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180 I larvlty Road Munchc1cr New llainp~hirc 03103-3347 603-623-3600 F X 603-624-9463 WWW glJCOITI
IAR-1314 A GI
Inlt GcoLnvironmcntil
2012 16 January 04002930700 No File
Lesieur y NancMs rdinator CooPretreatment Industrial
Plant Treatment Wastewater Franklin Division Water
Services Environmental of Department Hampshire New Street River 528
03235 Hampshire New Franklin
Monitoring Discharge Wastewater trial IndusRe (PSNl-1) ampshirc lI New of Service Public
Station Merrimack Hampshire New Bow
Lessieur Ms Dear
Analytical attached the submit lo eased lpis Inc tal nGeoEnvironmeGZA PSNH of behalf On The (WWTS) system treatment wastewater advanced y ltechnologicalPSNHs from Report The weeks several for criteria desi1ll the with ce rdanaccoin g tinoperabeen now has WWTS the of e representativare 2012 5 January on sampling from obtained results analytical attached ed treate thof characteristics The generated wastewater treated (FGD) Desulfurization Gas Flue
forward going consistent be to expected are wastewater
State the that request respectfully we data cal lytianaative trepresenavailable of consideration In as requirements sampling month first the satisfy to report analytical attached the accept
Agreement l SpeciaPSNHs in established
NOTATION ANALYTICAL
on interference matrix overcome to techniques analytical specialized requires wastewater FGD an offer We this of unaware be may laboratories analytical Many analysis metals trace some
heir tto nk lia and site web (EPAs) s Agencyection Protl tanvironmenEthe from below excerpt guidance further contains that procedure draft
WASTEWATER FGD OF ANALYSIS LABORATORY
interferences matrix cause to known constituents contain can systems FGD from Wastewater MS) -(ICPspectrometry mass -plasma coupled inductively during that observed has EPA
cause may wastewater the in present commonly elements certain wastewater FGD of analysis of elements certain of quantization r andodetection the bias that es interferencpolyatomic at elements trace measuring when ant ignificsecome bmay rences interfepotential These interest
range billion -parts-perlow the in concentrations
An Equal Oppommity Employer MFVH
Franklin Wastewater Treatment Plant File No 04002930700
January 16 20 12 Page 2
As part or a recent sampling effort for the steam electric power generating effluent guidelines rulcmaking EPA developed a standard operating procedure (SOP) that was used in conjunction with EPA Method 2008 to conduct ICY-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR I 366 already allow the analytical community tlexihility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The drali SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (iebull a synthetic FGD wastewater matrix) EPA s draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater e ither for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs ~ tanltard QQ_erating Procedure Inductively Coupled PlasmaMass Spectrometry for _]race Elcrlent Analysis in flue Gas Dcsllfurilltion Wastcwaters (30 pp 174K)
We trus t that this submittal adequately address your infonnational needs Should you have any questions please contact me at 232-8744
Very truly yours
GZA GEOENVIRONMENTAL INC
rfJraquootJti ~ Ronald A Breton P E Principal
RABtmd p04jobs0029)00sl04002930700worklsamplinamp and rc-ponirgrcmiddotpomfonal 2930100 cover letter 0 11112dOCJlt
Attachment(s)
SUMMARY ANALYTICAL DATA Puhlic Service Company of New Ilampshirc
Merrimack Station Bow New Hampshirc
PARAMETER RESULTS (mgL) 1052012 Alkalinity IRO
Aluminum 004 11
Ammonia 092
Antimony 0 000520
Arcnic 000498
Barium 0 300
Brryllium 0000522
BOD lt 6
Cadmium 0000207
Calcium 5050
Chloride 11000
Chlorine (Total Rrsidual) lt 005
Chromium (T) lt 000050
COD 130
Copper lt 000050
Cyanide(T) 002
Fluoride 10
Iron lt 0050
Lead lt 0000200
Manganese 0293
Mrrcury (l0000105
Molybdenum 0140
Nitrate 100
Nickel 000803
OampG lt 5
pH 73
Selenium 0074
Silver lt0000100
Sodium 2774
Sulfate 1200
Sulfide lt 01
Sulfite lt 2
TDS 21000
Thallium 000664
TSS 14
ITO ND(I) Zinc lt0001
voe EPA624 (2) Semi VOCs 625 ND(3)
Phenolic Compounds lt03
PCBs ND(4)
NOTES
I No lTO compounds were detected above O0 I mglL 2 One compound was detected by Method 624 Toluene at 2 microgL 3 Semi VOCs were not detected by Method 625 above detection limits ( I microgL and 5 microgL depending on
parameter and 50 microgL for benzoic acid) 4 PCB compounds analyzed by method 608 were not detected at concentrations greater than 03 microgL
lt04M100HJOOl(l4QOf)01CIOlilflSAMlIJp(l l)PJllfIRl1~NMIAli 040090100 IUSlLT$011612AJNfJIW lflOIIIJI l 1 GZA GeoEnvironmental Inc
--~-------------e_a_s_t_e_r_n_a_n_a_ly_t_ic_a_l__
Arthur Auclair
Northeast Utilities
97 River Road
Bow NH 03304
Subject Laboratory Report
Eastern Analytical Inc ID 106677
Client Identification Merrimack Station
Date Received 152012
Dear Mr Auclair middot
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certi fies that the enclosed test results meet all requirements of NE LAP and other applicable state certi fications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NHOOS) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
-~~ l-t3-12shy of pages ( excluding cover letter) Lorraine Olashaw Lab Director Date
SAMPLE CONDITIONS PAGE EAi 10 106677
Client Northeast Utilities
Client Designation Merrimack Station
Temperature upon receipt (0 C) 47 Received on ice or cold packs (YesNo) y Acceptable temperature range ( C) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments jotherthan thermal preservation)
10667701 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667702 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667703 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
Samples were property preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint middot middot lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone(603)228-0525 1
LABORATORY REPORT EAi ID 106677bull Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID Matrix
Date Sampled Date Received
Units
Date of Analysis
Analyst
Method
Dilution Factor
Chlorornethane Vinyl chloride Brornornethane Chloroethane Trichloronuorornethane Acrolein Acetone 11-Dichloroethene Methylene chloride Carbon disulfide Acrylonitrile Methyl-I-butyl ether(MTBE) trans-12-Dichtoroethene Vinyl acetate 11-Dichloroethane cis-12-Dichloroethene 2-Butanone(MEK) Chloroform 111-Trichloroethane Carbon tetrachloride Benzene 12-Dichloroethane Trichloroethene 12-Dichloropropane Bromodichloromethane 2-Chloroethylvinylether 4-Methyl-2-pentanone(MIBK) cis-13-Dichloropropene Toluene trans-13-Dichloropropene 112-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene mp-Xylene o-Xylene Styrene Bromoform 1122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 4-Bromofluorobenzene (surr) 12-Dichlorobenzene-d4 (surr) Toluene-lt18 (surr)
Treat Tank Eff Grab
10667702
aqueous
1512
1512
ug1
1612
KJP
624
lt5 lt2 lt2 lt5 lt 5
lt 50 lt 50
lt 1 lt5 lt5
lt 50 lt 10 lt2
lt 10 lt2 lt2
lt 10 lt2 lt2 lt 2 lt 1 lt2 lt 2 lt2 lt2 lt2
middotlt 10 lt2
2 lt2 lt 2
lt 10 lt2 lt2 lt2 lt 1 lt 1 lt 1 lt 1 lt2 lt2 lt 1 lt 1 lt1
98 R 90R
100 R
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysls Date Units Limits RPO Method - -shy--middot----shy-shy-shy- ---shy --shy--middot-
Chloromethane lt5 19 (97 R) 21 (105 R) (8 RPD) 162012 ug1 0 - 273 20 624
Vinyl chloride lt2 18 (91 R) 20 (101 R) (10 RPD) 162012 ug1 0 - 251 20 624
Bromomethane lt2 21 (105 R) 23 (113 R) (7 RPD) 162012 ug1 0 bull 242 20 624 Chloroethane lt5 19 (95 R) 20 (101 R) (6 RPO) 162012 ug1 14 - 230 20 624
T richloronuoromethane lt5 17 (84 R) 18 (88 R) (5 RPO) 162012 ug1 17 - 181 20 624
Acrolein lt 50 lt 50 (RNA) lt 50 ( R) ( RPO) 1162012 ug1 624
Acetone lt 50 lt 50 (78 R) lt 50 (90 R) (14 RPD) 1162012 ug1 624 1 1-Dichloroethene lt 1 17 (83 R) 18 (89 R) (7 RPO) 162012 ug1 0 - 234 20 624
Methylene chloride lt5 18 (88 R) 19 (93 R) (6 RPO) 162012 ug1 0 bull 221 20 624
Carbon disulfide lt5 17 ( R) 19 ( R) ( RPO) 162012 ug1 624
Acrylonitrile lt 50 lt 50 ( R) lt 50 ( R) ( RPO) 162012 ug1 624 Methyl-I-butyl ether(MTBE) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
trans-12-0ichloroethene lt 2 18 (89 R) 18 (92 R) (3 RPO) 162012 ug1 54 - 156 20 624
Vinyl acetate lt 10 30(R) 30 ( R) ( RPO) 162012 ug1 624 1 1-0ichloroethane lt2 19 (93 R) 20 (98 R) (5 RPD) 162012 ug1 59 shy 155 20 624
cis-12-0ichloroethene lt 2 19(R) 20 ( R) ( RPO) 162012 ug1 624
2-Butanone(MEK) lt 10 20(R) 20 ( ooR) ( RPO) 162012 ug1 624
Chloroform lt2 19 (94 R) 20 (99 R) (5 RPO) 162012 ug1 51 - 138 20 624
11 1-Trichloroethane lt2 18 (91 R) 19 (97 R) (6 RPO) 162012 ug1 52 bull 162 20 624
Carbon tetrachloride lt 2 18 (91 R) 19 (95 R) (4 RPO) 162012 ug1 70 - 140 20 624 Benzene lt 1 19 (97 R) 20 (102 R) (5 RPO) 162012 ug1 37 shy 151 20 624
12-0ichloroethane lt2 18 (91 R) 19 (94 R) (3 RPO) 162012 ug1 49 - 155 20 624 Trichloroethene lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 71 bull 157 20 624 12-0ichloropropane lt2 19 (95 R) 20 (98 R) (3 RPO) 162012 ug1 0 bull 210 20 624
Bromodichloromethane lt2 19 (96 R) 20 (100 R) (4 RPO) 162012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 23 (115 R) 24 (121 R) (5 RPO) 162012 ug1 0 bull 305 20 624 4-Methyl-2-pentanone(MIBK) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
cis-13-Dichloropropene lt2 22 (109 R) 23 (113 R) (4 RPO) 162012 ug1 0 - 227 20 624
Toluene lt 1 20 (101 R) 21 (103 R) (2 RPD) 162012 ug1 47 bull 150 20 624 trans-13-0ichloropropene lt2 18 (90 R) 19 (93 R) (3 RPO) 162012 ug1 17 - 183 20 624 1 12-Trichloroethane lt2 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 52 bull 150 20 624 2-Hexanone lt 10 20 (R) 20 ( R) ( RPO) 162012 ug1 624 Tetrachloroethene lt2 20 (100 R) 21 (106 R) (6 RPO) 162012 ug1 64 bull 148 20 624 Oibromochloromethane lt2 20 (102 R) 21 (104 R) (2 RPO) 162012 ug1 53 - 149 20 624 Chlorobenzene lt2 20 (98 R) 20 (100 R) (2 RPO) 162012 ug1 37 bull 160 20 624 Ethylbenzene lt 1 20 (101 R) 21 (105 R) (4 RPO) 162012 ug1 37 - 162 20 624 mp-Xylene lt 1 40 (101 R) 43 (106 R) (5 RPO) 162012 ug1 70 bull 130 20 624 o-Xylene lt 1 21 (104R) 22 (109 R) (5 RPO) 162012 ug1 70 - 130 20 624 Styrene lt 1 21 ( R) 22 ( R) ( RPO) 162012 ug1 624 Bromoform lt2 18 (88 R) 18 (90 R) (2 RPO) 162012 ug1 45 - 169 20 624 1 122-Tetrachloroethane lt2 20 (99 R) 20 (100 R) (1 RPO) 162012 ug1 46 - 157 20 624 13-Dichlorobenzene lt 1 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 59 - 156 20 624 14-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 12-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 4-Bromofluorobenzene (surr) 100R 101 R 102 R 162012 Rec 70 - 130 624
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units limits RPO Method
12-Dichlorobenzene-d4 (surr) 93 R 90R 89R 162012 Rec 70-130 624
Toluene-dB (surr 100 R 102R 102 R 162012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 4
bull ~ LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512
Date Received 1512
Units ug1
Date of ExtractionPreparation 1612
Date of Analysis 1612
Analyst JMR
Method 625mod
Dilution Factor
Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol
Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1
lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol
46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1
lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane
13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1
lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether
Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1
lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
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bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
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rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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Franklin Wastewater Treatment Plant File No 04002930700
January 16 20 12 Page 2
As part or a recent sampling effort for the steam electric power generating effluent guidelines rulcmaking EPA developed a standard operating procedure (SOP) that was used in conjunction with EPA Method 2008 to conduct ICY-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR I 366 already allow the analytical community tlexihility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The drali SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (iebull a synthetic FGD wastewater matrix) EPA s draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater e ither for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOPs ~ tanltard QQ_erating Procedure Inductively Coupled PlasmaMass Spectrometry for _]race Elcrlent Analysis in flue Gas Dcsllfurilltion Wastcwaters (30 pp 174K)
We trus t that this submittal adequately address your infonnational needs Should you have any questions please contact me at 232-8744
Very truly yours
GZA GEOENVIRONMENTAL INC
rfJraquootJti ~ Ronald A Breton P E Principal
RABtmd p04jobs0029)00sl04002930700worklsamplinamp and rc-ponirgrcmiddotpomfonal 2930100 cover letter 0 11112dOCJlt
Attachment(s)
SUMMARY ANALYTICAL DATA Puhlic Service Company of New Ilampshirc
Merrimack Station Bow New Hampshirc
PARAMETER RESULTS (mgL) 1052012 Alkalinity IRO
Aluminum 004 11
Ammonia 092
Antimony 0 000520
Arcnic 000498
Barium 0 300
Brryllium 0000522
BOD lt 6
Cadmium 0000207
Calcium 5050
Chloride 11000
Chlorine (Total Rrsidual) lt 005
Chromium (T) lt 000050
COD 130
Copper lt 000050
Cyanide(T) 002
Fluoride 10
Iron lt 0050
Lead lt 0000200
Manganese 0293
Mrrcury (l0000105
Molybdenum 0140
Nitrate 100
Nickel 000803
OampG lt 5
pH 73
Selenium 0074
Silver lt0000100
Sodium 2774
Sulfate 1200
Sulfide lt 01
Sulfite lt 2
TDS 21000
Thallium 000664
TSS 14
ITO ND(I) Zinc lt0001
voe EPA624 (2) Semi VOCs 625 ND(3)
Phenolic Compounds lt03
PCBs ND(4)
NOTES
I No lTO compounds were detected above O0 I mglL 2 One compound was detected by Method 624 Toluene at 2 microgL 3 Semi VOCs were not detected by Method 625 above detection limits ( I microgL and 5 microgL depending on
parameter and 50 microgL for benzoic acid) 4 PCB compounds analyzed by method 608 were not detected at concentrations greater than 03 microgL
lt04M100HJOOl(l4QOf)01CIOlilflSAMlIJp(l l)PJllfIRl1~NMIAli 040090100 IUSlLT$011612AJNfJIW lflOIIIJI l 1 GZA GeoEnvironmental Inc
--~-------------e_a_s_t_e_r_n_a_n_a_ly_t_ic_a_l__
Arthur Auclair
Northeast Utilities
97 River Road
Bow NH 03304
Subject Laboratory Report
Eastern Analytical Inc ID 106677
Client Identification Merrimack Station
Date Received 152012
Dear Mr Auclair middot
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certi fies that the enclosed test results meet all requirements of NE LAP and other applicable state certi fications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NHOOS) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
-~~ l-t3-12shy of pages ( excluding cover letter) Lorraine Olashaw Lab Director Date
SAMPLE CONDITIONS PAGE EAi 10 106677
Client Northeast Utilities
Client Designation Merrimack Station
Temperature upon receipt (0 C) 47 Received on ice or cold packs (YesNo) y Acceptable temperature range ( C) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments jotherthan thermal preservation)
10667701 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667702 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667703 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
Samples were property preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint middot middot lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone(603)228-0525 1
LABORATORY REPORT EAi ID 106677bull Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID Matrix
Date Sampled Date Received
Units
Date of Analysis
Analyst
Method
Dilution Factor
Chlorornethane Vinyl chloride Brornornethane Chloroethane Trichloronuorornethane Acrolein Acetone 11-Dichloroethene Methylene chloride Carbon disulfide Acrylonitrile Methyl-I-butyl ether(MTBE) trans-12-Dichtoroethene Vinyl acetate 11-Dichloroethane cis-12-Dichloroethene 2-Butanone(MEK) Chloroform 111-Trichloroethane Carbon tetrachloride Benzene 12-Dichloroethane Trichloroethene 12-Dichloropropane Bromodichloromethane 2-Chloroethylvinylether 4-Methyl-2-pentanone(MIBK) cis-13-Dichloropropene Toluene trans-13-Dichloropropene 112-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene mp-Xylene o-Xylene Styrene Bromoform 1122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 4-Bromofluorobenzene (surr) 12-Dichlorobenzene-d4 (surr) Toluene-lt18 (surr)
Treat Tank Eff Grab
10667702
aqueous
1512
1512
ug1
1612
KJP
624
lt5 lt2 lt2 lt5 lt 5
lt 50 lt 50
lt 1 lt5 lt5
lt 50 lt 10 lt2
lt 10 lt2 lt2
lt 10 lt2 lt2 lt 2 lt 1 lt2 lt 2 lt2 lt2 lt2
middotlt 10 lt2
2 lt2 lt 2
lt 10 lt2 lt2 lt2 lt 1 lt 1 lt 1 lt 1 lt2 lt2 lt 1 lt 1 lt1
98 R 90R
100 R
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysls Date Units Limits RPO Method - -shy--middot----shy-shy-shy- ---shy --shy--middot-
Chloromethane lt5 19 (97 R) 21 (105 R) (8 RPD) 162012 ug1 0 - 273 20 624
Vinyl chloride lt2 18 (91 R) 20 (101 R) (10 RPD) 162012 ug1 0 - 251 20 624
Bromomethane lt2 21 (105 R) 23 (113 R) (7 RPD) 162012 ug1 0 bull 242 20 624 Chloroethane lt5 19 (95 R) 20 (101 R) (6 RPO) 162012 ug1 14 - 230 20 624
T richloronuoromethane lt5 17 (84 R) 18 (88 R) (5 RPO) 162012 ug1 17 - 181 20 624
Acrolein lt 50 lt 50 (RNA) lt 50 ( R) ( RPO) 1162012 ug1 624
Acetone lt 50 lt 50 (78 R) lt 50 (90 R) (14 RPD) 1162012 ug1 624 1 1-Dichloroethene lt 1 17 (83 R) 18 (89 R) (7 RPO) 162012 ug1 0 - 234 20 624
Methylene chloride lt5 18 (88 R) 19 (93 R) (6 RPO) 162012 ug1 0 bull 221 20 624
Carbon disulfide lt5 17 ( R) 19 ( R) ( RPO) 162012 ug1 624
Acrylonitrile lt 50 lt 50 ( R) lt 50 ( R) ( RPO) 162012 ug1 624 Methyl-I-butyl ether(MTBE) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
trans-12-0ichloroethene lt 2 18 (89 R) 18 (92 R) (3 RPO) 162012 ug1 54 - 156 20 624
Vinyl acetate lt 10 30(R) 30 ( R) ( RPO) 162012 ug1 624 1 1-0ichloroethane lt2 19 (93 R) 20 (98 R) (5 RPD) 162012 ug1 59 shy 155 20 624
cis-12-0ichloroethene lt 2 19(R) 20 ( R) ( RPO) 162012 ug1 624
2-Butanone(MEK) lt 10 20(R) 20 ( ooR) ( RPO) 162012 ug1 624
Chloroform lt2 19 (94 R) 20 (99 R) (5 RPO) 162012 ug1 51 - 138 20 624
11 1-Trichloroethane lt2 18 (91 R) 19 (97 R) (6 RPO) 162012 ug1 52 bull 162 20 624
Carbon tetrachloride lt 2 18 (91 R) 19 (95 R) (4 RPO) 162012 ug1 70 - 140 20 624 Benzene lt 1 19 (97 R) 20 (102 R) (5 RPO) 162012 ug1 37 shy 151 20 624
12-0ichloroethane lt2 18 (91 R) 19 (94 R) (3 RPO) 162012 ug1 49 - 155 20 624 Trichloroethene lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 71 bull 157 20 624 12-0ichloropropane lt2 19 (95 R) 20 (98 R) (3 RPO) 162012 ug1 0 bull 210 20 624
Bromodichloromethane lt2 19 (96 R) 20 (100 R) (4 RPO) 162012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 23 (115 R) 24 (121 R) (5 RPO) 162012 ug1 0 bull 305 20 624 4-Methyl-2-pentanone(MIBK) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
cis-13-Dichloropropene lt2 22 (109 R) 23 (113 R) (4 RPO) 162012 ug1 0 - 227 20 624
Toluene lt 1 20 (101 R) 21 (103 R) (2 RPD) 162012 ug1 47 bull 150 20 624 trans-13-0ichloropropene lt2 18 (90 R) 19 (93 R) (3 RPO) 162012 ug1 17 - 183 20 624 1 12-Trichloroethane lt2 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 52 bull 150 20 624 2-Hexanone lt 10 20 (R) 20 ( R) ( RPO) 162012 ug1 624 Tetrachloroethene lt2 20 (100 R) 21 (106 R) (6 RPO) 162012 ug1 64 bull 148 20 624 Oibromochloromethane lt2 20 (102 R) 21 (104 R) (2 RPO) 162012 ug1 53 - 149 20 624 Chlorobenzene lt2 20 (98 R) 20 (100 R) (2 RPO) 162012 ug1 37 bull 160 20 624 Ethylbenzene lt 1 20 (101 R) 21 (105 R) (4 RPO) 162012 ug1 37 - 162 20 624 mp-Xylene lt 1 40 (101 R) 43 (106 R) (5 RPO) 162012 ug1 70 bull 130 20 624 o-Xylene lt 1 21 (104R) 22 (109 R) (5 RPO) 162012 ug1 70 - 130 20 624 Styrene lt 1 21 ( R) 22 ( R) ( RPO) 162012 ug1 624 Bromoform lt2 18 (88 R) 18 (90 R) (2 RPO) 162012 ug1 45 - 169 20 624 1 122-Tetrachloroethane lt2 20 (99 R) 20 (100 R) (1 RPO) 162012 ug1 46 - 157 20 624 13-Dichlorobenzene lt 1 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 59 - 156 20 624 14-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 12-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 4-Bromofluorobenzene (surr) 100R 101 R 102 R 162012 Rec 70 - 130 624
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units limits RPO Method
12-Dichlorobenzene-d4 (surr) 93 R 90R 89R 162012 Rec 70-130 624
Toluene-dB (surr 100 R 102R 102 R 162012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 4
bull ~ LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512
Date Received 1512
Units ug1
Date of ExtractionPreparation 1612
Date of Analysis 1612
Analyst JMR
Method 625mod
Dilution Factor
Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol
Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1
lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol
46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1
lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane
13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1
lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether
Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1
lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
SUMMARY ANALYTICAL DATA Puhlic Service Company of New Ilampshirc
Merrimack Station Bow New Hampshirc
PARAMETER RESULTS (mgL) 1052012 Alkalinity IRO
Aluminum 004 11
Ammonia 092
Antimony 0 000520
Arcnic 000498
Barium 0 300
Brryllium 0000522
BOD lt 6
Cadmium 0000207
Calcium 5050
Chloride 11000
Chlorine (Total Rrsidual) lt 005
Chromium (T) lt 000050
COD 130
Copper lt 000050
Cyanide(T) 002
Fluoride 10
Iron lt 0050
Lead lt 0000200
Manganese 0293
Mrrcury (l0000105
Molybdenum 0140
Nitrate 100
Nickel 000803
OampG lt 5
pH 73
Selenium 0074
Silver lt0000100
Sodium 2774
Sulfate 1200
Sulfide lt 01
Sulfite lt 2
TDS 21000
Thallium 000664
TSS 14
ITO ND(I) Zinc lt0001
voe EPA624 (2) Semi VOCs 625 ND(3)
Phenolic Compounds lt03
PCBs ND(4)
NOTES
I No lTO compounds were detected above O0 I mglL 2 One compound was detected by Method 624 Toluene at 2 microgL 3 Semi VOCs were not detected by Method 625 above detection limits ( I microgL and 5 microgL depending on
parameter and 50 microgL for benzoic acid) 4 PCB compounds analyzed by method 608 were not detected at concentrations greater than 03 microgL
lt04M100HJOOl(l4QOf)01CIOlilflSAMlIJp(l l)PJllfIRl1~NMIAli 040090100 IUSlLT$011612AJNfJIW lflOIIIJI l 1 GZA GeoEnvironmental Inc
--~-------------e_a_s_t_e_r_n_a_n_a_ly_t_ic_a_l__
Arthur Auclair
Northeast Utilities
97 River Road
Bow NH 03304
Subject Laboratory Report
Eastern Analytical Inc ID 106677
Client Identification Merrimack Station
Date Received 152012
Dear Mr Auclair middot
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certi fies that the enclosed test results meet all requirements of NE LAP and other applicable state certi fications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NHOOS) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
-~~ l-t3-12shy of pages ( excluding cover letter) Lorraine Olashaw Lab Director Date
SAMPLE CONDITIONS PAGE EAi 10 106677
Client Northeast Utilities
Client Designation Merrimack Station
Temperature upon receipt (0 C) 47 Received on ice or cold packs (YesNo) y Acceptable temperature range ( C) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments jotherthan thermal preservation)
10667701 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667702 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667703 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
Samples were property preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint middot middot lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone(603)228-0525 1
LABORATORY REPORT EAi ID 106677bull Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID Matrix
Date Sampled Date Received
Units
Date of Analysis
Analyst
Method
Dilution Factor
Chlorornethane Vinyl chloride Brornornethane Chloroethane Trichloronuorornethane Acrolein Acetone 11-Dichloroethene Methylene chloride Carbon disulfide Acrylonitrile Methyl-I-butyl ether(MTBE) trans-12-Dichtoroethene Vinyl acetate 11-Dichloroethane cis-12-Dichloroethene 2-Butanone(MEK) Chloroform 111-Trichloroethane Carbon tetrachloride Benzene 12-Dichloroethane Trichloroethene 12-Dichloropropane Bromodichloromethane 2-Chloroethylvinylether 4-Methyl-2-pentanone(MIBK) cis-13-Dichloropropene Toluene trans-13-Dichloropropene 112-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene mp-Xylene o-Xylene Styrene Bromoform 1122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 4-Bromofluorobenzene (surr) 12-Dichlorobenzene-d4 (surr) Toluene-lt18 (surr)
Treat Tank Eff Grab
10667702
aqueous
1512
1512
ug1
1612
KJP
624
lt5 lt2 lt2 lt5 lt 5
lt 50 lt 50
lt 1 lt5 lt5
lt 50 lt 10 lt2
lt 10 lt2 lt2
lt 10 lt2 lt2 lt 2 lt 1 lt2 lt 2 lt2 lt2 lt2
middotlt 10 lt2
2 lt2 lt 2
lt 10 lt2 lt2 lt2 lt 1 lt 1 lt 1 lt 1 lt2 lt2 lt 1 lt 1 lt1
98 R 90R
100 R
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysls Date Units Limits RPO Method - -shy--middot----shy-shy-shy- ---shy --shy--middot-
Chloromethane lt5 19 (97 R) 21 (105 R) (8 RPD) 162012 ug1 0 - 273 20 624
Vinyl chloride lt2 18 (91 R) 20 (101 R) (10 RPD) 162012 ug1 0 - 251 20 624
Bromomethane lt2 21 (105 R) 23 (113 R) (7 RPD) 162012 ug1 0 bull 242 20 624 Chloroethane lt5 19 (95 R) 20 (101 R) (6 RPO) 162012 ug1 14 - 230 20 624
T richloronuoromethane lt5 17 (84 R) 18 (88 R) (5 RPO) 162012 ug1 17 - 181 20 624
Acrolein lt 50 lt 50 (RNA) lt 50 ( R) ( RPO) 1162012 ug1 624
Acetone lt 50 lt 50 (78 R) lt 50 (90 R) (14 RPD) 1162012 ug1 624 1 1-Dichloroethene lt 1 17 (83 R) 18 (89 R) (7 RPO) 162012 ug1 0 - 234 20 624
Methylene chloride lt5 18 (88 R) 19 (93 R) (6 RPO) 162012 ug1 0 bull 221 20 624
Carbon disulfide lt5 17 ( R) 19 ( R) ( RPO) 162012 ug1 624
Acrylonitrile lt 50 lt 50 ( R) lt 50 ( R) ( RPO) 162012 ug1 624 Methyl-I-butyl ether(MTBE) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
trans-12-0ichloroethene lt 2 18 (89 R) 18 (92 R) (3 RPO) 162012 ug1 54 - 156 20 624
Vinyl acetate lt 10 30(R) 30 ( R) ( RPO) 162012 ug1 624 1 1-0ichloroethane lt2 19 (93 R) 20 (98 R) (5 RPD) 162012 ug1 59 shy 155 20 624
cis-12-0ichloroethene lt 2 19(R) 20 ( R) ( RPO) 162012 ug1 624
2-Butanone(MEK) lt 10 20(R) 20 ( ooR) ( RPO) 162012 ug1 624
Chloroform lt2 19 (94 R) 20 (99 R) (5 RPO) 162012 ug1 51 - 138 20 624
11 1-Trichloroethane lt2 18 (91 R) 19 (97 R) (6 RPO) 162012 ug1 52 bull 162 20 624
Carbon tetrachloride lt 2 18 (91 R) 19 (95 R) (4 RPO) 162012 ug1 70 - 140 20 624 Benzene lt 1 19 (97 R) 20 (102 R) (5 RPO) 162012 ug1 37 shy 151 20 624
12-0ichloroethane lt2 18 (91 R) 19 (94 R) (3 RPO) 162012 ug1 49 - 155 20 624 Trichloroethene lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 71 bull 157 20 624 12-0ichloropropane lt2 19 (95 R) 20 (98 R) (3 RPO) 162012 ug1 0 bull 210 20 624
Bromodichloromethane lt2 19 (96 R) 20 (100 R) (4 RPO) 162012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 23 (115 R) 24 (121 R) (5 RPO) 162012 ug1 0 bull 305 20 624 4-Methyl-2-pentanone(MIBK) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
cis-13-Dichloropropene lt2 22 (109 R) 23 (113 R) (4 RPO) 162012 ug1 0 - 227 20 624
Toluene lt 1 20 (101 R) 21 (103 R) (2 RPD) 162012 ug1 47 bull 150 20 624 trans-13-0ichloropropene lt2 18 (90 R) 19 (93 R) (3 RPO) 162012 ug1 17 - 183 20 624 1 12-Trichloroethane lt2 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 52 bull 150 20 624 2-Hexanone lt 10 20 (R) 20 ( R) ( RPO) 162012 ug1 624 Tetrachloroethene lt2 20 (100 R) 21 (106 R) (6 RPO) 162012 ug1 64 bull 148 20 624 Oibromochloromethane lt2 20 (102 R) 21 (104 R) (2 RPO) 162012 ug1 53 - 149 20 624 Chlorobenzene lt2 20 (98 R) 20 (100 R) (2 RPO) 162012 ug1 37 bull 160 20 624 Ethylbenzene lt 1 20 (101 R) 21 (105 R) (4 RPO) 162012 ug1 37 - 162 20 624 mp-Xylene lt 1 40 (101 R) 43 (106 R) (5 RPO) 162012 ug1 70 bull 130 20 624 o-Xylene lt 1 21 (104R) 22 (109 R) (5 RPO) 162012 ug1 70 - 130 20 624 Styrene lt 1 21 ( R) 22 ( R) ( RPO) 162012 ug1 624 Bromoform lt2 18 (88 R) 18 (90 R) (2 RPO) 162012 ug1 45 - 169 20 624 1 122-Tetrachloroethane lt2 20 (99 R) 20 (100 R) (1 RPO) 162012 ug1 46 - 157 20 624 13-Dichlorobenzene lt 1 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 59 - 156 20 624 14-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 12-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 4-Bromofluorobenzene (surr) 100R 101 R 102 R 162012 Rec 70 - 130 624
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units limits RPO Method
12-Dichlorobenzene-d4 (surr) 93 R 90R 89R 162012 Rec 70-130 624
Toluene-dB (surr 100 R 102R 102 R 162012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 4
bull ~ LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512
Date Received 1512
Units ug1
Date of ExtractionPreparation 1612
Date of Analysis 1612
Analyst JMR
Method 625mod
Dilution Factor
Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol
Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1
lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol
46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1
lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane
13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1
lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether
Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1
lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
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3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
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bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
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WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
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(~ All A~d) ib FGgt sJ c~tlio((
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eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
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--~-------------e_a_s_t_e_r_n_a_n_a_ly_t_ic_a_l__
Arthur Auclair
Northeast Utilities
97 River Road
Bow NH 03304
Subject Laboratory Report
Eastern Analytical Inc ID 106677
Client Identification Merrimack Station
Date Received 152012
Dear Mr Auclair middot
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certi fies that the enclosed test results meet all requirements of NE LAP and other applicable state certi fications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NHOOS) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
-~~ l-t3-12shy of pages ( excluding cover letter) Lorraine Olashaw Lab Director Date
SAMPLE CONDITIONS PAGE EAi 10 106677
Client Northeast Utilities
Client Designation Merrimack Station
Temperature upon receipt (0 C) 47 Received on ice or cold packs (YesNo) y Acceptable temperature range ( C) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments jotherthan thermal preservation)
10667701 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667702 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667703 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
Samples were property preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint middot middot lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone(603)228-0525 1
LABORATORY REPORT EAi ID 106677bull Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID Matrix
Date Sampled Date Received
Units
Date of Analysis
Analyst
Method
Dilution Factor
Chlorornethane Vinyl chloride Brornornethane Chloroethane Trichloronuorornethane Acrolein Acetone 11-Dichloroethene Methylene chloride Carbon disulfide Acrylonitrile Methyl-I-butyl ether(MTBE) trans-12-Dichtoroethene Vinyl acetate 11-Dichloroethane cis-12-Dichloroethene 2-Butanone(MEK) Chloroform 111-Trichloroethane Carbon tetrachloride Benzene 12-Dichloroethane Trichloroethene 12-Dichloropropane Bromodichloromethane 2-Chloroethylvinylether 4-Methyl-2-pentanone(MIBK) cis-13-Dichloropropene Toluene trans-13-Dichloropropene 112-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene mp-Xylene o-Xylene Styrene Bromoform 1122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 4-Bromofluorobenzene (surr) 12-Dichlorobenzene-d4 (surr) Toluene-lt18 (surr)
Treat Tank Eff Grab
10667702
aqueous
1512
1512
ug1
1612
KJP
624
lt5 lt2 lt2 lt5 lt 5
lt 50 lt 50
lt 1 lt5 lt5
lt 50 lt 10 lt2
lt 10 lt2 lt2
lt 10 lt2 lt2 lt 2 lt 1 lt2 lt 2 lt2 lt2 lt2
middotlt 10 lt2
2 lt2 lt 2
lt 10 lt2 lt2 lt2 lt 1 lt 1 lt 1 lt 1 lt2 lt2 lt 1 lt 1 lt1
98 R 90R
100 R
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysls Date Units Limits RPO Method - -shy--middot----shy-shy-shy- ---shy --shy--middot-
Chloromethane lt5 19 (97 R) 21 (105 R) (8 RPD) 162012 ug1 0 - 273 20 624
Vinyl chloride lt2 18 (91 R) 20 (101 R) (10 RPD) 162012 ug1 0 - 251 20 624
Bromomethane lt2 21 (105 R) 23 (113 R) (7 RPD) 162012 ug1 0 bull 242 20 624 Chloroethane lt5 19 (95 R) 20 (101 R) (6 RPO) 162012 ug1 14 - 230 20 624
T richloronuoromethane lt5 17 (84 R) 18 (88 R) (5 RPO) 162012 ug1 17 - 181 20 624
Acrolein lt 50 lt 50 (RNA) lt 50 ( R) ( RPO) 1162012 ug1 624
Acetone lt 50 lt 50 (78 R) lt 50 (90 R) (14 RPD) 1162012 ug1 624 1 1-Dichloroethene lt 1 17 (83 R) 18 (89 R) (7 RPO) 162012 ug1 0 - 234 20 624
Methylene chloride lt5 18 (88 R) 19 (93 R) (6 RPO) 162012 ug1 0 bull 221 20 624
Carbon disulfide lt5 17 ( R) 19 ( R) ( RPO) 162012 ug1 624
Acrylonitrile lt 50 lt 50 ( R) lt 50 ( R) ( RPO) 162012 ug1 624 Methyl-I-butyl ether(MTBE) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
trans-12-0ichloroethene lt 2 18 (89 R) 18 (92 R) (3 RPO) 162012 ug1 54 - 156 20 624
Vinyl acetate lt 10 30(R) 30 ( R) ( RPO) 162012 ug1 624 1 1-0ichloroethane lt2 19 (93 R) 20 (98 R) (5 RPD) 162012 ug1 59 shy 155 20 624
cis-12-0ichloroethene lt 2 19(R) 20 ( R) ( RPO) 162012 ug1 624
2-Butanone(MEK) lt 10 20(R) 20 ( ooR) ( RPO) 162012 ug1 624
Chloroform lt2 19 (94 R) 20 (99 R) (5 RPO) 162012 ug1 51 - 138 20 624
11 1-Trichloroethane lt2 18 (91 R) 19 (97 R) (6 RPO) 162012 ug1 52 bull 162 20 624
Carbon tetrachloride lt 2 18 (91 R) 19 (95 R) (4 RPO) 162012 ug1 70 - 140 20 624 Benzene lt 1 19 (97 R) 20 (102 R) (5 RPO) 162012 ug1 37 shy 151 20 624
12-0ichloroethane lt2 18 (91 R) 19 (94 R) (3 RPO) 162012 ug1 49 - 155 20 624 Trichloroethene lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 71 bull 157 20 624 12-0ichloropropane lt2 19 (95 R) 20 (98 R) (3 RPO) 162012 ug1 0 bull 210 20 624
Bromodichloromethane lt2 19 (96 R) 20 (100 R) (4 RPO) 162012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 23 (115 R) 24 (121 R) (5 RPO) 162012 ug1 0 bull 305 20 624 4-Methyl-2-pentanone(MIBK) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
cis-13-Dichloropropene lt2 22 (109 R) 23 (113 R) (4 RPO) 162012 ug1 0 - 227 20 624
Toluene lt 1 20 (101 R) 21 (103 R) (2 RPD) 162012 ug1 47 bull 150 20 624 trans-13-0ichloropropene lt2 18 (90 R) 19 (93 R) (3 RPO) 162012 ug1 17 - 183 20 624 1 12-Trichloroethane lt2 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 52 bull 150 20 624 2-Hexanone lt 10 20 (R) 20 ( R) ( RPO) 162012 ug1 624 Tetrachloroethene lt2 20 (100 R) 21 (106 R) (6 RPO) 162012 ug1 64 bull 148 20 624 Oibromochloromethane lt2 20 (102 R) 21 (104 R) (2 RPO) 162012 ug1 53 - 149 20 624 Chlorobenzene lt2 20 (98 R) 20 (100 R) (2 RPO) 162012 ug1 37 bull 160 20 624 Ethylbenzene lt 1 20 (101 R) 21 (105 R) (4 RPO) 162012 ug1 37 - 162 20 624 mp-Xylene lt 1 40 (101 R) 43 (106 R) (5 RPO) 162012 ug1 70 bull 130 20 624 o-Xylene lt 1 21 (104R) 22 (109 R) (5 RPO) 162012 ug1 70 - 130 20 624 Styrene lt 1 21 ( R) 22 ( R) ( RPO) 162012 ug1 624 Bromoform lt2 18 (88 R) 18 (90 R) (2 RPO) 162012 ug1 45 - 169 20 624 1 122-Tetrachloroethane lt2 20 (99 R) 20 (100 R) (1 RPO) 162012 ug1 46 - 157 20 624 13-Dichlorobenzene lt 1 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 59 - 156 20 624 14-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 12-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 4-Bromofluorobenzene (surr) 100R 101 R 102 R 162012 Rec 70 - 130 624
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units limits RPO Method
12-Dichlorobenzene-d4 (surr) 93 R 90R 89R 162012 Rec 70-130 624
Toluene-dB (surr 100 R 102R 102 R 162012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 4
bull ~ LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512
Date Received 1512
Units ug1
Date of ExtractionPreparation 1612
Date of Analysis 1612
Analyst JMR
Method 625mod
Dilution Factor
Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol
Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1
lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol
46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1
lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane
13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1
lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether
Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1
lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
SAMPLE CONDITIONS PAGE EAi 10 106677
Client Northeast Utilities
Client Designation Merrimack Station
Temperature upon receipt (0 C) 47 Received on ice or cold packs (YesNo) y Acceptable temperature range ( C) 0-6
Date Date Sample Dry Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments jotherthan thermal preservation)
10667701 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667702 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
10667703 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy
Samples were property preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint middot middot lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an middotas received basis
All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone(603)228-0525 1
LABORATORY REPORT EAi ID 106677bull Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID Matrix
Date Sampled Date Received
Units
Date of Analysis
Analyst
Method
Dilution Factor
Chlorornethane Vinyl chloride Brornornethane Chloroethane Trichloronuorornethane Acrolein Acetone 11-Dichloroethene Methylene chloride Carbon disulfide Acrylonitrile Methyl-I-butyl ether(MTBE) trans-12-Dichtoroethene Vinyl acetate 11-Dichloroethane cis-12-Dichloroethene 2-Butanone(MEK) Chloroform 111-Trichloroethane Carbon tetrachloride Benzene 12-Dichloroethane Trichloroethene 12-Dichloropropane Bromodichloromethane 2-Chloroethylvinylether 4-Methyl-2-pentanone(MIBK) cis-13-Dichloropropene Toluene trans-13-Dichloropropene 112-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene mp-Xylene o-Xylene Styrene Bromoform 1122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 4-Bromofluorobenzene (surr) 12-Dichlorobenzene-d4 (surr) Toluene-lt18 (surr)
Treat Tank Eff Grab
10667702
aqueous
1512
1512
ug1
1612
KJP
624
lt5 lt2 lt2 lt5 lt 5
lt 50 lt 50
lt 1 lt5 lt5
lt 50 lt 10 lt2
lt 10 lt2 lt2
lt 10 lt2 lt2 lt 2 lt 1 lt2 lt 2 lt2 lt2 lt2
middotlt 10 lt2
2 lt2 lt 2
lt 10 lt2 lt2 lt2 lt 1 lt 1 lt 1 lt 1 lt2 lt2 lt 1 lt 1 lt1
98 R 90R
100 R
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysls Date Units Limits RPO Method - -shy--middot----shy-shy-shy- ---shy --shy--middot-
Chloromethane lt5 19 (97 R) 21 (105 R) (8 RPD) 162012 ug1 0 - 273 20 624
Vinyl chloride lt2 18 (91 R) 20 (101 R) (10 RPD) 162012 ug1 0 - 251 20 624
Bromomethane lt2 21 (105 R) 23 (113 R) (7 RPD) 162012 ug1 0 bull 242 20 624 Chloroethane lt5 19 (95 R) 20 (101 R) (6 RPO) 162012 ug1 14 - 230 20 624
T richloronuoromethane lt5 17 (84 R) 18 (88 R) (5 RPO) 162012 ug1 17 - 181 20 624
Acrolein lt 50 lt 50 (RNA) lt 50 ( R) ( RPO) 1162012 ug1 624
Acetone lt 50 lt 50 (78 R) lt 50 (90 R) (14 RPD) 1162012 ug1 624 1 1-Dichloroethene lt 1 17 (83 R) 18 (89 R) (7 RPO) 162012 ug1 0 - 234 20 624
Methylene chloride lt5 18 (88 R) 19 (93 R) (6 RPO) 162012 ug1 0 bull 221 20 624
Carbon disulfide lt5 17 ( R) 19 ( R) ( RPO) 162012 ug1 624
Acrylonitrile lt 50 lt 50 ( R) lt 50 ( R) ( RPO) 162012 ug1 624 Methyl-I-butyl ether(MTBE) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
trans-12-0ichloroethene lt 2 18 (89 R) 18 (92 R) (3 RPO) 162012 ug1 54 - 156 20 624
Vinyl acetate lt 10 30(R) 30 ( R) ( RPO) 162012 ug1 624 1 1-0ichloroethane lt2 19 (93 R) 20 (98 R) (5 RPD) 162012 ug1 59 shy 155 20 624
cis-12-0ichloroethene lt 2 19(R) 20 ( R) ( RPO) 162012 ug1 624
2-Butanone(MEK) lt 10 20(R) 20 ( ooR) ( RPO) 162012 ug1 624
Chloroform lt2 19 (94 R) 20 (99 R) (5 RPO) 162012 ug1 51 - 138 20 624
11 1-Trichloroethane lt2 18 (91 R) 19 (97 R) (6 RPO) 162012 ug1 52 bull 162 20 624
Carbon tetrachloride lt 2 18 (91 R) 19 (95 R) (4 RPO) 162012 ug1 70 - 140 20 624 Benzene lt 1 19 (97 R) 20 (102 R) (5 RPO) 162012 ug1 37 shy 151 20 624
12-0ichloroethane lt2 18 (91 R) 19 (94 R) (3 RPO) 162012 ug1 49 - 155 20 624 Trichloroethene lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 71 bull 157 20 624 12-0ichloropropane lt2 19 (95 R) 20 (98 R) (3 RPO) 162012 ug1 0 bull 210 20 624
Bromodichloromethane lt2 19 (96 R) 20 (100 R) (4 RPO) 162012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 23 (115 R) 24 (121 R) (5 RPO) 162012 ug1 0 bull 305 20 624 4-Methyl-2-pentanone(MIBK) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
cis-13-Dichloropropene lt2 22 (109 R) 23 (113 R) (4 RPO) 162012 ug1 0 - 227 20 624
Toluene lt 1 20 (101 R) 21 (103 R) (2 RPD) 162012 ug1 47 bull 150 20 624 trans-13-0ichloropropene lt2 18 (90 R) 19 (93 R) (3 RPO) 162012 ug1 17 - 183 20 624 1 12-Trichloroethane lt2 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 52 bull 150 20 624 2-Hexanone lt 10 20 (R) 20 ( R) ( RPO) 162012 ug1 624 Tetrachloroethene lt2 20 (100 R) 21 (106 R) (6 RPO) 162012 ug1 64 bull 148 20 624 Oibromochloromethane lt2 20 (102 R) 21 (104 R) (2 RPO) 162012 ug1 53 - 149 20 624 Chlorobenzene lt2 20 (98 R) 20 (100 R) (2 RPO) 162012 ug1 37 bull 160 20 624 Ethylbenzene lt 1 20 (101 R) 21 (105 R) (4 RPO) 162012 ug1 37 - 162 20 624 mp-Xylene lt 1 40 (101 R) 43 (106 R) (5 RPO) 162012 ug1 70 bull 130 20 624 o-Xylene lt 1 21 (104R) 22 (109 R) (5 RPO) 162012 ug1 70 - 130 20 624 Styrene lt 1 21 ( R) 22 ( R) ( RPO) 162012 ug1 624 Bromoform lt2 18 (88 R) 18 (90 R) (2 RPO) 162012 ug1 45 - 169 20 624 1 122-Tetrachloroethane lt2 20 (99 R) 20 (100 R) (1 RPO) 162012 ug1 46 - 157 20 624 13-Dichlorobenzene lt 1 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 59 - 156 20 624 14-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 12-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 4-Bromofluorobenzene (surr) 100R 101 R 102 R 162012 Rec 70 - 130 624
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units limits RPO Method
12-Dichlorobenzene-d4 (surr) 93 R 90R 89R 162012 Rec 70-130 624
Toluene-dB (surr 100 R 102R 102 R 162012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 4
bull ~ LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512
Date Received 1512
Units ug1
Date of ExtractionPreparation 1612
Date of Analysis 1612
Analyst JMR
Method 625mod
Dilution Factor
Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol
Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1
lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol
46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1
lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane
13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1
lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether
Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1
lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
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- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
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3 MEOH VIAL SAMPLE ID
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IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
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bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
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WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
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eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
LABORATORY REPORT EAi ID 106677bull Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID Matrix
Date Sampled Date Received
Units
Date of Analysis
Analyst
Method
Dilution Factor
Chlorornethane Vinyl chloride Brornornethane Chloroethane Trichloronuorornethane Acrolein Acetone 11-Dichloroethene Methylene chloride Carbon disulfide Acrylonitrile Methyl-I-butyl ether(MTBE) trans-12-Dichtoroethene Vinyl acetate 11-Dichloroethane cis-12-Dichloroethene 2-Butanone(MEK) Chloroform 111-Trichloroethane Carbon tetrachloride Benzene 12-Dichloroethane Trichloroethene 12-Dichloropropane Bromodichloromethane 2-Chloroethylvinylether 4-Methyl-2-pentanone(MIBK) cis-13-Dichloropropene Toluene trans-13-Dichloropropene 112-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene mp-Xylene o-Xylene Styrene Bromoform 1122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 4-Bromofluorobenzene (surr) 12-Dichlorobenzene-d4 (surr) Toluene-lt18 (surr)
Treat Tank Eff Grab
10667702
aqueous
1512
1512
ug1
1612
KJP
624
lt5 lt2 lt2 lt5 lt 5
lt 50 lt 50
lt 1 lt5 lt5
lt 50 lt 10 lt2
lt 10 lt2 lt2
lt 10 lt2 lt2 lt 2 lt 1 lt2 lt 2 lt2 lt2 lt2
middotlt 10 lt2
2 lt2 lt 2
lt 10 lt2 lt2 lt2 lt 1 lt 1 lt 1 lt 1 lt2 lt2 lt 1 lt 1 lt1
98 R 90R
100 R
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysls Date Units Limits RPO Method - -shy--middot----shy-shy-shy- ---shy --shy--middot-
Chloromethane lt5 19 (97 R) 21 (105 R) (8 RPD) 162012 ug1 0 - 273 20 624
Vinyl chloride lt2 18 (91 R) 20 (101 R) (10 RPD) 162012 ug1 0 - 251 20 624
Bromomethane lt2 21 (105 R) 23 (113 R) (7 RPD) 162012 ug1 0 bull 242 20 624 Chloroethane lt5 19 (95 R) 20 (101 R) (6 RPO) 162012 ug1 14 - 230 20 624
T richloronuoromethane lt5 17 (84 R) 18 (88 R) (5 RPO) 162012 ug1 17 - 181 20 624
Acrolein lt 50 lt 50 (RNA) lt 50 ( R) ( RPO) 1162012 ug1 624
Acetone lt 50 lt 50 (78 R) lt 50 (90 R) (14 RPD) 1162012 ug1 624 1 1-Dichloroethene lt 1 17 (83 R) 18 (89 R) (7 RPO) 162012 ug1 0 - 234 20 624
Methylene chloride lt5 18 (88 R) 19 (93 R) (6 RPO) 162012 ug1 0 bull 221 20 624
Carbon disulfide lt5 17 ( R) 19 ( R) ( RPO) 162012 ug1 624
Acrylonitrile lt 50 lt 50 ( R) lt 50 ( R) ( RPO) 162012 ug1 624 Methyl-I-butyl ether(MTBE) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
trans-12-0ichloroethene lt 2 18 (89 R) 18 (92 R) (3 RPO) 162012 ug1 54 - 156 20 624
Vinyl acetate lt 10 30(R) 30 ( R) ( RPO) 162012 ug1 624 1 1-0ichloroethane lt2 19 (93 R) 20 (98 R) (5 RPD) 162012 ug1 59 shy 155 20 624
cis-12-0ichloroethene lt 2 19(R) 20 ( R) ( RPO) 162012 ug1 624
2-Butanone(MEK) lt 10 20(R) 20 ( ooR) ( RPO) 162012 ug1 624
Chloroform lt2 19 (94 R) 20 (99 R) (5 RPO) 162012 ug1 51 - 138 20 624
11 1-Trichloroethane lt2 18 (91 R) 19 (97 R) (6 RPO) 162012 ug1 52 bull 162 20 624
Carbon tetrachloride lt 2 18 (91 R) 19 (95 R) (4 RPO) 162012 ug1 70 - 140 20 624 Benzene lt 1 19 (97 R) 20 (102 R) (5 RPO) 162012 ug1 37 shy 151 20 624
12-0ichloroethane lt2 18 (91 R) 19 (94 R) (3 RPO) 162012 ug1 49 - 155 20 624 Trichloroethene lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 71 bull 157 20 624 12-0ichloropropane lt2 19 (95 R) 20 (98 R) (3 RPO) 162012 ug1 0 bull 210 20 624
Bromodichloromethane lt2 19 (96 R) 20 (100 R) (4 RPO) 162012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 23 (115 R) 24 (121 R) (5 RPO) 162012 ug1 0 bull 305 20 624 4-Methyl-2-pentanone(MIBK) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
cis-13-Dichloropropene lt2 22 (109 R) 23 (113 R) (4 RPO) 162012 ug1 0 - 227 20 624
Toluene lt 1 20 (101 R) 21 (103 R) (2 RPD) 162012 ug1 47 bull 150 20 624 trans-13-0ichloropropene lt2 18 (90 R) 19 (93 R) (3 RPO) 162012 ug1 17 - 183 20 624 1 12-Trichloroethane lt2 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 52 bull 150 20 624 2-Hexanone lt 10 20 (R) 20 ( R) ( RPO) 162012 ug1 624 Tetrachloroethene lt2 20 (100 R) 21 (106 R) (6 RPO) 162012 ug1 64 bull 148 20 624 Oibromochloromethane lt2 20 (102 R) 21 (104 R) (2 RPO) 162012 ug1 53 - 149 20 624 Chlorobenzene lt2 20 (98 R) 20 (100 R) (2 RPO) 162012 ug1 37 bull 160 20 624 Ethylbenzene lt 1 20 (101 R) 21 (105 R) (4 RPO) 162012 ug1 37 - 162 20 624 mp-Xylene lt 1 40 (101 R) 43 (106 R) (5 RPO) 162012 ug1 70 bull 130 20 624 o-Xylene lt 1 21 (104R) 22 (109 R) (5 RPO) 162012 ug1 70 - 130 20 624 Styrene lt 1 21 ( R) 22 ( R) ( RPO) 162012 ug1 624 Bromoform lt2 18 (88 R) 18 (90 R) (2 RPO) 162012 ug1 45 - 169 20 624 1 122-Tetrachloroethane lt2 20 (99 R) 20 (100 R) (1 RPO) 162012 ug1 46 - 157 20 624 13-Dichlorobenzene lt 1 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 59 - 156 20 624 14-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 12-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 4-Bromofluorobenzene (surr) 100R 101 R 102 R 162012 Rec 70 - 130 624
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units limits RPO Method
12-Dichlorobenzene-d4 (surr) 93 R 90R 89R 162012 Rec 70-130 624
Toluene-dB (surr 100 R 102R 102 R 162012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 4
bull ~ LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512
Date Received 1512
Units ug1
Date of ExtractionPreparation 1612
Date of Analysis 1612
Analyst JMR
Method 625mod
Dilution Factor
Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol
Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1
lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol
46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1
lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane
13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1
lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether
Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1
lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
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QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
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rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysls Date Units Limits RPO Method - -shy--middot----shy-shy-shy- ---shy --shy--middot-
Chloromethane lt5 19 (97 R) 21 (105 R) (8 RPD) 162012 ug1 0 - 273 20 624
Vinyl chloride lt2 18 (91 R) 20 (101 R) (10 RPD) 162012 ug1 0 - 251 20 624
Bromomethane lt2 21 (105 R) 23 (113 R) (7 RPD) 162012 ug1 0 bull 242 20 624 Chloroethane lt5 19 (95 R) 20 (101 R) (6 RPO) 162012 ug1 14 - 230 20 624
T richloronuoromethane lt5 17 (84 R) 18 (88 R) (5 RPO) 162012 ug1 17 - 181 20 624
Acrolein lt 50 lt 50 (RNA) lt 50 ( R) ( RPO) 1162012 ug1 624
Acetone lt 50 lt 50 (78 R) lt 50 (90 R) (14 RPD) 1162012 ug1 624 1 1-Dichloroethene lt 1 17 (83 R) 18 (89 R) (7 RPO) 162012 ug1 0 - 234 20 624
Methylene chloride lt5 18 (88 R) 19 (93 R) (6 RPO) 162012 ug1 0 bull 221 20 624
Carbon disulfide lt5 17 ( R) 19 ( R) ( RPO) 162012 ug1 624
Acrylonitrile lt 50 lt 50 ( R) lt 50 ( R) ( RPO) 162012 ug1 624 Methyl-I-butyl ether(MTBE) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
trans-12-0ichloroethene lt 2 18 (89 R) 18 (92 R) (3 RPO) 162012 ug1 54 - 156 20 624
Vinyl acetate lt 10 30(R) 30 ( R) ( RPO) 162012 ug1 624 1 1-0ichloroethane lt2 19 (93 R) 20 (98 R) (5 RPD) 162012 ug1 59 shy 155 20 624
cis-12-0ichloroethene lt 2 19(R) 20 ( R) ( RPO) 162012 ug1 624
2-Butanone(MEK) lt 10 20(R) 20 ( ooR) ( RPO) 162012 ug1 624
Chloroform lt2 19 (94 R) 20 (99 R) (5 RPO) 162012 ug1 51 - 138 20 624
11 1-Trichloroethane lt2 18 (91 R) 19 (97 R) (6 RPO) 162012 ug1 52 bull 162 20 624
Carbon tetrachloride lt 2 18 (91 R) 19 (95 R) (4 RPO) 162012 ug1 70 - 140 20 624 Benzene lt 1 19 (97 R) 20 (102 R) (5 RPO) 162012 ug1 37 shy 151 20 624
12-0ichloroethane lt2 18 (91 R) 19 (94 R) (3 RPO) 162012 ug1 49 - 155 20 624 Trichloroethene lt2 19 (93 R) 20 (98 R) (5 RPO) 162012 ug1 71 bull 157 20 624 12-0ichloropropane lt2 19 (95 R) 20 (98 R) (3 RPO) 162012 ug1 0 bull 210 20 624
Bromodichloromethane lt2 19 (96 R) 20 (100 R) (4 RPO) 162012 ug1 35 - 155 20 624 2-Chloroethylvinylether lt2 23 (115 R) 24 (121 R) (5 RPO) 162012 ug1 0 bull 305 20 624 4-Methyl-2-pentanone(MIBK) lt 10 20 ( R) 20 ( R) ( RPO) 162012 ug1 624
cis-13-Dichloropropene lt2 22 (109 R) 23 (113 R) (4 RPO) 162012 ug1 0 - 227 20 624
Toluene lt 1 20 (101 R) 21 (103 R) (2 RPD) 162012 ug1 47 bull 150 20 624 trans-13-0ichloropropene lt2 18 (90 R) 19 (93 R) (3 RPO) 162012 ug1 17 - 183 20 624 1 12-Trichloroethane lt2 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 52 bull 150 20 624 2-Hexanone lt 10 20 (R) 20 ( R) ( RPO) 162012 ug1 624 Tetrachloroethene lt2 20 (100 R) 21 (106 R) (6 RPO) 162012 ug1 64 bull 148 20 624 Oibromochloromethane lt2 20 (102 R) 21 (104 R) (2 RPO) 162012 ug1 53 - 149 20 624 Chlorobenzene lt2 20 (98 R) 20 (100 R) (2 RPO) 162012 ug1 37 bull 160 20 624 Ethylbenzene lt 1 20 (101 R) 21 (105 R) (4 RPO) 162012 ug1 37 - 162 20 624 mp-Xylene lt 1 40 (101 R) 43 (106 R) (5 RPO) 162012 ug1 70 bull 130 20 624 o-Xylene lt 1 21 (104R) 22 (109 R) (5 RPO) 162012 ug1 70 - 130 20 624 Styrene lt 1 21 ( R) 22 ( R) ( RPO) 162012 ug1 624 Bromoform lt2 18 (88 R) 18 (90 R) (2 RPO) 162012 ug1 45 - 169 20 624 1 122-Tetrachloroethane lt2 20 (99 R) 20 (100 R) (1 RPO) 162012 ug1 46 - 157 20 624 13-Dichlorobenzene lt 1 20 (100 R) 21 (104 R) (4 RPO) 162012 ug1 59 - 156 20 624 14-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 12-Dichlorobenzene lt 1 20 (98 R) 20 (102 R) (4 RPO) 162012 ug1 18 - 190 20 624 4-Bromofluorobenzene (surr) 100R 101 R 102 R 162012 Rec 70 - 130 624
eastern analytical inc wwweailabscom Phone (603) 228-0525 3
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units limits RPO Method
12-Dichlorobenzene-d4 (surr) 93 R 90R 89R 162012 Rec 70-130 624
Toluene-dB (surr 100 R 102R 102 R 162012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 4
bull ~ LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512
Date Received 1512
Units ug1
Date of ExtractionPreparation 1612
Date of Analysis 1612
Analyst JMR
Method 625mod
Dilution Factor
Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol
Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1
lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol
46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1
lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane
13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1
lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether
Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1
lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
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3 MEOH VIAL SAMPLE ID
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IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
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bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
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WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
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MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
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(~ All A~d) ib FGgt sJ c~tlio((
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eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units limits RPO Method
12-Dichlorobenzene-d4 (surr) 93 R 90R 89R 162012 Rec 70-130 624
Toluene-dB (surr 100 R 102R 102 R 162012 Rec 70 - 130 624
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweailabscom Phone (603) 228-0525 4
bull ~ LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512
Date Received 1512
Units ug1
Date of ExtractionPreparation 1612
Date of Analysis 1612
Analyst JMR
Method 625mod
Dilution Factor
Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol
Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1
lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol
46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1
lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane
13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1
lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether
Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1
lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
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3 MEOH VIAL SAMPLE ID
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IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
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WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
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ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
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MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
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eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
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bull ~ LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
-- ______ ___ - - -- -middotmiddot ----~ - middotmiddotmiddot
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512
Date Received 1512
Units ug1
Date of ExtractionPreparation 1612
Date of Analysis 1612
Analyst JMR
Method 625mod
Dilution Factor
Phenol lt 1 lt 12-Chlorophenol lt 124-Dichlorophenol lt 1245-Trichlorophenol lt 1246-Trichlorophenol
Pentachlorophenol lt5 2-Nitrophenol lt 1 4-Nitrophenol lt5 24-0initrophenol lt5 2-Methylphenol lt 1
lt 134-Methylphenol lt 124-Dimethylphenol lt 14-Chloro-3-methylphenol
46-Qinitro-2-methylphenol lt5 Benzoic Acid lt 50 N-Nitrosodimethylamine lt 1 n-Nitroso-di-n-propylamine lt 1 n-Nitrosodiphenylamine lt 1
lt 1bis(2-Chloroethyl)ether lt 1bis(2-chloroisopropyl)ether lt 1bis(2-Chloroethoxy)methane
13-Dichlorobenzene lt 1 14-Dichlorobenzene lt 1 12-Dichlorobenzene lt 1 124-Trichlorobenzene lt 1 2-Chloronaphthalene lt 1
lt 14-Chlorophenyl-phenylether lt 14-Bromophenyl-phenylether
Hexachloroethane lt 1 Hexachlorobutadiene lt 1 Hexachlorocyclopentadiene lt5 Hexachlorobenzene lt 1 4-Chloroaniline lt 1 2-Nitroaniline lt5 3-Nitroaniline lt 1 4-Nitroaniline lt 1 Benzyl alcohol lt5 Nitrobenzene lt 1 lsophorone lt 1 24-0initrotoluene lt 1
lt 126-Dinitrotoluene Benzidine (estimated) lt5 33-Dichlorobenzidine lt 1 Pyridine lt5 Azobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 5
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
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3 MEOH VIAL SAMPLE ID
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IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
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WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
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MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
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eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
ltmiddotbull lt
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1 512
Date Received 1512
Units ug1
Date of Ext ractionPreparation 1 612
Date of Analysis 1612
Analyst JMR
Method 625mod
1Dilut ion Factor Carbazole lt 1
Oi-n-butylphthafate lt5
Phenol--06 surr) 24R
Dimethylphthalate lt 1 Diethylphthalate lt 1
Butylbenzylphthalate lt 1 bis2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Dibenzofuran lt 1 Naphthalene lt 1
lt 12-Methylnaphthalene Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo(a)anthracene lt 1 Chrysene lt 1 Benzo[b)fluoranthene lt 1 Benzo(k)fluoranthene lt 1 Benzo[a)pyrene lt 1
lt 1lndeno[123-cd)pyrene Dibenz(ah)anthracene lt 1 Benzo[ghi)perylene lt 1 2-Fluorophenol surr) 33 R
90R246-Tribromophenol surr) 71 R Nitrobenzene-05 surr) 72R2-Fluorobiphenyl (surr)
p-Terphenyl-014 (surr) 84R
eastern analytical inc wwweailabscom Phone (603) 228-0525 6
QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
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eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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QC REPORT EAi 10 106677I
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
LCS LCSO Analysis Date Units Limits RPO MethodParameter Name Blank
lt 1 14 (27 R) 14 (29 R) (7 RPO) 152012 ug1 15 - 130 20 625modPl1enol lt 1 29 (59 R) 30 (60 R) (2 RPO) 152012 ug1 30 - 130 20 625mod2-Chlorophenol lt 1 35 (70 R) 36 (72 R) (3 RPO) 152012 ug1 30- 130 20 625mod2 4-0ichlorophenol lt 1 18 (72 R) 19 (75 R) (4 RPO) 152012 ug1 30 - 130 20 625mod245-Trichlorophenol lt 1 34 (68 R) 36 (71 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod246-Trichlorophenol
39 (78 R) (14 RPO) 152012 ug1 30 - 130 20 625modPentachlorophenol lt5 34 (68 R)
lt 1 35 (70 R) 37 (73 R) (4 RPO) 152012 ug1 30 bull 130 20 625mod2-Nitrophenol lt5 16 (32 R) 17 (35 R) (9 RPO) 152012 ug1 15 - 130 20 625mod4-Nitrophenol lt 5 38 (75 R) 40 (81 R) (8 RPO) 152012 ug1 15 bull 130 20 625mod24-Dinitrophenol lt 1 15 (61 R) 16 (64 R) (5 RPO) 152012 ug1 30 - 130 20 625mod2-Methylphenol lt 1 13 (53 R) 14 (54 R) (2 RPO) 152012 ug1 30 - 130 20 625mod34-Methylphenol lt 1 33 (66 R) 34 (67 R) (2 RPO) 152012 ug1 30 - 130 20 625mod24-Dimethylphenol lt 1 36 (73 R) 36 (73 R) (0 RPO) 152012 ug1 30 - 130 20 625mod4-Chloro-3-methylphenol
152012 ug1 30 - 130 20 625mod4 6-0inilro-2-methylphenol lt5 39 (77 R) 41 (81 R) (5 RPO)
lt 50 (31 R) lt 50 (34 R) (9 RPO) 152012 ug1 15 bull 140 20 625modBenzoic Acid lt 50 12 (47 R) (2 RPO) 152012 ug1 40 - 140 20 625modN-Nitrosodimethylamine lt 1 12 (46 R)
lt 1 17 (67 R) 17 (69 R) (3 RPO) 152012 ug1 40 - 140 20 625modn-Nitroso-di-n-propylamine 23 (90 R) (0 RPO) 152012 ug1 40 - 140 20 625modn-Nitrosodlphenylamine lt 1 22 (90 R)
16 (64 R) (2 RPO) 152012 ug1 40 - 140 20 625modbis(2-Chloroethyl)elher lt 1 16 (63 R)
lt 1 15 (61 R) 15 (62 R) (2 RPO) 152012 ug1 40 bull 140 20 625modbis(2-ch loroisopropyl)ether lt 1 17 (69R) 18 (70 R) (1 RPO) 152012 ug1 40-140 20 625modbis(2-Chloroethoxy)methane lt 1 13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod13-0ichlorobenzene
13 (52 R) 13 (52 R) (0 RPO) 152012 ug1 40 - 140 20 625mod14-Dichlorobenzene lt 1
lt 1 14 (54 R) 14 (55 R) (2 RPD) 152012 ug1 40 - 140 20 625mod12-Dichlorobenzene lt 1 14 (57 R) 14 (58 R) (2 RPO) 152012 ug1 40 bull 140 20 625mod1 2 4-Tr ichlorobenzene
16 (65 R) (3 RPO) 152012 ug1 40 - 140 20 625mod2-Chloronaphthalene lt 1 16 (63 R)
18 (72 R) (1 RPO) 152012 ug1 40 - 140 20 625mod4-Chlorophenyl-phenylether lt 1 18 (71 R)
lt1 19 (75 R) 19 (75 R) (0 RPD) 152012 ug1 40 - 140 20 625mod4-Bromophenyl-phenylether lt 1 11 (43 R) 11 (43 R) (0 RPO) 152012 ug1 40 - 140 20 625modHexachloroethane lt 1 10 (40 R) 10 (42 R) (5 RPD) 152012 ug1 40- 140 20 625modHexachlorobutadiene
Hexachlorocyclopentadiene lt5 bull 9 (37 R) 10 (41 R) (10 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 19 (78 R) (7 RPO) 152012 ug1 40 - 140 20 625modHexachlorobenzene lt 1 20 (80 R) 20 (80 R) (0 RPO) 152012 ug1 15 - 140 20 625mod4-Chloroaniline
2-Nitroaniline lt5 17 (67 R) 18 (71 R) (6 RPO) 152012 ug1 40 - 140 20 625mod
19 (76 ooR) (4 RPO) 152012 ug1 40 - 140 20 625mod3-Nitroanlline lt 1 18 (73 R)
lt 1 18 (73 R) 19 (77 R) (5 RPO) 152012 ug1 40 -140 20 625mod4-Nitroaniline lt5 16 (65 R) 17 (67 ooR) (3 RPO) 152012 ug1 40- 140 20 625modBenzyl alcohol lt 1 16 (65 R) 17 (68 R) (5 RPO) 152012 ug1 40 - 140 20 625modNitrobenzene
lsophorone lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
21 (85 R) (5 RPO) 152012 ug1 40 - 140 20 625mod24-Dinitrotoluene lt 1 20 (81 R)
lt 1 19 (75 R) 20 (79 R) (5 RPO) 152012 ug1 40 - 140 20 625mod26-0initrotoluene
Benzidine (estimated) lt5 23 (92 R) 20 (81 R) (13 RPO) 152012 ug1 15 - 168 20 625mod
ug1 40 -140 20 625mod33-0ichlorobenzidine lt 1 19 (75 R) 19 (76 ooR) (1 RPO) 152012
Pyridine lt5 11 (45 R) 11 (46 ooR) (2 RPO) 152012 ug1 40- 140 20 625mod
18 (71 R) 18 (71 Rl (0 RPO) 152012 uQ1 40-140 20 625modAzobenzene lt 1
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
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Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
QC REPORT EAi ID 106677
Batch ID 734507-32510A010512E6251Client Northeast Utilities
Client Designation Merrimack Station
Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method ---middotmiddotmiddot-------middot------------- ------- ------- - - ---middot-- ---- - --- --- ----- --------------middot-
Carbazole lt 1 20 (79 R) 20 (81 R) (3 RPO) 152012 ug1 40 - 140 20 625mod
lt 1 18 (73 R) 18 (74 R) (1 RPO) 152012 ug1 40 - 140 20 625modDimethylphthalate
Diethylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 - 140 20 625modDi-n-butylphthalate lt 5 19 (77 R) 19 (76 R) (1 RPO)
Butylbenzylphthalate lt 1 19 (76 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
bis(2-Ethylhexyl)phthalate lt5 19 (76 R) 19 (76 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
152012 ug1 40 bull 140 20 625modDi-n-octylphthalate lt 1 18 (73 R) 19 (75 R) (3 RPO)
Dibenzofuran lt 1 16 (66 R) 17 (67 R) (2 RPO) 152012 ug1 40 - 140 20 625mod
Naphthalene lt 1 17 (67 R) 17 (67 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
2-Methylnaphthalene lt 1 16 (62 R) 16 (62 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Acenaphthylene lt 1 16 (63 R) 16 (65 R) (3 RPO) 152012 ug1 40 bull 140 20 625mod
Acenaphthene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
Fluorene lt 1 17 (70 R) 18 (71 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (74 R) 19 (76 R) (3 RPO) 152012 ug1 40 bull 140 20 625modPhenanthrene
Anthracene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 - 140 20 625mod
Fluoranthene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 18 (73 R) 18 (73 R) (0 RPO) 152012 ug1 40 bull 140 20 625modPyrene
Benzo[aanthracene lt 1 19 (75 R) 19 (76 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
Chrysene lt 1 19 (77 R) 19 (77 R) (0 RPO) 152012 ug1 40 bull 140 20 625mod
lt 1 19 (75 R) 19 (77 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[bfluoranthene lt 1 19 (77 ooR) 20 (79 R) (3 RPO) 152012 ug1 40 - 140 20 625modBenzo[k]fluoranthene
Benzo[a)pyrene lt 1 19 (76 ooR) 19 (77 R) (1 RPO) 152012 ug1 40 bull 140 20 625mod
lndeno(1 2 3-cd)pyrene lt 1 19 (78 R) 19 (77 R) (1 RPO) 152012 ug1 40 - 140 20 625mod
19 (77 R) (4 RPO) 152012 ug1 40 - 140 20 625modOibenz[ahjanthracene lt 1 20 (80 ooR) ug1 40 bull 140 20 625modBenzo[ghi)perylene lt 1 20 (79 ooR) 19 (77 R) (3 RPO) 152012
39R 39R 152012 Rec 21 -110 20 625mod2-Fluorophenol (surr) 39 R
28R 29R 152012 Rec 15 - 94 20 625modPhenol-d6 (surr) 28R 152012 Rec 15 - 110 20 625mod246-Tribromophenol (surr) 76R 92R 82R
76R 75R 77R 152012 Rec 35 middot 114 20 625modNitrobenzene-05 (surr)
2-Fluorobiphenyl (surr) 77R 73R 75 R 152012 Rec 43 - 116 20 625mod
33 - 130 20 625modp-Terphenyl-014 (surr) 89R 95 R 90R 152012 Rec
shy
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits
Hexachlorocyclopentadiene exhibited recovery below acceptance limits in the LCS Hexachlorocyclopentadiene was not detected in the sample
J eastern analytical inc wwweailabscom Phone (603) 228-0525 8
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
Oil amp Grease (HEM)
Treat Tank Eff Grab
10667702
aqueous
151 2
t 512
mgL
1912
191 2
LAS
1664A
lt5
eastern analytical inc wwweailabscom Phone (603) 228-0525 9
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
QC REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Analysls Date Units Limits RPO MethodParameter Name Blank LCS LCSD
lt5 37 (93 R) 33 (82 R) (13 RPD 192012 mgL 78 - 114 18 1664A Oil amp Grease (HEM)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below
eastern analytical inc wwweaiabscom Phone (603) 228-0525 10
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
LABORATORY REPORT
Client Northeast Utilities
Client Designation Merrimack Station
EAi ID 106677
Sample ID
Lab Sample ID
Matrix
Date Sampled Date Received
Units
Date of ExtractionPrep
Date of Analysis
Analyst
Method
Dilution Factor
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260 TMX (surr)
DCB (surr)
T reat Tank EH Grab
10667702
aqueous
1512 1512
ug1
1612
1612
JW
608
lt 03
lt 03 lt03
lt 03
lt 03
lt 03 lt 03
81 R 96R
eastern analytical inc wwweailabscom Phone (603) 228-0525 11
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
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r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
QC REPORT EAi ID 106677
Client Northeast Utilities Batch ID 734508-43146A010612E608P1
Client Designation Merrimack Station
Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method --- - - ---- -middot------ -------- -middot--middot-middot middot ---- - ----middot-------------------middot--shymiddot-middotmiddotmiddot---middot middot-------- -- middotmiddot ---------middotmiddot-- - middot- ----middot-middot middot--shy
PCB-1016 lt 03 20 (101 R) 21 (106 R) (5 RPO) 162012 ug1 40 - 140 20 608
PCB-1221 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1232 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1242 lt 03 lt 0 3 (R NIA) lt 03 (R NIA) (RPO NIA) 1162012 ugll 608
PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NIA) (RPO NIA) 162012 ug1 608
PCB-1254 lt 03 lt 03 (RNA) lt 03 (R NA (RPO NA) 162012 ug1 608
PCB-1260 lt 03 20 (102 R) 21 (105 R) (3 RPO) 162012 ug1 40 - 140 20 608
162012 Rec 30 - 150 608TMX (surr) 84 R 88R 90R
95R 101 R 100R 162012 Rec 30 - 150 608DCB (surr)
Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted middott Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 12
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
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3 MEOH VIAL SAMPLE ID
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IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
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WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
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(~ All A~d) ib FGgt sJ c~tlio((
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eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
LABORATORY REPORT EAi ID 106677
Client Northeast Utilities
Client Designation Merrimack Station
Sample ID Treat Tank Eff Composite
Lab Sample ID 10667701
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1512 Units Date Time Method Analyst
Solids Suspended 14 mgL 011012 1540 2540D DLS Solids Dissolved 21000 mgL 011112 1315 2540C DLS Fluoride 10 mgL 011112 1123 3000 KL Sulfate 1200 mgL 011112 1123 3000 Kl Chloride 11000 mgL 011012 1217 4500CIE DLS Nilrale-N 100 mgl 010612 1257 3532 DLS Alkalinity Total (CaC03) 180 mgL 011112 940 23208 SEL Ammonia-N 092 mgL 011012 8304500NH30 SEL BOD lt6 mgL 010612 1405 smiddot2f0B SKC COD 130 mgL 011212 1020 H8000 SKC pH 73 SU 010512 15 10 4500H+B NZ
Sample ID Treat Tank Eff Grab
Lab Sample ID 10667702
Matrix aqueous
Date Sampled 1512 Analysis Date Received 1 512 Units Date Time Method Analyst
Cyanide Total 002 mgL 011112 845 4500CNE KJR Sulfide lt 01 mgL 011112 13208131HACH KJR Sulfite lt 2 mgL 010512 1730 377 1 Jl Total Residual Chlorine lt 005 mgL 010512 1650 4500CIG NZ Total Phenols lt 03 mgL 010912 900 4201 JGC
Total Phenols The reporting limit for Total Phenols has been elevated due to matrix interferences
eastern analytical inc wwweailabscom Phone (603) 228-0525 13
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
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IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
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bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
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r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
QC REPORT EAi ID 106677bull ~ Client Northeast Utilities
Client Designation Merrimack Station
Date of
Parameter Name Blank LCS LCSD Units Analysis Limits RPO Method
Solids Suspended lt 5 90 (90 R) 93 (93 R) (3 RPO) mgL 11012 90 - 110 20 2540U
Solids Dissolved lt5 970 (97 R) NA mgL 11112 85 - 115 2540C
Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPO) mgL 11112 90 - 110 20 3000
Sulfate lt 1 21 (106 R) 21 (103 R) (3 RPO) mgL 11112 90 - 110 20 3000
Chloride lt 1 26 (103 R) 26 (103 R) (0 RPO) mgL 11012 90 - 110 20 4500CIE
Nitrate-N lt 005 53 (106 R) 53 (106 R) (0 RPO) mgL 1612 90 - 110 20 3532
Alkalinity Total (CaC03) lt 1 10 (99 R) 10 (100 R) (1 RPO) mgL 11112 85 - 115 20 2320B
Cyanide Total lt 002 027 (106 R) 023 (91 R) (15 RPO) mgtl 11112 85 - 115 20 4500CNE
Ammonia-N lt 005 20 (100 R) 21 (105 R) (5 RPO) mgL 11012 90 - 110 20 4500NH30N
Sulfide lt 01 04 (98 R) 04 (90 R) (9 RPO) mgL 11112 80 - 120 20 8131HACH
Sulfite lt2 NA NA mgL 1512 3771
Total Residual Chlorine lt 005 088 (101 R) 087 (100 R) (1 RPO) mgL 1512 80 - 120 20 4500CIG
BOD lt6 430 (109 R) 390 (97 R) (12 RPO) mgL 1612 84 bull 115 20 52106
COD lt 10 100 (101 R) 100 (98 R) (3 RPO) mgL 11212 85 - 115 20 H8000
Total Phenols lt 005 028 (112 R) 027 (106 R) (6 RPO) mgL 1 912 85 - 115 20 4201
pH 60 (101 R) 605 (101 R) (0 RPO) SU 1512 595 bull 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 14
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
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PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
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ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
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METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
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rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
QC REPORT EAi 10 1066774
l1LAAI Client Northeast Utilities
Client Designation Merrimack Station
Duplicate Duplicate Date of Parameter Name Parent ID Parent Duplicate Units Analysis RPO Method
Solids Suspended 10669203 180 160 (13 RPO) mgL 11012 20 25400 Solids Dissolved NA NA mgL 111 12 2540C Fluoride NA NA mgL 11112 20 3000 Sulfate NA NA mgL 11112 20 3000 Chloride NA NA mgL 11012 20 4500CIE Nitrate-N NA NA mgll 1612 20 3532 Alkalinity Total (CaC03) NA NA mgL 11112 20 23208 Cyanide Total NA NA mgL 11112 20 4500CNE Ammonia-N 10662702 13 13 (2 RPO) mgL 11012 20 4500NH3D Sulfide NA NA mgL 11112 20 8131HACH Sulfite 10667702 lt 2 lt 2 (RPD NIA) mgL 1512 20 3771 Total Residual Chlorine NA NA mgL 1 512 20 4500CIG BOD 10665702 410 400 (3 RPO) mgL 1 612 20 52108 COD NA NA mgL 11212 20 H8000 Total Phenols NA NA mgL 1912 20 4201 pH 10664901 63 63 (0 RPD) SU 1 512 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweailabscom Phone (603) 228-0525 15
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
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-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
QC REPORT EAi 10 106677 IMAI Client Northeast Utilities
C lient Designation Merrimack Station
MSMSD MSMSD Date of
Parameter Name Parent ID Parent Matrix Spike MSD Units Analysts Limits RPD Method
Solids Suspended NA NA NA mgll 110112 20 25400
Solids Dissolved NA NA NA rngL 1111112 2540C
Fluoride NA NA NA mgll 111112 20 3000
Sulfate NA NA NA mgll 111112 20 3000
Chloride 10663202 11 22 (110 R) 22 (109 R) (1 RPO) mgll 111012 80-120 20 4500CIE
Nitrate-N 10667801 12 12 (110 R) 12(109R)(1 RPO) rngL 116112 80-120 20 3532
Alkalinity Total (CaC03) 10660701 29 48 (98 R) NA mgll 111 111 2 80shy 120 20 23208
Cyanide Total 10667702 002 025 (93 R) 023 (86 R) (8 RPO) mgL 111112 75-125 20 4500CNE
Amrnonia-N 10662702 13 16 (115 R) 15 (85 R) (30 RPO) mgll 1110112 80-120 20 4500NH3
Sulfide NA NA NA mgL 1111112 20 8131HAC
Sulfite NA NA NA mgL 11512 3771
Total Residual Chlorine NA NA NA mgL 1512 20 4500CIG
BOD 10665702 410 760 (82 R) NA mgL 16112 75-125 20 52108
COD 10667701 130 220 (92 R) 230 (99 R) (7 RPO) mgll 11212 80shy 120 20 H8000
Total Phenols 10667702 lt 03 04 (42 R) 04 (42 R) (133 RPO) rngL 1912 80-120 20 4201
pH NA NA NA SU 15112 10 4500H+B
Total Phenols The MS and MSD recoveries were below acceptance criteria even when the parent sample was diltuted indicating a matrix
interference
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bullf Flagged analyte recoveries deviated from the QAQC limits
eastern analytical inc wwweaiabscom Phone (603) 228-0525 16
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
~ 414 Pontius Ave North Scatt le WA 98 I09Ph 206-6V-6960 Fx 206-622-6870 GLOBAL SCIENCES
I I January 2012
Jeff Gagne
Eastern Jnalytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station
Enclosed arc the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered
with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this rcpo11 please feel free to contact me
Sincerely
Liz Siska
Project Manager
17
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
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bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
~ FRONTIER
GLOBAL SCIENC E S
414 Pontius Ave North Seattle WA 98109 Ph 2 OCi-622-60
Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory
Client
Frontier (ilobal_ Sciences_Inc
Eastern Anilitical)m
SDG
PrnjltmiddotltmiddotI Merrimack Slation
Sample ID Lah ID Matrix Date Samolcd Date Received
Treat Tank Eff Composite 1201073-0 1 Water 05-Jan- I 2 I 000 06-Jan- I 2 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan- l2 0800 06-Jan- I 2 0950
The results in this report onl_y apply to the samples analyzed in accordance with thechain ofcustody document This analytical reporl must be reproducedin its entirety
Frontier Global Sciences Inc
Liz Siska Project Manager
Pagel o26 1201073 Final Report
OlJl2012
18
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
414 Pontius Ave Nor1h Seattle WA 98109 lh 206-622-60-~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received al Fnmticr (ilohal Sciences (FGS on January 6th 2012 The samples were received intact on-ice with temperatures 111casured at 34 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and aualyzed for tolal metals in accordance with FGS-05-1EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method I631 E
ANALYTICAL AND QUALITY CONTROL ISSUES
There were no analylical diflicultics expcrienced with analysis of these samples with the exceptions flagged in the report
Frontier Global Sciences Inc
Liz Siska Project Manager
The resulls in 1his report only apply to the samples analyzed in accordance wlrh tire chain ofcustody document This analytical report must be reproduced in its emirety
Page2 o26 20073 Final Report
OJIJJ2012
19
1 ~bullbull bull bull bull bull bull
-middot bull
~ bull~middot1middot~middotr S ~1 rmiddot-nc -iri r-- middot11middotmiddot 1 middot -dmiddot1middot~11~r ( CUtr ~middotmiddotr_~
middot--middot middotmiddot- middotmiddotmiddotmiddotshy -- _ -middot-- ~---shy ---~-middotshy
- - --shy ~-- -
- ---middotshy ~ middot-middot middotshy -~ middotmiddot-middotmiddot shy I---~-~----middot---- shy middot
middot---middot--middot-- ----middot-middotmiddot --middot-middotmiddot middot------middotmiddot 1----middot--
- -- -1
~J middotmiddot h middot 1 C ~
-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
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rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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-
Frontier Global Sciences Inc The results in this rchai11 ofcustody do
eport only apply to the sacument This ana1ica re
mples analyzed in accordance with the port must be reproduced in its entirety
Liz Siska Project Manager
114 11111 i11s vc N1r1h Scatt le W 98109~~ lh 206-622-60
FRONTIER Fx 206-622-6870 CLUBAL ~C I ENC ( S
CHAIN OF CUSTODY FORMS
shyshy
Page 3 o26 I 201073 Final Report
OJ1112012
20
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
4 14 Pontius Avlt North Scatk WA 9X I 09 Ph 206-622-6960
~ Fx 206-622-6870 GLOllAL SCIENCl$
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix W)Cf Lihorntory ILgt lWl07 l-Ol
Analylc lhsult MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
A Juminum 411 22 200 microgL 5 F201062 2A 10002 010912 FGS-054
Antimony 0520 0023 0 100 11gL 5 F201062 2 10002 0 I 0912 F(iS-054
Barium 300 014 100 microgL 5 F201062 2A 10002 01 091 2 FGS-054
Beryllium 0522 0 114 0300 microgL 5 F201062 2A 10002 0109)2 FGS-054
Cadmium 0207 0021 0100 microgL 5 F201062 2Al0002 010()12 FGS-054
Calcium 5050000 16200 200000 Jtg1 5000 F201077 2 JOO 15 O I I 012 FltS-054
Chromium ND 004 050 microg1 5 F201062 2Al0002 0I 09 I2 FGS-054 u Copper ND 005 050 microgL 5 F201062 2 10002 010912 FUS-054 u Iron ND 65 500 microgL 5 F201062 2Al0002 010912 FGS-054 u Lead ND 0020 0200 microgL 5 F201 062 2Al0002 0I 0912 FGS-054 u Manganese 293 074 100 microgL 100 l-201062 2A I0002 0109 12 FGS-054
Molybdenum )40 00] 030 11gl 5 F201062 2A 10002 010912 FGS-054
Nickel t03 004 050 microgL 5 F201062 2110002 010912 FGS-054
Silver ND 0030 0100 microgL 5 F201062 2AJ0002 010912 FGS-054 u Sodium 277000 115 2000 microgL 100 r-201062 2AJ0002 00912 rGS-054
Thallium 664 0006 0025 microgL 5 F201062 2AI0002 OI0912 FGS-054 QB-OJ Zinc ND 008 100 11gL 5 F201062 2110002 0 I 0912 FGS-054 u
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordilnce with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 4 o26 I20073 Final Report
OJl 12012
21
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
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bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
-114 lonti11s vc North Slmiddotattk W 98109
~ Ph 206-lt7J-(960 t Fx 206-622-6870
GLOBAL SC IENC ES
ANALYTICAL RESULTS
Treat Tm1k Eff Grab
L1boratory ID 120 I073-02 Matrix W[t_er
Anilyte Result MDL MRL Units Dilution Batch Scq111nce Anilycd Method Notes
Arstbullnic 498 102 300 11gL 20 F201062 2A 10015 011012 FGS-054
Mercury 105 034 2 02 ng1 4 F201063 2090 I 0 0 I 0912 EPA 163 lE FB-1631
Selenium 740 388 120 pgL 20 F201062 2A 10015 01101 2 HjS-051
The results in this report only apply to the samples analyzed in accorda11ce with thechain ofcustody document Tls analytical report must be reproduced in its e111Jrety
Frontier Global Sciences Inc
Liz Siska Project Manager
Page 5 o26 1201073 Final Report
Olll2012
22
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
1 J1 10111ius A vc Norih Seattle W 98109~ lh 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX DUPLJCATESTIUPLICATES
SOURCE I 201073-02
Batch F201063 Sc1ucncc ]Alt)2SJll
Preparation rCI O[ idition Lab Number F201061 DUI
Sample Duplicate Concentration Concentration Yo RPD
Analyte ugL ngL MRL RPO Limit Method Noles
Mercury 1048 1054 202 0617 24 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyed i11 accorda11ce with the chain ofcustody document This allOytical report must be reproduced in Its entirety
Page 6of26 1201073 Final Report
Ollll2012
23
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
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Q ~ - ~ ~ 0 Q ~~
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3 MEOH VIAL SAMPLE ID
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IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
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bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
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I
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r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
414 Pontius vc Nonh Scank WA 98109
- ~ Ill olt-ltin -60 FRONTIER Fx 206-622-CJrO
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DlJPLlCATE RECOVERY AND RPD
SOURCE 120middot1073-01
Batch F20106_f Sequence 2Al0002
Pre pa ration Closed Vessel Nitric Oven Digpoundslion Lab Number 1720 I 062-MSMSl21
Anilyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Kccovcry
Limits Method Notes
Beryllium 0522 20200 2676 107 75 shy 135 FGS-054
Aluminum 411 15150 2 107 11 2 80 shy 11 5 FGS-054
Chromium 047 70700 859 115 85 - 115 FGS-054
Iron ND 50500 5636 11 2 75 - 125 FGS-054
Nickel 803 40400 1198 977 68 shy 134 FGS-054
Copper 029 40400 400 918 51 - 145 FGS-054
Zinc 027 I0100 910 874 46 - 146 FGS-054
Arsenic 532 15 150 22 17 111 85 shy 11 5 FGS-054
Selenium 7173 30300 1006 95J 59 shy 149 FGS-054
Molybdenum 1403 20200 142 1 888 80 - 11 5 FGS-054
Silver ND 15150 1216 803 74 shy 119 FGS-054
Cadmium 0207 080800 1076 IU8 84 shy 11 3 FGS-054
Antimony 0520 080800 1360 104 79 shy 122 FGS-054
Bariwn 3000 10100 3050 498 80 shy 120 FGS-054 QM-02
Thallium 6645 040400 6882 587 64 - 137 FGS-054 QB-01 QM-02
Lead ND 15150 1635 108 72 shy 143 FGS-054
Analyte
Berylliwn
Spike Added (microgL)
MSD Cooce11tration
(microgL)
MSD
Recovery
1o RPD
Recovery Limits
RlD Limit Method Notes
20200 2639 105 139 75 - 135 20 FGS-054
Aluminum 15150 213 8 114 150 80 - 115 20 FGS-054
Chromium 70700 859 115 0061] 85 - 115 20 FGS-054
Iron 50500 5538 I 10 176 75-125 20 FGS-054
Nickel 40400 1220 103 183 68 - 134 20 FGS-054
Copper 40400 395 907 115 51 - 145 20 FGS-054
Zinc 10100 887 852 251 46- 146 20 FGS-054
Arsenic 15150 2281 115 284 85 - 115 20 FGS-054
Selenium 30300 1108 129 965 59 - 149 20 FGS-054
Molybdenum 20200 1435 159 0993 80 - 115 20 FGS-054 QM-02
Silver 15150 1226 810 0852 74 - 119 20 FGS-054
Cadmium 080800 0956 927 118 84 - 113 20 FGS-054
Frontier Global Sciences Inc
~
I ---lt1shy-~~-shy
Liz Siska Project Manager
The results in this report only apply to the samples anafy=ed in accordance with the chain ofcustody document This analytical report must be reproduced in its emirety
Page 7of26 I Z0073 Final Report
OIIIl2012
24
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
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bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
Frontier Global Sciences Inc The results in this reclain ofcustody docu
Liz Siska Project Manager
port only apply to lhe sme11t This analytical
amples analyzed in accordance with the report must be reproduced in its entirely
~
FRONTIER GLOBAL SCIENCES
41-1 Pontius vc North Seattle W 98109 Ph 206-lt72-60 Fx 206-622-6870
MATRIX SPIKE MATRIX SPIKE DUPLICATI RECOVERY ANU RPO
SOURCE 1201073-01
Hatch l-20 I 062 ScIUllllC 2 I 0002
Preparation Qoscd Vcssd Nitric Oven Ditbullcstion Lah Numhcr f 20 I 062-MSMSIgtI
Spike MSD MSD Added Concentration Yo Recovery RPO (microgL) (microgL) Analyte
RPIgt Recovery Limits Limit Mclhod Notes
Antimony 080800 J373 106 0924 79 shy 122 20 fGS-054 Barium 10100 3071 71 1 0703 RO - 120 20 FltS-054 QM-02 Thallium 040400 6918 676 0520 64 shy 137 20 FGS-054 QB-01 Lead 15150 1580 104 J44 72 shy 143 20 FGS-054
Page 8026 20073 FillOI Report
Olli112012
25
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
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Q ~ - ~ ~ 0 Q ~~
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3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
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bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
414 Ponti11s A vc North Scalllc- WA 9XI09
Ph 206-622-6960~ Fx 206-622-6S70 FRONTIERmiddot
CL06AL S C IENCES
MATRIX SPlKE MATR(X SPIKE DlJPLICATI~ RFCOVERY AND RPD
SOURCE 1201073-0lREI
Batch F20 I 0g Sequence 2A 10002
Preparation Closed Vessel Nitric Oven Digestion Lab Number F201062-M~MSD2
Sa mplc Spike MS MS Concentration Added Concentration lo Recovery
Analyte (JtgL) (ltgL) (agtL) Recovery Method Notes Limits
264500 -2560 75 shy 125 FUS-054 QM-02 Sodium 277400 50500
2871 -987 80 middot 120 FGS-054 QM-02 Manganese 293 1 6 0600
Spike MSD MSD o RPOAdded Concentration oo Recovery
RPIgt Limits Limit Mcthd Notes(microgL) (microgL) RecoveryAnalylc
- 1460 206 75 middot 125 20 f-GS-054 QM-02 Sodium 50500 270000 80 - 120 20 FGS-054 lt)M-02 Manganese 60600 2897 -553 o9n
Frontier Global Sciences Inc 17ie results in this report only apply to the samples analyzed i11 accordance witlt the chain ofcustody document This analytical report must be reproduced In its entirety
Page 9of26 201073 Final Report
Oll l 12012
26 Liz Siska Project Manager
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
4111nlius Avl Norlh
~ Scat1lc WA 98109bull Ph 206-622-6960
~TIE~~ Fx 206-622-6870 GLOBAL SCIENCES
MATRlX SPlKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01
Balch F201062 Scc1uc11cc 2A I 0002
Preparation Closed Vcssd Nilrilt Oven 1Jigcs1inn Lah Number f20 I 062-MSMSD1
Analytc
Bcrylli11111
Sample Concentration
(microgL)
0522
Spike Atlded JtgL)
10 100
MS Conccnlralion
(microgL)
10 96
MS Yo
Recomiddotcry
103
RccovClyLimits
75 shy 135
Mclhod
FltiS-054
Noles
AS Alttmin11111 4 1 I 20200 2 166 105 80 shy 115 FCiS-051 AS Chrorniu111 047 20200 2300 114 85 shy 11 5 FCiS-054 AS lrun ND 10100 1103 109 75 shy 125 F(iS-054 AS Nickel 803 25250 255 1 978 68 shy 131 FCiS-054 AS Copper 029 25250 2245 888 5 I - 145 F(S-051 AS Zinlt 027 50500 4227 X37 46 shy 146 FltiS-051 AS Arscnilt 532 20200 2350 11 4 85 - 11 5 F(iS-051 AS Selenium 71 73 20200 2872 107 59 - 149 FGS-054 AS Molybdenum 1403 101 00 2447 103 XO shy 11 5 F(iS-051 AS Silver ND 10100 8224 8111 74 shy 119 H iS-051 AS Cidmium 0207 20200 9 18 939 84 - 11 3 FGS-05t AS Antimony 0520 10100 l 116 105 79 - 122 FGS-05t AS 13ariurn 3000 t0400 7753 I 18 80 - 120 FCS-054 JS Thallium 6645 10100 I7tl6 107 64 - 137 FGS-054 AS QB-OJ Lead ND 50500 5195 103 72 shy 143 FGS-054 AS
Aoalyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPO
Recovery Limits
RPO Limit Metltod Notes
Beryllium 10100 1125 106 266 75 - 135 20 FGS-054 AS Aluminum 20200 2171 105 0234 80- 115 20 FGS-054 AS Chromium 20200 2313 I 14 0528 85 - I 15 20 FGS-054 AS Iron 10100 lll2 110 0802 75 - 125 20 FGS-054 AS Nickel 25250 2559 982 0346 68 - 134 20 FGS-054 AS Copper 25250 2255 892 0424 51 - 145 20 FGS-054 AS Zinc 50500 4255 842 0647 46 - 146 20 FGS-054 AS Arsenic 20200 2365 114 0629 85 - 115 20 FGS-054 AS Selenium 20200 2870 107 00540 59 - 149 20 FGS-054 AS Molybdenum IO 100 2467 105 0806 80- 115 20 FGS-054 AS Silver IOJOO 8290 82 l 0798 74 - 119 20 FGS-054 AS Cadmiwn 20200 1931 946 0670 84 - 113 20 FGS-054 AS Antimony IO 100 1131 07 129 79 - 122 20 FGS-054 AS
Frontier Global Sciences Inc
~ -__ - --lt1-lt--4-x-__~
Liz Siska Project Manager
The results in this report only apply to the samples anaf)Zedin accordance with tire chai11 ofcustody docume11r This analytical report must be reproduced in its entirety
Page Oo26 1201073 Final Report
0111112012
27
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
-11 middot1 Pontius Ave Nor1h Sc1ttlc WA 981 oltgt~lh 206-622-ltgt960bull Fx 206-622-lt870-~ONTIER~
GLOBAL SCIENCES
shy
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01
Batch J2P1Pigt1 Sequence 2-1JQOOf
Preparation Clo~cd Vcs~cl Nitric Oven Digcstion
Analytc
Barium
Srikc MSO Added Concentration (JlgL) (microgL)
MSIgt o
Recovery
bully RPO
Recovery Limits
RPOLimit Method Notes
40400 779amp 119 0575 80 middot 120 20 FCS-05middot1 AS
Thallium 10100 1756 108 0595 64 - 137 20 FGS-054 S QB-01
Lead 50500 52 16 )03 0399 72 - 143 20 FGS-054 AS
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to 1he samples analyzed ill accordance with the chain ofcustody docume111 This analy1cal report must be reproduced in its entirety
Page 11 of26 1201073 Final Reporl
011111201)
28
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
4 14 lon1ius Ave Nor1h Seattle WA 98 1Olt) ~--~ Ph 20(i-622-lti0 bull
FRONTIER b 206-622-6870 GLOBAL SCIENCES
MATRIX SPIK~2 MATRIX SPIKE DUPLICATE RECOVERY ANO RPO
SOURCE 1201073-0IRl~l
Scqucnctbull ~ tnool Prcparnlion
Analyle
Sodium
Closed Vc~scl Nilric Oven Di1eSlio11
Sample Concentration
(microgL)
277400
Spike Adclcd (microgL)
202000
Lah Numhcr
MS Cn11cc11tration
(microgL)
474400
F20 I 0lt2-
MS Oo
Recovery
975
MS MSD1
Rccovuy Limil-
75 - 125
Mclhod
FGS-054
Noles
AS Mingancsc
Analytc
Sodium
293 1
Spike Added (microgL)
202000
20200
MSO Concc11tration
(microgL)
480300
2
MSD Yo
Recovery
100
396
o RPO
125
104
Recovery Limits
75 - 125
80 120
RPD Limit
20
FGS-054
Method
FGS-051
AS
Notes
AS Manganese 20200 2405 105 0346 80 bull 120 20 FGS-054 AS
shy
The results in this report only apply 101he samples analyzed in accordance with the chain ofcustody document 771s analytical repomiddott mus be reproduced in its entir-ety
Page 12of26 1201073 Final Report
OIll2012
Frontier Global Sciences Inc
Liz Siska Project Manager 29
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
1~ 1-1 10111 ius Av No11h Scallk WA 9Kl09 ~ Ph 206-6t~-60
FRONTER- Fx 06-6E 6K70
cLoBAL SC I ENCES
MATRJX SPIKE MATRlX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-02
Sequence 2 A090(0 Balch F201063
lrcf)arntion BrCI Oxidation Lah Numhcr f20 I 063-MSMSD I
Sample Spike MS MS Concenlration uConcentration Atlded Rccocry
Analy1c (ngL) (ngL) (ngL) Recovery Mc1hod NotesLimils
Mercury I048 20400 3136 102 71 - 125 EPA 16J JE
Spike MSU MSLgt Yo Recovery RPOAdded Conccnt-alion
RPO Limits Limil Me1hod Notes(ngL) (ngL) RecoveryAnalytc
Mercury 20400 2708 8 ( 4 147 71 - 125 21 EPA 1631E
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 13 of26 20073 FinaReport
01112012
30
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
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3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
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r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
I
414 Pontius Ave North Scallk W 9XIOIJ
lh 206-622-6960 Fx 206-622-6870~~~~
GLO BA L SCIEN CES
MATIUX SPIKE MATRJX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Ualch 20 I 063 Set1mmiddotnce gt li)90 IQ
Jgtrcparltion Br() Oxidat ion Lah Number J20 I 063-MSMSm
Analyte
Sample Conccntrition
(ngL)
Spike Added (ngL)
MS Concc11tr1tion
(ngL)
MS o
Recovery Rltcomiddote ry
Limits Method Noles
Mcrcury
Analyte
761 20400 2786 992 71 - 125 EPJ 1631E
Spike Added (ng1)
MSD ltonccnlralion
(ngL)
MS D oo Yo
RPO Recovery
Recovery Limits
RPOLimit Meihod Notes
Mercury 20400 2837 102 182 71 - 125 2middot1 EPA 163 1 E
Frontier G lobal Sciences Inc
Liz Siska Project Manager
The r~ults in this report only apply to the samples analyzed in accordance with 1ie chain ofcustody document T71is analytical report must be reproduced in its emirety
Page 4of26 120073 Final Report
Ol112012
31
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
414 Pontius Ave North
~ Scat k WA 11810)
Ph 206-022middotltgt0
~RONTfER Fx 206-622-6870 GL OBAL SCIEN CES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPI)
SOlJRCE 1201029-01
Batch F20 I 063 Sequence 2A090 I 0
lrcpa ration 13rCI Oxidation Lah Number F201063-MSMSD3
Sample Spike MS MS Concentration Added Concentration Recovery
Analyte (ngL) (ngL) (ugL) Recovery Method Noles Limits
Mercury 534 I 0200 1558 JOO 71 - 125 EPA 1631E
Spike MSD MSD bully
Added Concentration f~ I Recovery RPORPIgt Limits Limit Method Noles(nglL) (ngL) RecoveryAnalyte
Mcrcmy 10200 1407 856 102 71 - 125 24 EPA 1631 E
The results in this report only apply to he samples a1UJyzed in accordance wi1h the chain ofcustody document This analytical report must be reproducedin its enlirery
Frontier Global Sciences Inc
_~-f A i ~middot _ -ltlt~-- ~
Liz Siska Project Manager
Page 15 o26 1101073 Final Reporl
011 12012
32
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
Frontier Global Sciences Inc
Liz Siska Project Manager
II
middot114 10111 iu~ ve Ntrth Scali le WA 98109~~ Ph 206-622-6960
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201030-02
Btlch _F20 I063 Sclt1ucncc 2 A090 l 0
Prept ralion BrCl Oxidation L1h Number t2J) I 063-M5fM~121
Sample Spike MS MS Conccntralion Added Conccnlra1ion Recovery
Analylc (ngL) (ngL) (ngL) Recovery Melhod NotesLimi1s
Mercury 551 10 200 11R2 910 71 - 125 EPA 16311
Spike MSD MSO Uo Recovery RI() Added ConcenIralion Yo
RPD Limit Umil Method Noles (ngL) (ngL) Recovery Analyle
Menuiy 10200 1461 890 140 71 - 125 24 EPA 163 IE
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its emirery
Page 16oj26 1201073 Final Report
0112012
33
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
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Q ~ - ~ ~ 0 Q ~~
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3 MEOH VIAL SAMPLE ID
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IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
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bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
Frontier Global Sciences Inc
Liz Siska Project Manager
middot11 4 lon1i11~ Av~middot North Sc111k WA C)ilOltJ lh 06-62-60
~ Fx 20ltH22middotltgtR7U GLOBAL SC I ENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOYtiRY AND lPD
SOURCE 1201073-01 RE2
Batch F201077 Scqucnc( 2A IOOl 5
Prcpan1tion Closed V csscl Nitric Ovc11_J)ig~t ion L1h Number F20 I077-MSMSD I
Sample Spike MS MS Concentration Added Concentration Oo Rccowry
Anily tc ltbullg1) (microJIL) ptJL) Recovery Method Notes Limits
Calcium 5052000 15150 5067000 IOIO 70 - 130 FGS-054 QM-02
Spike MS D MS D Recovery RPO Added Concentration 0o
rubullo Limits Limit Method Notes (microgL) (microJ1 ) Recovery Analytc
Calcium 15 150 5034000 - 1190 0660 70 - 130 20 FCS-0 51 QM-02
The rewits i11 this report on~middot apply to the samples analyzed in accordance wi1h the cltai11 ofcustody document This analytical report must be reproduced in its e111irety
Page 17 026 1201073 Final Report
Ol112012
34
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
1 J1 10111 ills A vc Nrn1h Scauk WA 98109 Ph 206-622-ltgt960 1)i 06-1gt)~-6((J
GLOBAL SCllNCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE2
Batch F20 1077 Sequence ]_A 100 15
Preparation qg~ccj_c~cl ~ it rii_C )_~_c_l_J ~poundtt_o_n Lab Nnmbtgtr F701 077-MSMSD2
Sample Spike MS MS Concentration Added Concentration o RecoveryAnalytc (11gL) (11gL) (11gL) Hccocry MllbmlLimits Notes
Calcium 5052000 10100000 15570000 104 70 - I JO FGS-051
Spike MSD MSD Oo Added Concentration Recovery RlD 0o
RPD Limits (ltgL) (11gL) Recovery Limit Method NolesAnalytc
Calcium 10100000 15550000 104 01 25 70 - 130 20 FCiS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This analytical report must be reproduced in its enlirety
Page 8of26 1201073 Final Report
0112012
35
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
Frontier Global Sciences Inc
Liz Siska Project Manager
41-1 Po111ius 1vc Nor1h s~a11k W1 ltgt8 10gt
Ph 206-622-lt0~ FRONT(ER Fx 206-622-6870 CL08 AL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 I062 Sequence 2A I0002
Pre pa ration JQ~QYc~cl Nitric Ovc1U)igpoundstjm1 Lab Number F201062-BSIBSD I
LCS Source Blank Spike
Spike LCS ICS Added Concentration o Recove ry
Analyfc C1gL) (microgL) Recovery Limits Mclhml Noles
DeryIlium 20000 2039 102 75 I5 FltiS-054
Sodium 50000 487 974 80 - 120 FGS-054 A luminurn 15000 1524 102 85 11 5 FGS-054
Calcium 15000 1550 103 80 - 120 FGS-054
Chromium 70000 682 974 85 11 5 FGS-051
Manganese 60000 603 IOI RS - 11 5 FGS-054
Iron 50000 4815 963 80 middot 120 FGS-054
Nickel 40000 406 102 68 middot 134 FGS-054
Copper 40000 4 15 104 5 1 - 145 FGS-054
Zinc 10000 10 16 102 46- 146 FGS-054
Arsenic 15000 1538 103 85 115 FGS-05J
Selenium 30000 3 150 105 59 middot 149 FGS-054
Molybdenum 20000 197 983 85 middot 115 FGS-054
Silver 15000 1569 105 74 middot 119 FGS-054
Cadmium 080000 0850 106 84 middot 11 3 FGS-054
Antimony 080000 0866 108 79 middot 122 FGS-054
Barium 10000 I041 104 85 middot 11 5 FGS-054
Thallium 040000 0433 108 64 - 134 FGS-054
Lead 15000 1611 107 72 middot 143 FGS-054
shy
shy
shy
shy
Spike LCSO LCSD Added Concentration Recovery RPO
Analyte (JigL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 2078 104 191 75 - 135 20 FGS-054
Sodiwn 50000 496 992 188 80 - 120 20 FGS-054
Aluminum 15000 1544 103 128 85 shy 11 5 20 FGS-054
Calcium 15000 1583 106 210 80 shy 120 20 FGS-054
Chromium 70000 695 993 190 85 - 115 20 FGS-054
Manganese 60000 615 103 197 85 shy 115 20 FGS-054
Iron 50000 4946 989 269 80 - 120 20 FGS-054
1ne results in this report only apply to the samples analyud in accordance with the chain ofcustody docume11 7nis analytical rtport must~ reproduced 11 its entirety
Page 9o26 1201073 Final Report
0111112012
36
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
Frontier Global Sciences Inc
Liz Siska Project Manager
-114 Pontius J vc No11h Scatllc WA 0810lt) lh 20(1-62 60~
FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Ballth F20 1062 Sequence 2A 10002
lrcpa ration Clo~cd Ycsscl Nitric Oven Oigcstion Lab Number F20 I 062-BSBSD1
LCS Source Blan~_Spi~
Spike LCSO LCSD Added Concentration Yo l~ecovery RPIgt
Analytc (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Nickel 40000 415 10-1 220 68 shy 134 20 FGS-054
Copper 40000 428 107 301 51 - 145 20 FGS-054
Zinc 10000 1052 105 348 46 shy 146 20 FGS-054
Arsenic 15000 1569 105 200 85 shy 11 5 20 FGS-054
Selenium 30000 3257 109 335 59 shy 149 20 FGS-054
Molybdenum 20000 193 966 172 85 - 115 20 FGS-054
Silver 15000 1557 104 0768 74 - 119 20 FltoS-054
Cadmium 080000 0868 108 2 04 84 shy 113 20 FGS-054
Antimony 080000 0872 109 0661 79 shy 122 20 fGS-054
Barium 10000 1054 105 125 85 shy 115 20 FGS-054
Thallium 040000 0443 I I I 227 64 shy 134 20 FGS-054
Lead 15000 1641 109 185 72 shy 143 20 FGS-054
77e results in this report only apply 10 the samples analyzed in accordance wilh the chain ofcustody document This anaylical report must be reproduatd in its entirety
Page20of26 1201073 Final Report
0111112012
37
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
-11-1 1lt1111 ius w Nori fl Scal1lc W 98109
~ Ph ]06-62-6960 FRONTIER Fx 206-(2-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLI CATE
RECOVERY AND RPJgt
Balch F20106J Sequence ] OQ0 I 0
lrcpa ration fuCIOxidlt1_lioq Lab Numlcr f20 I 063-HSHSI gtJ
LCS Source Nist 164 Id
Spike LCS LCS Added Concentration oo Recovery
Analylc (ngL) (ngL) Rccomiddotery Limits Method Notes
Mercury I5lti79 1550 98R 80- 120 EPA 16311
Spike LCSD Added Concentration
Analytc (n~L) (ngL)
Mercury 15679 1595
LCSD Oo
Recovery Yo
RPO Recovery
Limits
llI)
Limit Mcthocl Notes
102 289 80 - 120 2middot1 EPA 1631E
Frontier Global Sciences Inc
_ Amiddot1 ~- --lt-JltJ-to(__
Liz Siska Project Manager
The rtsuits in this report only opply to the samples a11olyed i11 accordanct with the cha11 ofcustody documtnt This analgttical report must bt reproduad in Is entirety
Page 21 o26 120073 Final Rtporl
OJIJJ2012
38
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
414 Pontius A VC North Scat le WA 98109---~~~Ph 206-622-6960
FRONTIER rx 206-622-6870 CL08AL SCIEN CES
shy
LABORATORY CONTROL SAMJgtLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F701077 Sequence _2A I 00L~
Preparation Closed Vcs5cl Nitric Oven Digestion Lab Number f20 I 077-11$mSDJ
LCS Source Blank Spike
Spike LCS LCS Added Concentration Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Cakium 15000 1517 101 80 - 120 FGS-054
Spike LCSIgt LCSD Added Concentration 0o Recovery RPO
Anilyte (microgL) (JtgL) Recovery RPO Limits Limit Method Notes
Calcium 15000 1571 105 347 80 - 120 20 FGS-054
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in his reporl only apply lo he samples analyzed i11 accordance with 1he chain ofcustody document This analy1ical report must be reproduced in Is enlfrel)I
Page22o26 1201073 Final Report
Ol112012
39
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
4 14 10111 ius Avc Nor1h Scatlh WA 981(1)
lh 206-622-6960 Fx 2ltl6-622-6S70
PREPARAT ION BLANKS
Instrument J_g-17 Seq uence 2~Q20
Prcpa ration BrCI Oxidatitm
Lab Sample ID Analy lc Found M RL Units Hatch Mtlhod Noles
F201063-BLK I
F201063-BLK2
F201063-BLK3
F20 I063-13LK4
r20 I063-I3LK5
Mercury
Mercury
Mercury
Mercury
Mercury
-0009
-0006
-002
003
011
050
050
050
050
052
ngL
ngL
ngL
ngL
ngL
F20 1063
f201063
F20 1063
f-20 1063
F201063
EP 163 IE
EPA 1631E
EPA 163 IE
fPA 163 1E
EPA 1631E
u lJ
u u Q13-04
u QIJ-06
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this repor only apply 10 the samples analr-ed in accordance with tire chain ofcustody document This a11aytlca rtporl must be reproduced in its entirety
Page 23 oj26 120073 Final Report
Oll12012
40
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
middot11 bulll Pnnl iu~ Ave Nor1h
II ~-~ FRONTIER
GLOUAL SCIENC[S
Sealtic WA 98109 lh 206-622-60 Fx 20(1-622-6-70
PREPARATION BLANKS
lnslrument JCPMS-6 Sr(Jurnce 2 A 10002
P reparation (loscd Vessel Nil1 ic Ovcn_Digcst ion
Lab Sample JI) Am1lytc Found MRL Units Batch Method Notes
F201062-8LKI Beryllium 00002 0060 microgL F201062 FGS-054 lJ
F201062-0LKI Sodium 009 20 )lgL F201062 FliS-054 lJ
F201062-BLKI Aluminum 0 09 40 microgL F201062 FGS-054 u F201062-BLK I Calcium 05 40 microgL F201062 fGS-054 u F20 I 062- BLK I Chromium 003 010 microgL F201062 FGS-054 u F201062-BlKI Manganese -0002 010 ~1gL f-201062 FGS-054 u F201062-HLK I Iron -006 I 00 microgL F201062 FGS-054 u F201062-BLKI Nickel 0004 0 10 microgL F201062 FGS-054 u F20 I 062-BLK I middot Copper -00003 0 10 microgL F201062 FGS-054 lJ
(J F20 I 062-0LK I Zinc 004 020 )lgL F201062 FltS-054
F201062-BLKl Arsenic -007 015 microgL F201062 FvS-054 u F201062-BLKI Selenium 0003 060 microgL F201062 FGS-054 u F20 I 062-BIK I Molybdenum 0005 006 microgL F201062 FGS-054 u F20 I062-UI KI Silver 00002 0020 microgL F201062 FGS-054 u F201062-BLKI Cadmium -000002 0020 microgL F201062 FGS-054 u FW1062-BLKI Antimony -00003 0020 microgL F20l062 FGS-054 u F20 I 062-BLK I Barium -004 020 microgL F201062 FGS-054 u F20 I062-BLK l Thallium 0007 0005 microgL F20 1062 FGS-054 QB- 10
f20 I062-BLK I Lead 0003 0040 microgL F20J062 FGS-054 lJ
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with the chain afcus1ady document This anaylical report must be reproduCld in its entirety
Page24 o26 120073 Final Report
OJ112012
41
~ shy
FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
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eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
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FRONTIER--
4 14 lrnti11s he North Seattle WA ltJXIOlt) lh 20lt-lt2-ltgt0 1x 206-622-0870
GLOBAL SCIENCES
Instrument JCPMS-6 Sequence I A I001 5
Preparation ~loscd Vcsscl_Nitric Oven Digestion
Lab Sample ID Analytc Found MRL Units Ba1ch Method Notes
F20l077-BLK I Calcium 02 40 pgL f-201077 FGS-054 u
PREPARATJON BLANKS
Frontier Global Sciences Inc
--1 I ~- ---lti-~~middotK-o__~
Liz Siska Project Manager
The results in this report on(yapply to the samples onalyzedin accordance with 1he chain ofcustodydocument This analytical report mus be reproducedin its entirety
Page 25of26 1201073 Final Report
012012
42
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
114 10111i11s Avlt N(gt11h
SeatI le WA Q8 I 09 ~---~ lh 2 06-622-6960 r-RONTIER Fx 206-622-6870
GLOUAL SCIENCES
Nofes and Definitions
lJ Analyte included in the analysis hut not detected
QM-02 The MS andor MSI) recoveries outsitfc accepla11cc limits due lo spike concentrition less than I times the sample concentration The batch was accepted based on LCS and LCSD rccovcrits withi11 conlrol limits and when analysis permits acceptable ASASO
QB- IO The method blank andor initialcontinuing calihration blank contains analyle at a concentration ahove the MRL Only rqmrt sample results greater than IO times the contamination value (QB-0 I) or samples less than the MRL (QB-02)
QB-06 The blank was preserved to 5 BrCI r1thcr than I The control limit for blanks preserved to greater than I BrCI is ohc prt~ervation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI mlher than I Thc control limit for blanks preserved lo greater than I BrCI is the preservation pcrctntage mulliplicd by the MRL
QB-0 I The method blmk andor initialcontinuing ltii i brat ion blank contains tnalyte al i conccntralion above the MRL Ilowcver the bla11k concentralion(s) arc less than I0 ofthe sample result
FB-1631 Required cquipmcntticldfillcr blank nol submitlcd by the client The ~ample has been analyzed according 10 1631 E bul does 110
med 163 IE criteria
AS This MS andor MSD is an analytical spike anltVor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analytc Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Ditlerence
RSD Relative Standard Deviation
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analy=ed in accordance with 1he chain ofcurtody documenr This onalyrical report must be reproduced i11 its entirety
Page 26026 1201073 Final Report
011111202
43
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy
-~CHAIN-OF-CUSTODY RECORD age i of ~i 106677
SAMPLING
DATE TtME
BOLD F IELDS REQUIRED PLEASE C IRCLE REQUESTED ANALYSIS
is ~ I ~ i I e ~ ~ ~ I c r- ~ ~ - ~ ~ - -
c g ~ ~ I~ - co ~ s I ~ Ce ~ ~ I - middot~ middot - - IO
Q ~ - ~ ~ 0 Q ~~
i ~ ~ ~ ta ~ ~ -o aol t ~ 3E ~ ~ ~ c 2 - 9 w O 1- - I I e = _ ~ =V U l --c ~ I I~ 71 Xc -middot bull 0 2 - ~ - on ( -c pound - ~ 1 Q -0 ~ =i _ 5 ~ ~ X ~ i 14 I ~ I - - ~ - a c Q ~ I NOTES
3 MEOH VIAL SAMPLE ID
i( f ft h~ pound f-j f~ I
IFCOMPOSITE
I N D ICATE 80TH
START amp F tNISH
DATE I T1ME f1tJ lt bullmiddot TV
-i _ 1_0 bullltshy
- - - ~ i O g) Ic I Z ~ i S S ~ ~ ~ ~middot i I~ -lt g ~ ~ i l ~ ~ ~ E C i ~ ~ ~ 4 0 ~ ~ - ~ ~ g i ~ 1 ~ ~ g ~ ~li~ ~iI I) - - - ~ o = 9middot ~~middot- o - 1 o - - 5 ~ - II --1- co I~-- shy - -- Q middot1shy ~ ---~=
bullbull 1 r I1~~ 1 ~ _ I X X-- shy -r _lt n
1shy - shy - - shy1 ( +middot i I_ ~~ (bull h
I
middoti12 -~ ~f- middotmiddot 1~~J I1i t
r ~=~t~~ C- ~~l 15 i_ cgtfc 1~6I _J I I LJ--11 I I I I I I I I I I I I3lU-middotX 2 I
bull I 1 I I I I I I I I I I 1 I Il I I I i I --I
1 l l11m A-11 1-loit GW-G1ou11 0 WAT~ IW-Suum WAm DW-OMNXING VIAm
WW-Wmpound wmA IPbullrnrnm H-HCL H-HNO I-H 1rn H_a-N aOH H-MEOH
PROJECT MANAGER Ifr ~lwmiddot Aj -ltr COMPANY Jc-11q ) l)-- _middot-~-----s- - - - - - - - - -
C bull7 7 (ADOEII IS fpjc kl
ZIP v--en~ middot~~L-L-~ - -- lmE 211 PHo~e-1l LYdegcu-middotmiddotmiddot_middot___ _____ _____ _ EXT ____ _
ht--- - - - --- ----- shyt -1lll li( ( lo CltG e 1 lt C IJ_____ _ ___ _ ___ _
Im H~11E Vrh~-lt- Sh 1 bull~ 1Lgtlt~-- ---- ----- -
hoJE[ 5ltji1
MA ME YT OHE_ ___ _ _ _ _IUIE NH
REGULATORY PROGRAM NPDES RGP POTW ~TORNWUEROk
GWP Oil fu~o B~OWHIIEtO Ot OTHEA - - ----- ---
PO uJJ-Jc-l
METALS 8 RCRA 13 PP FE HN PB CUDATE NEEDED _L 2+__i_____ _ _ TlHP I_-- bullc
QAQC REPORTING-~VEL
A CCD OR
PRESUMPTIVE CERTAINTY
RECEIVED BYRELINQUISHED BY DAIL TIHf Summo (OHTAHIHAIION _ _ ___ ___ _
FIELD REAO INGI--- - ----- - shyRELINQUISHED BY Om TIHl RECEIVED BY
REPORTING OPTIONS OTHER 11nm - ---- --- - ---PRELllil YEI oa No
ICE G_j) No
0110LVEO METAL FIELD FILTERED YEI NOII Ytl hx OR PDF
Hom (IE SPEmL DETECTION LIIIITI BILLING INFO If OIFFEUHT) ELECTRONIC OPTIONS Q) ht~(S dJc Id gtIamp eJ CJ No fu E-MAIL POf EQUII
I Cmiddot c
1 r~ I rt f-10 i As J middotn t
~J~r(c Cwtlclthd -lt~) d ~c1 -tgteclj[_ I
l) N $ middot Hj
(~ All A~d) ib FGgt sJ c~tlio((
IITE HIITORT (i)Sed Co17 ~r rs ltgtT--~1
~1- - ~
e lt-shy
eastern analytical inc ~5 c--u Dk1middot1EICoNccw NH onoi I romiddot 60J12sos1s 1soo2s1oss I FMlt 6032184591 I E-ML cunoMER_srnvnEAILAsscoMI wwweA1LAascoH
rfmowi bor1101 mmiddotiw (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
shy
shy
shy
shy
shy