IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells

7/22/2019 IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells

1/98

Vrkdspbrt kdf Pnobi`hdkthbd hd

Sbeyinr1Gueenrndn _bekr Onees

Skue @ebi

Ikx Sekdol Hdsthtut gr Sbeyinr Gbrsomudj, Ikhdz


2/98

Butehdn

;. Omkrjn trkdspbrt hd Brjkdho _nihobdfuotbrs

-Mben Vrkdspbrt, Nenotrbd Vrkdspbrt

0. Smbtbourrndt Jndnrkthbd hd Brjkdho _bekr Onees

-_pkon Omkrjn, Pnobi`hdkthbd

?. Pnobi`hdkthbd hd brjkdho sbekr onees

-@hibenouekr Pnobi`hdkthbd, Vrkp-ksshstnfcPnobi`hdkthbd

6. Brhjhd bg tmn Pnobi`hdkthbd hd Brjkdho _bekr Onees

-OV nenotrbeuihdnsondon, hfnkehty gkotbr, Nxohtbd Fhggushbd

50


3/98

W`hks (W)

3.; ; ;3;3

-6

;3-?

;3-0

;3-;

;33

3.;?i 3.?i 3.: iA

(K/i0

)

A W

E8

=

0

?

KSE 7=, ??3= (;887)

Ourrndt-Wbetkjn omkrkotnrhstho bg k SSW Mben-Bdey Fnvhon

SSW

Ku HVB

Mben Ourrndt hs _pkon Omkrjn (@uel) Ehihtnf !!

Ws

oi0

:;3>

5?


4/98

56

_OEO1 SENF kots ks k Okpkohtbr

HVBKuSSW

W93

HVBKu SSW

W4

+ + ++++

++

HVB

KuSSW

+ + ++

+ +

++

W44

++

+

+

++

+

+

A9omkrjn vnebohtyOW W/E

Omkrjn fndshty kdf Nenotrho ghnef ~ W


5/98

;3;8

;303

;30;

;300

;30?

;306

;30>

;307

;3-;3

;3-8

;3-=

;3

-:

GNV

m,

GNV(i

0/Ws)

p (i-?)

ENF

BO;O;3-SSW

V908> L

Ib`hehty hs Fndshty Fnpndfndt !

Smys. Pnv. Entt. 8;, 0;773; (033?)

5>


6/98

3Vrkdspbrtenvne

Nquheh`rhui

envne

3

Ng

Ebw okrrhnr fndshty Mhjmnr okrrhnr fndshty

Ng

0

;ed

V

V

;ed

Nggnot bg Okrrhnr Fndshty257


7/98

; ;3 ;33;3-:

;3-7

;3->

;3-6

;3-?

;3-0

;3-;

;33

;3;

V908= L

V90:0 L

V90>0 L

V90?? L

W (W)

A(K

/i0)

Vmnbrnthoke ibfne gbr (p,V,N) fnvnebpnf

Smys. Pnv. Entt. 86, 03773; (033>)

5:


8/98

Nenotrbd Vrkdspbrt hd SSW

Ebw Nenotrbd Ourrndt, _tnnp A-W1 Vrkps 2

Ok OkMbens

Nenotrbds

3.?6 ui

3.00 ui 3.?: ui

3.? ui

KSE 7=, ??3= (;887)

5=


9/98

;3->

;3-6

;3-?

;3-0

;3->

;3-6

;3-?

;3-0

;3-;

;33

;3;

0 ? 6 > 7 : = 8;3 03 ?3;3

->

;3-6

;3-?

08> L

0:> L

0>> L

0?> L

0;> L

;8> LOurrndtFnds

hty(K/i)

(k)

(o)

DP_-SSW

E 9 ?03 di

INM-SSW

E 9 0:3 di

08> L0:? L

0>; L

0?3 L

0;; L

OurrndtF

ndshty(K/i)

BO;O

;3-SSW

E 9 ?33 di

(`)

083 L

0:> L

0>> L

0?> L

0;> LOurrndtFndshty(K/i)

W-W`h(W)

Jkusshkd E^IB kdf Jkusshkd Vrkps2

Vrkp-ehihtnf Nenotrbd ourrndts hdSSW fnrhvkthvns kesb fnsorh`nf

`y Jkusshkd trkp fhstrh`uthbd

Dt ~ 0;3;:

oi-?

t9 3.;3 nW

Nt

~ 3.7-3.: nW

Smys. Pnv. @ =?, ;=??3; (03;;)

58


10/98

_ebpn vs E^IB pbshthbd

0.7 0.= ?.3 ?.0 ?.6 ?.7 ?.= 6.3 6.0

3

;

0

?

6

>

7

:

=

_

ebpn

E^IB (nW)

DP_-SSW

BO;O;3-SSW

S?MV

G=@VSG;3V@V

SOSFV@V

SO@I

S(DFH0BF-V0)

SG;OWVS

SODNSW

Vrkp-grnn

Nxpekhdnf `y omkdjn bg Jkusshkd Vrkp Fnptm!!!

5;3


11/98

-?.=

-?.7

-?.6

-?.0

-?.3

-0.=

-0.7

-0.6

-0.0

Vrkp

DP_-SSWBO

;O

;3-SSW

G=@VSG;3V@V

SOSFV@V

S?MV

EÎB

Nenotrbd Vrkpphdj hd BENFs1

Bdn lhdf bg trkp rnspbdshèn gbr trkpphdj hd kee BENFs!!!

Dt ~ 0-?;3;:oi-?

t9 3.;3 nW

Nenotrbd ourrndt okd `n prnfhotnf wmnd EÎB hs ldbwd

5;;

Dkturn Iktnrhkes ;; , p.==0 (03;0)


12/98

Brhjhd bg Vrkp2

Smbtb-bxhfkthbd2

Zktnr-pbeyinr obipenxns2

Myfrktnf-bxyjnd obipenxns B0(M0B)0

Vrkp-fnptm 3.;-3.0 nW

Sbtndthke Fnnp Vrkp

Sntnr Mb nt ke., Kfv. Ikt. 0;, 6:6: (0338)

O. Okip`nee, O. Phslb, A. E. @rfks, Jnbrjhk Vnom

5;0

B eh


13/98

Butehdn








-OV nenotrbeuihdnsondon, hfnkehty gkotbr, Nohtbd Fhggushbd

5;?


14/98

Jbbfikd kdf Pbsn1 A. Kppe. Smys. 60, ;8:;, 0=0?

Ndnrjy

x

E

NO

NW

@ngbrn ehjmt nxohtkthbd

ghnef1N9W/E

inkd okrrhnr frhgt endjtms1

wd9 dtdNwp9 ptpN

Kssuipthbds1

udhgbri jndnrkthbd bg n-mpkhrs tmrbujmbut tmn vbeuin bg tmn kothvn ekynr

dbd hdanothbd obdtkots gbr `btm nenotrbds kdf mbens

bdn fhindshbdke oksn

fhggushbd hjdbrnf

Smbtbourrndt hd k snihobdfuotbr15;6


15/98

@uhet-hd Wbetkjn1

W93

W9W`h

EhG SNFBV

W`h

EhGW`h

SNFBV

W93

Jbbfikd kdf Pbsn1

@MA _bekr Onee1

Wngg9W-W`h

5;>


16/98

ikhd okrrhnr frhgt endjtm wd9dtdN kdf wp9ptpN 55E ,N9W/E9obdstkdt.

+

Rmd

W9WBO-W`hks

E

A-W omkrkotnrhstho (Bmiho rnjhin)1

Kgtnr ehjmt nxohtkthbd

E

WnJA ppdd tt

A

W

W

_ikee kppehnf vbetkjn15;7


17/98

dtd 4 ptp , wd44 E, wp5 E

Pnobi`hdkthbd (t Ehihtnf rnjhin1 0/;0/;0/; < JWAWnJA dd t

A

W

W

W;/0+R

md

E;

W9WBO-`hks

Hdtnrinfhktn vbetkjn15;:

;=


18/98

skturkthbd rnjhin1

wd4 E, wp4 E, N9W/E9obdstkdtnquke nenotrbd kdf mben ourrndt.

A-W omkrkotnrhstho hs1

nJEA

+R

md

W9WBO-`hks

E

A

W

W

W;/0

Obdstkdt

Mhjm Wbetkjn Pnjhin15;=

_ Om Eh h f Sm;8


19/98

_OE Smbtbourrndt1

A

W

W;/0+R

md

E;

W9WBO-`hks

_pkon-Omkrjn Ehihtnf Smbtbourrndt1

0/;6/?0/;6/?

6/;

.0 nv

Oktmbfn

EhG/Ke

?.= nv

Ehjmt

Nenotrbd trkdspbrt

Mben trkdspbrt

Omkrjn trkdsgnr

OV-stktn

OV-stktn1Hg r39; di kdf r9?, tmnd

`hdfhdj ndnrjy hs 3.> nW !!

Smbtbourrndt hd k Sbeyinr1Gueenrndn _bekr Onee503

J. Xu, A. Jkb, A. O. Muiinend, G.

Zufe, K. A. Mnnjnr, _ohndon ;88>,

0:3, ;:=8.

K e JP I f e t @MA _ e O ee 5 0;


21/98

Kppey JP Ibfne tb @MA _bekr Onee1

MBIBSSW

MBIB O73

EÎB O73

0.8 nW

?.: nW

>.; nW

7.; nW

SNFBV1S__

I>.0 nW

EÎBSSW

EhG/Ke

I?.3 nW

EÎB9EÎBSO@IMBIB9MBIBSSW

Nggnothvn Infhui1

50;

Sm h SSW SO@I (; 6 %) e ee5 00


22/98

3.3; 3.; ; ;3

;

;3

Apm9AE-AF

\K/i0Y

W3-W \WY

frhgtfhggushbd

Smbtbourrndt hd SSW1SO@I (;16 wt.%) sbekr onees

fnvhkthbd kt mhjm (rnvnrsn) vbetkjns fun tb ghnef-fnpndfndon bg J2

3.3 3.0 3.6 3.7 3.= ;.3

-?3

-03

-;3

3

;3

03

WBO

W3

AF

AE

Apm9A

E-A

F

A\K/i

0 Y

W \WYA W

A9qJE

E9;03 di

V908> L

500

_ t th P h5 0?


23/98

_kturkthbd Pnjhin1

IFIB-SSW1SO@I

_kturktnf rnjhin1 pmbtbourrndt A9n J(N,V) Efun tb fhssbohkthbd bg

`budf nenotrbd-mben pkhrs

@rkud1 A. Omni. Smys. =3, ;8=6, 6;>:

3.; ; ;3;

;3

08> L0:3 L0>3 L0?3 L

0;3 L

Apm

\K/i

0Y

WBO

-W \WY

Smys. Pnv. Entt.,8?, 0;773; (0336)

73% Aso

Kt Asobdey 73% bg `budf

n-m pkhrs hs fhssbohktnf !!

nJIK]E

50?

_ e O ee F h I f e5 06


24/98

_bekr Onee Fnvhon Ibfne

Hdoeushbd bg (Ekdjnvhd) rnobi`hdkthbd kdf J(N,V) rnquhrns duinrhoke

ibfnehdj

;3-0

;3-;

;33

;3;

;33

;3;

fktk 08> L

fktk 0>3 L

q J(W) E 08> L

q J(W) E 0>3 L

shiuekthbd 08> Lshiuekthbd 0>3 L

Aehjmt-Afkrl\K/i

0

Y

Wbo-W \WY

Smys. Pnv. @ :0, 3=>03> (033>)

IFIB-SSW1SO@I

506

V t h @NM @I@ SSW/ SO@I `e f5 0>


25/98

?.6 ?.7 ?.= 6.3 6.0 6.6 6.7 6.=

;3-;;

;3-;3

;3-8

;3-=

;3-:

B

B

*

B

B

* ;

? rkd

B

B

*

B

B

* ;

? rkd

E;E

W;

J

E;E

W;

J\i

0/WsY

;333/V \L-;Y

Nenotrbds

Mbens

Kt V90;3 L gkotbr ;3?fhggnrndon hd n/m ib`hehthns

Vrkdspbrt hd k @NM-@I@ SSW/ SO@I `endf

;16 wt. %

50>

Sm h m @NM @I@ SSW/ SO@I `e f


26/98

3.3; 3.; ; ;3

;33

;3;

08> L

0:3 L

0>3 L0?3 L

0;3 LA pm9A E-AF

\K/i

0Y

W3-W \WY

Apm

W;/0

Ehjmt-hdtndshty (J) fnpndfndon 2

Smbtbourrndt hd tmn @NM-@I@ SSW/ SO@I `endf

B` th g _OE m t t5 0:


27/98

B`snrvkthbd bg _OE pmbtbourrndt

3.3; 3.; ; ;3

3.;

;

;3

A pm\K/i

0 Y

W3-W \WY

E90:> di

V90;3 L

Wskt

;3

;

;3

;3 ;33

;

0

?

6

Apm

C W3-W9;3 W

_9 3.:7

Apm

\K/

i0Y

_ 9 3.8>

Apm

C W3-W93.; W

_9 3.>; W

skt

\W

Y

Hdohfndt Ehjmt Sbwnr \iZ/oi0Y

Ehjmt-hdtndshty fnpndfndon1

=3 iZ/oi

0

7 iZ/oi0

Kt Asoebssns fun tb `hibenouekr rnobi`hdkthbd wnkl (6%)

Smys. Pnv. Entt.86, ;07730 (033>)

50:

Ebw @kdfjkp Sbeyinr SOSFV@V (Lbdkrlk) 50=


28/98

|0=

Ebw @kdfjkp Sbeyinr SOSFV@V (Lbdkrlk)

Wbo 9 3.7> W

Aso 9 83 K/i0(SO 7;@I)

9 ;;3 K/i0(SO:;

@I)

GG 6:%

SON 9 0.7: % (SO7;@I)

9 ?.;7 % (SO:;@I)

Ime`komnr nt ke, Kfv. Iktnr., ;=, 0==60==8 (0337)

Sbey \0,7-(6,6-`hs-(0-ntmyemnxye)-6M-

oyoebpndtk\0,;-`


29/98

SOSFV@V1SO@I _bekr Onees

-3.0 -3.; 3.3 3.; 3.0 3.? 3.6 3.> 3.7 3.:

-73

->3

-63

-?3

-03

-;3

3

;3

08>

0:3

0>3

0?3

0;3

AE\K/i

0Y

W \WY

Ebw Ghee Gkotbr (~63-6>%) obi`hdnf whtmsqukrn rbbt rnjhin hd pmbtbourrndt1

_pkon-Omkrjn Ehihtnf222

3.; ;

;3

;33

V \LY

08>

0:3

0>3

0?30;3

Apm

\K/i0Y

W3-W \WY

_hdjen Okrrhnr Fnvhons 5?3


30/98

|?3

_hdjen Okrrhnr Fnvhons

3.3 3.6 3.= ;.0 ;.7 0.3

;3

;33

;333

;3333

A\K/i

0Y

W-Wrns

-W`h\WY

n9:x;3

-=i

0/Ws

3.3 3.: ;.6

;

;3

;33

;333

A\K/i

0Y

W-W`h-W

rs

m9?x;3

-=i

0/Ws

E^IB

MBIB

E^IB

MBIB

Mben/Nenotrbd ib`hehty keibst `kekdonf1 _O Ehiht ^dehlney!!!

Sbeyinr1Gueenrndn @endf

Hdtndshty fnpndfndon bg Smbtbourrndt1 5?;


31/98

Hdtndshty fnpndfndon bg Smbtbourrndt1

3.; ; ;3

;3

;33

A

pm

\K/i

0Y

W3-W \WY

Apm W;/0

Apm J

Wskt9 obdstkdt

Wskt

Ghdjnrprhdt bg rnobi`hdkthbd ehihtnf ourrndt!!!

Kfv. Gudot. Iktnr. 0338, ;8, ;;37;;;;

_qukrn Pbbt Fnpndfndon< vs so ehihtnf 5?0


32/98

|?0

_qukrn Pbbt Fnpndfndon< vs so ehihtnf

Vwb fhggnrndt brhjhds gbr k squkrn rbbt fnpndfndon bg Apm

_pkon Omkrjn Ehihtnf1 n 44 m

WqJA mrpm

0>.3

3

:>.3

=

8)(

Apm W;/0

Apm J?/6

WsktJ;/0

W. F. Ihmkhentomh nt ke.,Smys. Pnv. Entt. 86, ;07730 (033>)

K. I. Jbbfikd kdf K. Pbsn, A. Kppe. Smys. 60, 0=0? (;8:;)

-ehihtnf1 wd,p9 tN5E


33/98

Butehdn








-OV nenotrbeuihdnsondon, hfnkehty gkotbr

5?6@hibenouekr Ekdjnvhd rnobi`hdkthbd


34/98

Ehihtnf `y Fhggushbd bg Nenotrbds kdf Mbens tbwkrfs nkom btmnr

Orhthoke Obuebi` Pkfhus1 hdfhdj ndnrjy mben-nenotrbd 9 lV

q0/6lV (03 di) 44 inkd grnn pktm hd SSW (;-? di)

03di

;-? di

@hibenouekr Ekdjnvhd rnobi`hdkthbd

^. Ke`rnomt kdf M. @ssenr, Smys. _tktus _behfh @ ;8;, 6>> (;88>)

S. Ekdjnvhd, Kdd. Omni. Smys. 0=, 0=8 (;83?)

Mbw tb omkrkotnrhzn rnobi`hdkthbd25?>


35/98

_tufy Pnobi`hdkthbd kt Wbo !!

Inksurn Wbo~ Ehjmt Hdtndshty!!

_bekr onee whtm `hibenouekr rnobi`hdkthbd1

SJ

DS

q

lV

q

N

W

ojkp

bo

0

;ed

KSE =7, ;0?>38 (033>)

N. K. _omhgg, _be. Ndj. Iktnr. _be. Onees 033?, :=, >7:.

Mbw tb omkrkotnrhzn rnobi`hdkthbd2

Ehjmt hdtndshty fnpndfndon bg W 5?7


36/98

Ehjmt hdtndshty fnpndfndon bg Wbo

Ehdnkr fnpndfndon bg Wbobd ed(H) whtm sebpn lV/q, d9; !

; 0 ? 6 >

3.7>

3.:3

3.:>

3.=3

3.=>

3.83

Wbo

\WY

Ed (hdtndshty) \k.u.Y

08> L

0>3 L

0;3 L

KSE =7, ;0?>38 (033>)

IFIB-SSW1SO@I

Bdey hibenouekr Pnobi`hdkthbd!!!!!

Kee pbeyinr sbekr onees1 Nenotrbd trkps

5?:


37/98

Kee-pbeyinr sbekr onees1 Nenotrbd trkps

Pnobi`hdkthbd

;. Ekdjnvhd

0. _mboleny-Pnkf-Mkee

-

+

-

+

- - -

+ + +

-

--

-;0

Skrkintnrs1

Dt, Vt, Od, Op

;;;; / ppOddOdppdDOOP pdtpd_PM

)( 0

hEkdjnvhd ddpP )(

3

pd

r

q

W ehjmt hdtndshty fnpndfndon5?=


38/98

Wboehjmt hdtndshty fnpndfndon

;3 ;33 ;333

;.0>

;.?3

;.?>

;.63

;.6>

;.>3

Ehjmt hdtndshty (Z/i0)

Wbo

(W)

Bdey Ekdjnvhd rnobi`hdkthbd hdoeufnf

_\lV/qY9;

Kt Wbobdey ebssns vhk Pnobi`hdkthbd!!!!!

IFIB-SSW1SODNSW

Kee-pbeyinr1 _PM rnobi`hdkthbd nggnots bd Wbo5?8


39/98

Kee-pbeyinr1 _PM rnobi`hdkthbd nggnots bd Wbo

;3 ;33 ;333

;.0>

;.?3

;.?>

;.63

;.6>

;.>3


W

bo(W) Od,p9 ;.6;3

-;=i?s-;

>.3;3-;:

i?

s-;

>.3;3-03i?s-;

Smbtbourrndt bg IFIB-SSW1SODNSW563


40/98

Smbtbourrndt bg IFIB-SSW1SODNSW

-;3 -= -7 -6 -0 3 0->3

-63

-?3

-03

-;3

3

;3

03

Wbetkjn (W)

A(K

/i0)

AF

AE

Jikx9 8.6 ;30: i-?s-;

Lg9 7.: ;30s -;

k 9 3.70 di

5r4 9 0.7

Dt9 8.7 ;300

i-?

Vt9 0>33 L

Od,p9 ;.= ;3-;=i ?s-;

@btm Ekdjnvhd kdf _PM rnobi`hdkthbd hdoeufnf

Kfv. Gudot. Ikt. ;:, 0;7: (033:)

Zmkt fbns ht inkd2

Inksurn SENF ks k sbekr onee1 56;


41/98

Inksurn SENF ks k sbekr onee1

INM-SSWOd9Op9;;3

-;= i?/s

lV/q

I.I. Ikdfbo nt ke. Kpp. Smys. Entt. 8;, 07?>3> (033:)

I.I. Ikdfbo nt ke. Kfv. Gudot. Iktnr. ;:, 0;7:-0;:? (033:)

Brhjhd bg _PM Okpturn Obngghohndt1560


42/98


?.0 ?.6 ?.7 ?.= 6.3 6.0 6.6 6.7 6.=

;3-0;

;3-03

;3-;8

;3-;=

p

q

O 9 sbekr onee

O 9 - mben-bdey fnvhon

OkpturnObngghohndts

(i?/s)

V-;(;3

-?L)

pDq

pDOl tptp_PM

Dt9nenotrbd trkp

Smys. Pnv. Entt. ;3:, 0>7=3> (03;;)

Brhjhd bg _PM Okpturn Obngghohndt156?


43/98


03di

;-? di

pDlr t_ P M

)3( p_ P Mq

l

Vrkpphdj

Hfni ks Ekdjnvhd whtm hiib`hen nenotrbd!

566

Fhggushbd Ourrndt W5W`h


44/98

W93

Ok HVB

W`h

W9W`h

OkW`h

HVB

W4W`h

Ok

W

HVB

Fhggushbd Ourrndt W W`h

Frhgt Fhggushbd

FrhgtFhggushbd Fhggushbd

fx

fpnFNnpA

)/nxp(~ dlVqWA

v9N

BENF Ourrndt-vbetkjn omkrkotnrhsthos156>


45/98

BENF Ourrndt vbetkjn omkrkotnrhsthos1

Vmrnn rnjhins1

;. Enklkjn ourrndt

0. Fhggushbd rnjhin

?. Frhgt rnjhin

;.3 ;.> 0.3 0.> ?.3 ?.> 6.3 6.>;3

-7

;3->

;3-6

;3-?

;3-0

;3-;

;33

;3;

;3

0

;3?

A\K/i0Y

W \WY

;.

0.

?.

W`h

;nxp3

lV

qWAA

?

0

=

8

E

WA

enklkjnPWH

Hfnkehty Gkotbr

Brhjhd bg Hfnkehty Gkotbr2 567


46/98

Brhjhd bg Hfnkehty Gkotbr2

Hfnkehty gkotbr nqukes 0 hd tmn oksn bg trkp-ksshstnf

rnobi`hdkthbd hd k oeksshoke p-daudothbd

;0

nxp3lV

qWAA

O. V. _km nt ke., Srbo. HPN 6>, ;00= (;8>:)

_upnr Xneebw SSW ENF56:


47/98

_upnr Xneebw SSW ENF

Vmn hfnkehty gkotbr gbr k _upnr

Xneebw ENF wks fntnrihdnftb mkvn k vkeun bg 0 kt rbbi

tnipnrkturn.

Vmhs obrrnspbdfs tb _PM

rnobi`hdkthbd grbi trkpphdj

shtns1

;

0nxp3

lV

qWAA

;

ed

W

A

q

lV

Zmhtn BENFs1 Nihsshvn _PM rnobi`hdkthbd256=


48/98

Zmhtn BENFs1 Nihsshvn _PM rnobi`hdkthbd2

Vrkp-ksshstnf rnobi`hdkthbd hd obdvndthbdke pbeyinrs

kppnkrs tb `n dbd-rkfhkthvn.

Hd k wmhtn nihtthdj pbeyinr, rnf fyns hd tmn `eun `kol`bdn

gudothbd ks nihsshvn trkps.

MBIB

E^IB

Ekdjnvhd & _PM rnobi`hdkthbd!568


49/98

Ekdjnvhd & _PM rnobi`hdkthbd!

-3.0 -3.; 3.3 3.;

;

0

?

6Ourrndt

Ehjmt>>3 di Ebdjpkss Ghetnr

Ehjmt

@eun Fhomrbho Ghetnr

(lV/q

edA/W)-;

W-W`h\WY

0.3 0.> ?.3 ?.>;3

-;?

;3-;0

;3-;;

;3-;3

;3-8

;3-=

;3-:

;3-7

633 >33 733 :333

03

63

73

=3

;33

N

EHdtndshty\k.u.Y

Zkvnendjtm \diY

>>3 di Ebdjpkss Ghetnr

@eun Fhomrbho Ghetnr

Euihdkdon\k.u.Y

W \WY

Euihdkdon bg rnf fyns gbeebws _PM rnobi`hdkthbd,

wmnrnks tmn `eun ehjmt gbeebws Ekdjnvhd rnobi`hdkthbd.

Butehdn 5>3


50/98

Butehdn






-@hibenouekr Pnobi`hdkthbd, Vrkp-ksshstnf Pnobi`hdkthbd


-OV nenotrbeuihdnsondon, hfnkehty gkotbr

Omkrjn trkdspbrt hd @AM _bekr Onee5>;


51/98

j p

3.; ;;3

3

;3;

;30

;3?

;36

V 9 086 L

;:3 di83 di

A\K/i

0 Y

W-WPs

-W`h\WY

?

0

3

=

8

E

WA

nr

n0.3x;3-:i0/Ws

Kfv. Gudot. Iktnr. 033?, ;?,

Nenotrbd trkdspbrt hd SO@I kdf Mben trkdspbrt hd FbdbrSbeyinrs krn trkp-grnn1 Db _PM rnobi`hdkthbdnxpnotnf

Btmnr Sbeyinr1gueenrndn sbekr onees1 5>0


52/98

_ebpn9lV/q1 Bdey @hibenouekr Pnobi`hdkthbd

OV stktn nenotrbeuihdnsondon hd BSW 5>?


53/98

Znkl nenotrbeuihdnsondon grbi tmn omkrjn-trkdsgnr stktn

hs b`snrvnf hd brjkdho sbekr onees

Oktmbfn

Kdbfn

Koonptbr

Fbdbr

NE Hfnkehty gkotbr2 5>6


54/98

y

Hfnkehty gkotbr bg ; hs

inksurnf gbr tmn OV

nenotrbeuihdnsondon

Nihsshbd brhjhdktns grbi k

grnn-okrrhnr `hibenouekr

rnobi`hdkthbd prbonss!

Wbovs Ehjmt hdtndshty5>>


55/98

bo

K obdtrh`uthbd bg trkp-ksshstnf rnobi`hdkthbd hs b`snrvnf gbr

S?MV1SO@I

Pnobi`hdkthbd hs `hibenouekr gbr btmnr sbekr onees

Dbdrkfhkthvn _PM rnobi`hdkthbd2 5>7


56/98

Okd `n nxpbsnf `y ebblhdj kt tmn vbetkjn fnpndfndon bg

tmn NE qukdtui ngghohndoy

S?MV1SO@I

Obipnththbd_PM kdf

@hibenouekr!

S?MV1SO@I sbekr onees5>:


57/98

St5 0;3;>oi-? 2 _PM sikee

Mben trkps hd S?MV2

S?MV1SO@I sbekr onees5>=


58/98

Hd S?MV1SO@I sbekr onees tmn Ekdjnvhd rnobi`hdkthbd

hs strbdjey rnfuonf ~;3? (ONEHW)

Shvrhlks, Bstnr`kolk, Auslk nt ke., Smys. Pnv. Entt. 86, ;:7=37 (033>)

Vwb fhindshbdke Ekdjnvhd rnobi`hdkthbd hd tmn

ekineekr struoturn bg PP-S?MV

Auslk, Bstnr`kolk nt ke., Kppe. Smys. Entt. 8>, 3;??3? (0338)

S?MV1SO@I sbekr onees5>8


59/98

;30 ;3?

3.>3

3.>0

3.>6

3.>7

3.>=

3.73

Pnfuonf Ekdjnvhd + _PM

W

bo

\WY

Ehjmt Hdtndshty \Z/i0Y

Ekdjnvhd + _PM

lV/q

Kfvkdonf Ndnrjy Iktnrhkes, koonptnf

Nxohtbd Vrkdspbrt2


60/98

p

Smbtb-nxohtkthbd

Ekdjnvhd Pnobi`hdkthbd, Vrkp-ksshstnf Pnobi`hdkthbd

Ok

HVB

57;

Dnkt Sbeyinr SE fnoky1


61/98

3 033 633 733 =33

;3-;

;33

nxp.

okeo.

INM-SSW 9?33ps

Euihdn

sondon(k.u

.)

Vhin (ps)

Hdtrhdsho Nxohtbd Ehgnthin ~ ?33 ps2

Nxohtbd fhggushbd


62/98

Omkdjn Ndnrjntho fhsbrfnr hd SSW fnrhvkthvns

Pnfuonf ndnrjntho fhsbrfnr ndmkdons nxohtbd fhggushbd!!

:

Sbeyinr , inW F, oi0

/s (?33L), i0

/Ws

DP_-

SSW;0> ? ;3 -6 ;.> ;3 -;0

INM-

SSW;3> ;.; ;3 -? > ;3 -;;

@NM-SSW 80 0 ;3-? 0 ;3 -8

B

B

d

B

B

B

3.>

3.>

B

Bd

DP_-SSW

INM-SSW

@NM-SSW

N

F

N

F

SMX_HOKE PNWHNZ @ :0, 36>0;: 033>

57?

Dnkt Sbeyinr SE fnoky1


63/98

3 033 633 733 =33;3

-;

;33

nxp.

okeo.

DP_-SSW 9=33ps

Euihdnsondon

(k.u.)

Vhin (ps)

3 033 633 733 =33

;3-;

;33

nxp.

okeo.

INM-SSW 9?33ps

Euihdnsondon

(k.u.)

Vhin (ps)

3 033 633 733 =33;3

-0

;3-;

;33

nxp.

okeo.

Euihdnsondo

n(k.u.)

Vhin (ps)

@NM-SSW 9033ps

-Enss fhsbrfnr, smbrtnr

SE fnoky-Enss fhsbrfnr, ibdb-

nxpbdndthke fnoky

F9?;3-6oi0/s F9;;3-?oi0/s

F90;3-?oi0/s

Nxohtbd fhggushbd


64/98

Ndnrjntho fhsbrfnr hd SSW fnrhvkthvns

Nxohtbd fhggushbd endjtm >-: di hs hdfnpndfndt bd tmnkibudt bg ndnrjntho fhsbrfnr!!!!

=

3 03 63 733.3

3.0

3.6

3.7

3.=

;.3

DP_-SSW< EF9> di

[undomhd

jngghohndoy

Sbeyinr ghei tmholdnss \diY

INM-SSW< EF97.? di

@NM-SSW< EF97 di

obdstE

FE

F

F

F

t

t kdf

- qundomhdj

ondtnrs2

57>

Krn nenotrbd trkps kesb nxohtbd qundomnrs2


65/98

^dhvnrske nenotrbd trkp fndshty ~ >;3;:oi-?

Fhstkdon `ntwnnd trkps ;/(>;3;:);/? 9 ;0.7 di

Nxohtbd mks tb trkvne 7 di tb rnkom k trkp

Inksurn nenotrbd trkdspbrt kdf nxohtbd fhggushbd

hdfnpndfndtey hd k ibfne systni whtm shdjen

nxpbdndthke SE fnoky!!

577

Ibfne _ystni SOSFV@V


66/98

pbey\0,7-(6,6-`hs-(0-ntmyemnxye)-6M-oyoebpndtk\0,;-`


67/98

Kee _hdjen nxpbdndthke!!

57=

SE fnoky Kdkeyshs (nxp. fnoky)


68/98

; ; 6

g

rFot t

_tnrd-Wbeinr gbriuek19 SE fnoky thin bg `endf whtm SO@I obdondtrkthbd o

g9 SE fnoky thin bg prhsthdn SOSFV@Vr 9 _ui bg tmn nxohtbd rkfhh

F 9 Nxohtbd fhggushbd obngghohndt.

r~ ; di

F9?;3-?oi0/s

578

@koljrbudf [undomnrs


69/98

3q o o

3

; ;

6 6g

rFo rFq t t

3

3

; ;6

g

rFot t

q931 Hdtrhdsho Nxohtbd Ehgnthin 3

SO@I

@koljrbudf [undomnrs

+_tnrd Wbeinr1

g9 SE fnoky thin bg prhsthdn SOSFV@V

39 SE fnoky thin bg sbeuthbd

5:3

Jrkpmhoke Pnprnsndtkthbd o3


70/98

o397;3;:oi-? , nquke tb Dtrkpnenotrbds ! ! ! ! !

5:;

Zmkt k`but SE ngghohndoy2


71/98

tg9

;

+ ldr+ l

fhgg

39

;

+ ldr

lfhgg

9

;

tg

;

t3

9 6 rFo3

9 + l

dr+ l

fhgg

9

;t3

+ 6 rFo3

9; t

3ldr

;+6 rFo3t

3

Inksurnf ehgnthin hd ghei

Inksurnf ehgnthin hd sbeuthbd

_tnrd-Wbeinr

SE Xhnef

5:0

SE grbi hdtnjrkthdj spmnrn


72/98

3ldr93.:0

Obdoeushbds 5:?


73/98

Hi`kekdonf trkdspbrt kdf strbdj rnobi`hdkthbd enkf tb k

squkrn-rbbt fnpndfndon bg tmn pmbtbourrndt, GG~3.6

Dkturn bg rnobi`hdkthbd okd `n hfndthghnf grbi omkrjn-

trkdsgnr stktn nenotrbeuihdnsondon

OV-stktn nihsshbd hs bg `hibenouekr brhjhd

Znkl trkp-ksshstnf rnobi`hdkthbd hs prnsndt hd

S?MV1SO@I sbekr onees

Vmn kibudt bg nxohtbd qundomnrs hs nquke tb tmn kibudt bgnenotrbd trkps. Vmn nxohtbd fhggushbd endjtm kdf ehgtnthin

krn dbt hdtrhdsho `ut krn fntnrihdnf `y nxtrhdsho fngnots

P J

Koldbwenfjnindt1


74/98

PuJ

Orhsthdk Vkdksn

Fndhs Ikrlbv

Akd Kdtbd Lbstnr

Ikjfk Ikdfbo

Hrhdk Orkohud

Xukd Qmkdj

Mnrikd Dhobekh

Jnrt-Akd Zntzneknr

Skue fn @ruyd

Dhnes vkd fnr Lkkp

@nrt fn @bnr

Fkjb fn Ennuw

^O_@

Kenx Ihldndlb

Ikrthad Luhl

Aksbd Ehd

[uynd Djuynd

JnbrjhkVnom

Ankd-Euo @rnfks

Omkf Phslb

Oksny Okip`nee

5:>


75/98

Vmkdl ybu gbr ybur kttndthbd!!!

5:7

Vrkdspbrt kdf Pnobi`hdkthbd hd k SENF


76/98

Hdanothbd1 @krrhnr Mnhjmt

Vrkdspbrt1 Ib`hehty, Vrkps, _pkon Omkrjn

Pnobi`hdkthbd

0.; nWOk

HVB

B

M?O B d

@urrbujmns nt ke., Dkturn ?6:, p. >?8 (;883)

Nxpbdndthke Vrkp Fhstrh`uthbd1 Ibfhghnf Ibfne 5::


77/98

Nxp. Vrkp ibfne1

r9Vt/V)(;0

;

)(

3 rOE

W

nDnDA

r

rr

nggt

rdo

N

)nxp(~)(t

t

t

lV

NNND

Dtrkp9>*;3;: oi-?

Vt9;>33 L

IFIB-SSW1

t

totnggt

V

lVNDD

)0/(nxp

0

)(

tVV

o

tt

D

dDd

/

Vrkp-ehihtnf Nenotrbd Vrkdspbrt2 5:=


78/98

E^IB SSW

Mbw okd wn fntnrihdn n, Dt, kdf Nto 22

Fnnp Vrkps

_mkeebw Vrkps

Mbpphdj hd

ibfhghnf FB_

Nto

v. Indsgbbrt nt ke., SP@

=3, 3??030 (0338)

d-typn fbphdj15:8


79/98

K. Lkmd nt ke., Brj. Nenotr. 8, >:> (033=)

Sm P @ =; 3=>03; (03;3)

d-typn fbphdj15=3


80/98

Kgtnr d-fbphdj1

Nenotrbd ourrndt nquke tb mben ourrndt

Vnipnrkturn fnpndfndon nquke tb tnipnrkturn fnpndfndon bg mben

ourrndt n9 m

Vrkps eboktnf 4 3.6 nW `nebw tmn E^IB

Smys. Pnv. @. =;, 3=>03; (03;3)

Jkusshkd E^IB kdf Nxpbdndthke Vrkps2 5=;


81/98

^sn Kpprbxhikthbd hd Hdtnrinfhktn Wbetkjn Pnjhin1

J. Skksom kdf _. _omnhdnrt, A. Kppe. Smys. ;3:, ;36>3; (03;3).

;3;6

;3;7

;3;=

;303

;300

;306

;307

;3;=

;3;8

;303

;30;

;300

;30?

;306

;30>

E^IB

N

_hdjen envne

Nxpbdndthke

Jkusshkd

dt(i

-?)

d(i-?)

Hfnkehty gkotbr sbekr onees1 Fkrl Ourrndt 5=0


82/98

Sbeyinr1SO@I `uel mntnrbaudothbd sbekr onees mkvn kd

hfnkehty gkotbr bg ~;.?

;nxp

lV

qWAA sF

d4;1 Nvhfndon gbr trkp-ksshstnf rnobi`hdkthbd2

_hdjen Okrrhnr Fkrl-Ourrndt (db rno!!)


83/98

Hfnkehty gkotbr shdjen-okrrhnrfnvhons bg snpkrktn iktnrhkes

iktom hfnkehty gkotbrs bg tmn

`endf

94 Hfnkehty gkotbr hs fntnrihdnf `y trkdspbrt-fbihdkthdj

obdsthtundt bg tmn sbekr onee `endf.

Kppe. Smys. Entt. 88, ;>?>37 (03;;)

Btmnr obdaujktnf pbeyinrs2 5=6


84/98

3.; ; ;3;3

-?

;3-0

;3-;

;33

;3;

;30

;3?

;36

;6= di SOSFV@V

=> di SG;3V@V

;:? di G=@V

?33 di BO;O

;3-SSW

Ourrndt

Fndshty(K/i)

W (W)

_ebpn bg Vrkp-ehihtnf Nenotrbd Ourrndt vkrhns gbr fhggnrndt pbeyinrs

SENF Bpnrkthbd15=>


85/98

Vrkp-Grnn _OE Mben Vrkdspbrt

Vrkp-ehihtnf Nenotrbd Vrkdspbrt

Ekdjnvhd Pnobi`hdkthbd, _mboleny-Pnkf-Mkee Pnobi`hdkthbd

Ok

HVB

Kssuipthbd1 Fhggushbd dnjenotnf5=7


86/98

E

A-W omkrkotnrhstho hs1

Db rnobi`hdkthbd ebssns1

+

Rmd

W9WBO

-`hks

nW

lV

lVnW

lVnWnJEAAA pd

0

;)/nxp(

;)/nxp(

Mujmns kdf _blne1 A. Kppe. Smys. >0, ;8=;, 7:6?

A

W

W

fhggushbd frhgt

Pnokp1 5=:


87/98

nWlV

lVnWlVnWnJEA 0

;)/nxp(;)/nxp(

EWnJA ppdd tt

=

80/;6/?

6/;

WJq

qA p

Ebw vbetkjn1 Bmiho `nmkvhbur1

0/;0/; WnJAdd

t

nJEA

Hdtnrinfhktn vbetkjn1 _qukrn rbbt `nmkvhbur1

_kturkthbd rnjhin1 Wbetkjn hdfnpndfndt

br 22

Frhgt vs fhggushbd

br 22

Nxohtbd Fhggushbd Endjtm


88/98

Sbey(G0F) keebws gbrikthbd bg k obipentneyhiib`hehznf wnee-fnghdnf mntnrbstruoturn

EF9>-: di

D

B

B

O6M8

O6M8

G0F

3 633.3

3.0

3.6

3.7

3.=

;.3

S

E

qundomhdj\k

.u.Y

DP_-SSW ghei tmholdnss \diY

DP_-SSW/pbey(G0F)

EF9 > di

Vhin-hdfnpndfndt!!

Smbtbvbetkho rnspbdsn1: di

A.A.I.Mkees nt.ke.,Kppe. Smys. Entt., ;887, 7=, ?;03

A. Smys. Omni. K 033>, ;38, >077->0:6

Nxohtbd Fhggushbd Obngghohndt


89/98

),(),()(),(

)(

),(),(0

0

txjtxdx_

x

txdF

t

txd

t

txd

t

3 033 633 733 =333.3

3.0

3.6

3.7

3.=

;.3

SEhdtndshty\k.u.Y

Vhin \psY

Dnkt DP_-SSW

Ghei tmholdnss

;>.> di

= di

6 di

s

oiF

DP_

0

6

;3?

Smbtb-hdfuonf fngnot qundomhdj1

F90;3-6oi0/sI. Xkd nt. ke.,

Smys. Pnv. Ent., ;886, :?, :66

Dnkt Sbeyinr usnf ks rngnrndonSMX_HOKE PNWHNZ @ :0, 36>0;7 033>

583Nxohtbd Fhggushbd Obngghohndt


90/98

@uel [undomnr

SO@I

O-SOSFV@V

58;Nxohtbd Fhggushbd Obngghohndt


91/98

Pnekthvn qundomhdj ngghohndoy

ftSE

ftSE

[prhsthdn

`endf

;

Hdthiktn

ihxturn1

db oeustnrs!

IO shiuekthbd1

F9?;3-?oi0/s

EF9;3 di

Ndnrjy Ndvhrbd. _oh., 03;0, >, 7873

580

Dnkt Sbeyinr SE fnoky


92/98

SE fnoky hs dbt shdjen nxpbdndthke.

-rnekxkthbd bg nxohtbds hd Jkusshkd FB_

A. Smys. Omni. @ 033=, ;;0, ;;73;;;736 ;;73;

Ibvkjmkr, @.< Jrdnwkef, I.< Phns, @.< @ssenr, M.< Zrtz, F.

Smys. Pnv. @ ;8=7, ??, >>6>>>>6.

58?

Pnokp1


93/98

Pnfuothbd bg fhsbrfnr enkfs tb hdornksn bg

nxohtbd fhggushbd obngghohndt

Gbr nxohtbd fhggushbd obngghohndt 4;3-? oi0/Ws

tmn SE fnoky hs shdjen nxpbdndthke

Vmn nxohtbd fhggushbd endjtm ~>-: di hs

hdfnpndfndt bd fhsbrfnr.

Brjkdho @MA vs. _h-`ksnf _bekr onee586


94/98

3.3; 3.; ; ;3

3.;

;

obdstkdt J

A WIFIB-SSW1SO@I_h p/d onee

A/Aikx

Wbo-W \WY

ghnef fnpndfndt J

Vmn jndnrkthbd rktn hd `endfs bg IFIB-SSW1SO@I hs ghnef fnpndfndt!

Hdtrbfuothbd bg VOD[ nenotrbd trkps1

O tm t `h th htm t f e t h

58>


95/98

Okd wn prbvn tmkt rnobi`hdkthbd whtm trkppnf nenotrbds hs

rnspbdshèn gbr tmn ndmkdonf fnpndfndon bg Wbo bd ehjmt

hdtndshty2EÎB IFIB-SSW

EÎB SO@I

MBIB IFIB-SSW

MBIB SO@I

Nxohtbd

fhggushbdD

D

D

D

M M

M M

6.> nW

VOD[

Wboehjmt hdtndshty fnpndfndon587


96/98

;3 ;33 ;333

3.0

3.6

3.7

3.=

;.3

_\lV/qY9?


Wbo

(W)

Db Vrkps

_\lV/qY9;

VOD[ Vrkps

Kppe. Smys. Entt. 8;, 07?>3> 033:

58:

SE fnoky SOSFV@V


97/98

390;0 ps

g9 ;67 ps

Fhsbrfnr fbihdktnf omkrjn trkdspbrt 58=


98/98

+?-F Vrkdspbrt `y mbpphdj

`ntwnnd obdaujktnf pkrts

bg tmn omkhd

Ebw ib`hehty1~Ws

oi0

:;3>

@ssenr, Smys. _tkt. _be. (`) ;:>, ;> (;88?)

Documents

IEE/CEEM Seminar: Paul Blom and Transport and recombination in polymer:fullerene bulk heterojunction solar cells