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D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
July 4, 2011
MEMORANDUM
SUBJECT:
FROM:
FINAL Analytical Report
Project: 11-0427, Barber's Orchard
Superfund Remedial
4SESD-ASB
Terri White
ICS Chemist
ASB Inorganic Chemistry Section
Jenny Scifres, ChiefTHRU:
TO: Don Hunter
Attached are the final results for the analytical groups listed below. These analyses were performed in
accordance with the Analytical Support Branch's (ASB) Laboratory Operations and Quality Assurance Manual
(ASB LOQAM) found at www.epa.gov/region4/sesd/asbsop. Any unique project data quality objectives
specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the
Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and may have
been qualified if the applicable quality control criteria were not met. For a listing of specific data qualifiers and
explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are
accurate within the limits of the method(s) and are representative only of the samples as received by the
laboratory.
Analyses Included in this report: Method Used:
Total Metals (TMTL)
EPA 200.8Total Metals
Page 1 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Sample Disposal Policy
Because of the laboratory's limited space for long term sample storage, our policy is to dispose of samples on a
periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts
and/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample
disposal policy does not apply to criminal samples which are held until the laboratory is notified by the criminal
investigators that case development and litigation are complete.
These samples may be held in the laboratory's custody for a longer period of time if you have a special project
need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control
Coordinator, Debbie Colquitt, by e-mail at [email protected], and provide a reason for holding samples
beyond 60 days
cc: Nardina Turner
Page 2 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Date ReceivedDate CollectedMatrixLaboratory IDSample ID
SAMPLES INCLUDED IN THIS REPORT
Project: 11-0427, Barber's Orchard
BO0128910511 E112206-01 Potable Water 5/24/11 08:40 5/25/11 9:35
BO0154590511 E112206-02 Potable Water 5/24/11 13:45 5/25/11 9:35
BO0188890511 E112206-03 Potable Water 5/23/11 16:55 5/25/11 9:35
BO0270480511 E112206-04 Potable Water 5/23/11 17:47 5/25/11 9:35
BO0385570511 E112206-05 Potable Water 5/23/11 15:10 5/25/11 9:35
BO1037720511 E112206-06 Potable Water 5/23/11 15:20 5/25/11 9:35
BO1154760511 E112206-07 Potable Water 5/24/11 15:25 5/25/11 9:35
BO1159040511 E112206-08 Potable Water 5/23/11 18:00 5/25/11 9:35
BO1159040511D E112206-09 Potable Water 5/23/11 18:00 5/25/11 9:35
BO1202610511 E112206-10 Potable Water 5/24/11 10:15 5/25/11 9:35
BO1245800511 E112206-11 Potable Water 5/23/11 16:50 5/25/11 9:35
BO2430880511 E112206-12 Potable Water 5/24/11 12:15 5/25/11 9:35
BO3247820511 E112206-13 Potable Water 5/24/11 11:15 5/25/11 9:35
BO4381270511 E112206-14 Potable Water 5/24/11 11:45 5/25/11 9:35
MW010511 E112206-15 Groundwater 5/23/11 17:30 5/25/11 9:35
MW020511 E112206-16 Groundwater 5/23/11 17:35 5/25/11 9:35
MW030511 E112206-17 Groundwater 5/24/11 14:30 5/25/11 9:35
MW050511 E112206-18 Groundwater 5/24/11 09:30 5/25/11 9:35
MW090511 E112206-19 Groundwater 5/24/11 16:15 5/25/11 9:35
MW150511 E112206-20 Groundwater 5/24/11 09:10 5/25/11 9:35
MW170511 E112206-21 Groundwater 5/24/11 17:30 5/25/11 9:35
QAPB010511 E112213-01 Preservative Blank 5/26/11 08:45 5/26/11 11:45
BO2217660511 E112213-02 Potable Water 5/25/11 08:40 5/26/11 11:45
BO2300040511 E112213-03 Potable Water 5/25/11 09:30 5/26/11 11:45
MW040511 E112213-04 Groundwater 5/25/11 15:00 5/26/11 11:45
MW040511D E112213-05 Groundwater 5/25/11 15:00 5/26/11 11:45
MW100511 E112213-06 Groundwater 5/25/11 10:10 5/26/11 11:45
MW110511 E112213-07 Groundwater 5/26/11 08:15 5/26/11 11:45
MW120511 E112213-08 Groundwater 5/25/11 17:05 5/26/11 11:45
MW130511 E112213-09 Groundwater 5/25/11 14:15 5/26/11 11:45
MW140511 E112213-10 Groundwater 5/25/11 16:35 5/26/11 11:45
MW160511 E112213-11 Groundwater 5/26/11 08:30 5/26/11 11:45
Page 3 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
DATA QUALIFIER DEFINITIONS
U The analyte was not detected at or above the reporting limit.
B-2 Reporting level elevated due to trace amounts of analyte present in the method blank.
D-4 MRL elevated due to interferences.
J The identification of the analyte is acceptable; the reported value is an estimate.
QR-1 MRL verification recovery less than lower control limits.
QR-2 MRL verification recovery greater than upper control limits.
ACRONYMS AND ABBREVIATIONS
CAS Chemical Abstracts Service
Note: Analytes with no known CAS identifiers have been assigned codes beginning with "E", the EPA ID as assigned by
the EPA Substance Registry System (www.epa.gov/srs), or beginning with "R4-", a unique identifier assigned by the EPA
Region 4 laboratory.
MDL Method Detection Limit - The minimum concentration of a substance (an analyte) that can be measured and
reported with a 99% confidence that the analyte concentration is greater than zero.
MRL Minimum Reporting Limit - Analyte concentration that corresponds to the lowest demonstrated level of acceptable
quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and
moisture content of soil/sediments.
TIC Tentatively Identified Compound - An analyte identified based on a match with the instrument software's mass
spectral library. A calibration standard has not been analyzed to confirm the compound's identification or the
estimated concentration reported.
Page 4 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO0128910511 E112206-01
Matrix: Potable Water
Date Collected: 5/24/11 8:40
Project: 11-0427, Barber's Orchard
Station ID: BO012891
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:0112:11
Chromium ug/L EPA 200.82.0 J, QR-27440-47-3 1.0 6/24/116/08/1119:0112:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:0112:11
Page 5 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO0154590511 E112206-02
Matrix: Potable Water
Date Collected: 5/24/11 13:45
Project: 11-0427, Barber's Orchard
Station ID: BO015459
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:1112:11
Chromium ug/L EPA 200.85.27440-47-3 1.0 6/24/116/08/1119:1112:11
Lead ug/L EPA 200.8127439-92-1 1.0 6/24/116/08/1119:1112:11
Page 6 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO0188890511 E112206-03
Matrix: Potable Water
Date Collected: 5/23/11 16:55
Project: 11-0427, Barber's Orchard
Station ID: BO018889
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:1412:11
Chromium ug/L EPA 200.81.2 J, QR-27440-47-3 1.0 6/24/116/08/1119:1412:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:1412:11
Page 7 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO0270480511 E112206-04
Matrix: Potable Water
Date Collected: 5/23/11 17:47
Project: 11-0427, Barber's Orchard
Station ID: BO027048
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:1812:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:1812:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:1812:11
Page 8 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO0385570511 E112206-05
Matrix: Potable Water
Date Collected: 5/23/11 15:10
Project: 11-0427, Barber's Orchard
Station ID: BO038557
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:2112:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:2112:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:2112:11
Page 9 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO1037720511 E112206-06
Matrix: Potable Water
Date Collected: 5/23/11 15:20
Project: 11-0427, Barber's Orchard
Station ID: BO103772
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:3212:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:3212:11
Lead ug/L EPA 200.84.97439-92-1 1.0 6/24/116/08/1119:3212:11
Page 10 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO1154760511 E112206-07
Matrix: Potable Water
Date Collected: 5/24/11 15:25
Project: 11-0427, Barber's Orchard
Station ID: BO115476
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:3512:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:3512:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:3512:11
Page 11 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO1159040511 E112206-08
Matrix: Potable Water
Date Collected: 5/23/11 18:00
Project: 11-0427, Barber's Orchard
Station ID: BO115904
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:3912:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:3912:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:3912:11
Page 12 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO1159040511D E112206-09
Matrix: Potable Water
Date Collected: 5/23/11 18:00
Project: 11-0427, Barber's Orchard
Station ID: BO115904
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:4212:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:4212:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:4212:11
Page 13 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO1202610511 E112206-10
Matrix: Potable Water
Date Collected: 5/24/11 10:15
Project: 11-0427, Barber's Orchard
Station ID: BO120261
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:4512:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:4512:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:4512:11
Page 14 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO1245800511 E112206-11
Matrix: Potable Water
Date Collected: 5/23/11 16:50
Project: 11-0427, Barber's Orchard
Station ID: BO124580
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:4912:11
Chromium ug/L EPA 200.82.2 U, D-47440-47-3 2.2 6/24/116/08/1119:4912:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:4912:11
Page 15 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO2430880511 E112206-12
Matrix: Potable Water
Date Collected: 5/24/11 12:15
Project: 11-0427, Barber's Orchard
Station ID: BO243088
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:5212:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:5212:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:5212:11
Page 16 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO3247820511 E112206-13
Matrix: Potable Water
Date Collected: 5/24/11 11:15
Project: 11-0427, Barber's Orchard
Station ID: BO324782
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:5612:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:5612:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1119:5612:11
Page 17 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO4381270511 E112206-14
Matrix: Potable Water
Date Collected: 5/24/11 11:45
Project: 11-0427, Barber's Orchard
Station ID: BO438127
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1119:5912:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1119:5912:11
Lead ug/L EPA 200.81.07439-92-1 1.0 6/24/116/08/1119:5912:11
Page 18 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW010511 E112206-15
Matrix: Groundwater
Date Collected: 5/23/11 17:30
Project: 11-0427, Barber's Orchard
Station ID: MW01
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1120:0312:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1120:0312:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1120:0312:11
Page 19 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW020511 E112206-16
Matrix: Groundwater
Date Collected: 5/23/11 17:35
Project: 11-0427, Barber's Orchard
Station ID: MW02
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.37440-38-2 1.0 6/24/116/08/1120:2012:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1120:2012:11
Lead ug/L EPA 200.81.47439-92-1 1.0 6/24/116/08/1120:2012:11
Page 20 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW030511 E112206-17
Matrix: Groundwater
Date Collected: 5/24/11 14:30
Project: 11-0427, Barber's Orchard
Station ID: MW03
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1120:2312:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1120:2312:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1120:2312:11
Page 21 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW050511 E112206-18
Matrix: Groundwater
Date Collected: 5/24/11 9:30
Project: 11-0427, Barber's Orchard
Station ID: MW05
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1120:2712:11
Chromium ug/L EPA 200.81.9 J, QR-27440-47-3 1.0 6/24/116/08/1120:2712:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1120:2712:11
Page 22 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW090511 E112206-19
Matrix: Groundwater
Date Collected: 5/24/11 16:15
Project: 11-0427, Barber's Orchard
Station ID: MW09
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1120:3012:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1120:3012:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1120:3012:11
Page 23 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW150511 E112206-20
Matrix: Groundwater
Date Collected: 5/24/11 9:10
Project: 11-0427, Barber's Orchard
Station ID: MW15
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U7440-38-2 1.0 6/24/116/08/1120:3412:11
Chromium ug/L EPA 200.81.0 U7440-47-3 1.0 6/24/116/08/1120:3412:11
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1120:3412:11
Page 24 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW170511 E112206-21
Matrix: Groundwater
Date Collected: 5/24/11 17:30
Project: 11-0427, Barber's Orchard
Station ID: MW17
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1115:1812:18
Chromium ug/L EPA 200.81.0 U, J, QR-17440-47-3 1.0 6/24/116/08/1115:1812:18
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1115:1812:18
Page 25 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: QAPB010511 E112213-01
Matrix: Preservative Blank
Date Collected: 5/26/11 8:45
Project: 11-0427, Barber's Orchard
Station ID:
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1115:2112:18
Chromium ug/L EPA 200.81.0 U, J, QR-17440-47-3 1.0 6/24/116/08/1115:2112:18
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1115:2112:18
Page 26 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO2217660511 E112213-02
Matrix: Potable Water
Date Collected: 5/25/11 8:40
Project: 11-0427, Barber's Orchard
Station ID: BO221766
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1115:2512:18
Chromium ug/L EPA 200.81.0 U, J, QR-17440-47-3 1.0 6/24/116/08/1115:2512:18
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1115:2512:18
Page 27 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: BO2300040511 E112213-03
Matrix: Potable Water
Date Collected: 5/25/11 9:30
Project: 11-0427, Barber's Orchard
Station ID: BO230004
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1115:3512:18
Chromium ug/L EPA 200.81.0 U, J, QR-17440-47-3 1.0 6/24/116/08/1115:3512:18
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1115:3512:18
Page 28 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW040511 E112213-04
Matrix: Groundwater
Date Collected: 5/25/11 15:00
Project: 11-0427, Barber's Orchard
Station ID: MW04
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 J, QR-17440-38-2 1.0 6/24/116/08/1115:3912:18
Chromium ug/L EPA 200.83.1 J, QR-17440-47-3 1.0 6/24/116/08/1115:3912:18
Lead ug/L EPA 200.8117439-92-1 1.0 6/24/116/08/1115:3912:18
Page 29 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW040511D E112213-05
Matrix: Groundwater
Date Collected: 5/25/11 15:00
Project: 11-0427, Barber's Orchard
Station ID: MW04
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1115:4912:18
Chromium ug/L EPA 200.82.0 J, QR-17440-47-3 1.0 6/24/116/08/1115:4912:18
Lead ug/L EPA 200.86.07439-92-1 1.0 6/24/116/08/1115:4912:18
Page 30 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW100511 E112213-06
Matrix: Groundwater
Date Collected: 5/25/11 10:10
Project: 11-0427, Barber's Orchard
Station ID: MW10
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1115:5212:18
Chromium ug/L EPA 200.81.0 U, J, QR-17440-47-3 1.0 6/24/116/08/1115:5212:18
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1115:5212:18
Page 31 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW110511 E112213-07
Matrix: Groundwater
Date Collected: 5/26/11 8:15
Project: 11-0427, Barber's Orchard
Station ID: MW11
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1115:5612:18
Chromium ug/L EPA 200.82.0 J, QR-17440-47-3 1.0 6/24/116/08/1115:5612:18
Lead ug/L EPA 200.81.4 U, B-27439-92-1 1.4 6/24/116/08/1115:5612:18
Page 32 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW120511 E112213-08
Matrix: Groundwater
Date Collected: 5/25/11 17:05
Project: 11-0427, Barber's Orchard
Station ID: MW12
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1115:5912:18
Chromium ug/L EPA 200.81.0 U, J, QR-17440-47-3 1.0 6/24/116/08/1115:5912:18
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1115:5912:18
Page 33 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW130511 E112213-09
Matrix: Groundwater
Date Collected: 5/25/11 14:15
Project: 11-0427, Barber's Orchard
Station ID: MW13
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1116:0312:18
Chromium ug/L EPA 200.81.0 U, J, QR-17440-47-3 1.0 6/24/116/08/1116:0312:18
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1116:0312:18
Page 34 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW140511 E112213-10
Matrix: Groundwater
Date Collected: 5/25/11 16:35
Project: 11-0427, Barber's Orchard
Station ID: MW14
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.81.0 U, J, QR-17440-38-2 1.0 6/24/116/08/1116:0612:18
Chromium ug/L EPA 200.81.4 J, QR-17440-47-3 1.0 6/24/116/08/1116:0612:18
Lead ug/L EPA 200.81.0 U7439-92-1 1.0 6/24/116/08/1116:0612:18
Page 35 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Total Metals
Sample ID: Lab ID: MW160511 E112213-11
Matrix: Groundwater
Date Collected: 5/26/11 8:30
Project: 11-0427, Barber's Orchard
Station ID: MW16
CAS
Number Analyte Results Qualifiers Units MRL Prepared Analyzed Method
Arsenic ug/L EPA 200.83.9 J, QR-17440-38-2 1.0 6/24/116/08/1116:1012:18
Chromium ug/L EPA 200.85.77440-47-3 1.0 6/24/116/08/1116:1012:18
Lead ug/L EPA 200.8167439-92-1 1.0 6/24/116/08/1116:1012:18
Page 36 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
Batch 1106042 - M 200.2 Metals Water
Blank (1106042-BLK1) Prepared: 06/08/11 Analyzed: 06/24/11
EPA 200.8Chromium ug/LU 1.0 U
Arsenic "U 1.0 U
Lead "U 1.0 U
LCS (1106042-BS1) Prepared: 06/08/11 Analyzed: 06/24/11
EPA 200.8Chromium ug/L208.20 5.0 200.00 85-115104
Arsenic "196.47 5.0 200.00 85-11598.2
Lead "221.50 5.0 200.00 85-115111
Matrix Spike (1106042-MS1) Prepared: 06/08/11 Analyzed: 06/24/11 Source: E112206-01
EPA 200.8Chromium ug/L207.05 5.0 200.00 2.0496 70-130103
Arsenic "186.27 5.0 200.00 U 70-13093.1
Lead "222.08 5.0 200.00 0.59121 70-130111
Matrix Spike (1106042-MS2) Prepared: 06/08/11 Analyzed: 06/24/11 Source: E112206-15
EPA 200.8Chromium ug/L205.21 5.0 200.00 0.91611 70-130102
Arsenic "203.49 5.0 200.00 U 70-130102
Lead "219.00 5.0 200.00 U 70-130110
Matrix Spike Dup (1106042-MSD1) Prepared: 06/08/11 Analyzed: 06/24/11 Source: E112206-01
EPA 200.8Chromium ug/L210.19 5.0 200.00 2.0496 2070-130104 1.50
Arsenic "191.57 5.0 200.00 U 2070-13095.8 2.81
Lead "223.51 5.0 200.00 0.59121 2070-130111 0.640
Matrix Spike Dup (1106042-MSD2) Prepared: 06/08/11 Analyzed: 06/24/11 Source: E112206-15
EPA 200.8Chromium ug/L203.64 5.0 200.00 0.91611 2070-130101 0.768
Arsenic "200.14 5.0 200.00 U 2070-130100 1.66
Lead "215.85 5.0 200.00 U 2070-130108 1.45
Page 37 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
Batch 1106042 - M 200.2 Metals Water
MRL Verification (1106042-PS1) Prepared: 06/08/11 Analyzed: 06/24/11
EPA 200.8Chromium ug/L1.6203 1.0 1.0000 MRL-2,
QR-2
65-135162
Arsenic "0.82929 1.0 1.0000 MRL-2,
U
65-13582.9
Lead "0.82911 1.0 1.0000 MRL-2,
U
65-13582.9
Batch 1106043 - M 200.2 Metals Water
Blank (1106043-BLK1) Prepared: 06/08/11 Analyzed: 06/24/11
EPA 200.8Chromium ug/LU 1.0 U
Arsenic "U 1.0 U
Lead "U 1.0 U
LCS (1106043-BS1) Prepared: 06/08/11 Analyzed: 06/24/11
EPA 200.8Chromium ug/L207.21 5.0 200.00 85-115104
Arsenic "200.65 5.0 200.00 85-115100
Lead "206.91 5.0 200.00 85-115103
Matrix Spike (1106043-MS1) Prepared: 06/08/11 Analyzed: 06/24/11 Source: E112213-02
EPA 200.8Chromium ug/L202.01 5.0 200.00 U 70-130101
Arsenic "197.61 5.0 200.00 U 70-13098.8
Lead "206.33 5.0 200.00 U 70-130103
Matrix Spike (1106043-MS2) Prepared: 06/08/11 Analyzed: 06/24/11 Source: E112213-11
EPA 200.8Chromium ug/L187.98 5.0 200.00 5.7094 70-13091.1
Arsenic "189.54 5.0 200.00 3.9336 70-13092.8
Lead "210.55 5.0 200.00 15.541 70-13097.5
Matrix Spike Dup (1106043-MSD1) Prepared: 06/08/11 Analyzed: 06/24/11 Source: E112213-02
EPA 200.8Chromium ug/L202.18 5.0 200.00 U 2070-130101 0.0863
Arsenic "196.96 5.0 200.00 U 2070-13098.5 0.331
Lead "207.71 5.0 200.00 U 2070-130104 0.669
Page 38 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
Batch 1106043 - M 200.2 Metals Water
Matrix Spike Dup (1106043-MSD2) Prepared: 06/08/11 Analyzed: 06/24/11 Source: E112213-11
EPA 200.8Chromium ug/L192.78 5.0 200.00 5.7094 2070-13093.5 2.52
Arsenic "192.28 5.0 200.00 3.9336 2070-13094.2 1.43
Lead "216.38 5.0 200.00 15.541 2070-130100 2.73
MRL Verification (1106043-PS1) Prepared: 06/08/11 Analyzed: 06/24/11
EPA 200.8Chromium ug/LU 1.0 1.0000 MRL-2,
QR-1, U
65-135
Arsenic "0.53098 1.0 1.0000 MRL-2,
QR-1, U
65-13553.1
Lead "1.1162 1.0 1.0000 MRL-265-135112
Page 39 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
D.A.R.T. Id: 11-0427
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
Project: 11-0427, Barber's Orchard - Reported by Terri White
Notes and Definitions for QC Samples
U The analyte was not detected at or above the reporting limit.
B-4 Level in blank impacts MRLs.
MRL-2 MRL verification for Non-Potable Water matrix
QR-1 MRL verification recovery less than lower control limits.
QR-2 MRL verification recovery greater than upper control limits.
Page 40 of 40 E112206,E112213 TMTL FINAL 7/4/11 17:11
