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Ihenor 6e301111CHOCTH seuwerna (marepnaaa) Material Safety Data Sheet Harimenonanne: JIHrHocy.nr4oHant teximtreenie nopouncoo6pasume Teimpiecicoe (no IVI) Technical name Lignosulphonates technical powder He nmeer XniViHtleCKfle (no IUPAC) Trade name Do not have Toprosoe Commercial .1114rHoeyn4oaana exiiwwcne nopouncoo6pamme (TICTTI) Lignosulphonates technical powder CHHOHIIMEJ Synonyms He roneet Do not have Yeacantoe o6o311ageHHe xi Ha;memo:mime Rik (roar, TOCT P, TV, ISO it T.A.) Conventional mark and name ND Pate Standard GOST, P, Technical conditions TY,ISO) TY 2455-055-58901825-2008 «JIHruocynt4oHana Texmitlecnie Hopottm000pasHme» Lignosulphonates technical powder KoA 01C11 24 5563 5 Koji( Tit 133,11 3804000000 CAS 348061 51 6 XapawrepHernHa onacHoeTH: Ilt aK aBrIlOCylu4011BTOB B sou. p.3. 2 mr/ne. Description of the danger: Max. allowed concentration of lignosulphonates in the air 2mg/m3 JIHI'HOCyab+0112abl 011110CSITCSI K 4-my Haacey onaeurama H TweemiecHoro ,EletteTBilif Lignosulphonates refer to the 4 th class of danger, don't have toxic influence on humans organ km Ha oprann13m rienoseHa He (maw:puma. llortno6Han: a namaraembix 16-TH eneuutrunanosumbix aa3fteaax. (HanmeHosaHHe opramnaw3H) (name of the company) (ropo,a) (town) Tim 32SIBBTeall: BB01 , 1380/anerl•, n k 10 , i" 0. - p (HeHywHoe aariepicHyrb) Type of the applicant: producer 01C110 58901825 Code OpFaillnallall COMMITCM3: Company — complier: Forestry PyKOBOAKTWIla oprammatum saaanTeast: Head of applicant company Menbaatiefixo E.H. Melniebenlco Yd. (paelinutpoaKa) (decoding)

Ihenor - dhard.ucp-is.comdhard.ucp-is.com/docs/specs/feedstocks/lignosulfonates/lignosulph… · BO3ayXe pR5OIe 0.1-1Eki —2 rvirliv1 3 ,tum cootsetcmyeT 4 Knaccy ollacHoent no FOCT

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Page 1: Ihenor - dhard.ucp-is.comdhard.ucp-is.com/docs/specs/feedstocks/lignosulfonates/lignosulph… · BO3ayXe pR5OIe 0.1-1Eki —2 rvirliv1 3 ,tum cootsetcmyeT 4 Knaccy ollacHoent no FOCT

Ihenor 6e301111CHOCTH seuwerna (marepnaaa) Material Safety Data Sheet

Harimenonanne: JIHrHocy.nr4oHant teximtreenie nopouncoo6pasume Teimpiecicoe (no IVI) Technical name Lignosulphonates technical powder

He nmeer XniViHtleCKfle (no IUPAC) Trade name Do not have Toprosoe

Commercial

.1114rHoeyn4oaana exiiwwcne nopouncoo6pamme (TICTTI)

Lignosulphonates technical powder CHHOHIIMEJ Synonyms

He roneet Do not have

Yeacantoe o6o311ageHHe xi Ha;memo:mime Rik (roar, TOCT P, TV, ISO it T.A.) Conventional mark and name ND Pate Standard GOST, P, Technical conditions TY,ISO) TY 2455-055-58901825-2008 «JIHruocynt4oHana Texmitlecnie Hopottm000pasHme»

Lignosulphonates technical powder • KoA 01C11 24 5563 5 Koji( Tit 133,11 3804000000 CAS 348061 51 6

XapawrepHernHa onacHoeTH: IltaK aBrIlOCylu4011BTOB B sou. p.3. 2 mr/ne. Description of the danger: Max. allowed concentration of lignosulphonates in the

air 2mg/m3 JIHI'HOCyab+0112abl 011110CSITCSI K 4-my Haacey onaeurama H TweemiecHoro ,EletteTBilif

Lignosulphonates refer to the 4th class of danger, don't have toxic influence on humans organ km

Ha oprann13m rienoseHa He (maw:puma. llortno6Han: a namaraembix 16-TH eneuutrunanosumbix aa3fteaax.

(HanmeHosaHHe opramnaw3H) (name of the company)

(ropo,a) (town)

Tim 32SIBBTeall: BB01,1380/anerl•, • n k 10 , i" • • 0. - p (HeHywHoe aariepicHyrb)

Type of the applicant: producer

01C110 58901825 Code

OpFaillnallall COMMITCM3:

Company — complier: Forestry

PyKOBOAKTWIla oprammatum saaanTeast:

Head of applicant company

Menbaatiefixo E.H. Melniebenlco Yd.

(paelinutpoaKa) (decoding)

Page 2: Ihenor - dhard.ucp-is.comdhard.ucp-is.com/docs/specs/feedstocks/lignosulfonates/lignosulph… · BO3ayXe pR5OIe 0.1-1Eki —2 rvirliv1 3 ,tum cootsetcmyeT 4 Knaccy ollacHoent no FOCT

I illatimenonalme (iia3rianne) ii coc -ran rietuecTna ILfili ma -repitana. Name and composition of substance or material

J11111-10Cyrit4011aTM TeXEMlieeigfe nopouncoo6paname TY 2455-055-58901825-2008, Technical powder lignosulphonates spec. 2455-055-58901825-2008,

31Hruocymtbouami Texulligecloie nopounc000panue TOKCIPIFILI,

Technical powder lignosulphortates not toxic ue clauaLialar EiMpa)KelifiBIME pa3Thpa.)Katromprivm cBot4c-mam.11 Ha Komime noKpoBK

don't have clear irritation influence on skin and mucous eye membrane CJI14314CTLIe 06011014K14 rria3a; Kowto-pe3op6THEnioem ceHm6Pun3aproulee ecrBJ ie

skin-resorptive and sensitizingqffect are not discovered (according to transaction of toxicoiogical

(cornactio npo-roxony TQKCHKOMOrlit4eCKIIX kicerre i,RoBaHaii OF- 04 1 566 or 22.07.2,008 r investigations 011- 04 / 566 om 22.07.2008 ia)r Y1-1 C31-11A FHTHCHEil H o6LuecrBefmoro 3,.aopoBh5) FGYN SZNC hygiene and social health) Flpeigesn,Ho-Aonycfnimast KelluemparjHA 111411-1ocym40HaToB TeXHIltieCKIIX nopoinK005p331-1101X B

Limiting concentration of technical powder 1ignosuIphonates BO3ayXe pR5OIe 0.1-1Eki —2 rvirliv1 3 ,tum cootsetcmyeT 4 Knaccy ollacHoent no FOCT 12.1007-76,. in the air ofworking area-2 mg/m3 that corresponds to the zr class of the danger according to GUST 12.1,007-76

Plexog•rmm chipbem ,ang np0113BOACTRa JIHrflocysimiliollaToB TexifieNeCKPIX TiopoinK0o6pa3FITaix cllywar Jum-TocysnA4)0HaTbi T-extuviecime xalmme TY 2458-047-58901825-2006. Raw material for Technical powder lignosulphortates are Technical liquid lignosulphonates TY 2458-047-58901825-2006,

2.CBCRefiliSI 06 oprantnamill (sritfue)- rrpom3Rolurrreae HMI nocrasm,HRe. Information about company (person)-producer or supplier. Fla3Bamie oprai-nisaw: Name of the company: Forestry Development Corporation

Address: 188918, Leningrad region,

3.BgAm ouracitoro B03 eRei3eTBI1li 0 ye...110MIE lix BO3IIIIKHOBCHIJR.-

Types of dangerous effect and conditions of its appearance

4.Mepm n.epBoti uomouot, Measures offirst aid

5aMept.1 i cpeAcTsa oGeenemetmil nowapnori 6nonactioem. Measures to secure fire safety.

J1HrHOCY.flb4)OERTM Texmitieclare nopowKoo6pa.3Hme nowapo6e3onacHme, B3pbmo6e3oHaellbie. Technical powder lignosulphonates are fire-safe, non-explosive.

64Meptil no upeAorBpaigemuo vipe3BmgaiilithIX Measures to prevent extreme situations.

Ime

7.11pamma o6panxentra J xpanemta. Rules of storing and handling

Ynauoi3Ka ripo,ayKau gomKtia 11pQMBOXE,HTLO5 B tieTbi peXe er a fi C 6ymaxcHue MeaTIGI C The packing of the product should be made in four-layer paper bags with laminated gaiimuipoliamium emoem 14J1H B MATKlie Ro.wreibleptd («Bm--6erti)).

Page 3: Ihenor - dhard.ucp-is.comdhard.ucp-is.com/docs/specs/feedstocks/lignosulfonates/lignosulph… · BO3ayXe pR5OIe 0.1-1Eki —2 rvirliv1 3 ,tum cootsetcmyeT 4 Knaccy ollacHoent no FOCT

layer or into soft containers («Big Bags) . . ITopontox otient3rxrpocxonwleHw IOTA rourreanoro xpanefuri Tpe6yeT saxphrroro nomenlenna. Powder is very hygroscopic and needs closed packing for its long-term storage rapaHTHrunat cpox xpanetinsi 12 mecauen. Guarantee life-term 1 year from date of production

8.ErpaBH.113 0 wpm no o6ecnetteumo 600112CHOCTH 110J11b30Balreat

Rules and measures for guarantee safety of user XpaIIHTE) B cyxom, npoxnagnom, xopomo nponerpnaaemomITOMellICHHH.

Should be stored in dry room with good ventilation.

9.0113HtleaCHC H nrmiptecune cnoilerna. Physical and chemical characteristics

Ho nneuntemy Envy 9T0 mytunicTrzal nerxocunrmil II0p01110K OT caernoro go Temno-Kopatmeaoro unera 6es 6.necxa. Appearance: farinaceous, free flowing powder from light to dark brown colour without shine. rIopourox xoponto pacTaopnercz B sone, npenpantasicra B ognopoguro maccy. Powder has good in the water, after solubility turn into homogeneous mass. BnaxaocTr, He 6onee 8% Moisture not more than 8% KOHLICHTpaIIHR HOHOB Boylopo4a B 10%-HOM pacTnope JICTIT, He menee 4,0 eg. pH Concentration of hydrogen ions in 10% solution of TPLS not less than 4,0 unit pH flpegen npotutocm npn paCT50Ke111111 nucyatemmix o6pa3ticoa, ue menee 0,54 MIla (5,5 xrc/cm 2) Breaking point during stretching dry samples not less than 0,54 MPa (5,5 kgc/ cm2) Maccoan gona OCHOBEI0r0 BentecTaa, ae meHee 66% Mass fraction of base material not less than 66% Maccoaaa gonn 303111 IC tviacce cputx aemecra, ne 6onee 21,0% Mass fraction of ash to the mass of dry material, not more than 21,0% Macconam gonst pe,nyuktprotwax Betnecnin (PB) x macce cyxnx Berne/eta, tie 6onee 7,5% Mass fraction of reducing material (PB) to the mass of dry material, not more than 7,5%

10. CT26143MHOCTS u xumuttecuan aurrunnotrb. Stability and chemical activity. B yeR0111151X npaanntatoro xpaHefinn JICTU ABH5110TC51 XTAMWICCICH CTa61/11EHT,IMH.

On conditions of correct storage Lignosulfonates are chemically stable.

11. TOICCH4HOCTb.

Toxicity. Be TOKCIPIHM / Not toxic

12. Boaneriersue na ouppicatoutyto cpeny. Influence on the environment

13. YTHJIH3a1030 H saxopouemie onotton (oerancon). Utilization and burring of waste products (remains).

flo contacooaumo c nowe6cfrenem itonycicaeTea HCITOJI530BaHlie nErHocynt4onaTos no Hcrettefflux rapairrnCutoro cpoxa npn yCJI0B1414 coxpaueung nokasareneft mexicana B COOTBeTCIBHH C

Tpe6onamtuimu TY. As agreed with consumer, it is possible to use lignosulphonates after guarantee life-term on conditions that quality performance corresponds to Technical Conditions demand

Page 4: Ihenor - dhard.ucp-is.comdhard.ucp-is.com/docs/specs/feedstocks/lignosulfonates/lignosulph… · BO3ayXe pR5OIe 0.1-1Eki —2 rvirliv1 3 ,tum cootsetcmyeT 4 Knaccy ollacHoent no FOCT

14. lipaintaa Tpauctioginposattym. Transportation rules.

iiHrHOC•.11b4)0H4rbi Texuuttecxue nopouncoo6pasnme uonmunit Tpancnopmpona-rbou B yrtaxosanHom Hue B saxpigrux TpancrtopTHEax cpeAcmax B COOTBeTCTBHH C npasunamit nepeHo3KH rpyson, AORCTBYEOTAHMH Ha ouatutom BH4e Tpaticnovra H He SIBASHOTC51 onacHum rpy3om HO rOCT 19433-88.

Technical powder lignosulphonates should be in closed carries in accordance with freight rules, for this type of transport and are not dangerous goods in accordance with GUST 19433-88.

15. litt4topmatutst o mexcayaapognom u HatwoHaabHom 3alcoitoArreabeTse. Information about international and national legislation.

REACH: lipmpoatil nammep, He Tpe6ytouuttl peracTpamm REACH. Natural post reacted polymer REACH exemption (ECHA FAQ 7.7).

16. A0110411HHTeablian 0/14)0PrilagHt

Additional information .TIHrHocynb.oHant TeximitectcHe nopouncoo6pasHme npHmelisnarcm: Ligrzosulfonate are used - B XHMHtleCKOfi Hp0ME,HWICHHOCTH B npoamotuctse necnnumos H Hparpaawrenell cemsm; - in chemical industryfor production pesticides and disinfectant for sabadilla. - B He4rrenepepa6arbmatonkeft upomaunnemmera altHa perympoHamm BMKOCTH 6yposmx

pacTsopoB H B Kattecme KomnoHeHros reneo6pa3rouutx cucTem Aug perynuposaHuu CIIKTHaTpaHHOHHEIX HOTOKOB H orpatuttlettuz BOAOHPHTOKa B npoueccax, noHmtnaloutux Hecirreozualty;

- in petroleum refining industry for regulation of drilling mud viscosity and as component of gel- forming systems for regulation of filtration flows, for limit water production in process, which increase oil recovery. - H ttemeamoit rtpommumeHaocnt B KaaecTse nstactmlama-ropa Hemewra H pasmosanenst umama; - In cement industry as cement plasticizer and as liquefier of mud - B JIHTeRHOIVf npowasoncrue KaK CBA3y10IHHe Ao63mm B cocraue nponmonpurapHux Kpacox; - in foundry as connecting addition in dressing - tax Hexo,knoe cbiphe upset nponsnoAcTse nHrHorymarou. - As feed stock in production of lignoevmates.

flurnocy.TmcDowarm Hmnycxatercit rio texHonorknecKomy Lignosuplhonates are produced according to the technical order perstamemy «Hp0H3B0):(CTBO sunnocyrxr4oHatou Texantieclatx nopouncoo6pastuax «Production of technical powder lignosulphonates on spray drier, productivity 7-12t/h on Ha pactmuurre.mbHorx cyrtmnxe Hp0H3BOAHTCJILHOCTE110 7-12 Thiac no Henapstemoit snare» evaporable moisture» N258901825-43-08 yrBepxyzermomy B yeTaHOBASHHOM nopsume, H

)103DKEITA COOTBeerCTBOBatb Tpe6oHaatimm TY 2455-055-58901825-2008. (CasuerrapHo- wmitemlionortnecxoe 3annotteime Ha npoitramo Ne 47.01.05.24511.000656.10.05. OT

24.10.2005r.) N258901825-43-08 approved in determinate order and should correspond to Technical Conditions 2455-055-58901825-2008 demand. (Sanitary-epidemiological conclusion on the production N2 47.01.05.24511.000656.10.05. dd 24.10.2005 )

CaHirrapuo — stm,r(emilortorrimemoe 3axmotiemie Ha perriatvtenT N2 47.05.02.000.T.000 I 69.09.08 OT 11.09.2008 r. Sanitary-epidemiological conclusion on regulations N2 47 T.000169.09.08 dd 11.09.2008

HatiallEHHK TexHo.uorHgecKoro ceruena Chief of Technological department

A.B.KaprtoB Karpov A.B.

05.03.2012r.