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4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Hydro-Mechanical Properties of Carbonated Cements
1Laboratoire de Géologie2Schlumberger3BRGM
A. Fabbri1,3 , J. Corvisier1, A. Schubnel1, F. Brunet1
J. Fortin1, B. Goffé1, V. Barlet-Gouédard2, G. Rimmele2, Y. Leroy1
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
1) Carbonation under in situ conditions (P=30MPa, T= 90degC and sc CO2)
1) Wet or Dry scCO22) Wet or Dry cement samples
Existence or Non- of a carbonation frontscCO2
Motivation
2) Mechanical properties under in-situ pressure (Pc=30Mpa, Pp=28Mpa) tri-X stress conditions
1) Loading/Unloading cycles on wet and ry Carbonated cement samples
2) Permeability measruments and Elastic wavespeed determinationStatic elastic moduli
Evaluation of damage3) Macroscopic rupture strength
Evaluation of aging/wear
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Experimental Set-upSample carbonation
Technical characteristics
Sample maximum diameter30 mm
Maximum Pressure350 bars
Temperature heterogenities<3°C
Carbonation at 90°C and 28 MPa (Pc=Pp)
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
ResultsSample Carbonation
H20 saturated with CO2
Supercritical CO2 saturated with H20
dry sample & scCO2NO FRONT
Wet samples & scCO2 CARB. FRONT
Dry or wet samples & H20+CARB. FRONT
Example for a carbonation time of 35 days
d or HC
w orAC
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Experimental set-upMechanical and Physical Properties under in-situ cond.
Tests were performed @Pc= 30 MPaPp= 28 MPaTemp.= 20°C
Sample sizeDiam. 30length. 60
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Experimental set-up - wavespeed measurements
Mechanical and Physical Properties under in-situ cond.
4 couples of Source - receivers Triband (1P, 2S)→ Autopicking & Crosscorrelations: 0.5% of relative error on wavespeeds
PZT sensors: Piezo-ceramic (Lead Zirconate Transducers, 0.1-1MHz)Active source : Elastice wavespeed and travel time
PSV&SH
P
P, SV&SH
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Theoretical background - Crack density determination
Mechanical and Physical Properties under in-situ cond.
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Crack density
porosity
S wave
P wave
Effective Medium Modelling of rockcontaining Pores and Cracks usingNIA approximation
[Fortin, Gueguen and Schubnel,J.Geol.Res., 2007]
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Running a single test… on a (pre)carbonated cement sampleExperimental procedure
1) Confinement from 0 to 30MPa in dry conditions 2) Deviatoric stress (Gzz) from 0 to 30 MPa / Load-unload cycle3) Pore volume saturation with Argon gas at 28MPa4) Argon gas permeability5) Water saturation from 0 to 28 MPa6) Water permeability7) Deviatoric stress (Gzz) from 0 to 30 MPa 8) Water permeability 9) Deviatoric stress (Gzz) from 30 to 50 MPa10)Water permeability11)Deviatoric stress (Gzz) from 50 to rupture
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Elastic properties of porous rocks : modelling using EMT, DRYnon-interactive theory (isolated penny shaped cracks and holes)Counteracting effects of pore and cracks
The elastic potential can be written:
Stress interactions between holes and cracks
DRY:
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Elastic properties of porous rocks : modelling using EMT, DRYnon-interactive theory (isolated penny shaped cracks and holes)Counteracting effects of pore and cracks
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Connected domain CO2 migration
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
HC sample hardenedwith carbonation
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
AC sample ~ softenedwith carbonation
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
PS
LQ
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P-DP/2
Q c
onst
ant
L
S
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
AC samples permeability decreases with carbonation….
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
But increases dramatically with Gzz….
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Some experimental results Dry Confinement Dry deviatoric AC permeability Rupture Strength
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
Conclusion
-Micro-cracks
-Elastic moduli evolutions
-Permeability evolution
Damage accumulation in sample withCarbonation front
Damage is localized at the front
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
C2S + CaO vaterite aragonite
Conclusion
-Micro-cracks
-Elastic moduli evolutions
-Permeability evolution
Damage accumulation in sample withCarbonation front
Damage is localized at the front(real or due to deP?)
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
100MPa, température 200degCCorrosive Pore fluids16 coaxial feedthrough for acousticsCylindrical samples (diameter 40mm)
NEW EXPERIMENTAL SET UP
Tri-X MP-MT RIG
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
DISPOSITIF EXPÉRIMENTAL: EA, Vitesses et Capteurs PZTNEW EXPERIMENATL SETUP
AE monitoring : recording, localization, energy
4th MEETING of the WELL BORE INTEGRITY NETWORK, Paris - 18t/19th March 2008
COMING SOON….
The Venue: CSF in Ascona (Ticino, CH), on Lago Maggiore
The Centro Stefano Franscini is the congress centre of the Swiss Federal Institute of
Technology of Zurich(ETHZ) situated at Monte Verità. It is an ideal meeting point for all
members of the international scientific community who wish to discuss about the state of the
art and new challenges of any field of research.
8th Euroconference of Rock Physics and Geomechanics
Rock Physics, fluids and Society.
Focus on Thermo-Hydro-Chemo-Mechanical coupling applied to CO2 sequestration, waste
disposal, oil and geothermics.
FIRST CIRCULAR DRAFT
Venue: Ascona (CH), 9-13 September 2009 (see http://www.csf.ethz.ch)
Conveners: L. Burlini (ETH Zurich); A. Schubnel (ENS Paris); P. Baud (Uni Strasbourg)
If interested, please email [email protected]