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Historic lime mortar: Basic analysis techniques
Dr Alan M Forster
Assistant Professor
Lime mortars: Analysis overview
• Visual
• Acid Dis aggregation
• Thin Section
• ESEM
Visual analysis
Process
-Optical microscopy (20x)
Information derived
- Identification of macro pore
structure
- Aggregate: type, shape & texture
Basic chemical analysis (acid digestion)
Process
- Sample placed in HCL (10%) : Consumption of lime binder
- dry, weigh and grade the aggregate
Information derived
- Approximate mix proportions: lime to aggregate ratio
- Approximate assessment of hydraulicity
Thin section (petrographic) analysis
Process
- Impregnate with resin
- Cut into a thin slice
- Examine under polarised light
Information derived
- Assessment of 2 dim pore structure
- Assessment of aggregate types
Non-hydraulic lime mortar
Hydraulic lime mortar
O.P.C mortar
X-Ray Diffraction (XRD)
Process
- Powder sample
-X-ray bombardment of sample
- Return information indicates
nature of crystalline material
Information derived
- Identification of hydraulic
components and aggregate
types
Incident electron
beam
Backscattered
primary electrons
Secondary electrons
X-rays
Light
Auger electrons
Inelastically
scattered electrons
Unscattered electrons
Absorbed
electrons
SPECIMEN
Environmental Scanning Electron Microscopy
Process
- no need to pre-treat the sample
- place on stage and carbon coat
Information derived
- identification of pore structure
- identification of individual components
- simultaneous EDX mapping
- can simulate environmental conditions: wetting / drying, freeze / thaw etc
Wetting characteristics: hydrophillic surfaces
Wetting characteristics: hydrophobic surfaces
Non-hydraulic lime mortar
Hydraulic lime mortar
Hydraulic lime mortar
Hydraulic lime mortar
Portland cement mortar
Portland cement mortar
Portland cement mortar
Building response to climate change
• PI for £150K EPSRC project “An assessment of binder leaching
in traditional mortars for mass masonry”
• Increased rainfall and solubility of binder
• Loss of structural integrity
Evidence of binder migration
Provenance – regional manufacture
• Researching materials produced from small scale burning
• Complexity of mortars greater than modern counterparts
• Influenced principally by; raw materials (limestones) composition,
calcination temperature, residence time
Experimental Lime
Kiln, Scotland
Experimental Lime
Kiln, Czech
Republic
Selected examples of published works
Conclusion