To measure and evaluate thermodynamic and transport properties of next generation refrigerants To formulate accurate equations of state and correlations To establish an international collaboration network to obtain reliable thermodynamic information 1. 2. 3. Appearance of novel refrigerants during the early 1930s CFC (ChloroFluoroCarbon) and HCFC (HydroChloroFluoroCarbon) HFC (HydroFluoroCarbon) refrigerants and their mixtures Solution: Appearance of non-chlorine fluorocarbons HFO (HydroFluoroOlefin) refrigerants and their mixtures Solution: Appearance of low GWP refrigerants At the present, our task is to find the following next generation refrigerants: (1) (3) (2) (4) Lower ODP (Ozone Depletion Potential) Non-flammable or Mildly flammable Lower GWP (Global Warming Potential) Lower toxicity (As of July 2021) 2016 - 2017 2018 - 2020 2021 - 2022 2023 - 2027 2028 - 2009 - 2015 HFO refrigerants Screening/Assessments Mildly flammable low GWP refrigerants (GWP less than 300) ISO/DIS 17584:2020(E) [ 2016 ‒ 2020 ] R1234yf, R1234ze(E), R1233zd(E), R1336mzz(Z) ISO/DIS 17584 [2021 - ] Extension to the refrigerant blends Addition of non-flammable refrigerants Flammability reduction Mild flammable low GWP refrigerants (GWP less than 150) 2009 2013 2015 2016 2017 2018 2020 2021 2022 2023 2027 REFPROP 9.1 REFPROP 10.0 REFPROP 11 or 10.1 Construction of Heat Transfer Database + Roadmap for the Development of Next Generation Refrigerants *These researches are supported by NEDO projects “Development on High Efficient and Non-Freon Air Conditioning System(2016-2017)” and “Development Techniques for Next-Generation Refrigerant with Low GWP Values (2018-2022)” NEXT-RP NEXT-RP Mission Problem: Ozone layer depletion (1980s) Problem: Global warming (2000s) Problem: Flammability and Safety Proposal of novel next generation refrigerant blends (GWP less than 100) Research Center for Next Generation Refrigerant Properties I 2 CNER, Kyushu University Research Center for Next Generation Refrigerant Properties I 2 CNER, Kyushu University Research Center for Next Generation Refrigerant Properties (NEXT-RP) International Institute for Carbon-Neutral Energy Research (I²CNER), Kyushu University 744 Motooka, Nishi-ku, Fukuoka 819-0395 JAPAN TEL & FAX : 092-802-6704 MAIL : [email protected] WEBSITE : https://i2cner.kyushu-u.ac.jp/~next-rp Heat Transfer and Cycle Performance Evaluation Background of Next Generation Refrigerants Background of Next Generation Refrigerants

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Page 1: I2 NEXT-RP

To measure and evaluate thermodynamic and transport properties of next generation refrigerants

To formulate accurate equations of state and correlations

To establish an international collaboration network to obtain reliable thermodynamic information

1.

2.

3.

Appearance of novel refrigerants during theearly 1930s

▶ CFC (ChloroFluoroCarbon) andHCFC (HydroChloroFluoroCarbon)

▶ HFC (HydroFluoroCarbon)refrigerants and their mixtures

Solution:Appearance of non-chlorine fluorocarbons

▶ HFO (HydroFluoroOlefin)refrigerants and their mixtures

Solution:Appearance of low GWP refrigerants

At the present, our task is to find the following next generation refrigerants: (1) (3)

(2) (4)

Lower ODP (Ozone Depletion Potential)Non-flammable or Mildly flammable

Lower GWP (Global Warming Potential)Lower toxicity

(As of July 2021)

2016 - 2017 2018 - 2020 2021 - 2022 2023 - 2027 2028 -2009 - 2015HFO refrigerants

Screening/Assessments

Mildly flammablelow GWP refrigerants(GWP less than 300)

ISO/DIS 17584:2020(E) [ 2016 ‒ 2020 ]R1234yf, R1234ze(E), R1233zd(E), R1336mzz(Z)

ISO/DIS 17584 [2021 - ]Extension to the refrigerant blends

Addition of non-flammable refrigerants

Flammability reduction

Mild flammable low GWP refrigerants(GWP less than 150)

2009 2013 2015 2016 2017 2018 2020 2021 2022 2023 2027

REFPROP 9.1 REFPROP 10.0 REFPROP 11 or 10.1

Construction of Heat Transfer Database

+

Roadmap for the Development of Next Generation Refrigerants

*These researches are supported by NEDO projects “Development on High Efficient and Non-Freon Air Conditioning System(2016-2017)” and “Development Techniques for Next-Generation Refrigerant with Low GWP Values (2018-2022)”

NEXT-RPNEXT-RP Mission

Problem: Ozone layer depletion (1980s)

Problem: Global warming (2000s)

Problem: Flammability and Safety

Proposal of novel nextgeneration refrigerant blends

(GWP less than 100)

Research Center forNext Generation Refrigerant Properties

I2CNER, Kyushu University

Research Center forNext Generation Refrigerant Properties

I2CNER, Kyushu University

Research Center for Next Generation Refrigerant Properties (NEXT-RP)International Institute for Carbon-Neutral Energy Research (I²CNER), Kyushu University

744 Motooka, Nishi-ku, Fukuoka 819-0395 JAPANTEL & FAX : 092-802-6704 MAIL : [email protected] : https://i2cner.kyushu-u.ac.jp/~next-rp

Heat Transfer and Cycle Performance Evaluation

Background of Next Generation RefrigerantsBackground of Next Generation Refrigerants

Page 2: I2 NEXT-RP

Procedure for Identifying Next Generation Refrigerants at NEXT-RP

NEXT-RP Research Collaboration Map

NEXT-RP Members

(4) Evaluation of the performance of refrigeration/heat pump cycle

(3) Heat transfer analysis of several heat exchangers(Evaluation of heat transfer coefficients)

Screening and selection of new candidatesfor next generation refrigerants

(1a) Thermodynamic property measurementsCritical parametersVapor pressuresSaturated densitiesPvT propertiesVapor-liquid equilibriumSpecific heatSpeed of sound

(1b) Transport property measurementsThermal conductivityViscositySurface tension 

(2) Formulation of equation of state (EoS)Making the FLD file(REFPROP)

Requirements of next generation refrigerants(1) No ODP, (2) Low GWP, (3) No toxicity, (4) No flammability,(5) High performance, (6) Low cost and others…

Additional measurements,Improvement of EoS

NIST REFPROP installationas international standard

Additional measurements,Improvement of EoS

(5) Proposal of expectingnew refrigerants :Next generation refrigerants

NEXT-RP Director Yasuyuki TakataProfessorI²CNER PrincipalInvestigatorKyushu University

Yukihiro HigashiProfessorKyushu University

Kyaw ThuAssociate ProfessorKyushu University

Akio MiyaraProfessor, Saga UniversityI²CNER Visiting Professor

Ryo AkasakaProfessor, Kyushu Sangyo UniversityI²CNER Visiting Professor

Chieko KondouProfessor, Nagasaki UniversityI²CNER Visiting Professor

Takahiko MiyazakiProfessorKyushu University

Naoya SakodaAssociate ProfessorKyushu University

(Speed of sound)

(Thermodynamic properties)

(Thermodynamic properties)

(Thermodynamic properties)