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INDIAN OIL CORPORATION LIMITED CHENGALPET LPG BOTTLING PLANT RISK ANALYSIS STUDY REPORT PREPARED BY

INDIAN OIL CORPORATION LIMITED - …environmentclearance.nic.in/writereaddata/FormB/EC/... · procedure is restarted. 3 ... measure of the risk may be obtained through a simple matrix

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INDIAN OIL CORPORATION LIMITED

CHENGALPET LPG BOTTLING PLANT

RISK ANALYSIS STUDY REPORTPREPARED BY

IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

CONTENTS

1. Introduction 1

2. Risk Assessment and Hazard Identification 1

3. Methodology 2

3.1 General 2

3.2 Preliminary Risk Screening 3

3.3 Risk Classification and Prioritization 3

3.4 Analysis and Assessment Levels 3

3.5 Qualitative Analysis 6

3.6 Quantitative Analysis 7

4 Manufacturing process Flow chart & Description 8

4.1 Description of process 8

5. Liquefied petroleum gas (LPG) 10

6. Hazards from LPG Storage and Handling 12

6.1 Jet Fire 12

6.2 Vapour Cloud Explosion 12

6.3 Flash Fire 12

7. Hazardous conditions due to release of LPG 13

7.1 Thermal Effects 13

IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

7.2 Delayed Ignition and Explosion 14

8. Identification of Hazard for LPG unloading and storage and

filling 14

8.1 Categories of Hazards 14

8.2 Hazard Identification (HAZID) 15

9. Release and Outcome Scenarios 15

10. Consequence Analysis 19

10.1 Model Used For Consequence Analysis 19

10.2 Consequence Analysis For LPG Release Scenarios 19

10.3 Rupture of 18 MT Bullet Tanker 20

10.4 Rupture of 14.2 kg LPG Cylinder 24

10.5 Release of SRV of Mounded Bullets of 600 MT 28

10.6 Release of LPG from pump 30

10.7 Release of LPG From Compressor 33

10.8 Leak from LPG Transfer Line 36

10.9 Rupture of LPG Transfer Line 38

11. Failure Frequency Data Base 38

11.1 Flanges 38

11.2 Pumps Failure Frequencies 40

IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

11.3 Probability of Ignition 41

12. Risk Reduction Measures 42

12.1 Risk Mitigation Measures 42

12.2 Mounded Bullets 43

12.3 Maintenance Schedules 48

12.4 Electrical Hazards 48

12.5 Fire Fighting Facilities 50

12.6 Control Room 57

12.7 Safety Audit And Inspection 57

12.8 Induction And Refresher Safety Trainings 57

12.9 Emergency Response Plan 58

12.10 Mock Drill Exercises 58

IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

RISK ANALYSIS STUDY REPORT

1. INTRODUCTION

Industrial plants deal with materials, which are generally hazardous in nature by

virtue of their intrinsic chemical properties or their temperature or pressure of

operation or a combination of these. Fire, explosion, hazardous release or a

combination of these are the hazards associated with industrial plants. These

have resulted in the development of more comprehensive, systematic and

sophisticated methods of Safety Engineering such as Hazard Analysis and Risk

Assessment to improve upon the integrity, reliability and safety of industrial

plants.

The primary emphasis in safety engineering is to reduce risk to human life and

environment. The broad tools attempt to minimize the chances of accidents

occurring. There always exists, no matter how remote, that small probability of

a major accident occurring. If the accident involves highly hazardous materials

in sufficient large quantities, the consequences may be serious to the plant, to

surrounding areas and the populations therein.

2. RISK ASSESSMENT AND HAZARD IDENTIFICATION

Risk is defined as the unwanted consequences of a particular activity in relation

to the likelihood that this may occur. Risk assessment thus comprises of two

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

variables, magnitude of consequences and the probability of occurrence of

accident.

The first step in risk assessment is identification of hazards. Hazard is defined

as a physical or chemical condition with the potential of accident which can

cause damage to people, property or the environment. Hazards are identified by

careful review of plant operation and nature of materials used. The various

scenarios by which an accident can occur are then determined, concurrently

study of both probability and the consequences of an accident is carried out and

finally risk assessment is made. If this risk is acceptable then the study is

complete. If the risk is unacceptable then the system must be modified and the

procedure is restarted.

3. METHODOLOGY

3.1 General

A Risk Analysis is to provide sufficient information and assessment of risks to

show that a project satisfies the risk management requirements of the proponent

company and the relevant public authorities. Within this brief, the main objective

of the PHA is to show that the residual risk levels are acceptable in relation to the

surrounding land use, and that risk will be appropriately managed. This is done by

systematically:

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

• Identifying intrinsic hazards and abnormal operating conditions that could give

rise to hazards

• Identifying the range of safeguards

• Assessing the risks by determining the probability (likelihood) and

consequence (effects) of hazardous events for people, the surrounding land

uses and environment and

• Identifying approaches to reduce the risks by elimination, minimization and/or

incorporation of additional protective measures.

With proper application, this method should demonstrate that the plant can operate

within acceptable risk levels in relation to its surroundings.

The RA needs to be carefully and clearly documented with the assumptions and

uncertainties of final design and operation defined.

3.2 Preliminary Risk Screening

The need for a RA is determined by a preliminary risk screening of the proposed

development. The preliminary screening methodology concentrates on the storage

of specific dangerous goods classes that have the potential for significant offsite

effects. Specifically the assessment involves the identification of classes and

quantities of all dangerous goods to be used, stored or produced on site with an

indication of storage depot locations.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

3.3 Risk Classification and Prioritization

Multi Level Risk Assessment (1997) suggests the use of preliminary analysis of

the risks related to a proposed development, to enable the selection of the most

appropriate level of risk analysis.

The preliminary analysis, detailed in Section 6, includes risk classification and

prioritization using a technique adapted from the Manual for Classification of Risk

due to Major Accidents in Process and Related Industries (IAEA, 1993).

3.4 Analysis and Assessment Levels

The hazard analysis and quantified risk assessment regime relies on a systematic

and analytical approach to the identification and analysis of hazards and the

quantification of offsite risks to assess risk tolerability and land use safety

implications. Two key objectives are emphasized in the implementation of this

process:

• The systematic and analytical nature of the assessment process enables the

nature of the hazards, risks, leading risk contributors and events to be

identified and understood from design, operational and organizational

viewpoints.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

• The quantification of offsite risks, where applicable, enables judgments to be

made on location safety implications with regard to people, the biophysical

environment and other land uses.

Multi Level Risk Assessment (1997) prescribes three levels of risk assessment that

can be undertaken. The choice of an appropriate technique is based on the results

of preliminary screening, risk classification and prioritization and the potential for

significant offsite consequences arising from hazards identified for the proposed

development.

Level 1: This is a qualitative assessment using word descriptions to approximately

assess and rank risks. This is used when risk screening, classification and

prioritization indicate no major offsite consequences, adequate controls exist, and

surrounding land uses are not sensitive to the hazards posed.

Level 2: A semi quantitative assessment that utilizes the hazards identified in

Level 1 and provides a focused quantification of key potential offsite risk

contributors to demonstrate that risk criteria will be met.

Level 3: This involves a full quantitative risk assessment and is undertaken

whenever the scale and nature of an activity creates a significant risk of a major

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

accident. A fullscale analysis should also be carried out if partial quantification

cannot sufficiently demonstrate that relevant criteria will be met. The rationale for

the multilevel risk assessment approach is that:

• Preliminary analyses that indicate minor land use safety outcomes may only

require qualitative assessment (Level 1). The emphasis in such instances should

be on the identification of key risk elements and optimizing safety management

controls, therefore fulfilling objectives of Level 1 above.

• Preliminary hazard analyses that indicate significant potential risk impacts to

surrounding land uses should be subjected to a more detailed level of analysis

including partial or total quantification (Levels 2 and 3). For such cases there

should be increased emphasis on objectives of level 2 above, relating to land use

safety and risk tolerability.

3.5 Qualitative Analysis

Qualitative analysis uses words and descriptive scales to determine the likelihood

of each identified hazard and its consequences. This provides an estimate of the

likely rate of occurrence of hazardous events and their severity, from which a

measure of the risk may be obtained through a simple matrix format of the

equation:

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Risk = Likelihood x Consequence

The risk associated with a proposed development is determined by combining the

likelihood of the potentially hazardous events and the magnitude of their

consequences. The process of combining consequences and frequencies gives

appropriate weight to the range between small consequence events (which are

relatively frequent) and events of major consequence (which are very infrequent).

3.6 Quantitative Analysis

Quantitative analysis is conducted using numerical data values for both likelihood

and consequences. This data has been gathered from a variety of sources including

mathematical risk modeling, extrapolation from experimental studies or past data.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

A quantitative analysis can be used to estimate:

• Thermal radiation distances.

• Explosion overpressure.

• Toxic exposure levels and

• Fatality risk levels.

4. MANUFACTURING PROCESS FLOW CHART & DESCRIPTION

4.1 DESCRIPTION OF PROCESS

The bulk LPG storage & bottling facility at Chengalpet is operated by IOCL.

The plant functions primarily as LPG receipt, storage & bottling unit for filling

into various size cylinders.

The plant operations are categorized as,

1. Receipt of LPG

a. Transfer of LPG from M/s Indian Oil Petronas Pvt. Ltd. (M/s IPPL) through

bullet trucks

b. Truck unloading

c. LPG transfer to storage bullets

d. Storage of LPG in bullets

2. Receipt of Empty LPG Cylinders & Segregation

3. a. Bottling

i. Pumping of LPG to filling shed

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

ii. Bottling of LPG cylinders – (Existing-1x24 Point electronic carousal + 1

Proposed)

iii. Quality check on filled cylinders

b. Loading into Trucks

4. Dispatch

a. Loading of filled cylinders in trucks

b. Supply & distribution to consumers through Authorized Vendors

I. Receipt of Product

LPG dosed with mercaptan will be received from M/s IPPL through bullet

trucks. There are 8 nos of Tank Lorry Decantation (TLD) Bays for the purpose

of unloading of bullet trucks and LPG will be stored in mounded vessels (3 x

600MT storage capacity).

II. Receipt of Empty LPG Cylinders & Segregation

Empty LPG cylinders will be received from vendor trucks & faulty cylinders

will be segregated at the point of receipt and diverted towards valve refitting

section.

III a. Bottling

LPG from storage bullets will be pumped to LPG filling shed 2 carousels (1

Existing + 1 Proposed) having 24 filling machines each. Cylinder bottling will

be the primary process to be carried out. After filling, each cylinder is subjected

to quality check for LPG leaks.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

IV. Dispatch

Filled cylinders will be loaded into respective Authorized Vendor trucks and

dispatched. Cylinders that are damaged are stored separately and subsequently

sold as scrap metal (after cutting) to authorized scrap dealers.

The process flow chart for LPG filling is shown in Figure 1.

Figure 1: Process Flow Chart

5. LIQUEFIED PETROLEUM GAS (LPG)

Liquefied Petroleum Gas (LPG) is a colourless and odourless gas. It is highly

flammable at normal temperature and pressure (flammability limits 2.2% to 9.6

% in air), therefore there should be no ignition sources in close proximity to

areas where LPG is stored and handled. On release it may give rise to both fire

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

and explosion hazards. LPG is a blend of Propane and Butane, readily liquefied

under moderate pressure. LPG has a density of 1.5 to 2.0 and is heavier than air,

therefore, difficult to disperse. It should never be used or stored below ground,

as this could result in asphyxiation when released in a confined space. Since

LPG has only a faint scent, a mercaptan odorant is added to help in detection of

its leakage especially when used as a domestic fuel. In the event of a LPG leak,

the vaporization of liquid cools the surrounding atmospheric air and condenses

the water vapour contained in it to form a whitish fog, which is easy to observe.

LPG in fairly large concentrations displaces oxygen leading to a nauseous or

suffocating feeling.

Physical and chemical properties of LPG are as given below:

Boiling Point : - 42 ºC - 0ºC Vapour Pressure : 300 – 1400 kPa @ 40ºC Solubility in Water @ 20ºC : < 200ppm Physical State : Liquid Colour : Colourless Specific Gravity : Liquid 0.51 – 0.58 (water = 1) Vapour : 1.52 – 2.01 (air = 1) Auto ignition Temperature : 466.1 ºC Flammable Limits LEL

- Lower Flammability Limit (LFL) : 2.2% (in air v/v) Flammable Limits UEL

- Upper Flammability Limit (UFL) : 9.6% (in air v/v)

As part of LPG storage and filling facilities, IOCL has opted for mounded

bullets for storage of LPG. Hence in this case, there is no possibility of Boiling

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Liquid Expanding Vapour Explosion (BLEVE) as in the event of early fire,

flame impingement or heating of bullet will not be possible on mounded bullet.

Therefore, from mounded bullets, release of LPG is possible only from leakage

in piping, valves or flanges, etc.

6. HAZARDS FROM LPG STORAGE AND HANDLING

6.1 Jet Fire

If released LPG is ignited immediately, jet fire may take place. The extent of

injury to people depends on the heat flux and duration of exposure to heat.

6.2 Vapour Cloud Explosion

If released LPG is not ignited immediately, the cloud of vapour LPG will

spread in the surrounding area. LPG vapours are heavier than air and tend to

settle down at lower level. As long as the LPG concentration is between the

lower and higher flammability limits, the LPG vapour cloud may be set on fire

by an ignition source. For generation of over pressure effect, some degree of

confinement of the flammable cloud is required.

6.3 Flash Fire

When released quantities of LPG are not ignited immediately, vapour cloud of

LPG spreads in the surrounding area, some portion of LPG vapour cloud will

have LPG concentration between the lower and upper flammable limits, the

LPG vapour cloud may be set on fire by an ignition source in entire length of

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

flammable LPG vapour cloud resulting flash fire. In the event of flash fire,

essentially, no over pressure effect is possible.

7. HAZARDOUS CONDITIONS DUE TO RELEASE OF LPG

As a result of release of LPG followed by immediate or delayed ignition,

following hazardous conditions may be encountered:

7.1 Thermal Effects

In case of jet fire, thermal effect is likely to cause injury or damage to people

and damage to objects. A substantial body of experimental data exists and forms

the basis for thermal effect estimation. The consequence caused by exposure to

heat radiation is a function of:

• Radiation energy onto the human body [kW/m2];

• Exposure duration [sec];

• Protection of the skin tissue (clothed or naked body).

The following damage distances for thermal radiation are used in the risk

analysis:

37.5 kW/m2 : Damage to process equipment. 100% fatality in 60 s

exposure. 1% fatality in 10 s exposure.

12.5 kW/m2 : First degree burn in 10 s exposure

4.0 kW/m2 : First degree burn in 30 s exposure

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

7.2 Delayed Ignition and Explosion

In case of delayed ignition of LPG cloud, two physical effects may occur in

following ways:

• Flash fire over the whole or part of the LPG vapour cloud;

• Vapour cloud explosion that results in blast wave with typical peak

overpressures in circle around the ignition source. Vapour cloud explosion to

occur some degree of confinement is essential.

TNO Multi-energy method is used to calculate the blast overpressure. Table 1

gives extent of damage with respect to the peak overpressure resulting from a

blast wave:

Table 2 given provides an illustrative listing of damage effects caused by peak

overpressure.

8. IDENTIFICATION OF HAZARD FOR LPG UNLOADING AND

STORAGE AND FILLING

8.1 Categories of Hazards

For identification of hazards during handling and storage of LPG, it is essential

to identify categories of hazard. Hazard categories, which may be responsible

for accidental release of LPG from proposed expansion are listed in Table 3.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

8.2 Hazard Identification (HAZID)

Hazard Identification (HAZID) for the LPG storage and billing distribution

facilities has been carried out for likely hazardous events which may cause

major accident hazards. A systematic investigation has been carried with special

focus on external events that could potentially impact the operation and safety

of facility during transfer, storage and distribution of LPG.

9. RELEASE AND OUTCOME SCENARIOS

Based on unloading conditions and storage & handling conditions of LPG at the

IOCL’s bottling plant, maximum credible LPG release and outcome scenarios

which may result during operation of LPG storage and filling facilities are given

in Table 4.

Table 1: Damage Effects Due to Overpressure

Peak Overpressure Extent of Type

0.830 bar Total Destruction

0.350 bar Heavy Damage

0.170 bar Moderate Damage

0.100 bar Minor Damage

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Table 2: Illustrative Damage Effects due to Overpressures

Peak Overpressure (Bar) Failure

0.005 5 % Window Shattering 0.02 50 % Window Shattering 0.07 Collapse of a roof of a tank 0.07-0.14 Connection failure of panelling 0.08-0.1 Minor Damage to Steel Framework 0.15-0.2 Concrete block wall shattered 0.2 Collapse of Steel Framework 0.2-0.3 Collapse of self framing Steel panel building 0.2-0.3 Ripping of empty oil tanks 0.2-0.3 Deformation of a pipe bridge 0.2-0.4 Big trees topple over 0.3 Panelling torn off 0.35-0.4 Piping failure 0.35-0.8 Damage to Distillation Column 0.4-0.85 Collapse of pipe bridge 0.5 Loaded Train Wagon overturned 0.5 Brick walls shattered

0.5-1.0 Movement of round tank, failure of connecting piping

(Source: TNO)

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Table 3: Hazard Categories

Extreme Weather and Natural Disasters • High winds; • Squalls; • Lightning; • Cyclone; • Earthquake; etc

Human Factors • Occupational accidents; • Improper and Inadequate

training; • Non availability of SOPs; etc

Process Upsets • Pressure deviations; • Temperature deviations; • Flow deviations; • Level deviations; etc

Structural Failures • Subsidence; • Seismic; • Corrosion; • Fatigue; etc

Loss of Containment • Corrosion; • Change in fluid properties; • Deviation in Design / Operating

Conditions; • Unloading activities; • Maintenance activities; • Human errors during:

-operations maintenance; -Instrumentation; etc

• Ignition sources: - Electrical; - Hot surface; etc

Inspection and Maintenance • Confined Space; • Non Accessibility; • Reduced visibility; • Non availability of

maintenance and inspection schedules; etc

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Table 4: Selected Scenarios for Consequence Analysis

S.No. Release Source Failure Mode Possible Outcomes

1. LPG Bullet

Tanker (18 MT)

Catastrophic Rupture

(Fire) of LPG Bullet

Tanker

BLEVE/Fireball,

Thermal Radiation

Flash Fire/Vapour

Cloud Explosion

2. LPG Cylinder

(14.2 kg)

Catastrophic Rupture

(Fire) of Cylinder

BLEVE/Fireball,

Thermal Radiation

Flash Fire/Vapour

Cloud Explosion

3. Mounded Bullets

600 MT

Failure of SRV for

15 Minutes

Jet Fire

Flash Fire/ Vapour

Cloud Explosion

4. LPG Pump Release of LPG

Jet Fire

Flash Fire/Vapour

Cloud Explosion

5. LPG Compressor Release of LPG

Jet Fire

Flash Fire/Vapour

Cloud Explosion

6. Leak from LPG

Transfer Line Release of LPG Jet Fire

7. Rupture of LPG

Transfer Line Release of LPG Jet Fire

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

10. CONSEQUENCE ANALYSIS

Subsequent to the accidental release of a LPG, the consequence depends on

various factors e.g. type and quantity, presence and location of an ignition

source, meteorological conditions, etc. The consequence analysis for the

selected accident scenarios for LPG release has been carried out to estimate the

effect distance or vulnerability zone. Once the effect distances are computed

for various failure cases, risk can be quantified and appropriate measures can

be taken for risk mitigation to eliminate damage to life and property and

enhance the safety.

10.1 Model Used For Consequence Analysis

The risk assessment study involves a large number of computations for which

established computing aids are essential.

PHAST (Version 6.53.1) software of DNV has been used to perform the

consequence calculations. PHAST is consequence analysis software for

calculation of physical effects (fire, explosion, atmospheric dispersion) of the

escape of hazardous materials. PHAST software allows detailed modeling and

quantitative assessment of release of pure chemicals and mixtures.

10.2 Consequence Analysis for LPG Release Scenarios

The consequence analysis has been carried out for various LPG release

scenarios as described in Table 4. Out comes of consequence analysis have

been described in subsequent section.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

10.3 Rupture of 18 MT Bullet Tanker

In the event of catastrophic rupture of 18 MT LPG bullet tanker, BLEVE may

be occurred on immediate ignition. Various outcomes in the event of

catastrophic rupture of LPG bullet tanker will be as given below under different

stability classes:

BLEVE: Fire Ball Occurrence

Outcome Parameters 18 MT LPG Bullet

Tanker

Duration of Fire Ball, (s) 78.25

Radius of Fire Ball, (m) 10.88

Fireball Lift Off Height (m) 156.51

Flame Emissive Power

(kW/m2)

285.56

Thermal Radiation: Fireball Ellipse

Radiation

Effects B, 3 m/s D, 3 m/s E, 2m/s

4 (kW/m2) 439.01 449.199 439.01

12.5 (kW/m2) 237.853 237.853 237.853

37.5 (kW/m2) 78.2269 78.2269 78.2269

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

The intensity radii for fireball due to catastrophic rupture of 18 MT bullet truck

are given in Figure 2:

UEL & LEL Concentrations Distance (m)

Concentration B, 3 m/s D, 3 m/s E, 2m/s

UEL 48.4779 49.0013 49.0068

LEL 222.883 224.435 222.682

Figure 2: Intensity Radii for Fireball for 18MT Bullet Truck

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Maximum Distance (m) at Overpressure Level due to Early

Explosion

Concentration B, 3 m/s D, 3 m/s E, 2m/s

Overpressure

(0.1 bar) 191.144 191.144 191.144

Late explosion worst case radii for fire ball due to catastrophic rupture of 18

MT bullet truck are as given in Figure 3:

Figure 3: Late Explosion Worst Case Radii for 18 MT Bullet

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Flash Fire Envelope

Concentration Distance (m)

Concentration B, 3 m/s D, 3 m/s E, 2m/s

Furthest Extent

(LEL) 222.883 224.435 222.682

Note: All values are in m

Flash fire envelope due to catastrophic rupture of 18 MT bullet truck is shown

in Figure 4.

Figure 4: Flash Fire due to Rupture for 18 MT Bullet Truck

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

10.4 Rupture of 14.2 Kg LPG Cylinder

In the event of catastrophic rupture of 14.2 kg LPG cylinder, BLEVE may be

occurred on immediate ignition. Various outcomes in the event of catastrophic

rupture of LPG cylinder will be as given below under different stability classes:

BLEVE: Fire Ball Occurrence

Outcome Parameters 14.2 Kg LPG Cylinder

Duration of Fire Ball, (s) 7.67

Radius of Fire Ball, (m) 1.70

Fireball Lift Off Height (m) 15.35

Flame Emissive Power (kW/m2) 150.12

Thermal Radiation: Fireball Ellipse

Radiation Effects B, 3 m/s D, 3 m/s E, 2m/s

4 (kW/m2) 37.4981 37.9695 37.4981

12.5 (kW/m2) 19.3709 19.3709 19.3709

37.5 (kW/m2) 4.39453 4.39453 4.39453

Note: All values are in m

Intensity radii for fire ball due to catastrophic rupture of 14.2 kg cylinder are as

given in Figure 5:

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

UEL & LEL Concentrations Distance (m)

Concentration B, 3 m/s D, 3 m/s E, 2m/s

UEL 4.59188 4.5956 4.59643

LEL 27.4572 27.4699 27.1581

Note: All values are in m

Figure 5: Intensity Radii for Fireball for 14.2 kg LPG Cylinder

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Maximum Distance (m) at Overpressure Level due to Early Explosion

Concentration B, 3 m/s D, 3 m/s E, 2m/s

Overpressure

(0.1 bar) 17.6617 17.6617 17.6617

Note: All values are in m

Late explosion worst case radii for fire ball due to catastrophic rupture of

14.2 kg LPG cylinder are as given in Figure 6:

Figure 6: Late Explosion Worst Case for 14.2 kg LPG Cylinder

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Flash Fire Envelope

Concentration Distance (m)

Concentration B, 3 m/s D, 3 m/s E, 2m/s

Furthest Extent (LEL) 27.4572 27.4699 27.1581

Note: All values are in m

Flash fire envelope due catastrophic rupture of 14.2 kg LPG cylinder is shown

in Figure 7.

Figure 7: Flash Fire due to Rupture for 14.2 Kg LPG Cylinder

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

10.5 Release of SRV of Mounded Bullets of 600 MT

I. Jet Fire on Immediate Ignition

On release of LPG from SRV of mounded bullets, jet fire will be occurred on

immediate ignition. Thermal radiation distances from jet fire are given below:

Radiation Level Thermal Radiation Level Distances (m)

B, 3 m/s D, 3 m/s E, 2m/s

37.5 kW/m2 Not Reached Not Reached Not Reached

12.5 kW/m2 Not Reached Not Reached Not Reached

4 kW/m2 42.72 42.72 42.72

Thermal radiation intensity distance from jet fire is presented in Figure 8.

Figure 8: Thermal Intensity from Jet Fire due to Release from

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

II. UEL and LEL Concentration Distances

In the event of release of LPG from SRV of mounded bullets, vapour cloud will

be formed if it is not getting source of ignition. LPG vapours under UEL and

LEL concentration will be occurred at following distances.

Concentration UEL and LEL Concentration Distances (m)

B, 3 m/s D, 3 m/s E, 2m/s

UEL 0.145 0.148 0.147

LEL 2.316 2.796 2.606

UEL and LEL Concentration Height

Concentration

UEL and LEL Concentration

Height (m)

B, 3 m/s D, 3 m/s E, 2m/s

UEL 11.38 11.51 11.53

LEL 25.104 26.573 25.33

III. Flash Fire Envelope

On ignition of LPG vapours within UEL and LEL, flash fire envelope will be

formed as details given below:

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Flash Fire Envelope (m)

B, 2 m/s D, 3 m/s E, 2m/s

Furthest Extent 2.316 2.796 2.606

Flash fire envelope distances are also presented in Figure 9.

10.6 Release of LPG from Pump

I. Jet Fire on Immediate Ignition

On release of LPG from pump, jet fire will be occurred on immediate ignition.

Thermal radiation distances from jet fire are given below:

Figure 9: Flash Fire Envelope Distance

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Radiation Level Thermal Radiation Level Distances (m)

B, 2 m/s D, 3 m/s E, 2m/s

37.5 kW/m2 Not Reached Not Reached Not Reached

12.5 kW/m2 10.09 10.09 10.09

4 kW/m2 18.97 18.97 18.97

Thermal radiation intensity radii from jet fire are also presented in Figure 10.

Figure 10: Radiation vs Distance from Jet Fire due to Release from

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

II. UEL and LEL Concentration Distances

In the event of release of LPG from pump, vapour cloud will be formed if it is

not getting source of ignition. LPG vapours under UEL and LEL concentration

will be occurred at following distances.

Concentration UEL and LEL Concentration Distances (m)

B, 3 m/s D, 3 m/s E, 2m/s

UEL 0.084 0.083 0.079

LEL 1.038 1.073 1.041

UEL and LEL Concentration Height

Concentration UEL and LEL Concentration Height (m)

B, 3 m/s D, 3 m/s E, 2m/s

UEL 5.079 5.15 5.21

LEL 9.020 9.34 9.46

III. Flash Fire Envelope

On ignition of LPG vapours within UEL and LEL, flash fire envelope will be

formed as details given below:

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Flash Fire Envelope (m)

B, 3 m/s D, 3 m/s E, 2m/s

Furthest Extent 1.038 1.073 1.041

Flash fire envelope distances are also presented in Figure 11.

10.7 Release of LPG from Compressor

I. Jet Fire on Immediate Ignition

On release of LPG from compressor, jet fire will be occurred on immediate

ignition. Thermal radiation distances from jet fire are given below:

Figure 11: Flash Fire Envelope due to Release from Pump

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Radiation Level Thermal Radiation Level Distances (m)

B, 3 m/s D, 3 m/s E, 2m/s

37.5 kW/m2 5.21375 5.21375 5.21375

12.5 kW/m2 13.5293 13.5293 13.5293

4 kW/m2 23.4757 23.4757 23.4757

Thermal radiation intensity radii from jet fire are also presented in Figure 12.

Figure 12: Radiation vs Distance from Jet Fire (Compressor)

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

II. UEL and LEL Concentration Distances

In the event of release of LPG from compressor, vapour cloud will be formed if

it is not getting source of ignition. LPG vapours under UEL and LEL

concentration will be occurred at following distances.

Concentration UEL and LEL Concentration Distances (m)

B, 3 m/s D, 3 m/s E, 2m/s

UEL 0.087 0.082 0.072

LEL 1.126 1.198 1.21

UEL and LEL Concentration Height

Concentration UEL and LEL Concentration Height (m)

B, 3 m/s D, 3 m/s E, 2m/s

UEL 3.80125 3.88819 3.95768

LEL 9.10101 9.63366 9.90947

III. Flash Fire Envelope

On ignition of LPG vapours within UEL and LEL, flash fire envelope will be

formed as details given below:

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Flash Fire Envelope (m)

B, 3 m/s D, 3 m/s E, 2m/s

Furthest Extent 1.126 1.198 1.21

Flash fire envelope distances are also presented in Figure 13.

10.8 Leak from LPG Transfer Line The leak scenarios are considered for the LPG lines with hole diameter of 8 mm

and 20 mm (20 % of pipe diameter). Lower flammability limit (LFL) of LPG

(0.00899 fraction with air) and upper flammability limit (UFL) (0.01799

fraction with air) determines the area covered for the case of flash fire.

Figure 13: Flash Fire Envelope due to Release from Compressor

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Assuming the two isolation valves on both sides of the pipeline have been

closed by control room operator/PLC within 2 minutes of the pipeline

leak/rupture. As a result of leak, the case of jet fire may happen if ignition is

present immediately. If ignition source is not available, then there is chance of

forming heavy cloud which will spread and may further disperse under the

influence of prevailing wind direction.

The cloud may be ignited (provided an ignition source is present) at locations

where the gas concentrations is between the LFL and UFL. This may be

resulted in a non-explosive combustion (flash fire) or an explosive combustion

(vapour cloud explosion) (VCE). Flash fires are not further considered as their

duration is very short and therefore do not leads to severe heat radiation levels.

It is generally considered that a minimum quality of vapour needs to be released

in order to make an unconfined VCE possible. Guidelines are that the cloud size

needs to be between 2 and 10 tonnes for explosion possibly causing significant

blast effects, but a cloud size in excess of 15 tonnes is necessary to cause a

particularly damaging explosion.

In leak case, it is estimated that the total amount to be released during 2 minutes

of duration is about 820 kg considering the leak rate of 6.83 kg/s for 100 mm

pipeline from model. As the estimated quantity is well below the 2000 kg,

delayed ignition of vapour cloud are not considered in this report.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

10.9 Rupture of LPG Transfer Line

The rupture scenario is considered for the LPG line located above the ground

with LPG bullets. It is expected that the rupture of the transfer line will result in

LPG gas release and dissipate into the atmosphere. As a result of immediate

ignition, jet fire may happen if ignition is available immediately. The heat

intensity, or thermal radiation flux, is expected to be highest at the centre of the

jet fire. The heat radiation decreases with distance from the centre, depending

on wind speed and atmospheric stability.

11. FAILURE FREQUENCY DATA BASE

An incident frequency can be derived from internationally well known generic

databases incase the design is sufficiently similar to facilities represented in the

historical failure records. This database can be used to meet the project scope

requirements including LPG storage facility failure data. Using these data, the

frequencies of incidents can be estimated. The frequency of each incident is

equal of the failure frequencies of all individual components.

11.1 Flanges

For flanges, industrial sources give figures covering the range of 6E-4 (in LPG

service) to 1.6E-4 (in liquid ammonia service) failures per year. Whittle (1993)

quotes a lower failure rate of 6.2E-5 failures per year, while the failure rate

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

quoted by Sooby (1992) is even lower by over an order of magnitude of 3.3E-6

failures per year. Since the quality of the pipe flanges varies enormously with

application, it seems sensible to regard this range as a reflection of flange and

gasket quality. A failure frequency of 1E-5 per year is used for high quality

flanges (e.g. raised face, ring type, or grey lock flanges used in high pressure,

high temperature service). An analysis of flange failure hole sizes shows them

to be small. The analysis shows that the maximum equivalent hole diameter for

a flange leak from a 6 inch (15 mm) pipe is 12 mm. It has been assumed that for

pipes greater than 6 inch (15 mm) in diameter that 10% of all flange leaks

contribute to leaks in the range of 10 to 50 mm (i.e. 25 mm holes). For pipes of

6 inch (15 mm) diameter or smaller all leaks are taken to fall into the 0 to 10

mm hole size range (i.e. 5 mm holes).

Table 5 summarizes the leak frequencies for flanges by hole size.

Table 5: Frequencies of Flange Failure

S.No Hole size(mm) Failure Rate /year

1. 5 9.0 E-5

2. 25 1.0 E-5

3. Total 1.0 E-4

Leak frequencies for valve and flanges are summarized in Table 6 by hole size.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Table 6: Frequencies of Valves and Flange Failure

S.No Hole

size(mm) Failure Rate /year

1. 5 4.22 E-5

2. 25 1.38 E-4

3. Rupture 5.11 E-5

11.2 Pumps Failure Frequencies

The NPRDS Annual Reliability Report gives the most detailed leak data records

for pumps. Most of the pumps failures is detected whilst the system is in

service, The failure modes "leak" and "crack" contribute to the 5 mm leak

category. The failure modes "breach", "collapse" and "fracture/break" contribute

to the 25 mm leak category. All failures are considered as common-mode

failures. The pump leak frequencies are summarized in Table 8.

Table 8: Frequencies for Leakage of Pump

Equivalent Hole

Size (mm)

Leak Frequency/Item year

Centrifugal

Single Seal Double Seal

5 5.2 E-2 7.5 E-3

25 1.0 E-3 1.0 E-3

100 or Rupture 1.0 E-4 1.0 E-4

Total 5.31E-2 8.6 E-3

Note: Maximum equivalent hole size for pumps is considered to be 100 mm

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

11.3 Probability of Ignition

For the frequency assessment, it is necessary to estimate the probability of

ignition if a leak occurs. Ignition of a leak may occur either at the point or at

some distance from it. The cause of ignition may be the leak itself (e.g. a leak

may generate static electricity) or an ignition source, which then gives a spark

and ignites the leak. The information available on probability of ignition is

mostly in the form of expert estimates. Table 9 details the ignition probabilities

used in the studies.

Table 9: Probabilities of Ignition for Leaks of Flammable Fluids

Continuous

Release (kg/s)

Ignition Probability

Immediate Delayed No

<10 0.2 0.05 0.75

10-100 0.5 0.1 0.4

>100 0.7 0.2 0.1

Source: TNO (LPG – Study)

For small (0-25 mm) leaks probability

• Jet Fire (Immediate ignition- 25% probability)

• Flash Fire (75% probability)

For Medium (25-100mm) leaks probability

• Jet Fire (Immediate ignition- 25% probability)

• Flash Fire (75% probability)

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

The probability of ignition depends on the availability of a flammable mixture,

the flammable mixture and ignition source and the type of ignition source

(energy etc).

12. RISK REDUCTION MEASURES

Risk Assessment study provides a quantitative technique for assessing the

significance of the impact of any facility on its external environment, highlights

key areas for greater attention and provides a tool for comparing alternative

options. Though, it can not substitute for close attention to the fundamentals of

safety throughout the design process or for design reviews.

For risk reduction, attempts should be made to either reduce inventories that

could get released in the event of loss of containment or failure likelihood or

both as far as feasible. Risk Assessment identifies the dominant risk

contributors, which enables prioritisation of plants/section that deserve special

attention in terms of inspection and maintenance in particular and over all safety

management as a whole.

12.1 Risk Mitigation Measures

The LPG bottling plant is major accident hazard installations under

Manufacture, Storage, Import of Hazardous Chemicals. Rule, 1989 and

subsequent amendments. During design, construction and operation of the

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

facilities, numbers of safety provisions and risk reduction measures will need to

be implemented and followed meticulously in compliance with applicable acts,

rules, regulations, codes, standards, guidelines and best industry practices. This

also includes provisions of not only state-of-the-art equipment, control and

instrumentation to enhance safety but also high level induction and refresher

safety trainings from senior management to contractual workers levels at the

facilities.

Risk mitigation measures for the LPG bottling plant are described below:

12.2 Mounded Bullets

The mounded storage of LPG has proved to be safer as compared to above

ground storage vessels since it provides intrinsically passive and safe

environment and eliminates the possibility of Boiling Liquid Expanding Vapour

Explosion (BLEVE). The cover of the mound protects the vessel from fire

engulfment, radiation from a fire in close proximity and acts of sabotage or

vandalism. The area of land required to locate a mounded system is minimal

compared to conventional storage.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

The following measures are suggested during design, erection and operation of

mounded storage bullets for LPG.

i. Provisions of “OISD Standards 150: Design and Safety

Requirements for Liquefied Petroleum Gas Mounded Storage

Facility” shall be included in design and operation.

ii. Each mound bullet shall have accessibility to fire tender from at

least two sides.

iii. Minimum separation distance between mounded LPG storage and

any other (other than LPG pump/compressor house) facility

associated with LPG plant shall be 15 meters. This distance to be

measured from the edge of the mound at finished ground level and

also from the first valve on the vessel i.e. ROV.

iv. The minimum inter-distance between the edges of the vessel in a

mound shall not be less than 2 meters.

v. Proper provision shall be made for countering the consequences of

the settlement of the vessel under mound. The surrounding of the

bottom connection should be filled with such material that can

absorb such settlement.

vi. Provision shall be made to monitor the settlements of the mound by

providing permanent reference point. A minimum of three

reference points shall be installed to be able to also identify

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

possible vessel bending (One each near the vessel ends and one in

the middle.)

vii. The fire safe Remote Operated Shutdown Valve (ROV) on liquid

drain line from the vessel shall be either from bottom of the vessel

or from the top of the vessel as per the design considerations.

viii. In case of liquid drain line from the bottom of the vessel, the

minimum distance of 3 meters from the vessel to ROV shall be

maintained. The nozzle pipe shall have a slope of 1.5 Deg.

ix. There shall not be any other flanges, or any other tapping up-to the

ROV except in case of liquid drain line from top of the vessels.

x. Each vessel shall have at-least two pressure relief valves. The full

flow capacity of Pressure Relief Valves (PRV) on mounded vessels

may be reduced to not less than 30% of the capacity required for an

equivalent size of above ground vessel. For safety reasons, the

discharge of Pressure Relief Valves shall be connected to flare

system. In this case Pressure Relief Valves (PRVs) shall have lock

open (or car seal open) type isolation valves on both sides of

Pressure Relief Valve.

xi. The Pressure Relief valves shall be tested and calibrated every year

by a competent person and records shall be maintained.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

xii. Cathodic protection system shall be provided, maintained and

tested routinely.

xiii. Any change in the system will be marked on P&ID. The system of

“Management of Changes” may be developed as per “Guidelines

on Management of Change” (OISD GDN 178).

xiv. Any repairs or modifications should be undertaken after statutory

approval from applicable authority.

xv. Each storage vessel shall have minimum two different types of

level indicators and one independent high level switch. High level

alarms shall be set at not more than 85% level of the volumetric

capacity of the vessel.

xvi. Audiovisual indication shall be at local panel and control room.

xvii. Automatic fire detection and /or protection (Fixed) system based

on heat detection through thermal fuses/ quartz bulbs shall be

employed. Sensors shall be installed at all critical places including

as described below:

• Minimum 1 detector shall be provided on each exposed portion

of the vessel. However if the nozzles are covered in a dome,

each group shall have 2 numbers of detectors.

• At least one near the each liquid line ROV to take care of failure

of flanges.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

xviii. Suitable gas detectors shall be placed at critical locations in

the LPG storage area such as, near the ROV, in inspection tunnel,

near water draining/ sampling points, etc.

xix. Audio- visual alarms showing the location of gas leakage shall be

provided on the control panel in the control room. First level alarm

can be set at 20% LEL and second level alarm at 40 % LEL of

LPG.

xx. All mounded storage vessels, LPG Pump Houses, Bullet Tanker

Gantries shall be fully covered by medium velocity water spray

system.

xxi. LPG storage area, automatic detection of heat for automatic

actuation of medium velocity sprinkler system having remote/ local

operated deluge valve with spray density of 10 lpm/m2 of surface

area shall be provided.

xxii. Hydrant and monitor coverage shall also be provided on all four

sides of the mounds for adequate coverage of unprotected portions

exposed to thermal radiation including for top of the mound and for

piping, in the immediate vicinity of the mound. In view of

accessibility of unprotected portions of the vessels, for

effectiveness, installation of remote operated monitors at

appropriate height shall be considered.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

xxiii. Hydrant /monitors shall be located at a safe place around the

mound. In any case fire hydrant and/or monitors shall not be

installed within 15 meters from the facilities/equipment to be

protected.

12.3 Maintenance Schedules

The proper preventive maintenance schedule should be prepared to facilitate the

maintenance service to be rendered in a planned manner covering the necessary

work to be done, mentioning the periodicity i.e. daily, weekly, monthly, half

yearly and yearly schedules.

12.4 Electrical Hazards

Some Important measures to minimise electrical hazards are as given below:

• The classification of area for electrical installations at LPG storage

and handling facilities shall be as per OISD Standards 113.

• Inspection of electrical equipment shall be carried out as per OISD

Standards 137.

• All electrical equipments shall be provided with proper earthing.

• Earth pits shall be periodically tested and maintained in good

condition.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

• Emergency lighting shall be available at all critical locations including

fire pump room, control room, etc.

• All electrical equipments shall be free from carbon dust, oil deposits,

and grease.

• All electrical cable will be tagged for easy identification and cable

routing shall be planned away from heat sources, gas, water, oil, drain

piping and air conditioning ducts.

• All lights in LPG storage area, pump house, unloading bays, etc will

be flame proof.

• Provisions shall be made for approved insulated tools, rubber mats,

shock proof gloves and boots, tester, fuse tongs, discharge rod, hand

lamp, insulated ladder.

• Flame and shock detectors and central fire announcement system for

fire safety shall be provided in MCC control panel room.

• Temperature sensitive alarm and protective relays to make alert and

disconnect equipment before overheating shall be provided.

• Danger from excess current due to overload or short circuit should be

prevented by providing fuses, circuit breakers, thermal protection, etc.

• Only carbon dioxide and dry chemical fire extinguishers shall be used

for electrical fires.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

12.5 Fire Fighting Facilities

Fire protection system shall be designed in accordance with the requirements of

OISD, NFPA standards, design requirements and safe engineering practices.

Fire fighting facilities should have full capability for early detection and

suppression of fire. The fire fighting system will primarily consist of:

• Hydrant system

• Foam protection system

• Deluge sprinkler system

• Portable fire extinguisher

• Fire detection and alarm system

Occupational Health, Safety & Environmental Features in the Project

Process Safety & Safety Features

Process Safety focuses on the prevention of fires, explosions and accidental

chemical releases at LPG Bottling facilities.

Safety Management Systems

The Safety Officer in co-ordination with Shift-in-Charge review all plant

operations to identify potential unsafe conditions and / or potential problems

which may lead to health or safety exposures.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Plant personnel shall work with the Safety Officer to identify potential problems

and to identify proper operational procedures and the operational areas of the

plant. Actions to be taken include equipment or procedural changes,

development of exposure monitoring strategies, and inclusion of warning

statements in procedures.

Hazard Analysis by the Team

QRA studies are conducted at plant before commissioning and also applied to

the proposed installation and modification of buildings, equipments, mechanical

and electrical systems, utilities, fire protection system, grounds etc. Plans or

specifications on designated projects shall be submitted to an acceptance

committee consisting of Operations Manager, Engineering. Manager, Safety

Manager for review prior to project implementation. Recommendations will be

submitted with the final plans and specifications to the Departmental head for

review. If the departmental head finds that plans and specifications are not

meeting the recommendations of the acceptance committee, he shall return the

final plans to the originator for modifications or a justification of deviations.

Inspections

The officer in charge of each function is responsible for ensuring the timely

completion of periodic inspections and correction of problems.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

The frequency of specific inspections is as follows:

Safety Facilities in the Plant

• Leak detection, prevention

• Elimination of source of ignition

• Fire prevention / fighting

• Communication, First aid, Rescue and Personnel protection equipment.

Leak Detection:

Gas Monitoring System:

The system consists of gas detecting sensors with a control panel and audio /

visual alarms. Currently 34 gas sensors are installed in the plant, the location of

the sensors are give in the below table. Two additional gas sensors will be

installed for the proposed expansion, new carousel in and new carousel out.

The sensors give an initial alarm at 20% LEL and continuous alarm at 40%

LEL.

Location of Existing GMS Sensors

1 Bullet 1 ROV

2 Bullet 1 Access Tunnel

3 Bullet 1 Man Hole 1

4 Bullet 1 Man Hole 2

5 Bullet 2 ROV

6 Bullet 2 Access Tunnel

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

7 Bullet 2 Man Hole 1

8 Bullet 2 Man Hole 2

9 Bullet 3 ROV

10 Bullet 3 Access Tunnel

11 Bullet 3 Man Hole 1

12 Bullet 3 Man Hole 2

13 47.5 Kg Filling Machine

14 LPG P/H Pump

15 LPG P/H Compressor

16 Carousal In

17 Carousal Out

18 Evacuation

19 ICU

20 Valve Change Shed

21 Filled Cylinder Shed

22 TLD BAY No.1

23 TLD BAY No.2

24 TLD BAY No.3

25 TLD BAY No.4

26 TLD BAY No.5

27 TLD BAY No.6

28 TLD BAY No.7

29 TLD BAY No.8

30 TLD BAY END

31 Filled Cylinder Shed

32 Bullet 1 Drain

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Proposed Leak Prevention / Minimizing:

Air / Vapour Extraction System: It is basically a blower with ducts extended

to different operating points in filling shed. The blower extract any leaking

LPG vapour from the floor level and cold flares the same to free atmosphere at

LPG cylinder filling shed.

Remote Control Valves:

These are electro – pneumatically operated quick shut off valves provided on

LPG pipelines with actuating points located remotely and nearer to operating

facilities in plant. When actuated, the valves will close within 25 seconds,

starving the LPG flow in pipelines. The ROV’s are installed at the following

locations:

• Storage bullets Liquid & Vapour lines

• TLD liquid lines

• LPG Pump out let lines near filling shed

33 Bullet 2 Drain

34 Bullet 3 Drain

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

ROV’s Interlock with High Level Alarm

All LPG bulk mounded vessels are fitted with High Level Alarm switches

which gives alarm when product reaches 85% of its volume. A signal has been

taken from HLA to actuate the ROV to close which will stop the flow of liquid

into vessels. This stops the over filling/flowing of LPG into vessels.

Ignition Sources

Another identified potential source for Fire accidents is “Ignition”. To

eliminate such sources, following the following fire fighting Equipments are

installed in the plant.

Fire Fighting Equipments

Location/ Equipment Equipments Nos. Bulk Storage Area-Vessel DCP EXTINGUISHER 10 KG 10.00 Bulk Storage Area DCP EXTINGUISHER 75 KG 1.00 Cyl. Filling / Storage shed-10 Kg DCP DCP EXTINGUISHER 10 KG 52.00 Cyl. Filling / Storage shed-75 Kg DCP DCP EXTINGUISHER 75 KG 5.00 LPG Pump House DCP 10 KG DCP EXTINGUISHER 10 KG 5.00 LPG Pump House DCP 75 KG DCP EXTINGUISHER 75 KG 1.00 TTL BAY DCP 10 KG DCP EXTINGUISHER 10 KG 8.00 TTL BAY DCP 75 KG DCP EXTINGUISHER 75 KG 1.00 Air Compressor house DCP EXTINGUISHER 10 KG 2.00 Fire Pumps DCP EXTINGUISHER 10 KG 3.00 Office / stores DCP EXTINGUISHER 10 KG 2.00 Canteen DCP EXTINGUISHER 10 KG 3.00 Computer Room CO2- FIRE EXTINGUISHER 2.0 KG 2.00 MCC/DG room/ HT room CO2 4.5 KG CO2- FIRE EXTINGUISHER 4.5 KG 12.00 MCC/DG room/ HT room SAND BUCKET 9 LIT 9 LIT SAND BUCKET & STAND 8.00 Fire water Hoses IN HOSE BOXES FIRE HOSES 64.00 Jet noz_store JET NOZZLE 2.00

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

Jet noz_Hose Box JET NOZZLE 16.00 Jet noz_Fire Trolley JET NOZZLE 2.00 Water curtain nozzles WATER CURTAIN NOZZLES 2.00 Triple Purpose nozzle TRIPPLE ACTION NOZZLE 2.00 UNIVERSAL NOZZLE UNIVERSAL NOZZLES 2.00 Fire Hose box HOSE BOXES 36.00 Safety helmets SAFETY HELMET 64.00 Stretcher with blanket STRETCHER 1.00 First Aid Box FIRST AID BOX WITH ANTI

SNAKE 2.00

Rubber Hand Gloves RUBBER HAND GLOVES (PAIR) 2.00 Low Temp Rubber Hand Gloves LOW TEMP HAND GLOVES

(PAIR) 4.00

Low Temp Prot Clothing LOW TEMP PROTECTIVE CLOTHING 0.00

Fire Proximity Suit FIRE PROXIMITY SUIT 1.00 Resuscitators RESUSCITATORS 1.00 Red flags for Fire drill RED FLAG 2.00 Green flags for Fire drill GREEN FLAG 2.00 SCABA with spare cylinder SCABA WITH SPARE CYLINDER 1.00 PORTABLE GAS DETECTOR Portable 2.00 Hand operated siren HAND OPERATED SIREN 4.00 Electrical siren (1 km range) ELECTRIC SIREN 1 KM RANGE 1.00 Mobile trolley for FF FIRST AID FIRE TROLLEY 1.00 CO2 cartridges # 10 kg DCP (200 gms.) CO2 crtdg 200GM_10KG DCP FE 94.00 CO2 cartridges # 75 kg DCP(2 Kg) CO2 crtdg 2KG_75KG DCP FE 4.00 DCP bags for 10 kg F.Es DCP POWDER (Kg) 840.00 DCP bags for 75 kg F.Es DCP POWDER (Kg) 160.00 Hazardous area WATER MONITORS WATER MONITOR 16.00 Non-Hazardous area WATER MONITORS WATER MONITOR 7.00 Hazardous area DBL HEADED HYD POINTS DOUBLE HEADED HYDRANT

POINT 24.00

Non-Hazardous area DBL HEADED HYD POINTS

DOUBLE HEADED HYDRANT POINT 7.00

Fire water as per OISD # 144 FIRE WATER STORAGE (KL) 7,400.00 Fire pump as per OISD # 144 FIRE PUMP CAPACITY 415 m3 /hr 5.00

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

12.6 Control Room

• Control room shall be located at a sufficient distance from operating

areas

• All control room should be blast proof and shock proof.

• Critical switches and alarm should be always kept in line.

• Minimum number of doors shall be provided in the control room

while at least two doors should be provided for safe exit during

emergency.

• Smoke detection system shall be provided for control room.

12.7 Safety Audit and Inspection

Checklist based routine inspection and safety audits should be carried out in line

with OISD -144 for mounded bullets, pumps, piping and unloading bays, etc.

Any gap or non compliance should be implemented on priority in time bound

manner.

12.8 Induction and Refresher Safety Trainings

The provision shall be made for structured induction and refresher safety

trainings for LPG handling system from senior management to contractual

workers levels at the facilities.

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IOCL – CHENGALPET BOTTLING PLANT RISK ANALYSIS STUDY REPORT

12.9 Emergency Response Plan

Anticipating and planning for various contingencies is crucial for ensuring the

success of any emergency response actions in an actual Emergency Situation.

On-site Emergency response plan shall be prepared for LPG Storage and filling

facilities, to take the action in an unlikely event of emergency due to accidental

release of LPG. Emergency Response Plan should be updated based on findings

of mock drills.

12.10 Mock Drill Exercises

Mock drill should be conducted once in six months. Exercises or drills have two

basic functions, namely training and testing. While exercises do provide an

effective means of training in response procedures, their primary purpose is to

test the adequacy of the emergency management system and to ensure that all

response elements are fully capable of managing an unlikely emergency

situation.

Mock drills are best means of accomplishing the following goals and objectives:

• To reveal weaknesses in the plans and procedures before emergencies occur. • To identify deficiencies in resources (both in manpower and equipment).

• To improve the level of co-ordination among various response personnel,

departments and agencies.

• To clarify each individual’s role and areas of responsibility.

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