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2007 Oxidation O 0212 Iron and Manganese(III)—Porphyrins as New Applicable Catalysts for Selective Oxidation of Imines with Urea—Hydrogen Peroxide. — The system urea/hydrogen peroxide with iron(III) tetraphenylporphyrins as catalyst is used to oxidize imines. N-Aryl imines yield nitrones, whereas N-alkyl imines affordoxaziridines. Manga- nese(III) porphyrin complexes give comparable results. — (KARAMI*, B.; MONTAZEROZOHORI, M.; MOGHADAM, M.; FARAHI, M.; J. Chem. Res. 2007, 5, 275-277; Dep. Chem., Yasouj Univ., Yasouj 75914-353, Iran; Eng.) — M. Bohle 47- 035

Iron and Manganese(III)—Porphyrins as New Applicable Catalysts for Selective Oxidation of Imines with Urea—Hydrogen Peroxide

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Page 1: Iron and Manganese(III)—Porphyrins as New Applicable Catalysts for Selective Oxidation of Imines with Urea—Hydrogen Peroxide

2007

OxidationO 0212 Iron and Manganese(III)—Porphyrins as New Applicable Catalysts for Selective

Oxidation of Imines with Urea—Hydrogen Peroxide. — The system urea/hydrogen peroxide with iron(III) tetraphenylporphyrins as catalyst is used to oxidize imines. N-Aryl imines yield nitrones, whereas N-alkyl imines affordoxaziridines. Manga-nese(III) porphyrin complexes give comparable results. — (KARAMI*, B.; MONTAZEROZOHORI, M.; MOGHADAM, M.; FARAHI, M.; J. Chem. Res. 2007, 5, 275-277; Dep. Chem., Yasouj Univ., Yasouj 75914-353, Iran; Eng.) — M. Bohle

47- 035