
50.41
49.05
50.24
48.47
48.89
46.79
47.23
50.92
48.76
46.53
48.24
50.05
144.2
LCS
%
REC #
93.0
109
89 4
100
132
105
80.1
98.3
96.1
102
93 1
103
102
98.5
103
102
95 9
101
98.1
100
96.9
97 8
93.6
94 5
102
97.5
93.1
96.5
100
96.1
QC
LIMITS
REC
6 0 - 140
77 - 140
63 - 140
7 4 - 140
9 0 - 140
8 4 - 1 3 7
61 - 132
6 8 - 134
7 4 - 125
7 9 - 128
60 - 140
81 - 132
8 3 - 1 1 6
8 6 - 122
8 8 - 1 2 4
6 8 - 138
6 6 - 1 3 5
8 5 - 122
8 3 - 1 2 2
8 2 - 1 1 8
7 5 - 1 2 4
7 0 - 140
7 6 - 1 2 2
8 2 - 1 1 8
8 4 - 127
8 6 - 1 1 7
6 0 - 140
8 7 - 1 1 6
70 - 140
61 - 140
Page 1 of2
LCS / LCS DUPLICATE RECOVERY EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Americas. Inc.-IA
Matrix: Water
Batch. 1J81413
Preparation EPA 5030B
SDG:
Project:
Laboratory ID:
Initial/Final:
18J0485
IPL-Clinton FMGP Site
1J81413-BS1
5 ml / 5 ml
COMPOUND
Bromofonn
1,1,2,2-Tetrachloroethane
SPIKE
ADDED
(ug/l)
50.0000
50 OOOO
LCS
CONCENTRATION
(ug/l)
46.00
45.79
LCS
%
REC.#
92.0
916
QC
LIMITS
REC
7 5 - 1 2 0
7 4 - 126
# Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
Page 2 of2
I 1 I I I I I I B I I I I I i I 1 I I
ANALYSIS BATCH (SEQUENCE) SUMMARY EPA 8260B
Laboratory.
Client.
Sequence:
Matrix:
Kevstone Laboratories. Inc.
MWH Americas. Inc -IA
18JI413
Water
- Newton SDG.
Project:
Instmment:
Calibration
18J0485
IPL-Clinton FMGP Site
MS#1
18J1101
Sample Name
MS Tune
Calibration Check
LCS
PZOl-GW-009
PZOl-GW-009
Blank
BL02-SW-1001
BL02-SW-1001
BL02-SW-1001
BL02-SW-1001
PZ02-GW-009
PZ02-GW-009
PZ02-GW-009
PZ02-GW-009
PZ03-GW-009
PZ03-GW-009
PZ03-GW-009
PZ03-GW-009
PZ05-GW-009
PZ05-GW-009
PZ05-GW-009
PZ05-GW-009
PZOl-GW-009
PZOl-GW-009
PZOI-GW-009
PZOl-GW-009
PZOl-GW-901
PZOl-GW-901
PZOl-GW-901
PZOl-GW-901
MS Tune
Calibration Check
Lab Sample ID
18JI4I3-TUN1
I8J1413-CCV1
1J81413-BS1
1J8I413-MS1
1J81413-MSD1
1J81413-BLK1
18J0485-09
18J0485-09
18J0485-09
I8J0485-09
18J0485-02
18J0485-02
18J0485-02
18J0485-02
18J0485-03
18J0485-03
I8J0485-03
18J0485-03
18J0485-05
18J0485-05
18J0485-05
18J0485-05
18J0485-01
18J0485-0I
18J0485-01
18J0485-01
18J0485-08
18J0485-08
18J0485-08
18J0485-08
18J1413-TUN2
18J1413-CCV2
Lab File ID
IVOOI.D
1V002D
1V004.D
1V005.D
1V006 D
1V009.D
IVOll.D
IVOll D
IVOll.D
IVOll.D
1V012.D
1V012.D
1V0I2.D
1V012D
1V0I3D
1V013.D
IV013.D
1V013.D
1V014D
1V014D
IV014.D
1V014.D
1V015D
1V0I5.D
IV015.D
1V015.D
1V017D
1V0I7D
IV017.D
1V017.D
IV019D
1V021.D
Analysis Date/Time
10/14/08 13.02
10/14/08 13.40
10/14/08 14.56
10/14/08 15:34
10/14/08 16.12
10/14/08 18-07
10/14/08 19-24
10/14/08 19 24
10/14/08 19:24
10/14/08 19:24
10/14/08 20:02
10/14/08 20:02
10/14/08 20:02
10/14/08 20.02
10/14/08 20:40
10/14/08 20:40
10/14/08 20-40
10/14/08 20 40
10/14/08 21 19
10/14/08 21:19
10/14/08 21-19
10/14,/08 21:19
10/14/08 21:57
10/14/08 21:57
10/14/08 21-57
10/14/08 21.-57
10/14/08 23:14
10/14/08 23:14
10/14/08 23-14
10/14/08 23:14
10/15/08 00.32
10/15/08 01:48
Page 1 of 2
ANALYSIS BATCH (SEQUENCE) SUMMARY EPA 8260B
Laboratory
Client:
Sequence:
Matnx.
Kevstone Laboratories. Inc
MWH Amencas. Inc.-IA
18J14I3
Water
- Newton SDG:
Project:
Instmment:
Calibration:
18J0485
IPL-Clinton FMGP Site
MS#I
18J1101
Sample Name
' MW66-GW-009
MW66-GW-009
MW66-GW-009
MW66-GW-009
PZ4R-GW-009
PZ4R-GW-009
PZ4R-GW-009
PZ4R-GW-009
MW32-GW-009
MW32-GW-009
MW32-GW-009
MW32-GW-009
Lab Sample ID
18J0485-07
18J0485-07
18J0485-07
18J0485-07
18J0485-04
18J0485-04
18J0485-04
I8J0485-04
18J0485-06
18J0485-06
18J0485-06
18J0485-06
Lab File ID
1V024.D
1V024.D
1V024.D
1V024D
1V025.D
1V025.D
1V025D
1V025.D
1V026.D
1V026.D
1V026D
1V033D
Analysis Date/Time
10/15/08 03:44
10/15/08 03 44
10/15/08 03.44
10/15/08 03:44
10/15/08 04:22
10/15/08 04:22
10/15/08 04-22
10/15/08 04:22
10/15/08 05 01
10/15/08 05.01
10/15/08 05:01
10/15/08 09.39
Page 2 of2
I I I I
MASS SPECTROMETER INSTRUMENT PERFORMANCE CHECK EPA 8260B
Laboratory-
Clienl-
Lab File ID:
Instmment ID:
Sequence:
Kevstone Laboratories. Inc.
MWH Amencas, Inc.-IA
IVOOl D
MS#I
18J1413
- Newton SDG:
Project:
Injection Date:
Injection Time:
Lab Sample ID:
I8J0485
IPL-Clinton FMGP Site
10/14/08
13 02
I8J14I3-TUN1
in/z
50
75
95
96
173
174
175
176
177
ION ABUNDANCE CRITERIA
15-40% of 95
30-60% of 95
Base peak, 100% relative abundance
5 -9% of 95
Less than 2% of 174
50-100%of95
5-9% of 174
95-101% of 174
5-9% of 176
% RELATIVE ABUNDANCE
25.6
43.4
100
6.29
0
59
7.12
100
6.11
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
Pagc 1 of 2
MASS SPECTROMETER INSTRUMENT PERFORMANCE CHECK EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Amencas. Inc.-IA
Lab File ID: 1V0I9D
Instmment ID: MS#1
Sequence- 18J14I3
SDG.
Project:
Injection Date.
Injection Time:
Lab Sample ID:
18J0485
IPL-Clinton FMGP Site
10/15/08
00.32
18J1413-TUN2
m/z
50
75
95
96
173
174
175
176
177
ION ABUNDANCE CRITERIA
15-40% of 95
30-60% of 95
Base peak, 100% relative abundance
5-9% of 95
Less than 2% of 174
50- 100% of 95
5 -9% of 174
95-101% of 174
5-9% of 176
% RELATIVE ABUNDANCE
26.3
44.7
100
6.18
0
59.4
7.49
100
5.83
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
Page 2 of 2
I I I I
CONTINUING CALIBRATION CHECK EPA 8260B
Laboratory.
Client:
Instmment ID-
Lab File ID:
Sequence:
Lab Sample ID.
Kevstone Laboratories. Inc. - Newton
MWH Amencas. Inc.-IA
MS#1
1V002.D
18J1413
I8J1413-CCV1
SDG-
Project.
Calibration:
Calibration Date:
Injection Date:
Injection Tune:
18J0485
IPL-Climon FMGP Sile
18J1101
10/10/08 07.41
10/14/08
13.40
COMPOUND
Chioromethane
Vinyl Chlonde
Bromomelhane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethylene
Methylene Chlonde
trans-1,2-Dichlorocthy lene
1,1-Dichloroethane
Chlorcilbrm
1.1,1-Tnchloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroeihanc
Tnchloroethylene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromofonn
1,1,2,2-Tetrachloroethane
TYPE
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
CONC (ug/l)
STD
100 400
100.450
100 450
100 450
100.400
50.0000
50 OOOO
50.0000
50 OOOO
50.0000
50.0000
50.0000
50 OOOO
50 OOOO
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50 OOOO
50.0000
50 OOOO
50.0000
50.0000
150 000
50 OOOO
50.0000
CCV
94.71
106 9
91.95
102.7
97 06
53 73
50 84
56 00
53.54
53.82
51.36
50.38
51.55
50.32
50 42
51.77
51.15
51.04
48 00
51.04
51.21
49.75
50.70
51.81
50.23
49.57
145.2
49.45
52.65
RESPONSE FACTOR
ICAL
2.280102
1 759579
1 081288
0.9209739
1 467602
1.754758
1 164789
1 593169
2.198702
1 901571
1.328807
0.9288122
1 722599
0 707646
0.4487327
0.5729748
0 7321782
0.8081133
1.528182
0.6760527
0.3848596
0 2696252
0.4675008
0 4917014
0 9779628
1.551966
1.237231
0 2570563
2.257193
CCV
2.159377
1.804052
0.9942529
0.9457603
1 476407
1.885638
1.232271
1.784284
2.354408
2.046691
1.364985
0.9357987
1 77608
0.7121818
0.4525256
0.5932134
0.7490785
0.824913
1 467155
0 6901552
0.3941383
0.2682523
0.4740246
0.5094817
0.9824543
1.538685
1 198022
0.2542237
2.377037
MIN (#)
0.1
O.I
0.3
0.1
% DIFF / DRIFT
CCV
-5 3
25
-8 0
2.7
0.6
7.5
5.8
120
7 I
76
2.7
0 8
3 1
06
0 8
35
2.3
2.1
-4 0
2.1
24
-0.5
1.4
36
0.5
-0.9
-3.2
-1.1
5.3
LIMIT (#)
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
I Page 1 o f4
it Column to be used to flag Response Factor and %Din7Dnfl values with an asterisk
• Values outside of QC limits
Page 2 of4
CONTINUING CALIBRATION CHECK EPA 8260B
Laboratory- Kevstone Laboratories. Inc. - Newton
Client- MWH Americas. Inc.-IA
Instmment ID: M S ffl
Lab File ID- 1V02I D
Sequence 18J1413
Lab Sample ID: 18J1413-CCV2
SDG:
Project:
Calibration:
Calibration Date:
Injection Date:
Injection Time-
18J0485
IPL-Clinton FMGP Site
i8 jno i
10/10/08 07:41
10/15/08
01:48
I I I I I I I I 1 I i i I
COMPOUND
Chioromethane
Vinyl Chlonde
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethylene
Methylene Chlonde
trans-1,2-Dichloroethylene
1,1-Dichloroethane
Chlorofonn
1.1,1-Tnchloroethane
Carbon Tetrachloride
Benzene
1,2-Diohloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
Toluene
trans- 1,3-Dichloropropene
1,1,2-rnchloroethane
Tetrachloroethylene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Eihylbenzene
Xylenes, total
Bromofonn
1,1,2,2-Tetrachloroethane
TYPE
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
CONC (ug/l)
STD
100 400
100 450
100 450
100.450
100.400
50.0000
50.0000
50.0000
50.0000
50.0000
50 OOOO
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50 OOOO
50.0000
50 OOOO
50.0000
50.0000
50.0000
50.0000
150.000
50.0000
50.0000
CCV
105.8
113.3
98 09
1123
100.2
57.60
60.75
57.57
56.87
57.29
53.83
54.18
53.66
52.52
52 48
51.77
51.86
48.59
51 74
48.96
50.25
50.27
50.51
50 80
52.37
51.60
151.4
47.27
49.20
RESPONSE FACTOR
ICAL
2.280102
1 759579
1 081288
0.9209739
1.467602
1.754758
1 164789
1 593169
2.198702
1.901571
1 328807
0.9288122
1.722599
0 707646
0 4487327
0.5729748
0.7321782
0.8081133
1.528182
0.6760527
0.3848596
0 2696252
0 4675008
0.4917014
0.9779628
1.551966
1.237231
0.2570563
2.257193
CCV
2.412209
1.912082
1.060679
1.033866
1.523454
2.021382
1.472405
1 834365
2.500793
2.178638
1.430589
1.006492
1.848808
0.7433268
0.470986
0.5933108
0.7593536
0.7853952
1.581232
0.6619521
0.3867706
0.2710604
0 4722639
0 4995689
1.024328
1.601524
1.249048
0.2430115
2.221263
MIN (#)
0.1
01
03
0 1
% DIFF / DRIFT
CCV
5.8
8.7
-19
123
38
15.2
26 4
15.1
137
14.6
7.7
84
7.3
50
5.0
3.5
37
-2.8
35
-2.1
05
0.5
1.0
1.6
4.7
3.2
1.0
-5.5
-1.6
LIMIT (#)
20
20
20
20
20
20
20 •
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
Page 3 of4
# Column to be used to flag Response Factor and %Diff/Dnfl values with an asterisk
* Values outside of QC limits
Page 4 of4
I I I
SURROGATE STANDARD RECOVERY AND RT SUMMARY EPA 8260B
Laboratory:
Client:
Sequence:
Matrix:
Kevstone Laboratories. Inc. - Newton
MWH Amencas. Inc.-IA
I8J1413
Water
SDG:
Project:
Instmment.
Calibration:
18J0485
IPL-Clinton FMGP Site
MS#1
I8J1101
Surrogate
Compound
Spike
Level ug/l
%
Recovery
Recovery
Limits RT
Calibration
Mean RT RT Diff
RTDiff
Limit Q
Calibration Check (18J1413-CCV1) Lab File ID- 1 V002.D Analyzed: 10/14/08 13:40
Dibromofluoromethane
l,2-Dichloroethane-d4
Toluene-d8
4- B romofl uorobenzene
50 OOOO
50.0000
50 OOOO
50 OOOO
106
105
95.0
96.0
8 0 - 120
8 0 - 120
8 0 - 120
8 0 - 120
11 66
12.29
15.61
19.61
11.68286
12.32143
15.61143
19.61429
-0 0229
-0.0314
-0.0014
-0.0043
+/-1 0
H-/-1.0
+/-1 0
•*-/-10
LCS (1J81413-BS1 ) Lab File ID: I V004.D Analyzed- 10/14/08 14:56
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromonuorobenzene
50.0000
50 OOOO
50 OOOO
50.0000
105
96.1
95.7
99.9
7 4 - 132
7 4 - 133
8 5 - 1 1 5
7 7 - 1 2 2
11.67
12.29
15.61
19 62
11 68286
12.32143
15.61143
19 61429
-0.0129
-0.0314
-0.0014
0.0057
+l-\ 0
+/ -10
+i-\ .0
+i-\.Q
Matrix Spike (lJ814l3-IVfSl) Lab File ID: IV005.D Analyzed: 10/14/08 15.34
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Broinonuorobenzene
50.0000
50.0000
50.0000
50.0000
104
98.7
96.6
95.2
7 4 - 1 3 2
7 4 - 133
8 5 - 1 1 5
7 7 - 1 2 2
11 67
12.3
156
19.61
11 68286
12 32143
15.61143
19.61429
-0.0129
-0.0214
-0.0114
-0.0043
-I-/-1.0
+l-\ .0
+l-\ 0
+I-\.Q
Matrix Spike Dup (1J814I3-MSDI ) Lab File ID: 1 V006.D Analyzed: 10/14/08 16.12
Dibromofluoromethane
1,2-Di:hIoroethane-d4
Tolucne-d8
4-Broinonuoro benzene
50 OOOO
50 OOOO
50 OOOO
50 OOOO
106
101
96.9
96 6
7 4 - 132
7 4 - 133
8 5 - 1 1 5
7 7 - 122
11 66
12.3
15.6
19.61
11.68286
12.32143
15.61143
19.61429
-0.0229
-0.0214
-0.0114
-0 0043
+/-1 0
-I-/-1.0
-^/-1.0
-i-'-lO
Blank (IJ8141.1-BLK1) Lab File ID. 1 V009.D Analyzed: 10/14/08 1807
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Broinofluorobenzene
50.0000
50.0000
50.0000
50.0000
111
104
102
100
7 4 - 1 3 2
7 4 - 1 3 3
8 5 - 1 1 5
7 7 - 1 2 2
1164
12.29
15.6
19.62
11.68286
12 32143
15.61143
19 61429
-0.0429
-0.0314
-0 0114
0.0057
+I-\.Q
+l-\ .0
-H/-1.0
-H,/-1.0
BL(I2-SW-II)01 (18J0485-09) Lab File ID: 1 VOl I.D Analyzed- 10/14/08 19:24
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Broinofluorobenzene
50.0000
50.0000
50 OOOO
50.0000
113
103
101
99 6
7 4 - 132
7 4 - 1 3 3
8 5 - 1 1 5
7 7 - 122
11.66
12.3
15.59
19.61
11.68286
12.32143
15 61143
19.61429
-0.0229
-0.0214
-0.0214
-0.0043
•(-/-I.O
+!-\.0
+I-\.Q
+I-\.Q
PZ02-GW-009 (18J0485-02) Lab File ID: 1V012.D Analyzed: 10/14/08 20:02
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
50.0000
50.0000
50.0000
50.0000
115
102
101
96.9
7 4 - 132
7 4 - 133
8 5 - 1 1 5
7 7 - 122
11.66
12.29
15.6
19.61
11.68286
12.32143
15.61143
19.61429
-0.0229
-0.0314
-O.OI 14
-0.0043
+/-1.0
-I-/-1.0
-(-/-l.O
-I-/-1.0
Page 1 of 3
SURROGATE STANDARD RECOVERY AND RT SUMMARY EPA 8260B
Laboratory-
Client:
Sequence:
Matrix.
Keystone Laboratories, Inc
MWH Amencas. Inc.-IA
18J1413
Water
- Newton SDG-
Project:
Instmment:
Calibration-
18J0485
IPL-Clinton FMGP Site
MS ft\
18JI101
Surrogate
Compound
PZ03-GW-009 (18J0485-03)
Dibromofluoromethane
l,2-Dichloroethane-d4
Toluene-d8
4-Broinofluorobenzcne
PZ05-CW-009 (18J0485-05)
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromonuorobenzene
PZOl-GW-009 (18J0485-01 )
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
PZOI-GW-901 (18J0485-08)
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
Calibration Check (18JI413-CCV2
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
MW66-GW-009 (18J048S-07)
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
PZ4R-GW-009 (18J048S-04)
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
Spike
Level ug/l
50 OOOO
50 OOOO
50 OOOO
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50 OOOO
50.0000
50.0000
50.0000
50.0000
50 OOOO
)
50.0000
50.0000
50 OOOO
50.0000
50 OOOO
50.0000
50 OOOO
50.0000
50.0000
50.0000
50.0000
50.0000
%
Recovery
115
103
103
100
110
102
107
IOO
112
99.2
102
94.7
111
103
102
92.7
107
103
97.1
97.8
115
105
103
98.5
109
101
104
96.6
Recovery
Limits RT
Lab File ID: IV0I3.D
7 4 - 1 3 2
7 4 - 1 3 3
8 5 - 1 1 5
7 7 - 122
11.66
12.29
15.6
19.61
Lab File ID- 1V014.D
7 4 - 132
7 4 - 133
8 5 - 1 1 5
7 7 - 122
11.66
12.3
15.6
19.61
Lab File ID- 1V015D
7 4 - 132
7 4 - 133
8 5 - 1 1 5
7 7 - 122
11.66
12 29
15.61
19.61
Lab File ID. 1V0I7.D
7 4 - 132
7 4 - 133
8 5 - 1 1 5
7 7 - 122
11.66
12.3
15.6
1961
Lab File ID- 1V021 D
8 0 - 1 2 0
8 0 - 120
8 0 - 120
8 0 - 120
11.66
12.3
15.6
19.61
Lab File ID: 1V024D
7 4 - 132
7 4 - 133
8 5 - 1 1 5
7 7 - 1 2 2
11.66
12.29
15.6
19.61
Lab File ID: 1V025.D
7 4 - 1 3 2
7 4 - 133
8 5 - 1 1 5
7 7 - 122
11.66
12.3
15.6
1961
Calibration
Mean RT RT Diff
RT DifT
Limit Q
Analyzed: 10/14/08 20 40
11 68286
12 32143
15 61143
19.61429
-0.0229
-0.0314
-0.0114
-0 0043
-(•/-l.O
-I-/-1.0
-(-/-l.O
-H/-1.0
Analyzed. 10/14/08 21 19
11.68286
12.32143
15 61143
19 61429
-0.0229
-0.0214
-0.0114
-0.0043
-(-/-l.O
-I-/-1.0
+/-\.o
+/-\.o
Analyzed: 10/14/08 21 57
11.68286
12.32143
15.61143
19.61429
-0.0229
-0.0314
-0.0014
-0.0043
+/-1.0
-(•/-l.O
-(-/-IO
+/-\ 0
Analyzed: 10/14/08 23:14
11 68286
12.32143
15.61143
19.61429
-0.0229
-0.0214
-0.0114
-0.0043
Analyzed: 10/15/08 01.4
11 68286
12.32143
15.61143
19.61429
-0 0229
-0.0214
-0.0114
-0.0043
Analyzed: 10/15/08 03.4'
11.68286
12.32143
15.61143
19.61429
-0.0229
-0.0314
-0.0114
-0.0043
Analyzed 10/15/08 04-2.
11.68286
12.32143
15.61143
19 61429
-0.0229
-0.0214
-0.0114
-0.0043
+/-\ 0
+/-\ 0
+/-\ 0
-(•/-l.o
8
-(•/-l.O
-(-/-l.o
+/-\ 0
•(-/-l.o
i
-H/-1.0
+/-\ 0
-(-/-l.o
-(-/-l.o
2
-H/-1.0
H-/-1.0
-(-/-IO
-(•/-l.o
Page 2 of 3
SURROGATE STANDARD RECOVERY AND RT SUMMARY EPA 8260B
Laboratory:
Client:
Sequence:
Malnx.
Keystone Laboratones, Inc.
MWH Americas, Inc.-IA
18J1413
Water
- Newton SDG
Project:
Instmment.
Calibration:
18J0485
IPL-Clinton FMGP Sile
MS#1
I8J1101
Surrogate
Compound
MW32-GW-009 (18J0485-06)
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4- B romofl uorobenzene
Spike
Level ug/l
50.0000
50.0000
50 OOOO
50 OOOO
%
Recovery
109
99.5
108
99.4
Recovery
Limits RT
Lab File ID- 1V033.D
7 4 - 132
7 4 - 133
8 5 - 1 1 5
7 7 - 122
11.66
12.3
15.6
19.61
Calibration
Mean RT
Analyzed
11 68286
12 32143
15 61143
19 61429
RT Diff
RTDiff
Limit Q
10/15/08 09-39
-0.0229
-0 0214
-0 0114
-0.0043
+/-\ 0
-I-/-10
-(-/-IO
-(•/-l.O
Page 3 of 3
INITIAL CALIBRATION STANDARDS EPA 8260B
Laboratory. Keystone Laboratories, Inc. - Newton
Client: MWH Amencas, Inc.-IA
Sequence: 18J1101
Calibration: 18J1101
SDG:
Project:
Inslmment-
18J0485
IPL-Clinton FMGP Site
MS#1
Standard ID
8J13003
8J13004
8J13005
8J13006
8J13007
8J13008
8JI3009
Description
VOC Cal 1
VOC Cal 2
VOC Cal 3
VOC Cal 4
VOC Cal 5
VOC Cal 6
VOC Cal 7
Lab Sample ID
18J1101-CALI
18J1101-CAL2
18J1101-CAL3
18J110I-CAL4
18J1101-CAL5
18J1101-CAL6
18J1101-CAL7
Lab File ID
1V006.D
1V007D
1V008.D
1V009D
IVOIOD
IVOll.D
1V012.D
Analysis Date/Time
10/10/08 13:00
10/10/08 13-38
10/10/08 14:16
10/10/08 14:55
10/10/08 15:33
10/10/08 16:12
10/10/08 16-51
Page I of 1
B I 1
INITIAL CALIBRATION DATA EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Americas. Inc.-IA
Calibration- 18J1101
Matrix: Water
SDG:
Proj ect-
Instmment:
Calibration Date:
18J0485
IPL-Clinton FMGP Site
MS#I
10/10/08 07.41
Compound
Chlorumcthane
Vinyl Chlonde
Brumomcthanc
Chloructhanc
Trichlorofluoromelhane
1,1-Dichloroethylene
Melhylene Chloride
trans-1.2 Dichloroethylene
1,1-Dichloroethane
Chlorofonn
l,l,l-TnL-hl<)roethdne
Carbon Tetiachlonde
Benzene
1,2-Dichloroethane
Tnchloroethylene
1,2-Dichlorapropanc
Bromodichloromethane
CIS-1.3-Dichloropropene
Toluene
trans-1,3-Dichlompropene
1,1,2-Tnchloroethane
Tclrachlaroethylene
Dibromochloromethane
1,2-Dibiomocthane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromoform
1.1,2,2-Tetrachlorocthane
Dibromofluoromethane
1,2-Dichloroethane-d4
Level 01
ug/l
lOCH
loo ts
lOO^S
10043
lOCU
50
50
RF
2 47l<l«8
2 IV I I 7
1 III73
1 \3<m\
163:138
I906W5
1 758935
1417257
2175539
1 457885
0 9386155
1 891019
01071022
0 4611301
0 6 i :6>38
0 7694698
0 8378908
1 689189
0 6662702
0 4193903
0 296
0 4538196
05138366
1040647
16828
1 40IS89
0 2427311
2 297J69
1 001896
0 9540827
Level 02
ug/l
20 08
2009
20 09
20 09
20118
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
.10
10
ID
50
50
RF
2017122
1 786783
1 004168
09064617
I374M3
1 686909
1 158887
1 497285
2 077734
1 862195
1 216322
(1 7967745
1 396792
0 7091481
0 3901489
0 S4S8403
0 687039
07311963
1 433362
0 6150481
0 3728463
0 2472935
04411801
0 4795532
0 9148837
1 499363
1 203264
0 2298085
2 171124
0 9843944
0 9320444
Level 03
ug/l 1 RF
30 2
50 223
SO 225
.SO 225
50 2
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
23
25
25
23
25
75
25
25
SO
50
2 337159
1 843105
1 122668
0 9463K04
1 49986
1 816742
1 201821
1 660912
2 22515
1 938556
1 348K64
II 9409908
1 799921
0 7401889
0 4S06333
0 5819379
0 7482409
0 8141204
1 366139
0 679375
0 3960831
0 2813564
0 4833162
0 SOS2481
1 1109059
1 711042
1 305611
0 2584477
2 310662
0 9681976
0 9206909
Level 04
ug/l
100 4
I«I4S
100 45
100 43
1004
50
50
50
50
SO
50
SO
30
50
50
50
50
50
SO
50
SO
50
SO
50
50
50
ISO
50
50
SO
50
RF
2 526844
1 846225
1 20M4
09411204
1 5111583
1 82976
1 236394
1 633332
2 209339
1 937492
1 349449
0 9348124
1 795493
0 7286137
II 4694497
0 SIIM4S
0 7638379
0 854SH9
1 S0090n
0 7103886
03937044
0 2770938
0 47S9SS6
0 4978635
1 021(29
1 63715
1 292913
026078IS
2 262923
0 9369024
0 9I928S3
Level 05
ug'I
200 S
200 9
200 0
2110 0
200 8
IOO
IOO
IOO
IOO
IOO
IOO
IOO
IOO
l l «
IIKI
l l io
IOO
Mill
IOO
IOO
IIM
IOO
IOO
IOO
IOO
IOO
300
IOO
IOO
30
30
RF
2 219938
1 SSI086
1 114413
0 8334891
1 l'«1274
1 623558
1 099123
1 490166
2II62S98
1 783S96
1 261954
0 92113462
1 694608
0 6733003
0 4S94647
0 5651598
0 7318764
0 8036723
1 30341
0 6188337
0 3751477
0 2S838I9
0462871
0 4712316
01303807
1 469234
1 138426
0 2M3417
2211027
09141177
0 8826386
Level 06
ug/l
3012
301 i t
301 3;
301 3^
101 2
130
ISO
ISO
130
130
150
ISO
ISO
ISO
ISO
ISO
ISO
150
ISO
ISO
ISO
130
ISO
ISO
ISO
150
430
ISO
ISO
.30
30
RF
2 303126
1 608188
1053511
0 8788924
1 476307
1 755944
1 I7S29S
1 570747
2 207856
1 843264
1 141474
0 9796933
1 677718
0 6.S57I4S
04612646
0 3311637
0 709926
0 7899866
1 480749
0 688057
0 3663317
0 2M6738
0 4767782
0 484616
09694657
1 479014
1 180043
0 2733618
2 256503
0 9278994
0 9083801
I Page 1 of 6
INITIAL CALIBRATION DATA EPA 8260B
Laboratory. Kevstone Laboratories. Inc. - Newton
Client. MWH Amencas. Inc.-lA
Calibration: 18J1101
Matnx: Water
SDG:
Projcct-
Instmment.
Calibration Date:
18J0485
IPL-Clinlon FMGP Site
MS#1
10/10/08 07:41
Compound
Tolucne-dg
4-Bromonuorobenzene
Level 01
ug,-!
30
SO
RF
1 17069
0 4708293
Level 02
ug/l
50
SO
RF
1 152718
0 4347762
Level 03
ug/l
so
.30
RF
1 162814
1) 4727746
Level 04
ug/l
so
so
RF
1 138893
0 4866129
Level 05
ug/l
so
so
RF
1 13301
0 4638703
Level 06
ug/l
30
SO
RF
1094023
04338249
Page 2 of 6
I B I
INITIAL CALIBRATION DATA (Continued) EPA 8260B
Laboratory: Kevstone Laboratones. Inc. - Newton
Client: MWH Amencas. Inc.-IA
Calibration. 18J1I01
Matrix: Water
SDG:
Project:
Instruinent.
Calibration Date.
I8J0485
IPL-Clinlon FMGP Site
MS#1
10/10/08 07:41
Compound
Chloromsthaiie
Vinyl Chlonde
Bromomethane
Chloroethane
Tnchlorofluoromethane
l,i-Dichloroethylene
Melhyleoe Chlonde
trans-1.2-Dichloioethylene
1,1-Dichloroethane
Chloroform
1,1,1-Tnchloroethane
Carbon Tetrachlonde
Benzene
1.2-Dichloroethane
Tnchloroethylene
1.2-Dichlor(ipropane
Bromodichloromethane
CIS-1,3-Dichloropr(ipene
Toluene
trans-1,3-Dichloropropene
1,1,2-Tnchloroethane
Tetrachloroethylene
Dibiomochloromethane
1,2-Diliromoethane
Chlorobenzene
l-'thylbL-nzene
Xylenes, total
Bromofonn
1,1,2,2-TetTachlorocthane
Dibromofluoromethane
l,2-Di;hloroethane-d4
Level 07
ug/l
4016
4018
401 K
4018
401 6
:oo
200
200
200
:oo
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
bOO
200
200
50
50
RF
2 084519
1 4«049S
0 953W73
0 7999823
1 369914
1 661401
1 109215
1 S38785
2 190783
1 770352
13255
0 9702521
1 602569
0 6374344
04490357
0 5547731
0 7148571
0 7854116
I 431316
0 6843943
0 3705134
0 2625752
0 4745122
04845386
0 9330115
1385137
1 118472
0 2699215
2 20074
0 9293257
0 8999773
Level 08
ug/l RF
Level 09
ug/l RF
Level 10
ug/l RF
Level 11
ug/l RF
Level 12
ug/l RF
I Page 3 of 6
INITIAL CALIBRATION DATA (Continued) EPA 8260B
Laboratory.
Client:
Calibration-
Matnx.
Kevstone Laboratones. Inc
MWH Amencas, Inc.-IA
18J1I0I
Water
- Newton SDG-
Projcct:
Instmment:
Calibration Date:
18J0485
IPL-Clinton FMGP Site
MS#1
10/10/08 07:41
Compound
Toluene-d8
4-Bromofluorobenzene
Level 07
ug/l
50
50
RF
1 087036
04556742
Level 08
us/l RF
Level 09
ug'I RF
Level 10
ug/l RF
Level 11
ug/l RF
Level 12
ug/l RF
Page 4 of 6
INITIAL CALIBRATION DATA (Continued) EPA 8260B
Laboratory. Kevstone Laboratories. Inc. - Newton
Client. MWH Americas. Inc.-IA
Calibration- 18J1101
Matnx. Water
I I I I B I I I I I I I I I
SDG-
Project:
Instrument:
Calibration Date-
18J0485
IPL-Clinton FMGP Site
MS#1
10/10/08 07.41
Compound
Chloroim-thane
Vmyl Chlonde
Bromomethane
Chloroethane
Tnchlorofluoromethane
1,1-Dichloroethylcne
Methylene Chlonde
trans-1,2 -Dichloroethylene
I.l-Dich loroethane
Chloroform
1,1,1 -Tnchloroethane
Carbon Tetiachlonde
Benzene
1,2-Dichlomethane
Tnchloroethylene
1,2-Dichloropropane
Bromodichloromethane
CIS-1,3-Dichloropropene
Toluene
trans-l,j-Dichloropropene
1,1,2-Tnchlaroethane
Tetrachloroethylene
Dibromxhioromcthane
1,2-Dibromaethane
Chlorobenzene
Ethylbenzene
,X>lene.Motal
Bromolorm
1.1,2,2-Telrachloroelhane
Dibromofluoromethane
1.2-Dich1oroethane-d4
Toluene-dK
Mean RF
2 280102
1 759579
1 081288
0 9209739
1 467602
1 754758
1 164789
1.S93I69
2 198702
1 901.571
1 328807
0 9288122
1 722599
0 707646
0.4487327
0 5729748
0 7321782
0 8081133
1.528182
0 6760527
0 3848596
0 2696252
0 46750(18
0 4917014
0 9779628
1 551966
1237231
0 2570563
2 257193
0951819
0 9167285
1 137026
RFRSD
8 254024
13 64209
7815511
12 00292
6 885926
5 82358
4 655199
6 123852
5.313322
7.242521
5 726185
6 626526
6 390689
8 172226
5 959507
4 344307
4 12903
4 467241
6.099075
4 431089
4 957653
6 034538
3 439657
3 096882
4 9852(M
7 99789
8 057386
6 043256
2 440562
3 47369
2 50518
2 979711
Mean RT
3.161429
3 36
3 994286
4 205714
4 727143
5 89
7 203333
7 978571
9 211429
11 35429
11 65286
1196714
12.38714
12 46
13 57571
13 97286
14 46143
15 19857
1571714
16.09714
16.37714
16 56429
16 97857
17 14857
17 89143
18 06
18 83571
19 13857
19 83857
11 68286
12 32143
15.61143
RTRSD
0 1193418
0.1719091
01969436
0 1858115
0 1601697
0 1379926
0 0705854
8 677208E-02
7 783005E-02
7 005758E-02
6 430862E-02
0.033291
4429621E-02
4 713108E-O2
4093921E-02
3 181946E-02
2 320837E-02
2.356388E-02
3 232128l£-02
3 263389E-02
0 0347533
2 914252E-02
7.207996fc-03
2 837201 E-02
9 819918E-03
1 523753E-02
3 453174E-02
1.526718E-02
3 440163E-02
4 514779E-02
3.3O2007E-02
2 273774E-02
Linear r Quad COD LIMIT
SPCC (0 1)
CCC (30)
15
15
15
CCC (30)
15
15
-SPCC (0 1)
CCC (30)
15
15
15
15
15
CCC (30)
15
15
CCC (30)
15
15
15
15
15
SPCC (0 3)
CCC (301
15
SPCC (0.1)
15
15
15
15
0
Page 5 of 6
INITIAL CALIBRATION DATA (Continued) EPA 8260B
Laboratory-
Clienl:
Calibration.
Matnx.
Kevstone Laboratories, Inc.
MWH Amencas, Inc.-IA
18J1101
Water
- Newton SDG:
Project:
Instmment:
Calibration Date:
I8J0485
IPL-Clinton FMGP Site
MS ft\
10/10/08 07:41
Compound
4-Bromonuorabenzene
Mean RF
0 4657775
RFRSD
2 5369(M
Mean RT
19 61429
RTRSD
2 595095E-02
Linear r Quad COD LIMIT
15
Q
Page 6 of 6
HOLDING TIME SUMMARY EPA 8260B
Laboratory. Kevstone Laboratories. Inc. - Newton
Client: MWH Americas. Inc -IA
SDG:
Projecl:
18J0485
IPL-Clinlon FMGP Site
Sample Name
PZOl-GW-009
PZ02-GW-009
PZ03-GW-009
PZ4R-GVV-009
PZ05-GW-009
MW3:-GW-009
MW32-GW-009
MW66-GW-009
PZOl-GW-901
BL02-SW-1001
Date
Collected
10/07/08
17.50
10/07/08
13 30
10/07/08
15:25
10/08/08
09.25
10/07/08
16 30
10/08/08
12 00
10/08/08
12:00
10/08/08
09 02
10/07/08
08 00
10/08/08 10.15
Date
Received
10/08/08
16.57
10/08/08
16.57
10/08/08
16 57
10/08/08 16-57
10/08/08
16-57
10/08/08 16 57
10/08/08
16 57
10/08/08
16:57
10/08/08 16.57
10/08/08 16-57
Dale
Prepared
10/14/08 00-00
10/14/08
00-00
10/14/08 OOOO
10/14/08 00.00
10/14/08
OOOO
10/14/08
00-00
10/14/08 OOOO
10/14/08
OOOO
10/14/08 OOOO
10/14/08
OOOO
Days
to
Prep
6 26
6 44
6.36
5 61
631
5 50
5.50
5 62
6 67
5 57
Max
Days lo
Prep
14 00
14.00
14 00
14 00
14 00
1400
14 00
14 00
14 00
14 00
Dale
Analyzed
10/14/08 21:57
10/14/08 20:02
10/14/08 20 40
10/15/08 04-22
10/14/08 21:19
10/15/08 09-39
10/15/08 05:01
10/15/08 03-44
10/14/08 23.14
10/14/08 19-24
Days
lo
Analysis
7 17
7 27
7 22
6.79
7 20
6.90
6.71
6.78
7.63
6 38
Max
Days to
Analysis
14 00
14.00
14 00
14.00
14 00
14.00
14 00
14 00
14 00
14 00
Q
Page I of 1
ANALYSIS SEQUENCE
1811507
Instrument:
Calibnration ID:
MS#1
19D1002 Printed: 4/13/2009 9:14:31AM
Lab Number
18I1507-TUN1
18I1507-CCV1
1I81515-BS1
1I81S1S-MS1
II81SIS-MSD1
1I815J5-BLK1
1810314-01
1810314-01
1810314-01
1810314-01
1810314-01
1810314-01
1810314-01
1810314-01
1810314-01
1810314-01
1810314-02
1810314-03
1810378-04
1810378-04
1810378-04
1810378-04
1810378-04
Analysis
QC
QC
QC
QC
QC
QC
8260-100
8260(@benzene
8260-base-analysis
8260@xylenes
8260@toluene
8260@ethylbenzene
8260(^hlethane
8260|@chlbcnzene
8260@l,4-dcb
8260-201
8260-100
8260-100
8260@l,4-dcb
8260@bcnzene
8260@chlbcnzenc
8260@chlethane
8260@ethylbenzene
Container
B
B
B
B
B
B
B
B
B
B
C
C
H
H
H
H
H
Order
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
Position SID ID
9D10009
8H20008
ISTD ID
8H11010
8H11010
8H11010
8HI1010
SHIIOIO
8H11010
SHllOlO
8HI1010
SHUOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
Client
Barker-Lcmar Associates
Barker-Lemar Associates
Barker-Lcmar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lcmar Associates
Midwest Environmcntal Consulting
Midwest Environmental Consulting
Midwest Environmental Consulting
Midwest Environmental Consulting
Midwest Environmcntal Consulting
Comments
BatchQC
BatchQC
BatchQC
BatchQC
BatchQC
BatchQC
BatchQC
BatchQC
BatchQC
Samples Loaded By Date Data Processed By Date
Page 1 of2
ANALYSIS SEQUENCE
1811507
Instrument:
Calibnration ID:
MS#1
19D1002 Printed: 4/13/2009 9:14:31AM
Lab Number
1810378-04
1810378-04
1S1037S-04
1810378-07
1SI0378-07
1SI037S-07
1810378-07
1810378-07
1SI0S71-01
1810571-02
1810277-10
1SI0277-10
Analysis
8260@tolucne
S260@xylenes
S260-base-analysis
8260@chlcthane
8260@cthylbenzcnc
S260@xylenes
S260-base-analysis
8260-201
S260-100
8260-100
S260@bcnzcnc
S260-base-analysis
Container
H
H
H
H
H
H
H
H
C
B
H
H
Order
24
25
26
27
28
29
30
31
32
33
34
35
Position STD ID ISTD ID
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
SHIIOIO
Client
Midwest Environmental Consulting
Midwest Environmcntal Consulting
Midwest Environmental Consulting
Midwest Environmcntal Consulting
Midwest Environmental Consulting
Midwest Environmcntal Consulting
Midwest Environmcntal Consulting
Midwest Environmcntal Consulting
MWH Americas, Inc.-L\
MWH Americas, Inc.-L\
Fox Engineering Associates, Inc.
Fox Engineering Associates, Inc.
Comments
Samples Loaded By Date Data Processed By Date
Page 2 of2
PREPARATION BENCH SHEET
1181515
Matrix: Water
Keystone Laboratories, Inc. - Newton
Prepared using: Volatiles - EPA 5030B
rinted: 4/13/2009 9:24:27AM
Surrogate used: 8H15002
Lab Number
1810277-10
1810277-10
1SI0314-01
ISI0314-01
1SI0314-01
1810314-01
1810314-01
1SI0314-01
1SI0314-0I
1810314-01
11810314-01
1810314-01
1810314-02
1SI0314-03
1810378-04
1810378-04
1810378-04
1SI0378-04
1810378-04
1810378-04
1810378-04
1810378-04
1810378-07
Analysis
S260-basc-analysis
S260@benzene
8260-100
8260-201
S260-base-analysis
S260@l,4-dcb
S260@benzene
S260@chlbcnzcnc
S260(gchlcthane
S260@ethylbenzene
8260@tolucne
8260@xylenes
8260-100
8260-100
S260-basc-analysis
8260(g)l,4-dcb
S260@benzcne
S260(@chlbcnzcnc
S260@chlethane
S260(gtethylbenzene
S260@toluene
S260@xylcncs
8260-201
Prepared
09/11/OS 00:00
09/11/OS 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/OS 00:00
09/11/OS 00:00
09/11/08 00:00
09/11/OS 00:00
09/11/OS 00:00
09/11/OS 00:00
09/11/OS 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/OS 00:00
Initial (ml)
5
Final (ml) Spike ID Source ID
ul Spike
ul Surrogate Client
Fox Engineering Associat
Fox Engineering Associat
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lcmar Associates
Barker-Lemar Associates
Barker-Lemar Associates
Barker-Lcmar Associates
Barker-Lemar Associates
Midwest Environmental (
Midwest Environmental C
Midwest Environmental (
Midwest Environmental C
Midwest Environmcntal C
Midwest Environmental C
Midwest Environmental C
Midwest Environmental C
Midwest Environmental C
Extraction Comments
Added for BatchQC in: 1 IS 1515
Added for BatchQC in: 1 IS 1515
Added for BatchQC in: 1 ISIS IS
Added for BatchQC in: 1 IS 1315
Added for BatchQC in: IISISIS
Added for BatchQC in: 1 IS 1S15
Added for BatchQC in: 1 IS 1515
Added for BatchQC in: 1 IS 1515
Added for BatchQC in: 1181S15
Spiking Witnessed By Date Preparation Reviewed By Date Extracts Received By Date
Page I o f2
PREPARATION BENCH SHEET
1181515
Matrix: Water
Keystone Laboratories, Inc. - Newton
Prepared using: Volatiles - EPA 5030B
rinted: 4/13/2009 9:24:27AM
Surrogate used: 8H15002
Lab Number
1810378-07
1810378-07
1SI0378-07
1SI037S-07
1SI0571-01
1810571-02
IIS131S-BLKI
IISISIS-BSI
1I81515-MS1
IIS1515-MSD1
Analysis
8260-base-analysis
S260@chlethanc
S260@ethylbenzene
S260(gxylenes
8260-100
8260-100
QC
QC
QC
QC
Prepared
09/11/OS 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/OS 00:00
09/11/OS 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00.00
09/11/OS 00:00
Initial (ml)
r
Final (ml) Spike ID
SI03002
8103002
8103002
Source ID
1810314-01
1810314-01
ul Spike
5
50
50
ul Surrogate Client
Midwest Environmental C
Midwest Environmental C
Midwest Environmcntal (
Midwest Environmental (
MWH Americas, Inc.-L^
MWH Americas, Inc.-IA
Extraction Comments
Spiking Witnessed By Date Preparation Reviewed By Date Extracts Received By Date
Page 2 of2
Method Path : Method File : Title : 5 Last Update Response Via
G:\MSCHEM\1\METH0DS\ VW090908.M mL WATER : Wed Sep 10 07:44:25 2008 : Initial Calibration
Calibration Files 1 =1V002.D 2 =1V003.D =1V004.D 4 =1V005.D =1V006.D 6 =1V007.D 7 rlVOOB.D
-1 >
1, 2] 31 4] 5] 6] 7] 8 9 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1 2
3 4 5 6 7
I T TP TC T T T
TOM T
T T
T
T 1 T T TP
S ) T I T > T
T ) TC ) T ) T ) T ) S
) I ) TM ) T ) TM ) TC
Compound
pentafluorobenzene.. dichlorodiflou... chioromethane vinyl chloride bromomethane chloroethane trichlorofluor... acrolein 1,1-dichloroet. . . acetone iodomethane
112Trichloro22.. . acetonitrile methylene chio... acrylonitrile trans-1,2-dich... methyl-t-butyl... hexane 1,1-dichloroet... vinyl acetate dibromofluorom... 2,2-dichloropr... cis-1.2-dichlo... 2-butanone ethyl acetate bromochloromet... chloroform 1,1,1-trichlor... 1,1-dichloropr... carbon tetrach... 1,2-dichloroet.. .
0 0 0 0 0
0 0 1 2 0
0 0 0 1 0 1 1 0 0 0 0 0 0 1 0 0 0 0
1,4 -Di fluorobenzen. benzene 1,2-dichloroet... trichloroethene 1,2-dichloropr...
1 0 0 0
•
620 633 603 393 769
802 230 371 033 541
711 177 743 351 302 031 264 694 700 .919 .248 .067 .581 078 .708 .611 .460 .530
_ .283 .446 .333 .342
1
"" " 0. 0. 0. 0. 0. 0 0 0 0 1 2 0
0 0 0 1 0 1 1 0 0 1 0 0 0 1 0 0 0 0
. _
1 0 0 0
507 717 690 713 444 793 008 829 203 601 191 556
752 199 847 546 320 229 496 689 741 .040 .248 .076 .658 221 .768 .676 .506 .548
.498
.508
.374
.400
2
0. 0. 0. 0. 0. 1 0 0 0 1 2 0 0 0 0 0 1 0 1 1 0 0 1 0 0 0 1 0 0 0 0
_ _
1 0 0 0
•" ""
606 740 729 758 461 095 014 902 178 583 246 606 072 746 199 869 531 352 238 543 .686 .801 .061 .251 .074 .663 .222 .814 .726 .563 .540
- . — -.536 .508 .406 .404
3
0. 0 0 0 0 0 0 0 0 1 2 0 0 0 0 0 1 0 1 1 0 0 1 0 0 0 1 0 0 0 0
_ _
1 0 0 0
4
ISTD--610 740 708 747 458 863 013 899 204 507 211 612 069 735 187 851 473 360 215 470 .675 781 .046 .271 .072 .663 .215 .835 .722 .587 .538
0. 0 0. 0 0 0 0 0 0 1 2 0 0 0 0 0 1 0 1 1 0 0 1 0 0 0 1 0 0 0 0
-ISTD-.519 .497 .412 .421
1 0 0 0
578 695 676 604 448 852 012 861 187 490 117 581 069 751 188 854 465 344 234 500 665 774 028 258 073 654 187 .838 .714 .590 .545
_
.512
.480
.412
.408
5
0. 0 0. 0. 0. 0 0 0
1 2 0 0 0 0 0 1 0 1 1 0 0 0 0 0 0 1 0 0 0 0
. _ 1 0 0 0
579 686 635 577 434 849 013 851
491 134 590 071 741 182 839 430 357 225 453 671 757 .994 .228 .072 .636 177 .834 .714 .601 .539
.465
.469
.401
.395
6
0. 0 0
0 0 0 0 0 1 2 0 0 0 0 0 1 0 1 1 0 0 0 0 0 0 1 0 0 0 0
_ _
1 0 0 0
534 613 578
396 817 012 804 173 392 053 562 068 708 175 800 370 349 166 396 656 707 .941 .241 .070 .611 .132 .811 .681 .585 .535
- — ~ . .400 .445 .392 .380
7
0. 0 0. 0. 0. 0 0 0 0 1 2 0 0 0 0 0 1 0 1 1 0 0 1 0 0 0 1 0 0 0 0
_ _
1 0 0 0
569 687 664 667 433 863 012 850 196 491 141 578 070 735 187 829 452 341 191 446 677 752 004 249 072 638 176 .801 692 .556 540
. _
.459
.479
.390
.393
Avg
7. 7 7
12 6 12 15 4 10 5 3 4 2 2 5 5 5 6 6 6 2 5 5 5 4 4 4 5 5 9 1
6 5 7 6
%RSD
12 66 82 17 48 51 60 81 70 82 74 57 29 50 18 25 11 31 27 38 06 04 .49 .44 11 91 57 .94 .89 .54 11
.14
.61
.30
.53
VW090908.M Mon Apr 13 09:10:36 2009 VOCDATAOl Page: 1
Response Factor Report MS ttl
Method Method 8] 91 01 11 21 3 41 5 6 71
8) 91 01 1 2 3 41 5 61 7 8 9 0 1 2 3 4
5 6 7 8 9 0
' 1 2 '3 '4 5 6 7 8 9 0 1 2 3
T S T
T T TCM T
T
I T
T T T TPM TP TC T T T TP T S T
I TP
I T ) T T T
1 T T
1 T > T T T
» T > T > T
T T T
Path : G:\MSCHEM\1\METH0DS\ File : VW090908.M dibromomethane toluene-d8 {SS-3) bromodichlorom... 2-chloroethyl ... cis-1,3-dichlo... 4-methyl-2-pen... toluene trans-1,3-dich... ethyl methacry... 1,1,2-trichlor...
chlorobenzene-d5 tetrachloroethene 1,3-dichloropr... 2-hexanone dibromochlorom... 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrac... ethylbenzene m,p-xylenes o-xylene styrene bromoform isopropylbenzene bromofluoroben... 1,2,3-trichlor... trans-1,4-dich.. .
0.267 1.108 0.483 0.143 0.541 0.287 1.185 0.416 0.377 0.294
/ t - - • 0.308 0.598 0.234 0.387 0.399 0.784 0.298 1.277 1.013 1.076 0.815 0.232 0.889 0.435 0.075
1 A — rf "i r ViT iT•riV^»n^o'^ —
1,1,2,2-tetrac... bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethy... p-chlorotoluene tert-butylbenzene 1,2,4-trimethy... sec-butylbenzene p-isopropyltol... 1,3-dichlorobe... 1,4-dichlorobe... n-butylbenzene 1,2-dichlorobe... 1,2-Dibromo-3-... 1,2,4-trichlor... hexachlorobuta... naphthalene
Ll • • >
1.283 1.132 4.191 2.788 2.562 3.109 2.318 2.758 3.231 2.323 1.514 1.702
1.459
0.322 1.088 0.583 0.166 0.637 0.345 1.265 0.491 0.456 0.342
0.348 0.686 0.254 0.461 0.475 0.940 0.344 1.464 1.118 1.254 0.968 0.294 1.016 0.442 0.093 0.073
1.494 1.358 4.875 3.308 3.076 3.709 2.645 3.256 3.663 2.695 1.890 1.911 2.887 1.729 0.116 0.634 0.386 1.027
0. 1. 0. 0. 0. 0. 1. 0. 0 0.
0. 0 0 0 0 0 0 1 1 1 0 0 1 0 0 0
1 1 5 3 3 3 2 3 3 2 1 1 2 1 0 0 0 0
331 077 618 182 654 342 343 523 475 337
358 670 252 474 456 923 352 447 109 237 971 293 054 439 .096 073
.484
.360
.043
.182
.088
.524
.718
.230
.765
.758
.879
.840
.966
.739
.143
.638
.363
.888
0. 1. 0. 0. 0. 0. 1. 0. 0 0.
0. 0 0 0 0 0 0 1 1 1 0 0 1 0 0 0
1 1 5 3 3 3 2 3 3 2 1 1 3 1 0 0 0 0
327 080 612 170 659 346 350 540 474 341
0. 1. 0. 0. 0. 0. 1. 0. 0 0
- T QTr* xo 11.
371 663 276 486 458 947 355 452 083 226 958 304 059 434 .088 077
0 0 0 0 0 0 0 1 1 1 0 0 1 0 0 0
- T CTF* - -
.525
.406
.022
.177
.094
.567
.758
.215
.852
.799
.909
.909
.171
.771
.152
.680
.387
.935
J —
1 1 4 3 3 3 2 3 3 2 1 1 3 1 0 0 0 0
319 042 609 174 656 339 330 541 480 334
363 638 273 495 470 944 366 432 068 189 941 318 038 440 .090 .079
.504
.421
.975
.249
.069
.500
.753
.215
.773
.695
.896
.881
.113
.734
.158
.699
.387
.936
0. 1. 0. 0. 0. 0. 1. 0. 0. 0.
0. 0. 0 0 0 0 0 1 1 1 0 0 1 0 0 0
1 1 4 3 3 3 2 3 3 2 1 1 3 1 0 0 0 0
312 041 591 167 633 328 296 539 456 325
368 634 252 499 457 941 358 391 041 167 923 322 028 434 087 076
495 .423 .988 .267 .128 .560 .846 .255 .900 .756 .933 .924 .201 .723 .175 .743 .399 .980
0. 1. 0. 0. 0. 0. 1. 0 0 0
0 0 0 0 0 0 0 1 0 1 0 0 0 0 0 0
1 1 5 3 3 3 2 3 3 2 1 1 3 1 0 0 0 1
295 021 573 161 594 312 237 510 434 308
351 598 255 479 442 894 343 327 991 113 884 311 978 428 .084 073
.443
.416
.013
.238
.111
.506
.794
.180
.896
.766
.943
.953
.168
.699
.177
.749
.408
.016
0 1 0. 0 0 0 1 0 0 0
0 0 0 0 0 0 0 1 1 1 0 0 1 0 0 0
1 1 4 3 3 3 2 3 3 2 1 1 3 1 0 0 0 0
310 065 581 166 625 328 287 508 450 326
352 641 257 469 451 910 345 399 060 180 923 296 009 436 .088 .075
.461
.359
.872
.173
.018
.496
.690
.158
.726
.685
.852
.874
.084
.693
.154
.690
.388
.964
7. 2. 8. 7. 6. 6. 4. 8 8 5
6 5 5 8 5 6 6 5 4 5 6
10 5 1 7 3
5 7 6 5 6 5 6 5 6 6 8 4 4 6
14 7 3 5
18 90 01 45 91 64 75 83 00 56
02 38 50 14 62 45 49 09 50 63 10 29 88 10 64 27
62 .66 .27 .54 .69 .29 .53 .66 .28 11 .14 .48 .15 .24 .72 .18 .92 .54
VW090908.M Mon Apr 13 09:10:36 2009 VOCDATAOl Page: 2
Method Path : G:\MSCHEM\1\METH0DS\ Method File : /W090908.M 84) T 1,2,3-trichlor... 0.381 0.353 0.372 0.385 0.421 0.442 0.392 8.43
(tt) = Out of Range
VW090908.M Mon Apr 13 09:10:36 2009 VOCDATAOl Page;
BFB
Data Path Data File Acq On Operator Sample Misc ALS Vial
G:\MSCHEM\1\DATA\091108A1\ 1V042.D 14 Sep 2008 12:18 pm TVK TUNE
2 S a m p l e M u l t i p l i e r : 1
I n t e g r a t i o n F i l e : R T E I N T 5 . P
M e t h o d : G:\MSCHEM\1\METHODS\VW090908.M T i t l e : 5 mL WATER L a s t U p d a t e : Wed S e p 10 0 7 : 4 4 : 2 5 2 0 0 8
Abundance 2000000
1500000
1000000
TIC- 1V042.D\data ms
500000
U ' ( i i i i | i i i i i r T T i i i i T i | i T i " ^pT I I I I I I I I I 'I n r-i I I I I I I I I 'I I I I I I I I I I I r f 1-r r i I f I l-t I I I I I l ' l I I I I I I I r I 1 I I I I 1 I I I I I I I I
Time-> 17.60 17.80 18.00 18.20 18.40 18.60 18.80 19 00 19.20 19 40 19 60 19.80 20.00 20.20 20 40 20.60 20.80 21 00 21 20 21.40 Abundance Average of 19.564 to 19.585 min.: 1V042.D\data ms (-)
300000
250000
200000
150000
100000
50000
0
95.0
75.0
50.0
37.0
40
61.0 68 0
70
87.0
r V
80
174 0
105 8 118 8 127 9 140 9 "T" - r
130
154.8 " T T "
m/z-> 30 50 60 ' ] '
90 ~ 100 110 120 140 150 160 170 180
A u t o F i n d : S c a n s 1 6 2 7 , 1 6 2 8 , 1 6 2 9 ; B a c k g r o u n d C o r r e c t e d w i t h S c a n 1 6 1 5
Target Mass
50 75 95 96
173 174 175 176 177
Rel. to Mass
95 95 95 95
174 95
174 174 176
Lower Limit%
15 30
100 5
0.00 50 5
95 5
Upper Limit%
40 60
100 9 2
100 9
101 9
Rel. Abn%
18.4 43.9
100.0 5.8 0.0
77.3 7.6
97.7 6.8
Raw Abn
55325 132045 300992 17442
0 232768 17676
227349 15550
Result Pass/Fail
PASS PASS PASS PASS PASS PASS PASS PASS PASS
VW090908.M Mon A p r 13 0 9 : 1 6 : 5 7 2 0 0 9 VOCDATAOl P a g e :
I I I I I
Evaluate Continuing Calibration Report
Data File : G:\MSCHEM\1\DATA\091108A1\1V043.D Acq On : 14 Sep 2008 12:56 pm Sample : CCV Misc : f. Quant Time: Apr 10 07:58:07 2009
Quant Method : G:\MSCHEM\l\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:VOC H20
Vial Operator Inst Multiplr
3 TVK MS ttl 1.00
Min. RRF Max. RRF Dev
0.000 Min. Rel. Area 3 0% Max. Rel. Area
10% Max. R.T. Dev 0.50min 500%
Compound AvgRF CCRF %Dev Area% Dev(min)
l i 4
1 8
l i 12
11 16
19
I T TP TC T T T
TCM T
T T
I 20 TP 1 S T T T
2 23
Ibe 27 T 8 TC
loo 31 12
T T T S
Ib3 I 34 TM
•^7 38
I; 42
"45 46
UAI T
•48 I
T TM TC T S T
T T TCM T
pentafluorobenzene (IS-1) dichlorodiflouromethane chlorome thane vinyl chloride bromomethane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone lodomethane carbon disulfide 112Trichloro221trifluoroeth acetonitrile methylene chloride acrylonitrile trans-1,2-dichloroethene methyl-t-butyl ether hexane 1,1-dichloroethane vinyl acetate dibromofluoromethane (SS-1) 2,2-dichloropropane cis-1,2-dichloroethene 2-butanone ethyl acetate bromochloromethane chloroform 1,1,1-trichloroethane 1,1-dichloropropene carbon tetrachloride 1,2-dichloroethane-d4 (SS-2
1,4-Difluorobenzene (IS-2) benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromomethane toluene-d8 (SS-3) bromodichloromethane 2-chloroethyl vinyl ether cis-1,3-dichloropropene 4-methyl-2-pentanone toluene trans-1,3-dichloropropene ethyl methacrylate 1,1,2-trichloroethane
chlorobenzene-d5 (IS-3)
1.000 0.569 0.687 0.664 0.667 0.433 0.863 0.012 0.850 0.196 1.491 2.141 0.578 0.070 0.735 0.187 0.829 1.452 0.341 1.191 1.446 0.677 0.752 1.004 0.249 0.072 0.638 1.176 0.801 0.692 0.556 0.540
1.000 1.459 0.479 0.390 0.393 0.310 1.065 0.581 0.166 0.625 0.328 1.287 0.508 0.450 0.326
1.000 0.601 0.748 0.719 0.689 0.461 0.84 7 0.006 0.915 0.161 1.470 2.084 0.536 0.067 0.765 0.202 0.869 1.513 0.209 1.261 0.838 0.682 0.158 0.979 0.223 0.073 0.685 1.202 0.800 0.701 0.560 0.579
1.000 1.484 0.505 0.388 0.407 0.320 1.106 0.599 0.140 0.504 0.346 1.298 0.415 0.448 0.330
0.0 -5.6 -8.9 -8.3 -3.3 -6.5 1.9
50. Ott -7.6 17.9 1.4 2.7 7.3 4.3 -4.1 -8.0 -4.8 -4.2 38.7tt -5.9 42. Ott -0.7 79. Ott 2.5
10.4 -1.4 -7.4 -2.2 0.1
-1.3 -0.7 -7.2
0.0 -1.7 -5.4 0.5
-3.6 -3.2 -3.8 -3.1 15.7 19.4 -5.5 -0.9 18.3 0.4
-1.2
88 87 89 89 81 88 86 39 90 69 86 83 77 86 91 95 90 9 0 51 91 50 89 18 82 72 88 91 87 84 85 84 95
89 87 90 84 86 87 91 87 73 68 89 86 68 84 86
0.00 0.00 0.00 0.00 0.00 0.02 0.00
-0.01 0.00
-0.01 0.00 0.00 0.00
-0.02 0.00
-0.02 0.00
-0.02 0.00 0.00 0.00
-0.02 0.00 0.00 0.00
-0.02 0.00 0.00 0 . 0 0 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
-0.01
1 . 0 0 0 1 . 0 0 0 0 . 0 92 0 . 0 0
J 0 9 0 9 0 8 . M Mon A p r 13 0 9 : 1 6 : 2 7 2 0 0 9 VOCDATAOl P a g e : 1
Evaluate Continuing Calibration Report
Data File Acq On Sample Misc Quant Time
G:\MSCHEM\1\DATA\091108A1\1V043.D 14 Sep 2008 12:56 pm CCV f. Apr 10 07:58:07 2009
Vial Operator Inst Multiplr
3 TVK MS ttl 1.00
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:VOC H20
Min. RRF : 0.000 Min. Rel. Area : 10% Max. Max. RRF Dev : 30% Max. Rel. Area : 500%
R.T. Dev 0.50min
Compound AvgRF CCRF %Dev Area% Dev(min)
49 T 50 51 T 52 T 53 T 54 TPM 55 TP 56 TC 57 T 58 T 59 T 60 TP 61 T 62 S 63 T 64
65 1 66 TP 67 T 68 T 69 T 70 T 71 T 72 T 73 T 74 T 75 T 76 T 77 T 78 T 79 T 80 81 T 82 T 83 T 84 T
tetrachloroethene 1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachioroethane ethylbenzene m,p-xylenes o-xylene styrene bromoform isopropylbenzene bromofluorobenzene (SS-1,2,3-trichloropropane
4)
trans-1,4-dichloro-2-butene
1,4-dichlorobenzene-d4 (IS-1,1,2,2-tetrachioroethane bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethylbenzene p-chlorotoluene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene p-i sopropyltoluene 1,3-dichlorobenzene 1,4-dichlorobenzene n-butylbenzene 1,2-dichlorobenzene 1,2-Dibromo-3-chloropropane 1,2,4-trichlorobenzene hexachlorobutadi ene naphthalene 1,2,3-trichlorobenzene
0.352 0.641 0.257 0.469 0.451 0.910 0.345 1.399 1.060 1.180 0.923 0.296 1.009 0.436 0.088 0.075
1.000 1.461 1.359 4.872 3.173 3.018 3.496 2.690 3.158 3.726 2.685 1.852 1.874 3.084 1.693 0.154 0.690 0.388 0.964 0.392
0.302 0.634 0.219 0.445 0.424 0.869 0.336 1.348 1.005 1.121 0.854 0.281 0.951 0.438 0.086 0.043
1.000 1.522 1.319 4.590 3.023 2.847 3.309 2.533 3.020 3.456 2.400 1.759 1.719 2.543 1.645 0.128 0.502 0.268 0.612 0.245
14.2 1.1
14.8 5.1 6.0 4.5 2.6 3.6 5.2 5.0 7.5 5.1 5.7 -0.5 2.3
42.7tt
0.0 -4.2 2.9 5.8 4.7 5.7 5.3 5.8 4.4 7.2
10.6 5.0 8.3
17.5 2.8
16.9 27.2 30.9tt 36.5tt 37.5tt
75 88 73 85 85 85 88 86 86 84 82 85 83 93 90 52
90 89 84 82 85 82 83 82 84 80 77 83 81 72 83 75 66 62 59 59
0.00 0.00 0.00 0.00 0.00
-0.01 0.00
-0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
-0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
-0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01
{#) = Out of Range SPCC's out = 0 CCC's out
VW090908.M Mon Apr 13 09:16:27 2009 VOCDATAOl Page;
I I I I I
Quantitation Report
Data File : G:\MSCHEM\1\DATA\091108A1\1V043.D Acq On : 14 Sep 2008 12:56 pm Sample : CCV Misc : f. Quant Time: Apr 10 07:58:07 2009
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H20
(QT Reviewed)
Vial: 3 Operator: TVK Inst : MS ttl Multiplr: 1.00
Compound R .T . Qlon Response Cone U n i t s Dev(Min)
Inte 1)
33) 48) 65)
Syst( 22)
rnal Standards pentafluorobenzene (IS-1,4-Difluorobenzene (I. chlorobenzene-d5 (IS-3) 1,4 -dichlorobenzene-d4.
em Monitoring Compounds dibromofluoromethane (.
Spiked Amount 50.000 32) Sp 39)
1,2-dichloroethane-d4 . iked Amount 50.000 toluene-d8 (SS-3)
Spiked Amount 50.000 62} Sp:
bromofluorobenzene (SS-iked Amount 50.000
Target Compounds 2) 3) 4) 5) 6) 7) 8) 9)
10) 11) 12) 13) 14) 15) 16) 17) 18) 19) 20) 21) 23) 24) 25) 26) 27) 28) 29) 30) 31) 34) 35) 36) 37) 38) 40) 41) 42)
dichlorodiflouromethane chioromethane vinyl chloride bromomethane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone lodomethane carbon disulfide 112Trichloro221trifluo. acetonitrile methylene chloride acrylonitrile
1) 11 . . 13
17 . . 21
. . 11 Range . . 12 Range
15 Range
4) 19 Range
2 3 3 3 4, 4 5, 5, 5 6 6. 5 . 6 . 6. 7,
trans-1,2-dichloroethene 7, methyl-t-butyl ether hexane 1,1-dichloroethane vinyl acetate 2,2-dichloropropane cis-1,2-dichloroethene 2-butanone ethyl acetate bromochloromethane chloroform 1,1,1-trichloroethane 1,1-dichloropropene carbon tetrachloride benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromome thane bromodichloromethane
7, 8. 8, 9,
10. 10. 10. 10. 10. 11. 11. 11. 11. 12. 12. 13. 13. 14. 14.
2-chloroethyl vinyl ether 14. cis-1,3-dichloropropene 15.
.694
.055
.798
.300
.538 70
.196 70
.547 70
.578 70
.711
.046
.233
.841
.051
.552
.495
.673
.872
.009
.124
.694
.584
.940
.715
.704 ,777 ,561 ,977 ,249 ,417 ,459 .585 ,753 ,983 202 517 872 841 270 333 483 881 080 374 917 127
168 114 117 152
111 - 130 65
- 130 98
- 130 95
- 130
85 50 62 94 64
101. 56 61 43
142 76
101 41 84 53 61 73 57 63 43 77 61 43 45 49 83 97 75
119 78 62 95 63 93 83 63 75
1508904 2291334 2032644 550935
1028356
50 50 50 50
50 Recovery
873975 53 Recovery
2533830 51 Recovery
890409 50 Recovery
1813052 2255990 2170304 2080152 1390329 2556769
17537 1380110 706593m
5935141 5887815 1252676 163505
1154109 609128
1310787 3588846 550780
1903474 2079151 238022
1477424 947910 176168
1033865 1813933 1206647 1057212 845477
3399849 1157276 887943 932932 733845
1372663 692485
1155627
105 108 108 103 106 98 47 53 119 131 91 71 77 52
108 52 81 53, 52, 47, 10. 48.
126. 81. 53. 51. 49. 50. 50. 50. 52. 49. 51. 51. 51. 90. 40.
.00
.00
.00
.00
.36 = .68 = .90 = .23 =
.58
.75
.30
.33
.30
.21
.92
.82
.66
.93
.14
.79
.78
.04
.04
.40
.88
.55
.95 ,65 ,50 ,76 ,04 ,17 ,71 11 90 63 38 85 75 70 82 59 53 91 36
ug/L ug/L ug/L ug/L
ug/L 100.72% ug/L 107.36% ug/L 103.80% ug/L 100.46%
0.00 0.00 0.00 -0.01
-0.02
0.00
0.00
0.00
Qvalue ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ^ ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
100 98 98 97 99 99 88 93
99 99
100 97 98 99 95
100 98 99 97 94 97 96 92 91 98 93 99 99
100 98 95
100 94
100 99 98
J090908.M Mon Apr 13 0 9 : 1 6 : 1 5 2009 VOCDATAOl P a g e : 1
Quantitation Report
Data File : G:\MSCHEM\1\DATA\091108A1\1V043.D Acq On : 14 Sep 2008 12:56 pm Sample : CCV Misc : f. Quant Time: Apr 10 07:58:07 2009
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H20
(QT Reviewed)
Vial: 3 Operator: TVK Inst : MS ttl Multiplr: 1.00
Compound R.T. Qlon Response Cone Units Dev(Min)
43 44 45 46 47 49 50 51 52 53 54 55 56 57 58 59 60 61 631 64] 661 67 68 691 70 711 72 73 74 75 76 77 78 79 80 811 82 83 84
1 4-methyl-2-pentanone toluene
> trans-1,3-dichloropropene ethyl methacrylate 1,1,2-trichloroethane tetrachloroethene
< 1,3-dichloropropane > 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2 -tetrachioroethane ethylbenzene m,p-xylenes o-xylene styrene
isopropylbenzene 1,2,3-trichloropropane trans-l,4-dichloro-2-b... 1,1,2,2-tetrachioroethane bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethylbenzene p-chlorotoluene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene p-isopropyltoluene 1,3-dichlorobenzene 1,4-dichlorobenzene n-butylbenzene 1,2-dichlorobenzene 1,2-Dibromo-3-chloropr... 1,2,4-trichlorobenzene hexachiorobutadiene naphthalene 1,2,3-trichlorobenzene
15 15 16 16 16 16 16 16 16 17 17 17 18 18 18 18 19 19 19 19 19 19 19 20 20 20 20 20 21 21 21 21 21 21 23 24 24 24 25
.400
.651
.029
.186
.312
.500
.574
.721
.920 088 839 974 006 194 791 812 .096 347 872 893 799 809 956 093 220 251 701 775 028 247 207 343 855 898 069 295 526 663 039
43 91 75 69 97
166 76 43
129 107 112 131 91 91 91
104 173 105 110 53 83
156 91 91
105 91
119 105 105 119 146 146 91
146 157 180 225 128 180
1228247 2973859 950335
1837270 755154 613828
1287694 773606 904058 861788
1766256 683750
2740649 4087642 2279423 1735283 571944
1933899 174019 159402 838414 726719
2528524 1665254 1568267 1823168 1395712 1664042 1904148 1322310 968866 947313
1401271 906445 70678
276624 147437 337279 135246
81 50 40 89 50 42 49 74 47 46 47 48 48 94 47 46 47 47 48 52 52 48 47 47 47 47 47 47 46 44 47 45 41 48 41 36 34 31 31
.61
.44
.78
.03
.55
.86
.43
.18
.46 99 73 74 .20 83 50 .25 .48 15 85 26 08 52 10 63 16 32 09 82 38 70 48 87 23 58 75 36 49 76 28
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
98 97 96 96 94 97 97 95 99 99
100 98 96 95 97 92 98 98
100 92 97 96 97 99
100 94 96 97 97 99 98 98 96 98 88 94 98
100 99
(tt) qualifier out of range (m) = manual integration (-i-) = signals summed
VW090908.M Mon Apr 13 09:16:15 2009 VOCDATAOl Page: 2
D a t a F i l e : G:\MSCHEM\1\DATA\091108A1\1V043.D Acq On : 14 Sep 2 008 1 2 : 5 6 pm Sample : CCV Misc : f. Quant T ime : Apr 10 0 7 : 5 8 : 0 7 2009
V i a l : 3 O p e r a t o r : TVK I n s t : MS ttl M u l t i p l r : 1 .00
Quan t Method : G:\MSCHEM\l\METHODS\VW090908.M Quant T i t l e : 5 mL WATER QLast U p d a t e : Wed Sep 10 0 7 : 4 4 : 2 5 2008 R e s p o n s e v i a : I n i t i a l C a l i b r a t i o n DataAcq Meth:V0C_H20
Abundance
3400000
TIC: 1V043.D\data.ms
Time->
V W 0 9 0 9 0 8
3.00 4 00 5.00 6.00 7 00 8 9.00 I ' ' ' I I ' ' ' ' I ' ' ' ' I ' • ' ' ' ' I ' *• '• ' I *•' ' ' I ' ' ' ' I ' ' ' ' I ' ' ' ' I ' ' • • I ' ' " ' ^ P ' ' ' I
10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27 00 28.00 29.00
M Mon Apr 13 09:16:18 2009 VOCDATAOl Page:
Quantitation Report (QT Reviewed)
Data File Acq On Sample Misc Quant Time
g:\mschem\l\data\091108al\lv045.d 14 Sep 2008 2:13 pm BS f. Apr 10 08:02:20 2009
Vial: 5 Operator: TVK Inst : MS ttl Multiplr: 1.00
Quant Method : G:\MSCHEM\l\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H2O
Compound R.T. Qlon Response Cone Units Dev(Min)
Internal Standards 1) pentafluorobenzene (IS-1) 11.695
33) 1,4-Difluorobenzene (I... 13.043 48) chlorobenzene-d5 (IS-3) 17.792 65) l,4-dichlorobenzene-d4... 21.303
System Monitoring Compounds 22) dibromofluoromethane (... 11.538 Spiked Amount 50.000 Range 70 32) l,2-dichloroethane-d4 ... 12.186 Spiked Amount 50.000 Range 70
39) toluene-d8 (SS-3) 15.540 Spiked Amount 50.000 Range 70
62) bromofluorobenzene (SS-4) 19.576 Spiked Amount 50.000 Range 70
168 114 117 152
1533546 2404621 2058268 546880
50.00 ug/L 50.00 ug/L 50.00 ug/L 50.00 ug/L
0. -0, 0. 0.
00 01 00 00
111 1072514 51.68 ug/L -0.02 • 130 Recovery = 103.36% 65 887772m 53.65 ug/L 0.00
• 13 0 Recovery = 107.30% 98 2575475 50.27 ug/L 0.00
• 13 0 Recovery = 100.54% 95 890941 49.63 ug/L 0.00
• 13 0 Recovery = 99.26%
'ar< 2 3 4 5 6 7 8 9
10 11 12 13 14 15 16 17 18 19 20 21 23 24 25 26 27 28 29 30 31 34 35 36 37 381 401 41) 42)
jet Compounds 1 dichlorodiflouromethane 1 chioromethane 1 vinyl chloride < bromomethane chloroethane trichlorofluoromethane
) acrolein i 1,1-dichloroethene 1 acetone 1 lodomethane ) carbon disulfide 1 112Trichloro221trifluo... 1 acetonitrile ) methylene chloride 1 acrylonitrile 1 trans-1,2-dichloroethene i methyl-t-butyl ether hexane 1,1-dichloroethane
) vinyl acetate 2,2-dichloropropane
< cis-1,2-dichloroethene 2-butanone ethyl acetate
) bromochloromethane chloroform 1,1,1-trichloroethane 1,1-dichloropropene carbon tetrachloride benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromomethane bromodichloromethane 2-chloroethyl vinyl ether cis-1,3-dichloropropene
2 3 3 3 4 4 5 5 5 6 6 5 6 6 7 7 7 8 8 9
10 10 10 10 10 11 11 11 11 12 12 13 13 14. 14 14. 15.
.710
.045 224 .842 040 552 .490 667 .866 .002 117 .699 585 .931 725 694 .767 546 976 248 427 448 585 763 983 202 506 861 840 270 333 482 880 078 371 914 121
85 50 62 94 64
101 56 61 43 142 76
101 41 84 53 61 73 57 63 43 77 61 43 45 49 83 97 75
119 78 62 95 63 93 83 63 75
2178541 2662289 2577580 2384913 1612019 3353952
10307 1562965 791827
7498082 7744612 2238209 208000 1199421 569054 1381503 5148681 800407
2044084 1384991 261303 1594558 1046383 241741
1061113 1928593 1287554 1165699 933044
3676523 1203774 954159
1009332 743240
1496879 974555
1190381
124 126 126 116 121 126 27 59 131 164 117 126 97 53 99 54 115 76 55 31 11 51
136 109 54 53 52 54 54 52 52 50. 53. 49. 53.
121. 39.
.82
.28
.56
.57 27 .76 .71 .97 .94 .00 .96 .22 .36 .21 .31 .34 .58 57 95 23 34 78 90 59 24 46 40 93 71 40 28 89 42 79 55 92 61
Qvalue ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L a ug/L ^ ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
100 99 98 94 99 99 89 97 94 99 98 98 98 94 97 94
100 100 99 95 91 96 96 97 89 96 94 98 98 98 96 94 99 93 99 97 99
VW090908.M Mon Apr 13 09:12:06 2009 VOCDATAOl Page: 1
I I I I I I I I I
Data File : Acq On Sample Misc : Quant Time:
Quantitation Report
g:\mschem\l\data\091108al\lv045.d 14 Sep 2008 2:13 pm BS f. Apr 10 08:02:20 2009
(QT Reviewed)
Vial: 5 Operator: TVK Inst : MS ttl Multiplr: 1.00
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:VOC H20
43 44 45 46 47 49 50 51 52 53 54 55 56 57 58 59 60 61 63 64 66 67 68 69 70 71 72 731 741 751 761 77) 78) 79) 80) 81) 82) 83) 84)
Compound
1 4-methyl-2-pentanone \ toluene 1 trans-1,3-dichloropropene 1 ethyl methacrylate 1 1,1,2-trichloroethane ' tetrachloroethene i 1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2 -tetrachioroethane ethylbenzene m,p-xylenes o-xylene styrene
isopropylbenzene 1,2,3-trichloropropane trans-1,4-dichloro-2-b... 1,1,2,2-tetrachioroethane bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethylbenzene p-chlorotoluene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene p-isopropyltoluene 1,3-dichlorobenzene 1,4-dichlorobenzene n-butylbenzene 1,2-dichlorobenzene 1,2-Dibromo-3-chloropr... 1,2,4-trichlorobenzene hexachiorobutadiene naphthalene 1,2,3-trichlorobenzene
15 15 16 16 16 16 16 16 16 17 17 17 18 18 18 18 19 19 19 19 19 19 19 20 20 20 20 20 21 21 21 21 21 21 23 24 24. 24. 25.
R.T.
.404
.646
.033
.190
.316
.504
.567
.725
.924
.091
.844
.969 Oil 190 788 809 103 345 869 891 806 806 953 089 213 255 704 778 030 250 209 335 860 891 063 287 519 656 031
Qlon
43 91 75 69 97
166 76 43
129 107 112 131 91 91 91
104 173 105 110 53 83
156 91 91
105 91
119 105 105 119 146 14 6 91
146 157 180 225 128 180
Response
1701224 3284174 973386
2163258 768441 664442
1292832 995741 957804 875767
1860121 684054
2994950 4462269 2539235 1850370 564182
2223683 193143 230035 844571 750979
2846854 1765356 1723423 1922857 1554801 1838527 2100217 1512013 995035
1004171 1560239 929057 82804
345332 196412 572040 249044
Cone Units Dev(Min)
107 53 39 99 49 45 49 94 49 47 49 48 52
102 52 48 46 53 53 74 52 50 53 50 52 50 52 53 51 51 49 48 46. 50. 49. 45. 46. 54. 58.
.71
.08
.80
.89
.02
.81
.01
.30
.66
.16
.64
.15 02 23 .26 .70 25 54 54 48 85 51 42 87 21 28 84 22 54 50 12 99 25 16 28 73 29 26 02
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
94 96 99 94 97 97 99 98 99 99 98 98 97 95 96 96 97 98 99 92 99 97 99
100 98 97 97 98 97 99 99
100 99 99 93
100 96
100 97
(tt) qualifier out of range (m) = manual integration (•»•) = signals summed
J090908.M Mon Apr 13 09:12:06 2009 VOCDATAOl Page: 2
Quantitation Report (QT Reviewed)
D a t a F i l e : g : \ m s e h e m \ l \ d a t a \ 0 9 1 1 0 8 a l \ l v 0 4 5 . d Acq On : 14 Sep 2008 2 : 1 3 pm Sample : BS Misc : f. Quant T ime: Apr 10 0 8 : 0 2 : 2 0 2009
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant T i t l e : 5 mL WATER QLast Upda t e : Wed Sep 10 0 7 : 4 4 : 2 5 2008 R e s p o n s e v i a : I n i t i a l C a l i b r a t i o n DataAcq Meth:VOC H20
V i a l : 5 O p e r a t o r : TVK I n s t : MS ttl M u l t i p l r : 1 .00
Abundance 3800000
TIC: 1v045.d\data.ms
Time~> 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10!00 1L00 12!00 1300 14!00 15!00 16.00 17.00 18.00 1900 20.00 21.00 22.00 23.00 2400 25.00 26.00 27.00 28 00 29.00
VW090908.M Mon A p r 13 0 9 : 1 2 : 0 8 2 0 0 9 VOCDATAOl P a g e : 3
I I I I
Data File Acq On Sample Misc Quant Time
Quantitation Report
G:\MSCHEM\1\DATA\091108A1\1V046.D 14 Sep 2008 2:51 pm 18I0314-01MS lOX Apr 13 09:38:31 2009
(QT Reviewed)
Vial: 6 Operator: TVK Inst : MS ttl Multiplr: 1.00
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H20
Compound R.T. Qlon Response Cone Units Dev(Min)
Internal Standards 1) pentafluorobenzene (IS-
33) 1,4-Difluorobenzene (I. 48) chlorobenzene-d5 (IS-3) 65) 1,4-dichlorobenzene-d4.
System Monitoring Compounds 22) dibromofluoromethane (. Spiked Amount 50.000 32) 1,2-diehloroethane-d4 . Spiked Amount 50.000
39) toluene-d8 (SS-3) Spiked Amount 50.000
62) bromofluorobenzene (SS-Spiked Amount 50.000
Tare 2 3 4 5 6 7 8 9
10 11 12 13 14 15 16 17 18 19 20 21 23 24 25 26 27 28 29 30 31 34 35 36 37 38 40 41 42
et Compounds dichlorodiflouromethane chioromethane vinyl chloride bromome thane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone lodomethane carbon disulfide 112Trichloro221trifluo. acetonitrile methylene chloride acrylonitrile trans-1,2-dichloroethene methyl-t-butyl ether hexane 1,1-dichloroethane vinyl acetate 2,2-di chloropropane cis-1,2-dichloroethene 2-butanone ethyl acetate bromochloromethane chloroform 1,1,1-trichloroethane 1,1-dichloropropene carbon tetrachloride benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromomethane bromodichloromethane 2-chloroethyl vinyl ether cis-1,3-dichloropropene
1 ) 1 1 . . 13
17 . . 21
. . 11 Range . . 12 Range
15 Range
4) 19 Range
2 3 3 3 4 4 5 5 5 6 6 5 6 6 7
e 7 7 8 8 9
10 10 10 10 10 11 11 11. 11. 12. 12. 13. 13. 14. 14.
er 14. 15.
.694
.056
.796
.294
.547 70
.187 70
.545 70
.572 70
.712
.047
.235
.839
.048 558 .497 .675 872 009 124 696 592 936 720 699 784 556 986 247 419 450 586 753 982 211 505 863 831 271 334 483 880 080 371 916 126
168 114 117 152
111 - 130
65 - 130
98 - 130
95 - 130
85 50 62 94 64
101 56 61 43
142 76
101 41 84 53 61 73 57 63 43 77 61 43 45 49 83 97 75
119 78 62 95 63 93 83 63 75
1540418 2412236 2013972 570661
1053057
50 50 50 50
50 Recovery
884294 53 Recovery
2604574 50 Recovery
902972 51 Recovery
2141188 2622056 2538166 2302726 1576941 3341078 120094
1537359 770200m
7319074 8102576 2312451 216723
1184660 609585
1393206 4998851 963288
1976766 4711843 246891
1568485 972398 237844
1019020 1887088 1251719 1200893 918748
3659015 1165859 1278929 975689 717410
1469190 502503
1193196
122 123 124 112 118 125 321 58
127 159 122 129 100 52
105 54
111 91 53
105 10 50
126 107 51 52 50 56 53 51. 50. 67. 51. 47. 52. 62. 39.
.00
.00
.00
.00
.52
= .20
= .68
= .41
=
.13
.82
.07
.05
.10
.71
.41
.73
.76
.37
.86 82 99 32 91 55 71 74 87 78 66 70 65 34 85 08 71 34 63 99 47 99 48 91 39 66 58
ug/L ug/L ug/L ug/L
ug/L 101.04% ug/L 106.40% ug/L 101.36% ug/L 102.82%
0.00 0.00 0.00 -0.02
0.00
0.00
0.00
-0.01
Qvalue ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ^ ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
100 99 97 93 98
100 100 94
100 99 98 99 97 98 94
100 99
100 97 90 97 93 92 92 98 94 96 97 99 97 94 98 94 97 98 98
*090908.M Mon Apr 13 09:21:54 2009 VOCDATAOl Page: 1
Quantitation Report
Data File : G:\MSCHEM\1\DATA\091108A1\1V046.D Acq On : 14 Sep 2008 2:51 pm Sample : 1810314-OlMS Misc : lOX Quant Time: Apr 13 09:38:31 2009
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H20
(QT Reviewed)
Vial: Operator: Inst Multiplr:
6 TVK M S ttl 1.00
43 44 45 46 47 49 50 51 52 53 54 55 56 57 58 59 60) 611 631 641 66] 67] 68] 691 70] 711 72] 731 74] 75] 76] 77) 78] 79] 80] 81) 82] 83) 84)
Compound
1 4-methyl-2-pentanone ) toluene ' trans-1,3-dichloropropene ) ethyl methacrylate 1 1,1,2-trichloroethane 1 tetrachloroethene 1,3-dichloropropane 2-hexanone dibromochloromethane
) 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachioroethane ethylbenzene m,p-xylenes o-xylene styrene
isopropylbenzene 1,2,3-trichloropropane trans-l,4-dichloro-2-b... 1,1,2,2-tetrachioroethane bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethylbenzene p-chlorotoluene tert-butylbenzene 1,2,4 -trimethylbenzene sec-butylbenzene p-isopropyltoluene 1,3-dichlorobenzene 1,4-dichlorobenzene n-butylbenzene 1,2-dichlorobenzene 1,2-Dibromo-3-chloropr... 1,2,4 -trichlorobenzene hexachiorobutadiene naphthalene 1,2,3-trichlorobenzene
]
15 15 16 16 16 16 16 16 16 17 17 17 18 18 18 18 19 19 19 19 19 19 19 20 20 20 20 20 21 21 21 21 21 21 23 24. 24 24. 25
R.T.
.399
.649
.035
.182
.318
.507
.570
.717
.925
.083
.838 974 006 185 783 814 099 340 865 886 801 801 959 086 223 254 706 779 031 241 209 336 861 893 064 290 521 657 033
Qlon
43 91 75 69 97
166 76 43 129 107 112 131 91 91 91
104 173 105 110 53 83
156 91 91
105 91
119 105 105 119 146 146 91
146 157 180 225 128 180
Response
1646211 3243576 963451
2324505 741456 740779
1249029 976625 932189 859788
1787441 659497
3000581 4414152 2479270 1928451 553334
2202075 181371 221225 806095 727058
2865993 1733370 1746278 1927929 1530020 1823242 2078231 1534501 984797 991402
1633284 900618 82213
354881 211075 574038 248169
Cone Units Dev(Min)
103 52 39
106 47 52 48 94 49 47 48 47 53 103 52 51 46 54 51 73 48 46 51 47 50 48 49 50 48 50 46 46 46 46 46 45 47 52. 55
.90
. 2 6
.27
.99
.15
.20
.39
.52
.39
.31
.75 44 26 35 15 87 36 19 38 20 34 86 54 87 69 31 83 58 87 08 59 35 40 60 89 04 67 18 41
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
97 99 95 94 98 99 98 97 96 99 97
100 96 94 94 96
100 98
100 95 99 99 97 97 98 97 94 97 98 98 99
100 99
100 97 98 99
100 90
m cjualifier out of range (m) = manual integration (•»•) = signals summed
VW090908.M Mon Apr 13 09:21:54 2009 VOCDATAOl Page:
n e t
Data File : G:\MSCHEM\1\DATA\091108A1\1V046.D Acq On : 14 Sep 2008 2:51 pm Sample : 18I0314-01MS Misc : lOX Quant T ime : Apr 13 0 9 : 3 8 : 3 1 2009
Vial Operator Inst Multiplr
6 TVK MS ttl 1.00
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant T i t l e : 5 mL WATER QLas t U p d a t e : Wed Sep 10 0 7 : 4 4 : 2 5 2008 R e s p o n s e v i a : I n i t i a l C a l i b r a t i o n DataAcq Meth:V0C_H20
Abundance
3600000
TIC: 1V046.D\data ms
Time-> 3.00 4.00 5.00 6.00 7.00 8.00 9.00 I I I I I I I I I I I I I I I I I I I I I I I ' ' I I I I I I I • • • I ' " ' ' I ' ' ' ' I ' ' ' ' I ' ' ' ' ! " ' ' ' ' I ' ' ' ' I ' ' ' ' I ' ' ' ' I ' ' ' ' I
10.00 1100 12.00 13.00 14.00 15.00 16.00 17 00 18.00 19.00 20.00 21.00 22.00 23 00 24.00 25.00 26.00 27.00 28.00 29.00
VW090908.M Mon Apr 13 09:21:56 2009 VOCDATAOl Page:
Quantitation Report (QT Reviewed)
Data File : G:\MSCHEM\1\DATA\091108A1\1V047.D Acq On : 14 Sep 2008 3:30 pm Sample : 18I0314-01MSD Misc : lOX Quant Time: Apr 13 09:38:36 2009
Quant Method : G:\MSCHEM\l\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H20
Vial Operator Inst Multiplr
7 TVK MS ttl 1.00
Compound R.T. Qlon Response Cone Units Dev(Min)
Internal Standards 1) pentafluorobenzene (IS-1) 33) 1,4-Difluorobenzene (I.. 48) chlorobenzene-d5 (IS-3) 65) 1, 4-diehlorobenzene-d4..
System Monitoring Compounds 22) dibromofluoromethane (.. Spiked Amount 50.000 32) 1,2-dichloroethane-d4 .. Spiked Amount 50.000 39) toluene-d8 (SS-3) Spiked Amount 50.000 62) bromofluorobenzene (SS-4) Spiked Amount 50.000
Target Compounds 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 23 24 25 26 27 28 29 30 31 34 35 36 37 38 40 41 42
dichlorodiflouromethane chioromethane vinyl chloride bromomethane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone lodomethane carbon disulfide 112Trichloro221trifluo.. acetonitrile methylene chloride acrylonitrile trans-1,2-dichloroethene methyl-t-butyl ether hexane 1,1-dichloroethane vinyl acetate 2,2-dichloropropane cis-1,2-dichloroethene 2-butanone ethyl acetate bromochloromethane chloroform 1,1,1-trichloroethane 1,1-dichloropropene carbon tetrachloride benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromomethane bromodichloromethane 2-chloroethyl vinyl ether cis-1,3-dichloropropene
) 1 1 . 13
17 21
. 11 Range . 12 Range
15 Range ) 19 Range
2 3 3 3 4 4 5 5 5 6 6 5 6 6 7 7 7 8 8 9
10 10 10 10 10 11 11 11 11. 12. 12. 13. 13. 14. 14.
r 14. 15.
.690
.051
.798
.300
.543 70
.192 70
.538 70
.578 70
.712
.048 236 841 051 552 490 668 879 005 120 700 581 937 722 702 785 555 983 245 426 458 583 761 982 201 512 859 837 266 339 479 885 085 376 910 119
168 114 117 152
111 - 130 65
- 130 98
- 130 95
- 130
85 50 62 94 64
101 56 61 43 142 76
101 41 84 53 61 73 57 63 43 77 61 43 45 49 83 97 75
119 78 62 95 63 93 83 63 75
1560206 2444079 2088434 560641
1091996
50 50 50 50
51 Recovery
914444 54 Recovery
2645476 50 Recovery
920492 50 Recovery
2323147 2751193 2656671 2374173 1637340 3503981 127149
1608079 801985m
7566895 8447159 2447123 219165
1200113 628102
1432526 5114012 1067831 2053746 4928960 252370 1630025 1027350 251622
1069145 1941593 1344047 1241548 941508
3698222 1196253 1311200 997730 738435
1509678 569427
1230055
130 128 128 114 121 130 335 60
131 162 126 135 100 52 107 55
112 100 55
109 10 52
132 112 53. 52. 53. 57. 54. 51. 51. 68. 51. 48. 53. 70. 40.
.00 ug/L
.00 ug/L
.00 ug/L
.00 ug/L
.72 ug/L = 103.44% .32 ug/L = 108.64% .80 ug/L = 101.60% .54 ug/L = 101.08%
-0.01 0.00 0.00 -0.01
-0.01
0.00
0.00
0.00
Qvalue .83 ug/L .27 ug/L .21 ug/L .06 ug/L .07 ug/L .17 ug/L 98 ug/L .65 ug/L .35 ug/L 6 8 ug/L 46 ug/L 64 ug/L 83 ug/L 33 ug/L 74 ug/L 38 ug/L 84 ug/L 4 0 ug/L 25 ug/L 25 ug/L 76 ug/L # 02 ug/L 11 ug/L 12 ug/L 72 ug/L 90 ug/L 76 ug/L 51 ug/L 26 ug/L 86 ug/L 11 ug/L 80 ug/L 95 ug/L # 67 ug/L 13 ug/L 08 ug/L 27 ug/L
98 98
100 95
100 99 92 94
99 99 98 95 95 96 95
100 93 99 96 87 97 96
100 90 97 96 96
100 98 95 95 97 97 98 97
100
VW090908.M Mon Apr 13 09:21:59 2009 VOCDATAOl Page: 1
I I I I I I I I I I I I I I I I I I
Quantitation Report
G:\MSCHEM\1\DATA\091108A1\1V047.D 14 Sep 2008 3:30 pm 18I0314-01MSD lOX
Data File Acq On Sample Misc Quant Time: Apr 13 09:38:36 2009
(QT Reviewed)
Vial: 7 Operator: TVK Inst : MS ttl Multiplr: 1.00
Quant Method Quant Title QLast Update Response via
G:\MSCHEM\1\METHODS\VW090908.M 5 mL WATER Wed Sep 10 07:44:25 2008 Initial Calibration
Data/kcq Meth:V0C_H20
Compound R.T. Qlon Response Cone Units Dev(Min)
43 44 45 46 47 49 50 51 52 53 54 55 56 57 58 59 60 61 63 64 66 671 68 69 70 71 72 731 741 751 76] 77] 78] 79] 80] 811 82] 83) 84]
1 4-methyl-2-pentanone 1 toluene 1 trans-1,3-dichloropropene 1 ethyl methacrylate 1 1,1,2-trichloroethane 1 tetrachloroethene 1 1,3-dichloropropane 1 2-hexanone ) dibromochloromethane ) 1,2-dibromoe thane chlorobenzene 1,1,1,2 -tetrachioroethane ethylbenzene m,p-xylenes o-xylene styrene bromoform isopropylbenzene 1,2,3-trichloropropane trans-1,4-dichloro-2-b... 1,1,2,2-tetrachioroethane bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethylbenzene p-chlorotoluene tert-butylbenzene 1,2,4 -trimethylbenzene sec-butylbenzene p-isopropyltoluene 1,3-dichlorobenzene 1,4-dichlorobenzene n-butylbenzene 1,2-dichlorobenzene 1,2-Dibromo-3-chloropr... 1,2,4 -trichlorobenzene hexachlorobutadi ene naphthalene 1,2,3-trichlorobenzene
15 15 16 16 16 16 16 16 16 17 17 17 18 18 18 18 19 19 19 19 19 19 19 20 20 20 20 20 21 21 21 21. 21 21 23. 24. 24. 24. 25.
.401
.642
.029
.185
.311
.500
.572
.719
.918
.084 840 965 007 187 784 816 099 339 862 883 798 798 957 082 218 250 701 775 026 247 204 342 856 898 068 286 516 664 032
43 91 75 69 97
166 76 43 129 107 112 131 91 91 91
104 173 105 110 53 83
156 91 91
105 91
119 105 105 119 146 14 6 91
146 157 180 225 128 180
1707145 3333504 987216
2433168 769071 788622
1298745 1016241 956899 887199
1868806 690171
3047722 4601272 2562557 1987724 560429
2305400 189669 220381 845031 749124
2947469 1804904 1782807 1992112 1602861 1873618 2197353 1640373 1029215 1030642 1766762 946149 81871
357293 215747 555653 254689
106 53 39
110 48 53 48 94 48 47 49 47 52
103 51 51 45 54 51 70 51 49 53 50 52 50 53 52 52 54 49 49 51 49 47 46 49 51. 57.
.34
.01
.72
.54
.27
.59
.52
.85
.89
.08 16 88 .17 89 98 56 28 71 82 32 58 15 95 74 68 81 14 91 60 50 57 04 08 83 53 15 60 42 88
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
98 98 97 95 93 99 99 95 98 98 97 97 97 94 96 99
100 97 96 97 98 99 97 98 96 94 97 94 99 98
100 97 97 98 95 99 95
100 93
{#) = cjualifier out of range (m) = manual integration (+) = signals summed
J090908.M Mon Apr 13 09:21:59 2009 VOCDATAOl Page: 2
Quantitation Report (QT Reviewed)
Data File : G:\MSCHEM\1\DATA\091108A1\1V047.D Acq On : 14 Sep 2008 3:30 pm Sample : 1810314-OlMSD Misc : lOX Quant Time: Apr 13 09:38:36 2009
Vial Operator Inst Multiplr
7 TVK MS ttl 1 . 0 0
Q u a n t M e t h o d Q u a n t T i t l e Q L a s t U p d a t e R e s p o n s e v i a
G:\MSCHEM\1\METHODS\VW090908.M 5 mL WATER Wed S e p 10 0 7 : 4 4 : 2 5 2 0 0 8 I n i t i a l C a l i b r a t i o n
D a t a A c q M e t h : V 0 C _ H 2 0
Abundance 4000000
3500000
3000000
2500000
2000000
1500000
1000000
500000
Time->
VW090908 ,
TIC. 1V047 D\data ms
I ' ' ' ' T 4.00 5.00 6.1 800 10.00 11.00 12.00 13.00 14.00 15 00 16.00 17.00
M Mon A p r 13 0 9 : 2 2 : 0 2 2 0 0 9 VOCDATAOl
I I I-r l ' l I iT I | T I I I p I I I I I I 11 '11 I I I I I I I I I
19 00 20.00 21.00 22.00 23.00 24.00 25 00 26.00 27.00 28.00 29.00
P a g e : 3
Quantitation Report (QT Reviewed)
Data File : G:\MSCHEM\1\DATA\091108A1\1V050.D Acq On : 14 Sep 2008 5:24 pm Sample : BLK Misc : f. Quant Time: Apr 13 09:38:42 2009
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H20
Vial Operator Inst Multiplr
10 TVK MS ttl 1.00
Compound R.T. Qlon Response Cone Units Dev(Min)
Internal Standards 1) pentafluorobenzene (IS-
33) 1,4-Difluorobenzene (I. 48) chlorobenzene-d5 (IS-3) 65) 1,4-diehlorobenzene-d4.
System Monitoring Compounds 22) dibromofluoromethane (. Spiked Amount 50.000
32) 1,2-diehloroethane-d4 . Spiked Amount 50.000
39) toluene-d8 (SS-3) Spiked Amount 50.000 62) bromofluorobenzene (SS-Spiked Amount 50.000
Target Compounds 2 3 4 5 6 7 8 9
10 11 12 13 14 15 16 17 18 19 20 21 23 24 25 26 27 28 29 30 31 34 35 36 37 38 40 41 42
dichlorodiflouromethane chioromethane vinyl chloride bromome thane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone lodomethane carbon disulfide 112Trichloro221trifluo. acetonitrile methylene chloride acrylonitrile trans-1,2-dichloroethene methyl-t-butyl ether hexane 1,1-dichloroethane vinyl acetate 2,2-dichloropropane cis-1,2-dichloroethene 2-butanone ethyl acetate bromochloromethane chloroform 1,1,1-trichloroethane 1,1-dichloropropene carbon tetrachloride benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromomethane bromodichloromethane 2-chloroethyl vinyl ether cis-1,3-dichloropropene
1) 11.687 .. 13.046
17.790 .. 21.301
.. 11.539 Range 7 0
12.189 Range 7 0
15.540 Range 70
4) 19.570 Range 7 0
0.000 0.000 0.000 3.828 0.000 0.000 0.000 0.000 0.000 0.000 6.105 0.000 0.000 6.919 0.000
e 0.000 0.000 0.000 0.000 8.818 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
er 0.000 0.000
168 114 117 152
111 - 130 65
- 130 98
- 130 95
- 130
94
76
84
43
1701836 2433133 2069247 564029
1230704
50.00 50.00 50.00 50.00
53.44 Recovery
940464 51.21 Recovery =
2718185 52.44 Recovery =
892759 49.47 Recovery =
0 0 0
1173 0 0 0 0 0 0
2369 0 0
10793m 0 0 0 0 0
490 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
N.D N.D N.D N.D N.D. N.D. N.D N.D. N.D. N.D N.D. N.D N.D. 0.43 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D.
ug/L ug/L ug/L ug/L
ug/L 106.88% ug/L 102.42% ug/L 104.88% ug/L 98.94%
-0 0 0 -0
-0
0
0
-0
01 00 00 01
02
00
00
02
Qvalue
d
d ug/L
d
d d
d
/090908.M Mon Apr 13 09:22:05 2009 VOCDATAOl Page: 1
Quantitation Report (QT Reviewed)
Data File : G:\MSCHEM\1\DATA\091108A1\1V050.D Acq On : 14 Sep 2008 5:24 pm Sample : BLK Misc : f. Quant Time: Apr 13 09:38:42 2009
Vial: Operator: Inst : Multiplr:
10 TVK MS ttl 1.00
Quant Method Quant Title QLast Update Response via
G:\MSCHEM\1\METHODS\VW090908.M 5 mL WATER Wed Sep 10 07:44:25 2008 Initial Calibration
DataAcq Meth:V0C_H20
43 44 45 46 47 49 50 51 52 53 54 55 56 57 58 59 60] 611 63] 64] 66] 67] 68] 69] 701 711 72] 73 74] 751 76] 77] 78] 79] 80] 81) 82) 83) 84)
Compound
1 4-methyl-2-pentanone 1 toluene 1 trans-1,3-dichloropropene 1 ethyl methacrylate 1,1,2-trichloroethane tetrachloroethene 1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachioroethane ethylbenzene m,p-xylenes o-xylene styrene
isopropylbenzene 1,2,3-trichloropropane trans-1,4-dichloro-2-b... 1,1,2,2-tetrachioroethane bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethylbenzene p-chlorotoluene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene p-isopropyltoluene 1,3-dichlorobenzene 1,4-dichlorobenzene n-butylbenzene 1,2-dichlorobenzene 1,2-Dibromo-3-chloropr... 1,2,4-trichlorobenzene hexachiorobutadiene naphthalene 1,2,3-trichlorobenzene
R.T.
0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
17.790 17.790 0.000 0.000 0.000 0.000 0.000 0.000
19.791 0.000
20.084 20.084 0.000
20.273 0.000
20.787 21.039 21.258 21.218 21.332 0.000
21.929 0.000
24.350 24.528 0.000
25.053
Qlon
91 91
83
91 91
91
105 105 119 146 146
146
180 225
180
Response
0 0 0 0 0 0 0 0 0 0 0 0
3309 3309
0 0 0 0 0 0
323 0
354 354
0 454
0 869
2013 1962 1058 1951
0 501
0 1783 5189
0 9636
Cone Units Dev(Min)
N.D. d N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 0.23 ug/L # 1.19 ug/L i N.D. d 2.18 ug/L n
12 83
74
(tt) cjualifier out of range (m) = manual integration (-i-) = signals summed
VW090908.M Mon Apr 13 09:22:05 2009 VOCDATAOl Page;
Iio: (Ql I V K
D a t a F i l e : G:\MSCHEM\1\DATA\091108A1\1V050.D Acq On : 14 Sep 2008 5:24 pm Sample : BLK Misc : f. Quant T ime: Apr 13 0 9 : 3 8 : 4 2 2009
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant T i t l e : 5 mL WATER QLas t U p d a t e : Wed Sep 10 0 7 : 4 4 : 2 5 2008 R e s p o n s e v i a : I n i t i a l C a l i b r a t i o n DataAcq Meth:V0C_H20
Abundance
2000000
1800000
1600000
1400000
1200000
1000000
800000
600000
400000
200000 1
-"-n-
4
V i a l : 10 O p e r a t o r : TVK I n s t : MS ttl M u l t i p l r : 1 .00
L.
TIC- 1V050.DVdata ms
T T - I
10.
? CO
1 E
I i 3
I ' ' " I V T J I S T ^ - n ^ M I 1 I I I 1 1 ' I ' I '•• f ' T ^ Time-> 3.00 4.00 5.00 6 00 7 00 8 00 9.00 10 00 11.00 12.00 13.00 14.00 15.00 16 00 17.00 18 00 19.00 20.00 21.00 22 00 23 00 24.00 25.00 26.00 27.00 28.00 29.00
VW090908.M Mon A p r 13 0 9 : 2 2 : 0 8 2 0 0 9 VOCDATAOl P a g e : 3
Quantitation Report (QT Reviewed)
Data File : G:\MSCHEM\1\DATA\091108A1\1V051.D Acq On : 14 Sep 2008 6:02 pm Sample : 1810314-01 Misc : f. Quant Time: Apr 13 09:38:48 2009
Quant Method : G:\MSCHEM\l\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H20
Vial: Operator: Inst : Multiplr:
11 TVK MS ttl 1.00
Compound R.T. Qlon Response Cone Units Dev(Min)
Internal Standards 1) pentafluorobenzene (IS-1) 33) 1,4-Difluorobenzene (I. 48) chlorobenzene-d5 (IS-3) 65) 1,4-dichlorobenzene-d4.
System Monitoring Compounds 22) dibromofluoromethane (. Spiked Amount 50.000 32) 1,2-dichloroethane-d4 . Spiked Amount 50.000 39) toluene-d8 (SS-3) Spiked Amount 50.000 62) bromofluorobenzene (SS-4) Spiked Amount 50.000
Target Compounds 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 23 24 25 26 27 28 29 30 31 34 35 36 37 38 40 41 42
dichlorodiflouromethane chioromethane vinyl chloride bromomethane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone lodomethane carbon disulfide 112Trichloro221trifluo.. acetonitrile methylene chloride acrylonitrile trans-1,2-dichloroethene methyl-t-butyl ether hexane 1,1-dichloroethane vinyl acetate 2,2-dichloropropane cis-1, 2-dichloroethene 2-butanone ethyl acetate bromochloromethane chloroform 1,1,1-trichloroethane 1,1-diehloropropene carbon tetrachloride benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromomethane bromodi chlorome thane 2-chloroethyl vinyl ether cis-1,3-dichloropropene
.) 11.687 13.050 17.793 21.296
. 11.541 Range 7 0 . 12.191 Range 70
15.536 Range 7 0 ) 19.569 Range 7 0
0.000 3.286 0.000 3.797 0.000 0.000 0.000 5.655 5.906 0.000 6.116 0.000 0.000 6.900 0.000 7.692 0.000 0.000 0.000 9.297 0.000
10.455 10.623 10.978 0.000 0.000 0.000 0.000 0.000
12.264 0.000
13.479 0.000 0.000 0.000
r 0.000 0.000
168 114 117 152
111 - 130 65
- 130 98
- 130 95
- 130
50
94
61 43
76
84
61
43
61 43 45
78
95
1664321 2410518 1970622 508591
1220566
50.00 ug/L 50.00 ug/L 50.00 ug/L 50.00 ug/L
54.19 ug/L Recovery = 108.38%
954473 53.15 ug/L Recovery = 106.30%
2632643 51.26 ug/L Recovery = 102.52%
855117 49.76 ug/L Recovery = 99.52%
0 713
0 907
0 0 0
2402 12680
0 8713
0 0
347 0
770 0 0 0
12207 0
463117 329 333
0 0 0 0 0
13842 0
3518222 0 0 0 0 0
-0.01 0.00 0.00 -0.02
-0.01
0.00
0.00
•0.02
Qvalue N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1.95 ug/L # N.D. N.D. N.D. N.D. d N.D. N.D. N.D. N.D. N.D. N.D. 0.25 ug/L tt N.D.
13.86 ug/L N.D. N.D. N.D. N.D. N.D. N.D. d N.D. d N.D. N.D.
187.17 ug/L N.D. N.D. N.D. N.D. N.D.
46
77
96
97
VW090908.M Mon Apr 13 09:22:11 2009 VOCDATAOl Page: 1
I I I I I
Quantitation Report
Data Pile : G:\MSCHEM\1\DATA\091108A1\1V051.D Acq On : 14 Sep 2008 6:02 pm Sample : 1810314-01 Misc : f. Quant Time: Apr 13 09:38:48 2009
(QT Reviewed)
Vial: 11 Operator: TVK Inst : MS ttl Multiplr: 1.00
Quant Method Quant Title QLast Update Response via
G:\MSCHEM\1\METHODS\VW090908.M 5 mL WATER Wed Sep 10 07:44:25 2008 Initial Calibration
DataAcq Meth:V0C_H20
Compound R.T. Qlon Response Cone Units Dev(Min)
43 44 45 46 47 49 50 51 52 53 54 55 56 57 58 59 60 61 63 64 66 67 68 69 70 71 72 73 74] 75] 761 77) 78) 79) 80) 81) 82) 83) 84)
1 4-methyl-2-pentanone 1 toluene i trans-1,3-dichloropropene ethyl methacrylate 1,1,2 -trichloroethane tetrachloroethene
' 1,3-dichloropropane I 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2 -tetrachioroethane ethylbenzene m,p-xylenes o-xylene styrene bromoform isopropylbenzene 1,2,3 -trichloropropane trans-1,4-diehloro-2-b... 1,1,2,2-tetrachioroethane bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethylbenzene p-chlorotoluene tert-butylbenzene 1,2,4-trimethylbenzene see-butylbenzene p-i sopropyltoluene 1,3-dichlorobenzene 1,4-dichlorobenzene n-butylbenzene 1,2-dichlorobenzene 1,2-Dibromo-3-chloropr... 1,2,4-trichlorobenzene hexachiorobutadiene naphthalene 1,2,3-trichlorobenzene
0.000 15.651 0.000 0.000 0.000
16.495 0.000 0.000 0.000 0.000 0.000 0.000
18.013 18.190 18.786 0.000
19.548 0.000 0.000 0.000 0.000 0.000
19.978 19.978 0.000
19.978 0.000
20.784 21.024 21.275 21.328 21.328 0.000
21.924 0.000
24.359 24.527 0.000
25.060
91
166
91 91 91
173
91 91
91
105 105 119 146 146
146
180 225
180
0 12975
0 0 0
929731 0 0 0 0 0 0
6614 3093 385
0 599
0 0 0 0 0
731 731
0 731
0 830 534 716
1191 1191
0 320
0 326
2513 0
3153
N.D. 0.21 N.D. N.D. N.D.
66.96 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 0.64 N.D. 0.79
d ug/L H
d ug/L
d
ug/L d
ug/L »
76
99
93
54
in) cjualifier out of range (m) = manual integration (+) = signals summed
/090908.M Mon Apr 13 09:22:11 2009 VOCDATAOl Page: 2
Quantitation Report (QT Reviewed)
Da ta F i l e Acq On Sample Misc Quant Time
G:\MSCHEM\1\DATA\091108A1\1V051.D 14 Sep 2008 6 :02 pm 1 8 1 0 3 1 4 - 0 1 f, Apr 13 0 9 : 3 8 : 4 8 2009
V i a l : 11 O p e r a t o r : TVK I n s t : MS ttl M u l t i p l r : 1 .00
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant T i t l e : 5 mL WATER QLast U p d a t e : Wed Sep 10 0 7 : 4 4 : 2 5 2 008 Response v i a : I n i t i a l C a l i b r a t i o n DataAcq Meth:VOC H20
Abundance 5000000
4500000
4000000
3500000
3000000
2500000
2000000
1500000
1000000
500000
TIC.1V051.DVdata.ms
S 8
fi V
i
3 1 -
V U M 0 " i " | M I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I ^ \ I I I / 1 N I I I I I I I I I I I I . .
Time-> 3.00 4 00 5.00 6.00 7.00 8 00 9 00 10.00 11.00 12 00 13.00 14.00 15.00
VW090908.M Mon Apr 13 09:22:14 2009 VOCDATAOl
E £
i o
£ a
N I I I 1 1 I I I I I ' i \ I I I I I I I ' i S I f I I I I / V l I I I I I I I I I I I I I I I 1 1 I I I I I I I I I I I I I I I I I I 1 1 I I
16.00 17.00 18.00 19.00 20.00 21.00 22.00 23 00 24.00 25.00 26.00 27.00 28.00 29 00
P a g e : 3
Quantitation Report (QT Reviewed)
Data File : G:\MSCHEM\1\DATA\091108A1\1V056.D Acq On : 14 Sep 2008 9:12 pm Sample : 1810571-01 Misc : f. Quant Time: Apr 10 07:54:03 2009
Vial Operator Inst Multiplr
16 TVK M S ttl 1.00
Quant Method Quant Title QLast Update Response via
G:\MSCHEM\1\METHODS\VW090908.M 5 mL WATER Wed Sep 10 07:44:25 2008 Initial Calibration
DataAcq Meth:V0C_H20
Compound R.T. Qlon Response Cone Units Dev(Min)
Internal Standards 1) pentafluorobenzene (IS-
33) 1,4-Difluorobenzene (I. 48) ehlorobenzene-d5 (IS-3) 65) 1,4-dichlorobenzene-d4.
System Monitoring Compounds 22) dibromofluoromethane (. Spiked Amount 50.000
32) l,2-dichloroethane-d4 . Spiked Amount 50.000
39) toluene-d8 (SS-3) Spiked Amount 50.000
62) bromofluorobenzene (SS-Spiked Amount 50.000
Target Compounds 2) dichlorodiflouromethane 3} chioromethane 4) vinyl chloride 5) bromomethane 61 chloroethane 7) trichlorofluoromethane 8) acrolein 9) 1,1-dichloroethene
10) acetone 11) lodomethane 12) carbon disulfide 13) 112Trichloro221trifluo. 14) acetonitrile 15) methylene chloride 16) acrylonitrile 17) trans-1,2-dichloroethene 18) methyl-t-butyl ether 19) hexane 20) 1,1-dichloroethane 21) vinyl acetate 23) 2,2-dichloropropane 24) cis-1,2-dichloroethene 25) 2-butanone 26) ethyl acetate 2 7) bromochloromethane 28) chloroform 29) 1,1,1-trichloroethane 30) 1,1-dichloropropene 31) carbon tetrachloride 34) benzene 35) 1,2-dichloroethane 36) trichloroethene 37) 1, 2-dichloropropane 3 8) dibromomethane 40) bromodichloromethane 41) 2-chloroethyl vinyl ether 42) cis-1,3-dichloropropene
1) 11.688 .. 13.049
17.796 .. 21.300
11.532 Range 70
12.180 Range 7 0
15.536 Range 70
4) 19.572 Range 7 0
0.000 0.000 0.000 3.834 0.000 0.000 0.000 5.931 5.869 0.000 6.118 0.000 0.000 6.946 7.730
e 0.000 0.000 0.000 0.000 8.816 0.000 0.000 0.000 0.000 0.000 0.000 0.000
11.699 11.699 0.000
12.337 0.000 0.000 0.000 0.000
er 0.000 0.000
168 114 117 152
111 - 130 65
- 130 98
- 130 95
- 130
94
61 43
76
84 53
43
75 119
62
1635003 2304330 1960942 534049
1174664
50.00 ug/L 50.00 ug/L 50.00 ug/L 50.00 ug/L
53.09 ug/L Recovery = 106.18%
931902 52.82 ug/L Recovery = 105.64%
2614831 53.26 ug/L Recovery = 106.52%
857436 50.14 ug/L Recovery = 100.28%
0 0 0
1146 0 0 0
3032 163448
0 10106
0 0
3914 518
0 0 0 0
1027 0 0 0 0 0 0 0
128759 1621
0 432188
0 0 0 0 0 0
-0.01 0.00 0.00 -0.01
-0.02
-0.01
0.00
-0.01
Qvalue N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D.
25.54 ug/L N.D. N.D. N.D. N.D. d N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. d N.D. N.D. N.D. N.D. 5.69 ug/L # N.D. N.D. d
19.59 ug/L N.D. d N.D. N.D. N.D. N.D. N.D.
95
47
96
J090908.M Mon Apr 13 09:22:17 2009 VOCDATAOl Page: 1
Quantitation Report
Data File : G:\MSCHEM\1\DATA\091108A1\1V056.D Acq On : 14 Sep 2008 9:12 pm Sample : 1810571-01 Misc : f. Quant Time: Apr 10 07:54:03 2009
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H20
(QT Reviewed)
Vial Operator Inst Multiplr
16 TVK MS ttl 1.00
Compound R.T. Qlon Response Cone Units Dev(Min)
43 44 45 46 47 49 50 51 52 53 54 55 56 57 58 59 60] 61] 63] 64] 66] 67] 68] 69] 701 71 721 731 74 75] 76] 77] 781 79] 80] 811 82] 83) 84)
1 4-methyl-2-pentanone 1 toluene i trans-1,3-dichloropropene 1 ethyl methacrylate > 1,1,2-trichloroethane ' tetrachloroethene 1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachioroethane ethylbenzene m,p-xylenes o-xylene styrene bromoform i sopropylbenzene 1,2,3-trichloropropane trans-1,4-dichloro-2-b... 1,1,2,2-tetrachioroethane bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethylbenzene p-chlorotoluene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene p-isopropyltoluene 1,3-dichlorobenzene 1,4-dichlorobenzene n-butylbenzene 1,2-dichlorobenzene 1,2-Dibromo-3-chloropr... 1,2,4-trichlorobenzene hexachiorobutadiene naphthalene 1,2,3-trichlorobenzene
15.526 15.631 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
17.994 18.192 18.796 18.848 19.593 19.342 0.000 0.000 0.000 0.000
19.561 0.000 0.000 0.000 0.000
20.787 20.787 21.258 0.000 0.000 0.000 0.000 0.000 0.000 0.000
24.841 0.000
43 91
91 91 91
104 173 105
91
105 105 119
128
13509 19634
0 0 0 0 0 0 0 0 0 0
1234 3711 429
1008 814
4033 0 0 0 0
1300 0 0 0 0
697 697
1664 0 0 0 0 0 0 0
352 0
0.89 ug/L tt 0.33 ug/L N.D. N.D. N.D. N.D. N.D. N.D. d N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D.
1 95
{#) = cjualifier out of range (m) = manual integration (+) = signals summed
VW090908.M Mon Apr 13 09:22:17 2009 VOCDATAOl Page: 2
int J lior ivic
Data File : G:\MSCHEM\l\DATA\091108Al\lV056.D Acq On : 14 Sep 2008 9:12 pm Sample : 1810571-01 Misc : f. Quant T ime : Apr 10 0 7 : 5 4 : 0 3 2009
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant T i t l e : 5 mL WATER QLas t U p d a t e : Wed Sep 10 0 7 : 4 4 : 2 5 2008 R e s p o n s e v i a : I n i t i a l C a l i b r a t i o n DataAcq Meth:V0C_H20
Vial: Operator: Inst : Multiplr:
16 TVK MS ttl 1.00
Abundance
2000000
1800000
1600000
1400000
1200000
1000000
800000
600000
TIC. 1V056.D\data ms
400000
200000
A.
s
Q
.1
-T 10
% E e
V- ^ k. I I I I I I I I I I I i I I I I I I I I I I I I I ] I I I I I I [ 1 I I I I M I I f I l ' l ' I i ' [ I ' i i I I I I I I I 1 I I I ' I ' r i I I I I I I 1 I ' l ] • I I I I I I I I I I M I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I
Time-> 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14 00 15.00 16.00 17.00 18.00 19 00 20.00 21.00 22.00 23.00 24.00 25.00 26 00 27.00 28.00 29.00
VW090908.M Mon Apr 13 09:22:19 2009 VOCDATAOl Page:
Quantitation Report (QT Reviewed)
Data File Acq On Sample Misc Quant Time
G:\MSCHEM\1\DATA\091108A1\1V057.D 14 Sep 2008 9:50 pm 1810571-02 f. Apr 13 09:38:59 2009
Vial Operator Inst Multiplr
17 TVK MS ttl 1.00
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration DataAcq Meth:V0C_H20
Compound R.T. Qlon Response Cone Units Dev(Min)
Internal Standards 1) pentafluorobenzene (IS-1) 33) 1,4-Difluorobenzene (I. 48) chlorobenzene-d5 (IS-3) 65) 1,4-dichlorobenzene-d4.
System Monitoring Compounds 22) dibromofluoromethane (. Spiked Amount 50.000 32) 1,2-diehloroethane-d4 . Spiked Amount 50.000 39) toluene-d8 (SS-3) Spiked Amount 50.000 62) bromofluorobenzene (SS-4) Spiked Amount 50.000
Target Compounds 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 23 24 25 26 27 28 29 30 31 34 35 36 37 38 40 41 42
dichlorodiflouromethane chioromethane vinyl chloride bromome thane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone lodomethane carbon disulfide 112Triehloro221trifluo.. acetonitrile methylene chloride acrylonitrile trans-1,2-dichloroethene methyl-t-butyl ether hexane 1,1-diehloroethane vinyl acetate 2,2-dichloropropane cis-1,2-dichloroethene 2-butanone ethyl acetate bromochloromethane chloroform 1,1,1-trichloroethane 1,1-dichloropropene carbon tetrachloride benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromomethane bromodi chlorome thane 2-chloroethyl vinyl ether cis-1,3-dichloropropene
) 11.686 . 13.044
17.796 . 21.302
11.529 Range 70
12.177 Range 70
15.528 Range 7 0 ) 19.566 Range 70
0.000 0.000 0.000 3.820 0.000 0.000 0.000 0.000 5.873 0.000 6.123 0.000 6.625 6.938 0.000 0.000 0.000 0.000 0.000 8.808 0.000 0.000
10.760 0.000 0.000 0.000 0.000 0.000
11.686 0.000 0.000 0.000 0.000 0.000 0.000
r 0.000 0.000
168 114 117 152
111 - 130
65 - 130
98 - 130
95 - 130
94
43
76
41 84
43
43
119
1669796 2399693 2002642 524110
1176484
50.00 ug/L 50.00 ug/L 50.00 ug/L 50.00 ug/L
52.06 ug/L Recovery = 104.12%
936836 52.00 ug/L Recovery = 104.00%
2738359 53.56 ug/L Recovery = 107.12%
871006 49.87 ug/L Recovery = 99.74%
0 0 0
687 0 0 0 0
446 0
3703 0
327 40024
0 0 0 0 0
464 0 0
342 0 0 0 0 0
3525 0 0 0 0 0 0 0 0
-0.01 -0.01 0.00 0.00
-0.03
-0.02
-0.01
-0.02
Qvalue N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. 1.63 ug/L N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. d N.D. N.D. N.D. N.D. d N.D. N.D. N.D. N.D. N.D.
95
VW090908.M Mon Apr 13 09:22:22 2009 VOCDATAOl Page: 1
Quant 1 tai. ion Report (QT Reviewed)
Data File Acq On Sample Misc Quant Time
G:\MSCHEM\1\DATA\091108A1\1V057.D 14 Sep 2008 9:50 pm 1810571-02 f . Apr 13 09:38:59 2009
Vial: 17 Operator: TVK Inst : MS ttl Multiplr: 1.00
Quant Method : G:\MSCHEM\1\METHODS\VW090908.M Quant Title : 5 mL WATER QLast Update : Wed Sep 10 07:44:25 2008 Response via : Initial Calibration Datei; cq Meth:V0C_H20
Compound R.T. Qlon Response Cone Units Dev(Min)
43 44 45 46 47 49 50 51 52 53 54 55 56 57 58 59 60 61 63 64 66 67 68 69 70 71 72 73 74 75 76 77 78 79] 80 81 821 83] 84)
'i 4-methyl-2-pentanone •i toluene trans-1,3-dichloropropene
) ethyl methacrylate 1 1,1,2-1 ri chloroethane tetrachloroethene 1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachioroethane ethylbenzene m,p-xylenes o-xylene
) styrene bromoform isopropylbenzene 1,2,3 -trichloropropane trans-1,4-dichloro-2-b... 1,1,2,2-tetrachioroethane bromobenzene n-propylbenzene o-chlorotoluene 1,3,5-trimethylbenzene p-chlorotoluene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene p-isopropyltoluene 1,3-dichlorobenzene 1,4-dichlorobenzene n-butylbenzene 1,2-dichlorobenzene 1,2-Dibromo-3-chloropr... 1,2,4 -trichlorobenzene hexachiorobutadiene naphthalene 1,2,3-trichlorobenzene
0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000
17.796 91 17.796 91 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000
19.577 91 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
0 0 0 0 0 0 0 0 0 0 0 0
3428 3428
0 0 0 0 0 0 0 0
2072 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
N.D. d N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D.
1^1 qualifier out of range (m) = manual integration (H-) = signals summed
J090908.M Mon Apr 13 09:22:22 2009 VOCDATAOl Page: 2
Quantitation Report (QT Reviewed)
D a t a F i l e Acq On Sample Misc Quant Time
G:\MSCHEM\1\DATA\091108A1\1V057.D 14 Sep 2008 9 :50 pm 1810571-02 f. Apr 13 0 9 : 3 8 : 5 9 2009
Quant Method : G:\MSCHEM\l\METHODS\VW090908.M Quant T i t l e : 5 mL WATER QLast Upda te : Wed Sep 10 0 7 : 4 4 : 2 5 2008 R e s p o n s e v i a : I n i t i a l C a l i b r a t i o n DataAcq Meth:V0C_H20
V i a l : 17 O p e r a t o r : TVK I n s t : MS ttl M u l t i p l r : 1 .00
Abundance
2000000
1800000
1600000
1400000
1200000
1000000
800000
600000
400000
200000
*~T-| I I - T ^ ^ ^ r ^ T ^
ia a ES 1
•?
I I I I I I I I JM
a
^ \ - r
TIC: 1V057 D\data ms
n • ' • • I ' ' ' ' I ' ' ' ' I ' ' 1 1 1 ' ' ' ' I ' ' ' • I . , . . I . . • . I . . • . I • • . • I . . . . I . . . . I . .
Time-> 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13 00 14.00 15.00
VW090908 .M Mon A p r 13 0 9 : 2 2 : 2 5 2 0 0 9 VOCDATAOl
i. I ' I ' M ' '
eo
i
Ji e 3
i- I I 1 I I rTTTf=TT=
16.00 17.00 18.00 19.00 20.00 21.00 22 00 23.00 24.00 25.00 26.00 27.00 28 00 29.00
P a g e : 3
• Keystone Laboratories, Inc. - Newton I SDG:
CLASS: GCMS »«BBVS»
• METHOD: EPA 8260B SEP i a m
I I I I I I I I I I I I I I I I Page I of I
ANALYSES DATA PACKAGE COVER PAGE EPA 8260B
Laboratory: Keystone Laboratories, Inc. - Newton
Client: MWH Americas, Inc.-IA
SDG:
Project: IPL-Clinton FMGP Site
Client Sample Id:
BLOI-SW-1001
BLOl-SW-907
Lab Sample Id:
1810571-01
1810571-02
1 certify that this data package is in compliance with the terms and conditions ofthe contract, both technically and for completeness, for other than the conditions detailed above. Release ofthe data contained in this hardcopy data package and in computer-readable data submitted on diskette has been autorized by the Laboratory Manager or the Manager's designee, as verified by the following signatures.
Signature: v v.v. W vawv-f i^a .c i "^ ' ' -—' Name: - N v A r: \ V N . O ^ - \ ^ p S o . - - ^
Date: • • \ \ \ ^ \JSL Title: 9r(^\K' V l i v ( lAaa tP r^ t
Page 1 of 1
METHOD DETECTION AND REPORTING LIMITS EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Americas. Inc.-IA
Matrix: Water
SDG:
Project: IPL-Clinlon FMGP Site
Instrument: MS #1
Analyte
Chioromethane
Vinyl Chloride
Bromomethane
Chloroethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
cis-1,2-Dichloroethylene
2-Butanonc (MEK)
Chloroform
1,1,1-Trichloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
B romod ich Ioromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone (MIBK)
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
2-Hexanone (MBK)
Dibromochloromethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromoform
1,1.2,2-Tetrachloroethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
MDL
0.6
0.8
0.5
0.6
0.4
1.7
1.0
3.9
0.2
0.8
0.3
0.3
0.4
0.2
0.4
0.4
0.2
0.2
0.3
0.2
0.2
0.2
0.3
0.3
0.2
0.3
0.4
0.4
O.I
0.2
0.2
0.5
0.2
0.3
0.4
0.3
0.3
MRL
1.0
1.0
1.0
1.0
1.0
10.0
1.0
5.0
I.O
2.0
I.O
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
I.O
1.0
5.0
1.0
I.O
1.0
I.O
5.0
I.O
i.o I.O
2.0
1.0
1.0
1.0
1.0
1.0
Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/'l
u&'l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Ug/I
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/'l
ug/l
ug/'l
Page I of2
METHOD DETECTION AND REPORTING LIMITS EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Americas. Inc.-IA
Matrix: Water
SDG:
Project: IPL-Clinton FMGP Site
Instrument: MS #1
Analyte
Naphthalene
MDL
0.4
MRL
1.0
Units
ug/l
Page 2 of2
I ORGANIC ANALYSIS DATA SHEET EPA 8260B
BLOl-SW-1001
Laboratory:
Client:
Matrix:
Sampled:
Solids:
Batch:
Kevstone Laboratories, Inc. - Newton
MWH Americas. Inc.-IA
Water Laboratory ID:
09/10/08 11:50 Prenared:
Preparation:
1181515 Scauence: 1811507
SDG:
Project:
1810571-01
09/11/08 00:00
EPA5030B
Calibration
IPL-Clinton FMGP Site
File ID: IV056D
Analyzed: 09/14/08 21 12
Initial/Final: 5 ml / 5 ml
UNASSIGNED Instniment: MS#1
1 CAS NO.
1 74-37-3 75-01-4
1 74-83-9 i 75-00-3
75-35-4 67-64-1
• 75-15-0
75-09-2 156-60-5
1 1634-04-4
75-34-3 156-59-2 78-93-3 67-66-3 71-55-6
' 56-23-5 71-43-2 107-06-2 79-01-6 78-87-5 75-27-4
10061-01-5 108-10-1 108-88-3
10061-02-6 1 79-00-5
127-18-4 591-78-6 124-48-1 108-90-7 100-41-4
1330-20-7 75-25-2
79-34-5 541-73-1 106-46-7
95-50-1
91-20-3
COMPOUND
Chioromethane Vinyl Chloride Bromomethane Chloroethane 1,1-Dichloroethylene Acetone Carbon Disulfide
Methylene Chloride trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE) 1,1-Dichloroethane cis-1,2-Dichloroethylene 2-Butanone (MEK) Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane
Trichloroethylene 1,2-Dichloropropane Bromodichloromethane
cis-1,3-Dichloropropene 4-Methyl-2-pentanone (MIBK) Toluene
trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethylene 2-Hexanone (MBK) Dibromochloromethane Chlorobenzene Ethylbenzene Xylenes, total Bromoform
1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene
1,2-Dichlorobenzene Naphthalene
DILUTION CONC. (ug/l)
1.0 l.O 1.0 1.0 1.0
25.5 10
5.0 I.O
2.0
10 1.0 5.0 10 1.0 1.0 1.0
19.6 l.O
10 1.0
1 0 5.0 1.0
1.0 1.0 I.O 5.0 1.0
1.0 1.0
2.0 10
J.O 1.0 1.0
1 0 1.0
Q U u u u u
u u u u u u u u u u u
u u u u u u u u u u u u u u u u u u u u
SYSTEM MONITORING COMPOUND | ADDED (ug/l) CONC (ug/I) % REC QC LIMITS Q
Pagc 1 of 4
ORGANIC ANALYSIS DATA SHEET EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Nevyton
Client: MWH Americas. Inc.-IA
Matrix: Water Laboratory ID:
Sampled: 09/10/08 11:50 Prepared:
Solids: Preparation:
Batch: 1181515 Sequence: 1811507
SDG-
Project:
1810571-01
09/11/08 00:00
EPA 5030B
Calibration:
BLOl-SW-1001
IPL-Clinton FMGP Site
File ID: 1V056.D
Analyzed: 09/14/08 21:12
Initial/Final: 5 ml /5 ml
UNASSIGNED Instrument: MS#1
SYSTEM MONITORING COMPOUND
Dibromofluoromethane l,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
ADDED (ug/'l)
50.0000 50.0000 50.0000 50.0000
CONC (ug/l)
53.1 52.8 53.3 50 1
% REC
106 106 107 IOO
QC LIMITS
74-132 74-133 85-115 77 - 122
Q
* Values outside of QC limits
Page 2 of4
I H Laboratory:
Client:
H Matrix:
Sampled:
• solids: Batch:
ORGANIC ANALYSIS DATA SHEET EPA 8260B
BLOl-SW-907
Kevstone Laboratories. Inc. - Newton
MWH Americas. Inc.-IA
Water Laboratory ID:
09/10/08 11:50 Prepared:
Preparation:
1181515 Sequence: 1811507
SDG:
Project:
1810571-02
09/11/08 00:00
EPA 5030B
Calibration:
IPL-Clinton FMGP Site
File ID: 1V057.D
Analyzed: 09/14/08 21:50
Initial/Final: 5 ml /5 ml
UNASSIGNED Instmment: MS#I
i
CAS NO.
74-87-3 75-01-4
74-83-9 75-00-3 75-35-4 67-64-1
75-15-0 75-09-2
156-60-5 1634-04-4
75-34-3 156-59-2
78-93-3 67-66-3 71-55-6 56-23-5 71-43-2 107-06-2 79-01-6 78-87-5 75-27-4
10061-01-5 108-10-1
108-88-3
10061-02-6 79-00-5 127-18-4 591-78-6 124-48-1
108-90-7 100-41-4
1330-20-7 75-25-2 79-34-5
541-73-1
106-46-7 95-50-1
91-20-3
COMPOUND
Chioromethane Vinyl Chloride Bromomethane Chloroethane 1,1-Dichloroethylene
Acetone Carbon Disulfide Methylene Chloride trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1 -Dichloroethane cis-1,2-Dichloroethylene
2-Butanone (MEK) Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane
Trichloroethylene 1,2-Dichloropropane Bromodichloromethane
cis-1,3-Dichloropropene 4-Melhyl-2-pentanone (MIBK) Toluene
trans-1,3-Dichloropropene 1,1,2-Trichloroethane
Tetrachloroethylene 2-Hexanone (MBK) Dibromoch Ioromethane Chlorobenzene Ethylbenzene Xylenes, total
Bromoform 1,1,2,2-Tetrachloroethane l,3-Dichloroben2ene
1,4-Dichlorobenzene 1.2-Dichlorobenzene Naphthalene
DILUTION CONC. (ug/l)
1.0 1.0 1.0 1.0 1.0 10.0 1.0 5.0
1.0 2.0 1.0
1.0 5.0 1.0 1.0 1.0 1.0 1.0
1.0 1.0 1.0
1.0 5.0 1.0
1.0 1.0
1.0 5.0 1.0 1.0 1.0 2.0 1.0 1.0 1.0
1.0 10
1.0
Q U
u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u
SYSTEM MONITORING COMPOUND ADDED (ug/l) CONC (ug/l) % REC QC LIMITS 0
I Page 3 of4
ORGANIC ANALYSIS DATA SHEET EPA 8260B
BL01-SW.907
Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Americas. Inc.-IA
Matrix: Water Laboratory ID:
Sampled: 09/10/08 11:50 Prepared.
Solids: Preparation:
Batch: 1181515 Sequence: 1811507
SDG:
Project:
1810571-02
09/11/08 00:00
EPA 5030B
Calibration:
IPL-Clinton FMGP Site
File ID: 1V057.D
Analyzed: 09/14/08 21:50
Initial/Final: 5 ml / 5 ml
UNASSIGNED Instniment: M S l i
SYSTEM MONITORING COMPOUND
Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
ADDED (ug/l)
50.0000 50.0000 50.0000 50.0000
CONC (ug/l)
52.1 52.0 53.6 49.9
% REC
104 104 107 99.7
QC LIMITS
74-132 74- 133 85-115 77-122
Q
* Values outside of QC limits
Page 4 of4
I I i
PREPARATION BATCH SUMMARY EPA 8260B
Laboratory:
Client:
Batch:
Kevstone Laboratories. Inc. - Newton
MWH Americas. Inc.-IA
1181515 Batch Matrix: Water
SDG:
Project:
Preparation:
IPL-Clinton FMGP Site
EPA 5030B
1 1 1
SAMPLE NAME
BLOI-SW-1001
BLOI-SW-907
Blank
LCS
Matrix Spike
Matrix Spike Dup
LAB SAMPLE ID
1810571-01
1810571-02
1I81515-BLK1
1181515-BSI
1181515-MSl
1181515-MSDl
LAB FILE ID
1V056.D
IV057.D
1V050.D
1V045.D
1V046.D
1V047,D
DATE PREPARED
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
09/11/08 00:00
OBSERVATIONS
I I I I I I I I I I I I I Page I of 1
METHOD BLANK DATA SHEET EPA 8260B
Laboratory: Kevstone Laboratories. Inc. - Newton SDG:
Client: MWH Americas. Inc.-IA Project;
Matrix: Water Laboratory ID: 1181515-BLKI
Prepared: 09/11/08 00:00 Preparation: EPA 5030B
Analyzed: 09/14/08 17:24 Instrument: MS#I
Batch: 1I8I515 Sequence: 1811507
IPL-Clinton FMGP Site
File ID: 1V050.D
Initial/Final: 5 ml / 5 ml
Calibration: UNASSIGNED
CAS NO.
74-87-3
75-01-4
74-83-9
75-00-3
75-35-4
67-64-1
75-15-0
75-09-2
156-60-5
1634-04-4
75-34-3
156-59-2
78-93-3
67-66-3
71-55-6
56-23-5
71-43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
108-10-1
108-88-3
10061-02-6
79-00-5
127-18-4
591-78-6
124-48-1
108-90-7
COMPOUND
Chioromethane
Vinyl Chloride
Bromomethane
Chloroethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1 -Dichloroethane
cis-1,2-Dichloroethylene
2-Butanone (MEK)
Chloroform
1,1,1-Trichloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone (MIBK)
Toluene
trans- J ,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
2-Hexanone (MBK)
Dibromochloromethane
Chlorobenzene
CONC. (ug/l)
1.0
1.0
1.0
1.0
1.0
10.0
1.0
5.0
1.0
2.0
1.0
1.0
5.0
1.0
I.O
l.O
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
Q
u u
u u u u u
u u u u u u u u u u u
u u
u u
u u u u
u
u
u
u
Page I of 5
I I
METHOD BLANK DATA SHEET EPA 8260B
..aboratory:
Client:
Iplatrix:
Prepared:
B^nalyzed:
Batch:
Kevstone Laboratories. Inc. - Newton SDG:
MWH Americas. Inc.-lA Project;
Water Laboratory ID: 1181515-BLKI
09/11/08 00:00 Preparation: EPA 5030B
09/14/08 17:24 Instmment: MS#1
1181515 Sequence: 1811507
IPL-Clinton FMGP Site
File ID: IV050.D
Initial/Final: 5 ml/5 ml
Calibration: UNASSIGNED
1
CAS NO.
100-41-4
1330-20-7
75-25-2
79-34-5
541-73-1
106-46-7
95-50-1
91-20-3
COMPOUND
Ethylbenzene
Xylenes, total
Bromoform
1,1,2,2-Tetrachloroethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
Naphthalene
CONC. (ug/l)
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
Q
u u u u u u u u
SYSTEM MONITORING COMPOUND
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-dS
4-Bromofluorobenzene
ADDED (ug/l)
50.0000
50.0000
50.0000
50.0000
CONC (ug/l)
53.4
51.2
52.4
49.5
%REC
107
102
105
98.9
QC LIMITS
74- 132
74-133
85-115
77 - 122
Q
I I I I I I I I Page 2 of 5
MATRIX SPIKE / MATRIX SPIKE DUPLICATE RECOVERY EPA 8260B
Matrix Snike
Laboratory:
Client:
Matrix:
Batch-
Preparation:
Source Sample
Kevstone Laboratories, Inc.
MWH Americas. Inc.-IA
Water
1181515
EPA 5030B
Name: Matrix Spike
- Newton SDG:
Project:
Laborat
Initial/F
IPL-Clinton FMGP Site
Laboratory ID: 1181515-MSl
5 ml /5 ml
COMPOUND
Chioromethane
Vinyl Chloride
Bromomethane
Chloroethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichlorocthy lene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
cis-1,2-Dichloroethylene
2-Butanone (MEK)
Chloroform
1,1,1-Trichloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethylene
i ,2-Dichloropropane
Bromod ich Ioromethane
cis-1,3-Dichioropropene
4-Methyl-2-pentanone (MIBK)
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrach loroethy lene
2-Hexanone (MBK)
Dibromochloromethane
Chlorobenzene
Ethylbenzene
Xylenes, total
SPIKE ADDED
(ug/l)
941000
938.500
949.000
964 000
500.000
1648.00
1160.00
500.000
500.000
1144.00
500.000
500.000
1552.00
500.000
500.000
500.000
500.000
500.000
500 000
500.000
500.000
500.000
1096.00
500.000
500.000
500.000
500.000
1000.00
500.000
500.000
500.000
1500.00
SAMPLE CONCENTRATION
(ug/l)
ND
ND
ND
ND
ND
1.95
ND
ND
ND
ND
ND
13.86
ND
ND
ND
ND
ND
ND
187.2
ND
ND
ND
ND
ND
ND
ND
66.96
ND
ND
ND
ND
ND
MS CONCENTRATION
(ug/l)
1238
1241
1120
1181
587.3
1278
1229
523.2
545.5
1117
538.7
507.0
1266
520.8
507.1
536.3
519.9
504.7
679 9
514.8
523.9
395.8
1039
522.6
392.7
471.5
522.0
945.2
493.9
487.5
532.6
1555
MS %
REC. #
132
132
118
123
117
77.4
106
105
109
97.6
108
98.6
81.6
104
101
107
104
101
98.5
103
105
79.2
94.8
105
78.5
94 3
9J.0
94 5
98.8
97.5
107
104
QC LIMITS
REC.
60 - 140
79 - 140
60 - 140
67 - 140
81 -140
60-134
66-133
65-127
76-132
60- 140
72-137
76-129
67-133
78-124
84-126
83-129
62 - 140
63-138
82-125
82- 121
84-116
70- 128
72-135
76-138
72 - 122
81 -117
84-122
70- 136
76-121
84-116
65 - 140
61-137
Page 3 of 5
I I
MATRIX SPIKE / MATRIX SPIKE DUPLICATE RECOVERY EPA 8260B
Matrix Spike
1
Laboratory:
Client:
Matrix;
Batch:
reparation:
Kevstone Laboratories. Inc. - Newton
MWH Americas. Inc.-IA
Water
1181515
EPA 503OB
Source Sample Name: Matrix Spike
SDG
Project:
Laboratory ID:
Initial/Final:
IPL-Clinton FMGP Site
1181515-MSl
5 ml / 5 ml
1 1 1 1
1
COMPOUND
Bromoform
1,1,2,2-Tetrachloroethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
Naphthalene
SPIKE ADDED
(ug/l)
500.000
500.000
500.000
500.000
500.000
500.000
SAMPLE CONCENTRATION
(ug/l)
ND
ND
ND
ND
ND
ND
MS CONCENTRATION
(ug/l)
463.6
483.4
465.9
463.5
466.0
521.8
MS %
REC.//
92.7
96.7
93.2
92.7
93.2
104
QC LIMITS
REC.
62-121
76-122
82 - 122
82-119
78 - 120
60 - 140
COMPOUND
Chioromethane
Vinyl Chloride
Bromomethane
Chloroethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichloroethane
cis-1,2-Dichloroethylene
2-Butanone (MEK)
Chloroform
1,1,1-Trichloroethane
Carbon Ten-achloride
Benzene
1,2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone (MIBK)
SPIKE ADDED
(ug/l)
941.000
938.500
949.000
964.000
500.000
1648.00
1160.00
500.000
500.000
1144.00
500.000
500.000
1552.00
500.000
500.000
500.000
500.000
500.000
500.000
500.000
500.000
500.000
1096.00
MSD CONCENTRATION
(ug/l)
1283
1282
1141
1211
606.5
1314
1265
523.3
553.8
1128
552.5
520.2
1321
529.0
537.6
542.6
518.6
511.1
688.0
519.5
531.3
402.7
1063
MSD %
REC.#
136
137
120
126
121
79.6
109
105
111
98.6
no 101
85.1
106
108
109
104
102
IOO
104
106
80.5
97.0
% RPD#
3.53
3.28
1.78
2.48
3.22
2.77
2.89
0.0191
1.51
1.01
2 53
2.57
4.22
1.56
5 84
1.17
0.250
1.26
1.18
0.909
140
1.73
2.32
QC
RPD
18
21
26
23
15
19
20
22
16
13
14
12
16
14
15
16
20
17
17
20
23
23
24
LIMITS
REC.
60-140
79 - 140
60 - 140
67 - 140
81 - 140
60-134
66-133
65- 127
76-132
60 - 140
72-137
76-129
67- 133
78-124
84 - 126
83 - 129
62 - 140
63-138
82-125
82-121
84-116
70- 128
72- 135
I Page 4 of 5
MATRIX SPIKE / MATRIX SPIKE DUPLICATE RECOVERY EPA 8260B
Matrix Spike Dup
Laboratory:
Client:
Matrix:
Batch:
Preparation:
Kevstone Laboratories. Inc. - Newton
MWH Americas. Inc.-IA
Water
SDG:
Project: IPL-Clinton FMGP Site
1I8I515
EPA 5030B
Source Sample Name: Matrix Spike Dup
Laboratory ID: 1181515-MSDl
Initial/Final: 5 ml / 5 ml
COMPOUND
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
2-Hexanone (MBK)
Dibromochloromethane
Chlorobenzene
Ethylbenzene
Xylenes, total
Bromoform
1,1,2,2-Tetrachloroethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
Naphthalene
SPIKE ADDED
(ug/l)
500.000
500.000
500.000
500.000
1000.00
500.000
500.000
500.000
1500.00
500.000
500.000
500.000
500.000
500.000
500 000
MSD CONCENTRATION
(ug/l)
530.1
397.2
482.7
535.9
948.5
488.9
491.6
521.7
1559
452.8
515.8
495.7
490.4
498.3
514.2
MSD %
REC.#
106
79.4
96.5
93.8
94.8
97.8
98.3
104
104
90.6
103
99.1
98.1
99.7
103
% RPD#
i.42
1.14
2.35
2.63
0.349
1.02
0.838
2 07
0.238
2.36
6.49
6.20
5.64
6.70
1.47
QC LIMITS
RPD REC.
18
21
25
14
14
18
14
13
13
22
17
17
17
17
30
76-138
72-122
81 -117
84-122
70-136
76-121
84-116
65 - 140
61-137
62- 121
76-122
82-122
82-119
78-120
60-140
U Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
Page 5 of 5
I LCS / LCS DUPLICATE RECOVERY EPA 8260B
I c
iLaboratory:
Client:
'latrix:
Batch:
P r e p a r a t i o n
Kevstone Laboratories. Inc. - Newton
MWH Americas. Inc.-IA
Water
1I8I5I5
EPA 5030B
SDG:
Project:
Laboratory ID:
Initial/Final:
IPL-Clinton FMGP Site
1181515-BSl
5 m l / 5 ml
I
COMPOUND
Chioromethane
Vinyl Chloride
Bromomethane
Chloroethane
1,1-Dichloroethylene
Acetone
Carbon Disulfide
Methylene Chloride
trans-1,2-Dichloroethylene
Methyl-t-butyl Ether (MTBE)
1,1-Dichioroethane
cis-1,2-Dichloroethylene
2-Butanone (MEK)
Chloroform
1,1,1 -Trichloroethane
Carbon Tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethylene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
4-Methyl-2-pentanone (MIBK)
Toluene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Tetrachloroethylene
2-Hexanone (MBK)
Dibromochloromethane
Chlorobenzene
SPIKE ADDED
(ug/l)
94.1000
93.8500
94.9000
96.4000
50.0000
164.800
116.000
50.0000
50.0000
114.400
50 OOOO
50.0000
155.200
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
109.600
50.0000
50.0000
50.0000
50.0000
100.000
50.0000
50.0000
LCS CONCENTRATION
(ug/l)
126.3
126.6
116.6
121.3
59.97
131.9
118.0
53.21
54 34
115.6
55 95
51.78
136.9
53.46
52.40
54.71
52.40
52.28
50.89
53.42
53.55
39.61
107.7
53.08
39.80
49.02
45.81
94 30
49.66
49.64
LCS %
REC. if
134
135
123
126
120
80.1
102
106
109
101
112
104
88.2
107
105
109
105
105
102
107
107
79.2
98.3
106
79.6
98.0
91.6
94.3
99.3
99.3
QC LIMITS
REC.
6 0 - 1 4 0
77 -140
63 - 140
74 - 140
84 -137
6 1 - 1 3 2
1 68-134
7 4 - 1 2 5
7 9 - 1 2 8
6 0 - 1 4 0
8 1 - 1 3 2
7 9 - 1 2 7
6 5 - 1 3 6
8 3 - 1 1 6
8 6 - 1 2 2
8 8 - 1 2 4
6 8 - 1 3 8
6 6 - 1 3 5
8 5 - 1 2 2
8 3 - 1 2 2
8 2 - 1 1 8
7 5 - 1 2 4
7 4 - 1 3 6
70 - 140
7 6 - 1 2 2
8 2 - 1 1 8
8 4 - 1 2 7 [
6 8 - 1 4 0
8 6 - 1 1 7
8 7 - 1 1 6
I Page I of 2
LCS / LCS DUPLICATE RECOVERY EPA 8260B
Laboratory-
Client:
Matrix:
Batch:
Preparation:
Kevstone Laboratories. Inc.
MWH Americas. Inc.-IA
Water
1181515
EPA 5030B
- Newton SDG:
Project: IPL-Clinton FMGP Site
Laboratory ID: 1181515-BSI
Initial/Final: 5 ml / 5 ml
COMPOUND
Ethylbenzene
Xylenes, total
Bromoform
1,1,2,2-Tetrachloroethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
Naphthalene
SPIKE ADDED
(ug/I)
50.0000
150.000
50.0000
50.0000
50.0000
50.0000
50.0000
50.0000
LCS CONCENTRATION
(ug/l)
52.02
154.5
46.25
52.85
49.12
48.99
50.16
54 26
LCS %
REC. #
104
103
92.5
106
98.2
98.0
100
109
QC LIMITS
REC.
70 - 140
61 - 140
75-120
74-126
83-123
85-118
80- 121
60 - 140
# Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
Page 2 of2
I I I
ANALYSIS BATCH (SEQUENCE) SUMMARY EPA 8260B
'Laboratory:
Client:
|Sequence:
Matrix:
Kevstone Laboratories. Inc. - Newton
MWH Americas. Inc.-IA
1811507
Water
SDG:
Project;
Instmment:
Calibration.
IPL-Clinton FMGP Site
MS#I
UNASSIGNED
1 1 1 1
1 Sample Name
Calibration Check
LCS
Matrix Spike
Man-ix Spike Dup
Blank
BLOl-SW-1001
BLOl-SW-907
Lab Sample ID
1811507-CCVl
1181515-BSI
1181515-MSl
1181515-MSDl
1181515-BLKI
1810571-01
1810571-02
Lab File ID
IV043.D
1V045.D
1V046.D
1V047.D
1V050.D
1V056.D
IV057.D
Analysis Date/Time
09/14/08 12:56
09/14,/08 14:13
09/14/08 14:51
09/14/08 15:30
09/14/08 17:24
09/14/08 21 12
09/14/03 21:50
I I I I I I I I I I I I Page 1 of 1
Laboratory:
Client:
Instrument ID-
Lab File ID:
Sequence:
Lab Sample ID:
CONTINUING CALIBRATION CHECK
SDG:
Project:
Calibration:
Calibration Date:
Injection Date:
Injection Time:
COMPOUND TYPE STD 1 CCW
RESPONSE FACTOR
ICAL 1 CCV 1 MIN (#)
% DIFF/DRIFT
CCV 1 LIMIT (#)
tf Column to be used to flag Response Factor and %Diff>'Drift values with an asterisk
* Values outside of QC limits
Page I of I
I I
SURROGATE STANDARD RECOVERY AND RT SUMMARY EPA 8260B
Laboratory:
Client:
Sequence:
Matrix:
Kevstone Laboratories. Inc.
MWH Americas. Inc.-IA
1811507
Water
- Newton SDG:
Project:
Instmment:
Calibration:
IPL-Clinton FMGP Site
MS#1
UNASSIGNED
• Sunogate Compound
Spike Level ug/l
% Recovery
Recovery Limits RT
Calibration Mean RT RTDifl'
RTDiff Limit Q
Calibration Check (1811507-CCVl ) Lab File ID: 1 V043.D Analyzed: 09/14/08 12:56
1 Dibromofluoromethane
I l,2-Dichloroethane-d4
1 Toluene-d8
4-Bromofluorobenzene
50.0000
50.0000
50.0000
50.0000
101
107
104
100
80 - 120
80-120
80 - 120
80-120
11.54
12.2
15.55
19.58
11.5400
12.2000
15.5500
19.5800
- /-1.0
-1-/-I.0
+/-1.0
- /-1.0
1 * 1 *
*
•
LCS (1181515-BSI ) Lab File ID: 1 V045.D Analyzed: 09/14/08 14:13
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromonuorobenzene
50.0000
50.0000
50.0000
50.0000
103
107
101
99.3
74-132
74-133
85-115
77-122
11.54
12.19
15.54
19.58
11.5400
12.1900
15.5400
19.5800
- /-1.0
+/-[.0
-f-/-1.0
+/-\.o
1 * 1 * 1 * 1 *
1 Matri-i Spike (1181515-MSl ) Lab File ID: 1V046.D Analyzed: 09/14/08 14:51
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
50.0000
50.0000
50.0000
50.0000
101
106
IOl
103
74-132
74-133
85-115
77-122
11.55
12.19
15.54
19,57
11.5500
12.1900
15.5400
19.5700
+/-\.o
+/-1.0
•f/-l.O
+/-\.o
*
* * j
*
Matrix Spike Dup (1I8151S-MSD1) Lab File ID: 1 V047.D Analyzed: 09/14/08 15:30
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
50.0000
50.0000
50.0000
50.0000
103
109
102
101
74-132
74-133
85-115
77- 122
11.54
12.19
15.54
19.58
11,5400
12.1900
15.5400
19.5800
+/-\.o
+/-\.o
+/-\0
+/-\.o
*
*
*
•
Blank (1181515-BLKI ) Lab File ID: 1 V050.D Analyzed: 09/14/08 17:24
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
50.0000
50.0000
50.0000
50.0000
107
102
105
98.9
74- 132
74-133
85-115
77-122
11.54
12.19
15.54
19.57
11.5400
12.1900
15.5400
19.5700
+/-].0
•H/-1.0
- /-l.O
+/-\.o
*
* 1 •
«
BLOl-SW-lOOl (1810571-01 ) Lab File ID- 1V056.D Analyzed: 09/14/08 21:12 |
Dibromofluoromethane
1,2-Dichlorocthane-d4
Toluene-d8
4-B romofluorobenzene
50.0000
50.0000
50.0000
50.0000
106
106
107
100
74-132
74-133
85-115
77- 122
11.53
12.18
15.54
19.57
11.5300
12.1800
15.5400
19.5700
+/-\.Q
+/-].0
+f-].0
-(•/-IO
* 1 • [
• 1 * 1
BLOl-SW-907 (1810571-02) Lab File ID: 1V057.D Analyzed: 09/14/08 21:50 |
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-B romofluorobenzene
50.0000
50.0000
50.0000
50.0000
104
104
107
99.7
74-132
74-133
85-115
77-122
11.53
12.18
15.53
19.57
11.5300
12.1800
15.5300
19.5700
-H/-1.0
•/-].0
+/-] 0
-I-/-1.0
*
•
*
*
Page I of I
Laboratory:
Client:
Sequence:
Matrix:
INTERNAL STANDARD AREA AND RT SUMMARY
SDG:
Project:
Instrument:
Calibration:
Intemal Standard Response RT Reference Response
Reference RT Area %
Area % Limits RTDifi-
RTDiff Limit Q
Page 1 of I
I I
HOLDING TIME SUMMARY EPA 8260B
I (Laboratory: Kevstone Laboratories. Inc. - Newton
Client: MWH Americas. Inc.-IA
SDG:
Project: IPL-Clinton FMGP Site
I Sample Name
Date Collected
Date Received
Date Prepared
Days to
Prep
Max Days to
Prep Date
Analyzed
Days to
Analysis
Max Days to
Analysis
BLOl-SW-1001 09/10/08 11:30
09/11/08 10:05
09/11/08 00:00
051 14.00 09/14/08 21:12
4 39 14.00
I I I I I I I I I I I I I I I
BLOl-SW-907 09/10/08 11:30
09/11/08 10:03
09/11/08 00:00
O.SI 14.00 09/14/08 21:50
4.42 14.00
Page 1 of I
C H A I N O F C U S T O D Y R E C O R D
1 [feystSnr ^ L A B O R A T O R I E S , I N C .
6(X)E. 17*SLS. Newton, IA 50208 Phone:641-792-8451 Fax: 641-792-7989
[ j ] 3012 Ansborough Ave. Waterloo, IA 50701 Phone: 319-235-4440 Fax: 319-235-2480 www.keystonelabs.com
1155 Adams, Suite 120 KansasCity.KS 66103 Phone:913-321-7856 Fax: 913-321-7937 PAGE. / .OF_
7^rpT7dT~clF7Z PRINT OR TYPE INFORMATION BELOW
SAMPLER
SITE NAME
ADDRESS:_
CITY/ST/ZIP:
PHONE: =
rPE INFORMATION BELOW /
't, >^NAME:
(\hnh)i^,l^ SJ-rJJ^
REPORT Tl Vaioj if ^ j f t j n r j i ^
COMPANY NAMI 't pIlA^ff-
PHONE
PAX- ^ / 5 :z^J-9.^9:2. ' ^
^
BILL TO; NAME: / ^ ' ^ ^ / < A / : / n ^ ^ a s U L ^ COMPANY NAMF J ^ i 4 J ¥ -
CITY/ST/ZIP:
PHONE: _ n :
P< ' ^ ^ y 0^0 / / ) Severn/7tL'. i . CD .gcV-^Z/
Keystone Quote No.: A ^ ^ (II AwHlMllHI
CLIENT SAMPLE NUMBER
^l.O\~S^-\0Oi
UJ I-<
OV/o/dji
UJ
//5g
SAMPLE LOCATION
Ri>k \ .n^ i S<-W|P
t/i cc tu z <
o
o z
X
=fW
II
?^'^*3: IM '
CO
ANALYSES Jf'T'q
5* t ^
s*-1
1
REQUIRED L A B USE O N L Y
BLohSN - 'fo/ ZLkjEH. 02M. A W % oa
tjuM^-- ^ ^ S J ^ d ^ ' - ^
^ r ^
Relinquished by: (Signature) Date
Time
Received by: (Signature) Date
Time
TuiTi>Around: l A i Standard Rush
Contact Lab Prior to Submission
Relinquished by: (Signature) Date Received for Lab by: (Signature) Dat(
Time 4^ 3ate /
Time .
Remarks:
iCooUr
Onginal - Ratum with Report • Yellow - Lab Copy • Pink - Sampler Copy FORM. CCR 7-97
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
2/12/2009 Mr. Randy Kroneman
MWH Americas, Inc.
11153 Aurora Avenue
Des Moines IA 50322
Project Name: Clinton, IA FMGP Project*: 1914390.0102 Workorder*: 0901590A
Dear Mr. Randy Kroneman
The following report includes the data for the above referenced project for sample(s) received on 1/30/2009 at Air Toxics Ltd.
The data and associated QC analyzed by Modified TO-15 are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative.
Thank you for choosing Air Toxics Ltd. for you air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Brandon Dunmore at 916-985-1000 if you have any questions regarding the data in this report.
Regards,
'y'*/ntf^>j C- v>--*yw^^««-
Brandon Dunmore Project Manager
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 .FAX (916) 985-1020
Hours 8:00 A.M to 6:00 P.M. Pacific
Toxics LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0901590A
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED
FRACTION # OIA OIB 02A 02AA 02B 02BB 03A 03AA 04A 04/>iA 05A 05B 05C 06A 06B 06C OTA
Mr. Randy Kroneman MWH Americas, Inc. 11153 Aurora Avenue Des Moines, IA 50322
515-253-0830
515-253-9592
01/30/2009
02/09/2009
NAME BL03-SS-E001 BL03-SS-E001 BL03-SS-W001 BL03-SS-W001 Lab Duplicate BL03-SS-W001 BL03-SS-W001 Lab Duplicate BLOl-SG-EOOl BLOl-SG-EOOl Lab Duplicate BLOl-SG-SOOl BLOl-SG-SOOl Lab Duplicate Lab Blank Lab Blank Lab Blank CCV CCV CCV LCS
BILL TO: Accounts- CO Payable MWH Americas, Inc. POBox 6610 Broomfield, CO 80021
P.O.* 1914390.0102
PROJECT* 1914390.0102 Clinton, L\ FMGP
CONTACT: Brandon Dunmore
TEST Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modi fied TO-15 Modi fied TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15
RECEIPT VAC/PRES.
6.5 "Hg 6.5 "Hg 5 0 "Hg 5.0 "Hg 5.0 "Hg 5.0 "Hg 2.0 "Hg 2 0"Hg 23.5 "Hg 23.5 "Hg
NA NA NA NA NA NA NA
FINAL PRESSURE
5 psi 5 psi 5 psi 5 psi 5 psi 5 psi 5 psi 5 psi 5 psi 5 psi NA NA NA NA NA NA NA
Continued on next page
180 BLUE RAVINE ROAD. SUITE B FOLSOM. CA - 95630 (916) 983-1000 (800) 985-5955 . FAX (916) 983-1020
Paee I of 29
I I I I I I I I I I I I I I I I I I I
r/mAir ' ^Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0901590 A
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
Mr. Randy Kroneman MWH Americas, Inc. 11153 Aurora Avenue Des Moines, IA 50322
515-253-0830
515-253-9592
01/30/2009
02/09/2009
BILL TO: Accounts- CO Payable MWH Americas, Inc. POBox 6610 Broomfield, CO 80021
P.O.# 1914390,0102
PROJECT # 1914390.0102 Clinton, IA FMGP
CONTACT: Brandon Dunmore
FRACTION # 07AA 07B 07BB 07C 07CC
NAME LCSD LCS LCSD LCS LCSD
TEST Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15
RECEIIT VACyPRES.
NA NA NA NA NA
FINAL PRESSURE
NA NA NA NA NA
CERTIFIED BY: < : :^Af i»^2»^i^ t ^ p / '
DATE 02/12/09
Laboratory Director
Certfication numbere: CA NEL/^ - 021 lOCA, LA NELAP/LEL/>iP- AI 30763, NJ NELAP - CA004 NY NELAP - 11291, UT NELAP - 9166389892, AZ Licensure A20719
Name of Accrediting Agency: NELAP/Florida Department ofHealth, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/08, Expiration date: 06/30/09
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements ofthe NELAC standards
This report shall not be rcproJuceJ, except in lull, without the written approval of Air Toxics Ltd.
180 BLUE RAVINE ROAD. SUITE B FOLSOM. CA - 95630 (916) 985-1000 . (800) 985-3955 . FAX (916) 983-1020
Page 2 of 29
' iToxicsLTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
LABORATORY NARRATIVE Modified TO-15 FuU ScanySlM
MWH Americas, Inc. Workorder# 0901590A
Four 6 Liter Summa Special (SIM Certified) samples were received on January 30, 2009. The laboratory performed analysis via modified EPA Method TO-15 using GC/MS in the FuU Scan and SIM acquisition modes. The method involves concentrating up to 1.0 liters of air. The concentrated aliquot is then flash vaporized and swept through a water management system to remove water vapor. Following dehumidification, the sample passes directly into the GC/MS for analysis.
This workorder was independently validated prior to submittal using 'USEPA National Functional Guidelines' as generally applied to the analysis of volatile organic compounds in air. A rules-based, logic driven, independent validation engine was employed to assess completeness, evaluate pass/fail of relevant project quality control requirements and verification ofall quantified amounts.
Method modifications taken to run these samples are summarized in the table below. Specific project requirements may over-ride the ATL modifications.
Requirement ICAL %RSD acceptance criteria
Daily Calibration
Blank and standards
Method Detection Limit
TO-IS </=30% RSD with 2 compounds allowed out to < 40% RSD
+-30% Difference
Zero air
Follow 40CFR PL 136 App B
ATL Modifications For Full Scan: 30% RSD with 4 compounds allowed out to < 40% RSD
For SIM: Project specific; default criteria is </=30% RSD with 10% of compounds allowed out to < 40% RSD
For Full Scan: </= 30% Difference with four allowed out up to </=40%., flag and narrate oulliers
For SIM: Project specific; default criteria is </= 30% Difference with 10% of compounds allowed out up to </=40%.; flag and narrate outliers
Nitrogen
The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded I OX the calculated MDL in some cases
Receiving Notes
Sample BLOl-SG-SOOl was received with significant vacuum remaining in the canister. The residual canister vacuum resulted in elevated reporting limits.
Analvtical Notes
As per project specific client request the laboratory has reported estimated values for target compound hits that are below the Reporting Limit but greater than the Method Detection Limit Concentrations that are
Page 3 of 29
^ A i r ' iToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
below the level at which the canister was certified (at the Reporting Limit) may be false f)ositives.
The reported LCS/LCSD for MSD-W has been derived fix)m more tiian one analytical file.
Samples BLOl-SG-EOOl and BLOl-SG-SOOl were transfened fix)m SIM/Low Level analysis to fiill scan TO-15 due to high levels of target/non-target compounds.
Dilution was performed on samples BLOl-SG-EOOl and BLOl-SG-SOOl due to the presence of h i^ level non-target species.
The results for each sample in this report were acquired fiom two separate data files originating fix)m the same analytical run. The two data files have the saine base file name and are differentiated with a "sim" extension on the SIM data file.
Definition of Data Qualifying Flags
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction noi
perfonned). J - EstiiTiated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit UJ- Non-detected compound associated with low bias in the CCV N - Tlie identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector rl-File was requantified for the purpose of reissue
Page 4 of 29
r/mAir ' ^Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
Client Sample TD: BL03-SS-E001
LabID#:0901590A-01A
Compound
Naptithalene
Client Sample ID: BL03-SS-E001
LabID#:0901590A-01B
Compound
Benzene Toluene Ethyl Benzene
m,p-Xylene o-Xylene
Rot. Limit (ppbv)
0 86
Rpt. Limit (ppbv)
0 086 0 034 0 034 0.068 0.034
Amount (ppbv)
0.71 J
Amount (ppbv)
0.12 0.21 0.043 0 10 0 047
Rpt Limit (uG/m3)
4.5
Rpt. Limit (uG/m3)
0.27 0 13 0 15 0.30 0.15
Amount (uG/m3)
3.7 J
Amount (uG/m3)
0 38 0.79 0 18 0.45 0.20
Client Sample ID: BL03-SS-W001
LabID#:0901590A-02A
Rpt. Limit Compound (ppbv)
Naphthalene 0 80
Client Sample ID: BL03-SS-W001 Lab Duplicate
Lab ID#: 0901S90A-02AA Rot. Limit
Compound (ppbv)
Amount (ppbv)
0.057 J
Amount (ppbv)
Rpt. Limit (uG/m3)
42
Rpt. Limit (uG/m3)
Amount (uG/m3)
0.30 J
Amount (uG/m3)
Naphthalene 0 80 0.032 J 42 0 1 6 J
Client Sample ID: BL03-SS-W001
LabID/^:0901S90A-02B
Compound Rot. Limit
(ppbv)
Amount (ppbv)
Rpt. Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
0 080 0.032 0.032 0 064 0 032
0 071J
0 12 0 029 J 0.051 J 0.025 J
0 26
0.12
0.14
0.28
0.14
0.22 J 0.47
0.13J 0 22 J O i l J
Page 5 of 29
Air Tox ics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
I I I I I I I I I I I
Client Sample ID: BL03-SS-W001 Lab Duplicate
Lab IDft: 0901590A-02BB
Compound
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
Client Sample ID: BLOl-SG-EOOl
Lab ID#: 0901590A-03A
Compound
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
Rot. Limit (ppbv)
0.080 0.032 0.032 0 064 0.032
Rot. Limit (ppbv)
36000 36000 36000 36000 36000
Amount (ppbv)
0 064 J 0 12
0.030 J 0.049 J 0.025 J
Amount (ppbv)
15000 J 57000
26000 J 120000 28000 J
Rpt. Limit (uG/m3)
0 26 0 12 0.14 0 28 0 14
Rpt Limit (uG/m3)
120000 140000 160000 160000 160000
Amount (uG/m3)
0.21J 0.47
0 1 3 J 0.21J 0.11J
Amount (uG/m3)
47000 J 220000 11OOOOJ 510000
120000 J
Client Sample ID: BLOl-SG-EOOl Lab Duplicate
Lab ID#: 0901590A-03AA
Rot. Limit Compound (ppbv)
Amount (ppbv)
Toluene m, p-Xylene o-Xylene
3100
3100
3100
1200 J
3300
980 J
Rpt Limit (uG/m3)
12000
13000
13000
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xylene
Client Sample ID: BLOI-SG-SOOl
Lab IDft: 0901590A-04A
Compound
36000 36000 36000 36000 36000
R o t Limit (ppbv)
17000 J 72000
32000 J 130000 38000
Amount (ppbv)
120000 140000 160000 160000 160000
Rpt Limit (uG/m3)
54000 J 270000 140000 J 580000 160000
Amount (uG/m3)
4600 J
14000
4200 J
Page 6 of29
' XToxicSLTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS
Client Sample ID: BLOl-SG-SOOl Lab Duplicate
LabID#:090I590A-04AA
Compound
Toluene Ethyl Benzene m,p-Xylene o-Xylene
Rot. Limit (ppbv)
3100 3100 3100 3100
Amount (ppbv)
2900 J 1000 J 3800 960 J
Rpt Limit (uG/m3)
12000 13000 13000 13000
Amount (uG/m3)
11000 J 4400 J 16000 4200 J
Page 7 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL03-SS-E001
LabID#:0901590A-0IA
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020506 1.71
Date of Collection: 1/27/09 Date of Analvsis: 2/5/09 02:25 PM
Compound R o t Limit
(ppbv) Amount (ppbv)
Rpt Limit (uG/m3)
Amount (uG/m3)
Naphthalene 0.86 0.71 J 4.5
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates VeRecovery
3.7 J
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
96
98
98
70-130
70-130
70-130
Page 8 of 29
WL^ir ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL03-SS-E001
LabID#:0901S90A-01B
MODIFIED EPA IVIETHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020506sim 1.71
Date of Collection: 1/27/09 Date of Analvsis: 2/5/09 02:25 PM
Compound R o t Limit
(ppbv) Amount
(ppbv)
Rpt Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xylene
0.086
0.034
0.034
0 068
0 034
0.12
0.21
0 043
0.10
0 047
0.27
0 13
0.15
0.30
0.15
0.38
0.79
0 18
0 45
0.20
Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
98
98
101
70-130
70-130
70-130
Page 9 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL03-SS-W001
Lab m#: 0901S90A-02A
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: Dil. Factor:
Z020507 1.61
Date of Collection: 1/27/09 Date of Analvsis: 2/5/09 02:57 PM
Compound Rot. Limit
(ppbv) Amount (ppbv)
Rpt Limit (uG/m3)
Amount (uG/m3)
Naphthalene 0.80 0.057 J 4.2
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery
0 30 J
Method Limits
1,2-Dichloroethane-d4
Toluene-d8 4-Bromofluorobenzene
103
96
94
70-130
70-130
70-130
Page 10 of 29
' ITOXiCStra AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL03-SS-W001 Lab Duplicate
Lab IDft: 090IS90A-02AA
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020508 1.61
Date of Collection: 1/27/09 Date of Analvsis: 2/5/09 03:36 PM
Compound R o t Limit
(ppbv) Amount (ppbv)
Rpt Limit (uG/m3)
Amount (uG/m3)
Naphthalene 0 80 0.032 J 42 0.16J
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
102
99
97
70-130
70-130
70-130
Page 11 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL03-SS-W001
Lab ID#: 0901590A-02B
MODIFIED EPA METHOD TO-15 GC/MS SUM/FULL SCAN
File Name: DII. Factor:
z020507sim 1.61
Date of Collection: 1/27/09 Date of Analvsis: 2/5/09 02:57 PM
Compound Rot. Limit
(ppbv)
Amount (ppbv)
Rpt Limit (uG/m3)
0.26 0.12 0 14
0 28 0.14
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m, p-Xylene o-Xylene
0 080 0 032 0.032 0.064 0.032
0.071 J 0.12
0.029 J 0.051 J 0 025 J
0 22 J 0.47
0.13J 0.22 J O I U
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
106 100 99
70-130 70-130 70-130
Page 12 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL03-SS-W00I Lab Duplicate
Lab ID#: 0901590A-02BB
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020508sim 1.61
Date of Collection: 1/27/09 Date of Analvsis: 2/5/09 03:36 PM
Compound R D L Limit
(ppbv) Amount (ppbv)
Rpt Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xylene
0.080 0 032 0.032 0.064 0 032
0 064 J 0.12
0.030 J 0.049 J 0.025 J
0.26 0 12 0.14 0.28 0 14
0 21 J 0.47
0.13J 0.21 J O I U
J = Estimated value Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery Method Limits
1,2-Dichloroethane-d4
Toluene-d8 4-Bromofluorobenzene
102
101
99
70-130
70-130
70-130
Page 13 of 29
I I I I I I I I I I I I I I I I I I I
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BLOl-SG-EOOl
Lab ID#: 0901590A-03A
MODIFIED EPA JMETHOD TO-15 GC/MS
File Name: DII. Factor:
W020613 7200
Date of Collection: 1/28/09 Date of Analvsis: 2/6/09 01:05 PM
Compound Rot. Limit
(ppbv) Amount
(ppbv) Rpt Limit (uG/m3)
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xylene
36000
36000
36000
36000
36000
Naphthalene 140000
15000 J
57000
26000 J
120000
28000 J
Not Detected
120000
140000
160000
160000
160000
750000
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
105
104
97
Amount (uG/m3)
47000 J 220000 11OOOOJ 510000 120000 J
Not Detected
Method Limits
70-130
70-130
70-130
Page 14 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BLOl-SG-EOOl Lab Duplicate
Labn)#:090l590A-03AA
MODIFIED EPA METHOD TO-15 GC/MS
File Name: DII. Factor:
W020614 7200
Date of Collection: 1/28/09 Date of Analvsis: 2/6/09 01:25 PM
Compound Rot. Limit
(ppbv) Amount (ppbv)
Rpt Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
36000 36000 36000 36000 36000
140000
17000 J 72000 32000 J
130000 38000
Not Detected
120000 140000 160000
160000 160000
750000
54000 J 270000 140000 J 580000 160000
Not Detected Naphthalene
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates VoRecovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
105 103 97
70-130 70-130 70-130
Page 15 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BLOl-SG-SUOl
Lab ID#: 0901S90A-04A
MODIHED EPA METHOD TO-IS GC/MS
File Name: DII. Factor:
W020615 619
Date of Collection: 1/28/09 Date of Analvsis: 2/6/09 01:49 PM
Compound Rot. Limit
(ppbv) Amount (ppbv)
Rpt Limit (u6/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
3100
3100
3100
3100
3100
Not Detected 1200 J
Not Detected 3300 980 J
9900
12000
13000
13000
13000
Not Detected 4600 J
Not Detected 14000 4200 J
Naphthalene 12000 Not Detected 65000
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery
Not Detected
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
105
105
99
70-130
70-130
70-130
Page 16 of 29
^ A i r ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BLOl-SG-SOOl Lab Duplicate
Lab ID#: 090I590A-04AA
MODIFIED EPA METHOD TO-15 GC/MS
File Name: DII. Factor:
W020616 619
Date of Collection: 1/28/09 Date of Analvsis: 2/6/09 02:11 PM
Compound Rot. Limit
(ppbv) Amount (ppbv)
Rpt Umit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
3100
3100
3100
3100
3100
12000
Not Detected
2900 J
1000 J
3800
960 J
Not Detected
9900
12000
13000
13000
13000
65000
Not Detected
11000 J
4400 J
16000
4200 J
Not Detected Naphthalene
J = Estimated value Container Type: 6 Liter Summa Speciai (SIM Certified)
Surrogates %Recovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
104
104
98
70-130
70-130
70-130
Page 17 of 29
I I I I I I I I I I I I I I I I I I I
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 090IS90A-05A
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
Flie Name: Dli. Factor:
Compound
Naphthalene
J = Estimated value Container Type: NA •
Surrogates
Not Applicable
z020505a 1.00
Rot. Limit (ppbv)
0 50
Amount (ppbv)
0.16J
VoRecovery
Date of Collection: NA Date of Analvsis: 2/5/09 01:09 PM
Rpt Limit (uG/m3)
2.6
Amount (uG/m3)
0 87 J
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
95
95
92
70-130
70-130
70-130
Page 18 of 29
' iToxicsLTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0901590A-05B
MODIFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020505sima 1.00
Date of Coiiection: NA Date of Analvsis: 2/5/09 01:0g PM
Compound Rot. Limit
(ppbv) Amount (ppbv)
Rpt Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
0 050
0.020
0.020
0.040
0.020
0.024 J
0 0055 J
0 0022 J
0.0043 J
0.0022 J
0 16
0.075
0.087
017 0 087
0.075 J
0.021 J
0.0096 J
0.019 J
0 0094 J
J = Estimated value Container Type: NA - Not Applicable
Surrogates '/oRecovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
96
100
94
70-130
70-130
70-130
Page 19 of 29
I I I I I I I I I I I I I I
^ A i r ' iToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0901590A-05C
MODIHED EPA METHOD TO-IS GC/MS
File Name: DII. Factor:
w020609a 1.00
Date of Collection: NA Date of Analvsis: 2/6/09 10:12 AM
Compound Rot. Limit
(ppbv) Amount (ppbv)
Rpt Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene
Ethyl Benzene m,p-Xylene o-Xylene Methyl tert-butyl ether Naphthalene
J = Estimated value Container Type: N A - Not Applicable
Surrogates
1,2-Dichloroethane-d4 Toluene-d8
4-Bromofluorobenzene
5.0 50 5.0
50 50
5.0 20
Not Detected Not Detected Not Detected Not Detected Not Detected
Not Detected 15J
VoRecovery
102 100 97
16 19 22 22 22
18 100
Not Detected Not Detected Not Detected Not Detected Not Detected
Not Detected 78 J
Method Limits
70-130 70-130 70-130
Page 20 of 29
' IToxicsLTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0901S90A-06A
MODIFIED EPA METHOD TO-15 GC/MS SIM/FLILL SCAN
File Name: Dli. Factor:
Z020502 1.00
Date of Collection: NA Date of Analysis: 2/5/09 10:37 AM
Compound VoRecovery
Naphthalene
Container Type: NA - Not Applicable
Surrogates VoRecovery
98
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
102
103
101
70-130
70-130
70-130
Page 21 of 29
m A i r ' VToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
LabID#:0901590A-06B
MODIFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: Dli. Factor:
z020502sim 1.00
Date of Collection: NA Date of Analvsis: 2/5/09 10:37 AM
Compound %Recovery
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xylene
82 88 96 99 104
Container Type: NA - Not Applicable
Surrogates VoRecovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
105
103
102
70-130
70-130
70-130
Page 22 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
Lab ID#: 0901590A-06C
MODIFIED EPA METHOD TO-IS GC/MS
File Name: DII. Factor:
W020603 1.00
Date of Collection: NA Oate ofAnalysis: 2/6/09 07:30 AM
Compound VoRecovery
Benzene Toluene Ethyl Benzene m,p-Xyiene o-Xylene
107
109
106
106
106
Methyl tert-butyl ether
Naphthalene
Container Type: NA - Not Applicable
Surrogates VoRecovery
110
99
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
98
102
99
70-130
70-130
70-130
Page 23 of 29
^ A i r ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
LabID#:0901S90A-07A
MODIFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020503 1.00
Date of Collection: NA Date of Analvsis: 2/5/09 11:27 AM
Compound %Recovery
Naphthalene
Container Type: NA - Not Applicable
Surrogates %Recovery
100
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
102
103
96
70-130
70-130
70-130
Page 24 of 29
r/mAir ^ Toxics LTD,
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSD
LabID#:090I590A-07AA
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020504 1.00
Date of Collection: NA Date of Analysis: 2/5/09 12:08 PM
Compound VoRecovery
Naphthalene
Container Type: NA - Not Applicable
Surrogates VoRecovery
103
Method Limits
1,2-Dichloroethane-d4
Toluene-d8 4-Bromofluorobenzene
102
102
99
70-130
70-130
70-130
Page 25 of 29
I I I I I I I I I I I I I I I I I I I
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab IDff: 0901S90A-07B
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020503sim 1.00
Date of Collection: NA Date of Analysis: 2/5/0911:27 AM
Compound
Benzene Toluene Ethyl Benzene m, p-Xylene o-Xylene
Container Type: NA - Not Applicable
Surrogates VoRecovery
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
102
105
97
VoRecovery
86
94
96
99
104
Method Limits
70-130 70-130 70-130
Page 26 of 29
^ A i r ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSD
Lab ID#: 0901S90A-07BB
MODIFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020504sim 1.00
Date of Collection: NA Date OfAnalysis: 2/5/09 12:08 PM
Compound VoRecovery
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
84
93
94
98
102
Container Type: NA - Not Applicable
Surrogates VoRecovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
103
104
102
70-130
70-130
70-130
Page 27 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
LablD#:090l590A-07C
MODIFIED EPA METHOD TO-15 GC/MS
File Name: DII. Factor:
W020605 1.00
Date of Collection: NA Date of Analvsis: 2/6/09 08:25 AM
Compound %Recovery
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
102
106
104
105
108
Methyl tert-butyl ether Naphthalene
Container Type: NA - Not Applicable
Surrogates VoRecovery
102
111
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
94
103
99
70-130
70-130
70-130
Page 28 of 29
' \ToxicsLTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSD
Lab ID#: 090IS90A-07CC
MODIFIED EPA METHOD TO-15 GC/MS
Flie Name: Dli. Factor:
W020606 1.00
Date of Collection: NA Date of Analvsis: 2/6/09 08:43 AM
Compound VoRecovery
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
102 104 107 106 109
Methyl tert-butyl ether
Naphthalene
Q = Exceeds Quality Control limits
Container Type: NA - Not Applicable
Surrogates VoRecovery
94
141 Q
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
91 101 98
70-130 70-130 70-130
Page 29 of 29
Ai r \ToxicsLTD.
CHAIN-OF-CUSTODY RECORD
Sample Itansportatian Notice Relinquish rg sig-latur^or this docuinent irH:lir:ateSLtn8it sample i»baing shipped Vl conpitinoe-Mth 180 B L U E RAVINE R O A D , SU(TE B all ap3iicabi9 local, £tats, FcdGrai rational, and nl9mstcnai laws, reguiatoins and ordirancec of FOLSOM CA 95630-4719 a ny kind AirTnxicB Limit&rf aeeumoe na liabilitv »rth r«epeot to lhe ogBQcCon. handling or shipping t M c \ ggR.-] QAQ C A V I M m aS5-1(120 of tJieae samples. rWinquiahing signatjrc alao indicates ajpreement to hold harmless, defend, f ' ^ J 5»o-1 uuu ITKA i » i o j voa- iu^u and indennify AiiToiics Limited againet any clai"n, dsnaid O" adion, of an^ Mrtd, related to t l i Pano I r^ i collection, handling, or shippirfl of samples. D.O.T Fcaine (8tW} 467-4822 rs.q,e _ i _ — or _f—
Proiect Manage'
Collected bv:(P"i tart(t
Company JOlU/i-h
/ i i s ^ ' - ^ e £iM£ll^
Emai (f^^j^y lcyiiiWfVi/i(OflviJf^ii t v / t j u f
Address i / / ^ J /f^i?tfyg^/feShv CksfM>fLC. State 7>» Zip 5^3ZZ.
Phone ^ » - ^ S - ^ I 3 t D Fax S I 5 ' P ^ 3 ' 9 S ? 3 .
Project Info:
P.O. # / ^ / - V ^ ^ f / ? ' £>/C^
Projsct Name Ciifiihn.ZA n ^ J s i f
Itjrn Around Time:
Normal
QRush
ut> UM Or.)y
PresEurizBd.by
Date:
Pressurization Gas:
.N, He
Lab i:D. F[»id Sample i.D. (Location) Can#
Cbl f^BtPS-SS-g^x?/ % ^ ^ \ 5
Date Time Of Collection ofColisctlon
oiiz^-h-^. l^iCf
Analyses Requested .<D Canister Pressure/Vacuum
initial Firal Receipt Final
- i . 3 /
aQft^ BLC3 'Ss - h(, __ L 339(^:1 W
oiifTidJ l $ 3 ^
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i ^ ^ (&31- /Tiif^rf Sfr-^S- / / . / iu* ; C B T ^ t Q S i ^ } ^ _ » ^ . 5
<NafHtM^-y h-iael &StM Sfi^fS /^(ftA i ^ ^ ' ' ^ - *
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Relinquishdd by: (signature'i Dat»TimQ .
Relinquished by: (si^jncture) [>ate'.Time
Relinquished by: ileignature) Dal« Time
Rw^eo by. isignaturai Dets Tim^
Reoeivec by. {dignature) A^'/^ig
s ^ Rewived by; {signaturg) Date/Tim^
in<
^ Notes. ,
^ S i u r i ^ t * H A S c t £ a r ~ / * t ^ y U/'^'f'-*'^
Lab Use
Shipper N&nre Atr.B4»i» -Temnp ("C) <!iondifiorT
AAA- I faM Custody Seals Intatet? • WorkO-der#.
y^ j NO Monej n g n i s f l O
Fcni 'BS3i«..1
T.\BhE2-l
ANALYTICAL PAkAMClieRS
Analyte Snmp Water Sample AiiabrtJcal Method
Sobsbib Soil aad S«a G « Sample Analrtkal Metiiod
IndMT Air and Outdoor Air Sample Aiudy liud IVlJelliiid
VOC COPOs
Benzene
Eihylbenzene
Toluec&
Xylenes, Total
&^'-S46 8260 Modified TO-15 H i f ^ o w Level with SIM
SW-$46 8260 Modified TO-15 Higli/Low Level vrith SIM
SW-S4« 8260 Modified TO- IS Eligb/Lo w Level vrith SIM
SW-846 8260 Modified TO-15 HJgb-Tjjw Level vrith SIM*
Modified TO-15 Ilish/Low Level widi S M
MJodified TO-lS 3igb/Xo w Level ^itb. SIM
Modified TO-15 Hi^TjOfr Levd Moth SIM
Modified TO-15 Hi^i/Low Level 'svich SIM^
>'aph1Laleue sw.«4<;ga<;o Modified T O 15 Low Level ModiUfii] TO-15 Low Level
Leak Test Tiacer Gas
JEklium NA Modified ASTM D-1945 NA
Notes: ASTM D-1945 = Standard Test Method Analysis afNaniral Gat by Gas Chromaiograpby, (Amencan Sodety for Tefiting aitd Materials, 200 /). NA SIM SW-a46
TO-i5
VOC COPC «
= Not applicable. - Selected ion monitoring. = Test Methods p r Evaiuaiiiig SuKd Wj.t?«, SW-«44S, PhysicaliOiemical Metfinds, .1"* Pjtlitinn, WwiWiiPtnn. Dn. , (United State*
EnviniimiBDtal ProtectioD Agency pEPAl. 1 ^ ) . = CoimpMidium of Methods toe (he DeieciiQiaanon of Toxic Oiganic Coiqiouiids in Ambient Air. Seoond Edidoo. Conytendium Hethod
TO-15. Detennmmoii qf Volatile Organic Compounds (VOCs) tn Air CoUecxd In Speciaily-Prepared Caniatera and Anaiyzed I?} Gaj ChrOmatograpKy/MaiiSpeCtrOmntTy (GC/idS) CEPA, 1999).
= Volatue Oi ganic coiupouiul mustiiuBiit of poDeotial couceriL = '\ttit itepoTted o-xyleiie aod io,p-xyleae isoii3ei'iesulc& reported by this method will be suoimed to caJcvlate tool xylejie conetentratiofis.
Page 1 flf I
I
TABLE 4-1
VAPOR INTRUSION INVESTIGATION ACTION L £ V £ L S
Analyte
BCI12CQC
HrhylhenTena
Ntiphlhiilcnc
Tt)liju;iie
X) Idles, Toltl
Tout FlatunubJe Gas
Sump Water
Methiid Repnrting Limit (llgO.)
LO
It)
1.0
1.0
2.0
NA
SiibAlab Soil Gm, Soil Gas, and Indoor Air
Tai^getlndiHirAIr (JoncentTitlioji*
<MgrtB') (iJpliv)
0.31
0,97
0.072/7.2"
'!,20ft
100
NA
0.098
0.22
0.0137 n , 3 7 "
1,*iS0
23
NA
Indoor Air
Lower Explosive Limit
NA
NA
NA
NA
NA
TcnPiacrait
"Note*; * = T o onmply witli pre^c.rihetl c^mcer risk nf IR-Oft imd iion-tjincer Target haziird index of i fin resldcntinl
iiihtlatinn cxpniiiirc iiccnurifi. The tm- k:t innaor a.k cjAcLxitrtitions ore provided in Ihc Rcitidentiul Air Siipponlng Tabic in clic September 12, 2U0K wision ol Rm^toml Scremiaii l.e^eis for Chemical Cantemiinantii atSupeifitnd Sitts iUFA, 20D8).
** s Hic target indoor air contxntration Itir nuphtlmlciu: <;orrcsponding dr lG-()6 CUTIOCJ ri.<tk (0,072 ^g/m') Jt cwo orders of magnitude smaller than the lalMiratorv method jepmting limit IXN- iiaphthAlene hy Mcidifieri TO-15 T iw l^evel (2.fi2 fig/m''), u* IIMIWI in Table 4-4 i)r Ihi* QAPP. ThureFuTe, 7.2 fig/inV which correspiind!; tu a cLiiwei liak ot [ E 04, will bo Ubcd a atl .tclion lcVk>l lor 8iib6bb «oil g.m, induor :iir. aatl ouldoor air jiaphfhaleneroticentrntions duriig fhi» wipor IntMuinn inveKtigfirinii.
|tg/L = MiciT)gr{un(fi) per liter. jig/m'' = Micmj!raiTi(») p e r a ilii:: meter. NA ss Not appliuable. t m = Not «mbi ished. ppbv = ?»rt(s) per b i H ic n vo I ume.
P.i^, 1 nf I
MKI HOU 11H1N>11T1ING LIMIl^
Aiii)l}-tic«l Mctlwd Aiwlyt« Wl')
M«fhod KeportinK Limit'
fjig^m') (ppbv) Percent
Modified TO. 15 High/Li)wLevel v/lth SitA Modified TO. 15 HifilT/I.ow l,eve[ with SIM
Modified "IXJ-IS \jaw Uvel Mr dified I'O- l.S Hijjh/I ,<w T iivd with SIM Modified TO-15 IlighflLov/Level with SLM Modified TO-15 HigM^w J.evel witii SIM
Modilicd A«TM D-L!H5
SW-a4ft 8260D SW-a^O 82603 S\V-946 S2<iflB SW-846 82()0B SW-a46 8260B
Benzene Hrhj'Jbeiizeiie Naphthalene Tohl ene ni,p-Xylene o-Xylene
Hcliiim
Benzene Ethylbenzene NjiphChHlLHEi
Toluene XyLiifleii, TtnxJ
NA NA NA NA WA NA
NA
1,0 i,0 t o Ln 3.0
0 16 0,087 2.62 0.075 0,17 0,087
NA
NA NA NA NA NA
o.nsf) 0.020 0.50 0.020 0.040 0.020
NA
NA NA N'A NA NA
NA NA NA NA NA NA
0.05
NA N.\ NA NA NA
Notes i
" - Aepotting limifB are inHtiiinient" and time-^pe^ifiij (baxed cm Ubnntor^ ntjindaid nperatinf procedure Kijhcdtilc fiiiT update). LaboTaniry will luemuHt current repcirtiTig Mi itoi. The viiliien lixteil in thi.s table iii'e ndviiioiy only. Subnlub Jitiil gss, soil gu. Indoor air, and outdoor air 3anip1e nicthod >epcrtir4; llmitt HMSume a. one-llier sampJe ;iiuilyKi« viilume frnm a six-litei CLiiiixter; utitasl rsp[>rtin(i limitK will be higher depending on the canister dilution factor and/oi sample nuiti ix effects,
liS^L = .\li&ro£rflfm(t) pcsi' lilcr.
jLg m' ti .VlicrogramC*) per cubic meter,
pptrv = Pai r [ler bill inn vol nine.
Modified ASTM D-1943 => Staiidard Text Method Analy-us of Natural Oas by Oas ChfV!)mio%f(iphy. Amuriean Society for I'etting and MataiaLH (ASTM, 2l>fl /)'ax modified by A'lL,
M4idifiBi'iTO-L') = CnmpeiidtiVfi ofMi\hcdxfor lhe Dettrmlnaiicm ofToxic Ofganic CorKp&Hndx in .^fabiunt Air. Secviul Edition CuThpemlium fdtihtfd TO-15. Detemiination of Volatile Oiganic Compcmdi (VOCs) in Air Collccteti lit StKiiaily-Prnpau'd Ctaiisivrs Arui Analyzed by Cinn Chn>rtmuigr(iifhy/Mu)is Sfiettrtimrfry {GC/MS) (Uiiilctl Stalcxl Euvumunciital ft'occction Aficncy [EPAJ. lyyj) a« moJificd by ATL.
SW-a46^ Test Metfwds for Hvaliiatins Solid T ' Edition. Wiahint-tiin, D.r., (HPA. 198fiV
SIM = Selected ton isonitoting.
NA s Not applksible.
Waxu, SW-Mb., Fny^xal^Cheinical MecKod ,
Fage T of 1
j taToxics LTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
2/12/2009
Mr. Randy Kroneman MWH Americas, Inc. 11153 Aurora Avenue
Des Moines IA 50322
Project Name: Clinton, IA FMGP Project*: 1914390.0102 Workorder #: 0901590B
Dear Mr. Randy Kroneman
The following report includes the data for the above referenced project for sample(s) received on 1/30/2009 at Air Toxics Ltd.
The data and associated QC analyzed by Modified ASTM D-1945 are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative.
Thank you for choosing Air Toxics Ltd. for you air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Brandon Dunmore at 916-985-1000 ifyou have any questions regarding the data in this report.
Regards,
^^H / fU^n (-• V_.^yi«*«_
Brandon Dunmore Project Manager
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 .FAX (916) 985-1020
Hours 8:00 A.M to 6:00 P.M. Pacific
mAi r ^ XToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0901590B
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED
FRACTION # OIA OIAA 02A 03A 04A 05A 06A 06AA
Mr. Randy Kroneman MWH Americas, Inc. 11153 Aurora Avenue Des Moines, IA 50322
515-253-0830
515-253-9592
01/30/2009
02/12/2009
NAME BL03-SS-E001 BL03-SS-E001 Lab Duplicate BL03-SS-W001 BLOl-SG-EOOl BLOl-SG-SOOl Lab Blank LCS LCSD
BILL TO: Accounts- CO Payable MWH Americas, Inc. POBox 6610 Broomfield, CO 80021
P.O.# 1914390.0102
PROJECT # 1914390 0102 Clinton, IA FMGP
CONTACT: Brandon Dunmore
TEST Modified ASTM Modified ASTM Modified ASTM Modified ASTM Modified ASTM Modified ASTM Modified ASTM Modified ASTM
D-1945 D-1945 D-1945 D-1945 D-1945 D-1945 D-1945 D-1945
RECEIPT VAC/PRES.
6.5 "Hg 6.5 "Hg 5.0 "Hg 2.0 "Hg
23.5 "Hg NA NA NA
FINAL PRESSURE
5 psi 5 psi 5 psi 5 psi 5 psi NA NA NA
CERTIFIED BY: 3 1 ^ ^ £ ^ ^
DATE-02/12/09
Laboratory Director
Certfication numbers: CA NELAP - 021 IOC A, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892, AZ Licensure AZ0719
Name of Accrediting Agency: NELAP/Florida Department ofHealth, Scope of Application; Clean Air Act, Accreditation number: E87680, Effective date: 07/01/08, Expiration date: 06/30/09
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements ofthe NELAC standards
Tins report shall not be reproduced, except in full, without the wntten approv.il of .^ir Toxics Ltd
180 BLUE RAVINE ROAD. SUITE B FOLSOM. CA - 95630 (916) 985-1000 . (800) 985-5955 FAX (916) 985-1020
Paee I of 12
Wk^ir ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
LABORATORY NARRATIVE Modined ASTM D-1945
MWH Americas, Inc. Workorder# 09015908
I'our 6 Liter Summa Special (SIM Certified) samples were received on Januaiy 30, 2009. Tlie laboratory perfonned analysis via modified ASTM Method D-1945 for Helium in natural gas using GC/TCD. The method involves direct injection of 1.0 mL ofsample.
Method modifications taken to nm these samples are suminarized in the table below. requireiTients may over-ride the ATL inodifications.
Specific project
Requirement Normalization
Sample analysis
Sample calculation
Reference Standard
Sample Injection Volume
ASTM D-1945 Sum of original values should not differ from 100.0% by more than 1.0%.
Equilibrate samples to 20-50° F. above source temperature at field sampling
Response factor is calculated using peak, height for C5 and lighter compounds.
Concentralion should not be < half of nor differ by more than 2 X the concentration of the sample. Run 2 consecutive checks; must agree within 1%.
0.50 mL to achieve Methane linearity.
ATL Modifications Sum of origmal values may range berween 85-115%. Nomialization of data not performed.
No heating ofsamples is performed.
Peak areas are used for all target analytes to quantitate concentrations.
A minimum 3-point linear calibration is performed. The acceptance criterion is %RSD </= 15%. All target analytes must be withm the linear range of calibration (wilh the exception of 02, N2, and C6+ Hydiocarbons).
1.0 mL
Receiving Notes
Sample BLOl-SG-SOOl was received with significant vacuum remaining in the canister. The residual canister vacuum resulted in elevated reporting limits.
Analvtical Notes
As per project specific client request the laboratory has reported estimated values for target compound hits that are below the Reporting Uinit but greater than the Method Detection LimiL Concentrations that are below the level at which the canister was certified may be false positives.
Definition of Data Oualifving Flags
Six qualifiers may have been used on the data analysis sheets and indicate as follows: J - Estimated value.
Page 2 of 12
m A i r ' IToxiCSLTa
AN ENVIRONMENTAL ANALYTICAL LABORATORY
E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the detection limit M - Reported value may be biased due to apparent matrix interferences.
File extensions inay have been used on tlie data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector rl-File was requantified for the purpose of reissue
Page 3 of 12
Ai r Toxics LTD
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
Client Sample ID: BL03-SS-E001
Lab ID#: 09015908-01A
Compound RpL Limit Amount
r/») Helium 0.086 0.31
Client Sample TO: BL03-SS-E001 Lab Duplicate
Lab ID#: 09015908-01A A
Compound RpL Limit Amount
Helium 0 086 0.30
Client Sample ID: 8L03-SS-W001
Lab 1D#: 09015908-02A
Compound RpL Limit Amount
Helium 0.080 0.079 J
Client Sample ID: BLOl-SG-EOOl
Lab IDff: 090IS90B-D3A
Compound Rpt Limit Amount
Helium 0 072 20
Client Sample TD: 8L01-SG-S001
Lab Wit: 0901590B-04A
Compound RpL Limit Amount
f/o)
Helium 0.31 58
Page 4 of 12
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL03-SS-E001
Lab I D#: 09015908-01A
NATURAL GAS ANALVSIS 8V MOPFFIED ASTM D-1945
File Name: 9020219b Date of Collection: 1/27/09 DII. Factor: 171 Date of Analysis: 2/2/09 04:19 PM
RpL Limit Amount Compound py (%)
Helium 0 086 0 31
Container Type: 6 Liter Summa Special (SIM Certified)
Page 5 of 12
I I
mAi r I feaToxics LTD.
I I I I I
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 8L03-SS-E001 Lab Duplicate
Lab ID#: 09015908-01A A
NATURAL GAS ANALVSIS BV MODIFIED ASTM D-1945
File Name: 9020220b Date of Collection: 1/27/09 DII. Factor: 171 Date of Analvsis: 2/2/09 04:40 PM
RpL Limit Amount Compound P^ (%)
Helium 0.086 0.30
Container Type: 6 Liter Summa Special (SIM Certified)
Page 6 of 12
' IToxicsLTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL03-SS-W001
Lab IDft: 09015908-02A
NATURAL GAS ANALYSIS 8Y MODIFIED ASTM D-1945
File Name: 9020221b Date of Collection: 1/27/09 DII. Factor: 161 Date of Analvsis: 2/2/09 05:03 PM
RpL Limit Amount Compound P^ (%)
Helium 0 080 0 079 J
J = Estimated value Container Type: 6 Liter Summa Special (SIM Certified)
Page 7 of 12
mAir , \TOXICSLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: 8L0I-SG-E001
Lab ID#: 09015908-03A
NATURAL GAS ANALYSIS 8Y MODIFTED ASTM D-1945
File Name: 9020222b Date of Collection: 1/28/09 DII. Factor: 144 Date of Analysis: 2/2/09 05:29 PM
RpL Limit Amount Compound P^ (%)
Helium 0.072 20
Container Type: 6 Liter Summa Special (SIM Certified)
Page 8 of 12
WAi r ' iToxicSLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BLOl-SG-SOOl
Lab I D#: 09015908-04A
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
File Name: 9020223b Date of Collection: 1/28/09 DII. Factor: 6J9 Date of Analysis: 2/2/09 05:51 PM
RpL Limit Amount Compound P^ C/o)
Helium 0.31 58
Container Type: 6 Liter Summa Special (SIM Certified)
Page 9 of 12
I
mAi r I saToxicsLTD.
I AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab IDft: 09015908-05A
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
File Name: 9020203b Date of Collection: NA DII. Factor: 100 Date of Analysis: 2/2/09 08:58 AM
RpL Limit Amount Compound (%) (%)
Helium 0.050 Not Detected
Container Type: NA - Not Applicable
Page 10 of 12
WkAir ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
LabID//:090I590B-06A
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
File Name: 9020228b Date of Collection: NA DII. Factor: 100 Date of Analysis: 2/2/09 07:57 PM
Compound VoRecovery
Helium 104
Container Type: NA - Not Applicable
Page 11 of 12
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSD
Lab ID#: 09015908-06AA
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
File Name: 9020229b Date of Collection: NA DII. Factor: 100 Date of Analysis: 2/2/09 08:23 PM
Compound %Recovery
Helium 105
Container Type: NA - Not Applicable
I
mAir I fmToxicsLTD.
I I I I I I I I I I I I I I I I Page 12 of 12
\»
A i r \ToxicsLTD.
CHAIN-OF-CUSTODY RECORD
Project Manager l<.AN]>^J<^KCh^jUj;Nl . . , . ,
Collected by: <fmtaro Sign, A>y-^^^ ^Ky^/>?i>V^A//MeyA'MUh^iM
Com pany _i222*^Zf Ei ail fjr.t'ii'/-J^hvnei>viP^f''^t^9U ^»/./^«</
Sample liansportalion Notice " ^ Fl«lMquibliiriy«ii|ii£iiLi()i'i Uiii doLuini iii ndl<;dte»Llwils.imjdl&l:<iirig<ih|:f:ec iiicompliar)c»wiL-i IflO BLUE RAVINE ROAD, SUITE 8 all appirEbie Ideal Stntr Fn*ral, national, Fnijinterrgtinruil laws fRQulMinni; ami nr<1inHnnRR nf FOLSOM CA 95530-4719 ari> kind. Air Toxics jnit«d assjTes no liaa lity with respecr to the collection, handing or shipping fQ-c\ QOC innn P A V I f t i t i i QAR I m n .ot ihcM «dinpi«s Heiinqufihng sgnstu-ft aiea indisatee agneemeni to Hold harmless, aatend, l " ' * / i«3- i«uu P » A (if I D J ! I » 3 - I U ^ U and mdcmnifir' ii Toxi«;Limit5d agai ist anv daim, (Jemand, or urioti.oi any kjntJ. related to tne nana I rJi i colleciian iand ing, or ships n£ ol samplss. D O.T I lotlin« [MO) -s«7-4a22 ^ ^ 9 ^ — i — " ' —^—
Phone ^ ^ ^ - ^ ^ J " ^ S 3 0 Fax 5 " / 5 - ^ ^ 3 - f : 5 ' f ^
Project Info:
P.0.#
Projest Name O i f ^ ' p r h l A r ^ ^ ' i ^ f
Turn Around Time;
I^N:>rmal
QRixsh
Lirij 'Use pr/y
Pressurized by;
Data: I
Pr^^sisti ri 7ation. Qa:;:
LafaLD. Field Sample LD. (Location) Can« Data
of Collection Time
ofOollecllon fjrt-ii ^ ' ^ o /f-'-= nJ^->. (*J^X«. i'«-i^
Analyses Requesied ® Canister Pressuie/Vacuum'
Initial Final ^ teceipt' Firial IP")
jm. gLgg -.5 5 :^£" £>.i?.i_ Z $ i i 5 oifzi-h^, -af.'H) -6 -3 /
Q ^ 3103-ss h^^^/ ^5?i;L ^M^ tS3^ tn \a Ttf-tS t . tt-ot., li.T£ V i Sif'iJ,
-275$ - ^ ^ T .
CBB •O' ' K-
C2/ f - ? ; Qip^iOf / ^ ^ ^
> V / ^ ^/^ZS^J?
/?ii»«' jz?-/<> ;Vi/Z<.. -'3j:5?jrff'.i>«j^ . J , , j ^ ^
/5 /<i*.^? I^^ff 7t>-.'i t h t ^ ft7J^-X€'S.>.**j, L i . ^ 5 -p/¥ ^Z^.<i/
ridi-iquislied bv: isignatu-el- Date.-Tinne . ,
Rslnquislied by: leignatu'e; DatOfTime
ReMj sd by: (signatur^ Detev'Tlme -teceiysc i
RQC9iv0c by (eign^turs) ' ^ ^ I img
Rslinqurshed by. (signature) Date-Time Rec»ivBcby {signature] D<<td/ririi ^ f ' i i e ^ ifna-^f^sc^-tiffin ^ ^ f f k p / ^ * ^ ^
j t ' U j .
ete.tt.ift
Tenip (°C-)-- ' .ConidrticrK : • • f^kliislpdy Seals. Intact? • =\frork Order # .|__. SnipjperName Air Bill Vf
f\Mt I ^ : m " o^; w^/]^ j ^ l Y ^ H q None 0 9 0 1 5 9 0
=orr ia ft »/.n
TABLE 2-1
ANALYTICAL PAKAMETEKS
Anaiyto Sump Wetcr Sanmle Analytical Metbed
Subslab SoU and Soa Gas Sansplr Analj'tical Method
Indoor Air and Outdoor Air Sample AnoljiiGid Metliod
VOC COPCs
Beozeoe
£tliyIbtIEI£Iie
Toluenes
Xylenes, Total
SW-&46 S260 Modifie<l TO-15 agiOjOW Level wilh SIM
SW-846 S 2 ^ Modified TO-IS Higb/Low Level wUli SOA
&W-S46 8260 MotmeO. JX>-13 Ui^Low Level mOi SIM
SW-846 8260 Atodified iX)-15 Ui^i jow Uvel vriflj SIM*
Modified TO-15 High/Low Level widi SIM
MLtOiTied TO-15 Eai^i/Uiw Levd wiOi SOA
Modified TU-15 ilifib/Low Level widi SIM
Modifjsd IO-15 Uigb/Low Level with SIM*
Naphlbitleiie SW-846 &260 Modified TO-15 Low Levd Modified TO>lS Low Lc\-cl
Leak T«t< T r M » Gas
HaLiion NA Modified ASTM D-1945 XA
Notes; ASTM B-1945 - Standard Test Me^tod Analysis ofNatural Gas by Gas CkramaiogTapky, (America Socie^' fior Testing ud Materuls. 2007). XA SIM SW-B46
TO-L1
VOC COPC
= Not afipUoablc = Selected ion nunitodag. = Test Methods for Evuluuling Solid Wasle. SW-84^. Fbyslcal/Cbemical Mediods. 3* Edition, Wishuogtoi]. D.C., (Uaj»d States
bnviromnenlal PTotectioa Ageacy [EPAj, 1986). = ronipendiuni of MNhndg fbr fiie Determinarimi of Tonic Oroamic Cninpnund. in Ambient Air. Second Hditinn. Conytendaaa Mahod
TO-IS. Detennination of Volatile Organic Ccmpetutds (VOCs) in Air Collected In Speckdfy-Pre^^cared Ccnisters and Andyzed by Cas Chromatogn^y/Mass Spectrometry (GC/MS) (EPA, 1999).
^ Volalik urgauic ticia^und coi£titucat of poieutial codOeiiL = Tbe TepojCled o-;cyleDe and m-p-iiyleDe iwnwr results reported by this mettiod will be smmned ID raiknlnm total xylene ooncanlrationa.
Pftge 1 of I
TABLE 4-1
VAPOR tMTRUSlON INVESTIGATION ACTION LEVELS
Analyte
Benzene .
Ethylbenzene
Naphthalene -
1'o]uene
Xylenex, totnl
Total Rammiible Gu.s
SwTVip Water
Method Reporting Limit (118^0
1.0
].(]
].0
1.0
2.0
NA
«ub«lab Soi! Gai, SoU Gtii, and Indoor Air
Target I Conccr
0,31
0,97
0.072/7.2*
5,200
100
NA
ndaor Air ttratlon'
(ppbv)
0,098
0.22
0.0137 y 1.37'
1,380
23
.NA
Indoor Air
Luwcr Exptoiive Udlit
NA
NA
NA
NA
NA
Ten Percsnt
Notes: ^ s To cojnp;y willi piesciibed cancer tiik of Ili-06 uad ooii-cancev larget liauu'd index of 1 RIT nwidential
inhalation axposure scenario. The target indoor air {.-oncentriilioLis ore provided in ttie Kesidealinl Air SiippOl'lJilg Table iti [he SepLcmbcr 12, 2008 verNion nf Regional Scrff.n\nq !.pveh fpr Chumtcat CmtttotmaHts <u SuperfutidSites (HPA, 2008),
'' =Th[: target indoor tiir conociitration for naphtbaleiie coriespouding CO lC-06 Cdticer risk (0.072 p,gj m') iR two oi'deri of magnitude smaller ihan the laboraiory method leportin^ Umit for naplitltalene by Modified TO-IS \j9vi Level (2.62 ji^th^>, as [isted in Table 4-4 of ihis QAPP, Therefore, 7,2 pfi,'in , which coincspcndiv tu a cancer risk of lH-04, will be used a» atl action level tor subiLab ioil gaa, indoor air, and LiuUliiornJr naphthalene! aim^enlration.sdnrint'this vupi^ inrruiiinn inve^rigatinn,
pg/L isMicrOip-aii)(s)perJite3f. pg/m^ = Mionigrani(s) per cubic meter. NA = Not applicable. NR = Not iwrabliNhed. ppbv s P«Tt(s) per billion volunne.
PAgC 1 of 1
I I I I I I I I I I I I I I I I I 0 I
TABLE 4-4
METHOD REPORTING LIMITS
Analytical Methoil
ModifKd TO-1.5 Higb/Low U v e i wicll SIM Modified TO-15 Higli.'Low Uvel with SJIM
MnrtifiHi rO-1.5 lnwr>evel Modified TO-15 High/Low U v e l wiih SIM .\(odifie(1 TO-15 High/Low Level with SIM Modified lO^lS High/Lov» Level wilh SIM
Modified ASTM D-1945
sw-st5S2t;aB SW-Mft a26nB SW-M68260B sw-&4(S n6a& SW-Mti 8260B
Aaalyte
Benzene Ethylbeibatw Naphthaiena Toluene n],p-Xyleiie (vXyleiie
Helium
Benzene Bihylbcnzcnc NaphthjildK Toluene XyJciits. Tntal
(Mg/TO
NA NA NA NA NA NA
NA
1.0 1.0 1,0 LO 2.0
Method KppoirllnR Ltmlt '
dig^m')
01ft O.0S7 2,62 0.075 0.17 0.087
NA
NA NA NA NA NA
ippbv)
0.050 0,020 0,50 0,020 Q.040 0.020
NA
NA NA NA NA NA
Percent
NA NA NA NA NA NA
0.U5O
NA NA NA NA NA
Notw;
*• = Beporring limits are instrument' and dme-xpecifie (bused on laboratory standard operating procedure Mhedule for upditc). Laboratory will ii&e mott CLUI^JII lepurliiig litniLi, Thn values liKterl in thiji tdble nre advisory only. Stibshb mil ga>, soil gai, Indoor air, and outdoor na .Ntunple metliod repotting limili usMuniB 1 one-liliiT sumple aniilyxis volume from a six-lltcr canister; actual repoiUitg limits will be higher depending on the e^niater dilution factor and/or sumple matiix effects,
^ ^ . = Microgram(s) per litar.
pg/m' B Microg7am(ft) pei' cubic neter.
ppbv = Pail per liillio[i vDluimi.
Modified ASTM D-1945 =Stat\dafd Test Metliod Analytis ofNatural Gus by Guj Oirumuiugmphy, American Sodety for Testing tind Material (ASiM, 2007) as itiudified by ATL
MtKlificd TO-15 = Cimpendium of Methods for the. Determination of Toxic Organic CoMiwItndt in .Ambient Air. Second lidition. Compendium Metltod T0-J5. DetemtlrtuUvn. rif Volcdile Organic Compoutids (VOCa) in Air Collected In SpeeiaUyi'rc.pa.rea Vaniiten And Analyzed hy Gas CkrotmntugTOfihy/Mass Speammr-try (GC/MS) iirnited Slflted Environmentiil Protcciion Agcnay [EPA], 199?) w modified by ATL,
SW-846» Test Mtthodn for h\atuatins Solid Waste, SW R4(i, FhysicaJI/Chemicfil Methods, V* Editioji, Wasliingmn. n,C., (KPA. 1986).
SIM = Selected ion monitoring,
NA = Not applicable.
Page I of 1
^ A i r ' Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
2/13/2009
Mr. Randy Kroneman MWH Americas, Inc. 11153 Aurora Avenue
Des Moines IA 50322
Project Name: Clinton, IA FMGP Project*: 1914390.0102 Workorder #: 0901612A
Dear Mr. Randy Kroneman
The following report includes ttie data for ttie above referenced project for sample(s) received on 1/31/2009 at Air Toxics Ltd.
The data and associated QC analyzed by Modified TO-15 are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative.
Thank you for choosing Air Toxics Ltd. for you air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Brandon Dunmore at 916-985-1000 ifyou have any questions regarding the data in this report.
Regards,
' ^ i * 9 i a ^ n C v_.A'«*a^«e_
Brandon Dunmore Project Manager
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 .FAX (916) 985-1020
Hours 8:00 A.M to 6:00 P.M. Pacific
mAi r ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0901612 A
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED;
FRACTION ft
OIA OIB 02A 02B 03A 03AA
04A 04AA 04B 04BB 05A 05B OSC 06A
06B 06C 07A
Mr. Randy Kroneman MWH Americas, Inc. 11153 Aurora Avenue Des Moines, IA 50322
515-253-0830
515-253-9592
01/31/2009
02/10/2009
NAME
BL04-SS-E001 BL04-SS-E001
BL04-SS-W001 BL04-SS-W001 BL02-SS-E001 BL02-SS-E001 Lab Duphcate
BL02-SS-W001 BL02-SS-WOOI Lab Duplicate BL02-SS-W001 BL02-SS-W001 Lab Duplicate Lab Blank Lab Blank Lab Blank CCV
CCV CCV LCS
BILL TO: Accounts- CO Payable MWH Americas, Inc. POBox 6610 Broomfield, CO 80021
P.O.# 1914390.0102
PROJECT # 1914390.0102 Clinton, IA FMGP
CONTACT: Brandon Dunmore
TEST Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15 Modified TO-15
RECEIPT VAC/PRES.
5.0 "Hg 5.0 "Hg
4.0 "Hg 4.0 "Hg 2 5 "Hg 2 5 "Hg
2.0 "Hg 2.0 "Hg 2.0 "Hg 2.0 "Hg
NA NA NA NA
NA NA NA
FINAL PRESSURE
5 psi 5 psi
5 psi 5 psi 5 psi 5 psi
5 psi 5 psi 5 psi 5 psi NA NA NA NA
NA NA NA
Continued on next page
180 BLUE RAVINE ROAD. SUITE B FOLSOM. CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
PaBC 1 of 29
r^g^Air Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0901612 A
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED:
DATE COMPLETED:
FRACTION* 07AA 07B 07BB 07C 07CC
Mr. Randy Kroneman MWH Americas, Inc. II153 Aurora Avenue Des Moines, IA 50322
515-253-0830
515-253-9592
01/31/2009
02/10/2009
NAME LCSD LCS LCSD LCS LCSD
BILL TO: Accounts- CO Payable MWH Americas, Inc. POBox 6610 Broomfield, CO 80021
P.O.# I914390.0I02
PROJECT # 1914390.0102 Clinton, L\ FMGP
CONTACT: Brandon Dunmore
TEST Modified TO-15 Modified TO-15 Modi fied TO-15 Modified TO-15 Modified TO-15
RECEIPT VAC/PRES.
NA NA NA NA NA
RNAL PRESSURE
NA NA NA NA NA
CERTIFIED BY. C-y^'^3J»!^L^ (C^- -^z^-^*^*
DATE- 02/13/09
Laboratory Director
Certfication numbers: CA NELAP - 021 lOCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004 NY NELAP -11291, UT NELAP - 9166389892, AZ Licensure AZ0719
Name of Accrediting Agency: NELAP/Florida Department ofHealth, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/08, Expiration date: 06/30/09
Air Toxics Ltd. certifies that the test results contained in this report meet all requirements ofthe NELAC standards
This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd
180 BLUE RAVINE ROAD. SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020
Pane 2 of 29
I I I I I I I I I I I I I I I I I I I
m A i r ' iToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
LABORATORY NARRATIVE Modified TO-15 FuU Scan/SIM
MWH Americas, Inc. Workorder# 0901612A
Four 6 Liter SuiTuna Special (SIM Certified) samples were received on January 31, 2009. The laboratory performed analysis via modified EPA Method TO-15 using GC/MS in the Full Scan and SIM acquisition modes. The method involves concentrating up to 1.0 liters of air. The concentrated aliquot is then flash vaporized and swept through a vvater management system to remove water vapor. Following dehumidification, the sample passes directly into the GC/MS for analysis.
This workorder was independently validated prior to submittal using 'USEPA National Funcfional Guidelines' as generally applied to the analysis of volatile organic compounds in air. A rules-based, logic driven, independent validation engine was employed to assess completeness, evaluate pass/fail of relevant project quality control requirements and verification ofall quantified amounts.
Method modifications taken to run these samples are sununarized in tlie table below. Specific project requirements may over-ride the ATL modifications.
Requirement ICAL %RSD acceptance critena
Daily Calibration
Blank and standards
Method Detection Limit
TO-15 </=30% RSD with 2 compounds allowed out to < 40% RSD
+- 30% Difference
Zero air
Follow 40CFR PL 136 App. B
.4TL Modifications For Full Scan: 30% RSD with 4 compounds allowed out to < 40% RSD
For SIM: Project specific; default criteria is </=30% RSD with 10% of compounds allowed out to < 40% RSD
For Full Scan: </= 30% Difference with four allowed out up to </=40%.; flag and narrate oulliers
For SIM: Project specific; default criteria is <l= 30% Difference with 10% of compounds allowed out up to </=40%.: flag and narrate outliers
Nitrogen
The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded lOX the calculated MDL m some cases
Receiving Notes
There were no receiving discrepancies.
Analvtical Notes
As per project specific client request the laboratory has reported estimated values for target compound hits that are below the Reporting Limit but greater than tlie Method Detecfion LimiL Concentrations that are below the level at which the canister was certified (at the Reporting Limit) may be false positives.
Page 3 of 29
^Ai i " ' IToxicsLTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
The reported LCS/LCSD for MSD-W has been derived fi-om more than one analytical file.
Dilution was performed on sample BL02-SS-E001 due to the presence of high level non-target species.
The results samples BL04-SS-E001, BL04-SS-W001, and BL02-SS-W001 in this report were acquired fixjm two separate data files originating fixwn the same analytical run. The two data files have the same base file name and are differentiated with a "sim" extension on the SIM data file.
Definition of Data Oualifving Flags
Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction noi
perfonned). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector rl-File was requantified for the purpose of reissue
Page 4 of 29
yaAir ' Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
Client Sample ID: BL04-SS-E001
LabID#:090I612A-01A
Compound
Naphthalene
Client Sample ID: ; BL04-SS-E001
LablD#:0901612A-01B
Compound
Benzene Toluene Ethyl Benzene m, p-Xylene o-Xylene •
Client Sample ID: BL04-SS-W001
Lab[D#:0901612A-02A
Compound
Naphthalene
Client Sample ID: BL04-SS-W001
Lab \Dft: 0901612A-02B
Compound
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
Client Sample ID: BL02-SS-E001
LabID#:0901612A-03A
Compound
Toluene Ethyl Benzene
Rot. Limit (ppbv)
0 80
Rpt. Limit (ppbv)
0.080 0.032 0.032 0 064 0.032
Rpt. Limit (ppbv)
0.78
Rot. Limit (ppbv)
0.078 0.031 0.031 0 062 0.031
Rot. Limit (ppbv)
730 730
Amount (ppbv)
0.052 J
Amount (ppbv)
0 066 J 0 056
0.016 J 0.030 J 0.013 J
Amount (ppbv)
0.074 J
Amount (ppbv)
0.075 J 0 087
0.019 J 0 042 J 0.019 J
Amount (ppbv)
440 J 240 J
Page 5 of 29
RDt. Limit (uG/m3)
42
Rpt. Umit (uG/m3)
0 26 0.12 0.14 0 28 0 14
Rpt. Limit (uG/m3)
4 1
RPL Limit (uG/m3)
0.25 0 12 0.13 0.27 0.13
Rpt. Limit (uG/m3)
2800 3200
Amount (uG/m3)
0 27 J
Amount (uG/m3)
0 21J 0 21
0.069 J 0.13J
0 057 J
Amount (uG/m3)
0.39 J
Amount (uG/m3)
0.24 J 0 33
0.083 J 0.18J
0 082 J
Amount (uG/m3)
1700 J 1000 J
m A i r ' ^ToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS
Client Sample ID: BL02-SS-E001
Lab \Dtt: 0901612A-03A m.p-Xylene
o-Xylene
730
730
980
240 J
3200
3200
4200
1000 J
Client Sample ID: BL02-SS-E001 Lab Duplicate
Lab ID#: 0901612A-03AA
Roi Compound (f
t. Limit ppbv)
730 730 730 730
Amount (ppbv)
590 J
260 J 1200 360 J
Rpt. Limit (uG/m3)
2800
3200 3200 3200
Amount (uG/m3)
2200 J
1100J 5300 1600 J
Toluene Ethyl Benzene m.p-Xylene o-Xylene
Client Sample ID: BL02-SS-W001
LablD#:09016l2A-04A
Compound Rpt. Limit
(ppbv) Amount (ppbv)
Rpt. Limit (uG/m3)
Amount (uG/m3)
Naphthalene 0 72 0 040 J 3.8 0 21J
Client Sample ID: BL02-SS-\V001 Lab Duplicate
LabID#:0901612A-04AA
Rot. Limit Compound (ppbv)
Amount (ppbv)
RpL Limit (uG/m3)
Amount (uG/m3)
Naphthalene 0 72 0.026 J 3.8 0.14J
Client Sample ID: BL02-SS-W001
Lab ID#: 0901612A-04B
Compound R o t Limit
(ppbv)
0 072 0.029 0 029
0 058 0.029
Amount (ppbv)
0 14 0 20 0 051 0.13 0.048
RDL LimH (uG/m3)
0.23 0.11 0.12
0 25 0.12
Amount (uG/m3)
0.45 0.74 0.22
0.55 0 21
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xylene
Page 6 of 29
I I I I I I
^ , A i r " Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
Client Sample ID: BL02-SS-W001 Lab Duplicate
LabID#:0901612A-04BB Rot. Limit Amount Rot. Limit Amount
Compound (ppbv) (ppbv) (uG/m3) (uG/m3)
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xylene
0.072 0.029 0 029 0.058 0.029
0.12
0 20 0 057 0.14 0 050
0 23 0.11 0 12 0.25 0 12
0 39 0 75 0 24 0 59 0.22
Page 7 of 29
r^g^Air Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL04-SS-E001
Lab ID#: 0901612A-01A
MOPrFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020509 1.61
Date of Collection: 1/28/09 Date of Analvsis: 2/5/09 04:36 PM
Compound Rot. Limit
(ppbv) Amount (ppbv)
RDL Limit (uG/m3)
Amount (uG/m3)
Naphthalene 0 80 0 052 J 4.2
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery
0.27 J
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
109
96
96
70-130
70-130
70-130
Page 8 of 29
m A i r ' \ToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL04-SS-E001
LabID#:0901612A-01B
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020509sim 1.61
Date of Collection: 1/28/09 Date of Analvsis: 2/5/09 04:36 PM
Compound R o t Limit
(ppbv)
Amount (ppbv)
Rot. Limit (uG/m3)
0.26 0.12 0.14 0.28 0.14
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xylene
0 080 0.032 0.032 0.064 0.032
0.066 J 0.056
0.016 J 0.030 J 0013J
0.21 J 0 21
0.069 J 0.13J
0.057 J
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates '/oRecovery Metliod Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
111 100 96
70-130 70-130 70-130
Page 9 of 29
WL^ir ' iToxicsLTo.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL04-SS-W001
Lab IDft: 0901612A-02A
MODIFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020S10 1.55
Date of Collection: 1/28/09 Date of Analvsis: 2/5/09 05:16 PM
Compound Rot. Limit
(ppbv) Amount (ppbv)
RDL Limit (uG/m3)
Amount (uG/m3)
Naphthalene 0.78 0.074 J 4.1
J = Estimated value Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery
0.39 J
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
103 93
100
70-130
70-130
70-130
Page 10 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL04-SS-W001
Labn)#:0901612A-02B
MODinED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020510sim 1.55
Date of Collection: 1/28/09 Date of Analvsis: 2/5/09 05:16 PM
Compound R D L Limit
(ppbv) Amount (ppbv)
RDL Limit (uG/m3)
0 25 0 12 0 13 0 27 0 13
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xyiene
0.078 0.031 0.031 0.062 0.031
0.075 J 0 087
0.019 J 0 042 J 0.019J
0 24 J 0.33
0.083 J 018J
0.082 J
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates yoRecovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
105
94
101
70-130
70-130
70-130
Page 11 of 29
m A i r ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL02-SS-E001
LabID#:0901612A-03A
MOPniED EPA METHOD TO-15 GC/MS
File Name: DII. Factor:
W020610 146
Date of Collection: 1/28/09 Date of Analvsis: 2/6/09 11:40 AM
Compound R D L Limit
(ppbv) Amount (ppbv)
RDL Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
730 730 730 730 730 2900
Not Detected
440 J
240 J
980 240 J
Not Detected
2300
2800
3200
3200
3200
15000
Not Detected
1700 J
1000 J
4200
1000 J
Not Detected Naphthalene
J = Estimated value Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
105
103
99
70-130
70-130
70-130
Page 12 of 29
r/mAir ^ Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL02-SS-E001 Lab Duplicate
Lab ID#: 09016I2A-03AA
MODIFIED EPA METHOD TO-IS GC/MS
File Name: DII. Factor:
W020611 146
Date of Collection: 1/28/09 Date of Analvsis: 2/6/09 12:06 PM
Compound R D L Limit
(ppbv) Amount
(ppbv)
RDL Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
730
730
730
730
730
Not Detected 590 J 260 J 1200 360 J
2300
2800
3200
3200
3200
Not Detected 2200 J 1100J 5300
1600 J
Naphthalene 2900 Not Detected 15000 Not Detected
J = Estimated value Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
105
102
97
70-130
70-130
70-130
Page 13 of 29
m A i r ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL02-SS-W001
Lab ID#: 0901612A-04A
MODIFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020511 1.44
Date of Collection: 1/28/09 Date of Analvsis: 2/5/09 05:50 PM
Compound R D L Limit
(ppbv) Amount (ppbv)
RpL Limit (uG/m3)
Amount (uG/m3)
Naphthalene 0.72 0 040 J 38
J = Estimated value. Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery
0.21 J
Method Limits
1,2-Dichloroethane-d4 Toluene-dS 4-Bromofluorobenzene
101
95
96
70-130
70-130
70-130
Page 14 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL02-SS-W001 Lab Duplicate
LabID#:0901612A-04AA
MODIFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: Dil. Factor:
Z020512 1.44
Date of Collection: 1/28/09 Date of Analvsis: 2/5/09 06:34 PM
Compound R D L Limit
(ppbv) Amount (ppbv)
RDL Limit (uG/m3)
Amount (uG/m3)
Naphthalene 0 72 0 026 J 38
J = Estimated value Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery
O U J
Method Limits
1,2-Dichloroethane-d4
Toluene-d8 4-Bromofluorobenzene
109
93
93
70-130
70-130
70-130
Page 15 of 29
m A i r ' l7<3!X/CStra
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL02-SS-W001
LablD#:0901612A-04B
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: Dil. Factor:
z020511sim 1.44
Date of Collection: 1/28/09 Date of Analvsis: 2/5/09 05:50 PM
Compound Rot. Limit
(ppbv) Amount (ppbv)
RDL Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
0 072
0.029
0.029
0 058
0.029
0 14
0 20
0.051
0 13
0.048
0 23
0.11
0 12
0 25
0 12
0.45
0 74
0 22
0.55
0 21
Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates %Recovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
102
98
99
70-130
70-130
70-130
Page 16 of29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL02-SS-W001 Lab Duplicate
Lab ID#: 0901612A-04BB
MODIFTED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020512sim 1.44
Date Of Collection: 1/28/09 Date of Analysis: 2/5/09 06:34 PM
Compound R D L Limit
(ppbv) Amount (ppbv)
RoL Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m, p-Xylene o-Xylene
0 072
0.029
0.029
0.058
0.029
0.12
0.20
0.057
0 14
0 050
0 23
0.11
0 12
0.25
0.12
0.39
0.75
0.24
0.59
0.22
Container Type: 6 Liter Summa Special (SIM Certified)
Surrogates VoRecovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
110
96
96
70-130
70-130
70-130
Page 17 of 29
r/mAir ' ^ToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0901612A-05A
MODIFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020505a 1.00
Date of Collection: NA Date of Analvsis: 2/5/09 01:09 PM
Compound R D L Limit
(ppbv) Amount (ppbv)
RDL Limit (uG/mS)
Amount (uG/m3)
Naphthalene 0.50 0.16 J 2.6 0.87 J
J = Estimated value Container Type: NA - Not Applicable
Surrogates %Recovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
95
95
92
70-130
70-130
70-130
Page 18 of 29
^ . A i ' ' ' iToxicsLTD
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0901612A-05B
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020505sima 1.00
Date of Collection: NA Date of Analvsis: 2/5/09 01:09 PM
Compound R D L Limit
(ppbv) Amount
(ppbv)
RDL Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m.p-Xylene o-Xylene
J = Estimated value. Container Type: NA - Not Applicable
Surrogates
1,2-Dichloroethane-d4
Toluene-d8 4-Bromofluorobenzene
0.050 0 020 0.020 0.040 0.020
0.024 J 0 0055 J 0 0022 J 0.0043 J 0.0022 J
'/oRecovery
96 100 94
0.16 0.075 0 087 0 17 0 087
0 075 J 0.021 J 0 0096 J 0019J
0 0094 J
Method Limits
70-130
70-130 70-130
Page 19 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
LabID#:0901612A-05C
MODIFIED EPA METHOD TO-IS GC/MS
File Name: DII. Factor:
w020609a 1.00
Date of Collection: NA Date of Analvsis: 2/6/0910:12 AM
Compound R D L Limit
(ppbv) Amount (ppbv)
RDL Limit (uG/m3)
Amount (uG/m3)
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
5.0 50 50 5.0 50
Not Detected Not Detected Not Detected Not Detected Not Detected
16 19 22 22 22
Not Detected Not Detected Not Detected Not Detected Not Detected
Naphthalene
J = Estimated value Container Type: N A - Not Applicable
Surrogates
20 15J 100
'/oRecovery
78 J
Method Limits
1,2-Dichloroethane-d4
Toluene-d8 4-Bromofluorobenzene
102
100
97
70-130
70-130
70-130
Page 20 of 29
' IToxicsLTD. AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
LabID#:0901612A-06A
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020502 1.00
Date of Collection: NA Date of Analvsis: 2/5/0910:37 AM
Compound '/oRecovery
Naphthalene
Container Type: NA • Not Applicable
Surrogates '/oRecovery
98
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
102
103
101
70-130
70-130
70-130
Page 21 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: C C \
LablD#:090l612A-06B
MODEFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020502sim 1.00
Date of Collection: NA Date of Analvsis: 2/5/0910:37 AM
Compound '/oRecovery
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
82 88 96 99 104
Container Type: NA - Not Applicable
Surrogates '/oRecovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
105
103
102
70-130
70-130
70-130
Page 22 of 29
m A i r " iToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: CCV
LabID#:090l612A-06C
MODinED EPA METHOD TO-IS GC/MS
File Name: DII. Factor:
W020603 1.00
Date of Collection: NA Date OfAnalysis: 2/6/09 07:30 AM
Compound '/oRecovery
Benzene Toluene Ethyl Benzene m, p-Xylene o-Xylene
107
109
106
106
106
Naphthalene
Container Type: NA - Not Applicable
Surrogates '/oRecovery
99
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
98
102
99
70-130
70-130
70-130
Page 23 of 29
m A i r ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
LabID#:0901612A-07A
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020503 1.00
Date of Collection: NA Date of Analvsis: 2/5/09 11:27 AM
Compound '/oRecovery
Naphthalene
Container Type: NA - Not Applicable
Surrogates '/oRecovery
100
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
102
103
96
70-130
70-130
70-130
Page 24 of 29
m A i r ' ^ToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSD
LabID#:090l612A-07AA
MODIFIED EPA METHOD TO-IS GC/MS SIM/FULL SCAN
File Name: DII. Factor:
Z020504 1.00
Date of Collection: NA Date of Analvsis: 2/5/09 12:08 PM
Compound '/oRecovery
Naphthalene
Container Type: NA - Not Applicable
Surrogates '/oRecovery
103
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
102
102
99
70-130
70-130
70-130
Page 25 of 29
r/mAir ' ^Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
LabID#:0901612A-07B
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020503sim 1.00
Date of Collection: NA Date of Analvsis: 2/5/0911:27 AM
Compound '/oRecovery
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
86
94
96
99
104
Container Type: NA - Not Applicable
Surrogates '/oRecovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
102
105
97
70-130
70-130
70-130
Page 26 of 29
^ . A i r ' WoxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSD
LabID#:09016l2A-07BB
MODIFIED EPA METHOD TO-15 GC/MS SIM/FULL SCAN
File Name: DII. Factor:
z020504sim 1.00
Date of Collection: NA Date of Analvsis: 2/5/09 12:08 PM
Compound '/oRecovery
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
84
93
94
98
102
Container Type: NA - Not Applicable
Surrogates '^Recovery Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
103
104
102
70-130
70-130
70-130
Page 27 of 29
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab ID#: 0901612A-07C
MODIFIED EPA METHOD TO-IS GC/MS
File Name: DII. Factor:
W020605 1.00
Date of Collection: NA Date of Analvsis: 2/6/09 08:25 AM
Compound '/oRecovery
Benzene Toluene Ethyl Benzene m, p-Xylene o-Xylene
102
106
104
105
108
Naphthalene
Container Type: NA - Not Applicable
Surrogates '/oRecovery
111
Method Limits
1,2-Dichloroethane-d4 Toluene-d8
4-Bromofluorobenzene
94
103
99
70-130
70-130
70-130
Page 28 of 29
I I I I I I I I I I I I I I I I I I I
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSD
LabID#:0901612A-07CC
MODIFIED EPA METHOD TO-15 GC/MS
File Name: DII. Factor:
W020606 1.00
Date of Collection: NA Date OfAnalysis: 2/6/09 08:43 AM
Compound '/oRecovery
Benzene Toluene Ethyl Benzene m,p-Xylene o-Xylene
102
104
107
106
109
Naphthalene
Q = Exceeds Quality Control limits. Container Type: NA - Not Applicable
Surrogates '/oRecovery
1410
Method Limits
1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluoroben2ene
91
101
98
70-130
70-130
70-130
Page 29 of 29
TmzmBLTm Sample TransportaSion Notice R«tiriC(uifchliig^it'ri(iiure on this document indicates that sampia Is iieinn&hippivirn on mpfiitnce with 180 BDLUE RAVINE R O A D , SUITE B »li qpptic»3e bral. Stale, Federal, national, a id mternaijanai laws, regulatiois and orcinances o* FOLSQEUl C & 95630*4719
P anr/kind. Air Toxics Limited assumes no liabilrtywitltr»sp8ct to tho collaciion, handl-iig or&hipplrg / o i f t i oft lL. innA PAY iofi fA QflS-in<!Mi Dt these earrpfes Relinquishing aigiauro atea iivlicat«« tgnsj-nent to t»oc Harmless, d&fsnd, ^ * ^ ' * ' *» '»" ' ' ' * ' " • " * * y ^ ^ ! WJ^-iUZU
C i n l A D M - O F - C y S T O D Y R E C O R D ^ ^ indcmnly AE? TCKICS Umi-jed sgQirat any cJaui. deirand, cr £ction. of any tend rala:ed to -he p I ^ i I coltecHor, handling or Slipping Of 3amplB3. D O T Horn \4 (SD3i 467- '^22 ^ ^ ^ ^ — — ^^ —Jt—
Project Manager _ ^ ^ ^ i
Collected by: iPrntaifSigiO
Company j / ^ - ! * ' ^
Phone 0 ^ - Z S a ^ e , Z 3 ^
Projecl Info:
Email &yui».:.hzmmar^C^hb^^l >fcd <-«** .o t . ^ a A . -,-M _ ^ .Z Proiect # f i / 7 3 7 ^ s £ ) / a ^
t * ^^ /kA l^>y h / J f t d ^
.City Ut^MjusJAJe staie^^y H m ^ ^ M ^
LabLD. Field SampOe i.D. (Location)
e } \ P ^ ^ L d ^ S S - ^ 0 O (
Can# Date
of Colleclion
3*1371^ Opinio'}
Project Ma-ne Or f i f t / t , j ^ ^ i ^ i ^ _ £ _
Turn Around Time:
1^ Normal
QlFitJ&h
(P Time of Collection Analyses Requested
/ n o ^ /i--/5r ^ / ^ . - ^ s s x e ^ ^ i \ _ j o 31 j>^:x
Lsb L>(Ba O f l ^
Pressurized by:
Date;'
Pressurization Gas:
N, He
Canister Pressur&'Vaciiuim
Inhial X -inal ; Receipt Final
/92Aft Bt^o-i-gS - N ^ P I 3^o» Q3A£? g ^ 4:? -^:5 - g « ^ ^:??H (94Mv9i-i>j - ss ' ir oo)
a*f^»hf I f&T^'l
&iI^1flo'] i ' ^ 31 -I ( F { %
&/i^h'^ Igife? \-Bti3S'^2S
^ ^ ^ ^ ^ ^ : ^ ^ ^
RellncLiehedby. [signature i DatcTlmo
RelinqL i$h ?d ty' {sigruitjre.i Date,' • ime
ReJinqLishsd by: (signst imi Dat^inmc
Received :>/: (signaturs) D«t3/Tims
O'YD^^^^*^^^^ \/v h f f/J" Roc«ived by: (signature) Dat&Time
Received by (signature) Dste/Tjme
JNotes: W f ^ t c f - f n t ^ f i / ^ t f ^ » t i , a n ^ a-cha^
htJk/fS.
"Lab-- Shipper Name ' Air Bi l l * •" •: Jemg-CC) Conditi ori- Cusiody Seals Intact? Work Order*
Use Only ^^fif--^_ Auv
^ ^ Yes No eion«
-onr laiC BCtH
LIZI (ZZI czz] 1=1 : ZZI ZZI ZZI
TABLE 2-L
A N A L Y n C ^ PARAMETERS 0901612
Analyte Sump 1 ' ater Sample Analy tifsil Meduid
Sntatob Soil and Soil Gas Sdunitle Analytical Metbrvl
Indoor Air and. Outdftor Air JSample Analytical MediDd
VOC COPCs
Benzene
Ethylbetoese
Tolueite
Xylenes. Total
SW-946 8260 Modified TO-15 High 'Low Level 'k- ith SIM
S'W-84< S2ti0 ModifiedTO-i5 Hi^t/Low Level -Kith SIM
SW-S4fi 8260 Modifiod TO-15 I£^i/Low Level -KiOt STM
SW-!l*b 82M Modif cd TO-15 Hi^i/Low Level with SIM*
Modified TO-15 High/Low Level vritti SIM
ModtTied TO- IS ICgtk/Low L&vel witb S3M
Modified TO-li) HlgM jnw I^vel with SIM
Modified TO-15 High/Low Level with SIM*
Nuphttialene SW-346 82150 Mudilicd TO-15 Luw Level Mndified TO-15 Low T^vei
Leak Test Tracer Ga&
Helium NA idocificd ASTM D-194S NA
NoMSi AiiTM D-194;b = Standard'/ est Mettiod Anafysis of Afatwvt Ooi by Gas Lhrometography- (AiHencaa Society loi Tesbng anc Materuds, 2007). NA SESf
TO-15
VOC COPC
= Not applicable. = Selected ion monilxiniig. = Test Metfuids for EuHttating Solid Waste, SW-846, PhyucaL'Cheiaical Methods, 3"* Ediiiocu WashirigoB. D.C.. (United States
EaviroamenPiLl t%oi»ctio& Agency (EPA). 19&6). = Compendhim of Methods for tbe DietenniDation of Toxic Organic Compounds in Ambient Air. Second Edition. Compendium Meihod
TO-IS. Detetttumtion of Volatiin Otgaruc Ompownds. (VOCs) iri Air Collected In StfCcially-Prepared Canisiers a id Analysed by Cas ChmmatogmphyMass Spectrometry (GC/MS) (EPA, 1999).
= Volaule oigiiiiicainipuundouniUiluciiLorpouailijtluunirni. s: Tlic reported o-xylenc and ni,p-xylCQC i^mcx icsults itpoilcd by ttus metliod will be aiunmcd to calculate total xylene conccntiatioiiak
P^agelof 1
090161£( TABLE 4-1
VAPOR INTRUSION 11NV FSTTRATION ACTION LEVELS
Sump Water
AiuiLyte Method Kcportlnft
L imi t
Subtilah Slill CAM, Soil Gas, and Indoor Air
Tui^et Indoor Air Cuiu-Kiitrqlicii *
riidoor Air
LoMvr Explosive Limit
Bcozaie
IJLliylbenTieiie
>tapfalhalcne
'['oluene
Xyliincs, ToUil
Total Flammable Oas
1.0
1.0
1.0
1.0
2.0
NA
0.11
o.y?
0.072 / 7.2 "
5,2(10
100
NA
0.098
0.22
0.01.17 y 1.37'
i,3S0
2%
NA
NA
NA
NA
NA
NA
Ton PtTvwii
Notes: ^ = To comply with prescribed cdiiccr risk of lE-06 aiul noii-cqiicer tatj^t hazard indc.\ ot 1 tor rwidential
inhaliitiun expos Lire icenai'io. Tlie targpt indoor all ranoencratioiift tm. provided in tfie Residential Air Siippoiliiig Table ia tJie September 12, 200» \asion of Resio'tal Screening Lefels fnr Chemical Contutninams al Superfimd Siies (EPA, 2008).
** s The lurgct indoor nil' couceJitration foi naphlhalciic ccij're$pi?nding to lt-06 c<i.ieuf risk (0.077 fig/n\*") in nvn smiern nrmagiiiLiide !>n)allef lluui tli& Idboratoiy metliod reporting limit I'cf n<iphLhalene by Modified TO-15 Low Level (2.62 ns/n^'). as li-ited in Table/l--! of this (jAFP, llierelrire, 7.2 jis'in*, whL'h corresponds to a caiu:er riak ;rf 1E-04-, will bt iiwd nt, vu ncJ.ioii 1e,vel foe subj lah »ol] ga*. ind(Mjr ah", iind uLLidoor air oai^htbalenccnnccnlrutiLinji during tliis vapor inlrusion investigation.
jig(L p Micro£iflmi» psT lil^r llg'ln^ = MicrcB''a'"''s) P=r tiubie meter. NA - Not applicable. KE - Not esiablijh«<f. ppbv = Hai't]($) per bilbtm voluitic.
Page 1 of 1
TABLK4-4
MKTHOD KEVOKTlNt; LlMl'lti
O 9 O I 6 I S
Annlytrrni Mi'thitd
Modified T 0 ' \ 5 High/Low Level wiUi S M Modified TO-15 High/Low Level witb SIM
Modified TO-15 Low Level Modified TO-15 Higli/Tijw Level with SIM Modified TO-15 Higli/Low Level witli SIM Modified TO-15 High/Low L<?vel witb SLM
Modihc<IA!>TMO-1945
SW-846 8260B SW-846 8260B SV/-R46 82606 SW 846 8260B SW.846 8260B
Aiinlylc
Bisnzene fiiJiyllen^ene Naplitbaieite Tuluerift ititp-Xyiciie o-Xylciic
Helium
Benzene Hthylbenzuno. Naphthalene Toluene Xylenes. T[ilal
(J16/L)
NA NA NA NA NA NA
NA
1.0 10 1.0 1.0 2.0
Mrthfld Rep
Wm')
0.16 0.087 2.62 0,075 0.17 0.0«7
NA
NA NA NA NA NA
nrting Limit"
0.050 0,U2U • (1.5(1 U.Q20 0,040 0,020
NA
NA NA NA NA NA
TcfCCnt
NA NA NA NA NA NA
0,050
NA NA NA NA NA
Notes:
' = Rcpoi'ung Itniiu ai« in;trunnent- und tiiue-spEcific (based on lilbOJ'titory RTaiidiird operating pnouudiirc achcduk: fur iipdAte). L^borA'x>ry will use most current reporting limils. The vnluee llftled in this table urs adriaury only. iSiib»lnb «otl gan. soil g(ui, indoor air, aiid outdoor abr SAm))le mediod reporting limita aSBLicic a one-][(er Sfimple <ina'y«k vnlume friini a .lix-iiier canistei", aoliial lepoftiiig iiinlt> will be higher depending; on the coflis'.cr dilution thstor ond/or sample mmtix. etVecia.
• llfi/I' = Micrograni(H} per Liber,
Hgfm^ = MicrogramCs) per cub ir. merev.
ppbv = Pai t per bi 11 ion M^lumc
Modified ASTM lMfM5 "SUindard Test Metlwd Analysis of Natural Gas by Oan ChroTnat^graphy, American >Scx:iety for T«?jitlng andMatniaU (A-STM, 7007) m mmlified h> ATL,
Mndified TO-15 « Crmpendium af Metfie/ds Jor tlur. Detvimlnatlott of Toxic Orftanic Cantpoundi! In An\iiient Air. Second Edition. Co/apendimn Method TO-tS. Determination vf Vvlalile Ofsetnic Cmnpoundji (VOOt) in Atr Collected it> SpArmHy-Prepanxi Cunitter.s And Armlyied liy Ons Chroinatogrufiliy/iVass Spe.(,trometfy (CC/MS) (United Stiitcd Envii'ontncnwl Protection Ageney [El'A], 1999) asmoditicdby ATL.
SW-846 s: Tcjt Methods for Evaluating Solid Vfaxtc, SW-846. Pliykical/Cbeiniical Methods, 3** Edition. Wftshiflfcton. D . C (UFA, 1986).
SIM = Seiected ion jnonitoring.
NA - Not iippltcabk.
Pajie I of 1
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL U\BORATORY
2/12/2009
Mr. Randy Kroneman
MWH Americas, Inc.
11153 Aurora Avenue
Des Moines IA 50322
Project Name: Clinton, IA FMGP Project #: 1914390.0102 Workorder #: 0901612B
Dear Mr. Randy Kroneman
Ttie following report includes the data for the above referenced project for sample(s) received on 1/31/2009 at Air Toxics Ltd.
The data and associated QC analyzed by Modified ASTM D-1945 are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative.
Thank you for choosing Air Toxics Ltd. for you air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Brandon Dunmore at 916-985-1000 ifyou have any questions regarding the data in this report.
Regards,
^ J ^ i c f M ^ t C- v_-^/c*irf«e_
Brandon Dunmore
Project Manager
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 .FAX (916) 985-1020
Hours 8:00 A.M to 6:00 P.M. Pacific
I I I I I I I I I I I I I I I I I I I
mAir ' XToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
WORK ORDER #: 0901612B
Work Order Summary
CLIENT:
PHONE:
FAX:
DATE RECEIVED: DATE COMPLETED:
Mr. Randy Kroneman MWH Americas, Inc. 11153 Aurora Avenue Des Moines, IA 50322
515-253-0830
515-253-9592
01/31/2009
02/12/2009
BILL TO: Accounts- CO Payable MWH Americas, Inc. POBox 6610 Broomfiekl, CO 80021
P.O.# 1914390.0102
PROJECT # 1914390.0102 Clinton, IA FMGP
CONTACT: Brandon Dunmore
FRACTION # OIA 02A 03A 04A 05A 06A 06AA
NAME BL04-SS-EOOI BL04-SS-W00I BL02-SS-E001 BL02-SS-W00I Lab Blank LCS LCSD
TEST Modified Modified Modified Modified Modified Modified Modified
ASTM D-1945 ASTM D-1945 ASTM D-1945 ASTM D-1945 ASTM D-1945 ASTM D-1945 ASTM D-1945
RECEIPT VAC/PRES.
5.0 "Hg 4.0 "Hg 2.5 "Hg 2.0 "Hg
NA NA NA
FINAL PRESSURE
5 psi 5 psi 5 psi 5 psi NA NA NA
CERTIFIED BY. C ^ ^ ^ 2 X ! ^ e J < ^ -^-<
DATE: 02/12/09
Laboratory Director
Certfication numbere: CA NELAP - 021 lOCA, LA NELAP/LELAP- AI 30763, NJ NEL.A.P - CA004 NY NELAP -11291, UT NELAP - 9166389892, AZ Licensure AZ0719
Name of Accrediting Agency: NELAP/Florida Department ofHealth, Scope of Application: Clean Air Act, Accreditation number: E87680, Effective date: 07/01/08, Expiration date: 06/30/09
Air Toxics Ltd. certifies that the test resulls contained in this report meet all requirements ofthe NELAC standards
This report shnll not be reproduced, except in full, without the written approval of Air Toxics Ltd
180 BLUE RAVINE ROAD, SUITE B FOLSOM. CA - 95630 (916) 985-1000 (800) 985-5955 . FAX (916) 985-1020
Page 1 of 11
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
LABORATORY NARRATIVE Modified ASTM D-1945
MWH Americas, Inc. Worl{order# 0901612B
Four 6 Liter Siunnia Special (SIM Certified) samples were received on January 31, 2009. The laboratory performed analysis via modified ASTM Method D-1945 for Helium in natural gas using GC/TCD. The mediod involves direct injection of 1.0 mL ofsample.
Method modifications taken to run these samples are summarized in the table below. Specific project requirements may over-ride the ATL modifications.
Requirement Normalization
Sample analysis
Sample calculation
Reterence Standard
Sample Injection Volume
ASTMD-t945 Sum of original values should not differ from 100.0% by more than 1.0%.
Equilibrate samples to 20-50° F. above source temperature at field sampling
Response factor is calculated using peak height for C5 and lighter compounds
Concentration should nol be < half of nor differ by more than 2 X the concentration of the sample. Run 2 consecutive checks; must agree within 1%.
0.50 mL to achieve Methane linearity.
ATL Modiflcations Sum of original values may range between 85-115%. Normalization of data not perfonned.
No heating ofsamples is performed.
Peak areas are used for all target analytes to quantitate concentrations.
A minimum 3-point linear calibration is performed. The acceptance criterion is %RSD </= 15%. All target analytes must be within the linear range of calibration (with the exception of 02, N2, and C6+ Hydrocarbons).
1.0 mL
Receiving Notes
There were no receiving discrepancies.
Analytical Notes
As per project specific client request the laboratory has reported estimated values for target compound hits that are below the Reporting Limit but greater than the Method Detection LimiL Concentrations that are below the level at which the canister was certified may be false positives.
Definition of Data Oualifving Flags
Six qualifiers may have been used on the data analysis sheets and indicate as follows: J - Estimated value. E - Exceeds instrument calibration lange.
Page 2 of 11
Ai r Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the detection limit M - Reported value may be biased due to apparent matrix interferences.
File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector rl-File was requantified for the purpose of reissue
Page 3 of 11
m A i r ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Summary of Detected Compounds NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
Client Sample ID: BL04-SS-E001
Lab \Dft: 0901612B-01A
Compound Rpt. Limit
m Amount
f/.)
Helium 0 080 0.43
Client Sample ID: BL04-SS-W001
LablD#:0901612B-02A
Compound Rpt. Limit
f/o) Amount
Helium 0.078 0.32
Client Sample ID: BL02-SS-E001
LabID#:0901612B-03A
Compound Rpt. Limit
f/o)
Amount
f/o)
Helium 0.073 0.056 J
Client Sample ID: BL02-SS-W001
Lab 1D#: 0901612B-04A
Compound Rpt. Limit Amount
(%)
Helium 0.072 0.091
Page 4 of 11
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL04-SS-C001
Lab rD#: 0901612B-01A
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
File Name: 9020224b Dateof Collection: 1/28/09 DII. Factor: 1.61 Date of Analvsis: 2/2/09 06:15 PM
Rpt Limit Amount Compound f/o) f/o)
Helium 0.080 0.43
Container Type: 6 Liter Summa Special (SIM Certified)
I I
mAir I mdToxicsLTD
I I I I I I I I I I I I I I I I Page 5 of 11
^ A i r ' ^Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL04-SS-W001
LabID#:090l612B-02A
NATURAL GAS ANALYSIS BY MODIFIED ASTIM D-1945
File Name: 9020225b Date of Collection: 1/28/09 DII. Factor: 1^55 Date of Analvsis: 2/2/09 06:36 PM
Rpt. Limit Amount Compound py f/o)
Helium 0 078 0.32
Container Type: 6 Liter Summa Special (SIM Certified)
Page 6 of 11
I I
mAir I m^ToxicsLTD.
I I
I
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL02-SS-E001
LablD#:09016l2B-03A
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
File Name: 9020226b Dateof Collection: 1/28/09 DII. Factor: 1.46 Date of Analvsis: 2/2/09 07:09 PM
Rpt Limit Amount Compound f/o) f/e)
Helium 0 073 0 056 J
J = Estimated value Container Type: 6 Liter Summa Special (SIM Certified)
Page 7 of 11
m A i r ' IToxicsLTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: BL02-SS-W001
Lab 1D#: 0901612B-04A
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-194S
File Name: 9020227b Date of Collection: 1/28/09 DII. Factor: 1^44 Date of Analvsis: 2/2/09 07:34 PM
Rpt. Limit Amount Compound g ^ f/o)
Helium 0.072 0 091
Container Type: 6 Liter Summa Special (SIM Certified)
Page 8 of 11
I
mAir I s^ToxicsLTD.
I I I I I
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: Lab Blank
Lab ID#: 0901612B-05A
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
File Name: 9020203b Date of Collection: NA DII. Factor: 1^00 Date of Analysis: 2/2/09 08:58 AM
Rpt. Limit Amount Compound ^ f/o)
Helium 0.050 Not Detected
Container Type: NA - Not Applicable
Page 9 of 11
^ A i r ' "Toxics LTD.
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCS
Lab IDft: 0901612B-06A
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
File Name: 9020228b Date of Collection: NA DII. Factor: 1^00 Date of Analysis: 2/2/09 07:57 PM
Compound %Recovery
Helium 104
Container Type: NA - Not Applicable
Page 10 of 11
I
I fkdToxicsLTD.
I I I I I I I I I I I I I I I I
AN ENVIRONMENTAL ANALYTICAL LABORATORY
Client Sample ID: LCSD
LablD#:0901612B-06AA
NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945
File Name: 9020229b Date of Collection: NA DII. Factor: 1^00 Date of Analvsis: 2/2/09 08:23 PM
Compound %Recovery
Helium 105
Container Type: NA - Not Applicable
Page 11 of 11
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I I I I I ; I ' I I I I I ^ I i I ; I i I I I ; I i I i ATTACHMENT D
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ATTACHMENT D
QUALITY ASSURANCE REPORT
This Quality Assurance Report presents results of the validation of analytical data for sunnp water, soil gas, subslab soil gas, and associated quality control (QC) samples collected during the vapor intrusion sample collection activities conducted in September 2008, October 2008, and January 2009 at the former manufactured gas plant in Clinton, Iowa (site). Keystone Laboratories, Inc. (Keystone) of Newton, Iowa performed the water sample laboratory analyses. Air Toxics, Ltd. (ATL) of Folsom, California performed the soil gas and subslab soil gas laboratory analyses. The water samples were analyzed for volatile organic compounds (VOCs) by SW-846 8260B. The soil gas and subslab soil gas samples were analyzed for contaminants of potential concern benzene, ethylbenzene, toluene, m,p-xylene, and o-xylene (BETX) and naphthalene by ATL Modified EPA TO-15; and helium tracer gas by ATL Modified ASTM D-1945.
The analytical results were evaluated against project-specific data quality objectives (DQOs), which are quantitative and qualitative statements that specify data quality, and are expressed in terms of the following data quality indicators (DQIs): precision, accuracy, representativeness, comparability, completeness, sensitivity, and traceability. This data evaluation is presented in terms of these DQIs and is generally based on applicable portions of the Contract Laboratory Program National Functional Guidelines for Organic Data Review (United States Environmental Protection Agency [USEPA], 1999); the QC limits presented in the laboratory method-specific standard operating procedures (SOPs) and analytical reports; and the December 2008 Focused Remedial Investigation Work Plan Addendum (2008 Rl Work Plan Addendum). The analytical data were verified, validated, and qualified based on results of the following QC parameters and samples, where applicable:
Sample preservation. Sample container certification. Sample container initial and final vacuum measurements. Analytical holding times. Trip blank samples. Method blank samples. Initial calibration. Initial calibration verification standards. Continuing calibration verification standards. Mass tune standards. Surrogate spikes. Internal standards. Matrix spike samples (MSs). Matrix spike duplicate samples (MSDs). Laboratory control standards (LCSs). Laboratory control standard duplicates (LCSDs). Reporting limits. Laboratory duplicate samples.
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The following discussions describe how the data were validated for this project and identify data that have associated QC results outside of acceptance criteria. Data qualified based on results of the data validation are presented in Table D-1. Quality control parameters outside acceptance criteria that did not generate qualified data are presented in Table D-2. Data validation forms are included in Exhibit 1.
1.0 COMPLETENESS EVALUATION
Completeness is a measure of the amount of valid data obtained from a measurement system relative to the amount of data scheduled for collection under correct, normal conditions. Completeness measures the effectiveness of the overall investigation in collecting the required samples, completing the required analyses, and producing valid results.
1.1 Sampling Completeness
Each investigative sample was collected as specified in the 2008 Rl Work Plan Addendum. Sampling completeness for this project is 100 percent.
1.2 Analytical Completeness
Analytical completeness was evaluated using the following equation:
Number of Valid Data Points Completeness = X100
Total Number of Measurements
Where: The number of valid results is the total number of analytical measurements considered usable (not rejected ["R" flagged]) based on the precision, accuracy, and representativeness evaluations).
Analytical completeness for this project is 100 percent.
1.3 Completeness Summary
Each sample was collected and analyzed as scheduled in the 2008 Rl Work Plan Addendum. Based on results of the data validation described in the following paragraphs, all data are considered valid as qualified, resulting in 100 percent analytical completeness for this project.
2.0 REPRESENTATIVENESS EVALUATION
Representativeness is a qualitative expression of the degree to which sample data accurately and precisely represent a characteristic of a population, a sampling point, or an environmental condition. Representativeness is maximized by ensuring, for a given task, the number and location of sampling points, and the sample collection and analysis techniques are appropriate for the specific investigation; and the sampling and analysis program provides information reflecting "true" site conditions.
Laboratory data were evaluated for representativeness by assessing compliance with specified analytical criteria in the 2008 Ri Work Plan Addendum and laboratory SOPs, sample container criteria, and holding time criteria.
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2.1 2008 Rl Work Plan Addendum and Laboratory SOP Compliance
Soil gas and subslab soil gas samples were collected from the locations and analyzed by the methods specified in the 2008 Rl Work Plan Addendum.
2.2 Sample Preservation
Water sample preservation is achieved by method-specific addition of chemical preservatives to sample containers and/or maintaining method-specific sample temperatures to retard biological action, retard hydrolysis, and reduce sorption effects. Representativeness was evaluated in terms of the method-established sample preservation acceptance criteria presented in the laboratory SOP. The sample preservation for VOC water samples is a plH value less than 2 and a temperature of 4° Celsius (°C) ±2 "C. Each water sample met the established sample preservation criteria.
Soil gas and subslab soil gas sample preservation is achieved by securing the sample canister so that air does not enter the canister before or after sample collection. Representativeness was evaluated by measuring and comparing the canister vacuum after receipt from lab and before sample collection, and measuring and comparing the canister vacuum after sample collection with the canister vacuum before sample analysis, as indicated in Table D-3. Each soil gas and subslab soil gas sample met the established sample preservation criteria
2.3 Holding Time
Holding time reflects the length of time after sample collection that a sample or extract remains representative of environmental conditions. Depending on the analysis, either one or two holding times were evaluated. For those analyses that do not require sample extraction, only one holding time was evaluated (the length of time between sample collection and sample analysis). For analyses that require sample extraction prior to analysis, two holding times were evaluated (the length of time from sample collection to sample extraction and the length of time from sample extraction to sample analysis). Data for samples that were extracted and analyzed within holding time criteria are considered representative. Representativeness was evaluated in terms of the method-established holding time acceptance criteria presented in the laboratory SOP. For samples that were extracted or analyzed outside of holding criteria, the sample data are qualitatively evaluated to determine the potential effect of the holding time exceedance on sample representativeness. The holding time for the VOC water and associated water QC samples is 14 days from collection to analysis. The holding time for the soil gas and subslab soil gas samples is 30 days from collection to analysis. The holding time for each of the samples was met.
3.0 ACCURACY EVALUATION
Accuracy is a measure of the bias of a method or the level of agreement between a measurement and a known true value. Laboratory accuracy was evaluated using the initial calibration, initial and continuing calibration verification, mass tune standard, blank, surrogate, internal standard, MS/MSD, and LCS results.
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3.1 Initial Calibration
Initial calibration demonstrates analytical instrumentation is capable of acceptable performance at the beginning of an analytical run and of producing a linear calibration curve. Accuracy was evaluated in terms of the method-established initial calibration relative standard deviation and correlation coefficient acceptance criteria presented in the laboratory SOP. The initial calibration results met the established criteria.
3.2 Calibration Verification
Initial calibration verification (ICV) and continuing calibration verification (CCV) samples were analyzed during each analytical batch before batch samples and after a specific number of samples, respectively, to evaluate calibration accuracy for each analyte. The minimum RF, minimum and maximum relative peak areas, change in retention time, and percent drift (%D) for each ICV and CCV was compared to the method-established acceptance criteria presented in the laboratory SOP and analytical report to assess the analytical accuracy.
Percent drift (%D) is calculated using the following equation:
RF, -RF, o/„D = ' " ' " ^ ' X 1 0 0 %
RF,
Where: RFi is the average response factor from the initial calibration.
RFc is the average response factor from the calibration verification standard.
The ICV and CCV results met the established criteria.
3.3 Mass Tune Standards
For gas chromatography/mass spectrometry (GC/MS) methods, the analytical instruments must be tuned to demonstrate the instrument is functioning such that it will detect the compounds of interest during analysis. Mass tune standard data was compared to the method-established criteria presented in the laboratory SOP and analytical report to evaluate analytical accuracy. The mass tune standard results met the established criteria.
3.4 Blanks
Target analytes should not be detected in method and trip blanks at concentrations above the laboratory-established method reporting limits presented in the laboratory analytical report. If a target analyte was detected in a blank and in an associated groundwater sample, and the concentration of the analyte in the groundwater sample was less than five times the concentration detected in the blank, the analyte detected in the groundwater sample was qualified with a "UB" flag to indicate a nondetect. If the concentration of a target analyte in a groundwater sample was greater than five times the concentration detected in an associated blank, the groundwater sample datum was qualified with a "B" flag to indicate that a measurable concentration of a target analyte was detected in an associated blank.
If a common volatile laboratory contaminant (methylene chloride, acetone. 2-butanone, and cyclohexane) was detected in a blank and in an associated groundwater sample, and the concentration of the analyte in the groundwater sample was less than ten times the
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concentration detected in the blank, the analyte detected in the groundwater sample was qualified with a "UB" flag to indicate a nondetect. If the concentration of a target analyte in a groundwater sample was greater than 10 times the concentration detected in an associated blank, the groundwater sample datum was qualified with a "B" flag to indicate a measurable concentration of a target analyte was detected in an associated blank.
3.4.1 Method Blanks. The method blank contains each of the reagents used in the processing of samples and is carried through the complete analytical procedure used for the samples. Results of the method blank analyses are presented in the laboratory analytical report. BETX compounds were detected at concentrations below the method reporting limits in each method blank associated with the soil gas and subslab soil gas samples. Target analytes were not detected in method blanks associated with the sump water samples. Data qualified based on method blank results are presented in Table D-1. Detection of target analytes in the method blanks that did not result in qualified groundwater sample data are presented in Table D-2.
3.4.2 Trip Blanks. A trip blank accompanied each cooler containing water samples for VOC analysis and was analyzed to assess whether cross contamination of the water samples occurred from sample containers, other samples, or ambient air during transport to and at the laboratory. The trip blank accompanied the empty bottle sets to the site and consisted of a set of VOC sample bottles that had been filled by the laboratory with organic-free water. The trip blanks remained unopened during the sampling activities. None of the target VOCs were detected above the reporting limit in the trip blank. Therefore, sample data were not qualified due to the trip blank results.
3.5 Surrogate Spikes
Surrogate spike recoveries were used to evaluate the accuracy of the analytical data and to monitor laboratory control procedures for organic analyses. Samples were spiked with surrogates according to the laboratory SOP. The surrogate spike percent recovery (%R) data were evaluated using the laboratory-established acceptance criteria presented in the laboratory analytical report. The surrogate results are presented in the laboratory analytical reports with the sample data. Percent recovery (7oR) is calculated using the following equation:
|A-B| o/oR = l 1x100%
C
Where: A = The measured concentration of the spiked analyte in a spiked sample. B = The measured concentration of the spiked analyte in an unspiked sample. C = The concentration of the analyte used for spiking.
The surrogate recoveries for each sample met the established criteria.
3.6 Internal Standards
Internal standards are used to access accuracy and to determine the concentration of target analytes in samples for VOC GC/MS analysis. Internal standards are spiked in the sample after
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sample preparation/extraction, but prior to analysis. Analyte concentration is determined using the following equation:
^ As X CIS Cs=
Aisx RF
Where: Cs = Concentration of the analyte or surrogate. As = Peak area (or height) of the analyte or surrogate. CIS = Concentration of the internal standard. Ais = Peak area (or height) of the internal standard. RF = Average response factor of calibration curve.
Accuracy is assessed by comparing the internal standard recovery and retention time to the control limits established by the method and presented in the laboratory SOP and analytical report. However, surrogate spike recovery data are also used to assess data when internal standard recoveries are outside control limits. The internal standard results met the established criteria.
3.7 MS/MSD Samples
For water sample analysis, MS/MSD sample pairs were analyzed to assess accuracy and to identify possible adverse matrix effects. These samples were spiked with target analytes prior to extraction or analysis. The percent recoveries of the spiked compounds were compared to the laboratory-established QC limits presented in the laboratory analytical report. The following criteria were used to evaluate the MS/MSD samples:
3.7.1 MS/MSP Recovery Below Acceptance Criteria. MS compounds below the acceptance criteria indicated a potential low bias during sample analysis. If corresponding analytes were detected in the parent sample the data were qualified with a "J-" flag Indicating the data are estimated and are potentially biased low. If the corresponding analytes were not detected in the parent sample, the data were qualified with a "UJ" flag.
3.7.2 MS/MSD Recovery Above Acceptance Criteria. MS/MSD recoveries above the acceptance criteria indicate a potential high bias during sample analysis. Therefore, if corresponding analytes were not detected in the parent sample, data were not qualified because high recoveries indicate a high bias and do not affect nondetected analytes. If corresponding analytes were detected in the parent sample data were qualified with a "J-i-" flag indicating the data are estimated and are potentially biased high.
3.7.3 High Analyte Concentration in Parent Sample. If the concentration in the parent sample was more than four times the spiked analyte concentration, the overall change in the MS/MSD concentration is not significant enough for the instrument to detect the spiked compound. Therefore, if the MS/MSD recoveries were outside the acceptance criteria, no data were qualified.
3.7.4 High and Low MS/MSD Exceedances. Bias cannot be determined if one MS/MSD recovery is above and another recovery is below acceptance criteria. Therefore, analytes not detected in the parent sample were not qualified. Analytes associated with the MS/MSD detected in the parent sample are qualified with a "J" flag to indicate the data are estimated.
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3.7.5 Only the MS or MSD Outside Acceptance Criteria. If a target analyte was outside acceptance criteria in only the MS or MSD, and the RPD (discussed later in the precision section) was within acceptance criteria the following criteria were used to evaluate the MS/MSD data. If one recovery (MS or MSD) was outside the acceptance criteria and the other recovery was barely inside the acceptance criteria, the data were treated as if both the MS and MSD recoveries were outside the acceptance criteria and the parent sample data were qualified using the MS/MSD data qualification criteria listed above. If one of the recoveries was outside the acceptance criteria but the other recovery was within acceptance criteria, but closer to the other acceptance limit, it was assumed recovery outside the acceptance criteria was an anomaly, and not indicative of the sample media. Therefore, no parent sample data were qualified.
3.7.6 MS/MSD Summary. MS/MSD recoveries met established criteria.
3.8 LCS/LCSD
LCSs and/or LCSDs were analyzed to assess accuracy in the absence of matrix effects. Reagent grade water or air was spiked with target analytes prior to analysis. The percent recoveries of the spiked compounds were compared to the laboratory-established QC limits presented in the laboratory analytical report. The same criteria used to evaluate the MS/MSD samples described previously are used to evaluate the LCS/LCSD samples, except all samples associated with the LCS/LCSD are qualified. The LCS/LCD recoveries met established criteria.
4.0 PRECISION EVALUATION
Precision measures the reproducibility of measurements under a given set of conditions, and is expressed as RPD. Laboratory precision was evaluated using the RPDs between the MS/MSD pairs, LCS/LCSD pairs, and laboratory duplicates, where applicable.
4.1 MS/MSDs
If the RPD exceeded the acceptance criteria, corresponding analytes detected in the parent sample were qualified with a "J" flag indicating the data are estimated. Because bias cannot be determined for nondetect analytes, parent sample data for nondetect analytes were not qualified. MS/MSD RPD results met the established criteria.
4.2 LCS/LCSDs
If the RPD exceeded the acceptance criteria, corresponding analytes detected in the associated samples were qualified with a "J" flag indicating the data are estimated. Because bias cannot be determined for nondetect analytes, nondetect data were not qualified. LCS/LCSD RPD results met the established criteria.
4.3 Laboratory Duplicates
Laboratory duplicate analysis was conducted on both soil gas samples and three of the six subslab soil gas samples. The laboratory duplicate data is presented in analytical reports. If the RPD exceeded the acceptance criteria, corresponding analytes detected in the associated
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samples were qualified with a "J" flag indicating the data are estimated. Because bias cannot be determined for nondetect analytes, nondetect data were not qualified. Data qualified due to laboratory duplicate RPD results are listed in Table D-1. Data associated with laboratory duplicate RPD results outside of acceptance criteria that were not qualified are listed in Table D-2.
4.3 Precision Summary
None of the water sample data were qualified based on RPD results. Two soil gas results and one subslab soil gas result were qualified based on laboratory duplicate RPD results, and are indicated in Table D-1.
5.0 COMPARABILITY EVALUATION
Comparability is a qualitative parameter that expresses the confidence that one data set may be compared to another. For this project, sample collection and analysis followed standard methods and the data were reported using standard units of measure. As a result, the data from this project should be comparable to other data collected at this site using similar sample collection and analysis methodology.
6.0 SENSITIVITY EVALUATION
Sensitivity is the capability of a method or instrument to discriminate among measurement responses representing different levels of the variable of interest. Reporting limits were evaluated to assess sensitivity. The analytical sensitivity is acceptable.
7.0 TRACEABILITY EVALUATION
Traceability is the extent to which data can be substantiated by hard-copy documentation. Documentation exists in two forms: one that links quantification to authoritative standards and one that explicitly describes the history of each sample from time of collection to time of analysis. Samples, QC samples, and standards are traceable through the laboratory analytical reports and records. Sample history is traceable through the field notebooks, individual sampie collection forms, and chain-of-custody forms stored in the project file.
8.0 DATA VALIDATION SUMMARY
Based on the evaluated data completeness, respresentativeness, accuracy, precision, comparability, sensitivity, and traceability, the September and October sump water sample data and the January 2009 soil gas and subslab soil gas data are considered usable as qualified for the purposes of the Focused Rl activities.
PWVord ProcoB8in(JMU.IANT-IPL\CLINTON-FMGP SIteNLTR RPT.04-09-Focusad Rl Rpt Addendum\Attachmsnt D\Attachment D.03.09.Quallty Assurance Rp(.doc
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TABLES
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TABLE D--I
QUAUTY CONTROL PARAMETERS OUTSIDE OF CONTROL UMrrS RESULTING IN QUAUFIED DATA
AnalyUcal Batch QC Samplfl^arameter Control Umlta Result Analyta(a)
Sampla(8) Affectwl Flag Flag Applied To
Lab Sample Qualified Qualified Notea ftoautt 7 Sample Raeult
091590A
091590A
091S90A
Ogi590A 091590A
0gi590A 091590A
091590A 091590A
091590A 091590A
0giS90A 091590A
091590A 091590A
0901612A 0901612A 0901612A
0901612A 0901612A 0901612A
0901612A 0901612A 0901612A
0901612A 0eO1612A 0901612A
0901612A 0901612A 0901612A
Laboratoty Duplicate RPD
Laboratory Duplicate RPD
Laboratory Duplicate RPD
Method Blank Mettiod Blank
Method Blank Method Blank
Method Blank Method Blank
Method Blank Method Blank
Method Blank Method Blank
Method Blank Method Blank
Method Blank Method Blank Mettiod Blank
Mettiod Blank MettKXJ Blank Mettiod Blank
Method Blank Method Blank Method Blank
Method Blank Mettiod Blank Method Blank
Method Blank Mettiod Blank Mettiod Blank
<2S
<25
<25
<0 050 <0 050
<0.020 <0 020
<0.020 <0 020
<0 040 <0 040
<0 020 <0 020
<0 50 <0 50
<0 50 <0 50 <0S0
<0050 <0 050 <0 050
<0 020 <0 020 <0 020
<0 020 <0 020 <0 020
<0 040 <0 040 <0 040
32
83
58
0 024 J 0 024 J
0 005.') J 0.0055 J
00022J 00022J
00043J 0 0043 J
0 0022 J 0 0022 J
016 J 016J
016J 016J 016J
0024J 0.024 J 0 024 J
0 0055 J 0 0055 J 00055J
0 0022 J 0.0022 J 0 0022 J
0.0043 J 00043J 00043J
o-Xylene
Toluene
Naphttialene
Benzene Benzene
Toluene Toluene
Ettiylbenzene Ettiylbenzene
m,p-Xy(ene m.p-Xylene
o-Xylene o-Xylene
Naphttialene Naphttialene
Naphttialene Naphttialene Naphttialene
Benzene Benzene Benzene
Toluene Toluene Toluene
Ethylbenzene Ethylbenzene Ettiylbenzene
m.p-Xylene m.p-Xylene m,p-Xylene
BLOl-SG-EOOl
BLOl-SG-SOOl
BL03-SS-W001
BL03-SS-E001 BL03-SS-W001
BL03-SS-E001 BL03-SS-W001
BL03-SS-E001 B103-SS-W001
BL03-SS-E001 BL03-SS-W001
BL03-SS-E001 BL03-SS-W001
BL03-SS-E001 BL03-SS-W001
BL04-SS-E001 BL04-SS-W001 BL02-SS-W001
BL04-SS-E001 BL04-SS-W001 BL02-SS-W001
BL04-SS-E001 BL04-SS-W001 BL02-SS-W001
BL04-SS-E001 BLO4-SS-W001 BL02-SS-W001
BL04-SS-E001 BL04-SS-W001 Bin?-SS-W001
J
J
J
B UB
B B
B B
B B
B B
UB UB
UB UB UB
UB UB B
8 B B
B B B
B B B
Pnmary Result None 28.000 J Yes 28.000 J
Pnmary Result None 1.200 J Yes 1,200 J
Primary Result None 0 057 J Yes 0 057 J
Result 15x 0.024 (0 12) None 0 12 Yes 0 12 B Resulte 5x0.024 (012) None 0 032 J Yes 0 032J, UB
Result 2 5x 0 0055 (0.0275) None 0 21 Yes 0 21 B ResuH!! 5x 0 0055 (0 0275) None 0 12 Yes 0 1 2 B
Result 2 5x0.0022 (0 011) None 0 043 Yes 0 043B Result 2 5x0 0022 (0 011) None 0.029 J Yes 0 029 J.B
Result 2 5x0 0043 (0 0215) None 0 10 Yes 0 1 0 B Result 2 5x 0 0043 (0 0215) None 0 OSU Yes 0 051J, B
Result 2 5x0 0022 (0 011) None 0 047 Yes 0 047B Result 2 5x0 0022 (0 011) None 0 025 J Yes 0 025J, B
Result <5x016 (OBO) None 0 71J Yes 0 71J, UB Result < 5x 0 16 (0 80) None 0 057 J Yes 0 057J, UB
Result < 5x0.16 (0.80) None 0 052 J Yes 0 052 J , UB Result < 5x016 (0 80) None 0 074 J Yes 0 074J, UB Result < 5x0.16 (0 80) None 0.074 J Yes 0 040J, UB
Result < 5x0.024 (0.12) None 0 066 J Yes 0 066J. UB Result < 5x0.024 (012) None 0 075 J Yes 0 075J, UB Result 2 5x0 024 (012) None 014 Yes 014 8
Result 2 5x 0 0055 (0 0275) None 0 056 Yes 0 056B Result 2 5x 0 0055 (0 0275) None 0 087 Yes 0 087B Result 2 5x 0 0055 (0 0275) None 0 20 Yes 0 2 8
Result 2 5x0 0022 (0 011) None 0 016 J Yes 0 016 J, 8 Result 2 5x0.0022 (0 011) None 0 019 J Yes 0 019 J.B Result 2 5x0 0022 (0 011) None 0 051 Yes 0 051 B
Result 2 5x0.0043 (0.0215) None 0 030 J Yes 0 030J, B Result 2 5x0 0043 (0 0215) None 0 042 J Yes 0 042J,B Result 2 5x0 0043 (0 0215) None 013 Yes 0 1 3 B
Page 1 of 2
TABLE D-1
QUAUTY CONTROL PARAMETERS OUTSIDE OF CONTROL UMITS RESULTING IN QUAURED DATA
Analytical Batch
0901612A 0gO1612A 0901612A
0g01612A 0901612A
QC Sampla/Paramater
Method Blank Mettiod Blank Mettiod Blank
Laboratory Duplicate RPD Laboratory Duplkaite RPD
Control UmlU
<0 020 <0 020 <0 020
<25 <25
Result
00022J 00022J 0 0022 J
40 29
AnalyteCe)
o-Xylene o-Xylene o-Xylene
o-Xylene Toluene
Sample(8) Affected
BL04-SS-E001 BL04-SS-W001 8L02-SS-W001
BL02-SS-E001 BL02-SS-E001
Rag
B B B
J J
Rag Appltod To
Result 2 5x0 0022 (0 011) Result 2 5x0 0022 (0 011) Result 2 5x0.0022 (0.011)
Pnmary Result Pnmary Resull
Lab Notea
None None None
None None
Sample Result
0013J 0 019 J 0048
240 J 440J
Qualified 7
Yes Yes Yes
Yes Yes
Qualified Sample Reeult
0013J 0019J 0 0 4 8 8
240 J 440J
Notes: B = The analyte was detected in an associated blank, as well as in the sample at a concentration equal to or greater than 5 bmes ttiat detected in ttie blank J = The analyte was positively identilied, ttie quantilation is an estimation QC = Quality control RPD = Relative percent difference. UB s The analyte is considered nol detected, ttie concentration in the sample was less ttian 5 times ttiat detected in an associated blank
Page 2 of 2
TABLE D-2
QUALmr CONTROL PARAMETERS OUTSIDE OF COKTROL LIMtrs NOT RESULTING IN QUALIHED DATA
Analytical Batch QC Sample/Parameter Control Limits Result Analyte(s)
Sample(s) Affected Rag Flag Applied To
Lab Notes
Sample Result Result Qualifled7
0901590A
0901590A
0901612a
0901612a
Method Blank
Method Blank
Method Blank
LatMFBtory Control Sample Duplicate % Recovery
<5 <5
<5
60-140
15J
15J
ISJ
141
Naphthalene Naphthalene
Naphthalene
Naphttialene
BL01-SG-E001
BLOl-SG-SOOl
BL02-SG-E001
BL02-SG-E001
UB UB
UB
Result < 5x15 (75) Result < 5x15 (75)
None None
Result < 5x 15 (75) None
Positive Results Exceeds
QC Umits
140,000 U 12,000 U
2,900 U
2,900 U
No
No
NO
No
Notes: J = The analyte was positively identified; Ihe quantitation is an estimation QC = Quality control U = The analyte was analyzed lor, but nol detected The associated numencal value is at or below the method detection limit UB = The analyte is considered not detected, the concentration in the sample was less than 5 times that detected in an associated blank
Page 1 of 1
TABLE D-3
SOIL GAS AND SUBSLAB SOIL GAS SAMPLE PRESERVATION
Sample
BL01-SG-E001 BL01-SG-S001 BL02-SS-E001 BL02-SS-W001 BL03-SS-E00t BL03-SS-W001 BL04-SS-E001 BL04-SS-W001
Canister
931 4183 4374 35269 25315 33962 34377 34022
Receipt from Lab ("Hg)
29.22 29.21 29.17 29.13 29.18 29.21 29.17 29.18
Before Sample Collection ("Hg)
30.65 30.42 29.11 29.35 29.70 29.58 29.47 29.26
Canister Vacuum
Difference ("Hg)
1.43 1.21 -0.06 0.22 0.52 0.37 0.30 0.08
After Sample Collection ("Hg)
2.14 23.61 3.47 3.25 6.81 5.47 5.12 3.83
Receipt at Lab ("Hg)
2.0 23.5 2.5 2.0 6.5 5.0 5.0 4.0
Difference ("Hg)
-0.1 -0.1 -1.0 -1.3 -0.3 -0.5 -0.1 0.2
"Hg = Inch(es) mercury.
Page 1 of 1
EXHIBIT 1
^ M W H
EXAMPLE DATA VERIFICATION FORM
Analytical Mathod/Analytes:
Laboratory:
Batch Idantmcatlon:
QC Identification'*':
SW-846 8260B
Keystone Laboratories, Inc. - Newton. IA
1810571
1810571
Sample Collection Dati<s):
MWH Job Number
Matrix:
September 10,2008
1914390.0102
Sump Water
Verification Compiatod By (Signature and Data): / c : ^ ^ - d - ^ > t ^ - ^ ^ ^ - / ^ / j y ^ y C - d - ^ ^ - - ^ ^ /;;) V// ' - / / j ) ^
1 2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Sample Identification BLOI-SW-1001
Lab Identif lcation 1810571-09
Htto(Y/N) Y
Qualificationa Comments
Pagc I of 2
EXAMPLE DATA VERIFICATION FORM
Analytical MetlKxVAnalytes:
Laboratory:
Batch IdantHieation:
Quality Control Identification"':
SW-846 8260B
Keystone Laboratories, Inc. - Newton, IA
1810671
1810571
Data Validation Criteria
Hold Time Sample Preservation
Analyte List Reportinq Limits
Instrument Pertormance Check (Mass Tune)
Initial Calibration Initial Calibration Venfication
Initial Calibration Blank (iCP & GFAA Metiiods)
Continuing Calibration Venfication
Continuing Calibration Blank (ICP & GFAA Mettiods)
Method Blank
Surrogate Spike Recovery (organic analysis)
Sample Intemal Standard Retention Time (GC/MS Methods) Sample Intemal Standard EICP Area (GC/MS Methods) Laboratory Control Sampte
Laboratory Control Sampie Duplicate
Matrix Spike/Matrix Spike Duplicate
Trip Blanks (volatile organic compound analysis) Laboratory Duplicate
Post Digestion Spike (ICP & GFAA)
Field Dupiicata
Equipment Rinsate Blank
1 A
A
A
A
A
A
A
NA
A
NA
A
A
A
A
A
NA
A
A NA
NA
NA
NA
2 3 4 5 6 7 8 9 10 11 12 13 14 IS 16 17 18 19 20
Notes:
'*' LJst Quality Control batch identification if different than Batch Identification. A indicates verification critena were met. EICP = Extracted ion current profile. GC/MS = Gas chromatography/mass spectrometry. ICP = inductively coupled plasma. GFAA E Graphite fumace/atomic absorption. NA indicates criteria are not applicatile for the specified analytical method. X indk»ites venfication cntena were not met.
Page 2 of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analytas:
Lattoratory:
Batch Identification:
QC ManUficatton"':
Verification Completed By (Signature and Date):
SW-846 82608
Keystone Latwratones. Inc. - Newton, IA
18J0485
1BJ0485
Sample Collection Oate(s):
MWH Job Number
Matrix:
October 8,2008
1914390.0102
Sump Water
/ : ' ^ A . c ^ ^ / ^ t / a ^ . > / ^ o^Z/y/^':^
1 2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Sample Identification BL02-SW-1001
Lab Identification 18J0485-09
Hits (Y/N) N
Qualifications Comments
Page I of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method^Anaiytes:
Laboratory:
Batch Identification:
Quality Control ktentlflcation*":
SW-846 8260B
Keystone Laboratones, Inc - Newton, IA
18J0485
18J0485
Data Validation Criteria Hold Time Sample Preservation Analyte List Reporting Limits Instnjment Performance Check (Mass Tune) Initial Calibration Initial Calibration Verification Initial Calibration Blank (ICP & GFAA Methods) Continuing Calibration Verification Continuing Calibration Blank (tCP & GFAA Methods) Method Blank Sun-ogate Spike Recoveiy (organic analysis) Sample Intemal Standard Retention Time (GC/MS Methods) Sample Intemal Standard EICP Area (GC/MS Methods) Laboratory Control Sample Laboratory Control Sample Duplicate Matrix Spike/Matrix Spike Duplicate Trip Blanks (volatile organic compound analysis) Laboratoiy Duplicate Post Digestion Spike (ICP & GFAA) Field Duplicate Equipment Rinsate Blank
1 A A A A A A A
NA A
NA A A A A A
NA A A
NA NA NA NA
2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Notes:
" ' List Quality Control batch identification if different than Batch IdentifKation. A indicates verification critena were met. EICP = Extracted ion current profile. GC/MS = Gas chromatography/mass spectrometry. ICP = Inductively coupled plasma. GFAA = Graphite fumace^atomk: absorption. NA indicates critena are not applicat>le lor the speafied analytical method. X indicates verification criteria were not met.
Page 2 of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analytm:
Laboratory:
Batch Identification:
QC ldenttficatlon<^:
ATL Modified EPA TO-15 SIM (Naptithalene)
Air Toxics. Ltd.
0901590A-XXA
0901590A-XXA
Sample Collection Date(s):
MWH Job Number:
Matrix:
Januaiy 27 and 28.2009
1914390.0102
Verification Completed By (Signature and Date): / :^ .A/U^ '^~^- //^^U.^CuMl^
Sal Gas (SG) and Subslab Soil Gas (SS)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
,20
Sample Identification BL03-SS-E001
BL03-SS-W001
Lab Identification 0901590A-01A
0901590A-02A
Hits (Y/N) Y
Y
Qualifications J.UB
J.UB
1 1
Comments Estimated value detected between MDL and RL and less than 5 times the
concentration detected in the nnethod blank.
Estimated vaiue detected between MDL and RL and less than 5 times the concentration detected in the method blank. Lab duplicate RPD above control
limit.
Page ] of 2
EXAMPLE DATA VERIFICATION FORM
Anaiytical Metbod/Aniilytes:
Laboratory:
Batch Identificadon:
Quality Control IdentUkatioa^*^:
ATL Modified EPA TO-15 SIM (Naptittialene)
Air Toxics, Ltd.
09015gOA-XXA
0901590A-XXA
Data Validatioa Criteria Hold Time Sample Pre.servatioii Analyte Li.st Reporting Limits instrument Performance Citeck (Mass Tune) Initial Calibration Initial Calibration Verification Initial CalibratitMl Blank (ICP & GFAA Methods) Continuing Calibration Verification Continuing Calibration Blank (ICP & GFAA Mediods) Method Blank Surrogate Spike Recovery (organic analysis) Sample Intemal Standard Retention Time (GC/MS Methods) Sample Intemal Standaid EICP Area (GC/MS Methods) Laboratory Control Sample Laboratory Control Sample Duplicate Matrix Spike/Matrix Spike Duplicate IVip Blanks (volatile organic compound analysis) LatKiratory Duplicate Post Digestion Spike (ICP & GFAA) Field Duplicate F.quipmcnt Rinsate Blank
1 A A A A A A A
NA A
NA X A A A A A
NA NA NA NA NA
2 A A A A A A A
NA A
NA X A A A A A
NA NA X
NA NA
3 4 5 6 7 8 9 10 11 12 13
NAlNAl 1 1 1 1 1 1 1 1 1
14 15 16 17 18
1
19 20
I l l l l l !
Notes; (1) List Quality Coniroi batch identification if different than Batch Identification. A indicates verification cnteria were met. EICP = Extracted ion current profile. GC/MS = Gas chramatography/mass spectrometry. ICP = Inductively coupled plasma. GFAA = Graphite fumace/atomic absorption. NA indicates critena are not applicable for the specified analyucal method. X indicates verification cnteria were not met.
Page 2 of:
EXAMPLE DATA VERIFICATION FORM
Analyticai Method/Anatytas:
Laboratory:
Batch Idantlfication:
QC Identification''*:
ATL Modified EPA TO-15 SIM (BTEX)
AirToxKS, Ltd.
0901590A-XXB
Sample Collection Date(8):
MWH Job Number
Matrix:
January 27 and 28.2009
1914390.0102
Subslab Soil Gas (SS)
0901590A-XXB
Verif ic»tion Completed By (Signature and Date): j g ^ ^ ^ d . ^ ^-?<^ ^ : : : ^ . ^ . : i ^ ' ^ £} V / ^ / - / ^ ^
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Sample Identtf lcation BL03-SS-E001
BL03-SS-W001
Lab Identification 09015gOA-01B
0901590A-02B
Hlto(YyN) Y
Y
Qualifications B
J. UB. B
Comments BTEX detected in method blank. BTEX concentrations detected in sample at
concentratnns greater than 5 times the concentrations detected in the method blank.
BTEX detected in method blank. Benzene concentratkxi detected in sample at concentrabon less than 5 times the concentrabon detected in the method
blank. TEX concentratnns detected in sample at concentratkins greater than 5 times the concentrations detected in the method blank.
Page I of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analytes:
Laboratory:
Batch Identification:
Quality Control Identification"":
ATL Modified EPA TO-15 SIM (BTEX)
Air Toxics, Ltd.
0901590A-XXB
0901590A-XXB
Data Validation Criteria Hold Time Sample Preservation Analyte list Reporting Limits Instrument Perfonnance Check (Mass Tune) faiitial Calibration Initial Calibration Verification Iniiial Calibration Blank (ICP & GF/VA Methods) Continuing Calibration Verification Continuing Calibration Blank (ICP & GFAA Methods) Method Blank Surrogate Spike Recovery (organic analysis) Sample Internal Standani Retention Time (GC/MS Methods) Sample Intemal Standaid EICP Area (GC/MS Methods) LaboraUiry Control Sample Laboratory Control Sample Duplicate Matrix Spike/Matrix Spike Duplicate Trip Blanks (volatile organic compound analysis) lutboratoiy Duplicate Pest Digestion Spike (ICP & GFAA) Field Duplicate Equipmenl Rinsate Blank
1 A A A A A A A
NA A
NA X A A A A A
NA NA NA NA NA NA
2 A A A A A A A
NA A
NA X A A A A A
NA NA A
NA NA NA
3 4 S 6 7 8 9 10 11 12 13 14 IS 16 17 18 19 20
Notes: *' List Qualily Coniroi batch identification if different than Batch Identification. A indicales verification criteria were met. EICP = Extracted ion current profile. GC/MS = Gas chromatography/mass spectrometry. ICP = Inductively coupled plasma. GFAA = Graphite fumace/atomic absorption. NA indicates criteria are not applicable for the specified analyucal method. X indicates verification criteria were not met.
Page 2 of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analyles: ATL Modified EPA TO-15 Full Scan (BTEX + Naphthalene) Sample Collection Data(8): January 27 and 28, 2009
Laboratory: Air Toxics. Ltd. MWH Job Numbar: 1914390.0102
Batch Identification: 0901590A-XXC Matrix:
QC ldentificaUon<*>:
Soil Gas (SG)
0901590A-XXC
Verification Compieted By (Signature and Date): >~r<^-M/<:-^y^ . ^yA/^ -7
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Sample Identiflcation
BLOl-SG-EOOl
BLOl-SG-SOOl
Lab identiflcation
0901590A-03A
0901590A-04A
Kite (Y/N)
Y
Y
Qualifications
J
J
Comments
Lab duplicate RPD for o-xylene exceeded control limit.
Lxib duplicate RPD for toluene exceeded control limit.
Page 1 of 2
EXAMPLE DATA VERIFICATION FORM
Analyticid Method/Analytes:
Laboratory:
Batch Identification:
Quality Control Identification^*^
ATL Modified EPA TO-15 Full Scan (BTEX + Naphthalene)
Air Toxics, Ltd.
0901590A-XXC
0901590A-XXC
Data Validation Criteria Hold Time Sample Preservation Analyte List Reporting Umits instrument Performance Check (Mass Tune) Initial Calibration Initial Calibration Verification Initial Calibration Blank (ICP & GFAA Methods) Continuing Calibration Verification Continuing Calibration Blank (ICP & GFAA Methods) Method Blank Surrogate Spike Recovery (organic analysis) Sample internal Standard RetenUon Time (GC/MS Methods) Sample hitemal Standard EICP Area (GC/MS Methods) laboratory Control Sample Laboratory Control Sampie Duplicate Matrix Spike/Mauix Spike Duplicate Trip Blanks (volatile organic compound analysis) Laboratory Duplicate Post DiEcslion Spike (ICP & GF/\A) Field Duplicate Equipment Rinsate Blank
1 A A A A A A A
NA A
NA A A A A A A
NA NA X
NA NA NA
2 A A A A A A A
NA A
NA A A A A A A
NA NA X
NA NA NA
3 4 5 6
1
7 8 9 10 11 12 13 14 15 16
1
17 18 19
•
20
1 1 Notea:
*' Lisl Quality Control batch identification if different than Batch Identification. A indicates verificauon criteria were met. EICP = Extracted ion current profile. GC/MS = Gas chiomatography/mass spectrometry. ICP = biductively coupled plasma. GFAA ~ Graphiic fumace/atomic absorption. NA indicates criteria are not applicable for the specified analytical method. X indicates verification cnteria were not met.
Page 2 of 2
EXAMPLE DATA VERIFICATION FORM
AnalyUcal MathotyAnalytaa:
Latioratory:
Batch Identification:
QC IdenUflcation^*):
ATL Modified ASTM D-1945 (Helium)
Air Toxics, Ltd.
0901590B-XXA
Sample CollecUon Date(a):
MWH Job Number.
MaUlx:
January 27 and 28,2009
1914390.0102
Sal Gas (SG) and Subslab Soil Gas (SS)
0901590B-XXA
Verification Completed By (Signature and Date): A U A A ^ ^ ^ /(cy^/^'.j^^ ^ '^ /v /^^
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Sampie MenUfication BL03-SS-E001
BL03-SS-W001
BLOl-SG-EOOl
BL01-SQ-S001
Lab Identification 0901500B-01A
0901590B-02A
09015906-03A
0901590B-O4A
Hits (Y/N) Y
Y
Y
Y
QuaimcaUona
J
Comments
Estimated value detected between the MDL and RL
Page 1 of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analytes:
Laboratory:
Batch Identification:
Quality Control Identification'":
ATL Modified ASTM D-1945 (Helium)
Air Toxics, Ltd.
09015gOB-XXA
0901590B-XXA
Data Validation Criteria Hold Time Sample Preservation Analyte List Rcpoitinii Limits Instrument Performance Check (Mass Tune) Initial Calibration hiitiaJ Calibration Verification biitial Calibration Blank (ICP & GFAA Methods) Continuing Calibration Verification Continuing Calibration Blank (ICP & GFAA Methods) Method Blank Surrogate Spike Recovery (orKaiiic analysis) Sample Intemal Standard Retention Time (GC/MS Methods) Sample Internal Standaid FJCP Area (GC/MS Methods) Laboratory Control Sample tjihoratury Control Sample Duplicate Matrix Spike/Matrix Spike Duplicate Trip Blanks (volatile organic a>mpound analysis) Lat>ontory Duplicate Post Digestion Spike (ICP &. GFAA) Field Duplicate Equipment Rinsate Blank
1 A A A A
NA A A
NA A
NA A
NA NA NA A A
NA NA A
NA NA
2 A A A A
NA A A
NA A
NA A
NA NA NA A A
NA NA NA NA NA
NAlNA
3 A A A A
NA A A
NA A
NA A
NA NA NA A A
NA NA NA NA NA NA
4 A A A A
NA A A
NA A
NA A
NA NA NA A A
NA NA NA NA NA NA
5 6
1
7 8 9 10 11 12 13 14 15 16 17 18 19 20
Notes: '*' List Quality Control batch identification if different than Batch Identification. A indicates verification criteria were met. EICP = Eixtracted ion current profile. GC/MS = Gas chromatography/mass spectrometry. ICP = Inductively coupled plasma. GFAA = Graphite fumace/atomic absorption. NA indicates criteria are not applicable for the specified analytical method. X indicates verification criteria were not met
Page 2 of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analytas: _
Laboratory:
Batch ManUficatton:
QC Identtficatton'*':
Verification Completed By (Signature and Date):
ATL Modified EPA TO-15 SIM (Naphthalene)
Air Toxks. Ltd.
0901612A-XXA
Sample Collection Date(s):
MWH Job Nuinber:
Matrix:
Januaiy 27 and 28, 2009
1914390.0102
Subslab SoM Gas (SS)
0g01612A-XXA
^ <i5y2-^>/ -A"- /^^^-^M^^^m^ O'i / N / O J
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Sample MenUfication BL04-SS-EOO1
BL04-SS-W001
BL02-SS-W001
l.ab MenUfteation 0901612A-01A
0901612A-02A
0901612A-04A
Hits (Y/N) Y
Y
Y
Qualifications J
J
J
ComoMnta Estimatad value detected between MDL and RL. and less than the
concentratmn detected in the method blank.
Estimated value detected between MDL and RL and less than the concentratkm detected in the method blank.
Estimated value detected between MOL and RL. and less than the concentration detected in the method blank. Lab duplicate RPD exceeded
contnsi limit
Page I of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analytes:
Laboratory:
Batch Identification:
QuaUty Control Identification'*^
ATL Modified EPA TO-15 SIM (Naphthalene)
Air Toxics, Ltd.
0901612A-XXA
0g01612A-XXA
Oata Validation Criteria Hold Time Sample Preservation /knalyie List Reporting Limits histrument Performance Check (Mass Tune) Initial Calibration biidal Calibration Verification IniUal Calibration Blank (ICP & GFAA Methods) Continuing Calibration Verification Continuing Calibration Blank (ICP & GFAA Methods) Method Blank Suirogate Spike Recovery (organic analysis) Sampie Internal Standard Retention Time (GC/MS Methods) Sample Internal Standard EICP Area (GC/MS Methods) Laboratory Control Sample Laboratory Control Sample Duplicate Matrix Spike/Matrix Spik&Duplicate Trip Blanks (volatile organic compound analysis) Laboratory Duplicate Post Digestion Spike (ICP & GFAA) Field Duplicate Equipment Rinsate Blank
I A A A A A A A
NA A
NA X A A A A A
NA NA NA NA NA NA
2 A A A A A A A
NA A
NA X A A A A A
NA. NA NA NA NA NA
3 A A A A A A A
NA A
NA X A A A A A
NA NA X
NA NA NA
4 5 6
1
7 8 9 10 11 12 13 14 15 16 17 18 19 20
Notes: '*' Lisl Quality Control batch ideiiufication if different than Batch Identification. A indicates verification cnteria were met EICP = Extraeted ion cuireat proille. GC/MS = Gas chromatography/mass spectrometry. ICP = Inductively coupled plasma. GFAA = Graphite fiunace/atomic absorption. NA indicates criteria are not applicable for the specified analytical method. X indicates verification criteria were not met.
Page 2 of 2
EXAMPLE DATA VERIFICATION FORM
AnalyUcal Method/Analytas:
Laboratory:
Batch IdanUficaUon:
QC IdenttflcaUon'":
ATL Modified EPA TO-15 SIM (BTEX)
AirToxics. Ud.
Sample CoUection Dats(s):
MWH Job Numbar:
Januaiy 27 and 26.20Q9
1914390.0102
Og01612A-XXB SutMlab Sal Gas (SS)
0g01612A-XXB
Vertflcadon Complalad By (Signature and date): f^gJuMi W / ' A ^ U ^ - X . 0*i//'i/Q'^
1
2
3
4
5
6
7
a 9
10
11
12
13
14
15
16
17
18
19
20
Sample IdenUflcailon BL04-SS-E001
BL04-SS-W001
Blj02-SS-W00t
Lab Identification 0901612A-01B
0901612A-02B
0901612A-046
HKS (Y/N) Y
Y
Y
Qualifications J. UB. B
J. UB. B
B
Coinments EsSmated vakies detected between MDL and RL. Benzene concentration deiacted in sainple is less than 5 bmes the concsntration detected in the
method blank. TEX concentrations detected In the sample are greater than 5 tones the concentrations detected in the methcxi blank.
Estimated values detected between MDL and RL Benzene concentratkjn detected in sample is lass than 5 times the ooncentratkxi detected in tbe
method blank. TEX concentrations detected in the sample ara greater than 5 times the concentrations detected m the method blank.
BTEX concentrations detected in ttie sample are greater ttian 5 times ttie concentrations detected in ttie mettiod blank.
Page t of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analytes:
Laboratory:
Batch Identification:
Quality Control Identification**':
ATL Modified EPA TO-15 SIM (BTEX)
Air Toxics, Ltd.
0g01612A-XXB
0901612A-XXB
Data Validation Criteria Hold Time Sample Preservation Analyte list Repotting Umits Instniment Performance Check (Mass Tune) Initial Calibration Initial Calibration Verification Initial Calibration Blank (ICP & GFAA Methods) Continuing Calibration Venfication Continuing Calibration Blank (ICP & GFAA Metfiods) Method Blank Surrogate Spike Recovery (organic analysis) Sample hitemal Slandard Retention Tune (GC/MS Methods) Sample Intemal Standard EICP Area (GC/MS Methods) Laboratory Coniroi Sample Laboratory Control Sample Duplicaie Matrix Spike/Matrix Spike Duplicate Trip Blanks (volatile organic compound analysis) Laboratory Duplicate Post Digestion Spike (ICP & GFAA) Field Duplicate Equipment Rinsate Blank
1 A A A A A A A
NA A
NA X A A A A A
NA NA NA NA NA NA
2 A A A A A A A
NA A
NA X A A A A A
NA NA NA NA NA NA
3 A A A A A A A
NA A
NA X A A A A A
NA NA A
NA NA NA
4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 2U
Notes: ' " List Qualily Control batch identification if different than Batch Identification. A indicates verification cnteria were met. EICP = Extracted ion current profile. GC/MS = Gas chromatography/mass spectrometry. ICP = biductively coupled plasma. GFAA = Graphite fumace/atomic absorption. NA indicates criteria are not applicable for the specified analytical method. X indicates verification criteria were not met.
Page 2 of 2
EXAMPLE DATA VERIHCATION FORM
Anaiytical Method/Analytes: ATL Modified EPA TO-IS Full Scan (BTEX -t- Naphthalene) Sample CollecUon Date(s): January 27 and 28,2009
Laborattwy: Air Toxics, Ltd. MWH Job Number: 1914390.01(K
Batch MentlficaUon:
QC Mentification<^:
0901612A-XXC Matrix:
0901612A-XXC
Subslab Soil Gas (SS)
Verification Completed By (Signature and Oate): K^^^0-h.tZ4^~~^ I ' t J t ^ ^y l ^ / O ^ / / ^ U ' ^
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Sample Identifieatian BL02-SS-E001
Lab identification 0901612A-0aA
Hits (Y/N) Y
QuaNflcatlons
J
Comments Estimated values detected between MDL and RL Lab duplicate RPDs
exceeded control limits.
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EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analytes:
Laboratory:
Batch Identifieatian:
Quality Control Identification'*':
ATL Modified EPA TO-15 Full Scan (BTEX -t- Naphthalene)
Air Toxics, Ltd.
0901612A-XXC
0901612A-XXC
Data VaUdatiou Criteria Hold Time Sample Preservation Analyte List Reporting Limits hi.sti-uinent Perfomiance Check (Mass Tune) Initial Calibration Initial Calibration Verification biiual Calibration Blank (ICP & GFAA Methods) Continuing Calibration Verification Continuing Calibration Blank (ICP & GFAA Metiiods) Method Blank Surrogate Spike Recovery (organic analysis) Sample Litema] Standard Retention Tune (GC/MS Mediods) Sample Internal Standani EICP Area (GC/MS Methods) Laboratory Control Sample Laboratory Control Sample Duplicate Matrix Spike/Matrix Spike Duplicate Trip Blanks (volatile organic compound analysis) Laboratory Duplicate Post Digestion Spike (ICP & GFAA) Field Duplicate Equipment Rinsate Blank
1 A A A A A A A
NA A
NA X A A A A X
NA NA X
NA NA NA
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7 8 9 ID 11 12
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Notes: ' " Lost Quality Conuiol batch identification if different than Batch Identification. A indicates verification criteria were met. EUCP = Eixtracted ion cuirent profile. GC/MS = Gas chromatography/mass spectrometry. ICP = Inductively coupled plasma. GFAA = Graphite fumace/atomic absorption. NA indicales critena arc not applicable for the specified analytical method. X indicales verification criteria were not met.
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EXAMPLE DATA VERIFICATION FORM
Analyticai Method/Analytes:
ijilXMatory:
Batch Mantification:
QC Identification'":
ATL Modified ASTM D-1945 (Helium)
Air Toxics, Ltd.
0901612B-XXA
Sampie Coiiection Date(s):
MWH Job Number:
Matrix:
January 27 and 28, 2009
1914390.0102
Subslab Soil Gas (SS)
0901612B-XXA
Verification Compieted By (Signature and Date): /<^^:(A^cK^. /^u^-^:uA^ ^ ^ ^ / V / ^
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Sampie identification BL04-SS-E001
BL04-SS-W001
BL02-SS-E001
BL02-SS-W001
UbidentlficaUon 0901612B-O1A
0901612B-02A
0901612B-03A
0901612B-O4A
HitS(Y/N) Y
Y
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Y
—
. ._ .. _. .
QuaUfieaUons
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Commema
Estimated value detected between the MDL and RL.
Page 1 of 2
EXAMPLE DATA VERIFICATION FORM
Analytical Method/Analytes:
Laboratory:
Batch Identification:
Quality Control Identification'*':
ATL Modified ASTM D-1945 (Helium)
Air Toxics, Ltd.
0901612B-XXA
0g01612B-XXA
Data Validation Criteria Hold Time Sample Preservation Analyte List Reporting Limits Instniment Pertormance Check (Mass Tune) Initial Calibration hiitial Calibration Verification Initial Calibration Blank (ICP & GF/VA Methods) Continuing Calibration Verification Continuing Calibration Blank (ICP & GFAA Methods) Method Blank Suirogate Spike Recovery (organic analysis) Sample Intemal Standani Retention Time (GC/MS Methods) Sample Internal Standani EICP Area (GC/MS Metiiods) Laboratory Control Sample Uboratory Control Sample Duplicate Matrix Spike/Matrix Spike Duplicate Trip Blanks (volatile organic compound analysis) Laboratory Duplicate Post Digestion Spike (ICP & GFAA) Field DupUcate Equipment Rinsate Blank
1 A A A A
NA A A
NA A
NA A
NA NA NA A A
NA NA NA NA NA NA
2 A A A A
NA A A
NA A
NA A
NA NA NA A A
NA NA NA NA NA NA
3 A A A A
NA A A
NA A
NA A
NA NA NA A A
NA NA NA NA NA NA
4 A A A A
NA A A
NA A
NA A
NA NA NA A A
NA NA NA NA NA NA
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Notes: ' ' ' List Quality Control batch identification if different than Batch Identification. A indicates verificauon criteria were met. EICP = Extracted ion current profile. GC/MS = Gas chromatography/mass spectrometry. ICP = Inductively coupled plasma. GFAA = Graphite fumace/atomic at>sorption. NA indicates criteria are not applicable for the specified analytical method. X indicates verification criteria were not met.
Page 2 of 2
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