IATA, DOT, and Hazard Communication 2017 - … 01 16 DOT IATA KWE Englis… · IATA, DOT, and Hazard Communication 2017 ... Demonstrating an awareness of security risks ... This is

INSTRUCTOR:

Sean Halpin

General Awareness TrainingTHE SAFE TRANSPORT OF DANGEROUS GOODS BY AIR

IATA, DOT, and Hazard Communication 2017

Revised 1/13/17

I.A.T.A. General Awareness Training

• International Air Transportation Association

–Global reference for shipping Dangerous Goods AND the only reference recognized by the world’s airlines

– Founded in 1945 in Havana, Cuba• Originally 57 members from 31 nations,

now over 230 members from more than 140 nations

Revised 12/7/2016


• Mission

– Represent, Lead and Serve the airline industry

– Define all the Airline rules and regulations

– Main focus is to provide the safe and secure transportation of all passengers and crew

Revised 12/7/2016

I.A.T.A. General Awareness Training Objectives

• Enable employees working with or around dangerous goods to recognize and identify their dangers

• Properly mark and label dangerous goods containers for shipment

• Select proper packaging for dangerous goods under the direction of the Certified person

• Complete shipment declaration and AWB under the direction of the Certified person

• Develop appropriate response information to accompany shipment

Revised 12/7/2016


• Who should take this class

– Warehouse personnel

– Operators (moving or handling material)

– Customer Service

– Other Office Employees working around D.G.

• Frequency / Requirements

– Within 90 days of initial employment

– Every 2 yearsRevised 12/7/2016

2017 Regulations Changes Summary58th Edition Dangerous Goods Regulations

(Reference only – Recurrent Training)• Dangerous Goods

• UN 3480, Lithium ion batteries has been amended to show “forbidden” across columns I/J to identify that these batteries are now restricted to Cargo Aircraft Only. This change became effective 1 April 2016 through an addendum to the 57th edition of the DGR. There is no change to the entries for UN 3481, lithium ion batteries packed with equipment or lithium ion batteries contained in equipment;

• all entries for lithium batteries, UN 3090, UN 3091, UN 3480 and UN 3481 have been revised to identify that the hazard label has changed to now be the lithium battery Class 9 label. A new Special Provision A206 has also been assigned to reinforce this new requirement

• Special Provisions

• A181—Has been revised to more clearly describe the requirements for packages that contain both lithium batteries packed with equipment and lithium batteries contained in equipment.

• A331—Is a new special provision assigned against UN 3480, Lithium ion batteries to identify the possible requirements for a shipper to meet to obtain an approval to ship lithium ion batteries at a state of charge in excess of 30% of the rated capacity of the battery.

Revised 12/7/2016

2016 Regulations Changes Summary57th Edition Dangerous Goods Regulations

(Reference only – Recurrent Training)• Marking and Labels

• 7.1.5.5—Are the new provisions that set out the requirements for the lithium battery mark. The specification of the lithium battery mark is shown as Figure 7.1.C. The new mark comes into effect as of 1 January 2017 with a 2-year transition period during which time either the lithium battery mark or the lithium battery handling label may be applied to packages containing lithium batteries prepared in accordance with Section IB or Section II of the lithium battery packing instructions.

• 7.2.4.4—The provisions on additional text on hazard labels have been revised to identify that for the new Class 9–Lithium Battery hazard label the only information permitted in the bottom half of the label is the pictogram and the class number.

• 7.3.18—The specification of the new Class 9–Lithium Battery hazard label has been added as a new Figure 7.3.X. The new hazard label comes into effect as of 1 January 2017 with a 2-year transitional period during which time either the existing Class 9–Miscellaneous Dangerous Goods hazard label or the new Class 9–Lithium Battery hazard label may be applied to packages containing lithium batteries prepared in accordance with Section I, IA or IB of the lithium battery packing instructions.

Revised 12/7/2016

GHS Pictograms

!

Explosives,

self-reactives,

organic peroxides

Flammables, pyrophoric,

Self-heating, emits flam

gas,

self-reactive,

organic peroxides

oxidizers

Skin corrosion/burns,

eye damage

corrosive to metals

Acute toxicity,

fatal or toxic

Carcinogen, mutagenicity,

Repro toxicity, resp sensitizer,

target organ toxicity,

aspiration toxicity

Irritant, skin sensitizer,

acute toxicity, narcotic

effects, resp tract irritant,

haz to ozone layer

Aquatic toxicity

Gases under pressure

Copyright 2014 Du-All Safety, LLC

du-all.com, (510) 651-8289

Manufacturer/ Distributor Label

9

REGULATORY REFERENCES

ICAO Technical

Instructions

International Law

Recognized by 49CFR

IATA DGR

Easy to use

manual

Based on ICAO

49 CFR - United States

Hazardous Materials

Transportation Law

Revised 12/7/2016

Penalties for Non-Compliance

Civil

$250 to $50,000 per day/per violation

Criminal

Up to $250,000 (Individual)

Up to $500,000(Corporation)

Up to 10 years in prison

Revised 12/7/2016

SHIPPER RESPONSIBILITIES

Identification

Classification

Packing

Marking

Labeling

Documentation

TrainingRevised 12/7/2016

OPERATOR RESPONSIBILITIES

Acceptance

Storage and Loading

Inspection of information

Retention of Records

Training

Revised 12/7/2016

Dangerous Goods

Checklist for a

Non-Radioactive

Shipment

(pdf version is included in the handouts)

Revised 12/7/2016

Dangerous Goods

Checklist for a

Non-Radioactive

Shipment

(pdf version is included in the handouts)

Revised 12/7/2016

I.A.T.A. Dangerous Goods Handling

• S.D.S. (Safety Data Sheet)

– Documents that contain important information regarding the product they accompany. They are intended to provide workers and emergency personnel with procedures for handling or working with that dangerous substance in a safe manner, and include information such as physical data (melting point, boiling point, flash point, etc..), toxicity health effects, first aid, reactivity, storage, disposal, protective equipment, and spill-handling procedures and fire handling procedures

Revised 12/7/2016

PACKING GROUPS(Degree of Danger posed by the Dangerous Good or Hazardous Material)

PACKING GROUP I – GREAT DANGER

PACKING GROUP II – MEDIUM DANGER

PACKING GROUP III – MINOR DANGER

Revised 12/7/2016

I.A.T.A. Packaging Requirements

• Substances MUST be compatible with their packaging

• Metal packagings must be corrosion resistant or with protection against corrosion for substances with a Class 8 subsidiary risk

• NON COMPATIBLE DANGEROUS GOODS MUST NOT BE PACKAGED IN THE SAME CONTAINER

Revised 12/7/2016

CLASSIFICATIONS(Risk to Health, Safety, Property or Environment)

1. Explosives

2. Gases

3. Flammable Liquids

4. Flammable Solids

5. Oxidizers and Organic Peroxides

6. Toxic and Infectious Substances

7. Radioactive Materials

8. Corrosive Materials

9. Miscellaneous Dangerous GoodsRevised 12/7/2016

Class 1 - Explosives

Revised 12/7/2016

Class 2 Gases

2.1 Flammable gas

2.2 Non-flammable gas

2.3 Toxic gas

Revised 12/7/2016

Class 3 Flammable liquid

Revised 12/7/2016

Class 4 Flammable solid

4.1 Flammable solid

4.2 Spontaneously Combustible

4.3 Dangerous When WetRevised 12/7/2016

Class 5 Oxidizers & Organic Peroxides

5.1 Oxidizer

5.2 Organic Peroxide

Revised 12/7/2016

Class 6 Toxic & Infectious Substances

6.1 Toxic Substances

6.2 Infectious substances

Infectious substances - substances known

to contain, or reasonably expected to

contain, pathogens.

Revised 12/7/2016

Class 7 Radioactive Materials

Category I

black text

on white label

I red

Category II

black text

upper yellow

II red

Category III

black text

upper yellow

III red

Revised 12/7/2016

Class 8 - Corrosive Materials

Revised 12/7/2016

Class 9 Miscellaneous Dangerous Goods

Also included in Class 9:

• Aviation Regulated Solid

or Liquid (3.9.2.1).

• Elevated Temperature

Substance (3.9.2.3).

• Miscellaneous articles and

substances (3.9.2.6).

Revised 12/7/2016

Using the Alphabetical List of Dangerous Goods

(Used by I.A.T.A.Certified Personnel only)

Revised 12/7/2016

Single

Packaging types

Combination

Composite

Revised 12/7/2016

Packaging Markings

Revised 12/7/2016

A three-part code indicates the type of packaging

Packaging Markings

Revised 12/7/2016

Example markings for a liquids drum

Combination Packaging

4G/Y20/S/09

USA/CM0405

Revised 12/7/2016

Single Packaging Intended To

Contain Liquids

1A1/Y1.4/150/08/NL/RM0709

Revised 12/7/2016

UN Specification Packaging

Intended for Infectious

Substances

4G/CLASS 6.2/09

USA/HAZ PACKING CO.

Revised 12/7/2016

Handling Labels

Revised 12/7/2016

Example of a

Completed Package

4G/Y20/S/09

USA/T7402

Sodium Nitrite

UN1500

To:

From:

Revised 12/7/2016

DOCUMENTATION

• 2 Key Documents must accompany Dangerous

Goods shipments

• Air Way Bill (AWB)

• Dangerous Goods Declaration

Must Be Signed and dated by the Shipper or his

agent (I.A.T.A. Certified Person)

A type written signature is not allowed

Revised 12/7/2016

Example of

Completed Shipper’s

Dangerous Goods

Declaration

Revised 12/7/2016

Proper Basic Description of HM

Immediate Hazards to Health

Risk of Fire/Explosion

Immediate Precautions (Accident/Incident)

Immediate Methods for Handling Fires

Initial Methods for Handling Spills/Leaks (No Fire)

Preliminary First Aid Measures

EMERGENCY RESPONSE INFORMATION

Revised 12/7/2016

EMERGENCY RESPONSE TELEPHONE NUMBER

Includes Area OR International Access Code

No ‘1-800’ Numbers that do not work outside the U.S.

Entered In A Clearly Visible Location

Answered/Monitored 24 Hours A Day

Person Must be Knowledgeable

Must Be the Number Of the Person Offering Material

Revised 12/7/2016

Emergency Response Guide Page

Revised 12/7/2016

DOCUMENTATION - Airway Bill

1

2

Revised 12/7/2016

Dangerous Goods in Excepted Quantities

IP2

IP2Cushioning material

IP21 g 1 g 1 g

Revised 12/7/2016

Revised 12/7/2016

Revised 12/7/2016

Revised 12/7/2016

Questions?

Revised 12/7/2016

KWE/ DOT Hazardous Materials Transportation/ Presented by Du-All Safety

49

DOT Hazardous Materials Transportation

(49 CFR 172.704)

Sean Halpin

Du-All Safety

Course Objectives


50

Provide Students information to support the safe transportation of hazardous materials, including: Defining the requirements of 49 CFR, Part 172.704 for

certification in hazardous handling and transportation and of HM-232, the Security Regulation for awareness training.

Reviewing the requirements of the DOT regulations relative to the transportation of hazardous materials.

Reviewing the basic safety elements including recognition and identification of hazardous materials as required by the DOT regulations and the Hazard Communication Standard.

Reviewing the basic operations required for handling emergencies involving hazardous materials for the DOT Hazmat Employee.

Course Objectives


51

Demonstrating some basic functions required for a DOT Hazmat Employee including: basic knowledge of the Hazardous Materials Table (49 CFR 172.101), Labels and Placards, and Shipping Papers.

Reviewing the nine DOT hazard classes and associate them with the appropriate placards for use in transportation.

Demonstrating an awareness of security risks associated with hazardous materials transportation.

Demonstrating an awareness of methods designed to enhance transportation security.

Demonstrating an awareness of how to recognize and respond to possible security threats.

What this class does not prepare you for

This is a training course and does not specifically authorize you to perform any task – only your employer can do that.

This is a training course and the information provided by the instructors is not your organization’s policy – do not take information from this course as “above” your organization's policy.

This is a training course and does not provide adequate information to perform a task – you must know the specifics.

This training provide awareness of hazmat response so you can protect yourself – you are not a hazmat responder

52


HazMat Employee Defined

HazMat Employee

Load, unload, or handle hazmat, including:

Prepare hazmat for transport

Responsible for the safe transport of hazmat

Operate a vehicle used to transport hazmat

Supervise hazmat employees


53


54

Regulatory Overview

49 Code of Federal Regulations


55

Overlap in Regulations


56

“Each hazmat employee shall be provided general awareness/familiarization training designed to . . . enable the employee to recognize and identify hazardous materials consistent with the hazard communication standards . . . . Training conducted by employers to comply with the hazard communication programs required by the Occupational Safety and Health Administration (OSHA) . . . may be used to satisfy the training requirements . . .” of the DOT Regulation

What is HM-181, HM-126F, and HM-232?


57

HM-181 was actually born in 1991 and identifies changes made to the DOT regulations in the areas of hazardous material classifications, package labeling, placards, and the quantity of the package that the material is shipped in.

HM-126F, a similar amendment to the DOT regulations, sets minimum training requirements for individuals involved in all modes of transportation.

HM-232 is the recently enacted regulation regarding transportation security for hazardous materials.


58

Safety Overview

What is a Hazardous Material?


59

According to the U.S. Department of Transportation, a “Hazardous Material” is defined as “a substance or material, which has been determined by the Secretary of Transportation to be capable of posing an unreasonable risk to health, safety, and property when transported in commerce, and which has been so designated.

Hazardous Substances


60

Hazardous substances are chemicals and other substances that can affect your health, causing illness or disease.

Solvents, pesticides, paints, adhesives, petroleum products, heavy metals or any other substance that is hazardous to health and is used or produced at work.

How Many Hazardous Materials Can You Identify?What made the material hazardous?


61


62

Acutely toxic

Chronically toxic

Carcinogenic

Mutagenic

Teratogenic

Sensitizing agent

Corrosive

Irritant

Health Hazards


63

Physical Hazards

Combustible liquid

Compressed gas

Explosive

Flammable

Organic peroxide

Oxidizer

Pyrophoric

Unstable (reactive)

Water-reactive

Physical Properties -Flammable

Only vapors burn

Flash point - The lowest temperature where a liquid will give off vapors which can be ignited if an ignition source is present

Flammable – flash point above 140 degrees f

Combustible – flash point below 140 degrees f


64

Physical Properties – Specific Gravity

Specific Gravity

Specific Gravity is the weight of a liquid compared to the weight of water

Water has a specific gravity of 1

Swimmers

Floaters

Sinkers


65

Physical Properties – Vapor Density

Vapor density is defined as the weight of the material’s vapor, relative to the weight of air

The vapor density of air is 1

Sinkers

Risers

Floaters


66

Path of Exposure


67

Hazardous substances can get into your body in

different ways:

by breathing in the substance (inhalation)

(absorption) through the skin

accidental swallowing (ingestion), for example

(injection) through puncture wounds


68

Hazard Communication Program

Must comply with Hazard Communication Standard – 8 CCR 5194


69

Hazard Communication Program Requirements

Written program must include:

A list of hazardous chemicals present in the workplace

SDS

Labeling system information


70

Safety Data Sheets

Primary tool for getting detailed chemical information

Must be readily available

6a

Material Safety Data Sheets

Chemical Product and Company Name

Composition/Informationon Ingredients

Hazards Identification

First Aid Measures

Fire Fighting Measures

Accidental Release Measures

Handling and Storage

Exposure Controls/Personal Protection

Physical and Chemical Properties

Stability and Reactivity

71

SDS



72

SDS Information Includes (p1)

Chemical identity

Physical and chemical

characteristics

Physical and health hazards

Primary routes of entry


73


PEL, TLV, other exposure limit

Whether it is a carcinogen

Precautions for safe handling/use

Recommended engineering controls


74


Emergency first aid procedures

Date of preparation

Name, address, phone number of manufacturer, importer, responsible party


75


• SDSs also provide information regarding:

signs and symptoms of exposure

personal protective equipment

spill and leak clean-up

labeling information

HazMat Identification Systems


76

HazMat Identification

Labels

Placards

The Nine Hazard Classifications

77


HazMat Label

Labels must be used on packages containing a hazardous material in transport unless exempted

Different DOT label for each Hazard Class/Division

Labels for primary and subsidiary risks


78

DOT HazMat Label

DOT Labeling System

Diamond-shaped labels, 4 inches on each side, required to be affixed on two sides of non-bulk containers

Subsidiary labels indicate additional hazards, and lack the hazard class number


79

DOT Placard System

Diamond-shaped placards, 10 ¾ inches on each side, required to be placed on bulk containers

Placards must appear on all four sides of the vehicle


80

DOT Hazard Classification


81

Hazard Class 1 - Explosives

Subdivided into 6 divisions1.1-Mass explosion hazard

1.2- Projectile hazard

1.3- Fire, minor blast or projectile

1.4- Minor explosion

1.5- Very insensitive explosives

1.6- Extremely insensitive

82


CLASS 1- EXPLOSIVES PLACARDS


83



Hazard Class 2 - Gases

Pressurized or Liquified

Compressed nitrogen and liquified petroleum gases (LPG) are examples

Product and container present hazards

Subdivided into 4 divisions

85

Hazard Class 2- Gases

Subdivided into 4 divisions

2.1 - Flammable gases

2.2 - Non-flammable,non toxic*compresses gases

2.3 - Gases toxic* by inhalation

2.4 - Corrosive gases (Canada)*The word “poison” or “poisonous” are synonymous with the word “toxic”.

86


CLASS 2- Gases Placards


87

B L E V E

Boiling, Liquid, Expanding, Vapor, Explosion

Added DANGER with Class 2 hazmats

Besides the chemicals, there is danger of explosion of the tank from over pressure

Tanks should always be cooled

Relief valves should be allowed to vent

Stay away from tank ends


88


COULD THIS BLEVE?

Relief valve venting

Leak venting, not normal it

has ignited

Remember the position

of the poles

89


Notice the position of the fire

apparatus

90


Where is the fire

apparatus?

91


12 firefighters died here, you can’t run fast

enough!

92

Hazard Class 3 Flammable/Combustible Liquids

Flammable liquids can be ignited at room temperature.

Combustible liquids require some degree of pre-heating to ignite.

Number 1 RULE- ELIMINATE IGNITION SOURCES.

93


Hazard Class 3- Flammable and Combustible Placards


94

Hazard Class 4 - Flammable Solids

Three subdivisions

4.1 - Flammable solids

4.2 - Spontaneously combustible

4.3 - Dangerous when wet

95


Hazard Class 4 - Placards


96

Hazard Class 5 - Oxidizers and Organic Peroxides

Oxidizers release oxygen to enhance or intensify burn

Strong fuels, oxidizers can create conditions which can lead to violent combustion

Many organic peroxides are very unstable

97


Hazard Class 5- Oxidizers and Organic Peroxides Placards

98


Hazard Class 6 - Poisonous and Infectious Substances

Division 6.1 Toxic materials

Can include severely irritating substances

“Tear Gas”, Hydrocyanic acid, Carbon tetrachloride

Division 6.2 Infectious Substances

Potential to cause diseases in humans

Anthrax, human blood and many body fluids

99


Hazard Class 6 Placards


100

INFECTOUS WASTE101


Hazard Class 7 - Radioactive Materials

Three Types: Alpha, Beta, Gamma

Ionizing radiation hazard

Exposure does not always result in contamination

Safety Rules:

Time, Distance and Shielding

Shipped in specialized containers

102


Hazard Class 7- Radioactive Placards


103

Hazard Class 8 - Corrosive Materials

Those materials which can cause irreversible damage to human tissue.

In addition, the fumes or vapors from many of the materials are also very hazardous.

Examples: nitric acid, sodium hydroxide (caustic soda or lye), hydrochloric acid.

104


Hazard Class- 8 Corrosive Materials Placards


105

Hazard Class 9 - Miscellaneous Dangerous Goods (ORM-D)

Division 9.1 Misc. dangerous goods.

Division 9.2 Environmentally

hazardous substances.

Division 9.3 Dangerous waste.

106


Hazard Class 9- Miscellaneous dangerous goods Placards

Miscellaneous Not required for domestic transportation. Placard 454 kg (1,001) lbs.) or more gross weight of material which presents a hazard during the transport, but is not included in any other hazard class.

107


Placard any quantity of these

Enter Division Number1.1, 1.2, or 1.3 and

compatibility groupletter, when required.Placard any quantity

Enter compatibility

group letter, when required. Placard

454 kg (1,001 lbs.)

Placard any quantity ofDivision 2.3 material.

DANGEROUS WHEN WETPlacard any quantity ofDivision

4.3material

POISON Placard any quantity of 6.1, PGI, inhalation hazard only. Placard 454 kg (1,001 lbs.) or more or PG or II, other than PGI inhalation hazard.

RADIOACTIVE Placard any quantity of packaging bearing the RADIOACTIVE III label. Certain low specific activity radioactive materials in "exclusive use" will not bear the label but RADIOACTIVE placard is required.

108


Subsidiary Risk

Class numbers do not appear on subsidiary risk placard

Placard empty tank cars for residue of material last contained.

Required background for placards on rail shipments of certain explosives and poisons. Also required forhighway route-controlled quantities of

radioactive materials (see §§172.507 and 172.510).

109


The DANGEROUS Placard

Placard 454 kg (1,001 lbs.) gross weight of two or more categories of hazardous materials listed in Table 2. A freight container, until load device, motor vehicle, or rail car which contain non-bulk packaging with two or more categories of hazardous materials that require placard specified in Table 2 may be placarded with a DANGEROUS placard instead of the separate placarding specified for each of the materials in Table 2. However, when 2.268 kg (5,000 lbs.) or more of one category of materials is loaded at one facility, the placard specified in Table 2 must be applied.


110

Military Placards111


More Military…...

Some resemble UN/NA and some are completely different

112


More Military…...

Toxic or Harmful

113


Review -- Identification System

There are ________Classes of Hazmat

Green is associated with _______________Placard

Yellow is associated with Class _______________

Explain the acronym BLEVE_____________ ____

__________________________________

A blue placard means what?_________________

Corrosive Materials can do what?________________

Flammable and Combustible liquids are in the same class, what separates one from the other?__________

Class 2 has flammables, non flammables, poisons etc., what is the common denominator?________________

114


The Hazardous Materials Table


115



116

WHAT IS IT?

The Hazardous Materials Table is found in the HMR and lists materials that the Research and Special Programs Administration (RSPA) has determined to be hazardous.



117

Contains all the necessary information to identify the requirements that apply to each shipment of each hazardous material:

Column 1 – Symbols

Column 2 – Proper Shipping Descriptions And Names

Column 3 – Hazard Class Or Division

Column 4 – Identification Numbers

Column 5 – Packing Group

Column 6 – Labeling Requirements

Column 7 – Special Provisions

Column 8 – Packaging Authorizations

Column 9 – Quantity Limitations

Column 10 – Vessel Stowage

Who Uses It?


118

Anyone with the responsibility of determining:

What the hazards of a material are

The proper packaging, labeling, placards

The proper shipping descriptions

Any transportation restrictions

HazMat Table Question


119

What’s a hazardous materials table?a) A bench top in the chemical lab

b) The morning breakfast table

c) A list of substances that pose a risk to health, safety and property

d) All of the above

What’s the purpose of the Hazardous Materials Table?

a) To confuse everyone

b) The source of information on classifying, packaging and shipping materials.

HAZMAT TABLE - QUESTIONS


120

Who uses the hazardous materials table?

a) Everyone

b) Anyone who makes, handles, packages or ships hazardous materials

c) Those who determine shipping descriptions and packaging, labeling, shipping requirements

Shipping Papers


121

Shipping Papers


122

• Properly completed shipping papers must accompany every shipment of hazardous materials

• Whenever a hazardous material is transported, its description must appear on the shipping paper.• A Bill of Lading is the most common

• Hazardous Waste Manifest

• Multiple entries can be made on one shipping document.

• Hazardous and non-hazardous materials can both be listed on the same document.

Bill of Lading


123

• When both a hazardous and a non hazardous material are listed, the hazardous material must be:

• Listed FIRST

• Shown in contrasting color and highlighted on multi-sheet forms.

• Identified with an “X” or “RQ” in the “HM” column.

Bill of Lading


124

SHIPPING PAPERS


125

• Entry must be legible and in English

• Entry may not contain code numbers or abbreviations

• Each entry for each hazardous material must include the BASIC DESCRIPTION:• Proper shipping name (Column 2, Hazmat Table)

• Hazard class (Column 3, Hazmat Table)

• Identification Number (Column 4, Hazmat Table)

• Packing Group (Column 5, Hazmat Table)

SHIPPING PAPERS


126

• Shipping paper must:

• Contain the name of the shipper

• Indicate multiple pages, for example “page 1 of 4”.

• Show emergency response number

• Contain Shipper’s Certification

• Include the total quantity of material

• Accompany the shipment (give to the driver)

• Be readily available in driver’s compartment

SHIPPING PAPERS


127

SHIPPING PAPERS, QUESTIONS


128

• What can be used for a shipping document? ________________

• Can hazardous and non-hazardous materials be listed on the same shipping document (Y/N)?

• Name one item that must be on a shipping paper for every material shipped._____________________________

• Who gets the shipping paper when the shipment leaves the supplier?

• Where is the shipping paper kept? ______________________________

Packaging and Package Marking


129

Package and Package Marking


130

• Hazmat packaging must be designed to safely contain the material

• The more hazardous the material, the more strict the packaging requirement:

o Packing Group I – Great Danger

o Packing Group II – Medium Danger

o Packing Group III – Minor Danger

• All packaging must be tested prior to use

o Performance Oriented Packaging, “POP”

Packaging and Package Marking


131

• Performance Oriented Packaging (POP) requirements apply to:

o Bulk – Greater than 119 gallons, Example: Totes

o Non-bulk – Less than or equal to 119 gallons Examples: Drums, Bottles, Carboys

o New and reused packaging

o Specification and non-specification packaging

• All packaging must be marked

Package/Marking - Questions


132

What type of package can be used to ship a hazardous material?

a) Strong sturdy boxes or containersb) Boxes or container that have been tested for the

material being shipped.c) Only new boxes or containersd) All of the above

Can a material with a severe hazard rating be shipped in a package rated for a mildly hazardous material? _____

Only non-bulk packages need to be marked (T/F) _____

What is POP packaging?a) Specification packaging for carbonated beveragesb) What they pack firecrackers inc) Performance Oriented Packaging

Labeling


133

Labeling


134

• Hazardous Material Warning labels are color-coded so that the hazards can be quickly recognized.

• Labels correspond to the placards that must appear on bulk packaging, freight containers, transport vehicles or rail cars that contain a hazardous material.

• Labels are NOT required on bulk packages with placard(s).

Labeling


135

Labeling


136

• Labels must include both the hazard class and the division of hazard, if required, according to the Hazardous Materials Table (Col. 6).• Example: 5.1 for Oxidizer

• The first label listed is the primary hazard of the material. This label MUST contain the hazard class number.

• Additional labels indicate subsidiary hazards. These labels DO NOT contain the hazard class number.

• Labels must be visible. Example: Stretch wrapped skids of items.

Labeling


137

Labeling


138

Labeling Questions


139

How do you recognize a hazard from the label?1. By the color2. By the symbol on the label3. By the wording on the label4. By the number at the bottom of the label5. All of the above

You can use two (or more) labels on one package (T/F).

Labels do not need to be visible on all materials shipped as long as information is on the paperwork and the driver understands what he is shipping (T/F)

Labels are NOT required on bulk packages (T/F)

Placarding


140

Placarding


141

Hazmat placards are similar to the shape, color and design of hazmat warning labels. They serve the following purposes:

o To alert the public to the potential dangers of hazardous materials.

o To guide emergency personnel in their actions during a hazmat incident.

Placarding


142

Unless excepted, each:

o Bulk package

o Freight container

o Unit load device

o Transport vehicle

o Rail car

Containing any quantity of a hazardous material must be placarded on each side and each end with the placards specified in Part 172, Subpart F.

Placarding


143

Placarding


144

Placarding Questions


145

• Placards are different from labels in what ways?

1. They are bigger2. They typically contain only the hazard class

number3. They are used on bulk, freight, tankers, etc.4. All of the above

• The hazard class number on the placard must match the number in the shipping description (T/F).

• Semi trailers containing non-bulk packaging never need to be placarded (T/F)

Loading and Securement


146

HazMat Emergency Response


147

Your Actions in a HazMat Emergency

Stop

Warn

Isolate

Minimize Exposure

You are not an emergency responder – leave that to the professionals!


148

Response Exercise

Transporting 4 containers of hazmat (chlorine) when accident occurred on major freeway

No one is injured

Describe your SWIM actions

Stop

Warn

Isolate

Minimize


149

HazMat Emergencies


150

Those who handle hazardous materials must know:

The basic description & technical name of the material

Immediate hazard's to health

Risks of fire and exposure

Who to contact

How to clear the area

How to isolate a spill

Preliminary first aid and fire fighting methods

Emergency response phone numbers

Hazard RecognitionSite Hazards

Chemical Exposure

Explosion

Oxygen Deficiency or Oxygen Enriched Environments

Natural Radiation

Unstable Footing

Fire

Confined Spaces

Sharp Edges

151


Hazard RecognitionSpill Response Hazards

Dispersants/Degreasers

Heavy Machinery Outside the Hospital (Cranes)

Unguarded Equipment

Equipment/Vehicle Condition or Failure

Driving

Fatigue & Stress

Ergonomic Injuries

152


Hazard Recognition Site & Response

Electrical Hazards

Thermal Exposure

Noise

Traffic

Work-related Violence

Container Shapes Plastic Drums

Larger vehicles in the proximity of the building such as trucks with Ribbed Tank Cars

5-gallon Canisters

153


Hazard Recognition

Placards & Labels

Shipping Papers and SDS

154


National Fire Protection Association

NFPA 704 System

Indicates general hazards

Used on buildings

Not used everywhere

Discussed here because buildings where you pick up or deposit your load may be involved in an emergency

155


NFPA 704156

Fire Hazard

4 Flash Point below 73 O F

3 Flash Point below 100 O F

2 Flash Point from 100 to 200 O F

1 Preheating Required for Ignition

0 Will Not Burn


NFPA 704

4 Death or Severe Injury with Short Exposure

3 Severe Temporary or Long Term Injury

2 Severe Injury with Intense or Long Term Exposure

1 Irritation or Minor Injury

0 No Hazard

157

Health

Hazard


NFPA 704

4 Explosive Decomposition at Normal Temps.

3 Detonation with Strong Initiating Source

2 Unstable Chemical Reactions

1 Unstable at Elevated Temperatures

0 Stable


158

Reactivity

NFPA 704159

Specific

Hazards

OXY = OxidizerACID = Acid

ALK = AlkaliCOR = Corrosive

W = Water= Radioactive


DOT Hazard Classes

Class 1 Explosives

Class 2 Gases

Class 3 Flammable Liquid

Class 4 Flammable Solid

Class 5 Oxidizer

Class 6 Poisons

Class 7 Radioactive Material

Class 8 Corrosives

Class 9 Misc. Hazardous Material

160


Hazardous Material Identification System 161


Hazardous Material Identification System 162


References


163

DOT Emergency Response Guide

White

National Response Center

Placards

Yellow - U.N. Number

Blue - Alphabetical

Orange - Safety Recommendations

Green - Initial Isolation

164


Hazmat Quiz

1. Hazardous materials must be prepared for shipping in accordance with:

A) OSHA 1910.134

B) Hazardous Materials Regulation in 49 CFR

C) The AHERA Standard

D) all of the above

Hazmat Quiz

2. All hazmat employees must receive initial training and periodically retrained at least

A) annually

B) every 3 years

C) after each spill

D) don’t have to be retrained

Hazmat Quiz

3. A chemical burn is an example of what kind of hazard:

A) chronic

B) acute

C) cancerous

D) ergonomic

Hazmat Quiz

4. A hazmat employee is defined as one who:

A) works in a trucking company

B) has a direct affect on the safe transportation of hazardous materials

C) works in the loading and storage area of a company

D) owns/operates a truck

Hazmat Quiz

5. Hazardous chemicals should be stored:

A) alphabetically

B) according to compatibility

C) according to size of container

D) none of the above

Hazmat Quiz

6.What is the best source for locating information such as proper shipping name, hazard class, ID numbers and packing group numbers?

A) Labels

B) MSDSs

C) Hazardous Materials Table

D) Placards

Hazmat Quiz

7. All labels must be:

A) durable

B) weather-resistant

C) unobscured

D) all of the above

Hazmat Quiz

8. If there is a chemical spill you should do all of the following except:

A) identify the material

B) contain the material

C) clean up the material

D) none of the above

HAZMAT QUIZ

9. What is the hazard class associated with this label?

HAZMAT QUIZ

10. What is the hazard class associated with this label?

HAZMAT QUIZ

11. What is the hazard associated with this label?

Hazmat Quiz

12. Workers who must know how to deal with hazmat emergencies are:

A) emergency response personnel only

B) drivers

C) emergency response personnel

D) anyone who may be exposed to a hazardous materials incident/accident in the workplace

IATA Exam

1. T F The IATA Dangerous Goods Regulations is an easy to interpret and use manual based on ICAO

2. T F Shipper’s declarations must be kept for at least 3 months

3. T F I.A.T.A requires initial DGR training within 90 days of initial employment, General Awareness Training and re-certifications every 2 years

Revised 12/7/2016

IATA Exam

4. T F There are no fines for non compliance, only warnings and shipment delays

5. T F There are three Packaging Groups (I, II & III)

6. T F Non compatible Dangerous Goods may be packed within the same outer packaging

7. T F There are 10 Classifications of Dangerous Goods

Revised 12/7/2016

IATA Exam

8. T F The Alphabetical List of Dangerous Goods MUST be checked by I.A.T.A. Certified Person on duty to ensure compliance

9. T F Handling labels assist everyone handling dangerous goods and must be used

10. T F There are two key documents that must accompany a Dangerous Goods Shipment. The AWB and the Dangerous Goods Declaration

Revised 12/7/2016

Questions?• Class: IATA, DOT, and Hazard Communication General

Awareness Training

• Instructor: Sean Halpin

• Contact: (510) 651-8289; du-all.com

• Fax Sign-In Sheets to (510) 651-8937 or [email protected]

Revised 12/7/2016

mailto:[email protected]