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I
II
III
Periodic Trends
Valence Electrons
Electrons available to be lost, gained, or shared in the
formation of chemical compounds
Outer energy level
Atomic Radius
Distance from the center of atom’s nucleus to outermost electron.
1
2
3
4 5
6
7
Decreases UP and to the RIGHT Or Increases DOWN and to the LEFT
Atomic Radius
0
50
100
150
200
250
0 5 10 15 20Atomic Number
Ato
mic
Ra
diu
s (
pm
)Atomic Radius
Li
ArNe
KNa
Describe in terms of atomic structure:
Going down a group from top to bottom, adding energy levels.
Higher energy levels have larger orbital's
Describe in terms of atomic forces:
Shielding Effect ~ inner core e- block the attraction between the nucleus and the valence e-
Atomic Radius
Describe in terms of atomic structure: Electrons remain in the same energy level (not
farther away)
Describe in terms of atomic forces:
Increased nuclear charge (+) without additional shielding pulls e- in tighter
Atomic Radius
An atom or group of bonded atoms that has a positive or negative charge.
Ion
Cations (+)
lose e-
smaller
© 2002 Prentice-Hall, Inc.
Anions (–)
gain e-
larger
Ionic Radius
Larger – down a group.
Smaller – across a period.
Cations: Smaller than neutral atom
Anions: Larger than neutral atom
Ionic Radius
Trends in Ionic Size
Trends in Ionic Size
6.3S
ize
ge
ner
ally
incr
ease
s
1
2
3
4 5
6
7
The amount of energy required to remove an electron from a neutral atom.
Increases UP and to the RIGHT
Ionization Energy
Ionization Energy
Opposite trend from atomic radius. Larger atoms ~electrons held less
strongly ~ takes less energy to remove one.
Smaller atoms ~ electrons held more strongly ~ takes more energy to remove one.
Ionization Energy
Why small jumps within each group?
Ionization Energy
0
500
1000
1500
2000
2500
0 5 10 15 20Atomic Number
1st
Ion
izat
ion
En
erg
y (k
J)
Stable electron configurationsdo not easily give up electrons
Amount of energy to remove 1st electron, 2nd electron, 3rd electron.
Each higher ionization requires more energy.
Na Na+ + e- 496 KJ/mol
Na+ Na+2 + e- 4565 KJ/mol
Na+2 Na+3 + e- 6912 KJ/mol
*1st, 2nd, and 3rd Ionization Energies
Electron Affinity
The energy change that occurs when an electron is added to an atom.
Negative Electron Affinities
Energy is given off when an electron is added to an atom.
Non-Metals tend to gain electrons.
Non-Metals have NEGATIVE affinities.
Positive Electron Affinities
Energy is required to add an electron to an atom.
Metals tend to lose electrons
Metals have POSITIVE affinities.
Noble Gas Electron Affinities
Noble Gases have high positive electron affinities.
Octet Rule!
8 valence electrons
Electronegativity
The ability of an atom to attract electrons
Predict using octet rule and atomic radius.
F is most electronegative, Cs and Fr are least
electronegative.
Electronegativity