Integrated Pollution Prevention and Control (IPPC) Licensing

Integrated Pollution

Prevention and Control

(IPPC) Licensing

Application Form

Environmental Protection Agency

P.O. Box 3000, Johnstown Castle Estate, Co. Wexford Lo Call: 1890 335599 Telephone: 053-9160600 Fax: 053-9160699

Web: www.epa.ie Email: [email protected]

EPA Reg. No: (Office use only)

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IPPC Application Form V1/07

Page 2 of 216

CONTENTS

ABOUT THIS APPLICATION FORM........................................................................ 3

SECTION A: NON-TECHNICAL SUMMARY ...........................................................4

SECTION B: GENERAL ..................................................................................... 15

SECTION C: MANAGEMENT OF THE INSTALLATION .......................................... 20

SECTION D: INFRASTRUCTURE & OPERATION ................................................. 21

SECTION E: EMISSIONS.................................................................................. 31

SECTION F: CONTROL & MONITORING ............................................................ 35

SECTION G: RESOURCE USE AND ENERGY EFFICIENCY .................................... 37

SECTION H: MATERIALS HANDLING................................................................ 38

SECTION I: EXISTING ENVIRONMENT & IMPACT OF THE ACTIVITY.................. 39

SECTION J: ACCIDENT PREVENTION & EMERGENCY RESPONSE........................ 43

SECTION K: REMEDIATION, DECOMMISSIONING, RESTORATION & AFTERCARE43

SECTION L: STATUTORY REQUIREMENTS ........................................................ 44

SECTION M: DECLARATION............................................................................. 45

ANNEX 1: TABLES/ATTACHMENTS .................................................................... 46 ANNEX 2: CHECKLIST FOR ARTICLE 10 COMPLIANCE ..........................................212

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ABOUT THIS APPLICATION FORM

This form is for the purpose of making an application for an Integrated Pollution Prevention and Control (IPPC) Licence under the Environmental Protection Agency Acts, 1992 and 2003. There are separate application forms for licensees who wish to apply for a review of existing licences and for Pig & Poultry sector applicants. The Application Form must be completed in accordance with the instructions provided in the IPPC Licensing Application Guidance Note. The Guidance Note gives an overview of IPPC Licensing, outlines the licence application process (including number of copies required) and specifies the information to be submitted in the application. The Guidance Note and application forms are available to download from the IPPC Licensing pages of the EPA’s website at www.epa.ie. A valid application for an IPPC licence must contain the information prescribed in the Environmental Protection Agency (Licensing) Regulations, 1994 to 2004. Article 10 of the Regulations sets out the statutory requirements for information to accompany a licence application. The application form is designed in such a way as to set out these questions in a structured manner and not necessarily in the order presented in Article 10. In order to ensure a legally valid application in respect of Article 10 requirements, please complete the Article 10 Checklist provided in Annex 2. This Application Form does not purport to be and should not be considered a legal interpretation of the provisions and requirements of the Environmental Protection Agency Acts, 1992 and 2003 and the Environmental Protection Agency (Licensing) Regulations 1994 to 2004. While every effort has been made to ensure the accuracy of the material contained in the Application Form, the EPA assumes no responsibility and gives no guarantees, undertakings and warranties concerning the accuracy, completeness or up-to-date nature of the information provided herein and does not accept any liability whatsoever arising from any errors or omissions.

Should there be any contradiction between the information requirements set out in the Application Form and any clarifying explanation contained in the accompanying Guidance Note, then the requirements in this Application Form shall take precedence.

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SECTION A: NON-TECHNICAL SUMMARY

A non-technical summary of the application is to be included here. The summary should identify all environmental impacts of significance associated with the carrying on of the activity/activities, and describe mitigation measures proposed or existing to address these impacts. This description should also indicate the normal operating hours and days per week of the activity. The following information must be included in the non-technical summary: A description of: − the installation and its activities, − the raw and auxiliary materials, other substances and the energy used in or generated by

the installation, − the sources of emissions from the installation, − the environmental conditions of the site of the installation (e.g. soil and groundwater, air,

noise, surface water), − the nature and quantities of foreseeable emissions from the installation into each medium

as well as identification of significant effects of the emissions on the environment, − the proposed technology and other techniques for preventing or, where this is not

possible, reducing emissions from the installation, − where necessary, measures for the prevention and recovery of waste generated by the

installation, − further measures planned to comply with the general principles of the basic obligations of

the operator i.e.

(a) all the appropriate preventive measures are taken against pollution, in particular through application of the Best Available Techniques (BAT);

(b) no significant pollution is caused; (c) waste production is avoided in accordance with Council Directive 75/442/EEC of 15

July 1975 on waste; where waste is produced, it is recovered or, where that is technically and economically impossible, it is disposed of while avoiding or reducing any impact on the environment;

(d) energy and other resources are used efficiently; (e) the necessary measures are taken to prevent accidents and limit their consequences; (f) the necessary measures are taken upon definitive cessation of activities to avoid any

pollution risk and return the site of operation to a satisfactory state. − measures planned to monitor emissions into the environment. Supporting information should form Attachment No A.1

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Introduction:

The non technical summary from the previous application is included here with some

modifications to cover the ‘as built’ situation for recent expansion projects and the

proposed additional processing facilities for which this IPPC license review is being

submitted.

Site location and condition

Millipore is located approx 1 Km south-west of the village of Carrigtwohill east of Cork City. The facility was constructed in 1987 on a green field site which was previously used for agriculture and manufacturing operations have increased significantly in the intervening years The Plant Layout is shown in Attachment A on Drg No. IPPCATTA-001 Sht1/1 Rev 3 IPPC Application – Plant Layout Showing Site Boundary . Millipore Ireland B.V. currently holds an IPPC Licence number P0571-02 (issued 28.03.2007) and is licensed under the following activities: 12.2.1 The surface treatment of objects or products using organic solvents, with a consumption

capacity of more than 200 tonnes per year. &

11.1 The recovery or disposal of waste in a facility, within the meaning of the Waste Management Act, 1996, which facility is connected or associated with another activity specified in this schedule in respect of which a licence or revised licence under Part IV is in force.

Millipore Corporation now intends to transfer a number of additional products to the Cork site. Two processes will be transferred from sites in the USA and the UK to the Cork site. The transfer of these processes will be carried out on a phased basis over ca. 2 years commencing in mid 2009. The following changes to the plant will be required in order to facilitate this latest expansion:

• The installation of two new processing facilities in a section of the existing warehouse • Installation of a mezzanine floor in a section of the existing warehouse to house the new

facilities • The installation of a new bunded area to the east of the existing warehouse to house acid

and base storage tanks, neutralisation system and a fume scrubber • The construction of a small annex to the existing warehouse for solvent storage for the

new facility • The installation of dust collection facilities to abate dust emissions from the new process • The fitting out of a new laboratory facility within the existing building • The installation of additional utility systems to cater for the expanded production activities.

The new utility systems include : o Additional Water Purification facilities o A ca. 120kVA emergency electricity generator o A new ca. 4.5 t/hr steam boiler

A planning application has been lodged with Cork County Council in January 2009 for the proposed expansion. The installation & its activities

Millipore Ireland B.V. manufactures filtration devices and diagnostic membranes for analytical laboratories as well as the biopharmaceutical and microelectronics industries at its facility in Carrigtwohill, Co. Cork. The new processes to be installed comprise:

• The manufacture of glass beads with controlled pore size • The surface treatment of this glass with a range of active chemical substances

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Occupancy and hours of operation The plant employs approximately 600 people. It is not envisaged that the new process will significantly increase the workforce except in a small number of specialist areas. In general at weekends the numbers in the plant are approximately 15% of weekday occupancy levels. Work onsite begins at 8.00am for production staff and 8.30am for office staff and finishes (day shift) 4.30pm and 5.00pm respectively. Evening shifts start at 4.30 or 8.00pm finishing at 12.00pm or 8.00am. The new processes will operate to the same shift pattern as existing operations commencing on two cycle shift and eventually moving to 24 hour, seven day operation depending on volume requirements. The installation consists of the analytical area & membrane manufacturing. (Cleanrooms 1, 2 and 3) house the device assembly and packaging operations. A new cleanroom will form part of the new expansion. Analytical Area

Analytical areas and their hours of operation are detailed below.

Analytical areas – hours of operation

Cleanroom 1

Millex 7 day week 3 cycle 8hr shift Filter cutting, 5 day week 3 cycle 12hr shift Moulding 7 day week 3 cycle 8hr shift Stericup 5 day week 2 cycle 8hr shift

Clean Room 2

Millex 33 7 day week 3 cycle 8hr shift Cleanroom 3

Centrifugal / Amicon 5 day week 3 cycle 12 hr shift Millicell 5 day week 2 cycle 8hr shift Multiscreen 5 day week 2 cycle 8hr shift Harvester 5 day week 2 cycle 8hr shift Warehouse 5 day week 2 cycle 8hr shift All of the above shift patterns may alter slightly depending on production volume requirements. Controlled Pore Glass/ Organic Synthesis (CPG/OS)

CPG manufacture 7 day week 4 cycle 12 hour shifts Organic Synthesis 7 day week 4 cycle 12 hour shifts In the initial stages of manufacture, the shift pattern may be 5 day 3 cycle 8 hour shifts depending on the stages of the technology transfer and the production volume requirements.

Membrane Manufacture

Durapore / IC2 The OP2 building houses the Durapore membrane manufacturing operation. Durapore manufacturing consists of mixing, casting, annealing, hydrophilisation and solvent recovery. Durapore operates a 7 day 4 cycle 12 hour shift pattern The IC2 facility consists of mixing, casting, annealing and modification. IC2 will provide additional production capacity for manufacture of Durapore membrane to meet business needs. IC2 will also have the capability to produce additional membranes not currently manufactured in Cork. IC2 will commence production in Quarter 1 2009.

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Millipore has recently requested permission from the Agency to carry out trials of a minor modification to the Durapore process. This modification will facilitate the introduction of the Immobilon membrane manufacturing process to the Durapore plant. The process is essentially the same as the current Durapore process with the addition of an Acetic Acid treatment step to control the colour of the final membrane. Following successful trials of the acetic acid treatment step it is planned to manufacture validation batches in April / May 2009. Full scale production of this membrane will involve campaigns of ca. 1 to 2 week duration on a ca. quarterly basis. The process will produce ca. 150 kgs per day of BOD which will be treated in the on site waste water treatment plant. The only new material in this process is Glacial Acetic Acid, the details of which are included in Table G(i) . Aircasting(/ J1/J2/MW2/K)

The Aircasting operation currently houses the K,J2, MW2 & J1 membrane casting machines. The Highflow process consists of mixing and casting operations. In the mixroom lacquers are manufactured using high-grade nitrocellulose and cellulose acetate derived from wood pulp. The cellulose is mixed with a solvent blend to form a casting solution. The mixture is blended for three days and then cast either onto a continuous stainless steel support belt or onto a Mylar or Reemay carrier material. Finished membrane is wound up on rollers at the end of the machine CPG/OS (New process)

The new process comprises two parts as follows:

• CPG : Controlled Pore Glass Manufacture • OS : Organic Synthesis for surface treatment of the CPG intermediate product

The precise details of these processes are confidential as they involve proprietary processes and technology. The new facilities are designed as a multipurpose plant and will be used to manufacture a range of products, all of which are quite similar in nature and generally involve the same range of raw materials, reagents and solvents. The main raw material comprises glass frits which are manufactured elsewhere and delivered to the site for onward processing. The CPG process involves the following unit operations:

• Glass Heating using two electric furnaces • Hot Glass quenching • Glass bead grinding • Glass bead sieving • Acid / Base treatment • Glass bead drying

The CPG process is mainly physical in nature and with the exception of acid / base treatment does not involve the use of any other chemicals or organic solvents. The Organic Synthesis process involves the following unit operations

• Organic synthesis in small pilot scale glass lined reactors • Organic synthesis in small scale glass vessels • Filtration • Drying using a filter dryer • Drying using a tray dryer • Surface treatment of the glass with a range of organic chemicals in small scale glass

vessels • Buffer solution preparation • Drying of finished product using laboratory / pilot scale ovens

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Support operations for the above manufacturing steps involve a range of utilities and support systems including:

• Thermal Transfer fluid heating / cooling • Deionised Water generation & distribution • 120kV electricity generation dedicated to the new facility • Storage of drummed/ IBC’s of solvents • Bulk storage of ca. 32 to 36 % Hydrochloric Acid • Bulk storage of ca. 30 % Sodium Hydroxide • Fume Scrubber • Dust Collection system • Carbon Adsorber unit

Environmental Emissions: Emissions from Durapore/IC2

Waste concentrated solvents, Acetone, Methanol, Dimethylacetamide (DMAc), N-Methyl-2-Pyrrolidone (NMP) and Triethylene Glycol (TEG) from these processes are recovered for re-use in the onsite Solvent recovery units. Dilute waste streams are treated in the onsite wastewater treatment plant. Final effluent is discharged to the Carrigtwohill Sewage Treatment works in accordance with the requirements of the IPPC licence Reg P0571-02. Process exhausts are diverted to the onsite thermal oxidisers for destruction. Emissions from the thermal oxidisers meet emission limits as required under the IPPC licence. Non hazardous wastes from the process are segregated for recycling where possible and all waste is disposed of / recycled through authorised waste contractors only. Hazardous waste is segregated and incinerated via licensed facilities. A full waste management record is maintained on site in accordance with IPPC license requirements.

Emissions Aircasting: Process exhausts from the Highflow/ J2 operations are treated in the thermal oxidisers on site. The system consists of two thermal oxidisers which operate either as duty & standby or in tandem dependent on process requirements. The addition of further air casting operations (MW2 /J1) required the installation of a third thermal oxidiser and its associated stack. The new thermal oxidiser can also act as a backup to TO1 & TO2 and is fitted with an on-line continuous emissions monitor. Process wastewater from the Aircast operation is treated in the wastewater treatment plant and now accounts for approx 50 % of total plant COD loading. Non hazardous wastes from the process is segregated for recycling where possible and all waste is disposed/ recycled through authorised waste contractors only. Hazardous waste is segregated and incinerated via licensed facilities. A full waste management record is maintained on site in accordance with IPPC license requirements. CPG/OS Processes

The CPG process will not generate any significant air emissions as there are no organic solvents used in this process. Acid fumes will be generated as part of the acid treatment of the glass beads. These will be scrubbed in a dedicated caustic scrubber. Any dust generated in the process will be captured as near to the source as practicable and the air will be cleaned using dust collectors prior to discharge to atmosphere. The two furnaces will be fitted with local exhaust ventilation to remove excess heat from the area. It is not expected that these will generate any adverse environmental emissions. A dedicated fume hood will be provided to accommodate planned testing equipment associated with the CPG process. A porisometer containing mercury is used to test the CPG product. This unit generates a waste stream containing mercury which is treated as a hazardous waste for disposal.

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The OS process will generate some air emissions associated with materials transfer into process vessels, as a result of the processes undertaken in the vessels and in the drying operations. Due to the very small scale of these process operations, the emissions to air will be very limited in scale. Appropriate treatment systems will be put in place to ensure these emissions meet the requirements of BAT. These systems will include (as appropriate):

• Carbon Adsorption • Thermal Oxidation • Vent Condensing • Low Temperature Condensing

There will be four new air emission points associated with the new processes as follows:

• A2-30 Dust Collector • A2-32 Scrubber • A2-40 Filter Dryer • A2-41 Carbon Adsorber

There will be four new emissions to Sewer associated with the new process as follows:

• SE4 Existing Cooling Tower Water overflow • SE5 Neutralised Waste Water from CPG Process • SE6 Cooling Water from CPG Furnace & Quench Tank • SE7 Retentate from new RO Systems

Wastewater and Atmospheric emissions from the additional activities are detailed in tables E1 and E3 There will be a number of new emission points associated with the support operations for the new processes as follows:

• New ca.4.5 t/hr steam boiler operating on Natural Gas with potential Diesel option in the event of gas supply interruption

• New 120 kVA diesel driven electricity generator. This will be a potential emission point as the unit will only be required in the event of a mains power outage.

• A number of fume hoods (ca. 5) will be installed for handling of small volume reagents and laboratory testing.

The new processes will generate relatively small volumes of high strength waste water which will be treated in the on site waste water treatment plant. Neutralised waste water will arise from the CPG process and will be sent to sewer with the approval of the sanitary authority. Reject water from two new water purification plants will also be sent to the local authority sewer. The overflow from the existing cooling tower, currently sent to the on site waste water treatment facility, will be rerouted to the local authority sewer with the approval of the local authority.

Raw materials / auxiliary materials/ energy

Raw materials used in the current processes consist primarily of organic solvents (Acetone, Methanol, Ethanol, Butanol, Dimethylacetamide) along with Polyvinylidiene difluoride (PVDF) polymer Nitrocellulouse, cellulose acetate, Triethylene Glycol, N-Methyl-2-Pyrrolidone and the polymer, Polyethersulfone (PES). Solvents are purchased in bulk and stored in the relevant solvent storage tanks in the tank farms. Organic solvents are also recovered on site in two multipurpose solvent recovery units for reuse in the operation.

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The materials required for the CPG/OS processes will be delivered in mini bulk ( caustic & hydrochloric acid ), IBCs. drums ( solvents) and small packages. Millipore’s electricity requirements are provided both through the national grid and also from a combined heat and power plant (CHP) operated on site in association with Bord Gais. Millipore currently operates 2 natural gas boilers to meet the heating requirements of the site. The CHP also uses natural gas as a fuel for its engine. Millipore continuously reviews energy and resource consumption on site and this has led to the implementation of many initiatives in this area. The new processes will require back up electricity generation to be installed to ensure the continuity of critical steps in the synthesis operation in the event of a failure of the main power to the site. This will require the installation of a 120kVA diesel driven generator. This will be housed outdoors in a sound proof enclosure adjacent to the new facilities. A new dual fuel (gas / diesel) steam boiler of ca. 4.5 t/hr steam capacity is proposed as part of this application to support existing site operations as additional processing capacity is added. This boiler will be operated primarily on natural gas and will only be operated on diesel oil in the event of an interruption in the gas supply to the site. Emissions Prevention/ Recovery/ Abatement Technologies

In accordance with the requirements of BAT (Best Available Techniques) Millipore ensures that preventative measures are taken against pollution and that suitable abatement technologies are implemented to reduce the impact on the environment. Millipore currently operates three regenerative thermal oxidisers which abate solvent emissions from membrane manufacturing processes. Millipore operates two Solvent Recovery Systems for the recovery of organic solvents for reuse in the process. The units are capable of processing 1,000 kgs/hr feed and 1500 kgs/hr and can recover Acetone, Methanol and Dimethylacetamide. One of the units has the capability to recover N-Methyl-2-Pyrrolidone and Triethylene Glycol in addition to the solvents as described above. Process wastewater is treated in the onsite wastewater treatment plant which consists of primary and secondary treatment (activated sludge system). Final effluent discharges to the Carrigtwohill treatment works operated by the Local Authority. The wastewater treatment plant operates 24hrs/7days. Nature and Quantity of Foreseeable Emissions Air

Millipore currently operates three regenerative thermal oxidisers which abate solvent emissions from membrane manufacturing processes. Current throughput of two of these thermal oxidisers is 15,000m3/hr (consisting of a 10,000m3/hr unit and a 5,000m3/hr unit) with the third unit rated at 29,000 m3/hr. These are operated in accordance with the requirements of the IPPC license and are compliant with the corresponding emission limits. The new processes will be equipped with a range of air emissions abatement systems appropriate to the specific emissions as follows:

• Caustic scrubbing to minimise emissions of acid gases • Vent condensing and Carbon Adsorption to minimise emissions of chlorinated solvent • Low Temperature (-80deg C) condensation to minimise methanol emissions from the

vacuum dryer • Treatment of tray dryer emissions using one of the existing thermal oxidisers as

appropriate • Dust Collection System to gather dust from process equipment and abate it prior to

discharge

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Water

Process wastewater is treated in the onsite wastewater treatment plant which consists of primary and secondary treatment (activated sludge system). Final treated waste water discharges to the Carrigtwohill municipal treatment works operated by the Local Authority. The wastewater treatment plant operates 24hrs/7days. Current throughput of this system is ca. 150m3/day approx. This is expected to increase to max of 600m3/day by 2018 as additional facilities added in the last two years come up to full scale production,. The wastewater treatment plant is operated in accordance with the requirements of the current IPPC license and final effluent is compliant with corresponding emission limits. Waste sludge from the treatment plant is collected by a licensed contractor and disposed of appropriately as agreed with the Agency. The additional loading anticipated for the new processes will be in the range 20 to 30 m3/d and is not expected to pose any significant issue for the current waste water treatment plant in the initial phase of implementation. A study is currently underway to assess the longer term loading of the existing waste water treatment plant to ensure that it can handle the full extent of the loading expected over the next three to five year period which is expected to mainly arise from the membrane operations. It is likely that some influent load reduction will be required to maintain long term stable operation of the system over this timeframe. The relatively small loads from the proposed expansion are not expected to have any impact on current WWTP operation. The proposed direct discharges to sewer will not increase the BOD/COD loading to the local authority waste water treatment plant. The total additional hydraulic load will be 140 m3/day which represents a 13 % increase in the total currently permitted hydraulic load from the overall facility. The volume of surface water discharged is not expected to increase. The new surface water oil separator installed in 2008 will be adequate for future needs. Surface water emissions are monitored in accordance with IPPC licence requirements and have been found to be in compliance with these requirements. Noise

Regular noise monitoring is carried out in accordance with IPPC licence requirements and has been found to be within the required limits. As most of the proposed new equipment will be located indoors it is not anticipated that the new additional processing facilities will add significantly to current noise emissions. Therefore we expect that the existing limits will be met. Waste Solid waste (hazardous and non-hazardous) is disposed or recycled by licensed waste contractors as agreed with the Agency. A full record of all waste taken off site is maintained in accordance with condition 11.9 of the IPPC licence. It not anticipated that the volume of both hazardous and non-hazardous waste will increase to any significant extent as a result of the new processes. Accident Prevention The Emergency Response Plan contains information on the measures in operation to reduce the impact of an accidental emission or spillage. The Emergency Response Plan also includes the provisions for response to accidental emissions and emergency situations which arise outside of normal working hours i.e. night-time, weekends and holidays. The Site Management will update the Emergency Response Plan to ensure it is adequate to cover the range of new materials associated with the new processes. As the amounts of these solvents are generally small in relation to the quantity of bulk solvents currently stored and handled on site, it is not anticipated that there will be any significant additional accident prevention measures to be undertaken in relation to this development.

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Cessation of activities

Millipore Ireland has considered requirements for decommissioning and decontamination of all process related structures. This is outlined in the companies Environmental Liabilities Risk Assessment and Residuals Management Plan. The new processes will not significantly impact either the Environmental Liabilities Risk Assessment or the Residuals Management Plan. Any impacts identified will be included in updates to the existing documents as required under the current IPPC license. Measures planned to comply with principles of the basic obligations of the Operator The measures proposed or already in place to ensure that:

(a) The best available techniques are or will be used to prevent or eliminate or, where that is not practicable, generally reduce an emission from the activity;

(b) no significant pollution is caused; (c) waste production is avoided in accordance with Council Directive 75/442/EEC of 15 July

1975 on waste; where waste is produced, it is recovered or, where that is technically and economically impossible, it is disposed of while avoiding or reducing any impact on the environment;

(d) energy is used efficiently; (e) the necessary measures are taken to prevent accidents and limit their consequences; (f) the necessary measures are taken upon definitive cessation of activities to avoid any

pollution risk and return the site of operation to a satisfactory state; are as follows: − Two controlled emission points in place. A1-7 is the emission point for Thermal Oxidisers

TO-1 and TO-2. A1-8 is the emission point for thermal oxidiser TO-3. Both of these employ thermal recuperative oxidation which is one of the techniques mentioned for consideration in the determination of Best Available Techniques- BAT1.

− All high strength process waste water undergoes treatment which includes pH correction/neutralisation and biological treatment following by clarification (BAT2).

− Low strength process waste water (Water Purification system reject) arising from the new water treatment plant will be directed to Sewer. This will reduce the hydraulic loading of the existing waste water treatment plant and is consistent with the manner of disposal of existing water purification system waste streams.

− Neutralised waste water from the CPG process may be directed to sewer with the approval of the sanitary authority. This will reduce the hydraulic loading to the existing waste water treatment plant. This waste stream will not contain any organic solvents and is therefore suitable for direct discharge to sewer.

− Overflow from the existing cooling tower will be rerouted to the sewer with the approval of the local authority to minimise loading of the on site waste water treatment plant.

− Two solvent recovery plants are in operation at the site with solvent re-used in the manufacturing process (BAT3).

− Programmes to reduce resource consumption and reduce waste are ongoing as part of the Environmental Management Programme. Apart from recycling of certain materials, non-hazardous wastes are sent for engineered landfill, while hazardous wastes are sent for overseas incineration with heat recovery where possible. Waste oils are sent for recycling. The new CPG / OS processes will generate a relatively small volume of additional waste which will be handled in the same manner.

1 Section 20.11.4.3, Reference Document on Best Available Techniques for Surface Treatment using Organic Solvents (January 2007) page 520 2 Section 4.3.1 page 281 and page 288, Reference Document on Best Available Techniques in common Waste Water and Waste Gas Treatment/Management Systems in the Chemical Sector (February 2003); and Section 20.12.5 page 541, Reference Document on Best Available Techniques for Surface Treatment using Organic Solvents (September 2005). 3 Section 20.13.2.2 Reference Document on Best Available Techniques for Surface Treatment using Organic Solvents (January 2007) page 545

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− A 1 MWe combined heat and power plant (CHP) is in operation on the site.

− Bunding, bund testing, testing of pipelines, testing of underground tanks, groundwater monitoring and two firewater retention ponds are all in place in accordance with the existing licence requirements.

− A residuals management plan has been prepared for the site in accordance with the existing IPPC licence condition 10 and has been submitted to the Agency. This residuals management plan will be reviewed for the addition of the new facilities.

− The site has OHSAS 18001 (Safety Management System) accreditation.

− In addition to the abatement systems described above which are considered BAT, the following measures that are also considered BAT4 are implemented at the site:

o The site has ISO 14001 (Environmental Management System) accreditation (Paragraph 12 of BAT).

o Paragraph 13 and 14 in relation to monitoring consumption and emissions and on-going environmental improvements - implemented as outlined above.

o Where relevant, the measures contained in paragraph 15 in relation to prevention of unplanned releases/emissions; paragraph 16 in relation to storage of chemicals and waste; and paragraph 17 in relation to plant construction and operation.

o Paragraph 18 in relation to monitoring solvent emissions.

o Paragraph 22 in relation to using control measures to minimise the use of rinsing water and paragraph 23 in relation to use of cooling towers for cooling water.

o Paragraph 26 in relation to minimising raw material consumption.

o Paragraphs 37 in relation to recovering the heat where solvents are destroyed; paragraph 38 in relation to recovery of heat from thermal oxidation systems and paragraph 40 in relation to extracting air from the coating process machinery.

o Paragraph 50 in relation to carrying out solvent balances.

o Paragraph 51 in relation to recovery and reuse of solvent on-site.

o Paragraph 56 in relation to odour abatement through waste gas treatment.

o Paragraph 58 in relation to noise reduction through engineered controls.

Note: not all techniques in this BAT (Best Available Techniques) document are relevant to the site. Attachment I.8 for more information.

Monitoring

Millipore has a programme in place to ensure that all emissions are monitored in accordance with IPPC licence requirements. Details of monitoring points and methodologies are included in section F.2 and associated attachment.

Additional air emissions monitoring points will be provided for the new equipment to be installed for the CPG/OS processes as follows:

• A2-30 Dust Collector • A2-32 Scrubber • A2-40 Filter Dryer • A2-41 Carbon Adsorber

4 Section 21 Reference Document on Best Available Techniques for Surface Treatment using Organic Solvents (January 2007) pages 555 to 570

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In addition to the above major vent points, monitoring and sampling points will be provided at a number of the minor vent points as required during the commissioning phase as follows:

• Reactor System Ventilation • Fumehood vents

Additional Waste Water Sampling / Monitoring points will be provided for the following emission points as required:

• SE4 Existing Cooling Tower Water overflow • SE5 Neutralised Waste Water from CPG Process • SE6 Cooling Water from CPG Furnace & Quench Tank • SE7 Retentate from new RO Systems

A number of noise monitoring points have been relocated (AN3 and AN4) at the South of the facility to the Southern perimeter to more accurately reflect the noise levels at the perimeter of the site in these locations. It is not envisaged that any other additional monitoring arrangements will be required as a result of the new processes.

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SECTION B: GENERAL

B.1. Owner/Operator

Name*: Millipore Ireland BV Address: Tullagreen Carrigtwohill Cork Tel: 021-4883666 Fax: 021-4883048 e-mail: See below

* This should be the name of the applicant which is current on the date this IPPC Licence Application is lodged with the Agency. It should be the name of the legal entity (which can be a limited company or a sole trader). A trading/business name is not acceptable. Name and Address for Correspondence Only application documentation submitted by the applicant and by the nominated person will be deemed to have come from the applicant.

Name: Ms. Liz Henderson – EU EHS Manager Address: Millipore Ireland B.V. Tullagreen Carrigtwohill Co. Cork Tel: 021 4532256 Fax: 021 4883048 e-mail: [email protected]

Address of registered or principal office of Body Corporate (if applicable)

Address: Millipore Corporation Corporate Headquarters 290 Concord Road Billerica MA01 821, USA Tel: Fax: e-mail:

If the applicant is a body corporate, the following information must be attached as Attachment B1: a) a Certified Copy of the Certificate of Incorporation. b) the Company’s Registration Number from the Companies Registry Office. c) Particulars of Registered Office of the Company.

The above information has been previously submitted to the Agency and has not

changed in the interim.

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Name and address of the proprietor(s) of the Land on which the Activity is situated

(if different from applicant named above):

Proprietor’s Name:

Millipore Ireland B.V

Address: As above Tel: Fax: e-mail:

Name and address of the owner(s) of the building and ancillary plant in which the

activity is situated ( if different from applicant named above):

Name: As above* Address: Tel: Fax: e-mail:

* All facilities are in the ownership of Millipore Ireland B.V. with the exception of the

Combined Heat and Power Plant which is currently owned by Bord Gais Eireann

B.2. Location of Activity

Name: Millipore Ireland BV Address*: Tullagreen Carrigtwohill Cork Tel: 021-4883666 Fax: 021-4883048 Contact Name: Ms. Liz Henderson Position: EU Environmental ,Health & Safety Manager e-mail: [email protected]

* Include any townland.

National Grid Reference

(12 digit 6E,6N)

E180930,N072440

Location maps (≤A3), appropriately scaled, with legible grid references should be enclosed in Attachment B.2. The site boundary must be outlined on the map in colour. The site location is shown on Drg. No. 00417-001Rev A Site Location Map in Attachment B.2 The site boundary is outlined in red on Drg.No. IPPCATTB2-001 Sht1/1 Rev 3 IPPC Application –Plant Layout Showing Site Boundary in Attachment B.2

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Geo-referenced digital drawing files (e.g. AutoCAD files) in Irish Grid projection of the site boundary and overall site plan, including labelled emission, monitoring and sampling points, are also required. This data should be provided to the Agency on a separate CD-Rom containing sections B.2, E.6 and F.3.

Name of geo-referenced

digital drawing files

Each file is separately designated as the following listing: Drg. A-001 Rev3 Plant Layout showing Site Boundary Drg E.1-001 Sh3/4 Rev 3 Atmospheric Emission Points

Drg E.1-001 Sh4/4 Rev 3 Atmospheric Emission Points

Drg F2-001 Rev 3 Monitoring & Sampling Points

Name of CD-Rom with digital

drawing files

IPPC Review 2009 Digital Drawing Files

The above geo-referenced drawings are included in .dwg format (AutoCAD) on CR-ROM No.2 . The remaining drawings included in the attachments are contained on CD-ROM

No. 3 in .pdf format.

B.3. Class of Activity

Identify the relevant activities in the First, Third or Fourth Schedule of the PoE Act 2004 to which the activity relates:

Schedule Class DescriptionNote 1

1 Surface Coatings

12.2.1

The surface treatment of objects or products using organic solvents, with a consumption capacity of more than 200 tonnes per year

1 Waste 11.1 The recovery of waste in a facility, within the meaning of the Act of 1996, which facility is connected with another activity specified in this schedule in respect of which a licence under Part IV is in force.

Note 1: In order to give a precise identification select only those words from the description of the class or classes that best describes the nature of the activity for which the licence is being applied for.

B.4. Employees/ Capital Cost

Give- (i) In the case of an established activity, the number of employees and other persons working or engaged in connection with the activity on the date after which a licence is required and during normal levels of operation, or (ii) In any other case, the gross capital cost of the activity to which the application relates.

Number of Employees (existing facilities): 600

Gross Capital Cost (new proposals) € 6,000,000

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B.5. Relevant Planning Authority

Give the name of the planning authority in whose functional area the activity is or will be carried out.

Name: Cork County Council Address: County Hall Cork Tel: 021-4276891 Fax: 021 4276321

Planning Permission relating to this application:

has been obtained is being processed Xis not yet applied for is not required

Local Authority Planning File Reference

No:

094208

Attachment B.5 should contain all planning permissions, including a copy of all conditions, and the required copies of any EIS should also be enclosed. For existing activities, Attachment No B.5 should also contain all licences and permits past and present in force at the time of submission.

B.6. Relevant Sanitary Authority.

In the case of a discharge of any trade effluent or other matter to a sewer of a sanitary authority, give the name of the sanitary authority in which the sewer is vested or by which it is controlled.

Name: Cork County Council Address: County Hall Cork Tel: 021 4276891 Fax: 021 4276321

In the case of a discharge of any trade effluent or other matter to a sewer not vested by a sanitary authority, the applicant must supply as Attachment No B.6; (a) the name and address of the owner(s) of the sewer and the waste water treatment plant to which the sewer discharges and who are responsible for the quality of the treated effluent discharging to waters and (b) a copy of the effluent regulations and the agreement between the applicant and the aforementioned.

Name: N/A Address: Tel: Fax:

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B.7. Relevant Health Board Region

The applicant should indicate the Health Board Region where the activity is or will be located.

Name: Health Service Executive (HSE) Southern Area Address: Southern Area Wilton Road Cork Tel: 021-4545011 Fax: 021 4545748

B.8 Site Notice, Newspaper Advertisement and Planning Authority Notice.

Attachment No B.8 should contain a copy of the text of the site notice, a map (no larger than A3) showing its location on site (in accordance with Article 7 of the Regulations) and a copy of the newspaper advertisement. A copy of the notice given to the Planning Authority should also be included. A copy of the text of the site notice, a site location map Drg No. IPPCATB.8-001 Sht 1/1 Rev 3 which shows its location on the site and a copy of the newspaper advertisement published in the Irish Examiner on 12th.March 2009 are included in attachment B.8 . B.9 Seveso II Regulations

State whether the activity is an establishment to which the EC (Control of Major Accident Hazards involving Dangerous Substances) Regulations (S.I. No. 74 of 2006) apply. If yes, outline how the process comes under these regulations. Supporting information should be included in Attachment No B.9. The above regulations do not currently apply to the site. The additional materials required for the new processes will not change this situation. A summary of the applicability of this Regulation is included in attachment No. B.9

B.10 IPPC Directive

Specify whether the activity is a category of industrial activity referred to in Annex I of the IPPC Directive (96/61/EC) and if yes specify the category. The activity on site is referred to in Annex 1 of IPPC Directive 96/61/EC in category 6.7

6.7. Installations for the surface treatment of substances, objects or products using organic

solvents, in particular for dressing, printing, coating, degreasing, waterproofing, sizing, painting,

cleaning or impregnating, with a consumption capacity of more than 150 kg per hour or more than 200 tonnes per year

Supporting information should be included in Attachment No B.10.

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SECTION C: MANAGEMENT OF THE INSTALLATION

C.1 Site Management & Control

Details should be provided on the management structures for the activity. Organisational charts and all relevant environmental management policy statements, including provisions for on-going assessment of environmental performance, are required.

The Site Management Organisation Chart is included in Attachment No. C

C.2 Environmental Management System (EMS)

Indicate whether an Environmental Management System has been developed for the installation. If yes, specify which standard and include a copy of the accreditation certificate. Millipore Ireland B.V. operates an Environmental Management System in accordance with International Standard ISO14001 Environmental Management. A copy of the latest accreditation certificate No. 14.0193 is included in Attachment No. C A copy of the Millipore Cork Operations Policy which includes the site environmental policy is included in Attachment No. C The scope of this accreditation will be extended to include the new processes at the next periodic certification audit. C.3 Hours of Operation

Provide details of the hours of operation for the installation, including: (a) Proposed hours of operation. (b) Proposed hours of construction and development works and timeframes. (c) Any other relevant hours of operation expected. (a) The hours of operation of sections of the plant will vary depending on the demand for the product In the initial stages of manufacture, the shift pattern is likely to be 5 day 3 cycle 8 hour shifts depending on the stages of the technology transfer and the production volume requirements. This may extend to 7 day 4 cycle shift pattern within ca. 2 years of initial start up. (b) Construction on the new facilities will generally be from 0700 to ca. 2100 Monday to Friday and 0700 to 1800 on Saturday with occasional work on Sunday from 0700 to 1800 (c) The plant is in operation at all times of the year. Some parts of the facility may be subject to short duration shutdown periods for maintenance activities. These generally occur in the summertime. The plant may opt to cease operations for short periods such as Christmas or New Year. In all cases there will be a full time security presence on site with back up call in systems in the unlikely event of an incident occurring during these times. This information should form Attachment No C.

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SECTION D: INFRASTRUCTURE & OPERATION

D.1. Operational Information Requirements

D.1.1 Location and aspect:

The company is situated on a ca. 38 acre (15.4ha) site, in what were the grounds of Tullagreen House, Cobh Cross, Carrigtwohill Co. Cork. The grounds and buildings were designed to reduce the visual impact. During construction the original stone walls of the orchard of Tullagreen House were retained and now enclose the employee car park and the tank farm storage area. Mature lime trees adjacent to the wall were retained and complement the beech hedging and birch trees lining the entrance driveway. Millipore maintains the picnic and bird watching area at Slatty Water in front of the plant. The existing site at Tullagreen, covers 15.4 ha., of which approximately 1.4 ha (3.3 acres) are used for offices and production facilities with the remaining land used for ancillary operations, such as effluent treatment and storage area, firewater retention pond and car parking. A large portion of the land is let for agriculture. The site is located in an industrially zoned area. The site is bounded on the northern side by the N25, and on the south side by a local access road. To the east, the site is bounded by farmland; to the west the site is bounded by further farmland and Tullagreen House. Millipore Ireland proposes to extend operations on their existing site only in areas considered suitable for locating additional facilities. The current development proposal will have no significant impact on the developed area of the site as most of the development will take place within the existing warehouse area with only a small bund and solvent storage area being constructed.

D.1.2 PROCESS DESCRIPTION:

The main processes currently undertaken on the Millipore site fall into two categories:

- Assembly of devices - Membrane Manufacture

� Existing: Durapore, Hiflow, J2, IC2, Microweb 2, J1 The new extension will add two further processes to the current manufacturing capability, as follows:

• Controlled Pore Glass (CPG) manufacture • Organic Synthesis – coating of CPG with active substances

The precise details of these processes are confidential as they involve proprietary processes and technology. The facilities will be used to manufacture a range of products, all of which are quite similar in nature and generally involve the same range of raw materials, reagents and solvents. The main raw material comprises glass frits which are manufactured elsewhere and delivered to the site for conversion into controlled pore glass beads and subsequent surface coating.

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Assembly Plant (Clean Rooms 1, 2 and 3):

In this 68,000-sq. ft building plastic parts are injection moulded and assembled as devices in a number of assembly areas with various types of Millipore membranes to produce a range of medical and pharmaceutical filtration devices. Departments within the assembly plant building include:

• Millex©

• Moulding • Millex 33 • Stericup • Centrifugal/ Amicon • Millicell • Multiscreen • Harvester • Filter cutting • Office areas • Warehouse and shipping • Conference facilities

Existing Membrane Manufacture:

D.1.2.1 DURAPORE CASTING (OP2):

In 1989, a separate facility of 22,000 sq. ft was constructed to house the membrane manufacturing facility. Durapore© membranes are thin plastic membranes used in a variety of medical, pharmaceutical and beverage filtration processes. Membrane manufacturing consists of mixing the plastic material, polyvinylidene fluoride (PVDF) powder with solvent to form a lacquer. After mixing, the lacquer is cast onto a plastic film which carries the lacquer through a solvent bath where the membrane forms. The membrane is then separated from the carrier film and rinsed in a series of water rinses, dried, and wound into rolls. To improve the properties of the membrane it is then heat treated in the annealing area, followed by Hydrophilisation to improve the membranes wetability.

D.1.2.2. Aircast ( K Machine) PROCESS Description : Hi-flow membranes offer a basic substrate to which a client’s chemistry can be applied to generate a wide variety of diagnostic assays which are now a common feature of modern clinical and product quality assessments. Hi-flow membranes are presently used in pregnancy test kits, urine and blood sampling. Hi-flow membranes are manufactured using high-grade nitro-cellulose and cellulose acetate derived from wood pulp. The cellulose is mixed with a solvent blend, consisting of acetone (main component) along with ethanol and butanol to form a casting solution. The mixture is blended for three days and then cast onto a continuous stainless steel support belt 1.5 meters wide by 54 meters long. The support belt carries the casting solution through a series of formation and drying chambers. Within the chambers solvent evaporates under controlled conditions allowing nitro-cellulose and cellulose acetate polymers to precipitate and form membrane. Once the membrane is formed it is removed from the stainless steel support belt and passed through a rinse tank. It is then dried, slit and wound into four twelve-inch rolls. The rolls may be slit into smaller widths depending on customer requirements.

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D.1.2.3 J2 PROCESS DESCRIPTION

The J2 Membrane Processing Line is designed for the continuous production of high quality specialty membranes on a 24 hour 7 day operation. Membranes are manufactured using high-grade nitro-cellulose and cellulose acetate derived from wood pulp. The cellulose is mixed with a solvent blend, consisting of acetone (main component) along with ethanol and butanol to form a casting solution. The casting solution (lacquer) is pumped from the mix room on to the J2 casting machine. The lacquer is metered a precise amount to an extrusion slot die which extrudes the lacquer onto a stainless steel belt in a thin uniform layer. The belt conveys the lacquer through formation and drying processing sections where the lacquer is converted to a formed micro porous membrane. The membrane is then stripped off the belt where it is pulled at a controlled tension through an extraction tank where it is washed with an ROUF water/ Detergent mix. The wetted membrane is carried at controlled tension onto an impingement drum dryer where it is dried by high velocity heated air impingement. After the dryer the film is inspected with an on line inspection box into a slitter/winder machine where it is edge trimmed and cut into four strips and wound into rolls. The rolls are removed when they reach the correct footage of product.

D.1.2.4 IC2 PROCESS:

The IC2 process is designed with the capability to manufacture a range of both Durapore and PES membrane. . The main process elements of the IC2 process are:

- Mix Room Membrane lacquer is produced within the mix room. Solvents are fed into mix vessels from the tank farm. Kynar or PES (depending on the product being manufactured) is added to the solvents in the vessels to make the lacquer.

- Casting Machine

The lacquer is fed from the mixroom onto the casting machine via the slot coater. The membrane passes through a formation bath followed by four extraction tanks and finally through a drum dryer. The membrane is rolled onto rollers at the end of the casting machine.

- Annealing

To improve the properties of the membrane it is then heat treated in the annealing area. - Modification Machine

From the annealing area, the membrane is unrolled onto the Modification machine where it is wetted with methanol or monomer, washed with ROUF water and then coated with monomer. The monomer is then extracted from the membrane in methanol extraction tanks as well as hot and cold water extraction tanks.

D.1.2.5 MW2 PROCESS:

The MW2 machine is located in a purpose built building, and consists of the following main elements:

- Mixroom

The existing Highflow mixroom was extended to include additional tanks to feed the MW2 casting process.

MW2 membranes are manufactured using high-grade nitro-cellulose and cellulose acetate derived from wood pulp. The cellulose is mixed with a solvent blend, consisting of acetone (main component) along with ethanol and butanol to form a casting solution.

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- Casting machine

MW2 is a vertical air casting process.

The lacquer is pumped from the mix room to the MW2 casting machine room. The lacquer impregnated web then continues downward through the vertical air chamber where the lacquer is converted to a formed membrane. Conditioned air flows counter current from the bottom of the chamber and is exhausted from the top of the vertical air chamber.

At the bottom of the air cast formation chamber, the web enters a water bath, which acts as the bottom seal for the air chamber. The membrane is then pulled at controlled tension through a multiple zone extraction tank where it is sprayed with ROUF water.

The wetted membrane is carried at controlled tension onto a steam heated drum dryer where it is dried. The dried web is then pulled at controlled tension over an on-line inspection box and into a slitter/winder machine where it is edge trimmed and wound into a single wide roll, or slit into three lanes and wound into narrower width rolls.

D.1.2.6 J1 PROCESS:

The J1 machine is located in the existing Highflow. The existing Highflow mixroom was extended to include additional tanks to feed the J1casting process. J1membranes are manufactured using high-grade nitro-cellulose and cellulose acetate derived from wood pulp. The cellulose are mixed with a solvent blend, consisting of acetone (main component) along with ethanol and butanol to form a casting solution. The casting solution (lacquer) is pumped from the mix room on to the J1 casting machine.

The lacquer is metered a precise amount to an extrusion slot die which extrudes the lacquer onto a stainless steel belt in a thin uniform layer. The belt conveys the lacquer through formation and drying processing sections where the lacquer is converted to a formed micro porous membrane. The membrane is then stripped off the belt where it is pulled at a controlled tension through an extraction tank where it is washed with an ROUF water/ Detergent mix.

The wetted membrane is carried at controlled tension onto an impingement drum dryer where it is dried by high velocity heated air impingement. After the dryer the film is inspected with an on line inspection box into a slitter/winder machine where it is edge trimmed and cut into four strips and wound into rolls. The rolls are removed when they reach the correct footage of product.

D.1.2.7 Controlled Pore Glass (CPG) Manufacture – New Process

The CPG process involves the following unit operations:

• Glass Heating using two electric furnaces • Hot Glass quenching • Glass bead grinding • Glass bead sieving • Acid / Base treatment • Glass bead drying

The CPG process is mainly physical in nature and with the exception of acid / base treatment does not involve the use of any other chemicals or organic solvents. The Organic Synthesis process involves the following unit operations

• Organic synthesis in small pilot scale glass lined reactors • Organic synthesis in small scale glass vessels • Filtration • Drying using a filter dryer • Drying using a tray dryer (future) • Surface treatment of the glass with a range of organic chemicals in small scale glass

vessels • Buffer solution preparation • Drying of finished product using laboratory / pilot scale ovens

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Support operations for the above manufacturing steps involve a range of utilities including:

• Thermal Transfer fluid heating / cooling • Deionised Water generation & distribution • 120kV electricity generation dedicated to the new facility • Storage of drums and small volume solvents • Mini Bulk storage of ca. 32 to 36 % Hydrochloric Acid • Mini Bulk storage of ca. 30 % Sodium Hydroxide • Fume Scrubber • Dust Collection system • Carbon bed adsorption

The details of these support operations are described in section D.1.3 below.

D.1.3 ANCILLARY PROCESS DESCRIPTIONS

D.1.3.1 Tank Farm (West)

This is the original tank farm constructed at the time of the initial plant construction. All bulk solvent is stored in sealed stainless steel tanks in the existing tank farm. Solvents stored include Acetone, Ethanol and Butanol which feed the Highflow, J1, J2 and MW2 processes as well as Acetone, Methanol and Dimethylacetamide for Durapore casting. The tank farm consists of 21 tanks which include virgin, waste, recovered and QC tested solvents. Flammable solvents are stored under Nitrogen blanket. Transfer of solvent to the plant is by stainless steel pipe-work and pump. The tank farm is a bunded area with all runoff from here directed to the wastewater treatment plant. Drummed raw materials (low volume usage) are also stored within the tank farm area. Hazardous waste is stored in the drum store adjacent to the tank farm.

D.1.3.2 Solvent Recovery Unit (No.1)

This is the original solvent recovery unit installed at the time of construction of the original membrane plant. Concentrated solvents from the Durapore casting process are recovered for reuse in the Solvent Recovery Unit. This unit consists of a 3 stage distillation process for the 3 main process solvents.

Recovered solvents are resin filtered and pumped to QC storage. On completion of the relevant tests the solvent is pumped to bulk storage for re-use in the process.

The system consists of a flash vessel followed by two packed distillation columns connected in series. The rig is designed to process two different waste streams during consecutive recovery campaigns; one campaign recovers methanol and DMAc (dimethylacetamide) and the second acetone only.

Feed is introduced to the flash vessel as a liquid at ambient temperature and recirculated through filters and a shell-and-tube heat exchanger. The filters are present to remove small quantities of a soluble polymer called Kynar that comes out of solution when exposed to high temperatures, while the heat exchanger provides the necessary boil-up. The vapour generated in the flash vessel is then directed to column C-301 where water/methanol and high boiling DMAc are separated. The DMAc is removed as a vapour side-stream and the remainder is fed to column C-302 for separation.

During an acetone recovery campaign the vapour from flash vessel V-301 is passed through column C-301 without any separation taking place; the acetone/water split is carried out in column C-302. The overheads are then condensed and collected in reflux vessel V-302 whereupon it is pumped to column C-302; a pre-determined fraction of condensate is returned to C-301 to provide the necessary reflux. The final step in the recovery involves the separation of methanol/water, or acetone/water in column C-302. The methanol/acetone rich overheads are condensed and collected in reflux vessel V-303 and pumped to the QC tanks for analysis and to the larger holding vessels for storage. A pre-determined fraction of condensate is returned to C-302 to provide the necessary reflux, while the aqueous bottoms are directed to effluent.

Recovered solvents are resin filtered and pumped to QC storage. On completion of the relevant tests the solvent is pumped to bulk storage for re-use in the process.

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D.1.3.3 IC2 Tank Farm (East)

This tank farm was constructed in 2007/2008 as part of an expansion of membrane manufacturing operations. The tank farm provides storage for all bulk solvent for use in the IC2 facility. Bulk solvents including Acetone, Methanol, Dimethylacetamide, N-Methyl-2-Pyrrolidone and Triethylene Glycol is stored in sealed stainless steel tanks. These solvents are fed directly to the IC2 mixroom by stainless steel pipe-work and pump. The tank farm contains 33 tanks which includes virgin, waste, recovered and QC tested solvents. The tanks are provided with nitrogen blanketing, conservation vents and emergency vents. Level indication and separate high level protection is provided for each of the tanks. The tank farm is a bunded area with all runoff from here being tested prior to discharge to either the surface water or process systems. Hazardous waste is stored in the drum store adjacent to the tank farm.

D.1.3. Solvent Recovery Unit (No.2)

A new Solvent Recovery Unit is located adjacent to the new tank farm. The IC2 process was designed to maximise recovery of solvent waste streams and so minimise wastewater generation and loading on the WWTP. This SRU has significantly more capability and capacity compared to the original unit.

This SRU is capable of recovering Acetone, Methanol, Dimethylacetamide, NMP and TEG and is operated on a campaign basis.

The SRU consists of a Falling film evaporator, Wiped Film Evaporator and 2 distillation columns. Solvent is fed to the unit from waste solvent tanks in the tank farm with the recovered solvent being directed to dedicated solvent recovery tanks. The solvent is checked by QC prior to being stored in tanks awaiting reuse in the process.

The SRU is a packaged unit with all internal equipment, piping, electrics, installation and controls for operation and is liked to the site utility systems including cooling water and waste water treatment.

The SRU is located in a bunded area, with all runoff diverted to the wastewater treatment plant.

D.1.3.5 Thermal Oxidisers (TO1 & TO2)

The original VOC abatement system at Millipore consists of two regenerative thermal oxidisers with capacities to treat 10,000m3/hr & 5,000 m3/hr VOC’s. Both of these units have been supplied by Megtec Systems. The oxidisers operate on either a duty / standby arrangement with the 10,000m3/hr unit being the duty and the 5,000m3/hr acting as the standby. Under certain process conditions where the VOC loading to the oxidisers is high, both units operate in tandem.

The Thermal Oxidiser and vent header systems are designed to abate emissions from the following sources: Durapore process - Acetone, Methanol Highflow process (K) - Acetone, Ethanol ,Butanol J2 - Acetone, Ethanol,Butanol WWTP – Odour emissions from tank headspace The loading of the Thermal oxidizers varies depending on production in Durapore Highflow & J2. The expected maximum level of solvent to be treated is 15% of LEL. Two LEL meters and a dilution system maintain the feed VOC concentration at 10% - 12% of LEL (maximum). The oxidizer converts the solvent vapours to CO2 and H2O at a temperature of 1,000 deg C. In the event of a bypass on the thermal oxidisers, process emissions will vent to atmosphere via the stack. In the event that that the oxidisers cannot be put back on line within a specified time frame (max 10 minutes) production in all areas is ceased. The existing VOC abatement system is linked to the new thermal oxidiser TO3. The new thermal oxidiser TO3 will therefore act as a backup for the existing system An online FID has been installed on the stack, after the bypass valve. This will ensure that continuous information is available on emission levels

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D.1.3.6 Thermal Oxidiser TO3

This thermal oxidiser system is designed to thermally treat gases that are produced by the IC2 process, MW2,J1 processes as well as VOC’s stripped from off gases from the wastewater plant. The proposed thermal oxidiser is capable of treating 29,000 Nm3/hr of process exhaust and is a regenerative type, similar to the two original units. The VOCSIDIZER consists of a ceramic bed material contained in an airtight steel container. Electrical heating elements are placed in the bed by means of which the required start up temperature is obtained. Once fully operational it will run at a "self-sustaining" level, meaning that the heat release of the VOC oxidation is great enough to negate the need for any fuel or heater input during periods of normal solvent loading. Natural gas is provided as supplementary fuel for the thermal oxidiser. Collection ducting in polypropylene and stainless steel route the vent gases to the thermal oxidiser. LEL monitoring is provided on the ducting and a booster fan draws the gases into the collection ducting. A separate exhaust stack is also provided. The unit is provided with its own controls, which are linked in with the site SCADA system. This unit is fitted with a Residual Air Cleaner (RAC). The RAC consists of a container vessel fabricated from Carbon Steel, insulated and cladded with corrugated galvanized sheet metal. The RAC captures excess emissions generated during poppet changeovers and redirect them back to the inlet to the oxidizer. This ensures that emissions from the oxidizer meet BAT requirements. D.1.3.7 Wastewater Treatment Plant

Millipore’s wastewater treatment plant receives wastewater from Durapore casting, hydrophilisation, High-Flow, Solvent Recovery unit as well as rainwater/runoff from the tanker unloading areas and the tank farm bunds Wastewater from the IC2 process (casting &modification), the new SRU and Tank farm, MW2 as well as J1 will also be directed to the Wastewater Treatment Plant. The operation of the plant depends on production demand but generally runs seven days / week. The pipeline from the process plant to the effluent plant consists of a 6” double contained stainless steel pipe. Wastewater flows to the equalisation Basin, capacity 1200m3. An ultrasonic flow meter in the inlet section measures flow coming into the plant and this measurement is relayed back to the Scada system in the control room at the effluent plant. There are low and high level detectors in the equalisation basin and these will display alarm conditions if the level of effluent exceeds the set point. Two submersible pumps transfer effluent to the aeration tank. These pumps can be set in automatic or manual mode at the required rate. Wastewater is pumped via two duty/standby pumps to the aeration basin, which has a capacity of 1200m3. The aeration basin is an activated sludge system where a population of microorganisms breaks down the organic load in the effluent stream. Oxygen is supplied to the microbes via aeration blowers. There is also a facility to provide oxygen directly to the balancing tank using a BOC Vitox . This tank may be reconfigured to provide additional oxygenation in the event that this is required. This unit has a capacity 125kg O2/hr. Caustic Soda and Nutrients (N and P) are pumped from a covered chemical store to the aeration basin when necessary to adjust either pH or nutrient levels. From the aeration basin the effluent overflows to the final clarifier. In the clarifier, solids are allowed to settle and this settled sludge is returned to the aeration basin or wasted from the system. Excess sludge is dewatered using a centrifuge and disposed of via a suitable waste disposal contractor. The final effluent flows over the weir of the clarifier and towards the outflow weir. The pH of the final effluent is continuously monitored and the information is fed to the Scada system. An online TOC/ Total Nitrogen analyser as well as suspended solids probe constantly monitor the quality of the final effluent. A composite sampler located in the flow-measuring chamber takes a sample from the outflow on a flow proportionate basis. An ultrasonic flowmeter in the outflow continuously measures flows leaving the plant. From the outflow weir the treated effluent flows to the Carrigtwohill Municipal Treatment plant, where it undergoes primary and secondary treatment before discharge to Cork Harbour.

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Waste water from CPG / OS Processes

It is not envisaged that the new CPG and OS processes will require any additional waste water treatment capacity to be added.

It is proposed that the neutralised waste water from the CPG process ( ca.20m3/d) and the reject water (ca. 20 m3/d) from the new water purification plant will be sent directly to the Local Authority Sewer with the approval of the local authority. This will ensure that the hydraulic loading on the activated sludge system is minimised to facilitate stable plant operation.

Most of the waste products from the Organic Synthesis plant will be segregated and treated as hazardous waste. A small amount of waste water is expected to arise from vessel and floor washing which will be directed to the Activated Sludge Waste Water Treatment plant. The volume of this stream is expected to be very small in relation to the current waste water treatment capacity and is not expected to pose any problems for the waste water treatment plant.

D.1.3.8 ROUF Water Purification System

ROUF water is currently used on site in the Durapore, Highflow nd J2, IC2 /MW2 and J1 process areas. Additional Purified water will be required for the new CPG/OS processes. Additional water purification capacity will be provided for the CPG /OS processes which will incorporate reverse osmosis as well as ultrafiltration stages. It is envisaged that two separate water purification systems may be installed each with a capacity of ca. 11 m3/d of purified water. Reject water streams from the existing ROUF systems are discharged directly to sewer via Emission Points SE2 and SE3. It is proposed that the new water purification reject water will be similarly discharged directly to sewer via a new emission point SE7 with the approval of the local authority.

D.1.3.9 Steam and Condensate

It is envisaged that additional steam generation capacity will be required as the process throughput of the membrane plant increases in the coming years. It is proposed to install a new 4.5 tonne per hour ( approx) Dual Fuel Steam Boiler to meet the rising steam demand. This boiler will be operated primarily on natural gas and will only be operated on diesel oil in the event of an interruption in the gas supply to the site. Condensate return systems will be upgraded as required to match the proposed steam generation capacity. D.1.3.10 Nitrogen

A liquid nitrogen tank adjacent to the existing Durapore plant supplies nitrogen to the existing as well as the proposed facilities . The tank is supplied complete with vaporisers and gas controls. D.1.3.11 Natural Gas

Natural gas is used to feed the boilers, CHP, Solvent Recovery units and thermal oxidisers. The new processes or steam generation capacity is not expected to require any significant expansion of the on site natural gas network. D.1.3.12 Heat Transfer Fluid Systems Heating for the OS reactor vessels and dryers is provided by self contained electrically operated heat transfer fluid systems. These are located in a separate services area within the Organic Synthesis area. There are no environmental issues associated with these units. D1.3.13 Standby Electricity Generator

The organic synthesis steps of the process may be adversely impacted in the event of an interruption in the electricity supply at certain critical stages. A 120 KVA diesel generator will be provided to supply emergency power to these critical steps in the event of an interruption in supply from the electricity grid. The unit will be housed in a sound proof enclosure and located out doors in the vicinity of the process area. The precise final location of this unit has not yet been determined but will be advised to the Agency as the design of this aspect of the project is finalised.

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D.1.3.14 Storage of Chemicals The new processes will require the storage of the following chemicals : 32 to 36% Hydrochloric Acid: Stored in a small (ca. 10 m3) tank in a new bund area east of the Warehouse 30 % Sodium Hydroxide : Stored in an small (ca. 10 m3) in a new bund area east of the Warehouse The following drummed chemicals will be stored in 200 l drums in a bonded area in a new Chemical Store Adjacent to the Warehouse

• Propanol • Methanol • Dichloromethane • Acetone • Ethanol (This will be stored in a locked bonded area within the chemical store)

Dimethylsulfoxide will be stored in 200 litre drums in a purpose built store where it will be heated by means of heating jackets to above its melting point (18 Deg C) for transfer to the production area. A range of smaller volume solvents (ca. 1 to 20 litre scale) required for the process will be will be stored in hazardous chemical storage cabinets in the drum store areas and transferred to similar cabinets located in the production areas as required. Cold storage is required for some intermediate and final products. Dedicated small cold stores will be located within the warehouse and production areas. D.1.3.15 Acid Fume Scrubber

The CPG process generates acid fumes arising from the use of Hydrochloric Acid. These fumes are rendered harmless by scrubbing in a sodium hydroxide scrubber. This will be located in a bunded area to the East of the warehouse. The spent caustic solution will be treated in the on site neutralisation system. D.1.3.16 Dust Collection

The CPG process involves the grinding and sieving of glass beads which may give rise to dust. This dust will be captured at source and removed from the area using a dust collector. D.1.3.17 Carbon Adsorption Unit A carbon adsorption unit will be provided to treat the off gases from the process where Dichloromethane is handled. These off gases will already have been subject to vent condensing close to the source of the emission which will minimise the load on the carbon adsorption unit. This will ensure that the requirements of BAT are met in relation to handling chlorinated solvents. D1.3.18 Neutralisation System

All acid and base waste water is neutralised in a dedicated neutralisation system and sent directly to sewer via a new emission point SE 5. This process will not result in any additional BOD/COD load to the local authority sewer.

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D.2 DEVELOPMENT AND OPERATIONAL HISTORY OF THE SITE:

D.2.1 Development and operational history.

Millipore established its operations in Ireland in 1987. The initial phase of the plant manufactured water purification systems and filtration devices. In 1989 the second phase of the plant was established which involved the expansion of the existing manufacturing facility and the construction of a new membrane casting plant. In 1998-1999 a further expansion introduced a new Hi-flow membrane manufacturing process. The company currently employs ca.600 and operates on a twenty-four-hour basis. Millipore’s key customers consist of microelectronics industry and biopharmaceutical research. A summary of Millipore Ireland's development history is given below.

Jul ’87 Construction Commenced

Feb ’88 Filter Cutting and Millex start-up (Production Building OP1)

Jun ‘90 Steritest start-up

Feb ‘90 Construction of Casting Plant (Production Building OP2)

Oct ‘91 ISO 9002 Approval (from NSAI)

Oct’95 CE marking of Medical Devices & EN46002 Approval

July ’98 Construction of Hi-flow membrane manufacturing plant (Production Building Hi-Flow)

Feb ’99 Start-up of Hi-Flow membrane plant

Q4 ’00 ISO14001 accreditation

Apr ‘02 OHSAS 18001 Accreditation

Dec ‘02 Amicon Ultra 15ml

Jan ‘03 Millex 33

Apr ‘03 ISO13488 ‘96

May’03 ISO 9001:2000 Accreditation

Jan 04 2nd Millex 33 machine

Jan ’04 4ml Amicon

Feb ‘05 Harvester / Multiscreen

Dec ‘05 J2 – Air cast machine Jan – Dec 06 Multiscreen, Steriflip, Minicon, Miniplus, Cidra Cut Discs, Millex 13 o/mould,

Monitors, Matched Weights , ISO 14001 – recertification to ISO14001:2004 Jan – Dec 07 Centrifugals / Thermal Oxidiser 3 startup/ MW2, IPPC Licence Jan – Dec 2008 Startup of J1 Machine / IC2 expansion start up D.2.2 Historical Pollution Incidents, Prosecutions etc. There are no disused over or underground storage tanks at Millipore. There are no disused sites of waste disposal/treatment at Millipore. Millipore has a prosecution free history since the company’s start-up in 1987. Details of a spillage of 1320 liters of waste process solution from sump tank 502 on 23rd June 1994 was reported to Cork County Council. Millipore Ireland reported a release of 8,000kgs of methanol form the Solvent Recovery Unit in September 2005.

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Millipore Ireland reported groundwater contamination incidents to the Agency in 2008. An incident report and an environmental risk report are included in Attachment I.5 Millipore Ireland records all environmental incidents as per the “Incident reporting and corrective action procedure”. Any exceedence of license limits or unscheduled emissions are reported to the Agency and are included in the AER.

Attachment No D should contain a list of all unit operations (processes) to be carried out, including flow diagrams of each with any relevant additional information.

SECTION E: EMISSIONS

E.1. Emissions to Atmosphere

E.1.A. Details of all point emissions to atmosphere

Details of all point emissions to atmosphere should be supplied. Complete Table E.1(i) for Boiler Emissions and Table E.1(ii) and E.1(iii) for all other main emission points. Complete Table E.1(iv) for minor emission points. A summary list of the emission points, together with maps and/or drawings (no larger than A3), and supporting documentation should be included as Attachment No E. Plans of emission elevations, relevant roof heights, etc., should also be included, as should detailed descriptions and schematics of all abatement systems. The applicant should address in particular any emission point where the substances listed in the Schedule of S.I. 394 of 2004 are emitted.

For emissions outside the BAT guidance limit, a full evaluation of the existing abatement/treatment system must be provided. A planned programme of improvement towards meeting upgraded standards is required. This should highlight specific goals and a time scale, together with options for modification, upgrading or replacement as required to bring the emissions within the limits as set out in the BAT guidance note(s). These notes can be found on the EPA website at www.epa.ie. The new processes will require a number of additional emission points to air. The new emission points are as follows:

Utility Emission Points :

A1-10 Boiler No. 3

Main Emission Points :

A2-30 CPG Dust Collector A2-32 Scrubber A2-40 Filter Dryer A2-41 Carbon Adsorber

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Minor Emission Points

A3-300 CPG Furnace Canopy A3-301 CPG Furnace Canopy A3-302 CPG Quench Tank A3-303 CPG Drying Oven A3-304 CPG Drying Oven A3-305 CPG Drying Oven A3-306 Final Drying Oven A3-307 Final Drying Oven A3-312 Caustic Wash Tank Vent A3-313 Rinse Tank Vent A3-320 Reactor Area Local Extract Vent A3-321 Reactor Ventilation A3-322 Filter Dryer Local & Emergency Ventilation A3-323 OS Area Oven Vent A3-324 OEM Area Oven Vent A3-325 OEM Fumehood Vent A3-326 OS Area Fume Hood Vents A3-327 Clean Room Local Exhaust Vent A3-328 Clean Room Fume Hood Vent A3-333 Sodium Hydroxide Storage

All Supporting information is included in Attachment No. E.1 A

E.1.B. Fugitive and Potential emissions

Give summary details of fugitive and potential emissions in Table E.1(v). In relation to activities listed in the Schedule of Council Directive 1999/13/EC on the limitation of emissions of volatile organic compounds due to the use of organic solvents in certain activities and installations;

− specify the relevant category of activity in the Schedule − specify how the requirements in relation to fugitive emissions will be met.

The small scale of the process equipment and the relatively small throughput of solvents and reagents means that the relative impact of new fugitive emissions compared to the existing plant will be very small. All of the major solvents for the new processes will be handled in drums and small packages. The handling systems and operating procedures will be designed to minimise fugitive emissions by ensuring that all drums and other solvent containers will be tightly closed except during the short periods when they are in use. We do not anticipate any additional specific fugitive emission points from these processes as all emergency pressure relief systems are ventilated via local exhaust ventilation minor emission points. The process equipment is constructed from Borosilicate Glass and therefore has a maximum operating pressure of 0.5 barg. The small volume of this equipment and the relatively low pressure will limit the quantity of potential emissions in the event of an overpressure developing requiring the operating of pressure relief facilities.

All Supporting information is included in Attachment No. E.1 B

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E.2 Emissions to Surface Waters

Tables E.2(i) and E.2(ii) should be completed. A summary list of the emission points, together with maps/drawings (no larger than A3) and supporting documentation should be included as Attachment No E.2. The applicant should address in particular any emission point where the substances listed in the Schedule of S.I. No. 394 of 2004 are emitted.

Details of all List I and List II substances listed in the Annex to EU Directive 76/464/EEC (as amended), contained in any emission must be presented. All surface water runoff and storm water drains discharging to surface water bodies must be included. A National Grid References (12 digit, 6E, 6N) must be given for all discharge points. The identity and type of receiving water (river, ditch, estuary, lake, etc.) must be stated.

For emissions outside the BAT guidance limit, a full evaluation of the existing abatement/treatment system must be provided. A planned programme of improvement towards meeting upgraded standards is required. This should highlight specific goals and a time scale, together with options for modification, upgrading or replacement as required to bring the emissions within the limits as set out in the BAT guidance note(s). There will be no additional discharges to surface water arising from these processes.

All Supporting information is included in Attachment No. E.2

E.3 Emissions to Sewer

Tables E.3(i) and E.3(ii) should be completed. A summary list of the emission points, together with maps and/or drawings (no larger than A3) and supporting documentation should be included as Attachment No E.3. Details of all List I and List II substances listed in the Annex to EU Directive 76/464/EEC (as amended), contained in any emission must be presented. All relevant information on the receiving sewer, including any effluent treatment/abatement systems, not already described, with schematics as appropriate should also be included in Attachment No E.3. For emissions outside BAT guidance limit (where given), a full evaluation of the existing abatement/treatment system must be provided. A planned programme of improvement towards meeting upgraded standards is required. This should highlight specific goals and a time scale, together with options for modification, upgrading or replacement as required to bring the emissions within any limits set out in the BAT guidance note(s). There will be four new emission points to sewer as follows:

SE4 Existing Cooling Tower Water overflow (rerouted to Sewer) SE5 Neutralised Waste Water from CPG Process SE6 Cooling Water from CPG Furnace & Quench Tank SE7 Retentate from new Water Purification Systems

No significant additional BOD/COD allowance is required for these emission points as the maximum COD concentration limit requested from the local authority is 100 mg/l. The total additional hydraulic load is relatively small at ca. 16 % of the current overall allowance from the site.


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E.4. Emissions to Ground

Describe the existing or proposed arrangements necessary to give effect to Articles 3,4,5,6, and 7 of Council Directive 80/68/EEC of 17 December 1979 on the protection of groundwater against pollution by certain dangerous substances. The applicant should supply details of the nature and quality of the substance (agricultural and non-agricultural waste) to be landspread (slurry, effluent, sludges etc) as well as the proposed application rates, periods of application and mode of application (e.g., pipe discharge, tanker). For emissions outside the BAT guidance limit, a full evaluation of the existing abatement/treatment system must be provided. A planned programme of improvement towards meeting upgraded standards is required. This should highlight specific goals and a time scale, together with options for modification, upgrading or replacement as required to bring the emissions within the limits as set out in the BAT guidance note(s). There are no additional emission points to ground anticipated for these processes.


E.5 Noise Emissions Give particulars of the source, location, nature, level, and the period or periods during which the noise emissions are made or are to be made. Table E.5(i) should be completed, as relevant, for each source. Supporting information should form Attachment No E.5

For emissions outside the EPA Guidance Note for Noise in elation to Scheduled Activities 2nd Edition (2006), a full evaluation of the existing abatement/treatment system must be provided. A planned programme of improvement towards meeting upgraded standards is required. This should highlight specific goals and a time scale, together with options for modification, upgrading or replacement as required to bring the emissions within the limits as set out in the Guidance Note. Most of the new equipment required for the CPG/OS processes will be located indoors. We have designated one additional noise source (the Dust Collector Vent) as this is the point which is located closest to the nearest sensitive receptor at the North West of the site. The equipment is located indoors with a vent point above roof level. We do not anticipate any additional noise at the site boundary as a result of this

development.


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E.6 Tabular Data on Emission Points

Applicants should submit the following information for each emission point: Point

Code

Point Type Easting Northing Verified Emission

Provide label ID’s assigned in section E

A=Atmospheric SW=Surface Water SE = Sewer GW=Groundwater N = Noise SL=Soil/Ground WS=Waste

6E-digit GPS Irish National Grid Reference

6N-digit GPS Irish National Grid Reference

Y = GPS used N = GPS not used

e.g. SO2, HCl, NH3

An individual record (i.e. row) is required for each emission point. Acceptable file formats include Excel, Access or other upon agreement with the Agency. A standard Excel template can be downloaded from the EPA website at www.epa.ie. This data should be submitted to the Agency on a separate CD-Rom containing sections B.2, E.6 and F.3. All supporting information is located in Attachment E.6

SECTION F: CONTROL & MONITORING

Describe the proposed technology and other techniques for preventing or, where this

is not possible, reducing emissions from the installation/facility.

F.1: Treatment, Abatement and Control Systems

Details of treatment/abatement systems (air and effluent emissions) should be included, together with schematics as appropriate.

For each Emission Point identified complete Table F.1(i) and include detailed descriptions and schematics of all abatement systems. The main emissions to be abated with respect to the new processes are as follows:

• Dust Emissions • Caustic Scrubber • Filter Dryer • Carbon Adsorber

Attachment No F.1 should contain any supporting information. All supporting information is included in Attachment No. F.1

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F.2: Emissions Monitoring and Sampling Points

Identify monitoring and sampling points and outline proposals for monitoring emissions. Table F.2(i) should be completed (where relevant) for air emissions, for emissions to surface waters, for emissions to sewers, for emissions to ground, and for waste emissions. Where ambient environment monitoring is carried out or proposed, Table F.2(ii) should be completed as relevant for each environmental medium. Include details of monitoring/sampling locations and methods. Each of the main new emission points will be designated as new monitoring / sampling points as follows:


SE4 Existing Cooling Tower Water overflow (rerouted to Sewer) SE5 Neutralised Waste Water from CPG Process SE6 Cooling Water from CPG Furnace & Quench Tank SE7 Retentate from new Water Purification Systems

Two noise monitoring points, AN3(C) and AB4(D) have been relocated from within the site to the Southern boundary to more accurately reflect the noise levels at the site boundary. The ground water monitoring point AGW 6 has been relocated from its position under the new drum store area to an area down gradient to the South West of the site to more accurately monitor the groundwater status under the site. Attachment No F.2 should contain any supporting information. All supporting information is included in Attachment No. F.2 F.3: Tabular Data on Monitoring and Sampling Points

Applicants should submit the following information for each monitoring and sampling point: Point

Code

Point Type Easting Northing Verified Pollutant

Provide label ID’s assigned in section F3

M=Monitoring S=Sampling

6E-digit GPS Irish National Grid Reference

6N-digit GPS Irish National Grid Reference

Y = GPS used N = GPS not used

e.g. SO2, HCl, NH3

An individual record (i.e. row) is required for each monitoring and sampling point. Acceptable file formats include Excel, Access or other upon agreement with the Agency. A standard Excel template can be downloaded from the EPA website at www.epa.ie. This data should be submitted to the Agency on a separate CD-Rom containing sections B.2, E.6 and F.3. Point source monitoring/sampling refers to monitoring from specific emission points (e.g. from a boiler stack or outlet from a wastewater treatment plant). Examples of ambient monitoring includes monitoring of ambient air quality (e.g. boundary or off-site) or monitoring of river quality upstream/downstream of an effluent discharge.

All supporting information is located in attachment F.3

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SECTION G: RESOURCE USE AND ENERGY EFFICIENCY

G.1 Give a list of the raw and ancillary materials, substances, preparations, fuels

and energy which will be produced by or utilised in the activity.

The list(s) given should be very comprehensive, all materials used, fuels, intermediates, laboratory chemicals and product should be included. Particular attention should be paid to materials and product consisting of, or containing, dangerous substances as described in the EU (Classification, Packaging, Labelling and Notification of Dangerous Substances) Regulations 1994 [SI 77/94]. The list must classify these materials in accordance with Article 2 of these Regulations, and must specify the designated Risk Phrases (R-Phrases) of each substance in accordance with Schedule 2 of the Regulations Tables G.1(i) and G.1(ii) must be completed. Copy as required. All materials for the new processes are shown in the attachment as “NEW”. The quantities of all materials used in the new processes are very small compared to the volume of materials used in the membrane manufacturing processes.

Supporting information should be given in Attachment No G.

G.2 Energy Efficiency A description of the energy used in or generated by the activity must be provided. Outline the measures taken to ensure that energy is used efficiently and where appropriate, an energy audit with reference to the EPA Guidance document on Energy Audits should be carried out. The plant uses electricity and natural gas as sources of primary energy. A 1 MWe combined heat and power plant is in operation on the site. The unit is owned by Bord Gais Eireann who supplies electricity and heat in the form of steam and hot water to the site. The unit currently supplies ca. 40 % of the electricity used on site and ca. 12 % of the thermal energy used on site. The site management is active in the area of Energy Management and has pursued an active Energy Conservation Programme in recent years. A number of energy assessments have been carried out in recent years, the most recent being in 2008 when Millipore engaged with Sustainable Energy Ireland to assist in their efforts to institute a structured energy management system. A proposal is currently with the Agency regarding the completion of a complete Energy Audit when the current expansion of membrane manufacturing is completed. We expect that this audit will be carried out in 2009. The proposed CPG/OS facilities are relatively small compared with the overall site and therefore are not expected to give rise to any significant additional energy use due to the small scale of the production equipment. However, Millipore recognises the importance of considering all aspects of energy efficiency when installing new facilities. Energy conservation will therefore be considered as an integral part of the design process for the new facilities All supporting information is included in attachment G

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SECTION H: MATERIALS HANDLING

H.1 Raw Materials, Intermediates and Product Handling

All materials should be listed in Tables G.1(i) and G.(ii) of Section G. Details of the storage conditions, location within the site, segregation system used and transport systems within the site should be outlined here. In addition, information relating to the integrity, impermeability and recent testing of pipes, tanks and bund areas should be outlined. The new processes require the addition of three new storage areas as follows:

• A bunded area located to the East of the Warehouse area for storage of Acid and Caustic and their associated scrubbing and neutralisation systems.

• A new solvent storage area adjacent to the new production area at the East of the Warehouse building

• Additional storage areas for DMSO and small volume chemicals within the new production area.

In addition to the above specific areas, there will be small quantities of materials stored in chemical storage cabinets in the production areas of the plant. There will also be a small number of cold stores located in the production and warehouse areas.

All supporting information is located in Attachment No H.1

H.2 Describe the arrangements for the recovery or disposal of solid and liquid

wastes accepted into or generated by the installation/facility.

For each waste material, give full particulars of: (a) Name (b) Description & nature of waste (c) Source (d) Where stored and integrity/impermeability of storage areas (e) Amount (m3) and tonnage (f) Period or Periods of generation (g) Analysis (include test methods and Q.C. ) (h) European Waste Catalogue Code (i) Waste Category per EC Reg 1774/2002/EC where relevant Where any waste would be classified as Hazardous Waste as defined in the Waste Management Acts, 1996 to 2003, this should be made clear in the information provided.

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The volumes of waste anticipated for the new processes will be very small compared to the existing on site processes. These will be integrated into the existing waste management systems on site. Summary Tables H.1(i) and H.1(ii) should also be completed, as appropriate, for each waste. The licence/permit register number of the waste collection agent or disposal/recovery operator should be supplied as well as the expiry date of the relevant permits.

All supporting information is located in Attachment No H.2

H.3 Waste disposal by on-site landfilling

For wastes to be disposed of by landfilling on-site, full details of the disposal site should be submitted (to include inter alia, site selection procedures, location maps, (no larger than A3) geology, hydrogeology, operational plan, containment, gas and leachate management, post-closure care). Landfilling of waste does not occur on the Millipore Ireland BV site. All waste to be landfilled is collected and transported by licensed contractors and landfilled in licensed facilities. Supporting information should form Attachment No H.3.

SECTION I: EXISTING ENVIRONMENT & IMPACT OF THE ACTIVITY

Describe the conditions of the site of the installation.

Provide an assessment of the effects of any emissions on the environment, including

on an environmental medium other than that into which the emissions are made.

Describe, where appropriate, measures for minimising pollution over long distances

or in the territory of other states.

I.1.Assessment of atmospheric emissions Describe the existing environment in terms of air quality with particular reference to ambient air quality standards. Provide a statement whether or not emissions of main polluting substances (as defined in the Schedule of S.I. 394 of 2004) to the atmosphere are likely to impair the environment. It is not expected that any of the new emissions will impair the environment.

Give summary details and an assessment of the impacts of any existing or proposed emissions on the environment, including environmental media other than those into which the emissions are to be made. All supporting information is located in Attachment No I.1

Attachment No I.1 should also contain full details of any dispersion modelling of atmospheric emissions from the activity, where required. When carrying out dispersion modelling, regard should be had to the "Guidelines for the Preparation of Dispersion Modelling Assessments for Compliance with Regulatory Requirements – an Update to Royal Meteorological Society Guidance" or similar guidelines from a recognised authority.

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Due to the very small scale of this operation it is considered that full dispersion modelling is not required in this situation. The emissions from the following emission points were subject to screening using US EPA Screen3 Model to confirm the small scale of the emissions:


I.2. Assessment of Impact on Receiving Surface Water Describe the existing environment in terms of water quality with particular reference to environmental quality standards or other legislative standards. Table I.2(i) should be completed Provide a statement whether or not emissions of main polluting substances (as defined in the Schedule of S.I. 394 of 2004) to water are likely to impair the environment. Give summary details and an assessment of the impacts of any existing or proposed emissions on the environment, including environmental media other than those into which the emissions are to be made. There will be no new emissions to surface water arising from these processes. There

will be no impact on the receiving waters.

Full details of the assessment and any other relevant information on the receiving environment should be submitted as Attachment No I.2. All supporting information is located in Attachment No I.2 I.3. Assessment of Impact of Sewage Discharge. Give summary details and an assessment of the impacts of any existing or proposed emissions on the environment, including environmental media other than those into which the emissions are to be made. There will be no significant additional BOD/COD loading at the current waste water treatment outfall. The new emission points will not contribute any significant additional BOD /COD to the sewer. The overall increase in hydraulic load will be ca. 13 % of the current maximum permissible flow to the sewer from the existing processes. Based on the above, we expect no significant additional impact on the local authority sewer arising from these processes. Full details of the assessment and any other supporting information should form Attachment No

I.3.

All supporting information is located in Attachment No I.3

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I.4 Assessment of Impact of Ground/Groundwater Emissions Describe the existing groundwater quality. Tables I.4(i) should be completed. Give summary details and an assessment of the impacts of any existing or proposed emissions on the ground (aquifers, soils, sub-soils and rock environment), including any impact on environmental media other than those into which the emissions are to be made. This includes landspreading, land injection etc. Land on which material may be landspread shall be identified on a suitable scaled map (1:10,560 and 1:50,000) and submitted as no greater than A3 size. All vulnerable (as a result of ground emissions) surface water bodies must be identified on these maps. Additional information should be included in Attachment No I.4. Landspreading of Agricultural/Non Agricultural Wastes Tables I.4(ii) and I.4.(iii) should be complete where applicable. Further information is available in the Application Guidance Document. There will be no additional discharges to ground arising from the new processes.

All supporting information is located in Attachment No I.4 I.5 Ground and/or Groundwater Contamination Summary details of known ground and/or groundwater contamination, historical or current, on or under the site must be given. Full details of recent groundwater investigations are contained in the attachment. Full details including all relevant investigative studies, assessments, or reports, monitoring results, location and design of monitoring installations, plans, drawings, documentation, including containment engineering, remedial works, and any other supporting information should be included in Attachment No I.5. I.6 Assessment of the Environmental Impact of On-site Waste Recovery and/or Disposal.

Describe the arrangements for the prevention and recovery of waste generated by the activity.

Give details, and an assessment of the impact of any existing or proposed on-site waste recovery/disposal on the environment, including environmental media other than those into which the emissions are to be made. The small scale of the new processes will ensure that the volume of additional waste

arising will not be significant compared to that arising from the current activities on

site.

This information should form Attachment No I.6.

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I.7 Noise Impact Give details and an assessment of the impacts of any existing or proposed emissions on the environment, including environmental media other than those into which the emissions are to be made.

Ambient noise measurements Complete Table I.7(i) in relation to the information required below: (i) State the maximum Sound Pressure Levels which will be experienced at typical points on

the boundary of the operation. (State sampling interval and duration) (ii) State the maximum Sound Pressure Levels which will be experienced at typical noise

sensitive locations, outside the boundary of the operation. (iii) Give details of the background noise levels experienced at the site in the absence of

noise from this operation. Prediction models, maps (no larger than A3), diagrams and supporting documents, including details of noise attenuation and noise proposed control measures to be employed, should form Attachment No I.7. The current facilities do not give rise to any significant off site noise impacts as evidenced by the recent Noise Survey Report Ref. 28335 completed in December 2008. The new facilities are largely housed indoors. It is therefore very unlikely that any noise arising from these operations will adversely impact the noise levels at the boundary or at the nearest sensitive receptor which is located to the West of the site. Millipore will add the following noise source to its current list of noise sources:

• N11 Dust Collector

The only other item of outdoor equipment will be a fume scrubber which generally do not give rise to excessive or tonal noise. All new equipment, where practicable, will be specified to meet noise levels of 75 dBA or less measured in free field at 1 m. Two current noise measurement points AN3 (C) and AN4 (D) will be relocated from their current position within the site to positions on the Southern boundary to more accurately reflect the true measurements at the boundary. Millipore will undertake baseline measurements at these new points prior to commencement of the new CPG/OS operations to provide baseline data for comparison. I.8 Environmental Considerations and BAT

Describe in outline the main alternatives, if any, to the proposals contained in the

application.

Describe any environmental considerations which have been made with respect to the use of cleaner technologies, waste minimisation and raw material substitution. Describe the measures proposed or in place to ensure that: (g) The best available techniques are or will be used to prevent or eliminate or, where that

is not practicable, generally reduce an emission from the activity; (h) no significant pollution is caused;

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(i) waste production is avoided in accordance with Council Directive 75/442/EEC of 15 July 1975 on waste; where waste is produced, it is recovered or, where that is technically and economically impossible, it is disposed of while avoiding or reducing any impact on the environment;

(j) energy and other resources are used efficiently; (k) the necessary measures are taken to prevent accidents and limit their consequences; (l) the necessary measures are taken upon definitive cessation of activities to avoid any

pollution risk and return the site of operation to a satisfactory state. The new facilities will be designed to meet the requirements of BAT as defined in

the relevant EPA and EU BREFs. Supporting information should form Attachment No I.8.

SECTION J: ACCIDENT PREVENTION & EMERGENCY RESPONSE

Describe the existing or proposed measures, including emergency procedures, to minimise the impact on the environment of an accidental emission or spillage. Also outline what provisions have been made for response to emergency situations outside of normal working hours, i.e. during night-time, weekends and holiday periods. Describe the arrangements for abnormal operating conditions including start-up, leaks, malfunctions or momentary stoppages. The small scale of the new processes and the relatively small volumes of additional hazardous chemicals required will not give rise to any significant additional risks on the site. The current accident prevention and emergency response systems and procedures will be adequate for the new processes. All supporting information is located in Attachment No J

SECTION K: REMEDIATION, DECOMMISSIONING, RESTORATION & AFTERCARE

Describe the existing or proposed measures to minimise the impact on the environment after the activity or part of the activity ceases operation, including provision for post-closure care of any potentially polluting residuals. Supporting information should be included as Attachment No. K. Millipore has submitted an Environmental Liabilities Risk Assessment incorporating a Residuals Management Plan to the Agency in accordance with the terms of the existing IPPC license. The level of investment in the new facilities will be in the order of €6 M. This is relatively modest compared to the capital replacement value of the existing facilities. The extent of the new facilities is quite modest in comparison to the existing plant and equipment. The impact of the new facilities on the ELRA or RMP is therefore expected to be small. Millipore will update the ELRA and the RMP following completion of the installation of the CPG/OS facilities when the impact can be fully determined and quantified. All supporting information is located in Attachment No K

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SECTION L: STATUTORY REQUIREMENTS

Indicate how the requirements of Section 83(5)(a)(i) to (v) and (vii) to (x) of the EPA Acts, 1992 and 2003 shall be met, having regard, where appropriate, to any relevant specification issued by the Agency under section 5 (3) of the Act and the reasons for the selection of the arrangements proposed. Indicate whether or not the activity is carried out, or may be carried out, or is located such that it is liable to have an adverse effect on - (a) a site placed on a list in accordance with Chapter 1 of SI 94 of 1997, or (b) a site where consultation has been initiated in accordance with Article 5 of the EU Habitats Directive (92/43/EEC), or Indicate whether or not the activity is liable to have an adverse effect on water quality in light of S.I. No. 258 of 1998 (Local Government (Water Pollution) Act, 1977 (Water Quality Standards for Phosphorus) Regulations, 1998). Indicate whether any of the substances specified in the Schedule of the EPA (Licensing) (Amendment) 2004, S.I. 394 of 2004, are discharged by the activity to the relevant medium. The new processes will not change the status of the site with respect to the above

legislation.

Fit and Proper Person The PoE Act in Section 83(5) (xi) specifies that the Agency shall not grant a licence unless it is satisfied that the applicant or licensee or transferee as the case may be is a fit and proper person. Section 84(4) of the PoE Act specifies the information required to enable a determination to be made by the Agency. • Indicate whether the applicant or other relevant person has been convicted under the

PoE Act, the Waste Management Act 1996, the Local Government (Water pollution) Acts 1977 and 1990 or the Air Pollution Act 1987.

• Provide details of the applicant’s technical knowledge and/or qualifications, along with

that of other relevant employees. • Provide information to show that the person is likely to be in a position to meet any

financial commitments or liabilities that may have been or will be entered into or incurred in carrying on the activity to which the application relates or in consequence of ceasing to carry out that activity.

Supporting information should be included as Attachment No L with reference to where the information can be found in the application. Ms. Liz Henderson, EU Environmental, Health and Safety Manager is the nominated person with respect to the Protection of the Environment Act and is deemed to be a ‘fit and proper person’ under the terms of this act. All supporting information is located in Attachment No L

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SECTION M: DECLARATION

Declaration

I hereby make application for a licence / revised licence, pursuant to the provisions of the Environmental Protection Agency Acts, 1992 and 2003 and Regulations made thereunder. I certify that the information given in this application is truthful, accurate and complete. I give consent to the EPA to copy this application for its own use and to make it available for inspection and copying by the public, both in the form of paper files available for inspection at EPA and local authority offices, and via the EPA's website. This consent relates to this application itself and to any further information, submission, objection, or submission to an objection whether provided by me as Applicant, any person acting on the Applicant’s behalf, or any other person.

Signed by: Date: _________________ (on behalf of the organisation)

Print signature name: _________________

Position in organisation: _________________

Company stamp or seal:

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ANNEX 1: TABLES/ATTACHMENTS

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Table E.1 (i) BOILER EMISSIONS TO ATMOSPHERE (1 Page for each emission point) Emission Point:

Emission Point Ref. No:

A1-1

Location:

Byworth Steam Boiler, Services Room, OP2 building

Grid Ref. (12 digit, 6E,6N):

E180780,N072578

Vent Details

Diameter: 635 mm

Height above Ground(m): 14.32

Date of commencement of emission:

1990

Characteristics of Emission:

Boiler rating Steam Output: Thermal Input:

5443 kg/hr

4.396 MW Boiler fuel Type: Maximum rate at which fuel is burned % sulphur content:

Natural Gas 327 kg/hr

No S in natural gas. Trace sulphur added for safety reasons. NOx <200 mg/Nm3

0oC. 3% O2(Liquid or Gas), 6% O2(Solid Fuel) Maximum volume* of emission

9840 m3/hr 0oC, 3 % O2 (liquid or gas), 6 % O2 (solid fuel)

Temperature

256 oC(max) 299 oC(min) 243 oC(avg)

* Volume flow limits for emissions to atmosphere shall be based on Normal conditions of temperature and pressure, (i.e. 0oC,101.3kPa), dry gas; 3% oxygen for liquid and gas fuels; 6% oxygen for solid fuels.

(i) Period or periods during which emissions are made, or are to be made, including daily or seasonal variations (start-up/shutdown to be

included):

Periods of Emission (avg)

60 min/hr 24 hr/day 345 day/yr

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A1-4 - CHP plant,

Location:

Inside walled employee car park


E180794, N072478

Vent Details

Diameter: 400 mm

Height above Ground(m): 5


2001



500 kg/hr 0.690 MW

Boiler fuel Type: Maximum rate at which fuel is burned % sulphur content:

Natural Gas

209.6 kg/hr (262 m3/hr) No S in natural gas. Trace sulphur added for safety reasons

NOx <500 mg/Nm3


5472 m3/hr 0oC, 3 % O2 (liquid or gas), 6 % O2 (solid fuel)

Temperature

120 oC(max) 100 oC(min) 110 oC(avg)


(i) Period or periods during which emissions are made, or are to be made, including daily or seasonal variations (start-up/shutdown to be

included):



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A1-5

Location:

Corcoran Steam Boiler, Services Room, OP2 building


E.180784, N.072582

Vent Details

Diameter:

610 mm

Height above Ground(m):

14.32


2001


Boiler rating

Steam Output:

Thermal Input:

5700 kg/hr

4.013 MW Boiler fuel

Type:

Maximum rate at which fuel is burned

% sulphur content:

Natural Gas

327.2 kg/hr

No S in natural gas. Trace sulphur added for safety reasons

NOx mg/Nm3

0oC. 3% O2(Liquid or Gas), 6% O2(Solid Fuel) Maximum volume* of emission 9840 m3/hr

Temperature

oC(max) oC(min) 231oC(avg)


(i) Period or periods during which emissions are made, or are to be made, including daily or seasonal variations (start-up/shutdown to be included):



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A1-10

Location:

Proposed location adjacent to existing units


E.180787, N.072585

Vent Details

Diameter: 635 mm

Height above Ground(m): 14.32 m approx


Proposed July 09



4500kg/hr 3.96 MW

Boiler fuel Type: Maximum rate at which fuel is burned % sulphur content:

Natural Gas will be the normal fuel used. The boiler will be designed to operate on Low

Sulphur(0.1%) diesel fuel in the event of an interruption to the supply of natural gas to the site. No sulphur is present in natural gas except for trace odourant added for safety reasons

Natural Gas 258 kg/hr Diesel Oil : 346 kgs/r

Sulphur Content 0.35 kg/hr NOx <200 mg/Nm3


20,000 m3/hr 0oC, 3 % O2 (liquid or gas), 6 % O2 (solid fuel)

Temperature

oC(max) oC(min) 231 oC(avg)


(i) Period or periods during which emissions are made, or are to be made, including daily or seasonal variations (start-up/shutdown to be included):



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TABLE E.1(ii) MAIN EMISSIONS TO ATMOSPHERE (1 Page for each emission point)


A2-30

Source of Emission:

Dust Collector

Location:

CPG Building Roof


E180847 N072481

Vent Details Diameter:


400 mm 6.125

Date of commencement:

July 1st 2009


(i) Volume to be emitted:

Average/day 215000Nm3/d Maximum/day 257600Nm3/d

Maximum rate/hour 10732 Nm3/h Min efflux velocity 0.263 m.sec-1

(ii) Other factors

Temperature oC(max) oC(min) 20 \oC(avg)

For Combustion Sources: Volume terms expressed as : � wet. � dry. ________%O2

(iii) Period or periods during which emissions are made, or are to be made, including daily or seasonal variations (start-up /shutdown

to be included):



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A2-32

Source of Emission:

Caustic Scrubber

Location:

Bund at East side of Warehouse


E180879 N 072529



200mm 8.0


1st July 2009



Average/day 300Nm3/d Maximum/day 500Nm3/d

Maximum rate/hour 12Nm3/h Min efflux velocity 0.11 m.sec-1

(ii) Other factors

Temperature 25 oC(max) 5 oC(min) 20 oC(avg)



to be included):



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A2-40

Source of Emission:

Filter Dryer

Location:

OS Production Area Roof


E180873 N072488



50 mm 6.125


1st July 2009



Average/day 60 Nm3/d Maximum/day 120 Nm3/d

Maximum rate/hour 19 Nm3/h Min efflux velocity 2.7 m.sec-1

(ii) Other factors

Temperature 20oC(max) -80 oC(min) -70 oC(avg)



to be included): This unit will only operate on a very limited number of days per year due to the campaign nature of the process



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A2-41

Source of Emission:

Carbon Adsorber

Location:

OS Production Area roof


E180873 N072488



100 mm


1st July 2009


(i) Volume to be emitted: The volume to be emitted from this unit is very small due to the small volume of the equipment to which it is connected.

Average/day Nm3/d Maximum/day 1 Nm3/d

Maximum rate/hour 0.1 Nm3/h Min efflux velocity 0.04 m.sec-1

(ii) Other factors

Temperature 25oC(max) 5 oC(min) 20oC(avg)


(iii) Period or periods during which emissions are made, or are to be made, including daily or seasonal variations (start-up /shutdown to be included):



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TABLE E.1(iii): MAIN EMISSIONS TO ATMOSPHERE - Chemical characteristics of the emission (1 table per emission point) Emission Point Reference Number: A2-30

Parameter Prior to treatment(1) Brief As discharged(1)

mg/Nm3 kg/h description mg/Nm3 kg/h. kg/year

Avg Max Avg Max of treatment Avg Max Avg Max Avg Max

Glass Dust 150 180 1.36 1.63 Cyclone dust collection with outlet filter

0.75 1/m3 5.7E-3 6.8E-3 48 60

1. Concentrations should be based on Normal conditions of temperature and pressure, (i.e. 0oC,101.3kPa). Wet/dry should be the same as given in Table E.1(ii) unless clearly stated otherwise.

TABLE E.1(iii): MAIN EMISSIONS TO ATMOSPHERE - Chemical characteristics of the emission (1 table per emission point)

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Emission Point Reference Number: A2-32




Inorganic Chlorides 3.23 9.8 3.88E-5 0.00011 Counter current scrubbing with sodium hydroxide solution

0.0323 0.098 3.2E-7 1.18E-6 1.42E-4 4E-4

1. Concentrations should be based on Normal conditions of temperature and pressure, (i.e. 0oC,101.3kPa). Wet/dry should be the same as given in Table E.1(ii) unless clearly stated otherwise.

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Methanol 70000 631578 1.33 12 Ultra low temperature condensation

8.6E-5 2.6E-4 0.0016 0.0049 0.6 1.817

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Dichloromethane N/A N/A 0.00021 0.0005 Carbon Adsorption N/A N/A 2.1E-5 5E-5 2.1E-4 5E-4

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TABLE E.1(iv): EMISSIONS TO ATMOSPHERE - Minor atmospheric emissions

Emission point Description Emission details1 Abatement system employed

Reference Numbers material mg/Nm3(2)

kg/h. kg/year

A3-300 CPG Furnace Canopy Warm Air

A3-301 CPG Furnace Canopy Warm Air

A3-302 CPG Quench Tank Warm Air/Water

A3-303 CPG Drying Oven Vent Water Vap



A3-306 Final Drying Oven Vent Water Vap

A3-307 Final Drying Oven Vent Water Vap

A3-312 Caustic Waste Tank

Trace NaOH

A3-313 Rinse Tank Water Vap

A3-320 Reactor Area Local Extract Trace Organics

A3-321 Reactor Ventilation Trace Organics

1 The maximum emission should be stated for each material emitted, the concentration should be based on the maximum 30 minute mean.

2 Concentrations should be based on Normal conditions of temperature and pressure, (i.e. 0oC101.3kPa). Wet/dry should be clearly stated. Include reference oxygen conditions for combustion sources.

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TABLE E.1(iv): EMISSIONS TO ATMOSPHERE - Minor atmospheric emissions

Emission point Description Emission details1 Abatement system employed

Reference Numbers Material mg/Nm3(2)

kg/h. kg/year

A3-322 Filter Dryer Local / Emrg Vent

Trace Methanol

None

A3-323 OS Area Oven Vent Water Vap None

A3-324 OEM Area Oven Vent Trace Org None

A3-325 OEM Area Fumehood Vent Trace Org None

A3-326 OS Area Fume Hood Vents Trace Org None

A3-327 Clean Room Local Exhaust Trace Org None

A3-328 Clean Room Fume Hood Trace Org None

A3-333 Sodium Hydroxide Storage Trace NaOH

None

A3-350 Laboratory Fumehood Trace Org None



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TABLE E.1(v): EMISSIONS TO ATMOSPHERE – Fugitive and Potential atmospheric emissions

Emission point ref. no. (as per flow diagram)

Description Malfunction which could cause an

emission

Emission details (Potential max. emissions)1

Material mg/Nm3 kg/hour

There are not expected to be any significant separate fugitive emission or potential emission points as all emissions will come through minor emission points as per TableE.1(iv) with the exception of 120Kva generator

Emergency Generator

Power outage Hydrocarbons

Carbon Monoxide

NOx

Particulates

35

150

2800

80

0.046

0.2079

3.88

0.11

1 Estimate the potential maximum emission for each malfunction identified.

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TABLE E.2(i): EMISSIONS TO SURFACE WATERS (One page for each emission)

Emission Point:

Emission Point Ref. No: SW1

Source of Emission: Stormwater

car parks, roof areas , Hard standing draining to collection system

Location : Slatty Creek, Cork Harbour

Grid Ref. (12 digit, 6E,6N): E18084, N07225

Name of receiving waters: Slatty Creek, Cork Harbour

Flow rate in receiving waters: Not known m3.sec-1 Dry Weather Flow

Not known m3.sec-1 95%ile flow

Available waste assimilative capacity:

Not known kg/day

Emission Details:

(i) Volume to be emitted

Normal/day Rain 80 80m3 Maximum/day Rain 360 600m3

Maximum rate/hour Rain 92 m3

(ii) Period or periods during which emissions are made, or are to be made, including daily or seasonal variations (start-up /shutdown

to be included):

Periods of Emission (avg) 60 min/hr 24 hr/day 365 day/yr

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TABLE E.2(ii): EMISSIONS TO SURFACE WATERS - Characteristics of the emission (1 table per emission point) Emission point reference number :

Parameter Prior to treatment As discharged % Efficiency

Max. hourly average (mg/l)

Max. daily average (mg/l)

kg/day kg/year Max. hourly average (mg/l)


kg/day kg/year

Not applicable

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TABLE E.3(i): EMISSIONS TO SEWER (One page for each emission)

Emission Point:

Emission Point Ref. No: SE1

Location of connection to sewer: Adjacent to the Wastewater Treatment plant

Grid Ref. (12 digit, 6E,6N): E180793, N 072589

Name of sewage undertaker: Cork County Council

Emission Details:


Normal/day 450 m3 Maximum/day 600 m3

Maximum rate/hour 25 m3


to be included):



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Emission Point:


Location of connection to sewer: Highflow / Durapore

Grid Ref. (12 digit, 6E,6N): E180793, N072573


Emission Details:


Normal/day 168m3 Maximum/day 168m3

Maximum rate/hour 7m3


to be included):



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Emission Point:


Location of connection to sewer: IC2 area

Grid Ref. (12 digit, 6E,6N): E 180961, N072567


Emission Details:





to be included):




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Emission Point:


Location of connection to sewer: Cooling Tower IC2

Grid Ref. (12 digit, 6E,6N): E 181006, N072562


Emission Details:


Normal/day 50 m3 Maximum/day 50 m3



to be included):



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Emission Point:


Location of connection to sewer: Neutralisation system CPG

Grid Ref. (12 digit, 6E,6N): E 180916, N 07259


Emission Details:





to be included):



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Emission Point:


Location of connection to sewer: East of CPG/OS building

Grid Ref. (12 digit, 6E,6N): E 180903 , N 072493


Emission Details:





to be included):



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Emission Point:


Location of connection to sewer: East of CPG/OS Building

Grid Ref. (12 digit, 6E,6N): E180899, N 072485


Emission Details:





to be included):



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TABLE E.3(ii): EMISSIONS TO SEWER - Characteristics of the emission (1 table per emission point) Emission point reference number : SE1






kg/day kg/year

BOD

12,000 740 <268,000 3300 440 46000 69%

COD

20,000 1960 <700,000 8100 1100 114,400 74%

Suspended Solids

1000 400 18800

Sulphates

100 14 1800

Acrylates <1 <0.12 <42 <1 < 0.12 < 42

Total N (as N) 500 20 6,800 600 80 6200

Oils Fats Greases 30 3 1095

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kg/day kg/year

COD

100

Suspended Solids

10

Sulphates

200

Chlorides 250

Total Heavy Metals 1

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kg/day kg/year

COD

10

Suspended Solids

10

Sulphates

60

Total N (as N) 1.0

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kg/day kg/year

COD

100

Suspended Solids

10

Sulphates

200

Chlorides 250


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kg/day kg/year

COD

100

Suspended Solids

10

Sulphates

200

Chlorides 5000


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kg/day kg/year

COD

100

Suspended Solids

10

Sulphates

200

Chlorides 250


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TABLE E.4(i): EMISSIONS TO GROUND (1 Page for each emission point)

Emission Point or Area:

Emission Point/Area Ref. No:

SL1

Emission Pathway: (borehole, well, percolation area, soakaway, landspreading, etc.)

Rainwater Soakaway

Location :

North of Highflow Building


E18083, N07260

Elevation of discharge: (relative to Ordnance Datum)

Not known

Aquifer classification for receiving groundwater body:

Rf, regionally important fissured bedrock aquifer Lg, locally important sand/gravel aquifer

Groundwater vulnerability assessment (including vulnerability rating):

Vulnerability of the gravel areas is considered high where the watertable is >3m below the surface and considered extreme where the watertable is <3m below the surface.

Identity and proximity of groundwater sources at risk (wells, springs, etc):

Five groundwater monitoring wells on site – monitored on an annual basis. No other known wells in the vicinity.

Identity and proximity of surface water bodies at risk:

Tidal, Slatty Creek, Cork Harbour. 300 m from the centre of the site. Stream at western site boundary.

Emission Details:


Normal/day m3 Maximum/day m3

Maximum rate/hour m3


to be included):

Periods of Emission (avg) min/hr hr/day day/yr

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TABLE E.4(i): EMISSIONS TO GROUND (1 Page for each emission point)

Emission Point or Area:

Emission Point/Area Ref. No:

SL2

Emission Pathway: (borehole, well, percolation area, soakaway, landspreading, etc.)

Rainwater Soakaway

Location :

Path outside effluent plant control room building


E18097, N07260

Elevation of discharge: (relative to Ordnance Datum)

Not known

Aquifer classification for receiving groundwater body:

Rf, regionally important fissured bedrock aquifer Lg, locally important sand/gravel aquifer

Groundwater vulnerability assessment (including vulnerability rating):

Vulnerability of the gravel areas is considered high where the watertable is >3m below the surface and considered extreme where the watertable is <3m below the surface.

Identity and proximity of groundwater sources at risk (wells, springs, etc):

Five groundwater monitoring wells on site – monitored on an annual basis. No other known wells in the vicinity.

Identity and proximity of surface water bodies at risk:

Tidal, Slatty Creek, Cork Harbour. 300 m from the centre of the site. Stream at western site boundary.

Emission Details:


Normal/day m3 Maximum/day m3

Maximum rate/hour m3


to be included):

Periods of Emission (avg) min/hr hr/day day/yr

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TABLE E.4(ii): EMISSIONS TO GROUND - Characteristics of the emission (1 table per emission point) Emission point/area reference number: SL1 (uncontaminated rainwater)






kg/day kg/year

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TABLE E.4(ii): EMISSIONS TO GROUND - Characteristics of the emission (1 table per emission point) Emission point/area reference number: SL2 (uncontaminated rainwater)






kg/day kg/year

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Table E.5(i): NOISE EMISSIONS - Noise sources summary sheet

Source Emission point

Ref. No

Equipment Ref. No

Sound Pressure1 dBA at

reference distance

Octave bands (Hz) Sound Pressure1 Levels dB(unweighted) per band

Impulsive or tonal qualities

Periods of

Emission

31.5 63 125 250 500 1K 2K 4K 8K Chillers phase 1

N2

78@2m

72

82

79

78

74

74

68

61

52

broadband

24 hours

AHU VMF1 N3

75 at louvre

83

82

80

77

74

70

60

54

47

broadband

24 hours

AHU VMF4 N4

81 at louvre

87

85

83

85

76

75

73

66

62

broadband

24 hours

Drier Exhaust N5

77 @1m

81 78

80

80

72

71

67

64

54

broadband

24 hours

High velocity stack

N6

75 @1m

77

81

74

71

68

69

72

64

55

broadband

24 hours

Woods Roof Unit (near drier exhaust)

N7

77@1m

80

81

80

80

75

72

68

62

57

broadband

24 hours

Chillers (behind AHU VMF4)

N8

84@1m

81

89

85

90

82

79

72

67

60

broadband

24 hours

Thermal Oxidiser fan

N9 72@3m 72 74 73 68 70 67 64

59 54 broadband

24 hours

CHP

N10 CHP @8ms 68dB(A)

- 72 72 69 67 61 61 51 48 Non-tonal

24hr

Dust Collector N11 75 @ 1 m TBC - - - - - - - - Broadband 24 hr

1. For items of plant sound power levels may be used.

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TABLE F.1(i): ABATEMENT / TREATMENT CONTROL

Emission point reference number : A1 -1

Control1 parameter Equipment 2 Equipment maintenance Equipment calibration Equipment back-up

Burn temperature. Gas burner Monthly PM Ref. Procedure 004057650 in Attachment 12

Gas and air flowrates (backpressure).

Gas/air mix valve (flow control)

Monthly PM Ref. Procedure 004057650 in Attachment 12

Yearly overhaul for Insurance Co.

Control1 parameter Monitoring to be carried out3 Monitoring equipment Monitoring equipment calibration

Carbon monoxide in exhaust gas.

Burn efficiency Flue gas analyser – Geoff Castles boiler services

NOx in exhaust gas Emissions test Flue gas analyser – Geoff Castles boiler services

1 List the operating parameters of the treatment / abatement system which control its function. 2 List the equipment necessary for the proper function of the abatement / treatment system. 3 List the monitoring of the control parameter to be carried out.

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Emission point reference number : A1 - 4


Burn temperature. Gas burner PM PM carried out by Edina



PM PM carried out by Edina




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Emission point reference number : A1 - 5


Burn temperature. Gas burner Monthly PM Ref. Procedure 004057650



Monthly PM Ref. Procedure 004057650







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BLE F.1(i): ABATEMENT / TREATMENT CONTROL

Emission point reference number : A1 – 10 ( Proposed New Boiler)


Burn temperature. Gas burner Monthly PM Ref. Procedure 004057650



Monthly PM Ref. Procedure 004057650







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ABLE F.1(i): ABATEMENT / TREATMENT CONTROL

Emission point reference number : A1-7


Air flow rate fan Monthly preventive maintenance

N/A Duty only. Motor and fan spares in stock.

Gas flow rate (auxillary fuel) Gas control valve Monthly preventive maintenance

N/A

Bed Temperature Thermocouples Annual PM Spares held on site


Inlet VOC concentration Continuous LEL monitoring. LEL monitors (2 of) Auto-calibrating instruments. Service contract with LEL suppliers.

Thermal Oxidiser emissions Continuous TOC analysis Siemens Fidamat FID analyser Auto-calibrating instruments service contract with supplier


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Emission point reference number : A1-8




Gas flow rate (auxillary fuel) Gas control valve Monthly preventive maintenance

N/A

Bed Temperature Thermocouples Annual PM Spares held on site


Inlet VOC concentration Continuous LEL monitoring. LEL monitors (2 of) Auto-calibrating instruments. Service contract with LEL suppliers.

Thermal Oxidiser emissions Continuous TOC analysis Siemens Fidamat FID analyser Auto-calibrating instruments service contract with supplier


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Emission point reference number : A2-32 ( Fume Scrubber)




pH pH Analyser Quarterly Calibration


Pump Outlet Pressure

Air Flow

Pressure monitoring

Air Flow confirmation

Pressure Transmitter

Air Flow Switch

Annual calibration

Annual calibration


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Emission point reference number : A2-30 ( Dust Collector)





Filter Differential Pressure Differential Pressure Differential Pressure Monitor Annual Pressure Calibration


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Emission point reference number : A2-40 Filter Dryer Vent


Vacuum Pump System Vacuum Pump Annual PM N/A Duty only. Motor and fan spares in stock.

Low temperature cooling unit

Low Temperature Cooling Annual PM Annual Temperature calibration

Duty only. Motor and fan spares in stock.


Vacuum Pump Pressure

Temperature

Vacuum/ Pressure monitoring

Cooling System Temperature

Vacuum /Pressure Transmitter

Temperature Transmitter

Annual calibration

Annual calibration


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Emission point reference number : A2-41 Carbon Adsorber


Air Flow Fan Annual PM N/A Duty only. Motor and fan spares in stock.

Carbon Adsorption Activated Carbon Bed Annual PM N/A Spare Carbon in stock


Air Flow

Differential Pressure

Air Flow Monitoring

Differential Pressure Monitoring

Air Flow Switch

Differential Pressure Switch

Annual calibration

Annual calibration


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Emission point reference number : SW1


Oil and petrol from car parks

Oil interceptor Visual inspection twice weekly

Not applicable Not applicable


Oil and petrol from car parks Depth of the oil film should be checked periodically using Veeder-Root water-finding paste.

Dipstick of suitable length with a notch or other mark to indicate the surface level

Not applicable


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Emission point reference number : SE1


Duty & Standby Blowers in the aeration tanks

2 x 35Kw blowers D.O. probe checked and calibrated at regular intervals

Blowers

D.O. probe checked and calibrated

Spare probe in stock.

PH in aeration tank Caustic IBC and pump. Pump on preventive maintenance programme.

Pump delivery rate checked by Environmental personnel.

Pump spares in stock.

Nutrient level (N&P) Nutrient IBC and pump Pump on preventive maintenance programme

Pump delivery rate checked by Environmental personnel.

Pump spares in stock.

Flow Equalisation basin forward feed pumps

On PM schedule Flow meters calibrated annually

Duty standby

Pumps & motor spares

Sludge return / Wasting Sludge return pumps On PM Schedule N/A Duty standby

Pumps & motor spares

Temperature Heat Exchanger / Temperature probe

Pumps

On PM Schedule Temperature Probe calibrated annually

Spares


C.O.D. Daily Influent and Effluent C.O.D. HACH C.O.D. test kit. (heating element and colorimeter).

Standard solution used each day. Heating block and spectrophotometer on calibration schedule

pH Daily Aeration Tank and Effluent pH meter in analysis lab. Calibrated daily using buffer

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pH. solutions. Checked quarterly by contract company

MLSS

Daily aeration basin MLSS.

Electronic balance and oven.

Balance & oven weekly & calibrated annually.

Suspended Solids Effluent analyed on a continuous basis – composite sample tested daily

Electronic balance and oven.

In line suspended solids analyser

Balance & oven weekly & calibrated annually.

Calibrated by quarterly by contract company

Total Nitrogen

effluent & balance tank analysed daily.

Effluent monitored on a continuous basis

HACH Test N’Tube total N test

In line total N/ TOC analyser


C.O.D. Daily Influent and Effluent C.O.D. HACH C.O.D. test kit. (heating element and colorimeter).



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Emission point reference number : SL1 (Uncontaminated Water)


Not applicable



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Emission point reference number : SL2 (uncontaminated Water)


Not applicable



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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : A1-1 Byworth Boiler in OP2

Parameter Monitoring frequency Accessibility of Sampling Points

Sampling method Analysis method/ technique

NOx

Annually

Accessible.

Portable analyser Flue Gas analyser

CO Annually Accessible.


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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : A1-4 CHP Plant



NOx

Annually

Accessible.


CO Annually Accessible. Ladder to roof in warehouse.


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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : A1-5 Corcoran Boiler in OP1



NOx

Annually

Accessible.

Portable analyser Kane Mae Quintox Flue Gas Analyser



For

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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : A1-10 (Proposed Boiler)



NOx

Annually

Accessible.




For

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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : A1-8 Thermal Oxidiser



NOx

Quarterly

Accessible.

Heated sampling line with probe attached

Portable analyser

VOC’s Continuous Accessible FID On line FID

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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : A1-7 Thermal Oxidiser



VOCs Monthly (30 minutes) Accessible.

Heated sampling line with probe attached

Portable Bernath Atomic Heated FID for Total VOC Monitoring

NOx Monthly (30 minutes) Accessible.

Flue gas analyser Kane Mae Quintox Flue Gas Analyser

For

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ectio

n pur

pose

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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : A2-30 Dust Collector



Dust

Annually

Accessible.

Iso Kinetic Dust Sampling Portable analyser

For

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pose

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Emission Point Reference No. : A2-32 Scrubber



Inorganic Chlorides Quarterly

Accessible.

Adsorption onto tubes Laboratory

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Emission Point Reference No. : A2-40 Filter Dryer



VOCs Quarterly

Accessible.

Sample Probe Portable FID analyser

For

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Emission Point Reference No. : A2-41 Carbon Adsorber



VOCs

Quarterly

Accessible.

Sample Probe Portable FID analyser

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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : SW1, Slatty Creek (Stormwater discharge)



COD

Weekly

Accessible. Pipe ends <1m from river bank.

Grab sample.

HACH COD method ( Spectrophotometer).

pH

Weekly Accessible. Pipe ends <1m from river bank.

Grab sample. pH meter

Visual Inspection

Weekly Accessible. Pipe ends <1m from river bank.

Grab Sample Visual check

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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : SE1



BOD

Weekly Access to WWTP unrestricted

composite 5 day BOD

COD

Daily

Access to WWTP unrestricted

Composite

HACH - Spectrophotometer

Suspended Solids Daily Access to WWTP unrestricted

Composite

Standard Method Gravimetric

Sulphates

Monthly


Cmposite Standard Method -IC

Acrylates Monthly Access to WWTP unrestricted

Composite

HPLC

Total N (as N) Daily Access to WWTP unrestricted

Composite

HACH Test N’Tube Method

pH Daily Access to WWTP unrestricted

Composite

Flow Continuous


Online Meter

Temperature Continuous


Online Probe

Organic Solvents Quarterly


Composite Gas Chromatography

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Flow Bi-annual Accessible Grab Reverse Osmosis plant records

Temperature Bi-annual Accessible Grab Temperature probe pH Bi-annual Accessible Grab pH electrode COD

Bi-annual Accessible Grab HACH Spectrophotometer

Suspended Solids Bi-annual Accessible Grab Standard Method - Gravimetric

Sulphates

Bi-annual Accessible Grab Standard Method -IC

Chlorides

Bi-annual Accessible Grab Standard Method

Total Heavy metals Bi-annual Accessible Grab Atomic Absorption (GFAA)

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Sulphates


Chlorides



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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : SL1



Not monitored. Soakaway, no monitoring point.

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Sulphates


Chlorides



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Sulphates


Chlorides



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Sulphates


Chlorides



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Sulphates


Chlorides



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Sulphates


Chlorides



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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : SL2



Not monitored. Soakaway, no monitoring point.

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TABLE F.2(i) : EMISSIONS MONITORING AND SAMPLING POINTS ( 1 table per monitoring point) Emission Point Reference No. : N2



Sound Pressure level (dBA) at reference distance

Annually Accessible. Noisemeter Calibrated noisemeter

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TABLE F.2(ii): AMBIENT ENVIRONMENT MONITORING AND SAMPLING POINTS ( 1 table per monitoring point)

Monitoring Point Reference No : AGW1

Parameter Monitoring frequency Accessibility of Sampling point

Sampling method Analysis method / technique

pH (pH units) Yearly Accessible, ground level

Waterra Organic Sampling Tube

WTW portable pH meter

Conductivity (µS/cm) Yearly Accessible, ground level


WTW portable conductivity meter

NH3-N (mg/l) Yearly Accessible, ground level


G/67 Konelab

NO3-N (mg/l) Yearly Accessible, ground level


G/39:Based on APHA,1998,20th Edition,Method 4110B

Ortho-Phosphate (mg/l)

Yearly Accessible, ground level



Chloride (mg/l) Yearly Accessible, ground level



Flouride (mg/l) Yearly Accessible, ground level



Sulphate (mg/l) Yearly Accessible, ground level



Sodium (mg/l) Yearly Accessible, ground level


ICP-MS

Magnesium (mg/l) Yearly Accessible, ground level


ICP-MS

Potassium (mg/l) Yearly Accessible, ground level


ICP-MS

Calcium (mg/l) Yearly Accessible, ground level


ICP-MS

Methanol (mg/l) Yearly Accessible, ground level


G/14:Based on ASTM Method D3695

Ethanol (mg/l) Yearly Accessible, ground level



Acetone (mg/l) Yearly Accessible, ground Waterra Organic Sampling G/14:Based on ASTM Method

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level Tube D3695 Acetonitrile (mg/l) Yearly Accessible, ground

level Waterra Organic Sampling Tube


IPA (mg/l) Yearly Accessible, ground level



USEPA 524.2 (µg/l) Yearly Accessible, ground level


Headspace GC-MS

Mineral Oil Yearly Accessible, ground level


GC-MS

Beryllium Yearly Accessible, ground level


ICP-MS

Aluminium Yearly Accessible, ground level


ICP-MS

Chromium Yearly Accessible, ground level


ICP-MS

For

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Monitoring Point Reference No : AGW1 (contd)

Manganese Yearly Accessible, ground level


ICP-MS

Cobalt Yearly Accessible, ground level


ICP-MS

Nickel Yearly Accessible, ground level


ICP-MS

Copper Yearly Accessible, ground level


ICP-MS

Zinc Yearly Accessible, ground level


ICP-MS

Arsenic Yearly Accessible, ground level


ICP-MS

Selenium Yearly Accessible, ground level


ICP-MS

Silver Yearly Accessible, ground level


ICP-MS

Cadmium Yearly Accessible, ground level


ICP-MS

Tin Yearly Accessible, ground level


ICP-MS

Antimony Yearly Accessible, ground level


ICP-MS

Barium Yearly Accessible, ground level


ICP-MS

Lead Yearly Accessible, ground level


ICP-MS

Iron Yearly Accessible, ground level


ICP-MS

Boron Yearly Accessible, ground level


ICP-MS

Mercury Yearly Accessible, ground level


ICP-MS

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G/67 Konelab



















ICP-MS



ICP-MS



ICP-MS



ICP-MS







Acetone (mg/l) Yearly Accessible, ground level



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Acetonitrile (mg/l) Yearly Accessible, ground level








Headspace GC-MS



GC-MS



ICP-MS



ICP-MS



ICP-MS

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ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS

For

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G/67 Konelab



















ICP-MS



ICP-MS



ICP-MS



ICP-MS










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Headspace GC-MS



GC-MS



ICP-MS



ICP-MS



ICP-MS

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ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS

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G/67 Konelab



















ICP-MS



ICP-MS



ICP-MS



ICP-MS










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Headspace GC-MS



GC-MS



ICP-MS



ICP-MS



ICP-MS

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ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS

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G/67 Konelab



















ICP-MS



ICP-MS



ICP-MS



ICP-MS










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Headspace GC-MS



GC-MS



ICP-MS



ICP-MS



ICP-MS

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ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS



ICP-MS

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Monitoring Point Reference No : AN1



Noise Level

Yearly Accessible Bruel & Kjaer Sound Level Meter Type 2260

Calibrated Sound Level Meter

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Noise Level



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Noise Level



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Noise Level



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Noise Level



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Noise Level



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Noise Level



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Table G.1(i) Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Ref.

No or

Material/

Substance(1)

CAS

Number

Danger(2)

Category

Amount

Stored

Annual

Usage

Nature of Use R(3) - Phrase S(3) -

Phrase Code (tonnes) (tonnes)

A01 Acetic Acid 64-19-7 Flammable, Corrosive 0.01 >0.1 Laboratory op2 R:10-35 S:23-26-45

A02 Acetone 67-64-1 H. Flammable, Irritant 170 764 Production IC 2/OP2/ Highflow, MW2, J1,J2

R:11-36-66-67 S2-9-16-26

A04 Acetonitrile 75-05-08 H. Flammable, Toxic 0.04716 1.0218 Laboratory op2 R:11-23/24/25 S:16-27-45

A05 Air (including laser air) N/A 16 bottles

A07 AdjunctALK 1310-73-2 Corrosive 0.02 0.88 Boilers R:35 N/A

A12 Ammonia solution 32% extra pure

7664-41-7 Corrosive/Danger to Environment

0.002 0.012 Filtercutting R:34-50 S: 26-36/37/39-45-61

A14 Ammonium Persulphate 7727-54-0 Oxidiser, Irritant 0.05 0.06 Production IC 2/op2 R:8-20/21/22 S:17-26-27-36/37/39

A16 Aquamicron AKS 67-66-3 Highly Flammable, Toxic 0.0005 0.025 Laboratory op2 R22-38-40-48/20/22

S:36/37

A17 Aquamicron CXU 107-21-1 Irritant 0.001 0.006 Laboratory op2 R:10-23/24/25-39/23/24/25

N/A

A18 Argon 7440-37-1 Compressed Gas 2 btls 8 btls Maintenance

A27 Ambersil clear mould protective 68476-85-7 Extremely flammable 4.8 litres

A29 Arecal ULTRA 2000 74-98-6/106-97-8

Extremely flammable 3 N/A N/A

A38 AmertrolBCLA60SM N/A Corrosive 0.032 0.752 Boilers N/A N/A

A39 Amersite 2 7681-57-4 Harmful 1.1352 R:22-41-31 N/A

B03 Bioquase 17801 Corrosive, Toxic by ingestion

0.1 R:34-43, S:24/25-26- 28-36/37/39

B06 Butanol 71-36-3 Flammable,Harmful 25 76 Highflow, MW2,J1,J2 R: 10-22-37/38-41-67

S:16

B07 Butane gas 106-97-8 Extremely flammable 170

cannisters R:12

S:2-16-23-51

B11 Bio-Treat HD N/A N/A 1 R:36/38

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual

Usage Nature of Use R(3) - Phrase S(3) -


B12 Buffer solution PH 4.0 N/A 0.015 Laboratories N/A N/A

B13 Buffer solution PH 7.0 7732-18-5 0.015 Laboratories N/A N/A

B32 Bleach (for cleaners) 7681-52-9 0.005 0.06

C01 Cyrolite polyment 03708 N/A N/A 1 48.96 Millex 33 dept N/A N/A

C02 Carbaret Floor Polish N/A N/A 0.025 0.100 Cleaners NA NA

C03 Cellulose acetate CA-398-30 9004-35-7 0.5 5 Production hf

C06 COD Vials (0-150ppm/0-1500ppm/0-15000ppm)

N/A 0.001 1500 vials Laboratory R:49,R23/24/25,R33/R35

S13-26-28a-S45

C09 Cytochrome C C8266 9007-43-6 52 litres

C11 Chloroform 67-66-3 Toxic 0.00592 0.018 Laboratory R22-38-40 48/20/22

C15 Carbon Dioxide 00124-38-9 Non flammable, Non toxic gas, Asphxiant in high concentrations

20bottles 4 bottles Microlab incubator/ Fire suppression systems

S9, S23

C29 Copaslip (Lead Free ) N/A N/A 0.0108

C33 Cellfloc CE 190/C19/C180/C18 N/A Irritant 0.15 6 WWTP Plant R36,38 S24,25,36

C38 Celfoc A13 N/A Irritant 2 127 WWTP plant R36,38, 22 S24, 25, 36

C42

Cleaning agents for McDonalds, Klericide A, Klericide B, MP9 cleaner, Carefree Polish, Premstrip, Toilet descaler, carefree maintainer

N/A Irritants 0.107 1.878 Cleaning

D01 Detergent RBS 25 N/A Irritant 0.005 0.100 R36/38 S26,S28 S36/37/39

D06 Dimethyl acetamide 127-19-5 Harmful 90 208 Durapore / IC2 R:20/21 - R61 S:26-28-36

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual



D08 Dimethylformamide 68-12-2 Flammable, Harmful 0.002 0.030 Production op1 R:61-20/21-36 S:53-45

D09 DYCHEM Avalanche 1310-73-2 Corrosive 0.002 45 litres Production op2 R:35 S:26-27-37/39

D10 DYCHEM (Graffiti Remover) 108-94-1 Combustible 0.002 20 litres Production op2 R 10-20 S: 16-24/25

D11 DYCHEM Stainless Steel Cleaner

N/A Not Combustible 0.002 0.0185 Production op2

D12 di-Potassium hydrogen phosphate anhydrous extra pure Ph

'7758-11-4 0.005 0.010 Chemistry Lab.

D14 Dodecylbenzene-sulfonic acid sodium

25155-30-0 Harmful 0.2 0.3 R: 22, 37/38, 41 S: 26,27, 36/37/39

D15 Digestion Solution for COD 0-150ppm

N/A Toxic, Corrosive 0.001 0.005 Laboratory R 23/24/25, 35, 33

D25 Dimethyl Sulfoxide Chromalsolv for HPLC

7631-90-5 Combustible, Harmful, Irritant

0.00825 0.00825

D26 Defoam S10 N/A Slightly Irritating 0.15 1 WWTP R36,38 S24,25,36

E13 Ethanol 64-17-5 H. Flammable 25 125.5 Highflow, J1,J2, MW2 R: 11 S: 7-16

E20 Ethyl Acetate 141-78-6 Highly Flammable (Irritant)

0.0072 0.018 R11, 36, 66, 67 S16,26,33

E23 Elgalite RU3 5949-29-1 Irritant to Eyes 0.1 6 R36 S24, S25

E24 Elgalite RF 11 1310-73-2 Corrosive 0.1 6 R35, S22, S26, S37/39, S45

F06 Floor cleaner N/A N/A 0.1 0.832 S:2-26-46

F07 Fluroscein sodium 518-47-8 N/A 0.001 0.0052 S22, 24/25

F08 Food grade anti seize grease 0.001 0.0088

G02 Glycerol 56-81-5 Irritant 0.2 0.5 Highflow/ J1/J2 R36/38 S26,36

G10 LPG Gas 106-97-8 Extremely Flammable 7 bottles

G14 Calibration gas for VOC meter HSE

N/A 0.002 0.008

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Ref. No or

Material/ Substance(1)

CAS Number

Danger(2) Category

Amount Stored

Annual Usage

Nature of Use R(3) - Phrase S(3) - Phrase

Code (tonnes) (tonnes)

H01 HDS 10 N/A Not Classified 0.01 1500 bottles

Hand Soap N/A N/A

H04 Hydroquase 21219 N/A 0.2 S26,36/37/39

H05 Hydrochloric Acid 7647-01-0 Corrosive 0.012 0.01 Laboratory R 23, 35 S9, 26, 36/37/39, 45

H06 Hydrochloric Acid 0.1 M 7647-01-0 Corrosive 0.0047 0.007 Laboratory R 23, 35 S9, 26, 36/37/39, 45

H10 Hydrogen 1333-74-0 Extremely Flammable 0.0084 0.0168 LEL instruments R:12 S:9-16-33

H11 Hydrogen Peroxide (30%)(35%)

7722-84-1 Oxidiser, Corrosive 0.005 0.01 Laboratory R:34 S3-28-36/39-45

H12

Hydroxy propyl Acrylate

25584-83-2

Combustible, Toxic

1

20

Production IC2/OP2

R:23/24/25-34-43

S:26-36/39-45

H13 Hydroxy propyl acrylate 95% mixture of isomers

999-61-1 Combustible, Toxic 0.025 0.1044 R 26/27/28,34,43

S 36/37/39,45

H16 Hydranal composolver N/A Highly flammable(Toxic)

0.011 0.208 R 23, 22, 34 S16, 45, 36/37/39

H17 Hydroquase 20202/21219 7631-90-5 (Toxic by inhalation) 0.05 0.2 R49, S38,23

H21 HT-MAB SE 1505/1612 (YELLOW)

N/A 0.005 0.005 Moulding

H22 HT-MAB SE 5747 (BLUE) N/A 0.005 0.01 Moulding

H23 HT-MAB SE 6544 (GREEN) N/A 0.005 0.005 Moulding

H24 HT-MAB SE 9686 (GREY) N/A 0.005 0.005 Moulding

H32 HT-MAB SE 6638 (grey) N/A 0.005 0.005 Moulding

H33 HTMAB SE 4421 ( Blue) N/A 0.005 0.005 Moulding

H34 HT MAB SE 3543 (Red) N/A 0.005 0.005 Moulding

I03 Imaje 5110 or 7110 78-93-3 Highly Flammable, Irritant

0.020 0.01 Production op3 R11 R36/37 S9,S16,S25,S33

I04 Isopropanol 67-63-0 Highly Flammable 1 8.78 Millex R11 R36/37 S7 S16 S24 S25 S26

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual



I05 Ionic Strength Adjustor for ion selective electrodes

7631-99-4 0.00786 Laboratories

I06 Irgacure 2959 106797-53-9 Dangerous to the environment

0.05 2 Durapore / IC2 R 51.53 S 61

I07 Imaje 5191 or 6191 ketone additive

78-93-3 Highly flammable, Irritant

0.025 0.1 Assembly R 11, 36/37 S9,16,25,33

I08 Imaje 5506 78-93-3 Highly Flammable (Irritant)

0.025 0.2 Assembly R11,36,66,67 S9,16

I09 Imaje 7510 78-93-3 Highly Flammable (Irritant)

0.025 0.2 Assembly R11,36,66,67 S9,16

I10 IC-270BK Printing Ink 78-93-3 Highly flammable, Irritant

0.00108 0.0108 Assembly R11,36/37 S16,33,7/9,24/25

K02 Klericide 70/30 Cleaning Spray 64-17-5 Flammable 0.01 0.5785 Production IC2/OP1 + OP2

K03 Klericide CR - Klercide B - N/A Irritant 0.16 0.65 R:36/37/38

K04 Kynar (R) 460-PLT PVDF 24937-79-9 3 303.6 Durapore / IC2

K06 Kynar (R) 741A PWD PVDF 24937-79-9 3 92 Duerapore /IC2

K07 Kymene® 2064 Wet- Strength Resin

96-23-1 0.400 3.7 Durapore / IC2

K08 Kemira Thinner 1006 Flammable (Harmful, Irritant)

0.0025 0.01 R20/21, R65, R 38

S 36/37, S43b

K11 Klercide 5 N/A 0.001 0.025 Assembly

K12 Klercide CR A +B 68391-01-5 N/A 0.001 0.05 Assembly

L05 Loctite Food grade grease (8105)

N/A N/A 0.001 0.005

L06 Lexan Yellow Part No: 4506537 N/A N/A 0.001 0.005 Moulding

L07 Lexan Green Part No: 4506538 111211-39-3 N/A 0.001 0.005 Moulding

L08 Lexan Clear Part No: 4506539 111211-39-3 N/A 0.001 0.005 Moulding

L09 Lexan Blue Part No: 4506540 N/A N/A 0.001 0.006 Moulding

L18 Loctite 3211 N/A Irritant 0.009 0.036 R36/37/38,R43 S26,28

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Table G.1(i) Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual



L25 Leak Detector Spray 1336-21-6 0.0055 0.0055 Maintenance S2, S23

M01 Melinex 53038-59-9 Combustible 3 600 NA NA

M04 Methanol 67-56-1 Highly Flammable, Toxic

285 1860.86 Production IC 2/op2 R:11-23/24/25-39/23/24/25

S1/2-7-16-36/37-45

M05 Methyl Acetate 79-20-9 Highly Flammable 0.002 0.005 Laboratory R:11-36-66-67 S:2-16-26-29-33

M06 Methyl Ethyl Ketone (+MEK/Cyclohexanone mix 70/30)

78-93-3 Highly Flammable, Irritant

0.040 350 litres Assembly R: 11-36/37 S:9-16-25-33

M17 Moulding dye Blue P11595 N/A 0.01 0.01 Moulding

M18 Moulding dyeYellow P13093 N/A N/A 0.005 0.005 Moulding

M19 Moulding dye flash light grey K51338

N/A N/A 0.005 0.005 Moulding N/A N/A

M20 Moulding dye flash blue PR00083

N/A N/A 0.005 0.005 Moulding N/A N/A

M21 Moulding dyeGreen P13095 N/A N/A 0.005 0.005 Moulding

N01 Nitric Acid (fuming) 7697-37-2 Oxidising, Toxic 0.011 1.1162 Laboratory R8,35 S 23,26,36,45

N02 Nitrogen 7727-37-9 25 300 S:38

N03 Nitrocellulose Membrane(without backing)

9004-70-0 Fire Hazard 2 8 Highflow/ J1/J2/MW2 R: 11 S: 2-16-33-37/39

N04 Nitrocellulose 009004-70-0 Highly Flammable 5 320 Highflow/ J1/J2/MW2 R: 11 S: 2-16-33-37/39

N05 NUTO H Hydraulic Oils ISO VG 5 to 150

N/A 0.5 2600 L Moulding S23-25

N13 N-Methyl-2-pyrrolidone 872-50-4 Irritant 93 300 IC2 R: 36/38 S: 2-41 N17 NaCl 0.85% Ref 20030 N/A 0.025 0.2 Durapore N23 NP8096 N/A Corrosive 1 7 WWTP R35, R41, S24, 25, 36, N25 Nitrous oxide 10024-97-2 oxidising 2 6 cylinders S24, S

O01 Ortho Phosphoric Acid 7664-38-2 Corrosive 0.01 0.08425 Effluent R:34,36/38 S:26,36/37/39-45

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No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual



O03 Oxygen 7782-44-7 25 500 Effluent plant

P 01 Paramethoxy Phenol 150-76-5 Combustible, Harmful/Irritant

0.02 0.008 Production IC2/Casting VMF4

R:22,36/38 S22,37/39

P02 Peracetic Acid 15% 79-21-0 Oxidising, Combustible, Corrosive

0.001 0.001 Laboratory R7-20/21/22-35

P04 Phosphate Buffered Saline 7647-14-5 Irritant 0.01 0.5 R36/67/68 S26,36

P06 Poly (ethylene glycol) 25322-68-3 Flammable 0.005 0.025

P09 Polypropylene resin 4510601 9003-07-0 Combustible 2 30

P19 Premacut Cutting Fluid N/A 0.05 0.2

P20 Premstrip 90 N/A corrosive 0.010 0.040

P21 Pronatur Engineering Grease with PTFE

N/A Flammable 0.006

P22 Pronatur Maintenance Lubricant

N/A Flammable 0.01 0.05

P24 Propanol 71-23-8 0.010 13.25 R:11 S:7-16

P26 IR-270BK Printing Ink 78-93-3 HIghly Flammable 0.02 0.26

R: 11- 36- 66 - 67

S:16, 33, 7/9, 24/25

P29 Ponceau S Electran N/A 0.005 0.02

P30 Propane gas 00074-98-6 Compressed gas 0.2 0.2

P31 Polyethlylene high density Part no: 14351

9002-88-4 2 60 Moulding

P35 Peptone water (buffered) for microbiology

N/A 0.006 0.048 Microbiology Lab

P45 P880 7654-32-2 (Corrosive) 1 7 R34 S26

P34 PVC compound - Geon/Vinakon PR01059

N/A N/A 2 75

R01 Rocol Moisture Guard Spray 68476-85-7 Extremely Flammable 0.001 0.010 Maintenance R12 S16,23,2,51

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No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual



R02 Rocol Leak Detector Spray 000124-38-9 0.00072 0.036 Maintenance

R03 Rocol Chain and drive spray 000124-38-9 Flammable, Dangerous to the environment

0.0006 0.03 Maintenance R10, 51/53, 65 S16.51.2

R04 Rocol RTD liquid N/A 0.00093 0.046 Maintenance

R05 Rocol Foliac Super Red pipe jointing compound

0067-63-0 Highly flammable 0.0018 0.018 Maintenance R 11,20/22 S 7,16,33,51,23,24,2

R06 Rocol Anti-seize compound J166

N/A 0.001 0.024 Maintenance

R07 Rocol RTD compound N/A 0.001 0.024 Maintenance

S04 Sodium Chloride 7647-14-5 Irritant 0.015 25.68 Laboratory R 36/37/38 S 26, 36

S05 Sodium Hydroxide 30% 1310-73-2 Corrosive 4 148.37 Effluent R 35, S 1/2-26-37/39-45

S06 Sodium Hypochlorite 7681-52-9 Strong oxidising agent, Corrosive

0.01 0.300 Facilities R:31, 34 S:2, 28

S08 Sodium Persulphate 7775-27-1 Oxidiser, Harmful 0.010 0.0100 Effluent R8, 22, 42/4336/37/38

S:17,22,24,37,43

S13 Sulphuric Acid 7664-93-9 Toxic 0.023 0.7262 Laboratory R 35, S 26,30,45

S16 Silver Nitrate 7761-88-8 Oxidising, Corrosive

0.0087 0.026

S17 Shell Omala Oil N/A 0.025 0.025 Maintenance

S18 Shell Tellus Oil N/A 0.025 0.025

S19 Shell Polypropylene PMT 6100 9010-79-1 3 70 Moulding

S20 Silite RTV Silicone 17689779 Irritant 0.0041

S33 Sartomer 28961-43-5 Corrosive 0.025 0.015 R34, S:26,28,27,36/37/39

T01 Tampa Ink 180-E 1330-20-7 Flammable, Harmful 0.020 0.080 R20,21 S7/9,16,29

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No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual



T02 Tampa Ink 3356-Maraprop pp 64742-95-6 Highly Flammable 0.006 0.020 R10 S20/21,29.51

T04 Tampa Solvent (38279) N/A Flammable 0.010 0.005 R10 S7/9,16,29

T05 Tampa TPV Thinner 64742-95-6 Flammable, Irritant 0.007 0.010 R10,41 S20/21,25,26,29,51

T08 Teresso Oils ISO VG 32 to 460 N/A 0.050 0.15 Moulding S24

T09 Tetra ethylene glycol diacrylate

17831-71-9 Combustible, Corrosive 0.4 8.8 R34, S:26,28,27,36/37/39

T12 Trichloromethyl silane 75-79-6 HighlyFlammable/Reacts violently with water, Harmful

0.005 0.03175 Filtercutting R:11-14-36/37/38

S: 26-39

T14 Trizma Pre-set PH 7.5 N/A Irritant 0.005 0.05 Laboratory

T15 Tris Buffered Saline with BSA N/A Irritant 0.005 0.05 Laboratory R36/37/38, S26, 36

T16 Tris Buffered Saline PH 8.0 N/A Irritant 0.005 0.05 Laboratory R36/37/38, S26, 36

T21 Tyril867E Styrene Acrolyonitrile resin 01784

N/A N/A 2 75 Moulding N/A N/A

T30 Tween 20 N/A 0.01 0.01 Microlab

T36 Tampa Ink - Type B printing ink Sorte TP 218

112-07-2 Harmful 0.03 0.12 Assembly R10,40,43,20/21,36/38

S20/21,51,37,26

X01 Xylene 1330-20-7 Flammable, Irritant 0.00174 0.00435 R:10-20/21-38

W01 WL -200 Wash 78-93-3 Highly Flammable, Irritant

12 litres R:11, 36/37 S:16,33,7/9,24/25

W03 WD-40 64742-82-1 Flammable 100/year

W04 White spirit N/A flammable 0.06

T31 Triethylene glycol for synthesis 112-27-6 N/A 90 180 IC2 Casting S24/25

RADEL A 100-700 Natural Polyethersulfone

1 150 IC2 Mixroom

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No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual



N,N’-Methylenebisacrylamide 110-26-9 Harmful 0.4 10 IC2 Modification R20/22 S22

H40 Hexylene Glycol 107-41-5 Irritant .0.4 10 IC2 Modification R36/38

Plasdone C-30 9003-39-8 May form explosive dust-air mixture

0.05 0.2 J1

Savinyl Black RLSN New Chromium (III) Compound CRCMPD

Toxic 0.05 0.2 J1

Heliogen Green K 9360 14302-13-7 0.05 0.2 J1 Heliogen Green K 8730 1328-53-5 N/A 0.05 0.2 J1 N/A N/A

NEW 3-APTS

NEW Acetic Anhydride 108-24-7 Harmful, Corrosive R10, 20, 22, 34 S26, 36, 37, 39, 45

NEW Benzyl Alcohol 100-51-6 Harmful R20/22 S26

NEW DMSO 67-68-5 N/A 36.517 R36/37/38 S26, 36, 23

NEW Ethanolamine 14-43-5 Harmful, Corrosive R20/21/22, 34 S26, 27, 36, 37, 39, 45

NEW 3-GPTS 2530-83-8 Harmful 0.8 R21, 36/38 S26, 28

NEW Glycine 56-40-6 N/A 0.2558

NEW Hydrochloric Acid BP Grade 7647-01-0 Corrosive 0.0909 R23, 24, 25, 34, 36, 37, 38

S26, 36, 37, 39, 45

NEW Iminodiacetic acid 14-73-4 Irritant R36/37/38 S24/25

NEW CPG, 1000 Angstrom, 74 – 125 UM (CPG1000BL)



NEW L-Lysine 56-87-1 N/A N/A N/A

NEW 2-Mercaptoethanol 60-24-2 Toxic R23, 24, 25, 37, S26, 36, 37,

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual


Phrase 38, 41 39, 45, 53

NEW Ninhydrin 485-47-2 Harmful R22, 36, 37, 38 S26, 28, 36

NEW Nitric Acid 7697-37-2 Toxic, Corrosive, oxidizing

R35 S23, 26, 36, 45

NEW PEG 20000 25322-68-3 N/A

NEW rProtein A

NEW Sodium Bicarbonate 144-5-8 N/A 1.5725

NEW Di-Sodium Hydrogen PO4 7558-79-4 N/A R36, 37, 38 S26, 36

NEW Sodium Acetate 127-09-3 N/A 0.2572 S24/25

NEW Sodium Borohydride 16940-66-2 Toxic, Corrosive 0.0449 R15, 24, 25, 34 S22, 26, 36, 37, 39, 43, 45

NEW Sodium Metaperiodate 7790-28-5 Harmful 0.39 R8, 20, 22, 36, 37, 38

S17, 26, 36

NEW Sodium Azide 26628-22-8 Toxic, dangerous for the environment

R21, 26, 28, 32, 50, 53

S1, 2, 28, 45, 60, 61

NEW Sodium Hydroxide pellets 497-19-8 Harmful, Corrosive R35 S26, 37/39, 45

NEW Trimethylamine 75-50-3 Highly flammable, Harmful, Corrosive

R11, 20, 21, 22, 35

S3, 16, 26, 29, 36, 37, 39, 45

NEW Vinyl Sulphone 3680-02-2 Harmful R21, 22

NEW Sodium Phosphate 7601-54-9 Corrosive R36, 37, 38 S26, 36

NEW Acros Acetic Acid

NEW Absolute Ethanol 64-17-5 Highly flammable, Harmful

R11, 20, 21, 22, 36, 37, 38, 40

S7, 16, 24, 25, 36, 37, 39, 45

NEW Sodium Cyanoborohydride 25895-60-7

Toxic, Highly flammable, Dangerous for the environment, Corrosive

0.0505 R11, 15, 16, 26/27/28, 32, 34, 50/53

S1, 8, 26, 28A, 36/37/38, 43, 45, 50A, 60, 61

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual


Phrase

NEW MES, free acid monohydrate 4432-31-9 N/A


NEW Silica Gel 112926-00-8 S22, 36, 37, 45, 53


NEW Octadecyldimethylchlorosilane

NEW Phenyldimethylchlorosilane

NEW Sodium Lauryl Sulphate 151-21-3 Harmful R10, 20, 21, 22, 36, 37, 38

S26, 36, 37

NEW Ammonium Acetate 631-31-8 N/A R36, 37, 38 S26, 36

NEW nProtein A – 10g


New Snake Venom

NEW 1-(3-Dimethylaminopropylethylcarbimide)

25952-53-8 N/A

NEW Buffer solution pH4



NEW Crystal Violet 548-32-9 Harmful, Dangerous for the environment

R22, 40, 41, 50, 53

S26, 36, 37, 39, 46, 60, 61

NEW Hexamethylenediamine 124-09-4 Harmful, Corrosive R21/22, 34 S22, 26, 36/37/38, 45

NEW Toluene 108-88-3 Highly flammable, Toxic 0.263 R11, 20 S16, 25, 29, 33

NEW Periodic Acid 10450-60-9 Oxidizing, Toxic, Corrosive

R23, 24, 25, 34, 41

NEW 5’-O-DMT-2’dt-3’-O-succinate

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual


Phrase

NEW p-Toluenesulphonic Acid Monohydrate

6192-52-5 N/A R36, 37, 38 S22, 26, 36/37/38, 45

NEW N,N-Dimethylformamide 68-12-2 Harmful R20, 21, 36, 61 S45, 53

NEW vProtein-A (Lonza)

NEW Perchloric Acid 7601-90-3 Oxidising, Harmful, Corrosive

R35, 5, 8 S23, 26, 36, 45

NEW Sodium Thiosulphate Pentahydrate

10102-17-7 N/A

NEW Cresol Red 1733-12-6 N/A

NEW Recombinant Staphlococcal Protein A

NEW Human Immunoglobulin G NONE N/A

NEW Nu Page 4-12% Bis Tris Gel – pk10

NEW Nu Page MOPS SDS Running Buffer

NEW Novex Marker (12 Molecular Weight)

NEW Nu Page LDS Sample Buffer

NEW PAGE Blue G-90

NEW Di-Potassium Hydrogen 7758-11-4 N/A R36, 37, 38 S22, 24, 25

NEW Coomassie Blue 78642-64-5 N/A R36, 37, 38 S26, 36

NEW Sodium Dihydrogen Phosphate 7558-80-7 N/A R36, 37, 38 S26, 36

NEW Sucrose 57-50-1 N/A

NEW Trifluoroacetic Acid 76-05-1 Toxic, Corrosive, Dangerous for the environment

R23, 24, 25, 35, 52, 53

S9, 26, 27, 28, 45, 61

NEW Ammonium Sulphate 7783-20-2 N/A

NEW Ammonium Chloride 12125-02-9 Harmful R22, 36 S22

NEW BCA Assay kit N/A

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual


Phrase

NEW Barium Hydroxide 17194-00-2 Harmful, Corrosive R20/22, R34 S26, 36/37/39, 45

NEW Copper Sulphate 7758-99-8 Harmful, Dangerous for the environment

R22, 36, 38, 50, 53

S22, 60, 61

NEW Dimethylglyoxime 95-45-4 Harmful R22

NEW EDTA Disodium salt 6381-92-6 Harmful R22, 36, 37, 38 S26, 36

NEW HEPES 7365-45-9 N/A R36/37/38 S26, 37/39

NEW Iron II Sulphate Heptahydrate 7782-63-0 Harmful R22, 36/37/38 S26, 36, 37, 39

NEW Nickel II Sulphate 1010-97-0 Toxic R22, 40, 43 S22, 36/37

NEW Oxalic Acid Dihydrate ACS 6153-56-6 Corrosive, Harmful R20, 21, 22, 34 S24, 25

NEW PBS (Dulbecco) Tablets NONE N/A

NEW Potassium Carbonate 584-08-7 Harmful R22, 36, 37, 38

NEW Potassium Iodide 7681-11-0 N/A R36, 38, 42, 43, 61

S26, 36, 37, 39, 45

NEW Potassium Antiminate 29638-69-5 N/A

NEW Starch Soluble 9005-84-9 N/A

NEW Sodium Thioshate

NEW TRIS 77-86-1 N/A R36, 37, 38 S26, 36

NEW L-Tartaric Acid 87-69-4 N/A R36/37/38 S26, 37/39

NEW Trichloric Acid 76-03-9 Toxic, Dangerous for the environment, Corrosive

R35, 50/53 S26, 36/37/39, 45, 60, 61

NEW Enterooxin Assay Kit ABCDE

NEW Acetonitrile (HPLC Grade) 2206-26-0 Harmful R11, 23, 24, 25 S16, 27, 44, 45

NEW Agarose 9012-36-6 N/A R36

NEW Azocasein

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual


Phrase

NEW Citric Acid Monohydrate 5949-29-1 N/A R36/37/38 S26, 37/39

NEW Polyethylene Glycol 25322-68-3 N/A 0.1685

NEW Potassium Chloride 7447-40-7 N/A R36 S22, 24, 25, 26, 36

NEW Potassium Dihydrogen Phosphate

7778-77-0 N/A R36, 37, 38 S22, 24, 25

NEW Sodium Carbonate 497-19-8 N/A R36 S22, 26

NEW Protein A ELISA Test Kit for samples containing hlgG – EA (OEM Concepts CO-Z51)

NEW 1413 uS/cm Conductivity Buffer

NEW 12.88 uS/cm Conductivity Buffer

NEW pH10 Buffer

NEW Sodium Thiosulphate 7772-98-7 N/A

NEW Acetic Acid, glacial, ACS 99.7+%

54-19-7 Corrosive R10, 35 S23, 26, 35

NEW Ammonium Hydrogenfluoride 1341-49-7 Toxic, Corrosive R23, 24, 28, 35

NEW Ammonium Hydroxide 1336-21-6 Corrosive, Dangerous for the environment

R20, 21, 22, 34, 36/37/38, 41, 50

S26, 36, 37, 39, 45, 61

NEW 1, 2-Bis(triethoxysilyl)-ethane 16068-37-4

NEW Boric Acid 10043-35-3 N/A S22, 26, 36, 37, 38, 45

NEW Boron Nitride, powder 1 micron

10043-11-5 N/A R36, 37 S26, 36

NEW Bromothymol Blue, Sodium Salt

34722-90-2 N/A

NEW Ethanol denatured, reagent grade

67-17-5 Highly Flammable R11 S7, 16

NEW Gelatin from porcene skin 9000-70-8

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual


Phrase

NEW Heptane, anhydrous 142-82-5 Highly flammable, Dangerous for the environment, Harmful

R9, 11, 20, 22 S9, 16, 23, 29, 33

NEW Hydrofluoric Acid 7664-39-3 Very Toxic, Corrosive R26, 27, 28, 35 S26, 28, 36, 37, 39, 45

NEW Methyl Red 493-52-7 Harmful R20, 21, 22, 36, 37, 38, 40

S22, 36

NEW Mercury 7439-97-6 Toxic R23, 33 S7, 45

NEW Nickel powder 7440-02-0 Toxic, highly flammable R10, 17, 36, 37, 38, 40, 42, 43

S16, 22, 26, 36

NEW Nyacol – Zirconium Oxide 1314-23-4 N/A R36, 37, 38

NEW Nyacol – Zinc Oxide N/A R22, 50/53 S61

NEW Nyacol CE02

NEW Polyacrylic Acid 9003-01-4 N/A S24/25

NEW Polyethylene oxide 25322-68-3 Harmful R20, 36, 37 S22, 26, 36

NEW Poly(sodium 4-styrene sulfonate)

25704-18-1

NEW Silicon Oxide 7631-86-9 R20

NEW Sodium Ethoxide 141-52-6 Highly flammable, Harmful, Corrosive

R11, 14, 20, 21, 22, 34

S18, 16, 26, 27, 36, 37, 39, 43, 45

NEW Tert Amyl Alcohol 75-85-4 Highly flammable, Harmful

R11, 20, 21

NEW Tetrabutyl Orthosilicate 4766-57-8

NEW Tetraethoxysilane 78-10-4 Harmful R10, 20, 36, 37 S24, 25

NEW Tetra-n-propoxysilane 682-01-9 Irritant R36/37/38

NEW Triethylamine 121-44-8 Highly flammable, Harmful, Corrosive

0.0043 R11, 20, 21, 22, 35

S3, 16, 26, 39, 36, 37, 39, 45

NEW Trimethyl borate 121-43-7 Harmful R10, 21 S23, 25

NEW Trimethylpentane 540-84-1 Highly Flammable, Harmful, Dangerous for

R11, 20, 22, 36, 37, 38, 50, 53,

S16, 26, 33, 36, 37, 39

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Ref.

No or Material/

Substance(1) CAS

Number Danger(2)

Category Amount

Stored Annual


Phrase the environment 65, 67

NEW Tween 20 9005-64-5 N/A S24/25

NEW Zinc Acetic Dihydrate 5970-45-6 N/A R36/37/38

NEW Zirconium (IV) acetyl-acetonate

17501-44-9

NEW Zirconium (IV) Butoxide 1071-76-7

NEW Dichloromethane 75-09-2 Harmful 0.2416 R20, 22, 40 S23, 24, 25, 36, 37

NEW Benzyl Acetate 140-11-4 Irritant 0.3245 R36/37/38 S26, 37/39

NEW Glacial Acetic Acid 64-19-7 Corrosive , Flammable 5000 10000 Additive to Durapore process

R10/35 S23/26/45

Notes: 1. In cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance.

2. c.f. Article 2(2) of SI No 77/94 3. c.f. Schedules 2 and 3 of SI No 77/

Notes: 1. In cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. 2. c.f. Article 2(2) of SI No 77/94

3. c.f. Schedules 9 and 10 of SI No 62/2004

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Table G.1(ii) Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Ref. No or

Material/

TA Luft Class 1,

Odour EU Lists I and II (Tick and specify Group/Family Number)

Code Substance(1) 2 or 3 Odourous

Yes/No

Description

Threshold

Dangerous Substances Directive

76/464/EEC

Groundwater Directive 80/68/EEC

µg/m3 List I List II +1294

List I List II

A01 Acetic Acid N/A Yes Pungent 4988

A02 Acetone 3 Yes Pungent 723300 A04 Acetonitrile N/A Yes Pungent N/A

A05 Air (including laser air) N/A No

A07 AdjunctALK N/A No

A12 Ammonia N/A Yes Pungent 12055 √ √

A14 Ammonium Persulphate N/A No Odourless N/A

A16 Aquamicron AKS N/A Yes Pungent N/A

A17 Aquamicron CXU N/A Yes Pungent N/A

A18 Argon N/A No Odourless N/A

A27 Ambersil clear mould protective

N/A No

A29 Arecal ULTRA 2000 N/A Yes Characteristic

A38 AmertrolBCLA60SM N/A Yes Weak - slight

A39 Amersite2 N/A Yes Sulphur Oxides ~ 1663

B03 Bioquase 17801 Yes Pungent

B06 Butanol 3 Yes Alcohol 15380000

B07 Butane gas Yes hydrocarbon

B11 Bio-Treat HD Yes Natural

B12 Buffer solution PH 4.0 No

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Ref.

No or

Material/ TA Luft

Class 1, Odour EU Lists I and II

(Tick and specify Group/Family Number)


Yes/No

Description

Threshold


76/464/EEC



List I List II

B13 Buffer solution PH 7.0 No

B32 Bleach (for cleaners) Yes Chlorine-like

C01 Cryolite polyment 03708

C02 Carbaret Floor Polish N/A Yes Sweet N/A

C03 Cellulose acetate CA-398-30

N/A No

C06 COD Vials (0-150ppm/0-1500ppm/0-15000ppm)

N/A No

C09 Cytochrome C C8266

C11 Chloroform Yes Characteristic 1484100

C15 Carbon Dioxide

C29 Copaslip (Lead Free)

C33 Cellfloc CE 190/C19/C180/C18

C38 Celfloc A13

C42 Cleaning agents for McDonalds, Klericide A, Klericide B, MP9 cleaner, Carefree Polish, Premstrip, Toilet descaler, carefree maintainer

No

D01 Detergent RBS 25 NA No

D06 Dimethyl acetamide N/A No

D08 Dimethylformamide 5 Weak Amine Like 303500

D09 DYCHEM Avalanche N/A No

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Ref.

No or

Material/ TA Luft




Yes/No

Description

Threshold


76/464/EEC



List I List II

D10 DYCHEM (Graffiti Remover)

N/A No

D11 DYCHEM Stainless Steel Cleaner

N/A No

D12 Potassium Hydrogen Ortho phosphate

N/A No √ √

D14 Dodecylbenzene-sulfonic acid sodium

No

D15 Digestion Solution for COD 0-150 ppm

D26 Defoam S10

E13 Ethanol 3 Yes Alcohol 11472000

E20 Ethyl Acetate Yes Fruity odor. 182900

E23 Elgalite RU3 No

E24 Elgalite RF 11 No

F06 Floor Cleaner Yes Pine N/A

F07 Fluroscein sodium

F08 Food grade anti seize grease

G02 Glycerol

G10 LPG Gas

G14 Calibration gas for VOC meter HSE

No

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Table G.1(ii) Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site Ref.

No or

Material/ TA Luft




Yes/No

Description

Threshold


76/464/EEC



List I List II

H01 HDS 10 N/A No

H04 Hydroquase 21219

H05 Hydrochloric Acid N/A Yes Pungent 7501.3

H06 Hydrochloric Acid 0.1M Yes Pungent 7435

H10 Hydrogen N/A

H11 Hydrogen Peroxide N/A No

H12 Hydroxy propyl acrylate – same thing as H13 same pocket in folder

N/A Faint Acrylic N/A

H13 Hydroxy propyl acrylate 95% mixture of isomers

H16 Hydranal composolver

H17 Hydroquase 20202/21219 Yes Slight odour

H21 HT-MAB SE 1505/1612 (YELLOW)

H22 HT-MAB SE 5747 (BLUE)

H23 HT-MAB SE 6544 (GREEN)

H24 HT-MAB SE 9686 (GREY)

H32 HT-MAB SE 6638 (grey)

H33 HTMAB SE 4421 ( Blue)

H34 HT MAB SE 3543 (Red)

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Ref. No or

Material/

TA Luft Class 1,


Code Substance(1) 2 or 3 Odourou

s Yes/No

Description

Threshold


76/464/EEC



List I List II

I03 Imaje 5110 or 7110 N/A Yes Strong Characteristic N/A

I04 Isopropanol 60% solution 3 Yes Alcohol 149640

I06 Irgacure 2959 Yes Faint undefined

I07 Imaje 5191 or 6191 ketone additive

Yes Strong

I08 Imaje 5506 Yes Sweet

I09 Imaje 7510 Yes Sweet

I10 IC-270BK Printing Ink Yes Ketonic

K02 Klercide 70/30 Cleaning Spray

N/A Yes Alcohol N/A

K03 Klericide CR – Klericide B Yes Characteristic

K04 Kynar ® 460-PLT PVDF

K06 Kynar ® 741A PWD PVDF

K07 Kymene No

K08 Kemira Thinner 1006 K11 Klericide 5 Yes Slight Chlorine K12 Klericide CR A+B Barely perceptible L05 Loctite Food grade grease

(8105) No

L06 Lexan Yellow Part No: 4506537

No Slight or no odour

L07 Lexan Green part No: 4506538

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Ref. No or

Material/

TA Luft Class 1,



s Yes/No

Description

Threshold


76/464/EEC



List I List II

L08 Lexan Clear Part No: 4506539

L09 Lexan Blue Part No: 4506540

L18 Loctite 495

L25 Leak Detectot Spray Yes Ammonia

M01 Melinex

M04 Methanol 3 Yes Alcohol 7980000

M05 Methyl Acetate 2 Yes Pungent 615200

M06 Methyl Ethyl Ketone N/A Yes Sweet Solvent 89790

M17 Moulding dye Blue P11595

M18 Moulding dye Yellow P13093

M19 Moulding dye flash light grey K51338

No

M20 Moulding dye flash blue PR00083

No

M21 Moulding dye Green P13095

No

N01 Nitric Acid (fuming) N/A Yes Pungent N/A

N02 Nitrogen N/A No

N03 Nitrocellulose Membrane N/A No

N04 Nitrocellulose N/A Yes Alcohol N/A

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Ref. No or

Material/

TA Luft Class 1,



s Yes/No

Description

Threshold


76/464/EEC



List I List II

N05

NUTO H Hydraulic Oils ISO VG 5 to 150

N/A Yes Oil N/A

N 13 n-methyl-2-pyrrolidone 3 yes Mild amine odour N/A

N17 NaCl 0.85% ref 20030

N23 NP8096

N25 Nitrous Oxide Yes Slightly sweet

O01 Ortho Phosphoric Acid N/A Yes Pungent N/A

O03 Oxygen

P01 Paramethoxy Phenol 1 (phenols)

No Sharp N/A

P02 Peracetic Acid 15% N/A Yes Pungent N/A

P04 Phosphate Buffered Saline

P06 Poly (ethylene glycol)

P07 Polyproplene compound black conductive PF 1053

P08 Polyoxyethlenesorbitan monolaurate

N/A

P09 Polypropylene resin N/A N/A N/A

P19 Premacut Cutting Fluid

P20 Premstrip 90 N/A N/A

P21 Pronatur Engineering grease with PTFE

Sharp mint like

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Ref. No or

Material/

TA Luft Class 1,

Odour

EU Lists I and II (Tick and specify Group/Family Number)


Yes/No

Description

Threshold


76/464/EEC



List I List II

P22 Pronatur maintenance Lubricant

P24 Propanol 3 Yes Alcoholic 149640

P26 IR-270BK Printing Ink Yes Sharp mint-like

P29 Ponceau S Electran

P30 Propoane Gas Yes Solvent like

P31 Polyethlylene high density part no: 14351

P34 PVC compound – Greon/Vinakon PR01059

Yes Slightly Characteristic

P35 Peptone water (buffered) for microbiology

P45 PVC compound – Geon/Vinakon PR01059

R01 Rocol Moisture Guard Spray

N/A Yes Pungent / Characteristic N/A

R02 Rocol Leak Detector Spray

R03 Rocol Chain and drive spray

R04 Rocol RTD Liquid

R05 Rocol Foliac Super red pipe jointing compound

Yes Dilute Rubbing Alcohol

R06 Rocol Anti-seize compound J166

R07 Rocol RTD compound

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Ref. No or

Material/

TA Luft Class 1,

Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

S04 Sodium Chloride N/A No

S05 Sodium Hydroxide N/A No

S06 Sodium Hypochlorite N/A Yes Characteristic Bleach Odour N/A

S08 Sodium Persulphate N/A No

S13 Sulphuric Acid N/A Yes Acrid N/A

S16 Silver Nitrate No

S17 Shell Omala Oil

S18 Shell Tellus Oil

S19 Shell Polypropylene PMT 6100

S20 Silite RTV Silicone No

S33 Sartomer 28961-43-5

Yes Characteristic

T01 Tampa Ink 180-PE N/A Yes Solvent N/A

T02 Tampa Ink 3356 N/A Yes Solvent N/A

T04 Tampa Solvent (38279) N/A Yes Solvent N/A

T05 Tampa TPV Thinner N/A Yes Solvent N/A

T08 Teresso Oils ISO VG 32 to 460

N/A N/A

T09 Tetra ethylene glycol diacrylate

N/A Yes Musty Acrylic N/A

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Ref. No or

Material/

TA Luft Class 1,

Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

T10 Tetrahydrofuran 2 Yes Ether-like 89790

T11 Toner N/A No

T12 Trichloromethyl silane N/A Yes Acrid N/A

T14 Trizma Pre-set PH 7.5

T15 Tris Buffered Saline with BSA

T16 Tris Buffered Saline PH 8.0

T21 Tyril 867E Styrene Acrolyonitrile resin 01784

No

T30 TWEEN 20

T36 Tampa Ink-Type B printing ink Sorte TP 218

Yes Fruity

X01 Xylene Yes Characteristic

W01 Wl-200 Wash Yes Ketonic

W03 WD-40 Yes Characteristic

W04 White Spirit

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Ref. No or

Material/

TA Luft Class 1,

Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

Triethylene glycol for synthesis

112-27-6 No

RADEL A 100-700 Natural

Polyethersulfone

No

N,N’-Methylenebisacrylamide

110-26-9

Hexylene Glycol 107-41-5 No

Plasdone C-30 No

Savinyl Black RLSN New No

Heliogen Green K 9360 No

Heliogen Green K 8730

NEW 3-APTS (8-aminopyrene-1,3,6-trisulfonic acid, trisodium salt)

Not determined

NEW Acetic Anhydride Yes Strong acetic odor; good

warning properties

NEW Benzyl Alcohol Yes Slight aromatic odour

NEW Dimethylsulfoxide Yes Sulfurous

NEW Ethanolamine Yes Ammonia-like - fish-like -

objectionable

NEW 3-GPTS

NEW Glycine No

NEW Hydrochloric Acid BP Grade Yes Pungent odour of hydrogen

chloride

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Ref. No or

Material/

TA Luft Class 1,

Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

NEW Iminodiacetic acid No




NEW L-Lysine No

NEW 2-Mercaptoethanol

Yes Disagreeable and choking. Characteristic. Stench. Rotten eggs. (Strong.)

N/A

NEW Ninhydrin Yes Characteristic N/A

NEW Nitric Acid Yes Acrid. Disagreeable and

choking. (Strong.) 0.29

NEW PEG 20000 N/A

NEW rProtein A

NEW Sodium Bicarbonate No

NEW Di-Sodium Hydrogen PO4 No

NEW Sodium Acetate Yes Odourless to acetic

NEW Sodium Borohydride N/A

NEW Sodium Metaperiodate N/A

NEW Sodium Azide N/A

NEW Sodium Hydroxide pellets

NEW Trimethylamine Yes Ammoniacal. Fish. N/A

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Ref. No or

Material/

TA Luft Class 1,

Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

NEW Vinyl Sulphone N/A

NEW Sodium Phosphate No

NEW Acros Acetic Acid Yes Vinegar, sour, strong. 0.48

NEW Absolute Ethanol Yes Mild, rather pleasant, like

wine or whiskey N/A

NEW Sodium Cyanoborohydride N/A √

NEW MES, free acid monohydrate

N/A


NEW Silica Gel N/A


NEW Octadecyldimethylchlorosilane

NEW Phenyldimethylchlorosilane

NEW Sodium Lauryl Sulphate Yes Characteristic. Faint odor of

fatty substances (Slight.)

N/A

NEW Ammonium Acetate Yes Acetous (Slight.) N/A



New Snake Venom

NEW 1-(3-Dimethylaminopropylethylcarbimide)

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Ref. No or

Material/

TA Luft Class 1,

Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II




NEW Crystal Violet Yes Characteristic. (Slight.) N/A

NEW Hexamethylenediamine Yes fish-like, weak odor N/A

NEW Toluene Yes Sweet, pungent, Benzene-

like. 1.6

NEW Periodic Acid No

NEW 5’-O-DMT-2’dt-3’-O-succinate

NEW p-Toluenesulphonic Acid Monohydrate

No

NEW N,N-Dimethylformamide Yes Amine like. (Slight.) N/A

NEW vProtein-A (Lonza)

NEW Perchloric Acid Yes Acetic Acid, Strong 1

NEW Sodium Thiosulphate Pentahydrate

No

NEW Cresol Red No

NEW Recombinant Staphlococcal Protein A

NEW Human Immunoglobulin G

NEW Nu Page 4-12% Bis Tris Gel – pk10

NEW Nu Page MOPS SDS Running Buffer

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Ref. No or

Material/

TA Luft Class 1,

Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

NEW Novex Marker (12 Molecular Weight)

NEW Nu Page LDS Sample Buffer

NEW PAGE Blue G-90

NEW Di-Potassium Hydrogen Yes Ether odour N/A

NEW Coomassie Blue No

NEW Sodium Dihydrogen Phosphate

No

NEW Sucrose No

NEW Trifluoroacetic Acid N/A

NEW Ammonium Sulphate No 17

(Amonia)

NEW Ammonium Chloride No

NEW BCA Assay kit

NEW Barium Hydroxide No

NEW Copper Sulphate No

NEW Dimethylglyoxime No

NEW EDTA Disodium salt No

NEW HEPES No

NEW Iron II Sulphate Heptahydrate

No

NEW Nickel II Sulphate No

NEW Oxalic Acid Dihydrate ACS No

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Material/

TA Luft Class 1,

Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

NEW PBS (Dulbecco) Tablets

NEW Potassium Carbonate No

NEW Potassium Iodide No

NEW Potassium Antiminate

NEW Starch Soluble No

NEW Sodium Thioshate

NEW TRIS No

NEW L-Tartaric Acid No

NEW Trichloric Acid Yes Characteristic, pungent N/A

NEW Enterooxin Assay Kit ABCDE

NEW Acetonitrile (HPLC Grade) Yes Aromatic, sweetish. (strong) N/A

NEW Agarose No

NEW Azocasein

NEW Citric Acid Monohydrate No

NEW Polyethylene Glycol 20,000 No

NEW Polyethylene Glycol 3350 No

NEW Potassium Chloride No

NEW Potassium Dihydrogen Phosphate

No

NEW Sodium Carbonate No

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Material/

TA Luft Class 1,

Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

NEW

Protein A ELISA Test Kit for samples containing hlgG – EA (OEM Concepts CO-Z51)

NEW 1413 uS/cm Conductivity Buffer

NEW 12.88 uS/cm Conductivity Buffer

NEW pH10 Buffer

NEW Sodium Thiosulphate No

NEW Acetic Acid, glacial, ACS 99.7+%

Yes Pungent, vinegar like, strong 0.48

NEW Ammonium Hydrogenfluoride

N/A

NEW Ammonium Hydroxide Yes Ammonia like (strong) 5 - 50

NEW 1, 2-Bis(triethoxysilyl)-ethane

NEW Boric Acid No

NEW Boron Nitride, powder 1 micron

N/A

NEW Bromothymol Blue, Sodium Salt

N/A

NEW Ethanol denatured, reagent grade

Yes Characteristic of alcohol N/A

NEW Gelatin from porcene skin

NEW Heptane, anhydrous Yes Hydrocarbon, gasoline like 150

NEW Hydrofluoric Acid Yes Acrid (strong) 0.5-3

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Material/

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Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

NEW Methyl Red No

NEW Nickel powder N/A

NEW Nyacol – Zirconium Oxide No

NEW Nyacol – Zinc Oxide No

NEW Nyacol CE02

NEW Polyacrylic Acid Yes Hazy odour N/A

NEW Polyethylene oxide N/A

NEW Poly(sodium 4-styrene sulfonate)

NEW Silicon Oxide No

NEW Sodium Ethoxide N/A

NEW Tert Amyl Alcohol Yes Pungent, unpleasant 2.3

NEW Tetrabutyl Orthosilicate Yes Slight

NEW Tetraethoxysilane Yes Alcohol like N/A

NEW Tetra-n-propoxysilane N/A

NEW Triethylamine Yes Ammoniacal (strong) N/A

NEW Trimethyl borate N/A

NEW Trimethylpentane Yes Benzene like, odour of

gasoline N/A

NEW Tween 20 No

NEW Zinc Acetic Dihydrate Yes Slight, acetic acid (vinegar) N/A

NEW Zirconium (IV) acetyl-

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Odour



Yes/No

Description

Threshold


76/464/EEC



List I List II

acetonate

NEW Zirconium (IV) Butoxide

NEW Dichloromethane Yes Ethereal odour N/A √

NEW Benzyl Acetate

New Mercury No √

NEW Glacial Acetic Acid Yes Pungent , Vinegar like 4988

Notes (cont.): 4. The European Commission priority candidate list

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TABLE H.1(i): WASTE - Hazardous Waste Recovery/Disposal Note original Hazardous Waste Recovery/ Disposal arrangements are as per previous IPPC licence application and subsequent communications with the Agency The table below outlines new waste streams which will be generated from the CPG/OS processes

Waste material EWC Code Main source1 Quantity On-site Recovery/Disposal

Off-site Recovery, reuse or recycling

Off-site Disposal

Tonnes / month

m3 / month

(Method & Location ) (Method, Location & Undertaker)

(Method, Location &Undertaker)

Non Chlorinated Solvent 07-01-04 Organic Synthesis

6

Waste Broker: AVR SafewayCarrier: South Coast TransportMethod: D10 Incineration on landUndertaker & Location: SAVA Germany, ATM Holland

Chlorinated Solvent 07-01-04 Organic Synthesis

0.05


Mixed Acids 07-01-04 Organic Synthesis

3.25


Chemical glass bottles 07-01-04 Organic Synthesis

0.38


DMSO Empty Drums 07-02-01 Plastic drums with residual DMSO

0.15


Biohazard Waste 18-01-03 0 Healthcare Waste ManagmentEco Safe systems – Dublin KTK Landfill

Waste Mercury Laboratory Analysis (CPG)


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Waste Mercury Wipes Laboratory Analysis (CPG)


Laboratory scale chemicals Laboratory Analysis ( CPG/OS)


1 A reference should be made to the main activity / process for each waste.

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TABLE H.1(ii) WASTE - Other Waste Recovery/Disposal

Waste generated on site is as per previous application in 2006 – new wastes identified as part of the CPG/OS process transfer are

detailed below

Waste material EWC Code Main source1 Quantity On-site recovery/disposal2

Off-site Recovery, reuse or recycling

Off-site Disposal

Tonnes / month

m3 / month

(Method & Location) (Method, Location & Undertaker)

(Method, Location & Undertaker)

Glass Dust ( Borosilicate Glass)

To be determined

Dust collection system (CPG process)

0.4 Waste Broker: AVR Safeway Carrier: South Coast Transport Method: D10 Incineration on land Undertaker & Location: SAVA Germany, ATM Holland

1 A reference should be made to the main activity/ process for each waste. 2 The method of disposal or recovery should be clearly described and referenced to Attachment H.1

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Table I.2(i) SURFACE WATER QUALITY

(Sheet 1 of 2) Monitoring Point/ Grid Reference: ____Receiving river water quality ( Ambient)__10m downstream______________

Parameter Results

(mg/l)

Sampling

method2 (grab, drift

etc.)

Normal

Analytical Range2

Analysis

method / technique

12/7/06

Date Date Date

pH 7.3 Grab 0-14 Electrometric Measurement

Temperature Electrical conductivity EC Ammoniacal nitrogen NH4-N Chemical oxygen demand 9.4mg/L Grab Closed Reflux

Colorimetry Biochemical oxygen demand Dissolved oxygen DO 9.38mgD

O/L Grab EW 043

Dissolved oxygen measurement

Calcium Ca Cadmium Cd Chromium Cr Chloride Cl Copper Cu Iron Fe Lead Pb Magnesium Mg Manganese Mn Mercury Hg

Surface Water Quality (Sheet 2 of 2)

Parameter Results

(mg/l)

Sampling

method

Normal

Analytical

Analysis method

/ technique

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(grab, drift

etc.)

Range

12/7/06

Date Date Date

Nickel Ni Potassium K Sodium Na Sulphate SO4 Zinc Zn Total alkalinity (as CaCO3) 175

mgCaCO

3/L

Grab HA221 Buret Titration

Total organic carbon TOC 8.1mg/L Grab H10128 /9 acid persulphate digestion

Total oxidised nitrogen TON 6.56mg/LN

Grab Total oxidised nitrogen by calculation (Sum NO3/NO2)

Nitrite NO2 0.034 mg/L N

Grab Nitrite by Autoanalyser spectrophotometry

Nitrate NO3 6.45 mg/L N

Grab Nitrate by Autoanalyser spectrophotometry

Faecal coliforms ( /100mls) Total coliforms ( /100mls) Phosphate PO4 <0.03mg

/L P Grab Molybdovoanate

Method / acid persulphate digestion

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Table I.2(i) SURFACE WATER QUALITY (Sheet 1 of 2) Monitoring Point/ Grid Reference: ____Receiving river water quality_(Ambient)__20m downstream____________

Parameter Results

(mg/l)

Sampling

method2

(grab, drift etc.)

Normal

Analytical

Range2

Analysis method /

technique

12/7/0

6

Date Date Date

pH 7.4 Grab 0-14 Electrometric Measurement Temperature Electrical conductivity EC Ammoniacal nitrogen NH4-N Chemical oxygen demand 20.6mg/

L Grab Closed Reflux Colorimetry

Biochemical oxygen demand Dissolved oxygen DO 8.91mgD

O/L Grab EW 043

Dissolved oxygen measurement

Calcium Ca Cadmium Cd Chromium Cr Chloride Cl Copper Cu Iron Fe Lead Pb Magnesium Mg Manganese Mn Mercury Hg

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Surface Water Quality (Sheet 2 of 2)

Parameter Results

(mg/l)

Sampling

method (grab, drift

etc.)

Normal

Analytical Range

Analysis method /

technique

12/7/06

Date Date Date

Nickel Ni Potassium K Sodium Na Sulphate SO4 Zinc Zn Total alkalinity (as CaCO3) 138

mgCaCO

3/L

Grab HA221 Buret Titration

Total organic carbon TOC 15.7 mg/L

Grab H10128 /9 acid persulphate digestion

Total oxidised nitrogen TON 2.83mg/LN

Grab Total oxidised nitrogen by calculation (Sum NO3/NO2)

Nitrite NO2 0.09 mg/L N

Grab Nitrite by Autoanalyser spectrophotometry

Nitrate NO3 2.53 mg/L N

Grab Nitrate by Autoanalyser spectrophotometry

Faecal coliforms ( /100mls) Total coliforms ( /100mls) Phosphate PO4 <0.03mg

/L P Grab Molybdovoanate

Method / acid persulphate digestion

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Table I.4(i) GROUNDWATER QUALITY Monitoring Point/ Grid Reference: ___GW1 __N07242, E18071_______________________

Parameter Results (mg/l)

Sampling method

(composite etc.)

Normal Analytical

Range

Analysis method / technique

06/12/05 14/09/04 Date Date

pH 7.1 6.7 Waterra Organic Sampling Tube


Temperature Electrical conductivity EC 507µS/cm 413µS/cm Waterra Organic

Sampling Tube WTW portable conductivity

meter Ammoniacal nitrogen NH4-N Dissolved oxygen DO Residue on evaporation (180oC)

Calcium Ca 68.4 mg/l 77 mg/l Waterra Organic Sampling Tube

ICP-MS

Cadmium Cd <2 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS

Chromium Cr <2 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS

Chloride Cl 26 mg/l 20 mg/l Waterra Organic Sampling Tube

G/39:Based on APHA,1998,20th Edition, Method 4110B

Copper Cu 2 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS

Cyanide Cn, total Iron Fe 0.7 mg/l 0.2 mg/l Waterra Organic

Sampling Tube ICP-MS

Lead Pb <2 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS

Magnesium Mg 7.5 mg/l 6.1 mg/l Waterra Organic Sampling Tube

ICP-MS

Manganese Mn 1857 µg/l 1062 µg/l Waterra Organic Sampling Tube

ICP-MS

Mercury Hg <1 µg/l <1 µg/l Waterra Organic Sampling Tube

ICP-MS

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Table I.4(i) GROUNDWATER QUALITY (Sheet 1 of 2) Monitoring Point/ Grid Reference: ___GW1 contd

Parameter Results

(mg/l)

Sampling

method (composite etc.)

Normal

Analytical Range

Analysis method /

technique

06/12/05 14/09/04 Date Date Nickel Ni 2 µg/l <2 µg/l Waterra Organic


Potassium K 11.0 mg/l 5.6 mg/l Waterra Organic Sampling Tube

ICP-MS

Sodium Na 17 mg/l 18 mg/l Waterra Organic Sampling Tube

ICP-MS

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GROUNDWATER QUALITY (SHEET 2 OF 2)


Sampling method

(composite etc.)

Normal Analytical

Range


06/12/05 14/09/04 Date Date

Phosphate PO4 <0.02mg/l <0.02mg/l Waterra Organic Sampling Tube


Sulphate SO4 19.4 mg/l 13.7 mg/l Waterra Organic Sampling Tube


Zinc Zn <2 µg/l 85 µg/l Waterra Organic Sampling Tube

ICP-MS

Total alkalinity (as CaCO3) Total organic carbon TOC Total oxidised nitrogen TON Arsenic As <2 µg/l <2 µg/l Waterra Organic


Barium Ba 71 µg/l 71 µg/l Waterra Organic Sampling Tube

ICP-MS

Boron B <2 µg/l 52 µg/l Waterra Organic Sampling Tube

ICP-MS

Fluoride F <0.1 mg/l <0.1 mg/l Waterra Organic Sampling Tube


Phenol Phosphorus P Selenium Se <2 µg/l <2 µg/l Waterra Organic


Silver Ag <2 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS

Nitrite NO2 Nitrate NO3 Faecal coliforms ( /100mls) Total coliforms ( /100mls) Water level (m OD)

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Table I.4(i) GROUNDWATER QUALITY (Sheet 1 of 2) Monitoring Point/ Grid Reference: ___GW2___N07249, E18071______________________


Sampling method

(composite etc.)

Normal Analytical

Range


06/12/05 14/09/04 Date Date







ICP-MS


ICP-MS


ICP-MS



Copper Cu <2 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS




ICP-MS


ICP-MS

Manganese Mn <2 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS


ICP-MS

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Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique



Potassium K 5.9 mg/l 14 mg/l Waterra Organic Sampling Tube

ICP-MS

Sodium Na 15.9 mg/l 20 mg/l Waterra Organic Sampling Tube

ICP-MS

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Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique

06/12/05 14/09/04 Date Date

Phosphate PO4 <0.02 mg/l 0.03 mg/l Waterra Organic Sampling Tube





ICP-MS




ICP-MS

Boron B 44 µg/l 50 µg/l Waterra Organic Sampling Tube

ICP-MS






ICP-MS


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Table I.4(i) GROUNDWATER QUALITY (Sheet 1 of 2) Monitoring Point/ Grid Reference: ___GW3__N07259, E18072_______________________

Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique

06/12/05 14/09/04 Date Date





meter Ammoniacal nitrogen NH4-N Dissolved oxygen DO Residue on evaporation

(180oC)

Calcium Ca 80.2 mg/l 79mg/l Waterra Organic Sampling Tube

ICP-MS


ICP-MS


ICP-MS




ICP-MS




ICP-MS


ICP-MS

Manganese Mn <2 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS


ICP-MS

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Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique



Potassium K 1.1 mg/l 0.8mg/l Waterra Organic Sampling Tube

ICP-MS


ICP-MS

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Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique

06/12/05 14/09/04 Date Date






ICP-MS




ICP-MS


ICP-MS






ICP-MS


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Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique

06/12/05 14/09/04 Date Date





meter Ammoniacal nitrogen NH4-N Dissolved oxygen DO Residue on evaporation

(180oC)


ICP-MS


ICP-MS


ICP-MS




ICP-MS




ICP-MS


ICP-MS

Manganese Mn 143 µg/l 194 µg/l Waterra Organic Sampling Tube

ICP-MS


ICP-MS

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Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique




ICP-MS


ICP-MS

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Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique

06/12/05 14/09/04 Date Date






ICP-MS




ICP-MS


ICP-MS






ICP-MS


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Sampling method

(composite etc.)

Normal Analytical

Range


06/12/05 14/09/04 Date Date







ICP-MS


ICP-MS

Chromium Cr 2 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS




ICP-MS




ICP-MS

Magnesium Mg 10.4 mg/l 15 mg/l Waterra Organic Sampling Tube

ICP-MS

Manganese Mn 3 µg/l <2 µg/l Waterra Organic Sampling Tube

ICP-MS


ICP-MS

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Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique




ICP-MS

Sodium Na 182.7 mg/l 188mg/l Waterra Organic Sampling Tube

ICP-MS

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Parameter Results

(mg/l)

Sampling


Normal

Analytical Range

Analysis method /

technique

06/12/05 14/09/04 Date Date






ICP-MS




ICP-MS


ICP-MS






ICP-MS


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TABLE I.4(ii): LIST OF OWNERS/FARMERS OF LAND

Land Owner

Townlands where landspreading Map Reference

Fertiliser P requirement for each farm

*NMP must take account of on-farm slurry

Total P requirement of the client List _____________ TABLE I.4(ii): LANDSPREADING

Land Owner/Farmer________________________________ Map Reference_______________________

Field ID

Total Area (ha)

(a) Usable Area (ha)

Soil P Test Mg/l

Date of P test

Crop P Required (kg P/ha)

Volume of On-Farm Slurry Returned (m3/ha)

Estimated P in On-Farm Slurry (kg P/ha)

(b) Volume to be Applied (m3/ha)

P Applied (kg P/ha)

Total Volume of imported slurry per plot (m3)

TOTAL VOLUME THAT CAN BE IMPORTED ON TO THE FARM:

Concentration of P in landspread material - kg P/m3

Concentration of N in landspread material - kg N/m3

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Table I.7(i): AMBIENT NOISE ASSESSMENT

Third Octave analysis for noise emissions should be used to determine tonal noises

National Grid

Reference

Sound Pressure Levels

(6N, 6E) L(A)eq L(A)10 L(A)90

1. SITE BOUNDARY

Location 1: AN1 N.07254 E.18067 52 54 50 Location 2: AN2 N.07251 E.18068 53 55 49 Location 3: AN3 N.07243 E.18075 58 53 51 Location 4: AN4 N.07242 E.18090 52 64 49 Location 5: AN5 N.07261 E.18088 61 68 56 Location 6: AN6 N.07261 E.18077 65 56 58

2. NOISE SENSITIVE

LOCATIONS

Location 1: AN1 N.07254 E.18067 48 49 47 Location 2: AN2 N.07251 E.18068 47 48 45 Location 3: AN3 N.07243 E.18075 49 51 42 Location 4: AN4 N.07242 E.18090 44 46 41 Location 5: AN5 N.07261 E.18088 52 55 46 Location 6: AN6 N.07261 E.18077 55 57 51

NOTE: All locations should be identified on accompanying drawings.

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Table I.7(i) Ambient Noise Assessment

Third Octave analysis for noise emissions should be used to determine tonal noises

National Grid

Reference

Sound Pressure Levels

(5N, 5E) L(A)eq L(A)10 L(A)90

3. NOISE SENSITIVE

LOCATIONS

DAYTIME

Location 1: Tullagreen House (Nearest House)

48 dB(A)

2. NOISE SENSITIVE LOCATIONS

NIGHTTIME

Location 1: Tullagreen House (Nearest House)

47.5dB(A)

NOTE: All locations should be identified on accompanying drawings.

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ANNEX 2: CHECKLIST FOR ARTICLE 10 COMPLIANCE

Article 10 of the Environmental Protection Agency (Licensing) Regulations, 1994 to 2004 sets out the statutory requirements for information to accompany a licence application. The Application Form is designed in such a way as to set out these questions in a structured manner and not necessarily in the order presented in Article 10. In order to ensure a legally valid application in respect of Article 10 requirements, all Applicants should complete the following checklist and submit it with the completed Application Form.

Article 10(2)

Section in

Application

Checked by

Applicant ��

(a) give the name, address and telephone number of the applicant and, if different, any address to which correspondence relating to the application should be sent and, if the applicant is a body corporate, the address of its registered or principal office,

B1 ��

(b) give - (i) in the case of an established activity, the number of employees and other persons working or

engaged in connection with the activity on the date after which a licence is required and during normal levels of operation, or

(ii) in any other case, the gross capital cost of the activity to which the application relates,

B4 ��

(c) give the name of the planning authority in whose functional area the activity is or will be carried on,

B5 ��

(d) in the case of a discharge of any trade effluent or other matter (other than domestic sewage or storm water) to a sewer of a sanitary authority, give the name of the sanitary authority in which the sewer is vested or by which it is controlled,

B6 ��

(e) give the location or postal address (including where appropriate, the name of the relevant townland or townlands) and the National Grid reference of the premises to which the activity relates

B2 ��

(f) specify the relevant class or classes in the First Schedule to the Act to which the activity relates,

B3 ��

(g) specify the raw and ancillary materials, substances, preparations, fuels and energy which will be produced by or utilised in the activity,

G1/G2 ��

(h) describe the plant, methods, processes, ancillary processes, abatement, recovery and treatment systems, and operating procedures for the activity,

D1 ��

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Article 10(2) continued../

Section in

Application

Checked by

Applicant ��

(i) indicate how the requirements of section 83(5)(a)(i) to (v) and (vii) to (x) of the Act shall be met, having regard, where appropriate, to any relevant specification issued by the Agency under section 5(3) of the Act and the reasons for the selection of the arrangements proposed,

L ��

(j) give particulars of the source, nature, composition, temperature, volume, level, rate, method of treatment and location of emissions, and the period or periods during which the emissions are made or are to be made,

Table E ��

(k) describe the arrangements for the prevention or minimisation of waste and, where waste is produced, the on and of site arrangements for the recovery or disposal of solid and liquid wastes,

H2 ��

(l) specify, by reference to the relevant European Waste Catalogue codes as prescribed by Commission Decision 2000/532/EC of 03 May 2000, the quantity and nature of the waste or wastes produced or to be produced by the activity,

H1 ��

(m) provide: (i) details, and an assessment, of the impacts of any existing or proposed emissions on the

environment, including on an environmental medium other than that or those into which the emissions are or are to be made, and

(ii) details of the proposed measures to prevent or eliminate, or where that is not practicable, to limit, reduce or abate emissions,

I/F1 ��

(n) identify monitoring and sampling points and outline proposals for monitoring emissions and the environmental consequences of any such emissions,

F2,I,L ��

(o) describe the condition of the site of the installation,

I ��

(p) describe in outline the main alternatives, if any, to the proposals contained in the application which were studied by the applicant,

I8 ��

(q) specify the measures to be taken to comply with an environmental quality standard where such a standard requires stricter conditions to be attached to a licence than would otherwise be determined by reference to best available techniques,

L ��

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Article 10(2) continued../

Section in

Application

Checked by

Applicant ��

(r) describe the measures to be taken for minimising pollution over long distances or in the territory of other states,

I ��

(s) describe the measures to be taken under abnormal operating conditions, including start-up, shutdown, leaks, malfunctions, breakdowns and momentary stoppages,

J ��

(t) describe the measures to be taken on and following the permanent cessation of the activity or part of the activity to avoid any risk of environmental pollution and to return the site of the activity to a satisfactory state,

K ��

(u) describe, in the case of an activity which gives, or could give rise, to an emission containing a hazardous substance which is discharged to an aquifer and is specified in the Annex to Council Directive 80/68/EEC of 17 December 1979 on the protection of groundwater against pollution caused by certain dangerous substances, the arrangements necessary to comply with said Council Directive,

I4 ��

(v) include any other information required under Article 6(1) of Council Directive 96/61/EC of 24 September 1996 concerning integrated pollution prevention and control,

B10 ��

(w) include a non-technical summary of information provided in relation to the matters specified in paragraphs (f) to (v) above,

A ��

(x) state whether the activity consists of, comprises, or is for the purposes an establishment to which the European Communities (Control of Major Accident Hazards involving Dangerous Substances) Regulations, 2000 apply,

B9 ��

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Article 10(3)

Without prejudice to Article 12(1), an application for a licence shall be accompanied by -

Section in

Application

Checked by

Applicant ��

(a) a copy of the relevant page of the newspaper in which the notice in accordance with article 6 has been published,

B8 ��

(b) a copy of the text of the site notice erected or fixed on the land or structure in accordance with article 7,

B8 ��

(c) a copy of the notice given to the planning authority under section 85(1)(a) of the Act,

B8 ��

a copy of such plans, including a site plan and location map (no larger than A3), and such other particulars, reports and supporting documentation as are necessary to identify and describe -

(i) the activity

B2 ��

(ii) the position of the site notice in accordance with article 7,

B8 ��

(iii) the point or points from which emissions are made or are to be made, and

E ��

(d)

(iv) monitoring and sampling points, and

F2 ��

(e) a fee specified in accordance with section 94 of the Act.

A ��

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Article 10(4)

Checked by

Applicant ��

A signed original and 2 hardcopies of the application and accompanying documents/particulars in hardcopy format plus 2 copies of all files in electronic searchable PDF format on CD-Rom shall be submitted to the headquarters of the Agency. In cases where an E.I.S. is required to be submitted to the Agency in support of the application, a signed original and 2 hardcopies of the EIS plus 16* copies of all files in electronic searchable PDF format on CD-Rom shall be submitted to the headquarters of the Agency. * Energy sector applicants = 18 copies

��

Hardcopies submitted. ��

(b)

CD version submitted. ��

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Documents

Integrated Pollution Prevention and Control (IPPC) Licensing