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Intro to Chemistry

Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

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Page 1: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Intro to Chemistry

Page 2: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Atomic Structure Nucleus- center of an atom -contains protons

(which are positive) -contains neutrons

(which are neutral)

Ex- Sodium:

Page 3: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Atomic StructureOutside the Nucleus: Electrons (which are negative) surround

the nucleus in energy levels Outermost electrons are called valence

electrons

Page 4: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

An atom is defined by the number of PROTONS IT HAS!!!

Page 5: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Atomic Mass Unit (AMU)

The unit of measurement for an atom is an AMU. It stands for atomic mass unit.

One AMU is equal to the mass of one proton.

Page 6: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Atomic Mass Unit (AMU)

There are

6 X 1023 or 600,000,000,000,000,000,000,000 amus in one gram.

(Remember that electrons are 2000 times smaller than one amu).

Page 7: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Subatomic Particles Organized

Charge Location Mass

Protons

Neutrons

Electrons

Page 8: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Subatomic Particle Organized

Charge Location Mass

Protons Positive In nucleus 1 amu

Neutrons Neutral In nucleus 1 amu

Electrons Negative Outside of nucleus/ in energy levels

0 amu

Atomic Mass

Page 9: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Try it out!Read pp 104-108

then do #3, 4, 5 on page 110

Page 10: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

The Periodic Table can tell us a lot about the

elements.

Page 11: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:
Page 12: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

What’s in a square? Chemical Symbol- letter representing the atom

(sometimes from Latin)

ALWAYS write the first letter capital and second letter lower case Ex- Cu, Fe, Rb

Page 13: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Symbols

All elements have their own unique symbol.

It can consist of a single capital letter, or a capital letter and one or two lower case letters.

C Carbon

CuCopper

Page 14: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Atomic number = number of protons Don’t kill anyone in my class today!

Mass number = # protons + # neutrons Don’t use the one on the PT unless you have to! That is an

average! Use the Mass # given for that element!

Page 15: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Calculating Neutrons is a simple algebraic problem… Atomic Mass = protons + neutrons Atomic Number = protons Write the equation…

Mass # = protons + neutrons#Neutrons = (mass number – atomic number)

Page 16: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

What about Electrons? In a NEUTRAL atom, every + (proton) is

balanced by a –(electron). Therefore, in a neutral atom,

protons=electrons and you can use the following mneumonic:

A = P =E(atomic #) = (protons) = (electrons)

Page 17: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Complete the table below using the information given for each atom.Atom A has 3 protons and 4 neutrons.Atom B has 11 protons and 12 neutrons.Atom C has an atomic number of 19 and a mass number of 39.Atom D has an atomic number of 17 and a mass number of 35.

Atom # of protons

# of neutrons

Atomic # Mass # # of electrons

A

B

C

D

Page 18: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Complete the table below using the information given for each atom.Atom A has 3 protons and 4 neutrons.Atom B has 11 protons and 12 neutrons.Atom C has an atomic number of 19 and a mass number of 39.Atom D has an atomic number of 17 and a mass number of 35.

Atom # of protons # of neutrons

Atomic # Mass # # of electrons

A 3 4 3 7 3B 11 12 11 23 11C 19 20 19 39 19D 17 18 17 35 17

Page 19: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Try it out! (Blue Worksheet) Check answers at front…move onto yellow

sheet if doing well NEED TO KNOW…

Nuclear Symbol notation: Mass #

Atomic #

Mass hyphen notation: Symbol- Mass ex: N-14

Symbol

Page 20: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Atomic Mass Mystery…

Look at the atomic mass for Oxygen. What does it say (exactly?)15.9999

What is the atomic mass?P + N

So what the heck!?!?!Average of the actual isotopes on Earth!!!

Page 21: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

How can we change the mass of an element? We can’t mess with protons, but what

CAN we “mess with?”Neutrons…

What would that change about the atom? Changes the MASS Get an ISOTOPE

Page 22: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Isotopes

Isotopes are different atoms of the same element that contain the same number of protons but different number of neutrons.

Examples Cl-35 vs. Cl-37 17P 17P 18N 20N

Page 23: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

How to write isotopes…

Mass/Hyphen Notation: Especially important for a form of the isotope

that is NOT the “usual”Write the symbol, a dash, and the mass # for

that isotopeEx’s

C-14 C-12

Page 24: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

How to write isotopes…

Nuclear Symbol Notation Includes the symbol, atomic #, and the mass

# for that isotopeEx’s

14

6CMass #

Atomic # (=p)

Page 25: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

How do we Draw Atoms?

Bohr Models Lewis Dot Diagrams

Page 26: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

How to draw a Bohr Model1. Draw a nucleus & put protons and neutrons inside.

(may use a square shape so you don’t draw any electrons on it)

2. Remember the p=e in a neutral atom, so begin putting electrons on the energy levels until you use them all up.

Fill energy levels in order (can’t put any in 2nd shell until you’ve filled the first)

Page 27: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Drawing Bohr models, cont…Helpful hints:

1. Draw electrons at each of the four “corners”, then double up

2. Write the number of electrons you drew (in parentheses) on each energy level to help you keep track.

Page 28: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Electron configurations (Bohr Models)

Page 29: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

But…that can be a pain…

Most of the time we only really care about the valence electrons

Valence Electrons- electrons in the outermost shellUse the GROUP NUMBER!!!

Page 30: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Valence Electrons-

Find the number of valence electrons by counting over the rows (skipping transition metals)

Page 31: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Notice- rows 13, 14, 15, 16, 17, 18 have 3, 4, 5, 6, 7, and 8 valence electrons respectively.

Page 32: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Valence Electrons are what react!

Page 33: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

How to draw a Lewis Dot Structure1. Use the group # (top of the row on the

PT) to determine # of valence electrons

2. Write the symbol.

3. Draw dots around the symbol equal to the # of valence electrons (if group 2- draw two dots)

1. Place dots one at a time around the top, right, bottom and left side of the atom before you double any up.

Page 34: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

How to draw a Lewis Dot Structure1. Find the group # (top of the row on the PT)

Let’s do Phosphorus

2. Write the symbol. P

3. Draw dots around the symbol equal to the group number (if group 2- draw two dots)

1. Place dots one at a time around the top, right, bottom and left side of the atom before you double any up.

Page 35: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Octet Rule-

Most atoms want to have 8 electrons in their outer shell.

Page 36: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Octet rule exceptions… (octet rule=Most atoms want to have 8

electrons in their outer shell) Helium-

What is its group number?Why doesn’t it make sense to draw that many

dots?Because it only has 2 electrons TOTAL!

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Elements with a full outer shell naturally

Page 38: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Lewis Dot Structures

Page 39: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Families on the Periodic Table

Page 40: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Elements

Science has come a long way since Aristotle’s theory of Air, Water, Fire, and Earth.

Scientists have identified 90 naturally occurring elements, and created about 28 others.

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Elements

The elements, alone or in combinations, make up our bodies, our world, our sun, and in fact, the entire universe.

Page 42: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Mendeleev

In 1869, Dmitri Ivanovitch Mendeléev created the first accepted version of the periodic table.

He grouped elements according to their atomic mass, and as he did, he found that the families had similar chemical properties. 

Blank spaces were left open to add the new elements he predicted would occur. 

Page 43: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Periodic Table Organizes elements in a particular way

All the elements in this column (“family”) have similar properties. That’s why they are grouped together.

Page 44: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

EX- Valence electrons can be determined from the group number!

Page 45: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

What does it mean to be reactive?We will be describing elements

according to their reactivity. “Reactive Elements” do not have a full

outer shell of electrons. Therefore, they will “react” with other elements to get a full outer shell.

Page 46: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Let’s Color

Page 47: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

First let’s draw our staircase in black…

Page 48: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:
Page 49: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Make a chart

Metals Nonmetals

Page 50: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Properties of Metals

Physical Properties of Metals… Solid at room temperature good conductors of heat and

electricity. shiny. ductile (can be stretched into

thin wires). malleable (can be pounded

into thin sheets). A chemical property of many

metal is its reaction with water which results in corrosion. (rust)

Page 51: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Properties of Non-Metals

Physical properties of Non-metals … poor conductors of heat

and electricity. not ductile or malleable

Solid non-metals are brittle and break easily.

dull. Many non-metals are

gases.

Sulfur

Page 52: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Properties of Metalloids/Semiconductors

Metalloids (metal-like) have properties of both metals and non-metals. They are solids that can be

shiny or dull. They conduct heat and

electricity better than non-metals but not as well as metals.

They are ductile and malleable.

Silicon

Page 53: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Families Periods Columns of elements are

called groups or families. Elements in each family

have similar but not identical properties. For example, lithium (Li),

sodium (Na), potassium (K), and other members of family IA are all soft, white, shiny metals.

All elements in a family have the same number of valence electrons.

Each horizontal row of elements is called a period.

The elements in a period are not alike in properties. In fact, the properties change

greatly across even given row.

The first element in a period is always an extremely active solid. The last element in a period, is always an inactive gas.

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Hydrogen

Hydrogen is in a family of its own. It’s a nonmetal on the metal’s side

It’s a gas at room temperature.

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Alkali Metals

Group one the first column of the

periodic table. 1 valence electron. All metal properties (They

are shiny, etc) Soft metals: easily cut with

a knife.

Page 62: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Alkali Metals

They are the most reactive metals. They react violently with water. http://www.youtube.com/watch?v=uqDWbknpi

Vk http://www.youtube.com/watch?v=92Mfric7JUc Alkali metals are never found as free

elements in nature. They are always bonded with another element.

Page 63: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Use Purple

Page 64: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Alkaline Earth Metals Group 2 Second column of metals (Properties of metals) Also very reactive (but not as reactive as

Alkali metals) They have two valence electrons.

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Page 66: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Transition Metals

Big group in the middle. (group varies)

Properties of metals. (They are good conductors of heat and electricity, etc.)

Everything else varies (valence electrons, reactivity, etc)

Page 67: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Use orange

Page 68: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Halogen Family

Group 17 Second column from the

right. Halogens have 7

valence electrons, which explains why they are the most reactive non-metals. They are never found free in nature.

They react with alkali metals to form salts.

Page 69: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Use Red

Page 70: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Noble Gases

Group 18 8 valence electrons colorless gases extremely un-reactive.

Becauses their outermost energy level is full. called inert.

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Page 72: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Rare Earth Elements

The thirty rare earth elements are composed of the lanthanide and actinide series.

One element of the lanthanide series and most of the elements in the actinide series are called trans-uranium, which means synthetic or man-made.

Page 73: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

The next 4 families are named by the element at the top of the row

Boron Family- group 133 valence electrons

Carbon Family- group 144 valence electrons

Nitrogen Family- group 155 valence electrons

Oxygen Family- group 166 valence electrons

Page 74: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Predicting Ion Formation

Page 75: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Let’s look at our families- What ion will each form? It all starts with the noble gases…

Everyone wants to be NOBLE

Page 76: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

These are the “magic numbers”

Each of these atomic numbers will make a “full outer shell”

Other families will lose or gain electrons to get the these “numbers”

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Alkali Metals

All (except hydrogen- of course) will lose one electron to form a __________ charge. (+1)

Page 78: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Alkaline Earth Metals

All will lose two electrons to form a __________ charge. (+2)

Ex-

A neutral Mg atom has 12 protons and 12 electrons (+12) + (-12) = 0

A Mg ion has 12 protons and only 10 electrons

(+12) + (-10) = +2

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Boron Family

All will lose three electron to form a ____ charge. (+3)

Page 80: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Carbon Family is special

All have four valence electrons, so it can lose four OR gain four to fulfill its octet!

So it can form a _____ or a ______ion!

-(+4) or (-4)

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Nitrogen Family

All have five valence electrons, so it can gain three to fulfill its octet!

So it can form a ________ion!

- (-3)

Page 82: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

Oxygen Family

All will gain two electrons to form a __________ charge. (-2)

Ex-A neutral Oxygen atom has 8 protons and 8 electrons

(+8) + (-8) = 0

An Oxygen ion has 8 protons and 10 electrons (+8) + (-10) = (-2)

Page 83: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

HALOGENS

All will gain one electrons to form a __________ charge. (-1)

Page 84: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

How about those noble gases? They will NOT FORM IONS!!!

Page 85: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

What subatomic particles CAN we “mess with?” Already know…Neutrons…

Get an ISOTOPE, changes the mass

But what if I mess with Electrons…What would that change about the atom?Changes the CHARGEGet an ION

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Intro to Ions

Page 87: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

How are these ions made? Can you mess with protons? Would messing with neutrons

do anything to the charge? What must you mess with??? What charge does an electron

have? So what would happen to the

atom if they LOSE one? Would they get more positive or more negative overall???

Page 88: Intro to Chemistry. Atomic Structure Nucleus- center of an atom -contains protons (which are positive) -contains neutrons (which are neutral) Ex- Sodium:

IONS

If you mess with the electrons you change the overall charge of the atom…an atom that is no longer neutral is called an ION.

ANION- has a negative chargeMeans you added an electron!

CATION- has a positive chargeMeans you lost an electron