HSLA steel

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    Institut fr Eisenhttenkunde

    der RWTH achen

    Case Study:HSLA steel

    Prof. Dr.-Ing. Wolfgang Bleck

    Outline

    Case Study: HSLA steel Introduction Strengthening mechanisms in HSLA steels Strip processing Automotive application Conclusions

    Outline

    Case Study: HSLA steel Introduction Strengthening mechanisms in HSLA steels Strip processing Automotive application Conclusions

    1975 1995199019851980 20052000

    post-rolled steels isotropic steels

    microalloyed steels

    P-alloyed steels

    DP-steels

    BH-steels

    IF-steels

    TRIP steels

    SULC steels

    TWIP steels

    Al-alloyed steels

    Material design

    Process development

    Chronological development ofhigh strength steels for car bodies

    European consumption of hot and coldrolled high strength steels

    0

    1.000

    2.000

    3.000

    4.000

    5.000

    6.000

    7.000

    1990 1995 2000 2005 2010 Year

    C o n s u m p t i o n ,

    1 03

    t

    HSLACMnBoronDPCP, Mart, TRIP

    HSLA

    CMn

    CP, Mart,TRIP

    DP

    Boron

    0

    1.000

    2.000

    3.000

    4.000

    5.000

    6.000

    7.000

    1990 1995 2000 2005 2010 Year

    HSLABH, PHSIF, IsotropicDPCP, Mart, TRIP

    HSLA

    BH, P

    HSIF,isotropic

    DP

    CP, Mart,

    TRIP

    HotHot RolledRolled ColdCold RolledRolled

    Automotive share 2001: 41%2006: 45%

    Automotive share 2001: 92%2006: 93%

    urce: Leitner, E.: Hot & Cold Rolled High Strength Steels in Western Europe, Pariser & Leitner, Wien, 2002

    Outline

    Case Study: HSLA steel Introduction Strengthening mechanisms in HSLA steels Strip processing Automotive application Conclusions

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    Characteristics ofmicroalloying elements

    very low concentration: 10 -3.10 -1 %

    interaction with C, N and S

    precipitation of secondary phases

    strong influence on microstructure

    control of solution and precipitationby process management

    Microstructural impact of microalloying elements

    IF-status of matrixinfluence on recristallisationtexture developmentgrain boundary reinforcement

    Grain refinementPrecipitation hardening

    Hbond during enamelling

    influence on diffusion during hot dipgalvanizing

    influence on sulfide shape

    grain refinement

    precipitation hardening

    toughness improvement in the heataffected zone of welds

    increase of hardenability

    Cold rolled stripHot rolled strip

    Influence of precipitation temperatureon precipitate size

    coarseca. 50 nm

    fineca. 10 nm

    grain refinement

    medium strengthgood toughness

    precipitation hardening

    high strengthmedium toughness

    Acceleration of Transformation

    20

    200

    10080

    60

    40

    1000800 1200Precipitation temperature, C

    AlNNb(C,N)

    A v e r a g e p r e c

    i p i t a

    t e s

    i z e ,

    n m

    very coarseca. 100 nm

    Outline

    Case Study: HSLA steel Introduction Strengthening mechanisms in HSLA steels Strip processing Automotive application Conclusions

    Coldrolling

    Tandemmill

    Hot rollingheat treatment

    Compactstrip mill

    Hot strip

    mill

    CastedStrip

    Thin Slab

    Slab

    Hot rolledstrip

    Cold rolledstrip

    CAL

    HDG

    HDG

    CAL

    HDG : Hot Dip Galvanizing LineCAL: Continuous Annealing Line

    Process routes of HSLA steels Effect of Nb, Ti, V on the austeniteNo-Rex-Temperature

    r o l l i n g

    t e m p e r a

    t u r e

    i n C

    mass contents of Nb, Ti or V in %

    area of recristallisation

    area of strongly delayed or inhibited recristallisation

    Nb

    Ti

    V

    0 0,060,040,02 0,08 0,10 0 ,12 0,14 0,16750

    1000

    950

    900

    850

    800

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    Effects of soluble and precipitated MAEon austenite recrystallisation

    R e c r y s

    t a l l i s e

    d s

    t r u c

    t u r e

    f r a c

    t i o n

    i n %

    Interpass time in s

    10 -1 10 2 10 3 10 41 100

    20

    40

    60

    80

    100

    [Nb] Nb C

    0.002 % C0 % Nb

    0.002 % C0.10 % Nb

    0.020 % C0.10 % Nb

    Interaction of MAEduring hot strip processing

    Cooling

    NbC,V(C,N)

    Coiling

    NbC,TiC,V(C,N)

    Finishing

    NbC,TiC

    Roughing

    TiN

    [M]In solution

    coarseparticles100nm

    fine,deform. inducedparticles10nm

    fine,in rows arrangedparticles10nm

    extreme fineparticles

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    fullyrecrystallized

    partially recrystallized

    reduction of precipitationhardening

    c o l d r o l l i n g

    r e d u c t i o n A n n e a

    l i n g

    t e m p e r a

    t u r e ,

    C

    600

    650

    700

    750

    800

    850

    600

    0 0,01 0,030,02 0,050,04

    Nb-content,%

    Annealing limits for HSLA steels Influences on themicrostructure development

    metallurgicalprocessesin the material

    as castmicrostructure

    Hot stripmicrostructure

    Cold stripmicrostructure

    Reheating

    Hot Rolling

    Coiling

    Cold rolling and annealing

    process parameters

    transformationgrain growthprecipitation

    precipitation

    precipitationtransformation

    grain growth

    grain growthprecipitation

    dynamic and staticrecristallisation

    static Rex.

    static Rex.

    cooling rate

    temperature-time-cycle

    temperature-time-cycledeformation degree and deformation rate

    cooling ratecoiling temperature

    cold deform. degreeannealing cycle

    pass sequence

    Outline

    Case Study: HSLA steel Introduction Strengthening mechanisms in HSLA steels Strip processing Automotive application Conclusions

    Available Product forms of differenthigh-strength steels

    HSS

    H o

    t r o

    l l e d

    s t r i p

    E l e c t r o g a l -

    v a n

    i s e

    d

    h o

    t r o

    l l e

    d

    s t r i p

    H o

    t d i p

    g a l v a n

    i s e

    d

    s t r i p

    C o

    l d r o

    l l e d

    s t r i p

    E l e c t r o g a l -

    v a n

    i s e

    d

    c o l d s t r i p

    H o

    t d i p

    g a l v a n

    i s e

    d

    c o l d s t r i p

    BH IF-HS

    P IS

    HSLA DP

    TRIP CP/PM

    Automotive parts madefrom HSLA steels

    0.00

    200

    400

    600

    800

    1000

    1200

    0.00 0.05 0.10True strain

    0.15 0.20 0.25

    DDQDDQDC04, DC06

    AHSSAHSSPM1000, PM800, TRIP700Z, HT500X

    HSSHSSHT340LA, H260P, H260YD,

    H260B, H250G1, H180B

    T r u e s

    t r e s s ,

    M P a

    New steels for automobile applications

    Source :

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    Flow curves of cold-rolled sheet steelsDistribution of steel grades in a

    modern car

    Conclusions

    Microalloying is a well-developed method to increase strength bymaintaining good formability.

    HSLA steels are used widely for automotive applications due totheir attractive properties balance.

    HSLA steels have been developed for many different productforms and process routes.

    HSLA steels are easy handling materials both from theprocessing and from the application point of view.