Index

(page numbers in italics are main headings)

A-I72,547 A-174, 538, 545, 547 A-186, 538, 542 A-IS7, 538, 542, 543 A-lloo, 538, 541, 543, 547 A-B-A block copolymers, 239 A-line products, 188 AASHTO specification, 638 Abalyn, 563 Abbreviations, 38 Abhesive silicone, 531 Abietic acid, 562 Abitol,563 Abrading, 576 Abrasion, 79 Abrasive, 37, 130

bonded,664 coated, 671 grit, 671, 673 wheel, organic bonded, 666

ABS, 86, 444, 538, 732 AC-8 polyethylene wax, 417 Accelerated aging, 116 Accelerator, 18, 177, 212 Acetal,538 Acetate film backing, 659 Acetoxy curing, 524 Acetoxy sealant, 522 Acetylene, 285 Acetylene-terminated phenylquinoxaline oligomers, 507 Acid acceptor, 285, 292 Acid etching, 52 Acid number, in EVA, 410 Acoustical material, 98, 116 Acrylamide, 438, 441 Acrylate, 15 Acrylate-terminated nitrile, 210 Acrylated epoxy, 672 Acrylated urethane, 672 Acrylic, 24, 457, 5, 7, 22, 23, 158,593,693,700,702,

703,707,732,733, 735 application processes, 448 brick mastic, 445

carpet tile, 445 catalysts, crosslinkers, 441 ceramic tile, 446 chemistry, 437 chloroprene, 290 contact bonding, 443 emulsion sealant, 622 engineering adhesives, 447 filled,445 floor tile, 446 formulation, 441 glass transition temperature, 439, 440 heat and pressure bonding, 443 impact resistant, 447 modified,447 pressure-sensitive, 648, 659 properties, testing, 442 radiation curing, 448 sealant, 616 solution caulk, 621 suppliers of raw materials, 449 vacuum bonding, 444 wet laminating, 444

Acrylic acid, 17,271,438,441,651 Acrylic acid-modified polypropylene, 553 Acrylonitrile %,207 Acrylonitrile-butadiene-carboxyl, 276 Acryloxypropionic acid, 448 Additives for block copolymers, 242 Adherend preparation, 74,97 Adhesion, 39

contact, 65 contact angles, 45 measurement, 54 mechanical interlocking, 574 metal,48 molecular diffusion, interpenetration, 574 physical adsorption/wetting, 574 pressure-sensitive, 66 promoter, 596 setting, 40 static, 584 strength of, 61

757

758 INDEX

Adhesion (Continued) thermodynamics, 45 work of, 47

Adhesive primer, 719 Adhesive selection, 94 Adhesives in the economy, 21 Adtac, 266, 267 Advanced composite, 10 AEP. See also Aminoethyl piperazine, 354 Aero Research Ltd., 714 Aerospace, 713. See also Aircraft

bonding procedures, 727 film adhesives, 720 silicone, 530

AES, 43 Agerite, 292 Air pollution, 191 Air Products, 381, 401, 354, 406, 651 Aircraft,32, 713,28,359. See also Aerospace

metal bonding-nitrile phenolic, 217 schematic, 717 sealant, 307, 631

Airfield sealant, 631 Alclad aluminum, 719 Aliphatic amines, 351 Aliphatic resin, 562

glue, 692 Alkoxyalkyl cyanoacrylate, 476 Alkyd,668 Allied Chemical, 342, 354, 417 Alloprene, 365 Allyl ureide, 17 Alpha Techno, 463 Alpha-methylstyrene, 413, 563 Alumina, 708

trihydrate, 544 Alumina-zirconia abrasive, 671 Aluminum, 50, 48,81,97,274,313,542,618,714,

726 alloy, 719 oxide, 542 oxide abrasive, 671 to mylar, 278 zirconium, 552

Ambient temperature bonding, 605 American Cyanamid, 713,292,346, 372,719 American National Standards Institute, 114, 638 American Plywood Association, 683, 686 American Sealants Company, 451 Amicure, 354 Amidoamine, 352 Amine, 15

antioxidant, 212 curing agents, 350 reactivity, 537 terminated nitrile, 210, 221

Aminimide, 369, 370 AL-X-300, 378

Amino acid, 479 in animal glue, 124

Amino resin, 341, 601, 605

Amino silane, 190, 538, 541 Aminoethyl piperazine, 354 Aminoplast, 441 Aminopropyltriethoxysilane, 538 Amioca starch, 156 Ammonia, 53 Ammonium caseinate, 142 Ammonium thiocyanate, 128 Amoco, 413 Amphoteric, 137

starch, 157 AMS, 563 AMS/vinyl toluene, 564 Amylaceous matter, 119 Amylopectin, 153 Amylose, 153

starch, 161 Anaerobic, 25, 451, 7, 22, 23, 731, 732, 734

chemistry, 452 microencapsulation of curatives, 453 polyurethane adhesive, 367 ultraviolet light priming, 473

Ancamine, 354 Anchor coat for tufted carpet, 176 Anhydride, 353 Animal blood, 135 Animal glue, 123

amino acids, 124 bone, 126 composition, 125 flexible, 129 for coated abrasive, 673 hide, 126 lay flat, 129 liquid, 128 non-warp, 129 properties, 127 test grades, 127

Animal hair, 183 Anodizing, 97, 719 ANSI,114

specification, 638 Antifoam, 142 Antimony oxide, 189 Antioxidant, 176, 179, 190,212,292, 557

2246,292 for neoprene latex, 303 for thermoplastic rubbers, 256

APA,683 glued floor system, 686

APP,409,411,414,416 Appendix 2, 116 Appliance, 33, 31

silicone, 530 Application, 98 Araldite, 347

MY720, 348 Aramid, 327, 714

tire cord, 592 Architectural caulk, 617 Ardel,88

Arizona Chemical, 413, 419, 564 Annak,418 Armid C amide, 418 Aromatic amine, 352 Aromatic monomer resins, 412 Aromatic resin, 562 Arylene ether polymers, 515 Asahi,241 Asaprene,241 Asbestos, 327 Ashland, 337, 369, 370 Asphalt, 184, 252, 615

cutback, 687 Asphaltic, 180 ASTM, 116, 114,638,656

Committee 0-14, 96 sealant test methods, 636

Astrel,88 360, 516

Atactic polypropylene, 409, 411, 414, 416 ATBN,21O Athletic tape, 659 Atmospheric pollutant, 593 ATPQ,507 ATR,42 Attenuated total reflectance spectroscopy, 42 Auger electron spectroscopy, 43 Auger spectrum, 48 Automotive sealant, 631 Auto aftermarket, 22 Autohesion, 67 Automotive, 32, 729,28, 182,284,300, 301, 308, 359,

470,497 aftermarket, 529 door, 751 glazing, 189 holding adhesive, 731 hot melt, 417 internal trim, 177 robotic dispensing, 750 sealer gasket, 734, 735 silicone, 529 structural adhesive, 730 tape, 660

Avery, 207 Azamine, 354 Azido-formyloxyethylisophthalate, 592 Aziridinyl ester, carboxylic, 281

Backing for coated abrasive, 672 Backing for pressure sensitive, 643 Backup, 632 Bacteria, 112 Bag adhesive, 162 Bakelite, 423 Bandage tape, 659 Bareco, 417, 418 BASF,186

Wyandotte, 371 Bathtub caulk, 531 Bayer, 295, 372, 374

BOA, 311 BOMA, 353, 354 Be Square 175 microwax, 417 Bead management, 746 Bending, 104 Bentonite, 158, 624 Benzenoid resorcinol nucleus, 587 Benzimidazole po!ymers, 500 Benzophenone, 53 Benzothiazole sulfenamide, 595 Benzyl dimethylamine, 353, 354 Beryllium, 81 Beryllium oxide, 708 Beta ray, 111 BF3 oMEA, 353, 711 Bikerman, 537 Bimodal distribution of particles, 276 Biocide, 398 Bismaleimide, 720, 725 Bisphenol A, 276, 347 Bitumen, 181 Bituminous, 615, 735 Black adhesive, 180, 183 Bleach, 158 Blister test, 59 Block compression shear, 102 Block copolymer, 239, 17,421,568,645 Block shear, 99 Blocked di- or poly isocyanate, 369 Blocked isocyanate, 592 Blocking point, 119 Blood, 135, 145 Blow line blending, 608 BMC,550 BMI,725 Body shop robotic sealing, 754 Boehmite, 50 Boeing, 717 Boil test, 112 Bonded abrasive, 664, 323

epoxy, 667 phenolic, 667 rubber, 667 shellac, 667

Bonding technology, 571 Bonding, anaerobic, 457 Bone glue, 126 Bookbinding, 35, 34, 165

hot melt,415 Borated dextrin, 159 Borax, 158, 405 Borax fluidity method, 157 Borden, 337, 346 Boric acid, 405 Boron trifluoride amine, 354 Boron trifluoride monoethylamine, 353 Boscodur, 368 Bostik, 478, 368,483,484,485,487,493 Bottle labeling, 159 Bottom paste adhesive, 162 Box tape, 164

INDEX 759

760 INDEX

BP performance polymers, 554 BPDA,295 Brake, 730

lining, 327 Branched polymer, 155 Brass, 82, 274

composition, 595 Brass-coated steel wire, 593 Brick, 92 British gum, 157, 159 Brominated butyl rubber, 187, 188 Brominated phenolic resin, 191 Bromobutyl, 186 Bronze, 82 BRS Information Technologies, 114 BTL, 337 Building. See Construction, 678 Bulk unloader, 743 Bureau of Standards, 114 Burke-Palmason, 188 Butacite, 423 Butadiene, 207, 285 Butadiene-styrene-methyl methacrylate, 448 Butadiene-styrene-vinyl pyridine, 15 Butvar, 423 Butyl acrylate, 438, 441 Butyl glycidyl ether, 355 Butyl phenol dialcohol, 295 Butyl phenolic, 293

resin reactant, 292 Butyl rubber, 185, 185, 538, 647

additives, 190 applications, formulations, 194 commercial grades, 186 curing systems, 190 formulation, processing, 188 pigments, fillers, 189 sealant, 618,201,616,731 solvents, 191 tape, 731

C-4 olefin, 617 C-5 aliphatic resins, 411 C-5 oligomer, 645 C-5 resin, 562 C-9 aromatic resin, 412 C-9 oligomer, 645 C -9 resin, 562 Cab-O-Sil, 448 Cadmium, 81 Calcium carbonate, 189, 624 Calendering, 643 Calixarene, 475 Can sealant, 182 Canadian Specifications, Casein, 149 Canary dextrin, 157, 159 Canvas shoe sole, 182 Caprolactam-blocked, 369 Carbodiimide, 374 Carbon, 90

Carbon black, 179, 524 loading, 595

Carbon fiber, 714 Carbonless paper, 331 Carbopol, 213 Carborundum Co., 324 Carbowax, 164 Carboxyl, 270, 15

functional vinyl copolymer resin, 280 functionality, 392 reactive liquid polymer, 275 terminated liquid polymer, 272 terminated nitrile, 210, 221

Carboxylated acrylonitrile butadiene latex, 214 Carboxylated butadiene-styrene, 271 Carboxylated natural rubber, 271 Carboxylated neoprene latex, 281 Carboxylated olefin copolymer, 279 Carboxylated SBR latex, 230 Carboxylated vinyl acetate-ethylene polymer, 393 Carboxylic polyacrylate, 278 Carboxylic polymer, 270, 441 Carboxylic vinyl polymer, 213 Carboxymethyl cellulose, 164 Carboxymethyl starch, 158 Carcinogen, 712 Cardipol wax, 418 Cariftex, 241 Carpet backing, SBR, 232 Carpet seam hot melt tape, 418 Carton sealing, 159 Cartridge, 613 Case sealing, 159, 162 Casein, 135,4,99, 116, 175, 176,714

and blend formulas, 147 glue, 135 lime, 145 SBR latex, 143

Cashew nut shell liquid, 328 Catalytic curing agent, 353 Cationic starch, 157 Caulk,611 Cavedon, 552 Cellolyn, 563 Cellophane tape, 659 Cellular elastomer, 615 Cellulose plastic, 86 Cement, 196, 558

high tack, 215 Centrifuged latex, 168 Ceramic dual inline package, 712 Ceramic frit, 700 Ceramic tile, 175, 182,689 Ceramics, 91 CERDIP,712 Chang Chun, 406 Chang test, 657 Channel black, 212 Check valve, 739 Chelate titanate, 550

Chelating agent, 453 Chembond, 337, 346 Chemical pretreatment, 97 Chemical reagent, III Chemical surface treatment, 576 Chemical treatment, 80 Chemically cured sealant, 614 Chemigum, 207 Chloride impurity, 712 Chlorinated alkyl carbonate, 212 Chlorinated diphenyl, 310 Chlorinated paraffin, 623 Chlorinated rubber, 179,212,295,310 Chlorinated solvent system, 688 Chlorinated terphenyl, 623 Chlorobutyl, 186 Chlorobutyl rubber, 187,618 Chlorophenol, 591 Chloroprene, 284 Chlorosulfonated polyethylene, 447 Chroman, 587 Chromatography, 60 1 Chrome complex, 553 Chrome glue, 126 Chrome-sulfuric acid etching, 719 Chromic acid, 576

anodize, 719 surface treatment, 78

Chromium, 177 Ciba-Geigy, 277, 347 Clay, 158, 189,624 Cleaning, 576 Cleavage, 58, 109 Cleavage strength, 107 Climbing drum, 105 Cloth filling adhesive, 672 Cloud point, 567 Coalescence, 96 Coated abrasive, 671, 130, 324

flexing, 676 glue binder, 673 machine methods, 677 markets, 677 phenolic resin in, 674 pressure sensitive, 676 radiation curable resin in, 674 splicing, 676 urea-formaldehyde in, 674 varnish in, 674

Coating, glue, 131 Coating, phenolic, 325 Cobalt salts, 596 Coefficient of linear expansion, 613 Cohesive strength, 655 Cohesive-energy density, 13 Coir, 183 Cold corrugating, 161 Cold pour sealant, 614 Cold-box process, 326 Collagen, 123, 124

Colloid stabilizer, 158 SBR,232

Composition board, 335

INDEX 761

Composition vs. properties, polyvinyl acetal, 427 Compounding ingredients-nitrile rubber, 212 Compression loading, 98 Compression seal, 615 Compression shear, 101 Computer searchable database, 114 Concrete, 92, 182, 312, 686

adhesive, 356 wall, 691

Conductive, 705 adhesive, 119 die attach, 710 high purity adhesive, 710 low cost, 707 polymer, 18 tape, 712 thermal conductivity, 708 vs. solder, 708

Construction, 29,98,678,22,28, 116,284,300,301, 359

adhesives performance, 680 adhesive selection by substrate, 684 adhesive types, 685 APA glued floor system, 686 ceiling tile, 693 ceramic tile, 689, 692 concrete, masonry, 691 coverage, 681 duct tape, 660 freeze-thaw stability, 695 floor, 687 flooring, 683 marble, 680 panel, 692 plaster, gypsum wallboard, 691, 692 plastic foam, 691, 692 plywood, 607 poured concrete, 686 quarry tile, 689 resilient flooring, 688 SBR latex, 233 sealant, 612 sealant selection, 631 slate, 689 specialty adhesives, 693 subfloor, 686 tileboard, 692 trowel coverage, 682 wall, ceiling elements, 690 wood glue, 692 wood subfloor, 687

Consumer, 37, 36, 359 sealant, silicone, 531

Contact adhesive, 280, 287. 336 Contact angle, 45, 75 Contact cement, 693 Contact wheel, 675

762 INDEX

Control loop, 749 Convolute tube winding, 162 Coordinate titanate, 550 Copolymerization, 17 Copper, 51, 82

foil,700 Copper sulfide, 594 Cork,177 Corn starch, 156 Corona discharge, 52 Corrosion, 94 Corrosion protection tape, 660 Corrosivity, 119 Corrugated box, 162 Corrugating, 160, 159 Cosmetic item, 472 Cotton lamination, 274 Coumarone indene, 645 Coumarone resin, 175 Coupling agent, 63, 9, 62

non-silane, 549 silane, 536

CR,538 Crack propagation, 724 Creep, 94, 108, 196 Crepe, 168 Cresol-blocked, 369 Cresylic acid, 328 Critical surface tension, 12, 13, 76 CRLP, 275 Cross paste, 162 Crosslinking, 8, 18 Crosslinking degradation, 255 Crosslinking silicone, 523 Crown cork adhesive, 182 Crown cork closure, 177 Crown ether, 475 Crystal display, 702 Crystallinity, 285 CTBN,210 CTBN-epoxy adduct, 222 CTLP,272 Cumar,259,262,564 Cumene hydroperoxide, 451 Cure, 8

rate,601 temperature, 735 with sulfur, 190

Cure, phenol-formaldehyde, 321 Curing, 190 Curing agent, 212, 292, 349, 557

SBR,231 neoprene, 296

Curithane, 354 Curtainwall silicone, 531 Cutback, 618 Cutoff, 741 Cutting, 558 CV latex, 168 Cyanabond, 372 Cyanoacid initiator, 272

Cyanoacrylate, 463, 24, 9, 22, 23, 694 acid stabilizers, 465 adherend combination, 471 alkoxyalkyl, 468, 476 allyl,468 ethyl,463 toughened, 473

Cyanoethyl, 523 Cyanurate, 591, 592 Cycle, 113 Cyclic aging, III Cycloaliphatic, 564 Cycloaliphatic amine, 352, 354 Cycloheteroatom titanate, 550

D-417 aqueous dip, 590 D.E.H., 354 D.E.R., 347 DAD!, 365, 376 Dainippon ink, 371, 374 Dajac Labs., 346 Daltoftex A-IO, 376 Daltrol PRl, 376 Database, 114 De Bruyne, 714 Decal, 660, 733 Decorative laminate, 333 Decorative plywood, 607 Defoamer, 142, 158 Degradation, S-B-S vs. S-I-S, 646 Degradation, thermoplastic rubber, 255 Degrade mode, 754 Degreasing, 49, 79 Delamination test, 113 Den, 221 Denaturation, 137 Denka,406 Density, 119 Dental devices, 472 Depolymerized rubber, 171 Desmocoll, 367, 368 Desmodur, 359

HH,376 L,376 R,359, 360, 363, 375 RF, 295, 376 TH,375

Desmophen, 360, 375 DET,311 DETA. See Diethylene triamine, 354 Dexter Hysol, 482 Dextrin types, 157 Dextrin/silicate, 159 Dextrinization, 156 Diallylphthalate, 86 Dialog Information Retrieval Service, 114 Diamine, 479 Diaminodiphenyl sulfone, 354 Diamond Alkali, 313 Diamond in grinding wheel, 665, 668 Dianisidine, 365

Dianisidine diisocyanate. See DADI Diaper, 416, 659 Dibasic acid, 479 Dichloro-l,3-butadiene, 302 Dicy, 711 Dicy. See Dicyandiamide, 352 Dicyanatobenzene, 518 Dicyandiamide, 352, 354 Die attach, 710 Die bonding, 698, 700 Dielectric spectroscopy, 19 Diels-Alder adduct, 562 Diels-Alder reverse reaction, 514 Diethylene triamine, 354 Diethylhydroxylamine crosslinker, 627 Dihydric phenolic, 276 Diisocyanate, 605 Diluent, 354 Dimer acid, 480 Dimer-5 cycloaliphatic resins, 412 Dimethacrylate, 451 Dimethyl silicone polymer, 523 Dimethyldichlorosilane, 523 Dimethylsiloxane, 592 Dioctyl maleate, 651 Diphenylmethane-4,4'-diisocyanate. See MDI Dispensing equipment, 736 Dispensing gun, 746 Dispersion, 320 Disposable, 37, 36 Dissolving neoprene, 299 Dithiocarbamate, 177 Divinylbenzene, 188 DMP-30, 311, 312 Do-it-yourself, 180 Domain, 240 Door assembly, 753 Double lap, 101 Double-faced tape, 660 Dow, 347, 421 Dow Coming, 538, 649 Dry bonding, 173 Dry use, 99 Drying, 96 Du Pont, 284,408,277,327,337,364,369,406,417,

423,485,491,553,555,583,590,700 Duplex nitrile-epoxy film, 720, 723 Dupre, 47, 75 Duprene, 284 Durability, 109,69,97,117,118,119

aluminum, 97 Durez, 219, 220, 221, 310 Durez 12603, 295 DVB,188 Dymerex, 563, 564 Dynamic mixer, 737

Eastman, 414, 416, 419, 463, 493 Eastman 910, 463 Eastobond,419 ECN,277

Edge effect, 101 EDTA, 177,232 EEA,419 Elastic glazing compound, 617 Elastomer, 22, 546

INDEX 763

Elastomer blends, thermoplastic rubber, 251 Elastomeric modifier, 355 Electrical, 698, 484

bonded mica, 702 chloride impurity, 712 conductivity, 705 display, 702 glass/ceramic sealing, 701 gold filled, 706 insulation, 116, 119 laminate, 332 pressure sensitive, 701 printed wiring board, 700 properties, 548 silver filled, 706 tape, 189,200,660

Electrical/electronic, 32, 28 Electrolytic corrosion, copper, 119 Electromagnetic welding, 575 Electron, III Electron beam crosslink, 266, 267 Electron microprobe, 43 Electron spectroscopy, 19

for chemical analysis, 43 Electronic component, 472 Electronic encapsulation, 325 Electronic silicone, 530 Electropneumatic control, 748 Electrostatic coating, 673 Electrostatic shielding, 660 Elvax, 408, 414, 417 Elvax 170,418 Elvax II ethylene acid copolymer, 421 Emerez, 481 Emery Industries, 480 Emhart, 478 Empty drum, 744 Emser Werke, 485, 487, 495 Emulsion, thermoplastic rubber, 254 Encapsulated locking compound, 734 End joint, 336 Endblock-compatible resin, 568 Endex, 564 Ending, 164 Endblock compatible resins, 248 Engine nacelle, 713, 718 Engineered plastics, 329 Engineering adhesive, 447 Enichem, 241 Envelope, 164

adhesive, reseal, 176 self-adhesive, 174

EPDM, 181,538,547,548 Epi-Rez, 347 Epichlorohydrin, 347 Epikote, 219, 221

764 INDEX

EPM,538 Epo-Tuf, 354 Epolene, 414 Epon, 277, 347 Epon 1031, 348 Epotuf,347 Epoxide equivalent weight, 347 Epoxy, 347, 713,9,53,89,219,271,276,277,311,

312,313,427,441,537,540,541,542,550,603, 688,694,703,707,710,711,719,730,731,732, 735

acrylated, 672 adhesive formulations, 355 aliphatic amines, 351 aluminum, 50 amidoamines, 351 amine curing agents, 350 anhydrides, 353 aromatic amines, 352 carbon fiber, 90 carboxylated elastomer powder, 273 carboxylated VAE, 393 catalytic curing agents, 353 concrete adhesive, 356 conductive, 705 CTBN,222 curing agents, 351, 354, 349 cycloaliphatic amines, 352 dicyandiamide, 352 die-attach, 700 diluents, 354 duplex film, 723 elastomer, 726 elastomeric modifiers, 355 electrical, 698 fillers, 355, 356 film adhesive, 720 flexible, 349 from glycerine, 592 high functionality, 724 high performance, 348 high temperature, 725 IC,699 in bonded abrasive, 667 in adhesives, 350 nitrile, 9 novolac, 347 nylon, 720, 723 phenolic, 325, 714, 721, 720 polyamides, 352 polyethylene, 78 poly sulfide curing agents, 349 silane, 538, 190 surface mount, 702 two-phase toughened, 725 vinyl, 720, 722 water-soluble, 590

ESCA,43 Escore, 267 Escorez, 417,564

Estane, 367 Etching, 50, 80

solution, 576 Ethacrylonitrile, 207 Ethyl acrylate, 438 Ethyl acrylate-ethylene copolymer, 418 Ethy I orthosilicate, 524 Ethylene copolymer, 408 Ethylene dichloride, 213 Ethylene glycol dimethyacrylate, 447 Ethylene-acrylic acid, 271 Ethylene-ethyl acrylate, 418, 419, 421 Ethylene-methacrylic acid, 421 Ethylene-vinyl acetate, 27, 22, 25, 251, 408. See also

EVA Ethylenebisstearamide, 593 Ethylhexyl acrylate, 441, 648 Ethynyl, 15 Ethynyl-terminated imide oligomer, 514 Europrene, 241 EVA, 408, 5, 9, 251, 289, 301, 414, 416, 418

adhesive formulation, 409 polymers, 409 pressure sensitive, 648 vinyl acetate content, 412

Expandable foam, 716, 717 Expandable monomer, 17 Expansion, 613

. Experimental E-320 blocked isocyanate, 377 Extender, 608 Exterior, 116

wet use, 112 land and air, 111 marine, 111

Extruded tape, 613, 617 Exxon, 185, 186,417,564 Exxon Butyl, 186

Fabric bonding, 485 F actice, 190 Fairing compound, 718 Fatigue, 95 Fatigue strength, 108 FDA, 143, 165

PVOH,407 Fiber fragmentation, 60 Fiber Industries, Inc., 591 Fiberboard, 99, 605

shipping case, 116 Fiberglass, 536, 543 Fiberite, 337 Filler, 158, 179, 189,252,305,310,355,557,608

bonded abrasive, 664 content, 119 for neoprene, 296 for phenolic, 327 for SBR, 231

Fillet formation, 717 Film adhesive, 720, 10, 96, 714, 716 Filter, 334

Fina, 241 Finaprene, 241 Finger joint, 101, 336

test, 99 Fire door, 148, 149 Firestone, 241 Flame retardance, 10 Flame retardant, 189 Flame treatment, 53, 576 Floating roller metal peel, 722 Floating roller peel resistance, 105 Flocking adhesive, 178, 183 Floor, 687, 98 Flooring, 683 Flow properties, 119 Fluidity starch, 156 Fluorescent probe, 19 Fluorocarbon, 53, 46, 86 Fluoropolymer sealant, 628 Fluorosilicone, 530 Fluorosurfactant, 555 Flush door, 148 FM film adhesive, 720 Foam, 336 Foam control agent, 398 Foil-to-paper, 143, 159 Foral, 261, 417, 563, 564 Forest products, 31, 598, 28 Forest Products Laboratory, 50 Formaldehyde, 317, 337, 342

emission, 610 release, 605 scavenger, 344 toxicity, 346

Formaldehyde-to-resorcinol ratio, 585 Formvar, 423 Foundry, 22, 326

sand, 541 sand binder, 38, 37

FPL,50 Fracture strength, 109 Framing, 98 Franklin International, 678 Free energy, 45 Freeze-thaw stability, 695 Friction, 38, 37 Friction composite, 327 Fuller, H.B., 381 Fumaric ester, 271 Fumed silica, 524 Functionality, 10 Functionally terminated polymer, 209 Furan resin, 541 Furane resin, 89 Furfuryl alcohol, 148 Furniture, 31, 28, 284, 359

hot melt, 416

GAF,651 Gamma ray, 111

Gap filling, 98, 116,472,695, 717 Gasket, 735

glue in, 132 Gear pump, 736 Gel depressant, 128 Gel polymer, 286 Gel time, 601 Gelatin, 123 Gelatinization temperature, 155 General Electric, 522, 310, 337, 451, 649 General Mills, 480 Geon, 365 Georgia-Pacific, 598, 337 Gibbs free energy, 44 Glass, 91, 114, 714

bonding, 118 chipping, 131 fiber, 536 microsphere, 718 reinforced laminate, 90 tire cord, 592

INDEX 765

Glass transition temperature, 241, 244, 322, 391 Glass-to-metal assembly, 103, 731 Glazing design, 633 Glazing silicone, 530 Globular protein, 137 Glove, 178 Glue binder, 673 Glycerol, 158 Glycidoxy silane, 538 Glycidyl methacrylate, 17,441 Glyoxal, 405, 426 Gold,82 Gold-filled adhesive, 706 Goodrich, BF,206, 270, 365, 373,463 Goodyear, 207, 292, 412, 494, 564 GR-S, 227 Grace, W.R., 381 Grafted copolymer, 181 Grafted starch, 158 Grafting, 15, 287 Grain coat, 671 Graphite, 90

fiber, 10 GRAS, 143 Gravity coating, 673 Greaseless buffing compound, 131 Griltex, 487, 495 Grinding, 664 Grit blasting, 49 Gum adhesive, 178 Gum rosin, 412, 562 Gummed tape, 131, 164 Gun caulking, 613 Gun orifice size, 748 Gypsum, 98

wallboard, 116, 690

H-7 single-step adhesive dip, 591 Halogenated butyl rubber, 187

766 INDEX

Hammond, 656 Hardboard, 605, 608 Hardener, 142 Hardening, 95 Hardman, 187, 188 Header system, 745 Heat resistance, 18, 113 Heat sink, 709 Heat welding, 575, 579 Helicopter blade, 718 Henkel, 342, 346, 354, 463, 480, 482 Hercolyn, 563 Hercotac, 564 Hercules, 556, 564, 413, 414, 417, 418 Hershey drop, 730 Heterocyclic diamine, 482 Heveaplus MG, 170, 181, 184 HEW, 165 Hexa, 596 Hexamethylene diisocyanate, 375 Hexamethylenetetramine, 321 Hide glue, 126,692 High modulus composite, 716 High movement elastomeric sealant, 631 High temperature adhesives, 499

addition polyimide, 514 arylene ether polymers, 515 chronology, 501 needs, 519 other polymers, 518 PI,509 PPQ,504 PPQ, crosslinked, 507 PQ,502

High temperature resistance, 10 High temperature titanate, 550 High-energy radiation, III High-pressure decorative laminate, 345 High-tack cement, 215 Highway sealant, 631 Hildebrand, 13 Hindered bisphenol, 292 Hisil, 233, 296 Hitachi, 217, 295 HMPSA,642 HMTA,321 Hobby glue, 531 Hoechst, 406 Hold, 196 Home, 98 Honeycomb, 713, 105, 714, 723

climbing drum test, 723 sandwich construction, 715

Hooker Chemical, 313 Hospital tape, 659 Hostile environment, 109, 112 Hot melt, 408,478,497,5,96, 197, 199,279,560,

694,731,732,735,756 alpha-pinene, 413

application equipment, 419 applications, 414 aromaticity of hydrocarbon resin, 412, 413 bookbinding, 415 butyl sealant, 619 by polymer type, 411 cases, cartons, trays, 414 coating, 642 comonomers, 410 dimer acid polyamide, 480 ethylene acid copolymer, 417 furniture, 416 hydrocarbon resins, 411 labels, 417 melt index, 410 nonwovens, 416 nylon, 484 polyamide, 417 polymer suppliers, 412 polymers, 409 pressure sensitive, 418 pressure sensitive S-I-S, 259 rosin-based tackifiers, 412 sealant, 203 structural, 735 tackifiers, 411 terpolymer, 421 waxes, 413

Hot pour sealant, 613 Hot-box process, 327 HRH System, 596 Huels, 485 Humectant, 158, 398

PVOH,404 Humidity, 97, 111 Hybrid, 9, 15 Hycar, 207, 210

1072, 277, 278 1300 X 8, 277 CTBN,276

Hydrated calcium silicate, 285 Hydrated silica, 212 Hydrazide accelerator, 452 Hydrocarbon, 190 Hydrocarbon resin, 564, 411, 561, 562 Hydrochloric acid, 285 Hydrogen bond, 12 Hydrogen bonding, 14, 296, 297 Hydrogen ion concentration, 119 Hydroperoxide, 452 Hydroxy silane, 538 Hydroxyethyl cellulose, 165 Hydroxyethyl methacrylate, 367,438,441 Hydroxyethylation, 157 Hydroxyl, 15 Hydroxypropyl methacrylate, 448 Hydroxypropylated starch, 158 Hylene, 364 Hylene M, 375

Hylene MP, 377 Hypalon, 620

sealant, 616

IC,698 adhesive, 699 packaging, 710

Ice water label paste, 144 ICI,591 IISRP, 234 Imidazole, 221 Imide oligomer, ethynyl, 514 Imide oligomer, Nadic, 514 Imide oligomer, norbornene, 514 Imide polymers. See also PI, 509 Impact, 94 Impact resistant acrylic, 447 Impact strength, 107 Imperial Chemical Industries, 365 Impranil, 372 In situ resin fabric dip, 584 Induction curing, 357 Industrial laminate, 332 Information Handling Services, 114 Information sources, 5 Inhibited starch, 158 Insulated window sealant, 203 Insulating glass, 307

sealant, 631 Insulation, 336 Integrated circuit. See also IC, 698 Interdiffusion, 67 Interez, 347 Interfacial tension, 46 Interior, III Interior exposure, 99 Interior seam sealing, 750 Internal pressure, 13 Internal reflection, 42 Internal trim, 182 International Institute of Synthetic Rubber Producers, 234 Interpenetrating Polymer Network, 18 Invert emulsification, 304 Inverted emulsion, 165 Inverted probe machine, 119 lon-scattering spectroscopy, 44 IPN,18 Irgacure, 265 Irganox, 261, 374 Iron, 82

alloy, 83 oxide, 212, 530 substrate, anaerobics, 452

ISO, 114 Isobutylene, 185 Isocyanate, 15, 179

crosslink, 289 cure, 296 fiber treatment, 589

handling of, 375 prepolymer,9 primer, 190,363

Isocyanate-based adhesives, 359 Isocyanatoethy I methacrylate, 17 Isoelectric point, 137 Isoionic point, 125 Isonate, 369 Isonate 123P, 377 Isooctyl acrylate, 648 Isoprene, 185 ISS, 44 Itaconic ester, 271

Jelly gum, 159 Joining process, 574 Joint, 96

assembly, 98 design, 578 strength, 41 stressed in shear, 112

Kadel-II, 515 Kalar, 188 Kalene, 187 Karathane,372 Kenrich, 550 Ketoxime-blocked, 369 Kevlar, 327 Kitchen cabinet, 301 Knife application, 613 Knoevenagel reaction, 464 Kraton, 241, 263, 415, 416 Kraton 1l01, 261, 262, 264 Kraton 1102,262 Kraton 1107,258,259,260 Kraton D1320X rubber, 265, 266 Kristalex, 564 Kuraray, 172, 406

Label, 641, 164, 660 hot melt, 417 paste, 144

Labeling, 99, 116, 159 Lactam, 479 Laminate, high-pressure decorative, 345 Laminated assembly, 10 1 Laminated beam, 335 Laminated veneer lumber, 607 Laminated wood, 99, 113 Laminating, 162,213

phenolic, 331 Lap shear, 56

specimen, 721 LARC, 514, 515 Latex, 559

adhesive, 559 for casein and protein blends, 148 natural rubber, 167

INDEX 767

768 INDEX

Latex (Continued) nitrile, 214 preservation, 168 pressure-sensitive, 174 SBR,229 sealant, 616

Lauryl pentachlorphenate, 178 Lawter, 413 LDPE, 411, 414 Lead,82

body solder, 735 Leather, 177, 182,220

adhesive, nitrile, 216 LED,712 LEED,42 Leukonat, 376 Lewis acid salt, 711 Lewisol, 563 Library paste, 159 Lignocellulose structure, 602 Limonene, 413 Linear polymer, 154 Linseed oil, 328

putty, 617 Liquid adhesives, specifications, 116 Liquids, surface tension, 44 LMWPE, 412, 414, 416, 419 Loctite, 451, 463 Loose wrapping, 164 Low density polyethylene. See also LDPE Low drum, 744 Low energy electron diffraction, 42 Low molecular weight polyethylene. See LMWPE Low molecular weight resin, 556 Lower movement caulk, 616 LP-3,311 Lubricant, 158 Lumber, 99

laminate, 605, 607

Macromer, 15 Magnesia, 285 Magnesium, 82 Magnesium oxide, 281, 292 Make coat, 671 Malaysian Rubber Producers' Research Assoc., 167, 181 Maleic anhydride, 271, 280 Maltose, 155 Mandrel bend test, 119 Manufactured board, 608 Marble, 690 Marine, 111

sealant, 631 Marsden, 537 Masking tape, 645, 659 Mastic, 180, 559 Mastic strip, 614 Match glue, 133 Matrix resin, 536 MDA/MPDA eutectic, 354

MDA. See also methylene dianiline, 354 MDI, 359, 363, 364

phenol-blocked, 590 MDI-50, 375 Meat packaging hot melt, 418 Mechanical fastener, 715 Medical device, 472 Medical tape, 647 Medium density fiberboard, 608 Medium movement caulk and sealant, 616 MEK cement, 367 Melamine, 343, 540, 609 Melamine-formaldehyde, 341, 89, 405, 426, 538, 540 Melamine-urea-formaldehyde, 605 Memory, 415 Mercaptan, 208, 308, 349 Mercaptan-terminated polymer, 313 Mercapto silane, 538 Metal,48

bonded cutoff wheel, 665 bonded wheel, 669 bonding, 116 bonding with nitrile-phenolic, 217 complexing agent, 177 oxide, 289, 292, 303 refining, glue in, 133 solder, 700 surface treatment, 81

Metal-to-metal, 101,273,274 Metallic sodium, 576 Meter, mix and dispensing, 736 Metering cylinder, 738 Methacryl silane, 538 Methacrylate, 15

graft, 181 Methacrylato chromic chloride hydroxide, 553 Methacrylic acid, 207, 441, 447

copolymer, 302 Methacrylic acid-butadiene copolymer, 273 Methacrylic acid-chloroprene, 289 Methacrylonitrile, 207 Methacryloxy silane, 190 Methanolysis, 404 Methoxy curing, 524 Methyl acetate, 404 Methyl ethyl ketone, 213 Methyl methacrylate, 447

graft on neoprene, 301 graft on rubber, 170 graft onto nitrile, 214

Methyl styrene, 645 Methyl tris(methylethylketoximino)silane, 524 Methylene dianiline, 354 Methylene quinone intermediate, 587 Methylimidazole, 353 Methylolacrylamide, 392 Methylon, 310 Methyltriacetoxysilane, 524 Methyltrimethoxysilane, 524 MI,353

Mica board, 702 Microcrystalline wax, 419 Microelectronics, 698 Microscopy, 42 Midblock tackifier, 568 Midblock-compatible resins, 248 Mildewicide, 531 Military applications, polysulfide, 307 Military specification, 114 Milligan & Higgins, 123 Milling vs. viscosity, 211 Milling, neoprene, 298 Millmaster Onxy, 372 Mirror, 734 Mitsubishi, 220 Mix equipment, 736 Mixing, 97 Mobay, 369 Modified rosin, 564 Modified-rail test, 104 Modifying resin, 566 Modulus, 104, 715 Moisture, Ill, 609

resistance, 113 Moisture-curable, 8 Mold, 112

resistance, 99 Molding compound, phenolic, 328 Molecular weight, 68, 568

modifiers, 208 Mondur, 366 Mondur CB-75, 378 Mondur S, 377 Mondur SH, 377 Mondur TM, 376 Monoalkoxy titanate, 550 Monomer-Polymer, 346 Monsanto, 219, 292, 337, 346,497 Montac, 497 Monuron, 277 Motionless mixer, 737 MPDA: See also m-phenylene diamine, 354 Multicomponent sealant, 614 Multron, 366 Mylar to aluminum, 278

Nadic, 15 end-capped imide oligomer, 514 imide end group, 726

Naphthalene, 53 Napkin ring, 104 NASA, 499, 332 National Casein, 135 National Electrical Manufacturers Assoc., 332 National Standards Assoc., 114 National Starch, 381, 416, 463 National Wood Window and Door Assoc., 149 Natural adhesive, 22 Natural rubber, 167, 645 Naval stores, 644

NEMA,332 laminate grades, 333

Neoalkoxy titanate, 550 Neoprene rubber, 284, 693, 732

AC, 285, 287, 289, 299, 301

INDEX 769

AD, 285, 287, 289, 290, 293, 299, 300, 301 AD-G, for methyl methacrylate graft, 287, 289, 301 AF,289,290,294,296,299 AG, 286, 289, 290, 291, 296, 301 AH, acrylic copolymer, 290, 291, 294 application methods, 30 I carboxyl function, AF, Al, 280 CG,285 contact bond adhesive, 287 end uses, solvent cement, 300 FB,292 GN, 285, 292 latex, 286 latex anionic types, 303, 305 latex nonionic type, 303 latex 671A, 303, 304 latex-based adhesives, 301, 302 mastic, 291 methacrylic acid copolymer, 289 nonionic "latex-1I5", 301, 303, 305 phenolic, 9, 337 sealant, 616, 620 solvent adhesive, 287 solvent properties, 298 types, solvent adhesive, 288 WHV-A, 289, 291, 301

Nevchem, 564 Neville, 564 Nicamol,219 Nickel,83 Nicolmelt, 422 Nieuwland, 284 Nippon Goshei, 406 Nirez, 564 Nitrile rubber, 206, 538, 621, 694

anaerobics, 453 applications, 213 carboxyl terminated, 210 cold polymerization, 208 compounding, 210, 212 epoxy, 220 epoxy duplex film, 720, 723 hot, % acrylonitrile, 207 isocyanate, poly isocyanate, 214 latex, 214 phenolic, 217, 9, 714, 720, 730 phenolic, epoxy, 221 preparations, 206 PVC latex, 215 solvents,211 styrene-butadiene latex, 215 Vinsol,215

Nitrocellulose, 714 No-bake process, 326 No-carrier system, 161

770 INDEX

Nomex paper, nitrile-phenolic-epoxy, 220 Non-block, 164 Non-reactive diluents for epoxy adhesives, 355 Non-silane coupling agent, 549 Nondestructive test, 69 Nondrying mastic sealer, 617 Nonhygroscopic plasticizer, 164 Nonsag sealant, 614 Nonvolatile content, 119 Nonvulcanizing latex adhesive, 176 Nonvulcanizing solution adhesive, 179 Nonwoven, 178,416

carboxylated SBR, 232 Nopco Chemical, 373 Nordson, 743

foam melter, 484 Novolak, 318, 583 Novolak RFL dip, 584 NR,645 Nutshell flour, 608 NWWDA,149 Nylon, 538, 544

epoxy, 720 fabric bonding, nitrile-epoxy, 221 hot melt, 484

Occidental Chemical, 295, 3\0, 337 Octylated diphenylamine antioxidant, 292 Odor, 119 Oil filter, 484 Oil for SBR, 230 Oil-based caulk, 617 Oil/resin-based caulk, 616 Oleoresinous, 617 Oligomer, 15 Oppanol, 187 Optical adhesive, 98 Organofunctional silane, 536 Oriented strand board, 605, 609 OSB,609 Over-bake process, 327 Oxazolene, 422 Oxidation, 49 Oxidized starch, 156 Oxime curing, 524 Oxychloride bond, 668 Oxygen agent, 255 Oxygen bomb aging, 98 Oxygen-pressure method, 116 Ozone, 593 Ozone attack, 255

Pacific Anchor, 354 Packaging, 163,33,22,31, 199,359

hot melt, 414 tape, 659

Pandel,374 Paper bonding, 119, 99, 114, 116

glue in, 132 Paper box, 164

Paper coating, 160 carboxylated SBR, 232 casein in, 142

Papermaking, 160 PAPI, 359, 376 Para-tertiary butyl phenolic, 293 Paracril, 207, 219 Paraffin wax, 252 Paraformaldehyde, 343 Paraplex, 251 Particleboard, 344, 605, 609 Particulate structural adhesive, 277 Paste, 159,718

adhesive, 716 Patrick, 308 PBI,501 PBT, 544,545 PEEK, 88,90,515 Peel, 112 Peel adhesion, 654,442

testing, 657 Peel back, \05 Peel resistance, 105 Peeling, 55 Penacolite resin, 596 Penetration, 119 Pentalyn, 190, 262, 263, 563, 564 Perfect binding, 415 Permafil,452 PET, 87,489 Petroleum chemicals, 609 Petroleum resin, 179 Petrothene, 414 Pewter, 82 Pexite, 564 Pexul single-step adhesive dip, 591 Phase inversion temperature, 304 Phase ratio, 243 Phasing, 294 Phenol,337 Phenol-blocked, 369

isocyanate, 590 Phenol formaldehyde, 316, 598, 603, 89, 190, 280,425,

538, 540, 541, 542, 592, 593, 601, 703, 714 baking primer coating, 325 carboxylated V AE, 393 consumption, 317 contact adhesive, 336 crosslink pressure sensitive S-I-S, 264 cure, 321 dispersion resole, 321 epoxy, 325, 720, 721 foundry resin, 326 in bonded abrasive, 323, 665, 667 in coated abrasive, 324, 674 in coating, 325 in friction composite, 327 in insulation, 336 in wood bonding, 334

laminating, 331 manufacture, 323 molding compound, 328 neoprene blend, 337 nitrile, 217, 212, 720, 721 novolak, 318 poly sulfide, 311 reactions, 604 resin analysis, 322 resole, 319 structural adhesive, 337 toxicity, 337 vinyl, 720, 721

Phenol-resorcinol-fonnaldehyde, 604 Phenolic resin, 316, 212. See also Phenol-fonnaldehyde Phenylenediamine antioxidant, 176 Phenylquinoxaline polymers: See also PPQ, 504 Phillips, 241 Phosphite functionality, 550 Phosphoric acid anodizing, 97, 719 Phosphorylated starch, 158 Photoresist, 330 Phthalate plasticizer, 623 Physical properties, 114 PI, 509, 500. See also Polyimide

glass transition temperatures, 511 properties, 513

PlB,618 Picco, 262, 263, 564 Piccodiene, 564 Piccolastic, 564 Piccolyte, 190,413, 564 Piccotac, 414, 564 Piccotex, 262, 564 Piccovar, 262, 564 Pigment, 189,212 Pin and collar compression shear, 103 Pinene, 563 Pipewrap, 660 Pipewrap adhesive, 647

tape, 200 Plaslok, 338 Plasma treatment, 52, 576 Plasticizer, 158 Plastic, 114 Plastic laminate, 300, 301 Plasticity retention index, 169 Plasticizer, 142, 190,212, 310, 393, 482, 557

forthermoplastic rubber, 249 for SBR, 230

Plasticizing oil, 250 Plastics, 118,573 Plastics bonding selection chart, 580 Plastics Engineering Co., 338 Plastisol, 730, 751

See also PVC Platamid,487 Platinum, 83 Plueddemann, 537, 539, 542

Plywood, 98, 101, 116, 334, 345, 605 PMDI,606 PMF,327 PMR,515 Poly BD glycol, 360, 366, 377 Poly-pale resin, 564 Polyacetal, 576 Polyacrylamide, anionic, 165 Polyalkylene ether, 475 Polyalphamethyl styrene, 295

INDEX 771

Polyamide, 478, 5, 10,352,354,417,478,732 antioxidant, 482 application, 484 aromatic, 592, 714 dimer acid-based, 480 heterocyclic diamine, 482 hot melt, 480 melt point, 485 monofilament, 483, 484 monomers, 479, 484 nylon terpolymer powder, 486 nylon, effect of moisture, 486 nylon-type hot melt, 484 plasticizers, 482 shoe bonding, 484 tackifying resins, 482

Polyamideimide, 10, 668 Polyaryl sulfone, 88 Polyarylate, 88 Polyarylene ether properties, 517 Polybenzimidazole, 10. See also PBI Polybenzimidazoquinazoline, 502 Polybutadiene glycol, 360, 377 Polybutadiene segment, 453 Polybutadiene, thiol-terminated, 314 Polybutene, 190,413,617 Polybutene/polyisobutylene caulk, 616 Polycaprolactone glycol, 360, 377 Polycarbonate, 87, 538 Polychloroprene, 284 Polyester, 478, 488, 5, 9,87,181,540,550,668,702,

703,735. See also PET amide, 497 copolymers, 491 fiber activation, 591 film backing, 650 flame treatment, 576 hot melt gravure printing, 496 hydroxyl-terminated, 360 melt point, 492 monomers, 490 silane, 538 substrate, 77 synthesis, 490 thiol-terminated, 314 tire cord, 589 unsaturated, 537

Polyether, chlorinated, 87 Polyether, thiol-terminated, 314

772 INDEX

Polyether-ether-ketone, 88,90, 515 Polyether-polyester poly mercaptan, 314 Polyethersulfone, 515 Polyethylene, 14,78,87,538,546,576

liner, 716 Polyethylene glycol, 164 Polyethylene glycol dimethacrylate, 453 Polyethylene-vinyl acetate graft, 53 Polyethyleneterephthalate, 87, 489 Polyformaldehyde, 87 Polyimide, 500, 509, 10, 89, 668, 700, 703, 710, 712,

720, 725. See also PI Polyimide, nadic end group, 726 Polyimides, addition, 514 Polyisobutylene, 185,618,619, 647

blending, 194 Polyisocyanate, 179

curing agent, 295 Polyisoprene, synthetic, 172 Poly ken probe, 443

tack tester, 656 Polyketone, 515 Polymaleimide, 668 Polymer, 360, 516 Polymercaptan sealant, 625 Polymeric MOl, 606 Polymethylene polyphenyl isocyanate. See PAPI Polymethylmethacrylate, 87 Polyolefin, 408, 46, 538, 550, 735

polymer suppliers, 412 Polypale, 563 Polyphenylene sulfide, 88, 576 Polyphenylsulfone, 515 Polypropylene, 87, 190,409,538,546,576 Polypropylene carpet laminate with nitrile, 215 Polypropylene clay composite, 554 Polyquinoxalines, 502 Polysar, 227, 186, 187, 188 Polystal, 360, 366 Polystyrene, 87, 538

foam, 691 Polystyrene-polybutadiene-polystyrene, 240 Polystyrene-polyethylene/butylene-polystyrene,

240 Polystyrene-polyethylene/propylene, 240 Polystyrene-polyisoprene-polystyrene, 240 Poly sulfide, 307, 9, 349, 631, 694, 703

compounding, 309 curing agents, 309 glass, 307, 731 military applications, 307 phenolic, 310 sealant, 307, 616, 623 specifications, 310

Polysulfone, 88,515, 538 Poly terpene , 190,416,563 Polytetrafluoroethylene, 86, 576 Polyurethane, 28, 359, 22, 27,89,307,308,425,550,

603,605,610,631,668,703,731,754 acrylated,672

anaerobic, 453 aqueous dispersion, 371 blocked di- or polyisocyanate, 369 blocked MOl-epoxy, 590 crystallizing, 367 elastomer, 367 film and tape, 373 foam, 691 handling isocyanate, 375 identification of components, 375 in situ polymerization, 366 MOl adhesive for fibers, 364 MOl adhesive for rubbers, 363 powder, 373 sealant, 625, 616 stabilization, 374 thermoplastic, 360, 367 thiol-terminated, 314

Polyvinyl acetal, 423 health, toxicology, and safety, 424 reaction with dialdehydes, 426 reaction with isocyanates, 425 solvents, 428 viscosity, 430

Polyvinyl acetate, 26, 381, 22, 23, 99, 116, 158, 162, 163, 175, 603, 688, 692

biocide, 398 branching, 391 carboxyl functionality, 392 comonomers, 382 compounding, 393 copolymers, 384 effect of accelerated aging on copolymers, 386 effect of plasticizer on copolymers, 386 emulsions, 383 ethylene versus ester comonomers, 385 fillers, 397 functional groups, 392 foam control agents, 398 glass transition temperature, 391 heat sealing temperature, 390 homopolymers, 384 humectants, 398 modifiers, suppliers, 399 monomer, 382 nonionic surfactant protection, 389 N-methylolacrylamide, 392 plasticizers, 393, 395 polymerization, 382 pressure-sensitive, 650 protection by colloids, surfactants, 388 sealant, 622 self-crosslinking, 392 solvent reactivation, 390 solvents, 396, 397 surfactant and cellulosic protection, 389 tackifiers/ extenders, 395, 396 thickening response to plasticizer, 390 viscosity/rheology modifiers, 394, 395 wetting agents, 398

Polyvinyl alcohol, 401, 158, 162,302,423,668 borax, 405 boric acid, 405 crosslinking, 405 degree of hydrolysis, 404, 406 FDA regulations, 407 film, 405 gelation, 405 in PVAC emulsions, 404 manufacture, 404 molecular weight, 406 physical properties, 401 production, 406 solubility, 402 solution viscosity, 403 specifications, 406

Polyvinyl butyral, 6, 10,423,426,429, 703 Polyvinyl chloride, 6, 10,87, 181, 184,220,289,301,

308,359,365,367,444,470,472,484,538,578, 661, 732, 733, 735

bonding, carboxylated polymer/phenol-formaldehyde, 280

bonding, nitrile-phenolic, 218 floor tile, 647 plastisol, 730, 748, 751 pressure-sensitive tape, 621

Polyvinyl fluoride, 86 Polyvinyl formal, 423, 428, 429 Post-It Note, 661 Pot life, 608

guard, 741 Potato starch, 156 Powder adhesive, 277

carboxylic elastomer/epoxy, 273 Powdered thermoplastic rubber, 255 Powdered check valve, 740 PPG Industries, 296 PPQ,504

crosslinked, 507 glass transition temperatures, 505

PQ,502 PRC, 313 Preformed strip, 614 Preformed tape, 618 Pregelatinized starch, 159 Preparation, 74, 97, 117 Prepreg, 714 Preservative, 158, 178

for casein, 141 Pressure-sensitive, 35,641,7,22,116,119,179,183,

195, 199,560,701,732 acrylic, 648, 440, 732 adhesion, 66 adhesive systems, 644 adhesive thicknesses, 662 backing, 643 block copolymer adhesive, 645 carboxylic polyacrylate, 278 coated abrasive, 676 coated sheet, 661

construction, 642 EVA,648 hot melt, 418, 642 hot melt S-I-S, 259 latex, 174, 568 manufacture, 642 nitrile-epoxy, 222 polyisobutylene, butyl rubber, 647 PVC tape, 621 reclaim rubber, 648 rubber-based adhesive, 645 SBR,234 S-B-S, 261 silicone, 649 S-I-S, electron beam, 266 S-I-S, phenolic crosslink, 264 S-I-S/triacrylate, UV, 265 tackifier, 644 test methods, 655 theory, 651

INDEX 773

vinyl acetate copolymer, 650 Pressure-Sensitive Tape Council, 259, 570, 656 PRF,604 PRI, 169 Primary backing, 176 Primer, 49, 310, 716, 719 Primicor, 421 Printed circuit, 472 Printed wiring board, 700 Probe tack tester, 656 Products research, 313 Professional glaze, 617 Proportioning, 97 Protective colloid, casein, 142 Protein, 99

adhesive, 135 blend glue, 145

Pseudoplasticity, 212 PSTC, 656 PTFE, 53, 86, 576 Pull-off test, 58 Pull-out, 59 Pumping system, 743 Purge time, 742 Putty, 617 PVC latex-nitrile latex, 215 PVOH, 401. See also Polyvinyl alcohol Pyrrone, 10

Quarry tile, 689 Quartz, 91 Quat titanate, 550 Quick grab, 286

adhesive, 173 Quick stick, 442, 565, 657 Quinoid cure, 190 Quinoxaline polymers, 502

Radel, 515 Radiation curing, Ill, 448

774 INDEX

Radiation-curable, 672 coating silicone, 534 resin in coated abrasive, 674

Rail test, 104 Rate of development of shear strength, 104 Rate process assessment, 113 Rats, 119 RDGE,711 Reactive diluents for epoxy adhesives, 355 Reactive liquid polymer, 210 Reactive oligomer, 15 Reclaimed rubber, 180, 183, 184

pressure-sensitive, 648 Redux,714 Regalite, 564 Regalrez, 267, 564 Reichhold, 347, 381, 564 Reinforcing agent, 179 Reinforcing black, 190 Reinforcing resin, 564 Reinforcing tape, 660 Release coating, 532 Release paper, 716 Remoistenable, 164 Reseal adhesive, 176, 182 Resilient flooring, 688 Resin based mastic, 693 Resin cloud point, 567 Resin for elastomer adhesive, 556 Resin for neoprene, 293

latex, 304 Resinoid, 338

wheel,665 Resole, 319, 584 Resorcinol dicyanate, 518 Resorcinol diglycidyl ether, 711 Resorcinol-formaldehyde, 15, 158,214, 596, 604

latex, 583 Resorcinol-phenol-formaldehyde, 694 Resotropin, 596 Retrogradation, 157 RF,604

resin-to-Iatex ratio, 585 RFL, 583, 9, 15

adhesion theory, 586 dip pickup, 586 pH,586

Rheology, 64, 94, 119 silicone, 525

Ribbed smoked sheet, 168 Rilsan, 485, 487 Roaches, 119 Robotic dispensing, 743, 529

advances, 748 applications, 750 automotive, 750 bead management, 746 gun, 746 header system, 745

pumping system, 743 seam sealing, 752

Robotics, 357, 422 Rogers, 338 Rogue Valley Polymer, 338 Rohm and Haas, 437, 251, 381 Rolling ball, 119

tack, 261 Roofing silicone, 531 Room temperature vulcanizing, 522 Rope caulk, 617 Rosin, 564, 561, 562, 644 Rosin derivatization, 563 Rosin ester, 564, 175,412 RTV, 522

molding compound, 531 sealant, 627

Rubber, 167,91, 538 bonding, 220 cement, 119 compounding with glue, 132 phenolic, 703 research elastomerics, 188 to brass, 594 to metal, 273 to textile, 583

Ryton, 88

S-B-S polymer, 239, 646 S-EB-S polymer, 240 S-EP polymer, 240 S-I-S polymer, 646 S-I-S pressure-sensitive, 257 Saccharin, 452 SAE, 114 Saflex, 423 Sago starch, 156 SAN, 538 Sanding, 97 Sandwich panel, 105 Sanitary napkin, 659 Santowhite, 292 Sartomer, 265, 554 SBR,227, 301, 538, 547,688, 689

cold latex, 229 hot latex, 229 latex, 233 latex, carboxylated, 230 pressure-sensitive, 234 sealant, 621 tufted carpet backing, 232

SBR-casein, 143 Scanning electron microscopy, 42 Schenectady, 190, 191,263,295,338 Scission degradation, 255 Scorch retarder, 292 Screening, 94, 98

Sealant, 611, 181 and caulk properties, 615 butyl, 201 characteristics, 616 latex, 177 selection, joint design, 629 silicone, 522 specification, 634, 632

Sealing, 99, 116 Sealing tape, 189, 202 Secondary ion mass spectroscopy, 44 Selecting adhesives, 16 Self-adhesive envelope, 174, 182 SEM, 42, 50 Semi-interpenetrating polymer network, 513 Sensitizer, 53 Separator, 334 Sequestrant, 232 Set-up wheel, 131 Setback, 144 Setting, 40 Shall, 415 Shear, 100 Shear adhesion, 442 Shear load at rupture, 10 I Shear modulus, 104 Shear properties, 100 Shear resistance testing, 658 Shear-rate-dependent flow, 119 Shell Chemical, 239, 277, 347, 415, 416, 421,645 Shell molding process, 327 Shellac bond for abrasive, 667 Shellflex, 251, 259, 262, 263, 264, 417 Shellwax, 263 Sherex,354 Shoe,3~ 36,176,300,359,484

sole, 284, 289 sole-attaching adhesive, 119

Shot pump, 747 Shrinkage, II, 94 Side seam adhesive, 162 Silane, 536, 190, 592

amino, 538 coupling agent, 536, 538 epoxy, 538 for elastomer, 546 for thermoplastic resin, 540 for thermosetting resin, 539 glycidoxy, 538 hydroxy, 538 mercapto, 538 methacryl, 538 monomer, 310 primer, 310 vinyl, 538

Silanol-terminated poly(dimethylsiloxane), 522 Silica, 624 Silica, fumed, 524 Silicate bonded wheel, 668

INDEX 775

Silicon carbide, 672 Silicone, 522, 9, 307, 632, 660, 694, 703, 709, 732,

734,735 abhesive, 531 adhesive, 529 applications, 528 crosslinking, 523 cure characteristics, 525 electrical properties, 528 in aerospace, 530 in appliances, 530 in automotive, 529 in circuit board, 530 in construction, 530 in consumer sealant, 531 in electronic assembly, 530 molding compound, 531 polyisobutylene, 308 pressure sensitive, 649 radiation-curable coating, 534 release agent, 531 release coating, 532 rheology, 525 sealant, 627, 529, 616 shock-absorbent, 529 strength, elongation, 527 thermal properties, 528 weathering, 527

Siloxane, 522 Silver, 83

migration, 707 Silver-filled adhesive, 706 Silyl hydride group, 533 SIMS, 44 Single lap tensile shear, 10 1 SIPN,513 Size coat, 671 Sizing, glue, 131 Slate, 689 SMA resin, 554 SMC, 550, 731 SMR,168 Sodium, 53, 576 Sodium acetate, 404 Sodium alginate, 165 Sodium polyacrylate thickener, 214 Softener, 179 Sol polymer, 286 Solar radiation control film, 662 Solder, 735 Solder versus conductive, 708 Solprene, 241, 263 Solubility, 8 Solubility parameter, 12,266, 13,75, 242, 245, 296,

297,428,577,592,645 Soluble blood, 138 Soluble soap, 158 Solution, natural rubber, 179 Solution-polymerized, 210

776 INDEX

Solvent, 158, 191 cement, 558 for carboxylic elastomers, 272 for neoprene, 296 for polyvinyl acetal, 428 mixtures for hycar rubber, 211 reactivation, 390 release sealing compound, 201 SBR,231 thermoplastic rubber, 244 welding, 579 wiping, 97

Solventless release coating, 533 Soy, 135

bean oil, 328 casein glue, 150 flour, 145 protein, 135, 137

Soybean, 136 flour, 136

SP-560,295 Specification sealant, 632 Spectroscopy, 42, 601 Spiral tube winding, 162 Spiro monomer, 17 Sporting goods, 472 Spring loaded valve, 739 SST, 504 Stabilizer, 158, 255

SBR,231 Stainless steel, 84 Standard Malaysian Rubber, 168 Starch, 153

cook characteristics, 155 succinate, 158 varieties, 156

Static electricity, 253 Staybelite, 190,418, 563, 564 Staybelite ester, 563, 564 Stearic acid, 550, 596

functionality, 550 Steel, 51, 83

belted tire, 593 Stein Hall System, 160 Stenciling tape, 660 Stereon, 241 Sterman and Bradley, 537 Sterman and Marsden, 542 Stiffness, 715 Stonework, 92 Storage hardening, 169 Storage life, 119 Storage temperature, 97 Strength in bending, 104 Stress concentration, 715 Strip sealant, 614 Stripping, 164 Stripping tape, 659 Structural adhesive, 713

automotive, 730

hot melt, 735 laminated wood, 113 aerospace, 713

Styrene, 563, 564 Styrene-butadiene. See also SBR, 227

block copolymer, 415 latex-nitrile latex, 215 rubber, 227

Styrene-isobutylene resin, 413 Styrene-maleic anhydride copolymer, 554 Styrenic block copolymer, 27, 22, 25 Subfloor, 686 Sugar, 602 Sulfated alcohol, 158 Sulfenamide accelerator, 595 Sulfimide/amine salt, 452 Sulfochromate, 97 Sulfochromate etch, 97 Sulfonated caster oil, 158 Sulfur cure, 191 Super glue, 694 Super nirez, 564 Super sta-tac, 263, 564 Suprasec GA, 376 Surface, 41

abrasion, 79 cleanliness, 735 oxidation, 51 preparation, 74

Surface tension, 12, 46 Surface treatment, 48, 74, 118, 576, 726

aluminum, 719 carbon fiber, glass fiber composite, 90 ceramics, glass, 91 construction material, 92 metals, 81 rubber, 91 thermoplastics, 86

Surfactant resins, 473 Surgical tape, 179, 645 Swift adhesives, 123 Sylvachem, 354 Syntactic foam, 716, 718 Synthetic poly isoprene, 172

T -Peel test, 105 T. R. America chemicals, 346 Tack, 652, 172, 189, 196,442,563

rolling ball test, 443 tasting, 656

Tackifier, 565, 64, 65, 190 for pressure-sensitive, 644 SBR,230 selection, 566

Tackifying agent, 212 Tackifying resin, 556, 175, 179,482,641 Tactix 742, 348 Talc, 189 Tall oil resin, 412, 562, 645 Tannin, 602

Tape, 641, 613 automotive, 189 butyl,200 gummed, 131 pressure-sensitive, 659

Tapioca starch, 156 TAPPI, 99, 114, 143 TDI, 359, 366, 375 Tefton, 700 Telechelic liquid polymer, 209 Temperatures, 97, Ill, 112 Tennis ball, 178, 183 Tensile detachment, 56 Tensile properties, 99 Tensile shear, 101 Terephthalate, 489 Terlan,483 Terminology of adhesives, 116 Terpene, 564 Terpene phenolic, 285, 295, 304 Terpene resin, 413 Terpene tackifier, 644 Terrell,483 Tertiary amine, 353 Testing, 94, 99, 54, 581 TETA,354 Tetraethoxysilane, 524 Tetraethyl thiuram disulfide, 290 Tetrafunctional silane, 524 Tetrahydrofuran, 53 Tetramethyl thiuram disulfide, 595 Textile, 36, 164, 359 Textiles to rubber, 583 Thermal conductivity, 708 Thermal greases, 709 Thermid,514 Thermodynamics of adhesion, 45 Thermoplastic, 5, 22, 550

blends, thermoplastic rubber, 251 elastomer, 621 polyurethane, 367 rubber, 239, 289, 301

Thermosetting, 22 Thiazole, 177 Thickener, 212

PVOH,404 SBR,232

Thioglycollic acid, 271 Thiol-terminated polymer, 313 Thiourea, 128 Thixotropic, 614 Thixotropic gel, 476 Tight wrap, 164 Tile, 175 Tileboard adhesive, 690 Tinuvin, 374 Tire cord, 9

dip,233,274 Titanate, 549

coupling agent, 10

Titanium bonding, 85 PI,513 polyarylene ethers, 518 PPG,507 PPQ, 505, 508, 510

Titanium dioxide, 212, 624 TMPTA,265 Toa Gosei, 463 Toluene diisocyanate, 375. See also TDI Torque strength, 103 Torsional braid analysis, 19 Torsional fracture, 57 Toshiba, 217 Toughening with CRLP, 275 Toxicity, 18

formaldehyde, 345 Toys, 472 Trailing edge ftap, 718 Transformer, 165

INDEX 777

Triethylene glycol-bis(2-ethyl butyrate), 426 Triethylene tetramine, 354 Triftuoropropyl, 523 Trifunctional silane, 524 Trimethylolmelamine, 405 Trimethylolphenol, 592 Trimethylolpropane triacrylate, 265 Trioxane, 343 Triphenylmethane triisocyanate. See Desmodur R Tube,613 TufHo, 251 Tufprene, 241 Tufted carpet, 176

anchor coat, 182 backing, SBR, 232

Tung oil, 328 Tungsten, 84 Two-component RTV, 529 Two-phase structure, 240 Tyrite, 366

USA US Bureau of Standards, 114 US Consumer Products Safety Commission, 693 US Department of Agriculture, 480 US Department of Health, Education and Welfare, 165 US Food and Drug Administration, 143, 165 US Government regulations, 165,610 US Military specifications, 713 US Occupational Safety and Health Administration, 80 US Specification, 114 US Specification sources, 638 US Supersonic transport, 504 US Wright Air Development Center, 217 UCAR,220 UDEL, 88, 515 UF concentrate, 85, 342 UF reactions, 606 Ultraftex wax, 418 Ultramoll, 374 Ultrasonic cleaning, 49

778 INDEX

Ultrasonic welding, 575, 579 Ultraviolet light, 53

priming, 473 Uni-Rez, 482, 483 Union Camp, 416, 482, 483, 564 Union Carbide, 536, 538, 338, 381,419,421,423,651 Union Oil, 381 Uniroyal, 207 Unitiken, 406 Upjohn, 369 Urea, 128, 158, 343 Urea viscosity reducer, 144 Urea-formaldehyde, 341, 598, 99, 116, 119, 158,405,

605,714 in coated abrasive, 674 carboxylated vae, 393

USl, 414, 420 UV, 103

crosslink, 265 cured, 103 inhibitors for thermoplastic rubber, 256 curing methacrylate, 702

Vacuum bonding, 444 VAE,386 Valve, 739 Vanax, 290, 296, 552 Vanderbilt, 290, 292, 296 Vapor degreasing, 49 Varnish in coated abrasive, 674 Velcro, 662 Veneer, 101,607 Verona, 372 Versa1on, 482 Versamid,480 Versamine, 354 Vespel,89 Victrex, 515 Vinsol ester gum, 213 Vinsol resin, 215 Vinyl acetate, 382

in EVA, 409 -acrylate, 386 -dibutyl maleate, 385, 386 -ethylene, 385, 386

Vinyl chloride-vinyl acetate-maleic anhydride, 280 Vinyl cyc1ohexene, 314 Vinyl epoxy, 720, 722 Vinyl ester, 538 Vinyl ether polymer, 651 Vinyl flooring, SBR, 233 Vinyl phenolic, 714, 720, 721 Vinyl pyridine, 15

latex, 583 terpolymer, 584

Vinyl resin, 714 Vinyl silane, 538 Vinyl siloxane, 529, 532

Vinyl tile, 176, 182 Vinyl toluene, 563, 645 Vinyl. See also Polyvinyl acetate, PVC Vinylite VMCH, 280 Viscosity, 119, 192,430 Viscosity of S-B-S thermoplastic rubber, 246 Viscosity reducer, 142 Vistanex, 186 Vitrified bond, 668

bonded wheel, 665 Vituff,494 Volan, 553 VTBN,21O Vulcabond, 365

TX,376 Vulcanizing, 177

adhesive, 180 latex, 177

Vynathene, 420

Waferboard, 605, 609 Wall covering, 164 Wall materials, 690 Wall paper printing, 159 Walters (Jim) Resources, 327 Warp sizing, 132, 164 Washable rug anchor backing, 182 Water immersion, 111, 112 Water in wood, 603 Water on the surface, 537 Water soak, 112 Waterproofing, 530 Wax, 5, 413, 593 Wax blend, 198 Waxy starch dextrin, 159 Weathering test, 111 Wedge test, 97 Welding, 579 Westinghouse Electric, 338 Wet bonding, 173 Wet grab, 214 Wet test, 112 Wetting, 94 Wetting agent, 398 Wheat flour, 608 Wheat starch, 156 White dextrin, 157, 159 White glue, 381,692 Whittaker, 494 Williams, Landel, Ferry, 64 Windshield bonding, 754 Wingstay, 292 Wingtack, 259, 260, 262, 265, 267, 412, 413,564 Witco, 373 WLF,64 Wood, 99, 112, 117,598,22,92,98, 101, 145

framing, 116 phenolic resin bonding, 334

rosin, 412, 561, 562, 563, 644 turpentine, 644

Working properties, 114

X-ray, III photoelectron spectroscopy, 43

Xanthogen disulfide, 208 XPS, 43, 53

Yellow dextrin, 157 Young equation, 46, 75

Z-6020,538 ZBUD,I77

Zinc, 85 Zinc acetate, 144 Zinc dibutyldithiocarbamate, 259 Zinc diethyldithiocarbamate, 177 Zinc mercaptobenzthiazole, 177

INDEX 779

Zinc oxide, 144, 179, 180, 189,212,285,292,303,596 cure, 190, 191

Zircoaluminate, 552 Zirconate, 549 Zisman, 12, 46, 76, 537 2MBT,I77 Zonatac, 564 Zonester, 419 Zonyl,555