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1 Exhibition Hall 4A Technical Programme Fachprogramm

Honeywell AC High Ambient 2014 10

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Exhibition Hall 4A

Technical

Programme

Fachprogramm

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2006 Specialty Materials Senior Leadership Meeting

R410A and R22 low GWP alternatives for A/C

Focus on high ambient performances

Dr. Jean de BERNARDI, Dr. Abdenacer ACHAICHIA

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Snapshot

• T1 reflects traditional

 A/C conditions

• Increasing Tcond

ratings = need high

Tcritical refrigerants

• Increasing Pressure

ratio ratings =

compressors Heat

Pump optimization

needed for cooling

mode

Middle East is an evolving market

   L   T   R   E   F   R   I

   M

   T   R   E   F   R   I

   A   /   C

HEATING FLOORS

HP REVERSIBLE + SHW

HP RENOVATION 2

HP RENOVATION 1

Typical

R410A MAP

T3(H)

T3

T1

• R22 will be banned in pre-charged equipment in Saudi from 2015 / UAE should follow

• New EERs for ACs to be implemented from Jan’15 in all ME: new rating conditions

• R407C, R410A show a decline in efficiency at high ambient temperatures

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Solstice®

HFO’s – low and medium pressure applicat ions

Current ProductNon Flammable

(ASHRAE A1)

Mildly Flammable(ASHRAE A2L)

Examples of Potential

 Appl ications

R-134aGWP=1300

Solst ice yf GWP <1

 Auto A/C, Vending, Refr igerators

Solstice zeGWP <1

Chillers, CO2 CascadesRefrigerators

R-123GWP= 79

Solstice zdGWP =1

Centrifugal Chillers

High temperature heat pumps

Honeywell’s Solstice® low GWP refrigerants

Solstice® HFO Blends

Current Product

Solstice® N Series

Reduced GWP Option

Non Flammable (ASHRAE

 A1)

Solstice® L Series

Lowest GWP Option

Mildly Flammable (ASHRAE

 A2L)

Examples of Potential

 Appl ications

R-134aGWP=1300

N13 (R-450A)GWP = 547

Chillers, Med-temp

Refrigeration

R-22GWP=1760

N-20GWP = 891

L20 (R-444B)GWP = 295

Stationary A/C, Refrigeration

R-404AGWP=3943

N40 (R-448A)GWP = 1273

HDR 110GWP <150

Low-Temp Refrigeration

R-410AGWP=1924

L41 (R-447A)GWP = 572

Stationary A/C Applications

Note: All GWP values use the latest assessment from the ICCP, “AR5”

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R22

like

R410A

like

Tcr =96oC

Tcr =71oC

Condensation

Evaporation

CompressionExpansion

Condensation

Evaporation

Compression

Expansion

Impact of Tcritical at High Ambient Conditions

More efficient as cycle

operates away from

crit ical temperature

Less efficient as cycle

operates close to cri tical

temperature

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Condenser subcooling = 5oC; condenser TD = 10oC; Evaporating temperature = +10°C; evaporator exi t superheat = 5oC;

suction line superheat = 0oC; volumetric efficiency = 100%; isentropic efficiency = 70%; Capacity equalized at 35oC ambient.

Thermodynamic Performance

Fluid Properties Perf. at 46oC

NameGWP Tcrit

(oC)Glide(oC) Cap. Eff. Td (oC)

R22 1760 96 0.0 100% 100% 94

R407C 1624 86 4.7 97% 96% 86

L20 295 92 7.0 98% 98% 94

N20 891 94 4.9 96% 97% 79

R410A 1924 71 0.1 96% 90% 90

L41 461 84 4.3 98% 95% 100

R32 677 78 0.0 99% 94% 110

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R22 Replacement

Solstice® L20 (R-444B)

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Solstice® L20 (R-444B) as R22 replacement

7.0 kW Cooling only system with nominal COP of 3.0

Capillary tube designed for L20 & R407C

The circuitry of heat exchangers were modified to accountfor the glide and obtain better matching of temperature

profiles of the air and the refrigerant with no cost increase

L20 shows similar capacity and efficiency relative to

R22 over range of ambient temperatures observed inwarm climates

L20 shows 4% to 5% higher efficiency than R407C

L20 has 20% lower mass flow than R22 which leads to

lower pressure drop in the system and offers potentialfor further improvement in performance

L20 reduces the direct emissions substantially due tolower GWP (295) and lower charge (85%)

Performance Results

52

5235

35

46

46

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System meets new efficiency requirements for the Middle East

Overall, Solstice® L20 (R-444B) offers 12% reduction in CO2 emissions compared to R22

LCCP for Middle East Conditions

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Drop In performance shows similar capacity (99%) and COP (100%) and lower mass flow (80%)

L20 shows higher efficiency (103%) when heat exchangers circuitry modified to increase mass

velocity.

 Air Cooled Chillers- R407C Replacement

Solstice® L20 (R-444B)

Drop‐In 

Modified 

Circuitry 

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R410A Replacement

Solstice® L41 (R-447A)

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• Higher efficiency achieved for both heating andcooling modes relative to R410A

• ~11% higher displacement compressor required tomatch R410A capacity

• Discharge temperature was slightly higher with L-41 (~11oC) but well below maximum permissibleand below temperatures typically seen with R-32

Performance Results

Solstice® L41 (R-447A) in Mini-Split

Test condi tions based on ISO Std. 5151

• Honeywell Labs in Shanghai: Reversible splitsystem of 3.6 kW Cooling / 5.0 kW Heating

• Compressor displacement tested: 10.2 & 11.3cc

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Solstice® L41 reduces overall CO2 emissions by 3% in Southern Europe compared to R410A

LCCP for Southern Europe Conditions

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Solstice® L41 (R-447A) in Air Cooled Chillers

Drop In performance in a 70 kW chiller shows lower capacity (90%), slightly higher COP (103%)

and lower mass flow (69%)

Heat exchangers circuitry modified to increase mass velocity

Shows performance similar to R410A by using a 13% larger compressor displacement

Drop‐In

 

Modified Circuitry 

Larger Compressor

 Ai r temperature 35 oC, Water cooled from 12 oC to 7 oC, Superheat and subcooling of 5 oC

Compressor Isentropic and Volumetric efficiency constant

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Refrigerant / Oil Miscibility

Most current system designs assume that the refrigerant and oil aremiscible (one liquid layer).

Immiscibility can lead to oil logging in various parts of the system and can

lead to poor oil return to the compressor or an oil slug to enter the

compressor.Unlike R-32, Solstice® L41 (R-447A) has no immiscible region for all

likely operating temperatures of the A/C or heat pump.

-40

-20

0

20

40

60

80

40% 50% 60% 70% 80% 90% 100%

   T   e   m   p   e   r   a   t  u   r   e   (   °   C   )

Liquid Refrigerant Mass Fraction (g/g)

Miscib ility R410A with POE ISO 68

neatrefrigerant

Miscible

Immiscible

mixture 80% refrigerant/oilseparates at 34

 

C and at 5 

C

Immiscible

-40

-20

0

20

40

60

80

40% 50% 60% 70% 80% 90% 100%

   T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

Liquid Refrigerant Mass Fraction (g/g)

Miscibility R32 with POE ISO 68

neatrefrigerant

Immiscible     M     i    s    c     i     b     l    e

     M     i    s    c     i     b     l    e

-40

-20

0

20

40

60

80

40% 50% 60% 70% 80% 90% 100%

   T   e   m   p   e   r   a   t  u   r   e   (   °   C   )

Liquid Refrigerant Mass Fraction (g/g)

Miscibilit y L41 with POE ISO 68

neat

refrigerant

Miscible

separation at 76 

C for 70%refrigerant/oil mixture and at

-20 

C inc older temperatures

Immiscible

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Summary & Conclusions

Honeywell has developed a family of Low GWP Refrigerants to replace

today’s most common refrigerants in auto & stationary a/c and refrigeration

applications.

Solstice® L20 (R-444B) offers low GWP and superior performance for hotclimates.

Latest R-410A replacement, Solstice® L41 (R-447A) offers comparable

performance to both R-410A and R-32 but avoids the issues of high

discharge temperature and poor miscibility with existing lubricants that is

associated with R-32 while offering lower GWP.

We are continuing to work closely with industry to evaluate these products

in a broad range of stationary air conditioning applications. HFO’s and HFO blends should be considered as part of the solution to transition

away from high GWP refrigerants.

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DISCLAIMER

 Although al l statements and information contained herein are bel ieved to be accurate and reliable, they are presented wi thout guarantee or

warranty of any kind, expressed or implied. Information provided herein does not relieve the user from the responsibility of carrying out its

own tests and experiments, and the user assumes all risks and liability for use of the information and results obtained. Statements or

suggestions concerning the use of materials and processes are made without representation o r warranty that any such use is free of patent

infringement and are not recommendations to infringe on any patents. The user should not assume that all toxicity data and safety measures

are indicated herein or that other measures may not be required.

Thank you!!!

Questions?

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Exhibition Hall 4A

TechnicalProgramme

Fachprogramm