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IMF REACH Symposium
Organic Coatings- Keeping up
appearances after REACH
Jim Casper
Manager, Product Stewardship – Europe
PPG Industries
REACH - Registration
SUBSTANCE• REACH is a SUBSTANCE Regulation
• Estimated 30,000 substances used in Europe
• Toluene is a substanceXylene is a mixture of substances
most “raw materials” will be mixtures
Polymers do not have to be registered (provided the monomers are registered)
WHAT IS PAINT?
• PIGMENT – for colour and opacity
• BINDER – for physical performance
• SOLVENT – to aid/allow application
WHAT IS PAINT?• PIGMENT• BINDER• SOLVENT and:
• FLOW ADDITIVE• THICKENER• WETTING ADDITIVE• CATALYST• UV STABILISER• SLIP/ANTI-SCRATCH ADDITIVE• BRIGHTENER• SPECIAL EFFECT ADDITIVE• SLOW/FAST SOLVENT TO CHANGE DRYING SPEED• FLEXIBILISER• ……………………………….
Item Description %
1 Thickener 0.48%
2 Flow aid 0.01%
3 Adhesion promoter 0.15%
4 Catalyst 0.04%
5 Catalyst 0.04%
6 Catalyst 0.00%
7 Binder resin (solid part) 27.06%
8 Pigment 36.00%
9 Solvent 1 0.09%
10 Solvent 2 13.45%
11 Solvent 3 9.59%
12 Solvent 4 13.09%
Total 100.00%
PAINT – RAW MATERIAL LEVEL
Thickener 0.478% Active Ingredient A 0.478
Flow aid 0.010% Propritary silicone compound 0.001Xylene 0.004
Active Ingredient C 0.050Adhesion promoter 0.150% Active Ingredient D 0.050
Proprietary solvent 0.050
Catalyst 1 0.040% Proprietary tin compound 0.010Xylene 0.030
Catalyst 2 0.038% Proprietary zinc compound 0.010Xylene 0.028
Catalyst X 0.460Acrylic monomer 1 4.100Acrylic monomer 2 4.200
Binder resin 36.800% Acrylic monomer 3 6.100Acrylic monomer 4 6.100Acrylic monomer 5 2.100Solvent 1 4.500Solvent 2 9.240
PAINT – SUBSTANCE LEVEL (1)
PAINT – SUBSTANCE LEVEL (2)
Titanium dioxide 32.400Pigment 36.000% Aluminium Hydroxide 1.400
Amorphous Silica 1.400Organic additives 0.800
Catalyst Y 0.050Catalyst Z 0.060Acrylic monomer 3 2.400
Pigment-dispersant resin 10.500% Acrylic monomer 6 3.500Acrylic monomer 7 0.400Acrylic monomer 8 0.600Solvent 1 2.590Solvent 3 0.900
Solvent 1 9.590% Solvent 1 9.590
Solvent 2 6.394% Solvent 2 6.394
> 30 CHEMICAL SUBSTANCES
SUPPLIER
• Manufacturer/Importer of Substance is responsible for REGISTRATION
• Most users of chemicals are “Downstream users”, according to REACH
• Your Supplier may not be the person responsible for Registration
• Requires communication up/down supply chain
REACH COMPLIANCE
IMPACT THROUGH THE SUPPLY CHAIN
ChemicalManufacturer
ChemicalManufacturer
Chemicalmanufacturer
ChemicalManufacturer
Raw MaterialSupplier
PaintManufacturer
Customer(Paint User)
MSDS
Recommended protection methods
Identified Use
Exposure data
REACH COMPLIANCE
IDENTIFIED USE• Identified Use must be included in the
registration
• Downstream user (e.g. PAINT) can only use the substance if his use is identified
• Requires communication up/down supply chain
• Identified Use not yet defined!(RIP 3.5 –
Dec07/Jan08)
REACH COMPLIANCE
MAJOR THREATS
• Increased price of raw materials – as REACH COST is passed on down the supply chain
• Substances which may not be supported by the supplier - REFORMULATION
• Substances of high risk that will require AUTHORISATION
- use in your factory- se by your customers
• Workload/cost of collating data through the supply chain – PAPERWORK
Registration of new Substances
Ag
ency
sta
r t- u
p
>1000tonnesCMR 1, 2 > 1 tR50/53 > 100t
100-1000 tonnes 1-100 tonnes
1 December 2010 1 June
2013
1 June 2018
1 June 2007
1 June 2008
1 December 2008
REACH - TIMELINE
Phase-in substances registration
Pre
-reg
istr
atio
n
SO WHAT SHOULD I DO?
AWARENESS:
• All key staff aware of REACH
• Impact on business understood
ANALYSIS:
• Number of materials used understood
• Suppliers position recorded
• Business impact understood
ACTION
• Product-specific actions (No change, Stop Sales, Re-formulate………….)
ACTIONS REQUIRED NOW (1):
RAW MATERIALS SOURCED IN EUROPE
• Catalogue all raw materials used in products you manufacture
• Identify the supplier for each raw material
• Contact suppliers – confirm:• pre-register • Register• include your identified use
ACTIONS REQUIRED NOW (2):
CONSIDER OTHER MATERIALS
• Products/Resins/Raw materials you import into Europe
• Substances you manufacture
• Ancillary chemicals (cleaning materials….)
ACTIONS REQUIRED NOW (3):
AUTHORISED SUBSTANCES
• Consider options:
• Reformulate
• Seek Authorisation (with supplier)
• Stop sales (from 2010……)
Examples of CMR 1&2
• Strontium Chromate / Zinc Chromate
• Lead pigments (colour pigments, lead silicate)
• Di-Octyl Phthalate
•Dibutyltin compounds (new classification)
• N-methylPyrrolidine (new classification)
ACTIONS REQUIRED NOW (4):
COMMUNICATION WITH CUSTOMERS
• Prepare to answer questions from your customers (continuity of supply…)
• Prepare to discuss “identified use”
• MSDS• New requirements from 1 June 2007
(Email address, Section 2 & 3 reversed)• Check and implement the changes