High Strength Ternary Concrete

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    HIGH STRENGTH TERNARY CONCRETE

    [S. Kavya Priyadarshini1Research Scholar (M.Tech, T.E), Jawaharlal Nehru Technological University Hyderabad]

    [D. Praveen2Research Scholar (M.Tech, T.E), Malla Reddy Engineering College, Kompally]

    Abstract This project focused on study of the effect ofdifferent supplementary cementitious materials (slag cement and

    fly ash) on various properties of concrete, because combinationsof cement additions may provide more benefit for concrete than a

    single one. In present study concrete with ternary blends of

    Portland cement, slag cement and fly ash were produced to

    investigate their effects on compressive strength at 3,7 and 28

    days curing, split tensile strength and compaction factor at 28

    days curing. Portland cement is partially replaced by slag cement

    and fly ash from 0% to 25% of total cementitious material.

    Compressive strength at 3, 7 and 28 days and split tensile

    strength at 28 days shows same variation. Compressive strength

    and split tensile strength were found maximum at 45%

    replacement but modulus of elasticity was found maximum at

    30% total replacement of cement by slag cement and fly ash. The

    test results indicate that combination of fly ash and slag cement

    can be used to increase compressive strength and to increase theworkability of concrete.

    Hence an attempt has been made in the present

    investigation on replacement of cement by fly ash and slag

    cement together. A designed mix of 1:1.425:3.10 mix proportions

    with 53 grade cement, coarse aggregate passing through 20 mm

    sieve with a percentage of 100 %,sand and varying percentages of

    cement and fly ash slag cement are used .Hardened concrete is

    tested for cube compressive strength and split tensile strength.

    An attempt has been made to study the behavior of HIGH

    STRENGTH TERENARY CONCRETE with varying

    percentages of fly ash and slag cement as admixtures.

    KeywordsSlag Cement, ternary concerete, compressive

    strngth, split tensile strength, Flay ash

    1. Introduction

    High performance concrete prepared from ordinary

    Portland cement and various supplementary cementitious

    materials are increasingly finding their use in construction

    worldwide. High performance concrete is in general, cement-

    based concrete which meets special performance requirements

    with regard to workability, strength, and durability, that cannot

    always be obtained with techniques and materials adopted for

    producing conventional cement concrete. Supplementary

    cementitious material such as fly ash, ground granulated blast

    furnace slag and slag cement is extensively used in

    construction. A partial replacement of cement by mineraladmixtures such as, fly ash, slag cement in concrete mixes

    would help to overcome these problems and lead to

    improvement in the durability of concrete. The primary

    advantage of concrete prepared from these materials and

    Portland cement is in the enhancement of fresh and hardened

    properties of the concrete and ecological benefits resulting

    from industrial by-products utilization ratios this would also

    lead additional benefits in terms of energy savings, promoting

    ecological balance and conservation of natural resources etc.

    however the degree to which particular property is improved

    or the rate at which a property is improved is dependent on the

    type and amount of supplementary cementitious material/sused. Among the various minerals additives used in concrete

    mortars, slag cement is highly favored for its superior concrete

    durability properties. Concrete is composed of fine as well as

    coarse aggregates as fillers, and hydrated cement paste as a

    binder resulting from reaction of cementitious materials with

    water. The structure of cement hydration products is greatly

    influenced by the rate of hydration reaction, type of hydration

    products formed, the rate of hydration reaction and the

    resulting hydration products can be substantially modified by

    addition of mineral and chemical admixtures. It has been well

    established that in cement-rich mixtures, the rate of hydration

    reaction is high enough to cause plastic shrinkage cracks as

    well as non-homogeneity in microstructure of concrete. Theaccelerated hydration results significantly from evolution of

    high level of heat due to hydration reaction in the mixture.

    Consequently, long and thin cementing C-S-II crystals are

    formed during the hydration process under such a condition.

    Such crystals occupy less space compared to that formed

    during normal hydration process, leading to a less dense

    concrete microstructure. As a result, concrete strength and

    durability properties are adversely affected. To avoid these,

    low-heat cement as well as mineral and chemical admixtures

    are added. Class C fly ash and slag cement can be added to

    concrete to control rate of hydration reaction and to improve

    its microstructure.

    The improvement in microstructure occurs due to grain as

    well as pore refinements, especially in the interface region

    between the aggregates and Inclusion of a Class C fly ash, up

    to a certain level, can exhibit hydration reaction similar to that

    of concrete made with Portland cement alone. Therefore, a

    blend of Class C fly ash and slag cement should produce an

    improved rate of hydration reaction with a favorable

    microstructure compared to a concrete mixture without the

    addition of Class C fly ash and silica fume. Considering this, it

    was postulated that a blend of Class C fly ash and slag cement

    will result in improved concrete structure due to modification

    of rate of hydration reaction as well as other benefits that are

    derived when Class C fly ash and slag cement are added to

    concrete. This, in turn, will help enhance mechanical anddurability properties of the concrete. This project was

    undertaken primarily to verify this hypothesis in improving

    concrete mechanical properties..

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    2. NEED OF HIGH STRENGTH CONCRETE

    Long term durability, high strength and good workability are

    paramount concern of high performance concrete .hence it is

    desired to produce a concrete having very low permeability,

    high strength in flexure, compressive and split, and high

    modulus of elasticity to make it a high performance. Hence the

    Aims and objectives of this study are

    To determine high strength ternary concrete to use

    ternary blends of fly ash and slag cement

    To prepare the concrete cubes & cylinders using

    cement partly replaced by slag cement and fly ash.

    To determine compressive strength of hardened

    concrete at 3, 7 and 28 days of curing & compare

    various mixes.

    To determine compaction factor and workability

    using slump cone and vee bee test

    To determine split tensile strength at 28 days of

    curing & compare various mixes

    3 SCOPE OF PRESENT STUDY

    The scope of present experimental investigation is to study

    about replacement of cement by the combination of fly ash

    and slag cement together in producing high strength concrete.

    Cement was replaced by the combination of fly ash and slag

    cement together by weight of cement at varying percentage of

    0, 5,10,15,20 and 25

    The cubes were tested for compressive strength at ages of 3

    days 7 days and 14 days cylinders and for split tensile strength

    at 28 days. In the manufactures of concrete pipes, addition has

    shown to increase the external load bearing capacity of the

    increased resistance against chemical attack. Concrete

    containing CSF is known as to have improved resistance tofreezing thawing attack, chloride penetration and deiler

    making it useful for road construction. Other special

    applications are like prepacked concrete and ready mixed

    concrete etc.

    Due to the above reason slag cement can be advantageously

    utilized for preparing concrete mixes, which are stronger,

    more durable and also economical. The addition of slag

    cement does improve the performance of concrete

    substantially. But availability and cost are likely to limit its

    utilization at least for the present, only to special concretes

    suitable for specialized applications.

    4MATERIALS AND METHODSThe selection of mix materials and their required proportion is

    done through a process called mix design. There are number

    of methods for determining concrete mix design. The methods

    used in India are in compliance with the BIS (Bureau of Indian

    Standards). The objective of concrete mix is to find the

    proportion in which concrete ingredients-cement water fine

    aggregate and coarse aggregate should be combined in order

    to provide the specified strength workability and durability

    and possibly meet other requirements as listed in standards

    such as IS: 456-2000. The specification of a concrete mix

    must therefore define the materials and strength work and

    durability to be attained IS: 10262-2009 given the guidelines

    for concrete mix designs. In this study design mix are

    calculated using w/c ratios as 0.45. And nearest results areobtained for mix (1:1.425:3.125, w/c = 0.45). Five mixtures

    are prepared by replacing slag cement as 5% to 25% of total

    cementations material in all mixtures and variation of class-C

    fly ash(recommended by BIS) from 5% to 25 % (total

    replacement is from 0% to 25%)

    HIGH STRENGTH CONCRETE:

    The definition of high strength concrete in quantitative term

    which is acceptable to everyone is not possible. In North

    American practice high strength concrete is usually considered

    to be a concrete with a 28 day compressive strength of at least

    40 M pa. It is defined as concrete having minimum 28 day

    strength of 60 M pa. In many developed countries the concrete

    producers arbitrarily defined the high strength concrete as the

    concrete having the 28 day cube strength of above

    40 M pa when the normal weight aggregate is used. Clearly

    then, the definition of high strength concrete is relative, it

    depends up on both the period of time in question.

    The use of high strength concrete results in many advantages,

    such as reduction in beam and column sizes and increase in

    the building height with many stories. In pre-stressed concreteconstruction, a greater span depth ratio for beams may be

    achieved with the use of high strength concrete. In marine

    structures, the low permeability characteristics of high strength

    concrete can perform much better in adverse climatic

    conditions, and can reduce maintenance and repair costs.

    Extensive research works both at national and international

    level has been done on the use of various mineral admixtures

    in mortars and concrete with common goal.

    To combat the environmental hazards from the

    industrial wastes.

    To modify the properties of traditional concrete to the

    desired level suitable to the specific circumstances.

    To converse the natural resources used in the

    production of construction materials.

    To bring down the increasing cost economies of

    cement, building blocks and high strength concretes.

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    To rehabilitate the existing structures which are deteriorated

    over period of time. In India, only government educational and

    research institutions and constructions departments are

    responsible for research while in advanced countries, the most

    remarkable break through has been achieved by the building

    material industries and their R & D laboratories.

    An accepted fact in that these encouraging results on the use

    of admixtures are not penetrating into the user community andthe entire research work is flocked their origination. With the

    result, the very purpose of research work is questioned. Along

    with R & D units, the policy makers and consultants should

    take more interest in handling these issues directly keeping not

    only the techno economics in view but also national

    obligations.

    An attempt is made in this section to review the literature on

    mineral admixtures. With special reference to slag cement and

    fly ash there by summering the constructive conclusions of the

    researchers at one place for a glancing scan through.

    TERNARY CONCRETE

    High strength concrete or high performance concrete will be

    produced by using pozzolonic materials like fly ash, slag

    cement etc. The replacement of cement by any of this

    pozzolonic material is called binary concrete. The replacement

    of cement by one or more pozzolonic materials is called as

    ternary concrete. In the present investigation the pozzolonic

    materials slag cement and fly ash is used.

    Mix proportion

    Five mixtures were prepared by using ternary system of

    OPC, slag cement, and fly ash. One is control mix and

    other five mixes are made by replacing cement by slag

    cement as 5% to 25% in all mixtures and fly ash and slag

    cement varying from 5% to 25%.detailing of these

    mixtures is given in table 3.9.

    Materials used are as follows-

    Total cementitious material = 5 kg/m3

    Water = 7.5 lit/m3

    Fine aggregate = 7.125 kg/m3

    Coarse aggregate = 15.5 kg/m3

    W/c ratio = .45

    Cement: F.A:C.A = 1:1.425:3.10

    Mix Design

    S.noMix

    design

    Cement

    (kg/m3)

    Slag

    cement

    %

    Fly

    ash

    %

    w/c

    ratio

    1 5% 5 0 0 0.45

    2 10% 4.5 2.5 2.5 0.453 15% 4 5 5 0.45

    4 20% 3.5 7.5 7.5 0.45

    5 25% 3 10 10 0.45

    Size of Moulds

    S.no Moulds SizeSpecimen

    casted

    1Slump

    cone--

    Compaction

    Factor

    2 Cube150 mm X150mmX150mm

    CompressiveStrength

    3 Cylinder300mm

    X150mm

    Split Tensile

    Strength

    Testing Procedure and experimental setup

    After the specified period of curing the specimens were taken

    out of the curing tank and their surfaces were wiped off. The

    various tests were performed as described below.

    1 . Compressive Strength of cubes at 3, 7 14 and 28 days.

    2. Split Tensile Strength of cylinders at 28 days.

    Compressive Strength

    The specimens were tested at the age of 3, 7 14 and 28 days.

    The cubes were tested on compression testing machine after

    drying at room temperature according to IS 516- 1959. The

    load was applied continuously without impacts and uniformly

    140kg/cm/minute. Load was continued until the specimen

    failed and maximum load carried by the specimen was

    recorded. The cube compressive strength was obtained by

    considering the average of three specimens at each age.

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    Fig.4.1 Compression testing machine

    4.2 Split Tensile Strength

    The splitting tests are well known indirect tests used for

    determining the tensile strength of concrete. The test consists

    of applying a compressive line load along the opposite

    generators of a concrete cylinder placed with its axis

    horizontal between the compressive plates. due to the

    compression loading a fairly uniform tensile stress is

    developed over nearly 2/3 of loaded diameter as obtained from

    an elastic analysis. Due to this tensile stress a vertical crack is

    appeared in the cylinder at the failure. The magnitude of this

    tensile stress sp(acting in a perpendicular to the line of action

    of applied loading) is given by the formula(IS : 5816-1970) :sp= 2P/dl

    Fig. 4.2 Tensile testing of cylinder in CTM

    Fig.4.3 Specimen failed in tension (vertical crack is

    appeared)

    As mentioned in Section 1.4 of Chapter one above, since theobjective of the study was to understand the effects of various

    factors such as the seasonal variation, weekly variation, time

    of day variation, collision type, victim gender, crash location,

    and vehicle type on injury severity of crashes on NH-202,

    several data sources have to be used to obtain all the data

    necessary to carry out the study. In order to meet this objective

    of the research, which specifically is attempting to create a

    better understanding the effects of these factors believed to

    possibly influence injury severity, collection of accurate and

    representative data was the most critical and of course

    lengthiest part of the research.

    5RESULTS AND CONCLUSIONThe results of 3, 7 and 28 days compressive strength, split

    tensile strength are shown in Table 5.1 to 5.2 and in Fig. 5.1 to

    5.2 these results are discussed in the following sections under-

    5.1 Variation of 3, 7 and 28 days compressive & split

    tensile strength

    150mmX150mmX150mm size cubes were casted to calculate

    compressive strength. Cubes were tested after 3 7 and 28 days

    curing in compression values testing machine. Results

    obtained are tabulated in Table 5.1 and in Fig.5.1 to 5.2 andcompared in Fig. 51as shown below. 150mmX300mm

    cylinders were casted to calculate split tensile strength.

    Specimens were tested for split tensile strength after 28 days

    of curing in compressive testing machine. Results obtained are

    shown in Table 5.2 below.

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    Table 5.2(a) Variation of 3, 7 and 28 days compressive

    strength

    S.no

    % of fly ash

    and slag

    cement

    3days

    compressive

    strength

    7days

    compressive

    strength

    28days

    compressive

    strength

    1 100% OPC 210KN 220KN 245KN

    2 5% 197KN 192KN 195KN

    3 10% 198KN 195KN 205KN

    4 15% 204KN 202KN 210KN

    5 20% 188KN 192KN 185KN

    6 25% 176KN 170KN 170KN

    Discussion

    1. The compressive strength of any mix increases withcuring time. The percentage increase in compressive

    strength of control mix from 7 days to 28 days is 202KN

    to 210KN. This percentage increment increases up to 15%

    replacement and, after 15% replacement this increment

    starts decreasing and minimum at 25% replacement.

    2. The compressive strength for 7 days curing period,continuously decreases from control mix 20% to, mix for

    replacement of 25%, whereas for 28 days curing period, it

    increases from control mix from 5%to 15% replacement,

    the increment is 210 KN from 5% to 15% after this

    compressive strength suddenly decreases, this decrement

    is 170KN from mix 20% to 25% mix

    Table 5.2 (b) Variation of 3, 7 and 28 days split tensile

    strength

    S.no

    % of fly

    ash and

    slag

    cement

    3 days

    Split

    tensile

    strength

    7 days

    Split

    tensile

    strength

    28 days

    Split

    tensile

    strength

    1 5% 90KN 105KN 108KN

    2 10% 109KN 129KN 132KN

    3 15% 126KN 130KN 138KN

    4 20% 121KN 122KN 126KN

    5 25% 120KN 120KN 122KN

    The variation in 28 days split tensile strength is very similar

    to the 28 days compressive strength, it increases from 5% mix

    to 15% mix and then deceases from 15% mix to 25% mix.

    The increment from 5% mix to 15% mix is 2.55% and from

    15% mix to R-45 mix is 2.77%. The decrement from R-45 mix

    to R-60 mix is 12.93% and from R-60 mix to R-75 mix is

    19.19%.

    Conclusion

    Following conclusions have been drawn based on the results

    obtained:

    Compressive strength for 3 days for control mix was

    found as 204KN. Generally it should be the about

    210KN (5% of target mean strength). It may be due

    to the effect of temperature of curing water as the

    temperature of curing water was less than normaltemperature required. Compressive strength was

    consciously increases from 5% to 15% Decrease from

    20% to 25% is very less but it was more for 5% to

    15%. It may be due to the increased content of fly

    ash. As reaction of slag cement and fly ash starts after

    some days.

    Compressive strength at 7 days curing period was

    found maximum for 15% total replacement (7.5%

    slag cement and 7.5% fly ash). It may be due to the

    decrease in porosity and due to the change of calcium

    hydroxide in to CSH gel by slag cement and fly ash.

    On further addition of fly ash, compressive strength

    starts decreasing. This decrement is due to thedecrease in quantity of CSH gel due to the decrease

    in quantity of cement in mixture. The28 days

    compressive strength also found at 15% replacement

    Increase in 3 & 7 days compressive strength and split

    tensile strength up to 15% is due to decrease in

    permeability by the finer particles of slag cement and

    due to the conversion of Ca(OH)2in to C-S-H gel by

    the fly ash, which(C-S-H gel) is responsible for the

    strength of concrete.

    Decrease in 3, 7 and 28 days compressive strength

    and split tensile strength after total replacement of

    25%, is due to increase in fly ash content. Because

    due to the addition of fly ash after 25% total

    replacement, percentage of cement is very less due to

    which formation of C-S-H gel decreases, same time

    formation of Ca(OH)2 is also decreases. Due to

    decrease in Ca(OH)2and increase in fly ash quantity

    most of the fly ash remains useless and strength

    decreases.

    By using fly ash and slag cement, we can make a

    concrete with higher strength as per Indian standards

    which cannot be possible by using ordinary Portland

    cement alone. Also by replacing cement with slag

    cement and fly ash mix we can reduce the use of

    cement and by this emission of CO2, which forms

    during the formation of cement.

    Use of fly ash in making concrete, results inecological benefits as now a days Fly ash is a major

    solid industrial waste. It occupies a considerable

    amount of land and pollutes air and water sources.

    The disposal of fly ash is an environmental problem,

    as fly ash discharged on land may quickly spread far.

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    Scope for future work

    Properties of concrete discussed above can be further studied

    by taking in to account

    The following parameters:

    1.

    By varying the percentage replacement of fly ash

    with 5% 10% 15% 20% and 25%, more exactvariations can be found and more accurate value of

    percentage replacement, which gives the strength

    values, equals to strength values for control mix can

    be found.

    2. With the different percentage of fly ash and slag

    cement.

    3. Using different grade of cement i.e. 33 grade and 53

    grade.

    4. Using recycled aggregate.

    5. Using fiber concrete in place of plain concrete.

    GRAPHS

    Table 5.1: 3 days compressive strength for fly ashand slag cement

    S.

    No

    % Fly ash and

    Slag cement

    3 days Compressive

    strength (KN)

    1 5% 197

    2 10% 198

    3 15% 204

    4 20% 188

    5 25% 176

    Table 5.2: 7 days compressive strength for fly ash and slag

    cement

    S. No

    % Fly ash

    and Slag

    cement

    7 days Compressive

    strength (KN)

    1 5% 192

    2 10% 195

    3 15% 202

    4 20% 192

    5 25% 170

    REFERENCES

    1.

    Baoyu, L.; Angi, L.; and Pengfei, X., Applicationof concrete incorporating both condensed slagcementand fly ash at fancuo hydropower station, flyash, silica fume, slag, and natural pozzolans inconcrete proceedings, third international conference,SP-114, Americanconcrete institute, Detroit, 1989, V. 1,

    pp. 593-606.

    2. D.S. Lane, C. Ozyildirim Virginia TransportationProject Council, 530 Edgemont Rd.,Charlottesville, VA22903, USA:1998

    3.

    Elkem microsilica, Triple blend with fly ash CS-03 application : 2002

    4. G.G. Bye,Portland cement composition productionand propertiesPergamon, Oxford, UK,1983.

    5. G. J. Lynsdale and M. I. Khan, Chloride andoxygen permeability of concrete incorporating fly ashand slag cementin ternary systems SP 192-45

    170175

    180

    185

    190

    195

    200

    205

    210

    0% 10% 20% 30%comm

    pressivestrength

    Percentage of slag cement and fly ash

    3 days Compressive strength (KN)

    3 days

    Compr

    essiv

    160

    170

    180

    190

    200

    210

    0% 10% 20% 30%

    7 days Compressive strength (KN)

    7 days

    Compressi

    ve