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Inorganics-2 〜Carbon〜 Graphite Electrodes Carbon Structure Control Purification Mixing/ Dispersion High- Temperature Heat Treatment Shocaraiser Granular Graphite Granular-M Molding 31

Inorganics-2 〜Carbon〜...Since graphite electrodes are used under high temperature and oxidation atmosphere, they require low electric resistivity and thermal shock resistance

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  • Inorganics-2 〜Carbon〜

    Graphite ElectrodesCarbon

    Structure Control

    Purification

    Mixing/Dispersion

    High-Temperature

    Heat Treatment

    Shocaraiser™Granular Graphite

    Granular-M

    Molding

    31

  • Graphite Electrodes

    Graphite electrodes are conductive members of an electric steel-making furnace, which recycles scrap iron to manufacture steel products.

    Since graphite electrodes are used under high temperature and oxidation atmosphere, they require low electric resistivity and thermal shock resistance.

    The product is a large-size pillar-shaped graphite material with a maximum diameter of 800 mm and length of 3,000 mm.

    High-temperature heat treatment technology

    Raw materials are extruded, baked and then heat-treated at high temperature in a graphitizing furnace.We have the know-how (energization schedule, inter-electrode connection method, protection of the furnace body from high heat, etc.) to control the properties of the final products and heat-treat the materials with good yield.

    Product Example Our technologies

    32

    Graphitization Furnace

  • Advanced Battery MaterialsArtificial Graphite Anode Materials

    LIB Packing Materials

    SeparatorsSCMG™

    VGCF™SPALF ™

    SDX™Carbon Coated Foil

    Vapor-grown Carbon Fiber

    Carbon Structure Control

    Film/Crystal Growth

    High-Temperature

    HeatTreatment

    Mixing/Dispersion

    Casting/Molding

    Micro-particulation

    Laminate/Printing

    Showa Denko Packaging Co., Ltd.

    45

  • Anode Material for Lithium Ion Secondary Batteries 〜SCMG™〜

    2”φ

    Fine particle treatment technologyTechnology to control the particle size in accordance with various materials

    Heat treatment technologyOur original technology developed for manufacturing graphite electrodes Primary calcination technology with atmospheric controlSecondary calcination technology to control the carbon structure

    Heat treatment facilities Fine particles with carbon structure controlled

    Before cycles After 300 cycles

    SCM

    G™

    Nat

    ural

    gr

    aphi

    te

    We provide a negative-electrode carbon material that suffers no degradation by charge-discharge cycles.

    Capacity

    Char

    ge/d

    isch

    arge

    cyc

    le c

    hara

    cter

    istic

    s

    Artificial graphite

    XR-s

    Natural graphite

    SCMG™AF-C Soft carbonHard carbon

    For EV, PHEV, HEV, ESS

    For mobile phones

    BH

    40

    60

    80

    100

    0 100 200 300

    Batt

    ery

    capa

    city

    re

    sidu

    al r

    atio

    (%

    )

    Charge/discharge cycles

    SCMG™Natural graphite

    Lithium ion secondary battery negative-electrode material SCMG™ (Structure Controlled Micro Graphite)Lithium ion secondary battery negative-electrode material SCMG™ (Structure Controlled Micro Graphite)

    Mesoscopic graphite

    Product example Our technologies

    46

    SCMGTMSCMGTM

  • Strategic Technologies

    Catalyst

    Mixing/Dispersion

    Film/CrystalGrowth

    PolymerizationControl

    MolecularStructure

    52

    Fullerene

    Nanocarbon

    CarbonStructureControl

    Thin Film Process

    Frontier Carbon Corporation

    High-Performance

    Catalysts

    Purification

    Catalyst Group

    Thin Film

    Process Group

    Nano-carbonGroup

    Institute for Advanced and Core Technology

    TM

  • Strategic technology ~Carbon material~Product examples Our technologies

    N

    N

    N

    N

    ON

    O

    OtBu

    N

    N

    N

    tBuO

    O

    O

    OtBu

    OtBu

    O

    O

    O

    Frontier Carbon Corporation

    Mitsubishi Corporation◎World-class sales and marketing

    capabilities

    Showa Denko K.K.◎Nano carbon technology◎Able to develop, produce, and

    supply new products satisfying customers’ requirements

    High-temperature reaction control technology

    Separation and refinement technologies

    Organic synthesis technology

    Vacuum processing technology

    Fine particle treatment technology

    Crystallization technology Dispersion technology Measurement and

    evaluation technologies Surface analysis

    technology Chemical reaction

    simulation technology

    SemiconductorsNano lithography,

    material for lower films

    Sports gearGolf clubs,

    rackets, etc.

    Other industrial usesAdditives to polymers, rubber, and metal; hard carbon films

    LubricantsAdditive to lubricants,

    waxes, etc.

    EnergyOrganic photovoltaic

    panels,fuel cells

    Fullerene products

    Fullerene

    53