Homework Answers • 10.31 – Constant T so P vap is constant at 28.0 mm Hg • 10.47 – a) melting, b) no change, still liquid • 10.49 – boils when P atm gets down to P vap • 10.51 – 36.6 kJ released • 10.53 – 26.9 kJ released • 10.55 – • 10.57 – 7.12 J/(K∙mole) • 10.119 – BP = 77˚C, Pvap = 58.9 mm Hg Copyright © 2008 Pearson Prentice Hall, Inc. Chapter 1/1

Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

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Homework Answers

• 10.31 – Constant T so Pvap is constant at 28.0 mm Hg

• 10.47 – a) melting, b) no change, still liquid

• 10.49 – boils when Patm gets down to Pvap

• 10.51 – 36.6 kJ released• 10.53 – 26.9 kJ released• 10.55 – • 10.57 – 7.12 J/(K∙mole)• 10.119 – BP = 77˚C,

Pvap = 58.9 mm Hg

Page 2: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Unit Cellsin

Crystalline Solids

Page 3: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 4: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 5: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 6: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Probing the Structure of Solids: X-Ray CrystallographyDiffraction: Occurs when electromagnetic radiation is scattered by an object containing regularly spaced lines (such as a diffraction grating) or points (such as the atoms in a crystal).

Interference: Occurs when two waves pass through the same region of space.

Page 7: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Probing the Structure of Solids: X-Ray Crystallography

Bragg Equation: d =2 sin n

Page 8: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

ATP by X-ray diffraction

Page 9: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 10: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 11: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Unit Cells and the Packing of Spheres in Crystalline Solids

Body-Centered CubicPacking

Simple CubicPacking

Page 12: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 13: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 14: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Unit Cells and the Packing of Spheres in Crystalline Solids

Cubic Closest-Packing

Hexagonal Closest-Packing

Page 15: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Unit Cells and the Packing of Spheres in Crystalline SolidsUnit Cell: A small repeating unit that makes up a crystal.

Page 16: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Primitive cubic unit cell

Page 17: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Primitive cubic unit cell Body-centeredcubic unit cell

Page 18: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Body-centeredcubic unit cell

Primitive cubic unit cell

Page 19: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Face-centered cubic unit cell

Page 20: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Face-centered cubic unit cell

Page 21: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 22: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 23: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 24: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 25: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 26: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 27: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 28: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 29: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 30: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 31: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 32: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 33: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 34: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 35: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Structures of Some Ionic Solids

Page 36: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Structures of Some Ionic Solids

Page 37: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 38: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 39: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

Page 40: Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down

H46 – C10

• 10.11 – 10.16, 10.23, 10.25,10.73 – 10.77(odd), 10.79*, 10.83*, 10.115, 10.121*

A.2-Constant Current and Constant Voltage Regulator

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