Job Safety Assessment Form

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    Since Design for Safety is one of the key factors in the competition, we would like you to

    complete tx he attached Job Safety Assessment (JSA !orm" !ill in as much data as a#ailable" $f

    data are not a#ailable, lea#e the %eld blank" &he JSA should send us before February 15th,

    2014"

    Job Safety Assessment FormIndonesia Chem-E-Car Competition 2014

    ni!ersity' State olythecnic of )andung "ehi#$e %ame& Semar )adranayaJSA Author Conta#t %ame' Sidna *osim A" Author Emai$& sidna+osimgmail"comFa#u$ty Super!isor& -aryadi, h"D" Super!isor Emai$& rif+ishabiragmail"com'e!ision (' 'e!ision )ate'

    *urpose of E+periment Euipment& )rie.y describe your /hem010/ars design, intendedmode for operation (source of power, intended mode for

    control (stopping, and ma2or ha3ards and their control"

    )es#ribe your #ar.s desi/n&

    &he car that use hydrogen gas fuel produced from the reaction between Al and -/l supplied tothe fuel cell proton exchange membrane type that can generate electrical energy" &hen theelectricity generated is supplied to the motor to dri#e the wheels"

    *oer sour#e&

    Semar )adranaya uses !uel cell as power source" !uel cell is energy con#erters of chemical to

    electrical energy is en#ironmentally friendly" !uel cells are designed to be charged reactant isconsumed where the fuel cell to produce electricity and supply of hydrogen fuel and oxygen fromthe outside" !uel cell is classi%ed as a power plant for Semar )adranaya because fuel cells canoperate continuously or as long as there is a fuel supply and oxidant" Semar )adranaya usesroton 1xchange 4embrane (14 type of !uell /ell" &he membrane is a thin layer of solidelectrolyte separator which ser#es the cathode and anode" &his membrane is selecti#ely controlthe transport of protons from the anode to the cathode in a fuel cell" 14 catalyst containingplatinum ( t " $n addition, the fuel cell does not use corrosi#e .uids such as other types of fuelcells" -ydrogen as a fuel is consumed at the anode , producing electrons that are drawn to thecathode through the external circuit " -ydrogen ions enter the electrolyte solution and dispersedto the cathode by elektroosmotik .ow " At the cathode , oxygen is combined with the .ow ofelectrons and protons from the electrolyte to produce water and heat " $onic li+uids fuel cell ( $5!s

    is a hydrogen 0based fuel cell with an ionic li+uid as the electrolyte , which ser#es as a mediumfor proton ( - 6 migrate from the anode to the cathode "

    Stoppin/ me#hanism&

    /orrotion reaction with !e and -/l" &o stop the mechanism, reaction between hydrochloric acidand !errous is used" 7hen !errous is completely diluted in hydrochloric acid, the electricitysupply to the motor will be stopped"

    aards inherent in desi/n&

    8

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    /ontamination sensiti#e to foreign substances

    -ydrogen fuel cells re+uire pure , free from contamination of foreign substances " !oreign

    substances which include sulfur , a mixture of carbon compounds , etc" can deacti#ate thecatalyst in fuel cells and will e9ecti#ely destroy it " $n the heat of combustion engine ( internalcombustion engines , the entry of foreign substances that do not impede the con#ersion ofenergy through the combustion process "

    Safety measures'

    8" Doing trial and error to prepare reaction concept":" ;se glo#es" ;se white lab coat

    Chemi#a$ 'ea#tions& ro#ide details below on any chemical reaction(s that occur in yourprocess" lease show the species in#ol#ed, the stoichiometry and the heatof reaction, if a#ailable" Also list side reactions and any other reactions that

    may impact safety"

    :Al(s 6 ?-/l (a+ :Al/l@ (a+ 6

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    emperature *ressureormal ' :>o/ ( place condition ormal ' 8 atm4inimum ' EF o/ ( fuell cell reaction 4inimum ' 8 atm4aximum ' G EFo/ 4aximum ' : atm

    )isa$$oed A#ti!ities& All acti#ities listed below are not allowed""

    Item

    (a o transport of chemicals in pri#ate, uni#ersity or rental #ehicles either to or from thecompetition"

    (b /hemicals must not be stored in hotel rooms or other facilities not rated for chemical storage"Appro#ed chemical storage will be pro#ided at the host site"

    (c o #ehicle testing in hotel or dorm hallways, warehouses, or other facilities that are notdesigned for chemical handling" &his includes your uni#ersity and the competition site"

    (d o improper disposal of chemicals at the conclusion of the competition" All chemicalsshipped to the competition site must be disposed of in a safe and en#ironmental fashionfollowing all local, state and national regulatory measures" /hemical disposal will normally bepro#ided by the host site"

    )isa$$oed "ehi#$es& All of the items listed below are not allowed"

    Item E+p$anation

    (a !lames andHor smoke )oth inside and outside the #ehicle, except for commercial internalcombustion engines" See /hem010/ar Cules for using commercialinternal combustion engines"

    (b 5i+uid Discharge 5i+uid may not be discharged under normal operating conditions"(c Bpen andHor

    improperly securedcontainers

    /ontaining chemicals ha#ing an !A rating of : or greater"o open containers allowed at the starting line or during theoperation of your #ehicle" All containers with these chemicals mustha#e secure lids and must be secured to the #ehicle" All containersbrought to the starting line must ha#e lids, be properly labeled, andproper personal protecti#e e+uipment must be used"

    (d /hemical pouring atstarting line

    Any chemicals with an !A rating of : or greater" ;se a holding#essel on #ehicle, with #al#e, to load starting chemicals"

    (e Cegulated /hemicals A number of chemicals are listed by BS-A as a special ha3ard" Seelist below" BS-A has a special regulation for each chemical" Seeosha/o!for details"

    (f -ighly Ceacti#e H;nstable /hemicals

    Any chemical, raw material, intermediate or product with an !Areacti#ity H instability rating of ="

    (g -ydrogen peroxide -ydrogen peroxide at concentrations of greater than

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    'e/u$ated #hemi#a$s&

    "ehi#$e *rimary aards Che#6$ist& /heck the left hand column box if the ha3ards listed

    below exist on the #ehicle" &hen check the applicablemeans of control for each ha3ard"

    aard7#he#6 if present8

    Contro$

    (a ressure Anything greater than 8 psig 9ust meet a$$ reuirements be$o&ressure gauge (must read to :x max" operating pressure1mergency relief de#ice set to no more than 8"8 times max" operatingpressure" Celief si3ing calculations must be pro#ided"1mergency relief de#ice in proper location"ressure certi%cation K see ressure Lessel &esting rotocolroper management system to pre#ent o#er or mis0charging"

    All car components exposed to pressure must be certi%ed to operate atthat pressure" ro#ide manufacturers pressure speci%cations"oL/, cL/ or polyethylene terephthalate (1&1 or 1& plastics inpressure ser#ice

    9ust ha!e measurements or #a$#u$ations to pro!e ma+imumoperatin/ pressureSee Chem-E-Car 'u$es for more detai$s on these reuirements

    (b &oxic Any chemicals with an !A toxicity of : or greaterDoubly contained and handled properly"

    (c !lammable Any chemicals with an !A .ammability rating of : or higherDoubly contained and handled properly

    (d Ceacti#e Any chemicals with an !A instability H reacti#ity rating of : or

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    Chemi#a$ Information *a/e

    !ill in as much data below as a#ailable" $f data are not a#ailable, lea#e the %eldblank"

    Chemi#a$ :uantities& 5ist below the chemical names, concentrations, and total+uantity of chemical re+uired for the competition"

    Chemi#a$%ame

    Chemi#a$StateSo$id,

    ;iuid,

    C$(hydrochloricacid

    5i+uid0 84 K ?4

    A$(aluminium

    Solid 0 : O 8F cm

    Fe(ferrousmetals

    Solid 0 =F cm long

    Chemi#a$ *roperties and aards for A;; CE9ICA;S, in#$udin/rea#tants, intermediates and produ#ts

    Chemi#a$%ame

    *hysi#a$

    StateS, ;,