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OM325 OPERATING AND MAINTENANCE MANUAL for the HY-FEX HYPERBARIC FIRE EXTINGUISHER Part No: 6.7 Litre SE480BA Part No: 3.0 Litre SE481BA

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Page 1: Hy-Fex Hyperbaric Fire Extinguisher - OM325 - JFD | Home · OM325 OPERATING AND MAINTENANCE MANUAL for the HY-FEX HYPERBARIC FIRE EXTINGUISHER Part No: 6.7 Litre SE480BA Part No:

OM325

OPERATING AND MAINTENANCE MANUAL

for the

HY-FEX HYPERBARIC FIRE EXTINGUISHER

Part No: 6.7 Litre SE480BAPart No: 3.0 Litre SE481BA

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OM325 iP2141-OM-334 Rev 7 Approval Sheet

APPROVAL SHEET

DIVEX

MANUAL NUMBER: OM325

ADVITIUM NUMBER:

P2141-OM-334

DOCUMENT TITLE: Operation & Maintenance Manual for Hy-Fex Hyperbaric Fire Extinguisher, CE Marked (PED)

REV DATE BY CHECK APP COMMENTS

0 16/03/2007 Christine Bain Eliot Aitken Ray Wylie Original Issue

1 05/11/2008 Eliot Aitken Ray Wylie Ray Wylie ECN 11533

2 07/07/2009 Alison Middleton Ray Wylie Ray Wylie ECN 12634

3 09/05/2011 Debbie Allan Nick Graves Mark Stevens ECN 14061

4 08/08/2011 Debbie Allan Nick Graves Scott Waddell ECN 14227

5 09/03/2012 Debbie Allan Ketan Ashara Mark Stevens ECN 14612

6 19/02/2013 Debbie Allan Simon Bryce Mark Stevens ECN 15461

7 24/02/2014 Debbie Allan Vladimir Garzon Mark Stevens ECN 16456

ORIGINAL ISSUE DATE: 16 March 2007

ORIGINAL DOCUMENT BY: Christine Bain

CHECKED BY: Eliot Aitken

APPROVED BY: Ray Wylie

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ii OM325Approval Sheet P2141-OM-334 Rev 7

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OM325 iiiP2141-OM-334 Rev 7 Table of Contents

Page

PREFACE....................................................................................................................................... V

CHAPTER 1 - PRODUCT INFORMATION .................................................................................... 1

CHAPTER 2 - PRINCIPLE OF OPERATION ................................................................................. 7

CHAPTER 3 - TEST SUMMARY .................................................................................................. 15

CHAPTER 4 - EXPLODED VIEWS .............................................................................................. 19

CHAPTER 5 - MAINTENANCE INSTRUCTIONS ........................................................................ 23

ANNEX 1 - TRIDOL DATASHEET ............................................................................................... 29

TABLE OF CONTENTS

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iv OM325Table of Contents P2141-OM-334 Rev 7

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OM325 vP2141-OM-334 Rev 7 Preface

PREFACE

The following address should be used in all communications with the manufacturer:

Approvals and Markings:

1. Hy-Fex Hyperbaric Fire Extinguisher Marking: 0038

Divex Limited declares that this Pressure Equipment is in compliance with AssessmentProcedure Module B1 + D of the requirements of the Pressure Equipment Directive(97/23/EC) / Pressure Equipment Regulations SI 1999 No.2001 and SI 2002 No.1267and is manufactured under a Quality System approved by Lloyd’s Register Verification.

2. National Approvals

The Divex Limited Quality Management System has been approved by Lloyd’sRegister Quality Assurance Limited to BS EN ISO 9001.

Approval Certificate No. 0850495/A.

Divex Ltd

Enterprise Drive, Westhill, Aberdeen, AB32 6TQ, United Kingdom

Telephone: +44 (0)1224 740145

Fax +44 (0)1224 740172

Email [email protected]

Web www.divexglobal.com

Design Appraisal conducted by: Lloyd’s Register EMEA,71 Fenchurch Street,London,EC3M 4BS,United Kingdom

Notified Body No. 0038

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OM325 1P2141-OM-334 Rev 7 Chapter 1

CHAPTER 1 PRODUCT INFORMATION

Page

1.1 Hy-Fex Hyperbaric Fire Extinguisher ....................................................................... 3

1.2 Mounting Brackets ..................................................................................................... 5

1.3 Dimensions and Performance Data.......................................................................... 5

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OM325 3P2141-OM-334 Rev 7 Chapter 1

1.1 HY-FEX HYPERBARIC FIRE EXTINGUISHER

1.1.1 Hy-Fex Hyperbaric Fire Extinguishers are portable and designed for hyperbaric chambers,including medical therapy chambers.

1.1.2 Available in two size options, the 3-litre Hy-Fex Extinguisher is generally suitable for air divechambers and the entry and transfer locks of larger systems. The 6.7 litre Hy-FexExtinguisher is suitable for main locks of large systems and large treatment chambers.

1.1.3 The Hy-Fex Extinguisher comprises a robust aluminium cylinder, valve assembly, carryingand operating handle and an outlet hose and nozzle.

1.1.4 The AFFF extinguishing agent is propelled by a suitable chamber gas (air or Heliox withmaximum 20% oxygen), pressurised to 133 bar, providing an effective foam spray.

1.1.5 The control valve and handle assembly operates similar to conventional industrialextinguishers providing immediate on / off actuation control.

• Portable

• Two standard sizes available

• Rapid deployment and instant response

• Economical

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4 OM325Chapter 1 P2141-OM-334 Rev 7

1.1.6 The nozzle is venturi assisted which increases both foam volume and flame suffocationeffectiveness.

1.1.7 A contents gauge indicates the charge status.

1.1.8 Hy-Fex is suitable for multi-risk applications (fabrics, materials and liquid fires) and has beensatisfactorily function-tested and witnessed by DNV to 450msw.

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OM325 5P2141-OM-334 Rev 7 Chapter 1

1.2 MOUNTING BRACKETS

1.2.1 The Hy-Fex mounting bracket, sold separately, is available for secure and safe stowage,equipped with a Velcro strap enabling rapid deployment when required.

To comply with CE approval requirements the Hy-Fex extinguisher must be stowed using theappropriate Hy-Fex mounting bracket. See table below for details.

1.3 DIMENSIONS AND PERFORMANCE DATA

HY-FEX EXTINGUISHER VOLUME

3.0 LITRE 3.0 LITRE 7.5 LITRE 7.5 LITRE 6.7 LITRE

OBSOLETE OBSOLETE OBSOLETE

Hy-Fex Part No SE481AA SE481BA SE480AA SE480AB SE480BA

Bracket Part No SE4880 SE488010 SE4881 SE4882 SE488210

Refill Part No SE4816 SE4816 SE4817 SE4817 SE481710

Cylinder Volume 3.0 litres 3.0 litres 7.5 litres 7.5 litres 6.7 litres

Gas Void Volume (25%) 0.75 litres 0.75 litres 1.875 litres 1.875 litres 1.675 litres

Water (88% of combined liquid)

2 litres 2 litres 5 litres 5 litres 4.5 litres

Foam (12% of combined liquid)

0.3 litres 0.3 litres 0.7 litres 0.7 litres 0.6 litres

Extinguisher Height 575mm 540mm 810mm 645mm 675mm

Cylinder Diameter 114mm 117mm 140mm 168mm 152mm

Cylinder Centre to Handle Extremity

115mm

Cylinder Centre to Hose Extremity

130mm

Weight Charged (Approx.) 6kg 7kg 13kg 13kg 14kg

Foam Discharge Volume 22 litres 22 litres 50 litres 50 litres 45 litres

Discharge Time 22 seconds 22 seconds 50 seconds 50 seconds 45 seconds

Discharge Distance 6m

Effective Discharge 99%

Cylinder Test Pressure 300 Bar 310 Bar 300 Bar 300 Bar 310 Bar

Extinguisher Working Pressure

Extinguisher Working Pressure 133 Bar

Temperature Rating -15 to +55oC

Tested Depth 450msw

Recommended Chamber Volume

6m3 6m3 14m3 14m3 14m3

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OM325 7P2141-OM-334 Rev 7 Chapter 2

CHAPTER 2 PRINCIPLE OF OPERATION

Page

2.1 Introduction ................................................................................................................ 9

2.2 Servicing and Recharging Instructions ................................................................... 9

2.3 Discharge Guidance Notes ...................................................................................... 12

2.4 Operating .................................................................................................................. 13

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OM325 9P2141-OM-334 Rev 7 Chapter 2

2.1 INTRODUCTION

2.1.1 The Hy-Fex Hyperbaric Fire Extinguisher comprises;

• Aluminium Cylinder• Trigger Valve Assembly including pressure gauge and burst disc• Outlet Hose & Nozzle• Foam Mixture & Gas Propellant

2.1.2 The fire extinguishing medium is an aqueous film forming foam (AFFF) concentrate mixedwith water and propelled by pressurised air or heliox.

2.1.3 The volume of the foam/water mixture is 75% of the cylinder volume, the remainder beingpressurised gas.

2.1.4 The working pressure of the extinguisher is 133 Bar, and is operable at depths down to450msw.

2.1.5 The Hy-Fex fire extinguisher is ideally suited for hyperbaric environments due to;

a. Propellant operating pressure substantially higher than conventional fire extinguishers,with a charge pressure differential of up to 88 bar for a maximum operating depth of450 MSW, thus providing excellent energy potential to propel the extinguishing agentrapidly and effectively.

b. A wide operating temperature range from -15°C to +55°C. Ambient temperaturesbelow freezing may reduce foam expansion from the standard 10:1 ratio to anapproximate 9:1 ratio.

c. An optimised flow restriction incorporated into the trigger valve assembly ensuresrelatively constant discharge rates at all depths.

d. A consistent foam texture at all depths improves extinguishing effectivity. Foam texturegenerally improves as ambient pressure (gas density) increases. At shallower depthshigher pressure differentials between the propellant and ambient pressure, with the aidof the venturi nozzle, ensures a consistent foam texture is maintained.

e. Suitable for fabrics, combustible solids, flammable liquids and electrical fires up to 24Volt.

2.2 SERVICING AND RECHARGING INSTRUCTIONS

WARNINGUsers should ensure that the charging facility has an appropriate pressurelimiting or warning device to avoid over pressurising the extinguisher.

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10 OM325Chapter 2 P2141-OM-334 Rev 7

Fig 2.1 Ensure extinguisher is empty. Refer to Discharge Guidance Notes for discharging prior to servicing or recharging.

Place safety pin in valve ‘open’ position

Remove nozzle by turning anti-clockwise.

Fig 2.2 Grip the cylinder and remove valve assembly by turning it anti-clockwise using tool SE4899.

Fig 2.3 Perform scheduled maintenance as required on service label.

Fig 2.4 Check cylinder test date. If test is due, return to Divex for recertification.

Fig 2.5 Visually inspect cylinder internally, externally, including the cylinder and valve thread and O-ring sealing areas.

Fig 2.6 Unscrew three retaining screws until handle is loose, remove from valve body by pulling axially.

Fig 2.7 Using a 12mm socket, remove valve insert, stem, piston, O-rings and spring. If burst disc is ruptured remove with a 5/8” A/F socket.

Fig 2.8 Inspect valve insert seat, piston and all soft seals for wear or damage and replace as required. Clean, lubricate with DC4 Silicone Grease and reassemble in reverse order. Ensure valve piston seal is facing upwards.

Fig 2.9 To re-fill the extinguisher pour contents of refill bottle into extinguisher and add correct volume of de-ionised water using either the refill bottle or a funnel & measuring jug.

Refer to Dimensions and Performance Data table (page 5) for filling ratios.

Fig 2.10 Ensure that a serviceable O-ring is fitted before fitting the valve assembly into the cylinder. Torque valve assembly to 50 lbf.ft (67.8 N.m).

A ½” square drive adaptor is available from Divex, Part No. SE4899.

Invert the extinguisher repeatedly to ensure a good mixture.

Fig 2.11 Fit the ¼” BSP charging fitting into the end of the outlet hose.

Fig 2.12 Connect charging whip SE4800101 to the charging fitting.

Fig 2.13 Lock extinguisher valve in ‘open’ position using the safety pin then charge to 133 bar. DO NOT OVERCHARGE. Once fully charged, fit safety pin to valve in ‘closed’ position.

Fig 2.14 Fit frangible wire into safety pin and seal with crimp. Add a new entry to the service label with service date and signature.

Fig 2.15 Replace the nozzle, renew the instruction label if required and stow Hy-Fex bracket ready for use

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OM325 11P2141-OM-334 Rev 7 Chapter 2

.

Fig 2.1 Fig 2.2 Fig 2.3 Fig 2.4

Fig 2.5 Fig 2.6 Fig 2.7 Fig 2.8

Fig 2.9 Fig 2.10 Fig 2.11 Fig 2.12

Fig 2.13 Fig 2.14 Fig 2.15

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12 OM325Chapter 2 P2141-OM-334 Rev 7

2.3 DISCHARGE GUIDANCE NOTES

1. Refer to Annex 1 - Tridol Datasheet (page 29) for AFFF solution.

2. Wear appropriate PPE such as gloves and full face protection.

3. Conduct a risk assessment prior to discharge operation.

4. Restrict access to work area and inform personnel.

5. Allow for expansion volume of discharged foam. See table above.

6. Capture and dispose of foam in accordance with local and national statutoryregulations. Refer to MSDS for additional information.

7. Discharge foam horizontally from extinguisher nozzle and allow clear and freedischarge distance of ±10 metres.

8. Alternatively foam may be discharged into a strong large polyethylene or similarsuitable bag of adequate capacity to contain the foam volume. Provide a ±3/4" (20mmID) hose to vent bag at vicinity where extinguisher hose and nozzle enters bag, but notin direct path of extinguisher discharge nozzle. Ensure vent hose is directed away fromoperator. Once extinguisher is fully discharged, seal and label bag, handle with careand dispose of appropriately.

9. Allow ±60 seconds of continuous activation to completely discharge a fully charged 6.7litre extinguisher. Allow extra time if discharge is intermittent or interrupted.

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OM325 13P2141-OM-334 Rev 7 Chapter 2

2.4 OPERATING

2.4.1 INSTRUCTIONS FOR USE

Use in upright position (controlled discharge)..

Suitable for use on fabrics, combustible solids, flammable liquids and electrical fires up to 24Volt. Discharge range up to 6 metres.

Type: Aqueous Film Forming Foam (non toxic)

Class: A + B

Fire Rating: Refer to markings

Temp Rating: -15oC to 55oC

Cylinder Volume: Refer to stamped data on cylinder

Test Pressure: Refer to stamped data on cylinder

Working Pressure: 133 bar

Depth Rating: 450 msw

1. Pull out safety pin

2. Direct nozzle at base of fire

3. Squeeze lever

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OM325 15P2141-OM-334 Rev 7 Chapter 3

CHAPTER 3 TEST SUMMARY

Page

3.1 Hy-Fex Valve body ................................................................................................... 17

3.2 Hy-Fex Hose Assembly ............................................................................................ 17

3.3 Hy-Fex Cylinder ........................................................................................................ 17

3.4 Pressure Gauge ........................................................................................................ 17

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16 OM325Chapter 3 P2141-OM-334 Rev 7

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OM325 17P2141-OM-334 Rev 7 Chapter 3

3.1 HY-FEX VALVE BODY

3.1.1 The design of the valve body has been validated by hydrostatic over pressure testing to522.5 Bar in accordance with EN 12516-3.

All valve bodies are hydrostatically proof test to 272 Bar during manufacture and all valveassemblies are further tested to 190 Bar to ensure they withstand the burst disc ratedpressure.

3.2 HY-FEX HOSE ASSEMBLY

3.2.1 All hose assemblies are hydrostatically tested to 200 Bar.

3.3 HY-FEX CYLINDER

3.3.1 Cylinders have a maximum working pressure of 200 Bar or 206 Bar and are hydrostaticallytested to 300 Bar or 310 Bar. Refer to stamped data on cylinder.

3.4 PRESSURE GAUGE

3.4.1 Hy-Fex pressure gauges are calibrated and tested for use at up to 160 Bar.

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18 OM325Chapter 3 P2141-OM-334 Rev 7

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OM325 19P2141-OM-334 Rev 7 Chapter 4

CHAPTER 4 EXPLODED VIEWS

Page

4.1 Exploded View 3.0 Litre (SE481AA) & 7.5 Litre (SE480AA & SE480AB) Models 21

4.2 Exploded View 3.0 Litre (SE481BA) & 6.7 Litre (SE480BA) Models ..................... 22

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20 OM325Chapter 4 P2141-OM-334 Rev 7

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OM325 21P2141-OM-334 Rev 7 Chapter 4

4.1 EXPLODED VIEW 3.0 LITRE (SE481AA) & 7.5 LITRE (SE480AA & SE480AB) MODELS

IMPORTANTThese models SE481AA, SE480AA and SE480AB are no longer available due tocylinder obsolescence.

ORDER CODE

ORDER CODE

ORDER CODE

1 Cylinder SE4850/51/52 11 Valve Piston *+ SE4802 21 Instruction Label SE4800338

2 Valve Body, CE SE4840 12 Valve Stem + SE4802 22 Cylinder Boot SE4870/71/72

3 ‘O’ Ring Seal *+ SE4826 13 ‘O’ Ring Seal *+ SE4801 23 Velcro Pad SE4800336

4 Dip Tube (3l/7.5l) SE4860/61/62 14 ‘O’ Ring Support *+ SE4801 * Soft Seal Kit SE4801

5 Outlet Hose SE4837/38/39 15 ‘O’ Ring Seal *+ SE4801 + Hard & Soft Seal Kit SE4802 (inc SE4801)

6 Nozzle SE4815 16 Valve Seat Insert + SE4802 Foam Refill 3.0 Litre SE4816

7 Gauge, 0-160 Bar SE480610 17 ‘O’ Ring Seal *+ SE4801 Foam Refill 7.5 Litre SE4817

8 Bust Disc Valve SE4800339 18 Handle Assembly SE4807 Bracket, SE480AA SE4881

9 Plug FP198 19 Handle & Valve Assy SE4841 Bracket, SE480AB SE4882

10 Spring, Piston + SE4827 20 Service Label SE4800325 Bracket, SE481AA SE4880

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22 OM325Chapter 4 P2141-OM-334 Rev 7

4.2 EXPLODED VIEW 3.0 LITRE (SE481BA) & 6.7 LITRE (SE480BA) MODELS

ORDER CODE

ORDER CODE

ORDER CODE

1 Cylinder SE485010/485210

11 Valve Piston *+ SE4802 21 Instruction Label SE4800338

2 Valve Body, CE SE4840 12 Valve Stem + SE4802 22 Velcro Pad SE4800336

3 ‘O’ Ring Seal *+ SE4826 13 ‘O’ Ring Seal *+ SE4801 23 Seal security SE4829

4 Dip Tube (3l/6.7l) SE486010/486210

14 ‘O’ Ring Support *+ SE4801 * Soft Seal Kit SE4801

5 Outlet Hose SE4837/39 15 ‘O’ Ring Seal *+ SE4801 + Hard & Soft Seal Kit SE4802 (inc SE4801)

6 Nozzle SE4815 16 Valve Seat Insert + SE4802 Foam Refill 3.0 Litre SE4816

7 Gauge, 0-160 Bar SE480610 17 ‘O’ Ring Seal *+ SE4801 Foam Refill 6.7 Litre SE481710

8 Bust Disc Valve SE4800339 18 Handle Assembly SE4807 Bracket, 6.7 Litre SE488210

9 Plug FP198 19 Handle & Valve Assy SE4841 Bracket, 3 Litre SE488010

10 Spring, Piston + SE4827 20 Service Label SE4800325

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OM325 23P2141-OM-334 Rev 7 Chapter 5

CHAPTER 5 MAINTENANCE INSTRUCTIONS

Page

5.1 Periodic Inspection .................................................................................................. 25

5.2 Cylinder Inspection ................................................................................................. 25

5.3 Hydrostatic Expansion Test .................................................................................... 26

5.4 Misuse and Mishandling .......................................................................................... 26

5.5 Care and Maintenance ............................................................................................. 26

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OM325 25P2141-OM-334 Rev 7 Chapter 5

5.1 PERIODIC INSPECTION

*Recharge with correct combination of foam, water and air or heliox as per operatinginstructions.

5.2 CYLINDER INSPECTION

Cylinders must be visually inspected internally every 6 months by a competent person.

Discharge the extinguisher and remove the valve to allow internal inspection of the cylinder.

EN 1802 ‘Periodic inspection and testing of seamless aluminium alloy gas cylinders’provides the following guidance on cylinder inspection:

Inspect each cylinder internally using illumination to identify any defects such as dents, cuts,cracks, lamination or corrosion (See EN 1802 6.2a & 6.2c). Ensure the method ofillumination presents no hazard to the tester. Remove any internal liner or coating thatobstructs visual inspection (Note: Divex cylinders are not normally lined or coated).

Any cylinder showing presence of foreign matter or signs of more than light surface corrosionshould be cleaned internally under closely controlled conditions by shot blasting, water jetabrasive cleaning, flailing, steam jet, hot water jet, rumbling chemical cleaning or othersuitable method. Refer to EN 1802 annex E for further information on cleaning methodswhich must be compatible with the cylinder material.

If cleaning is required the cylinder should be re-inspected after the cleaning operation.

Where there is doubt concerning the type and/or severity of a defect found during visualinspection additional tests or methods should be conducted such as ultrasonic techniques,check weighing or other non-destructive tests. Only when all doubts are eliminated may thecylinder be further processed (Refer to Annex C of EN 1802 for detailed guidance on defectevaluation)

Weekly • Check pressure is at 133 Bar.

• Check safety pin is in position and sealed.

• Check cylinder for external damage.

• Examine hose / nozzle assembly.

Six Monthly • Discharge contents and carry out internal visual inspection.*

Five Yearly • Perform hydrostatic expansion test in accordance with BS EN 1802:2002, or IMCA D018, or in accordance with an equivalent recognised standard.*

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26 OM325Chapter 5 P2141-OM-334 Rev 7

5.3 HYDROSTATIC EXPANSION TEST

A hydrostatic expansion test shall be conducted at a period specified by national regulationsand in accordance with those regulations by a competent body. Where no nationalregulations exist attention is drawn to IMCA document D018.

5.4 MISUSE AND MISHANDLING

The fire extinguisher and cylinder must never be misused and / or mishandled. Misuse ormishandling may result in injury or death and damage to property. Always stow, store,charge, operate, maintain, inspect and test in accordance with this manual.

Hy-Fex Hyperbaric Fire Extinguishers are approved in accordance with CE regulations. Tomaintain CE approval only use Divex spares and re-fill solutions.

5.5 CARE AND MAINTENANCE

Suitable care and maintenance by competent personnel will extend the service life of Hy-FexFire Extinguishers.

Hy-Fex Fire Extinguishers are designed for emergency use and should be handled with care,and stowed using the appropriate mounting bracket (see table 1.3).

Damage to he protective coating of the cylinder must be repaired at the earliest opportunityby cleaning and re-painting the affected area with a red (RAL 3000) epoxy paint (EE 300090G TR LF).

If any part of the fire extinguisher has been exposed to seawater, or other corrosive fluids,rinse the fire extinguisher with fresh, clean potable water and dry thoroughly.

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OM325 27P2141-OM-334 Rev 7 Chapter 5

SERVICE RECORD

Date Service Sign Date Service Sign

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28 OM325Chapter 5 P2141-OM-334 Rev 7

SERVICE RECORD

Date Service Sign Date Service Sign

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OM325 29P2141-OM-334 Rev 7 Annex 1

ANNEX 1 TRIDOL DATASHEET

Material Safety Datasheet for Tridol S6 LT AFFF Extinguishing Agent

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30 OM325Annex 1 P2141-OM-334 Rev 7

(Intentionally Blank)

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Data Sheet No:F03-08/N2 Page 1 of 5 Issue/Date:3/19.05.06 Supersedes: 2/20.05.03

MATERIAL SAFETY DATA SHEET ________________________________________________________________________________________________________ 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY ________________________________________________________________________________________________________ 1.1 Product Identification TRIDOL ‘S’ 6% AFFF LOW TEMPERATURE GRADE ________________________________________________________________________________________________________ 1.2 Application and Use Fire Fighting Foam Concentrate ________________________________________________________________________________________________________ 1.3 Manufacturer/Supplier

Angus Fire*, Thame Park Road, Thame, Oxfordshire, OX9 3RT

Telephone: (01844) 265000 Fax: (01844) 265156

Emergency Telephone Number (24 hours) For information and supply: Angus Fire (015242) 61166

*(Angus Fire is a trading brand of Kidde Products Ltd, registered in England No. 462271)

________________________________________________________________________________________________________ 1.4 Product Description Hydrocarbon surfactants, fluorocarbon surfactants and glycol solvents. ________________________________________________________________________________________________________ 2. COMPOSITION ________________________________________________________________________________________________________ Substance Synonyms Concentration % Health class CAS-No. _________________________________________________________________________________________________________ Di-ethylene glycol 2-(2-Butoxyethoxy)ethanol 5-25 Xi , R36 112-34-5 monobutyl ether Ethylene glycol 1,2-Ethanediol 15-35 Xn ,R22 107-21-1 Hydrocarbon surfactants <5 Xi , R41,38 Magnesium sulphate <5 10034-99-8 Fluorosurfactants <5 Xi , R36,37,38 Water Balance ________________________________________________________________________________________________________ 3. HAZARDS IDENTIFICATION Human health hazards: Harmful if swallowed. Irritating to the eyes. _________________________________________________________________________________________________________ 4. FIRST AID MEASURES 4.1 General

First aiders should know and take the precautions appropriate to avoid danger to themselves and the casualty.

Take casualty together with material safety data sheet of this product to hospital or doctor, if necessary.

First Aid - Skin: Remove contaminated clothing. If there is skin contact, wash immediately with plenty of clean,

gently flowing water. If persistent irritation occurs, obtain medical attention.

First Aid - Eye: If there is eye contact, wash immediately with plenty of clean, gently flowing water for 10 minutes.

First Aid - Ingestion: If ingestion is suspected, do not induce vomiting, Send casualty to hospital immediately.

First Aid - Inhalation: Remove casualty from exposure. If there is breathing difficulty or cough, keep patient at rest, seated in

position of maximum comfort.

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Data Sheet No:F03-08/N2 Page 2 of 5 Issue/Date:3/19.05.06 Supersedes: 2/20.05.03

________________________________________________________________________________________________________5. FIRE FIGHTING MEASURES General Hazards

Fire fighting measures are not applicable as Tridol ‘S’ 6% AFFF (low temperature grade) is a fire extinguishing medium. If product containers are involved in fire, then a suitable extinguishing agent should be applied.

________________________________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid contact with skin, eyes and clothing. Do not breathe mists, aerosols. Personal protection: Wear protective clothing specified for normal operations. Environmental precautions: SPILLAGE: The practice of washing spills into drains should be avoided if at all possible and should under no circumstances be allowed without first consulting the local Water Authority and the Environment Agency. Clean-up methods - small Absorb or contain liquid with sand, earth or spill control material. Shovel up spillage: and place in a labelled, sealable container for subsequent safe disposal. _______________________________________________________________________________________________________ 7. HANDLING AND STORAGE No special handling techniques required. For best results, the product should be stored in sealed, original containers above -15oC and below 40oC. Freezing and thawing do not affect the substance properties but care must be taken to avoid freezing the container and its contents since the expansion of the container contents may cause cracking of a completely rigid container as ice forms. Personal Protective Equipment - Fire Fighting Angus Fire Foam Concentrates will be used by professional fire-fighters to control and extinguish flammable liquid fires. The nature of this process may involve exposure to heat, flame and possibly toxic vapours and fumes. It is normal procedure to wear appropriately designed personal protective equipment designed for use in firefighting situations. Angus Fire advises that this form of personal protective equipment should be used if the packaging materials become involved in fire. ________________________________________________________________________________________________________8. EXPOSURE CONTROL/PERSONAL PROTECTION

Engineering control measures: Use only in well ventilated areas

Occupational Exposure Limit: Pure Ethylene glycol (vapour): Occupational Exposure Standard (OES) Long term exposure limit (8 hour time weighted average) : 60 mgm- 3 Short term exposure limit (10 minute) : 125 mgm-3 Personal Protective Equipment - Other Handling

Avoid prolonged, extensive or repeated inhalation or contact to eyes and skin.

Hand Protection Wear impervious gloves of an approved type (e.g. neoprene). Eye Protection Wear safety goggles of an approved type (BS 2092).

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Data Sheet No:F03-08/N2 Page 3 of 5 Issue/Date:3/19.05.06 Supersedes: 2/20.05.03

________________________________________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid pH at 20oC: 6.5-8 Colour: Clear pale yellow Boiling Point: 1000 C at 760mm Hg Odour: Organic odour Freeze Point: -150C Flash Point: >980C Flammability: Not flammable Solubility: Miscible with water in all proportions Viscosity at 20oC: 3cs Specific Gravity: 1.04 ________________________________________________________________________________________________________ 10. STABILITY/REACTIVITY Stability Generally stable. As with all aqueous solutions Tridol ‘S’ 6% AFFF (low temperature grade) should be excluded from contact

with any materials which have violent reactions with water.

Stable up to 1000C

Hazardous Decomposition Products Do not expose containers to heat or flame, since the containers are made from high density polyethylene and will burn. Thermal decomposition of containers and/or products may generate acrid smoke and fumes and traces of Na2O,Cl-

SOx,NOx, and HF. ________________________________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION Inhalation Inhalation of hazardous amounts is unlikely when used as intended. May cause irritation to respiratory tract when inhaled. Ingestion Low oral risk when used as intended. May cause nausea, vomiting and diarrhoea when ingested. Contact to eyes or skin Low risk if appropriate precaution measures are taken (see section 6). May cause skin and eye irritation when in

contact with eyes or skin. ________________________________________________________________________________________________________ 12. ECOLOGICAL INFORMATION This has been deduced from data for a similar product. Actual values could well be different. Presumed to be non-toxic in normal use. Persistence/degradability: Biodegradable. Bioaccumulation: Bioaccumulation is unlikely to occur due to metabolism and excretion. Biodegradation Biodegradable: No direct data available Sewage treatment: Data not available _________________________________________________________________________________________________________ 13. DISPOSAL CONSIDERATIONS Disposal Waste should be disposed via local authority waste collection service or registered waste carrier. Ensure the destination is a licensed facility. Local legislation: Control of Pollution Act 1974 Environmental Protection Act 1990 Hazardous Waste Regulations 2005

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Data Sheet No:F03-08/N2 Page 4 of 5 Issue/Date:3/19.05.06 Supersedes: 2/20.05.03

_________________________________________________________________________________________________________ 14. TRANSPORT INFORMATION Label for conveyance: No Transport Warning Sign Required

Road:

UN No: N/C

Rail:

Rail Transport Class No: N/C

Sea:

Sea Transport Class No: N/C EmS No: N/C MFAG Table No: N/C

Air:

Air Transport Class No: N/C

________________________________________________________________________________________________________

15. REGULATORY INFORMATION

Label For Supply:

Harmful Risk Phrases: R-22 Harmful if swallowed. Safety Phrases: S-20, 36 When using do not eat or drink. Wear suitable protective clothing.

UK Regulatory References:

Health and Safety at work Act 1974.

Chemicals (Hazard Information & Packaging for Supply) Regulations 1994 / Amendment Regulations 1996.

EC Directives: Substances Directive 67/548/EEC as amended by 69/81/EEC, 70/189/EEC, 73/146/EEC, 75/409/EEC, 79/831/EEC General Preparations Directive 88/379/EEC. Statutory Instruments: Chemicals (Hazard Information and Packaging for Supply) Regulations.

Approved Code of Practice:

Classification and Labelling of Substances and Preparations Dangerous for Supply.

Guidance Notes: Occupational Exposure Limits EH40/96

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Data Sheet No:F03-08/N2 Page 5 of 5 Issue/Date:3/19.05.06 Supersedes: 2/20.05.03

________________________________________________________________________________________________________ 16. OTHER INFORMATION

Uses and restrictions:

Sources of Information Clayton, G.D. and F.E. Clayton: Patty’s Industrial Hygiene and Toxicology. Fourth edition volumes I - III (1991). Sax, N.I. and R.J. Lewis, Sr: Dangerous Properties of Industrial Materials. Seventh edition volumes I - III (1991).

Health & Safety Executive: Occupational Exposure Limits (EH 40/96). Note: EH40 is revised on an annual basis and newest issue should be applied. Other information: ______________________________________________________________________________________________________ DISCLAIMER: This information is based on our current knowledge and is intended to describe the product for the purposes of health,safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property

of the product. ______________________________________________________________________________________________________