HRS Co., Ltd. ˜문_1201.pdf · · 2018-01-11We developed the technologies of silicone rubber compounding, siloxane polymer ... market of it was started. (for the first ... Size

HR-TSP is an advanced silicone rubber with high thermal conductivityand superior flame-retardant. By combining the inherent siliconerubber properties of heat resistance, electrical insulation and long-termaging into one compound, this universally applicable material can bemade in an unlimited number of thermal management configurations.

www.hrssilicone.cn www.hrssilicone.com

HRS Co., Ltd.

We will make every effort to meet your service requirements by developingnew technologies and products through continuous research anddevelopment.

SPECIALIST INSILICONE RUBBER TECHNOLOGY

C / O / N / T / E / N / T / S

INTRODUCT ____ 03

HRS HISTORY ____ 04

OVERVIEW OF THE SILICONE RUBBER ____ 06

GENERAL PROPERTIES ____ 06

IMPORTANCE THERMAL CONDUCTIVITY SILICONE RUBBER ____ 07

THERMAL CONDUCTIVITY K ____ 07

HR-TSP SERIES ____ 08HR-TSP N4015 HR-TSP 4020 HR-TSP 4025HR-TSP 6030 HR-TSP 7040 HR-TSP 7050

TSP-FI SERIES ____ 13TSP-FI 4015 TSP-FI 4020 TSP-FI 6025TSP-FI 7030

HR-TC SERIES ____ 16HR-TC 3007 HR-TC 4010 HR-TC 5015

LSI-SH SERIES ____ 19LSI-SH 200/XX LSI-SH 500/XX

OTHERS ____ 21ACF Sheet Spacer panel

CERTIFICATES ____ 22

02

EVERYTHING FOR YOUR LIFE - HRSHRS Co., Ltd. was established in 1981 and developed silicone rubber compoundsfor the first time in Korea. We have focused on silicone rubber business for the last32 years. Now we have a variety of products such as HCR, LSR, RTV, and TSP(thermalconductive silicone rubber).

We developed the technologies of silicone rubber compounding, siloxane polymercomposition, and special functional polymer composition by ourselves. We havedeveloped more than 200 grades of silicone rubber materials for the use of electricityand electronics, information and telecommunication, consumer electronics,automobile, machinery, medical tools and various backbone industries, and thathave been sold in Korea and overseas countries. We are specialized in siliconerubbers and run environmental-friendly management as well as being certified ISO14001.

Our annual production capacity is over 6,000tons from two factories in Pyeongtaekand Asan. We are expanding our markets into Europe and North America as well asAsia and Middle East.

HRS Silicone 03

1978~19851978. 05 Established Hae Ryong Trading

Company (Importing business ofsilicone rubber)

1981. 07 Incorporated as Hae Ryong (started developing the manufacturingtechnology of silicone rubberCompound)

1983. 10 Awarded for New Materialdevelopment by the minister of theMinistry of commerce and industry

1985. 03 Changed the company name to HaeRyong Silicone Co., Ltd. Moved to thenew factory in Gimpo City

1985. 12 Acquired UL-94V0

1986~19901986. 08 Developed the technology for primary

synthesis of silicone gum for the firsttime in the country through acollaborate research with koreaAdvanced institute of Science andtechnology (KAIST)

1987. 06 Developed the basic technology forsilicone gum compounding

1990. 09 Made a contract with Bayer AG inGermany for technological affiliationand sales in Southeast Asia

1991 ~ 19951991. 07 Developed the technology to

manufacture the silicone rubber forgeneral purpose silicone rubber forgeneral purpose molding. UL standardcertification was acquired for that andthe sales in domestic and foreignmarket of it was started. (for the firsttime in Korea).

1991. 10 Established sales agencies inSoutheast Asia (8 Countries includingTaiwan and Malaysia)

1993. 05 Supplied and installed Fire Stop Sealfor the 3rd and 4th Yeonggwangnuclear power plant (the firstlocalization in the country)

1993. 11 Developed the technology tomanufacture the silicone RTV foam(the project to develop basic industrialtechnologies implemented incollaboration with National IndustrialTechnology Center)

SEOUL OFFICEMain BusinessesTrading TeamFinance TeamHR/IR TeamStrategy & Planning Team

PYONGTAEK PLANTMain BusinessesHCR Silicone Rubber LSR Silicone RubberRTV(F/S) Silicone RubberSilicone Gum/PolymerDM Dental Impression Materialsi

04

1995 ~ 20001995. 11 Exported silicone rubber amounting

more than U$5,000,000.00 for the firsttime in the country (received the towerof 5 million dollar export as the prize).Awarded the medal of commendationfrom the governor of Gyeonggi-do forthe merits of export (no.2222)*The tower of 5 million US dollar export

1995. 12 Acquired the certification for EM mark(silicone RTV foam) - National IndustrialTechnology Center no. 95-61

1996. 10 Acquired ISO 9001 certification.

2000 ~ 20052000. 05 Listed in KOSDAQ2002. 11 The company acquired the patent for

the addition- cure type low hardnesssilicone rubber with excellent magneto-adherence.

2004. 08 The construction of Pyeongtaekfactory was completed (productionfacility for silicone polymer, HCR andLSR)

2005. 06 The patent for shielding silicone rubberof self-adhesive electromagnetic waveswas registerd.

ASAN PLANTMain BusinessesRubber ArticleSilicone Sheet (S/S)

CHINA PLANTMain BusinessesRubber ArticleSilicone Sheet (S/S)

HRS Silicone 05

2006 ~2006. 08 Change of representative directors

(collaborative representative directors;Kang,Seong-ja, Ji, Won-Yeong)

2007. 03 Hae Ryong Silicone Company LimitedHRS Company Limited

2007. 07 Form strategic alliance with DowcorningCorporation for HCR business

2007. 10 Acquisition of co-patent with ComtechChemicals Ltd for "Manufacture process oflow hardness and low viscosity silicone foam"

2007. 11 Acquired ISO-140012008. 10 The construction of Asan factory was begun.2008. 11 Exported silicone rubber amounting more

than U$10,000,000.00 * The tower of 10 million US dollar export

2010. 07 Supply Agreement between Hilti and HRS2011. 05 SUZHOU HAERYONG SILICONE CO., LTD.

was established in china2012. 10 Acquired the patent for Silicon polymer

composition for backlight unit buffer spacermaterial of LCD

Silicone rubber’s special features such as “Organosiloxanes Polymer” has been originated from itsunique molecular structure that they carry both inorganic and organic properties unlike other organicrubbers. In other words, due to the Si-O bond of Silicone Rubber and its inorganic properties, SiliconeRubber is superior to ordinary organic rubbers in terms of heat resistance, chemical stability, electricalinsulating, abrasion resistance, weatherability and ozone resistance etc...

With these unique characteristics, Silicone Rubber has been widely used to replace petrochemicalproducts in various industries like aerospace, munitions industry, automobile, construction, electricand electronics, medical and food processing industry. Recently, these scopes of silicone applicationhave been expanding at a great speed by the demand of industries that want more reliable elastomer.

Main Characteristics of Silicone Rubber:- Excellent High and Low Temperature Resistance. - Excellent Electrical Properties. - Physiological Inertness. - Excellent Weatherability. - Oil Resistance. - Flame Retardant.

1. High bonding energy

Silicone rubber has siloxane bond (Si-O) of molecular structure as the main chains. While carbon bond, C-C,carries 84.9 Kcal/mol, siloxane bond carries 106.0 Kcal/mol It shows that siloxane bond has greater capacityand stability. As a result, silicone rubber has better heat resistance, electric conductivity and chemical stabilitythan any other ordinary organic rubbers. Siloxane bond’s energetic stability is secured due to sharp differencebetween Si and O in terms of electro-negativity making Si-O to be closest to ionic bond.

2. Low intermolecular force with spiral structure

With its coil shaped spiral structure and low intermolecular force, silicone (dimethylpolysiloxane) is highly elasticand compressible. Furthermore as methyl groups are located in the outside of coil structure, they are free torotate on its own. As a result silicone rubber has outstanding water repellency and contact resistance.

Bonding Energy Kcal/mol (KJ/mol)

C SI

C 84.9 (349) 58-80 (240-340)

Si 58-80 (240-340) 45 (189)

H 98.8 (414) 72.6 (304)

O 83.2 (349) 106.0 (423)

Classification

OVERVIEW OF THE SILICONE RUBBER

GENERAL PROPERTIES

06

Heat Generation(W)

Heat Generation(W/m2)

Fourier’s Law states that : Q = k

Q = Conducted heat (cal/sec)k = Thermal conductivity (cal/cm sec )A = Cross sectional area of test piece (cm2)L = Thickness of test piece (cm)T = Temperature difference between

* SI-unit conversion factor 1 cal/cm sec = 418.605 W/m both sides of test piece( )

Technology GrowingFrequency HigherSize Lighter

IMPORTANCE OF THERMAL CONDUCTIVITY SILICONE RUBBER

THERMAL CONDUCTIVITY K

HRS Silicone 07

HR-TSP SERIES

>> Soft SiliconeThermal Conductivity Products

_ HR-TSP is an advanced silicone rubber with highthermal conductivity and superior flame-retardant. Bycombining the inherent silicone rubber properties ofheat resistance, electrical insulation and long-termaging into one compound, this universally applicablematerial can be made in an unlimited number ofthermal management configurations.

_ HR-TSP is highly conformable and high heatconducting gel materials in a versatile sheet form. Theyeasily fit most all shapes and sizes of components,including protrusions and recessed area.

Feature_ Excellent thermal conductivity. _ Flexible and adhesive. _ Excellent flame retardant(UL94 V-0)_ Any thickness are available. _ Excellent electrical insulation. _ Retain good physical property in a wide

range of temperature.

Application_ Heat dissipation of MPU(Micro Processing Units) _ Heat dissipation of surface-mount Chips. _ Between a CPU and heat spreader. _ Between a CD ROM and a heat spreader. _ DVD and CD ROM Cooling.(6025/7030)_ RDRAM memory modules.(8035)

08

TSP Characteristics

Heat Transfer (k)Heat Stability

TSP(Thermal Sink Pad)

Geometry

Self BondingBuffering(Absorbing)

InsulationDielectric Strength

Case

LSI(Large - Scale Integration)

Pin

HRS Silicone 09

10

Properties

Thickness (mm)ColorHardness (Shore 00)Specific Gravity (g/cm3)Continue Use ( )Dielectric Breakdown (kV)Volume Resistivity ( cm)Thermal Conductivity (W/mK)Thermal Resistance (m2k/W)Flame Retardant level

Test Method

ASTM D 374Visual

ASTM D 2240ASTM D 792

-ASTM D 149ASTM D 257ASTM 5470ASTM D 150

UL 94

Value

0.5 ~ 45White/ Blue/ Gray/ Pink

30 ~ 702.4

- 60 ~ 150min 6

3 1013

1.55.5*10-3

V-0

TYPICAL PROPERTIES OF TSP-N4015

| Thermal Resistance |0.0122

0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0

Properties


Test Method

ASTM D 374Visual



UL 94

Value


40 ~ 802.7

- 60 ~ 150min 6

1 1013

2.03.8*10-3

V-0

TYPICAL PROPERTIES OF TSP-4020


0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0

HR-TSP N4015 / HR-TSP 4020

HRS Silicone 11


S P E C I A L I S T I N S I L I C O N E R U B B E R T E C H N O L O G Y

Properties


Test Method

ASTM D 374Visual



UL 94

Value


40 ~ 802.8

- 60 ~ 150min 6

1 1013

2.52.8*10-3

V-0


0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0

TYPICAL PROPERTIES OF TSP-6030Properties


Test Method

ASTM D 374Visual



UL 94

Value

0.5 ~ 45Gray

60 ~ 802.9

- 60 ~ 150min 6

1 1011

3.02.4*10-3

V-0


0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0

HR-TSP 4025 / HR-TSP 6030

12


Properties


Test Method

ASTM D 374Visual



UL 94

Value

0.5 ~ 45Gray

60 ~ 803.1

- 60 ~ 150min 6

1 1011

4.01.7*10-3

V-0

Properties


Test Method

ASTM D 374Visual



UL 94

Value

0.5 ~ 45Gray

60 ~ 803.2

- 60 ~ 150min 6

1 1011

5.08.5*10-4

V-0



0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0


0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0

HR-TSP 7040 / HR-TSP 7050

HRS Silicone 13

TSP-FI SERIES

>> Coated Glass Fiber Thermal Conductive Sheet

_ TSP-Fi-SERIES are filled thermally conductive polymersupplied on a rubber coated fiber glass. TSP-Fi-SERIES are a highly conformable.

_ Low modules silicone polymer filled with specialconductive filler that excellent heat conductivity andflame retardant UL94 V-0 level together with goodelectrical properties.

Feature_ Special fillers to achieve specific

performance and characteristics. _ Flexible and conformable. _ Good adhesive. _ Excellent flame retardant(UL94 V-0)_ Various thickness are available. _ Excellent electrical insulation.

Application_ Heat dissipation of MPU(Micro Processing Units) _ Heat dissipation of surface-mount Chips. _ Between Power Sources and Heat Sink. _ Automotive systems. _ Isolate electrical components._ Power supplies. _ Power semiconductors.

HRS Silicone 13

14

TSP-FI 4015 / TSP-FI 4020

TYPICAL PROPERTIES OF TSP-FI 4015Properties


Test Method

ASTM D 374Visual



UL 94

Value

0.3 ~ 2.0White/ Blue/ Gray/ Pink

40 ~ 802.4

- 60 ~ 150min 6

1 1013

1.55.5*10-3

V-0


0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0

TYPICAL PROPERTIES OF TSP-FI 4020Properties


Test Method

ASTM D 374Visual



UL 94

Value


40 ~ 802.7

- 60 ~ 150min 6

1 1013

2.03.8*10-3

V-0


0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0

HRS Silicone 15


TSP-FI 6025 / TSP-FI 7030

Properties


Test Method

ASTM D 374Visual



UL 94

Value


70 ~ 852.8

- 60 ~ 150min 6

1 1013

2.52.8*10-3

V-0

TYPICAL PROPERTIES OF TSP-FI 6025


0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0

Properties


Test Method

ASTM D 374Visual



UL 94

Value


60 ~ 803.0

- 60 ~ 150min 6

1 1013

3.02.4*10-3

V-0

TYPICAL PROPERTIES OF TSP-FI 7030


0.0098

0.0073

0.0049

0.0024

01.2 2.4 3.6 4.8

Ratio (dS/dR)

Res

ista

nce

(m K

/W)

2

6.0

>> High Hardness Thermal conductivity silicone

_ HR-TC SERIES are high thermally conductivity rubbersheets. They provide excellent heat conductivity andcushioning effect.

_ HR-TC SERIES are excellent mechanical and physicalcharacteristics. They are available for sheet, tape or asO-rings

Feature_ Excellent thermal conductivity. _ Excellent flame retardant(UL94 V-0)_ Various thickness are available. _ Excellent electrical insulation. _ Retain good physical property in a wide

range of temperature.

Application_ Heat dissipation of surface-mount Chips. _ Between Power Sources and Heat Sink. _ Automotive systems. _ Isolate electrical components._ Surface panel of LCD & PDP.

HR-TC SERIES16


HR-TC 3007 / HR-TC 4010

HRS Silicone 17

Properties

Thickness (mm)ColorHardness (Shore A)Specific Gravity (g/cm3)Continue Use ( )Dielectric Breakdown (kV)Volume Resistivity ( cm)Thermal Conductivity (W/mK)

Test Method

ASTM D 374Visual


-ASTM D 149ASTM D 257ASTM 5470

Value


351.9

- 60 ~ 150min 7

1 1013

0.7

TYPICAL PROPERTIES OF TC 3007

Properties


Test Method

ASTM D 374Visual



Value


452.4

- 60 ~ 150min 7

1 1013

1.0

TYPICAL PROPERTIES OF TC 4010

07 = Thermal conductivity(0.7W/mK)

30 = Hardness (Shore A)

TC = Thermal Conductivity rubber

TC - 30 07




TC - 40 10

18

TYPICAL PROPERTIES OF TC 5015 Properties


Test Method

ASTM D 374Visual



Value


502.4

- 60 ~ 150min 7

1 1013

1.5

HR-TC 5015




TC - 50 15

HRS Silicone 19

>> High Property LSR Silicone Sheet

_ LSI-SH-SERIES include excellent heat resistance,corona resistance and fine performance as an electricalinsulator.

_ Our line up includes high strength, transparent andflame retardant grades designed for a range of moldingapplications. We are also developing new products forother specific applications

Feature_ High mechanical property. _ Hardness are available from 30 to 70 (Shore A)_ Excellent heat stability. _ Easy cutting and mounting. _ High transparency.

Application_ Cushion of electronic parts. _ Insulating mat. _ Furniture manufacturing. _ IT and display industry._ Construction material.(500/XX)

LSR-SH SERIES

20

TYPICAL PROPERTIES OF LSI-SH 200/XX

TYPICAL PROPERTIES OF LSI-SH 500/XX

LSI-SH 200/XX / LSI-SH 500/XX

Properties

Thickness (mm)AppearanceHardness (Shore A)Specific Gravity (g/cm3)Tensile Strength (kgf/cm2)Elongation (%)Tear strength (kgf/cm)Dielectric Breakdown (kV)Rebound Resilience (%)

200/50

0.3 ~20.0Transparent

501.1290550352055

200/70

0.5~20.0Transparent

701.1590300152060

200/30

0.1~20.0Transparent

301.1185650302050

Properties

Thickness (mm)AppearanceHardness (Shore A)Specific Gravity (g/cm3)Tensile Strength (kgf/cm2)Elongation (%)Tear strength (kgf/cm)Flame Retardant level (UL94)

500/60

0.5 ~20.0White/Black

601.48502007

V-0

500/70

0.5~20.0White/Black

701.48502007

V-0

500/50

0.5~20.0White/Black

501.454020010V-0

xx = Hardness(Shore A)

200 = HRS LSR Silicone series

SH = Silicone Sheet

LSI = HRS Liquid silicone ruber

LSI - SH - 200 / xx

xx = Hardness(Shore A)

500 = Flame retanant Silicone

SH = Silicone Sheet

LSI = HRS Liquid silicone ruber

LSI - SH - 500 / xx

HRS Silicone 21

OTHERS

>> ACF SheetAs a thermal conductivity sheet that is applied for ACF processing of LCD,PDP, LED panel, ACF sheet has superior thermal conductivity and heatstability and optimized products for adhesive ACF processing.

Applications_ Sheet for ACF process of

LCD, PDP, LED panel._ Heat transfer sheet_ Heat resistant separate sheet_ Thermal diffusion sheet

>> Spacer panelSpacer panel product is produced by putting silicone rubber on tape orfilm such as PET, PE ect. It is applied for display space panel, silicone tapeand so on.

Applications_ Spacer panel for TV , monitor

etc . . ._ Electronic, electronics shield_ Silicone adhesive tape_ Silicone adhesive sheet_ Insulating tape, sheet.

Silicone Rubber

Adhesive PET film

CERTIFICATES

22

Ratified certificate

Business license

* The data and information presented in this catalog may not be relied upon to represent standard values. HRS. Co., Ltd, reservesthe right to change such data and information, in whole or in part, in this catalog, including product performance standards andspecifications without notice.

Users are solely responsible for making preliminary tests to determine the suitability of products for their intended use.Statements concerning possible or suggested uses made herein may not be relied upon, or be construed, as a guaranty of nopatent infringement.

HRS Silicone 23

Pyongtaek PlantBlock 6, Choopal Industrial Complex, 394-1 Choopal-ri, Paengseong-eup, Pyongtaek-city, Gyeonggi Province, KOREA 451-805TEL: 82-31-655-8822 FAX: 82-31-691-5901

Asan Plant511-13, Shinbong-ri, Yeongin-Myeon,Asan-City, Chungcheongnam-do, KOREA 336-822TEL: 82-41-543-4003 FAX: 82-41-543-4006

Seoul Office#1605, Miwon B/D, 43 Yoido-dong,Youngdeungpo-ku, Seoul, KOREA 150-733TEL: 82-2-780-6156~8 FAX: 82-2-785-7643

China PlantPlant 1, Science & Technology Park No.777 Kangyuan Road, Suzhou Xiangcheng EconomicDevelopment Zone. TEL: 0512-6939-0288 FAX: 0512-6618-9388

www.hrssilicone.cn www.hrssilicone.com

Documents

HRS Co., Ltd. ˜문_1201.pdf · · 2018-01-11We developed the technologies of silicone rubber compounding, siloxane polymer ... market of it was started. (for the first ... Size