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7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 1/17
STARTER
• You have 10 min to carry on with theRedox equations sheet
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 2/17
Watch the demonstration
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 3/17
Electrolysis is splitting upsubstances using
electricity
(Lysis is latin for splitting
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 4/17
!hat is electrolysis"
• Electric current is used tobrea#down a substance made upof ions
• $n electrolyte is the name for
the substance being bro#en down
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 5/17
Electrolysis $pparatus
Cathode (%ve electrode
power supplyAnode
(&ve electrodeElectrolyte
+ve
-ve
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 6/17
Electrolysis $pparatus
Cathode (%ve electrode
Anode(&ve electrode
Electrolyte' thisis what will beelectrolysed
power supply
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 7/17
•ositive
•$node
•)egative
•*s•+athode
,on-t get stressed
in the exam'Remember $)*+
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 8/17
STARTER: Label the diagram!
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 9/17
1. Electrolytes contain ositive and negative ions.
. "#ring electrolysis$ ositive and negative electrodes are #t into the electrolyte.
%. The ositive electrode is called the anode.
&. The negative electrode is called the
cathode.'. The negative ions (called anions) are
attracted to the anode.
*. At the anode$ the negative ions lose
electrons to become atomsmolec#les.,. The ositive ions (called cations) are
attracted to the cathode.
. At the cathode$ the ositive ions gainelectrons to become atomsmolec#les
Act the sentences!
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 10/17
+ -
n+
n+
n+
n+
n+
n+
n+
/l-
/l-
/l-
/l-
/l- /l-
/l-
/l-
n+
positive electrode negative electrode
molten zinc
chloride (ions free
to move)
(anode) (cathode)e
-
e
-
e
-
e
-
Cl2
(g)
e
-
e
-
e
-
e
-
Zn
(s)
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 11/17
+ -
n+
n+
n+
n+
n+
n+
n+
/l-
/l-
/l-
/l-
/l- /l-
/l-
/l-
n+
positive electrode negative electrode
molten zinc
chloride (ions free
to move)
(anode) (cathode)e
-
e
-
e
-
e
-
Cl2
(g)
e
-
e
-
e
-
e
-
Zn
(s)
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 12/17
+ -
n+
n+
n+
n+
n+
n+
n+
/l-
/l-
/l-
/l-
/l- /l-
/l-
/l-
n+
positive electrode negative electrode
molten zinc
chloride (ions free
to move)
(anode) (cathode)e
-
e
-
e
-
e
-
Cl2
(g)
e
-
e
-
e
-
e
-
Zn
(s)
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 13/17
1. Electrolytes contain ositive and negative ions.
. "#ring electrolysis$ ositive and negative electrodes are #t into the electrolyte.
%. The ositive electrode is called the anode.
&. The negative electrode is called the
cathode.'. The negative ions (called anions) are
attracted to the anode.
*. At the anode$ the negative ions lose
electrons to become atomsmolec#les.,. The ositive ions (called cations) are
attracted to the cathode.
. At the cathode$ the ositive ions gainelectrons to become atomsmolec#les
Draw the sentence
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 14/17
At the electrodes
/athode (-)
(negative electrode)
• 0ositive ions go here
(cations).• As metal ions are
ositive$ they go tothe cathode.
• ons gain electrons. They are reduced andbecome ne#tralatoms.
Anode (+)
(ositive electrode)
• 2egative ions go here(anions).
• As non-metal ions arenegative$ they go to theanode.
• ons lose electrons.
They areoxidised
andbecome ne#tral atoms
(3hich react together to4orm molec#les).
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 15/17
/ommon ions
• Li+$ 2a+$ 5 +$
• 6g+$ /a+ $ n+
• /#+
$
/#+
$
7e+
$ 7e%+$
Al%+
• 28&+ (ammoni#m ion)
• 7-$ /l-$ 9r-$ -
• -$ S-
• 8- (hydro;ide ion)$ /%-$ 2%
-
(nitrate ion)$ S&- (s#lhate ion)
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 16/17
Compound Anode Cathode
.odium/romide
otassium
*odide+alcium
luoride
agnesium2xide
Lithium
+hloride
7/21/2019 Intro to Electrolysis
http://slidepdf.com/reader/full/intro-to-electrolysis 17/17
Tr#e or 7alse
• Electrolysis is the splitting of asubstance using electricity.
• The anode is negative.
• Anions are negative
• Aluminium oxide is found in bauxite.
• Cathode is negative.• Cations are negative.