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Strengthening mechanisms in nanostructured Al/SiC p composite manufactured by accumulative press bonding Sajjad Amirkhanlou a,b,c,* , Mehdi Rahimian c,d , Mostafa Ketabchi a , Nader Parvin a , Parisa Yaghinali a , Fernando Carreño b a Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran, Iran b Department of Physical Metallurgy, CENIM-CSIC, Av. Gregorio del Amo 8, 28040 Madrid, Spain c Institute of Materials and Manufacturing, Brunel University London, London UB8 3PH, United Kingdom d IMDEA Materials Institute, C/Eric Kandel 2, 28906, Getafe, Madrid, Spain * Corresponding author: Email: [email protected]; [email protected] Abstract The strengthening mechanisms in nanostructured Al/SiC p composite deformed to high strain by a novel severe plastic deformation process, accumulative press bonding (APB), was investigated. The composite exhibited yield strength of 148 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24

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Strengthening mechanisms in nanostructured Al/SiCp composite

manufactured by accumulative press bonding

Sajjad Amirkhanlou a,b,c,*, Mehdi Rahimian c,d, Mostafa Ketabchi a, Nader Parvin a, Parisa Yaghinali

a, Fernando Carreño b

a Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran, Iran

b Department of Physical Metallurgy, CENIM-CSIC, Av. Gregorio del Amo 8, 28040 Madrid, Spain

c Institute of Materials and Manufacturing, Brunel University London, London UB8 3PH, United Kingdom 

d IMDEA Materials Institute, C/Eric Kandel 2, 28906, Getafe, Madrid, Spain

* Corresponding author: Email: [email protected];

[email protected]

Abstract

The strengthening mechanisms in nanostructured Al/SiCp composite deformed to high

strain by a novel severe plastic deformation process, accumulative press bonding (APB),

was investigated. The composite exhibited yield strength of 148 MPa which was 5 and 1.5

times higher than that of raw aluminum (29 MPa) and aluminum-APB (95 MPa) alloys,

respectively. A remarkable increase was also observed in the ultimate tensile strength of

Al/SiCp-APB composite, 222 MPa, which was 2.5 and 1.2 times greater than the obtained

values for raw aluminum (88 MPa) and aluminum-APB (180 MPa) alloys, respectively.

Analytical models well described the contribution of various strengthening mechanisms.

The contribution of grain boundary, strain hardening, thermal mismatch, Orowan, elastic

mismatch and load-bearing strengthening mechanisms to the overall strength of the

Al/SiCp micro-composite were 64.9, 49, 6.8, 2.4, 5.4 and 1.5 MPa, respectively. Whereas

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Orowan strengthening mechanism was considered as the most dominating strengthening

mechanism in Al/SiCp nanocomposites, it was negligible for strengthening of the micro-

composite. Al/SiCp nanocomposite showed good agreement with quadratic summation

model; however, experimental results exhibited a good accordance with arithmetic and

compounding summation models in the micro-composite. While average grain size of the

composite reached 380 nm, it was less than 100 nm in the vicinity of SiC particles as a

result of particle stimulated nucleation mechanism.

Keywords: Accumulative press bonding (APB); Severe plastic deformation (SPD);

Strengthening mechanisms; Analytical models; Metal matrix composites; Nanostructured

materials

1- Introduction

Aluminum matrix composites (AMCs), reinforced with particulate reinforcement, have

attracted considerable attention in automotive and aerospace industries, due to their low

weight and high mechanical properties [1, 2]. Silicon carbide (SiCp) is considered as a

typical cost effective particulate reinforcement used widely in AMCs because of its high

strength and modulus [3, 4]. Traditional processing routes for fabrication of Al/SiCp

composite, including casting, powder metallurgy and spray forming encounter various

shortcomings. The main drawbacks of those liquid state techniques [5, 6] can be referred as

SiCp agglomeration, weak adhesion and undesirable chemical reaction occurred between

Al and SiCp [7, 8]. However, manufacturing techniques in solid state can overcome the

above problems [9-11]. Microstructure and mechanical properties of Al/SiCp composite,

manufactured by accumulative roll bonding (ARB) as a solid-state process, was evaluated

by Jamaati et al. [12-14]. Accumulative press bonding (APB), introduced for the first time

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in our previous works, is another severe plastic deformation process [15, 16] enabling us to

fabricate particle reinforced AMCs. Uniform distribution of reinforcement, nano/ultra-fine

structure and high mechanical properties are obtained using APB process [17-20]. Many

researches were focused on the fabrication and characterization Al/SiCp composites

prepared by metal forming processes [21, 22]. However, individual contributions of

various micromechanics strengthening factors in AMCs deformed to high strain were not

investigated in previous studies. In this study the novel APB process was utilized for

fabrication of Al/SiCp composite and the effect and proportion of various strengthening

mechanisms on the final yield strength was assessed. Moreover, advanced microstructural

characterization techniques were employed to verify each strengthening mechanism.

2- Experimental procedure

As-received AA1050 aluminum sheets, chemical composition is given in Table 1, and SiC

particles with an average size of 10 m were used as raw materials. Aluminum sheets with

the dimensions of 100 mm 50 mm 1.5 mm were annealed at 623 K (350 ºC) for 1 h.

The accumulative press bonding (APB) process for manufacturing of the Al/10 vol.% SiCp

composite was schematically reported in ref. [23, 24]. The aluminum sheets were

degreased in acetone bath followed by scratch brushing with 0.4 mm wire diameter and

peripheral speed of 2800 rpm. The reinforcement particles were uniformly spread between

surfaces by a hand sprayer. A hydraulic press machine was utilized to form a mechanical

bond between two stacked sheets, in a channel die, where the thickness of sheets reduced

by 50%. The APB process was performed at ambient temperature. The fabricated sheet

was cut in two pieces and the whole mentioned process was repeated 5 times in order to

increase SiC particles to 10 vol.%. Thereafter, the above process was repeated 7 times but

without any reinforcement addition. The same process was employed for the production of

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the monolithic aluminum in which the aluminum sheets were processed by APB without

adding any SiCp powder through the process.

Tensile tests were performed according to ASTM E8 standard at a rate of 1.610−1 s−1 by

a Houndsfield H50KS machine. The gauge width, thickness and length of specimens were

6, 1.5 and 25 mm, respectively. Various microstructural aspects of specimens were

investigated by transmission electron microscopy (TEM, JEOL JEM 2000 FX II, JEOL

Ltd. Tokyo, Japan) operating at 200 kV and field-emission scanning transmission electron

microscopy (FE-STEM, HITACHI S-4800, Hitachi Ltd., Tokyo, Japan) operating at 10 kV

complemented by energy-dispersive spectroscopy (EDS, 10mm2 SDD Detector X-ACT,

Oxford instrument, Oxford, England). Also the grain boundary characterization was

performed by electron backscattered diffraction (EBSD, JEOL JSM 6500 F) adjusted at 20

kV with a working distance of 15 mm, step size of 80 nm and tilt angle of 70º. Thin foils

required for EBSD, TEM and STEM investigations were mechanically ground and

punched into 3 mm discs with an average thickness of less than 100 μm. The discs were

subsequently thinned to perforation using a twin-jet electropolishing facility (TenuPol-5,

Struers) with a solution of 30% nitric acid and 70% methanol at 11 V and 245 K (−28 ºC).

The X-ray pattern of the manufactured Al/SiCp composite was recorded with an X-ray

diffractometer (XRD). The XRD experiment was conducted by a Philips X’PERT MPD X-

ray diffractometer with CuKα radiation in the range of 2θ=25 °−95 ° using a step size of

0.05 ° and a counting time of 1 s per step. Consequently, XRD patterns were analyzed via

X’Pert HighScore software.

3- Results and discussion

The stress-strain curves of annealed aluminum (Al), monolithic aluminum (Al-APB) and

Al/SiCp-APB composite are shown in Figure 1. According to the Figure 1, the yield

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strength of the aluminum, which is 29 MPa, was improved by 5 times, as it increases to

148 MPa. A remarkable increase was also observed in the ultimate tensile strength of

Al/SiCp-APB composite, 222 MPa, which was 2.5 and 1.2 times greater than the obtained

values for raw aluminum (88 MPa) and aluminum-APB (180 MPa) alloys, respectively.

Although this study has not been done previously, relevant composites fabricated via other

production processes are summarized in Table 2. The superior strength of the produced

composite through APB process is obtained mainly due to the uniform distribution of

particles, formation of ultra-fine structure and low level of porosity. The enhancement of

composite’s strength can be described by different mechanisms. In following sections,

microstructural evidences and theoretical models are employed to explain each

strengthening mechanism.

3-1- Grain boundary

Figure 2 shows STEM micrographs of Al/SiCp composite after various cycles of APB

process. It is observed that gradual grain refining occurred during process and grains are

slightly elongated in the longitudinal direction. Average grain size reduced to 380 nm after

14 cycles of APB, Figure 2e. Grain refining is the most desirable strengthening mechanism

because it is only mechanism which leads to simultaneous increment of strength and

toughness [25, 26]. The formation mechanism of nano grains by the APB process is

considered as continuous dynamic recovery (CDR). In CDR the size of small (sub) grains

remains constant, whereas grains misorientation increases. In fact, there isn’t any

nucleation and growth of deformed nuclei in CDR, because the dislocations glide directly

from one side of grain to the other side resulting in the increment of grains misorientation.

This is the most equilibrated way of obtaining the finest and sharpest histogram of grain

sizes, which leads to the highest misorientation for the given processing conditions. The

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grain refinement mechanisms of pure aluminum under APB process were discussed in our

previous studies [19, 20]. However, two other factors encourage CDR of Al/SiCp

composite including severe shear deformation and micro-size particles. In fact, finer grain

size can be obtained in APB process on account of the present of non-deformable

reinforcements. Figure 3 displays the interface of the SiC particle and aluminum matrix.

The finer grain sizes are recognized in the vicinity of SiC particles where the average grain

size measured less than 100 nm. When the composite is exposed by deformation during the

process, the existence of non-deformable particles induces strain to their vicinity. As a

result, the vicinity of particles is fertilized to form new boundaries due to the introduction

of a high dislocation density, referred as particle stimulated nucleation (PSN) [27, 28]. The

accumulation of dislocations in the vicinity of particles facilitated the formation of fine

grains by continuous dynamic recovery mechanism. Consequently, the average grain size

of the composite, 380 nm, is finer than that of monolithic aluminum which is 450 nm [19].

Other factor, considered for grain refinement of pure aluminum and the composite, is

severe shear deformation. TEM micrographs of surface and center of the monolithic

aluminum after one APB cycle are shown in Figure 4. Comparison of Figure 4a and b

demonstrates the higher density of dislocation tangle zones on the surface. This

observation is attributed to the severe shear strain exists between the sample and press

anvil. In each APB cycle, the surface containing higher dislocation density is moved

toward the center resulting in homogeneous distribution of dislocation through the bulk

material. Therefore, dislocations formed because of severe shear contribute to the final

grain refinement. Grain boundary strengthening (∆ σGB) can be explained by well-known

Hall-Petch equation (Eq. 1) [29]. Higher fractions of grain boundaries existing in finer

grain structures increase the number of obstacles against dislocation movement.

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∆ σGB=k y (DG)−12 (1)

where DGis average grain size, k y is constant and typically equal to 40 MPa √ μm for

aluminum alloys [19, 30]. While the grain boundary strengthening was calculated 5.2 MPa

for Al [20], it increased to 59.6 MPa and 64.9 , for Al-APB and Al/SiCp composite,

respectively.

3-2- Thermal mismatch (TM)

Discrepancy of thermal expansion coefficient (CTE) between matrix and reinforcement

acts as a dislocation generation source [31, 32]. Since, thermal expansion coefficient of the

matrix, 23×10−6K−1, differs from the SiCp reinforcement, 4×10−6 K−1, strain is induced to

the matrix around the particles resulting in dislocation formation, as shown in Figure 5a.

Multi-directional thermal stresses at the particle/matrix interface, which are induced by the

difference of thermal expansion between aluminum and SiC particles, result in mismatch

strain around the particles. The system makes an attempt to reduce internal energy,

mismatch strain, via introducing new dislocations [33, 34]. High dislocation density in the

vicinity of particles, observed in Figure 5a, can arrange and form new grain boundaries via

continuous dynamic recovery during APB process, as shown in Figure 5b. Strengthening

effect of thermal mismatch (∆ σTM) can be expressed by the following equations [35, 36]:

∆ σTM=αGb√ ρTM (2)

where G is shear modulus (~25.4 GPa for aluminum) and α is the average value of

dislocation strengthening efficiency (∼1 for pure metals [37]) and b is the Burgers vector

(=0.286 nm [38]). Dislocation density, resulted from CTE mismatch, is governed by

particles volume fraction, V p, difference between processing and ambient temperature,

∆T=100K (100℃) [39], and variation between CTE of particles and matrix,

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∆C=CTE Al−CTESiC=19×10−6K−1. Dislocation density induced by thermal mismatch can

be calculated by [40]:

❑TM=12V p∆T ∆Cb (1−V p )d p

(3)

The amount of ∆ σCTE is calculated around 6.8 MPa for Al/SiCp composite, while this

mechanism is not taken into account for Al and Al-APB alloys.

3-3- Elastic mismatch (EM)

The difference of elastic modulus between matrix and reinforcement introduce an

additional dislocation into the composite in order to reduce induced plastic strain. The

density of generated dislocation due to elastic modulus mismatch can be estimated by Eq.

(4). These dislocations induce additional strength to the composite which is expressed by

Eq. (5) [41]:

ρEM=8V p

bd pε (4)

∆ σEM=αGb√ ρEM (5)

where is yield strain (0.2%) and ❑EM is density of dislocations caused by elastic

mismatch [42]. Whereas, due to absence of reinforcement in Al and Al-APB, there is no

elastic mismatch strengthening effect, it is calculated around 5.4 for Al/SiCp composite.

3-4- Strain hardening

Figure 6 displays EBSD/orientation imaging microscopy (OIM) and grain boundary maps

of Al/SiCp composite. The red/gray lines correspond to the low angle grain boundaries

(LAGBs) having misorientations 2-15º, and the high angle grain boundaries (HAGBs) are

shown as black lines which have misorientations above 15º. The fraction of high angle

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grain boundaries (f HAGB) and the mean misorientation angle of the boundaries (θ) for the

Al/SiCp composite were 73% and 35º, respectively. According to EBSD results, it is

obvious that APB process had a significant effect on the development of an ultra-fine grain

structure surrounded mainly by high-angle boundaries. Formation of the well-developed

high angle boundary during APB process is attributed to the rearrangement of the

dislocations via short-range diffusion [43-46]. As a result of mechanical deformation,

dislocations will be generated resulting in the increment of strength. It is well known that

dislocations tend to array and form low angle grain boundaries during severe plastic

deformation process. Therefore, low angle grain boundaries can be considered as a

dislocation resource. In other word, HAGBs contribute to the grain boundary strengthening

mechanism which is determined by Hall-Petch relation, whereas dislocation strengthening

mechanism is related to LAGBs, as explained by Hansen et al. [47]. The strength imposed

by LAGBs to the system is expressed by:

∆ σDis=αMGb√ ρDis (6)

where is the dislocation strengthening efficiency (the average value = 0.24) and M is the

Taylor factor (for aluminum is 3.06). Following equation shows the density of dislocations

introduced by LAGBs to the system [48, 49]:

ρDis=3 (1−f HAGB )θLAGB

bdr(7)

whereθLAGB ,f HAGB and drare the mean misorientation of LAGBs, volume fraction of

HAGBs and average LAGBs spacing that is measured from EBSD results. ∆ σDis is 8, 47

and 49 MPa for initial aluminum, Al-APB and Al/SiCp composite processed by APB,

respectively.

3-5- Orowan strengthening

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Orowan mechanism corresponds to the interaction of the particles and dislocations in

which nano particles pin dislocations resulting in bowing dislocation around particles and

create Orowan rings. Increment of yield strength, in polycrystalline materials, induced by

Orowan mechanisms can be calculated by [41, 50]:

∆ σorowan=0.4MGb ln(√2/3d

b )π √2/3d (√π /4 v p−1)√1−ϑ

(8)

where ϑ is the Poisson’s ratio (0.33). A small contribution of Orowan strengthening

mechanism, ∆ σorowan=2.4 MPa, in Al/SiCp micro-composite can be interpreted by large

distance of micro-size particles.

3-6- Load-bearing

FE-SEM micrographs of Al/SiCp composite after several APB cycles are shown in then

Figure 7. With increasing number of cycles, the laminar structure is converted into the

homogeneous structure. The formation mechanism of this structure is explained

comprehensively in our previous study [17, 18]. It should be briefly pointed out that

aluminum plastic flow, because of applied stress during APB, led to refinement and

dispersion of SiCp clusters. The high pressures associated with APB resulted in the

squeezing of the Al-matrices within the SiCp clusters producing homogenous structure.

Formation of strong bond between the particles and matrix due to extensive pressure can

be another advantage of current process. Since, in the tensile test a fraction of stress is

transferred to particles, having higher modulus and strength compared with matrix,

composite can withstand higher load than monolithic aluminum. In order to achieve

maximum potential of load-bearing effect, homogeneous distributed particles having

strong bond with matrix are required. Figure 8 displays SEM micrographs of Al/SiCp

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composite produced by APB together with its EDS and X-ray maps. Al4C3 phase, observed

usually in the cast Al/SiCp composites, exhibits detrimental effect on interfacial bonding

and mechanical properties on account of its brittle nature [51]. The X-ray maps (Figure 8b-

f) and X-ray diffraction pattern (Figure 9) show that there is no evidence of undesired

phase such as Al4C3 in the microstructure considered as the advantage of solid state

fabrication of Al/SiCp composite by the current process.

Well distributed particles endure a proportion of applied force imposed directly by tensile

test. The contribution of load-bearing mechanism in increasing of yield strength is

expressed by Eq. 9, which is the modification of shear-lag model:

∆ σLoad=0.5 vpσ m (9)

where vp and σ m are referred to volume fraction of particles and matrix yield strength,

respectively. ∆ σLoad is 1.5 MPa for Al/SiCp composite.

The total yield strength is calculated by three well-known models referred as arithmetic

summation (Eq. 10), quadratic summation (Eq. 11) and compounding methods (Eq. 12)

[41, 52, 53]:

σ Arith.=σ m+∆σ TM+∆σ EM+∆σ Load+∆σ Dis+∆σGB+∆σOrowan (10)

σ Quad.=σ m+√(∆σTM)2+(∆σEM )2+(∆σ Load)2+(∆σ Dis)

2+(∆σGB)2+(∆σOrowan)

2 (11)

σ Comp.=σm+∆ σGB+√(∆σTM )2+(∆σ EM)2+(∆σ Load)2+(∆σ Dis)

2+(∆σOrowan)2 (12)

Contribution of the various strengthening mechanisms as well as yield strength, obtained

by various models and tensile tests, are displayed in Table 3. The influence of each factor

on yield strength of micro-composite is evaluated against that of nanocomposite, which

was investigated in our previous study [20].

Matrix flow through micro-particles is easier than nanoparticles so nanocomposite is

associated with smaller grain (280 nm) compare with composites reinforced with micro-

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particles (380 nm). Therefore, improvement of yield strength due to grain boundary

mechanism is 75.6 MPa for nanocomposite, while this value is 64.9 for Al/SiCp micro-

composite. Although grain boundaries strengthening mechanism has conquered the second

place enhancing mechanical properties in the nanocomposite, it is promoted to first place

in the micro-size composite. By decreasing volume fraction of reinforcement/matrix

interfaces in the macro-composite compare with the nanocomposite, dislocation density

formed in the matrix of micro-composite due to thermal and elastic mismatch is

significantly decreased. Whereas Orowan strengthening mechanism was considered as the

most important strengthening mechanism in nanocomposites, it is negligible for

strengthening of the micro-size composites. As a result of large size and distance of

reinforcement, grains and subgrains interact with dislocations instead of interacting with

SiC particles. Strain hardening and grain boundary strengthening mechanisms are

considered as the two most effective strengthening mechanisms in Al/SiCp micro-

composite. The load transfer effect in both composites is negligible because of particulate

shape and low volume fraction of reinforcement. Since the number of active strengthening

mechanisms in Al/SiCp nanocomposite is considerably higher than the micro-composite,

the final experimental yield strength of the nanocomposite increased up to 210 MPa. Based

on the result of calculations performed by each model, it is understood that experimental

result exhibits a good accordance with arithmetic summation and compounding models in

micro-composite. However, nanocomposite shows good agreement with quadratic

summation model, as demonstrated in previous study [20]. Short dislocation gliding

distance in the nanocomposites imposed by well distributed nanoparticles and concomitant

very fine grains results in the overestimating of calculated results compared with

experimental one. In other words, the first obstacle on the way of dislocation movement,

which can be LAGBs, HAGBs or nanoparticles, leads to the strengthening of

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nanocomposite. Therefore, it is expected that considering the contribution of strain

hardening (LAGBs), grain boundaries (HAGBs) and Orowan (nanoparticles) mechanisms

together in strengthening of nanocomposite, exhibiting an overestimation of the resistance

of the alloy.

4- Conclusions

In the present investigation, the micromechanics strengthening in nanostructured Al/SiCp

composite deformed to high strain by a novel severe plastic deformation process,

accumulative press bonding (ARB), was investigated. The improvement in yield strength

of Al/SiCp composite was described by various strengthening mechanisms. Advanced

microstructural techniques were employed to present evidences of each strengthening

mechanism. The conclusions drawn from the results can be summarized as follows:

1) Homogeneous distribution of SiC particles (with average particle size of 10 µm) was

successfully achieved after 14 cycles of APB process.

2) The EDS maps and X-ray diffraction pattern showed that there was no evidence of

detrimental phases in the microstructure of Al/SiCp composite considered as the

advantage of solid state fabrication process.

3) Nanostructured Al/SiCp composite with the average grain size of 380 nm and well-

developed high-angle grain boundaries (73% high angle boundaries and 35° average

misorientation angle) was obtained by performing 14 cycles of APB process.

4) As a result of particle stimulated nucleation mechanism, grain size of the composite

was less than 100 nm in the vicinity of SiC particles.

5) The yield strength of the aluminum, being 29 MPa, was improved by 5 times, as it

increased to 148 MPa.

6) The contribution of grain boundary, strain hardening, thermal mismatch, Orowan,

elastic mismatch and load-bearing strengthening mechanisms were 64.9, 49, 6.8, 2.4,

5.4 and 1.5 MPa, respectively. Clearly, strain hardening and grain boundary

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mechanisms demonstrate higher contribution to the overall strength of the Al/SiCp

composite.

7) Al/SiCp nanocomposite showed good agreement with quadratic summation model,

however, based on the result of calculations performed by each model, it is understood

that experimental result exhibits a good accordance with arithmetic and compounding

summation models in micro-composite.

Acknowledgment

The authors acknowledge financial support from CICYT (Spain) under program

MAT2012-38962-C03-01, and the Ministry of Science, Research and Technology of Iran.

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Table captions:

Table 1. Chemical composition of AA1050 sheets.

Table 2. Summary of AMCs strength from literatures.

Table 3. Contribution of strengthening mechanisms and yield strength obtained by

theoretical models and experiment in Al/SiCp composites.

Figure captions:

Figure 1. Engineering stress-strain curves of annealed aluminum (Al), monolithic

aluminum (Al-APB) and Al/10 vol.% SiCp composite produced by APB process.

Figure 2. STEM micrographs of Al/SiCp composite after different APB cycles; (a) 2, (b) 5,

(c) 7 and (d) 10 and (e) 14 cycles.

Figure 3. STEM micrograph of aluminum/SiCp interface.

Figure 4. TEM micrographs of aluminum after one cycle of APB process; (a) surface (b)

center of specimen.

Figure 5. TEM micrographs of Al/SiCp interface after 14 cycle of APB process.

Figure 6. Al/SiCp composite after 14 APB cycle: (a) EBSD/OIM and (b) grain boundary

maps.

Figure 7. FE-SEM micrographs of Al/SiCp composite after (a) 1, (b) 3, (c) 5 and (d) 10 and

(e) 14 APB cycles.

Figure 8. (a) SEM micrograph of Al/SiCp composite along with its (b) aluminum, (c)

silicon and (d) carbon X-ray maps. EDS analysis of points (e) 1 and (f) 2.

Figure 9. X-ray diffraction (XRD) pattern of Al/SiCp composite.

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Tables:

Table 1. Chemical composition of AA1050 sheets.

Element Al Si Fe Mn Cu Mg Zn Ti

wt.% Bal. 0.2 0.22 0.02 0.01 0.01 0.01 0.01

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Table 2. Summary of AMCs strength from literatures.

AMCs Methods Reinforcement

particle size

YS (MPa) UTS (MPa) Reference

Al/5 wt.% Al2O3 Casting 20 µm ~112 ~157 [54]

Al/5 vol.% SiCp Casting 8 µm ~80 ~115 [55]

Al/3 wt.% Al2O3 Casting 50 nm ~107 ~162 [54]

Al/20 vol.% Al2O3 Casting+extrusion 12 µm ~175 ~220 [56]

Al/2 vol.% SiCp Friction stir welding 15 nm ~130 ~108 [57]

Al/20 vol.% SiCp Powder metallurgy 17 µm ~87 ~107 [58]

Al-5Cu/13vol.% SiCp Powder metallurgy 10 µm ~134 ~175 [59]

Al/10vol.% SiCp Accumulative press bonding 10 µm 180 222 Present work

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Table 3. Contribution of strengthening mechanisms and yield strength obtained by

theoretical models and experiment in Al/SiCp composites.

Strengthening mechanisms and yield strength Al/SiCp micro-composite Al/SiCp nano-composite

Grain boundary (∆ σGB) 64.9 75.6

Thermal mismatch (∆ σTM) 6.8 39.6

Elastic mismatch (∆ σTM) 5.4 34.4

Strain hardening (∆ σDis) 49 42

Orowan looping (∆ σOrowan) 2.4 172

Load-bearing (∆ σLoad) 1.5 0.3

Experimental yield strength (σ Ex .) 148 210

Calculated arithmetic yield strength (σ Arith.) 159 393

Calculated quadratic yield strength (σ Quad.) 111 228

Calculated compounding yield strength (σ Comp .)144

289

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