High-resolution Patterning Technologies using Ink-jet Printing and Laser Processing for Organic TFT Array Koei Suzuki, Kazuaki Tsuji, Atsushi Onodera, Takeshi Shibuya, Takanori Tano, and Hiroshi Miura; Research and Development Group, RICOH Co., Ltd.; Yokohama, Japan

Abstract

A 150 ppi organic thin film transistor (OTFT) array, which TFT have pixel circuit with two transistors and one capacitor was fabricated by printing methods and laser processing. TFT array pitch was 169 μm, a minimum width of the source electrode was 15 μm, channel length was 5 μm, and a diameter of via hole was about 20 μm. We have developed the surface energy controlled ink-jet printing with UV irradiation for fine Ag electrodes and the conventional ink-jet printing for organic semiconductor (OSC), and laser processing for Via hole.

Introduction In recent years, printed electronics are gaining attention as a

technology that enables various electric devices such as organic thin film transistors (OTFTs) [1, 2], RF-ID tags [3], printed circuits [4], sensors [5], displays [6] to be fabricated using printing process. This is because printing technologies have their potential for low cost, low environmental impact and large area fabrication. Then, several printing methods such as ink-jet printing, flexographic printing, screen printing, gravure printing, off-set printing have been developed to fabricate these devices. Ink-jet printing method has advantages of on-demand process, non-contact printing process and its scalability. However, one of the important problems is the resolution. A typical resolution using a conventional ink-jet printing method is limited around 50 μm. Therefore various methods have been proposed to improve resolution of printing using bank structures [2], self-assembled monolayer [7] and laser irradiation during ink-jet printing [8]. Another important problem is to connect two TFTs through a via for more functional devices such as RF-ID, printed circuit and sensors.

In previous work, we have developed the surface energy controlled ink-jet printing technique with UV irradiation son a novel polyimide for high-resolution electrode patterning [9] and fabricated 160 ppi all-printed TFT array on plastic substrate in 2008 [10, 11]. Then, we published 200 ppi all-printed TFT array and demonstrated a 200 ppi electronic paper display in 2009 [12]. Furthermore, we fabricated finer TFT array, a 300 ppi all-printed OTFT array on plastic substrate in 2010 [13]. Those TFT have pixel circuit with a single transistor and a storage capacitor (1T1C) for electrophoretic display, which is driven by applying a voltage across the two electrodes. TFT array pitch for 300 ppi with 1T1C is 85 μm.

In this paper, we have developed a new fabrication process of printed OTFT array using the surface energy controlled ink-jet printing and laser processing to connect two TFTs. And to integrate these methods, we fabricated current driven TFT array, which TFT have pixel circuit with two transistors and one storage capacitor (2T1C) [14]. TFT array pitch is 169 μm.

Experiment

TFT structure Figure 1 shows a schematic cross-section of printed OTFT

array with 2T1C. OTFT array pitch is 169μm. TFT is bottom-gate bottom-contact structure. The gate electrodes of both two transistors were fabricated using Ag nanoparticles ink by the surface energy controlled ink-jet printing. The gate insulator was a novel polyimide film fabricated by spin coating. Via hole was fabricated using excimer laser ablation, and diameter of via hole was about 20 μm. The source/drain (S/D) electrodes of both two transistors consist of Ag were also fabricated by surface energy controlled ink-jet printing method. During this step, the drain electrode of the switching transistor (Tsw) was electrically connected to the gate electrode of the driving transistor (Tdr) through a via. Small-molecule OSC for 150 ppi OTFTs with 2T1C was fabricated by conventional ink-jet printing under ambient conditions.

TswTdr

Substrate

Gate Insulator

Organic Semiconductor

Via

S/D Electrode Gate ElectrodeGate Electrode S/D Electrode

TswTdr

Substrate

Gate Insulator

Organic Semiconductor

Via

S/D Electrode Gate ElectrodeGate Electrode S/D Electrode Figure 1. Schematic cross-section of a printed OTFT array with 2T1C.)

Surface energy controlled ink-jet printing process and laser processing

We have developed a new hybrid process of the surface energy controlled ink-jet printing and laser processing for high-resolution and high-functional electrode patterning (see Figure 2). To contact two electrodes, additive process is only laser ablation compared with our previous surface energy controlled ink-jet printing methods.

The novel polyimide film was fabricated on electrodes by spin coating, whose surface had low surface energy after post-baking in N2 condition at 180˚C (Figure 2(a)). Next, via hole was made by selective removal of the polyimide film using an excimer laser (KrF λ=248nm) (Figure 2(b)). After UV irradiation from super-high pressure mercury lamp through a photo mask from the front side of the substrate, the high surface energy area corresponding to electrode patterns and the low surface energy area were formed on the novel polyimide film surface (Figure

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2(c)). Hydrophilic Ag nanoparticles ink was ink-jetted onto the high surface energy area and spread over the edge of the area with via hole filling (Figure 2(d)). After post-baking under ambient condition at 180˚C, the fine electrode patterns with via were fabricated. Using this novel polyimide as an insulating layer, additional fabrication process of wiring is only two photo process. One is exposure process without such wet process as development and cleaning. The other is laser processing to make electrical connection of two electrodes through a via. Thus, our hybrid process of the surface energy controlled ink-jet printing and laser processing takes advantage of practical number of process steps. Using laser processing for via hole we are connecting two more TFTs, and can fabricated higher functionality.

High surface energy area

(c) Photo maskUV irrad iation

(b) Laser ablat ionVia hole

Electrode

Ink-jet head(d)

Hydrophilic inkVia

Substrate

Nobel polyimide

(a)Low surface energy areaElectrode

High surface energy area

(c) Photo maskUV irrad iation

High surface energy area

(c) Photo maskUV irrad iation

(b) Laser ablat ionVia hole

(b) Laser ablat ionVia hole

Electrode

Ink-jet head(d)

Hydrophilic inkVia Electrode

Ink-jet head(d)

Hydrophilic inkVia

Substrate

Nobel polyimide

(a)Low surface energy areaElectrode

Substrate

Nobel polyimide

(a)Low surface energy areaElectrode

Figure 2. Schematic of the surface energy controlled ink-jet printing process (a) novel polyimide film coating, (b) Via hole pattering, (c) Formation of areas with different surface energy by UV irradiation, (d) Fabrication of electrodes with via by ink-jet printing

Results and Discussion

Electrode printing Figure 3 shows an optical micrograph of electrode patterns

overlaid with the gate insulator (a) without and (b) with the surface energy controlled ink-jet printing. Electrodes without the surface energy controlled ink-jet printing (Figure 3(a)) show droplet-like shape and rough surface with interference fringes, which depends on the difference of the film thickness due to surface roughness of electrodes. On the other hand, electrodes with the surface energy controlled ink-jet printing (Figure 3(b)) show photo mask-like sharp profile and very smooth surface because of no interference fringes.

(a)

(b)

Figure 3. Optical micrograph of electrodes (a) without and (b) with the surface energy controlled ink-jet printing

To investigate the minimum space between two electrodes, we prepared a photo mask with various line and space patterns. After UV irradiation on the novel polyimide film through the photo mask, hydrophilic Ag nanoparticles ink was ink-jetted. Controlling with ink-jet printing conditions such as drop size and ink volume per unit line, two kinds of electrodes with different thicknesses were fabricated. Figure 4 shows the dependence of the yield of electrodes separation on designed space against electrode thickness. Yield means the ratio of separation between the two electrodes and was determined by using an optical microscope with 100 points in one sheet. Figure 4 shows that minimum space up to 2 µm (designed) could be fabricated using the surface energy controlled ink-jet printing with UV irradiation on the polyimide film. In this case, minimum space of this photo mask was 2 µm. Then, smaller designed space of 1.0, 0.8, 0.6, 0.4 µm was investigated. Figure 5 shows the electrodes with minimum space

490 ©2013; Society for Imaging Science and Technology

0.8 μm (1.4μm measurement) was successfully fabricated for our process. Then, our surface energy controlled ink-jet printing is superior in the resolution to conventional ink-jet method.

We also examined alignment margin of electrode fabrication by this ink-jet technique, increasing the distance between the center of high surface energy line pattern and that of ink droplets impinging position 10 μm. Figure 5 shows that electrodes with linewidth of 80 μm can be successfully formed same as photo mask patterns apart from the center of the ideal impinging position by a distance of 50 μm. This is because the hydrophilic ink droplets, which land onto the low surface energy area, could be drawn into the high surface energy area. It is necessary to control jetting conditions such as velocity deviation and angle deviation from ink-jet nozzles for the conventional ink-jet printing precisely. Otherwise, the alignment margin of our process was very large such as ±50 μm for linewidth of 80 μm. Then, our process was robust for jetting conditions.

Thus, the surface energy controlled ink-jet printing technique possesses such unique features as good surface roughness, high-resolution patterning and high alignment margin because of using a photo mask.

0

20

40

60

80

100

120

0 2 4 6 8 10

Space (designed) [μm]

Yie

ld [%

]

Thickness AThickness B

Figure 4. Relationship between yield of electrodes separation and designed space against electrode thickness

20 μm20 μm

Figure 5. Optical micrograph of electrodes with minimum space 0.8 μm (1.4 μm measurement).

Impinging positions of ink droplets

10 30 50 μm

Impinging positions of ink droplets

10 30 50 μm

Figure 6. Optical micrograph of electrodes with linewidth of 80 μm to show alignment margin of the surface energy controlled ink-jet printing. White circles show impinging position of ink droplets

Via formation To confirm via formation process experimentally, we

fabricated via-hole chain test pattern. Both line width of upper electrode and lower electrode were 60 um. Diameter of via-hole was 20um and number of via-hole in series was 960. We fabricated successfully all via without any failure to optimize such as the upper and lower electrode thickness and laser ablation condition. Electrical connection between two electrode layers was also confirmed and resistance per via is below 0.1 Ohm. Figure 7 shows a SEM image with cross-section of via of test pattern. As shown in this figure, via-hole filling and upper electrode formation with fine shape can be confirmed.

Polyimide

Upper Electrode(Ag nanoparticle)

Lower Electrode (Ag nanoparticle)

Polyimide

Upper Electrode(Ag nanoparticle)

Lower Electrode (Ag nanoparticle)

200nm

Polyimide

Upper Electrode(Ag nanoparticle)

Lower Electrode (Ag nanoparticle)

Polyimide

Upper Electrode(Ag nanoparticle)

Lower Electrode (Ag nanoparticle)

200nm

Figure 7. A cross-section SEM image of a via.

Process integration of TFT array For printing process, deposition and pattering is same step.

This point of view is very important for process integration of printing process. In general it is difficult to achieve fine electrode patterning and low resistivity at same time. Therefore, we optimized the electrode thickness and the curing time for low resistivity. The electrode thickness was controlled by ink-jet condition such as ink volume per unit line. For example, the electrical resistance per unit length at 30 μm linewidth was 0.5 kΩ/cm.

We have fabricated a 300 ppi (TFT pitch is 85 μm × 85 μm) all-printed OTFT array with 1T1C on plastic substrate (see Figure 8). The minimum linewidth of the gate line and the source line were 25 μm, 20 μm, respectively. And both of the minimum space

NIP 29 and Digital Fabrication 2013 491

of the gate line and the source line were 10 μm. A channel length was 3 or 5 μm, a channel width is 57μm.

Next, we have optimized TFT design such as the line and space of the gate electrode and the S/D electrode. Adding to new laser ablation process for via formation, we have fabricated a 150 ppi (array pitch is 169 μm × 169 μm) printed OTFT array with 2T1C (see Figure 9). The minimum linewidth and the minimum space of the gate line were 25μm and 10 μm, respectively. And the minimum linewidth and the minimum space of the source line were 15 μm, 10 μm, respectively. A channel length was 5 μm, a channel width is 40μm. Via hole diameter is 20μm. Optimizing the surface of the gate insulator and small molecule OSC ink formulation such as the solvent and the concentration, OSC profile was separated with each others at 169 μm pitches without any bank structure. Maximum process temperature was 180˚C. All printing process, UV irradiation and laser process were done in air. Therefore, we showed a low cost, low environmental impact and high functional manufacturing process with the finest photo-assisted printed TFT array.

100μm100μm

Figure 8. Optical micrograph of a 300 ppi printed OTFT array with 1T1C (after S/D electrode fabrication).

100μm

Tdr

Via holeTsw

Figure 9. Optical micrograph of a 150 ppi printed OTFT array with 2T1C (after S/D electrode fabrication).

Performance of OTFT The transfer characteristics of a 150 ppi printed OTFT with

2T1C, W/L = 40 μm / 5 μm after OSC printing. Mobility of 0.19 cm2/Vs, Vth of 5.4 V, an on/off current ratio of 106 at Vds = -20 V were obtained after small-molecule OSC printing (see Table 1). These value were almost same as those of 300 ppi all-printed OTFT with 1T1C. High on/off current ratio is because of the separation of small-molecule OSC patterning with high mobility of TFT to optimize small molecule OSC printing process. As shown in figure 10, transfer characteristic of driving transistor can be controlled by voltage “Vsel” applied to switching transistor. Then we showed the switching characteristics of two transistors through via.

Table1 Transfer characteristics of 150 ppi 2T1C and 300 ppi 1T1C

　 1T1C 2T1C Channel length L [μm] 5 5 Channel width W [μm] 57 40 Mobility [cm2/Vs] 0.25 0.19 Vth [V] 1.3 5.4 on/off current ratio > 106 ~ 106

1.E-13

1.E-12

1.E-11

1.E-10

1.E-09

1.E-08

1.E-07

1.E-06

1.E-05

-20 -10 0 10 20Vsig / V

-Id

d / A

Vsel -20VVsel -5V

Vsel 0VVsel +10V

Vsel +20V

Figure 10. Static Characteristic of Integrated Transistor Circuit of a 150 ppi with 2T1C (Channel length L = 5 μm).

Conclusion We have developed the surface energy controlled ink-jet

printing with UV irradiation for Ag electrodes and the conventional ink-jet printing for OSC, and laser processing for Via hole. To integrate these printing methods and laser processing we have succeeded in fabricating a 150 ppi OTFT array with 2T1C. Laser processing method, surface energy controlled ink-jet printing method and conventional ink-jet printing method have very high affinity to digital fabrication. Then, our hybrid process of the surface energy controlled ink-jet printing and laser processing is promising for high-resolution, high-functional, low-cost and low-environmental impact manufacturing process.

492 ©2013; Society for Imaging Science and Technology

References [1] Z. Bao, Y. Feng, A. Dodabalapur, V. R. Raju, and A. J. Lovinger,

“High-Performance Plastic Transistors Fabricated by Printing Techniques,” Chem. Mater., 9, 1299 (1997).

[2] H. Sirringhause, T. Kawase, R. H. Friend, T. Shimoda, M. Inbasekaran, W. Wu, and E. P. Woo, “High-Resolution Inkjet Printing of All-Polymer Transistor Circuits,” Science 290, 2123 (2000).

[3] V. Subramanian, J. Frechet, P. Chang, D. C. Huang, J. Lee, S. Molesa, A. Murphy, D. Redinger, and S. Volkman, Progress Toward Development of All-Printed RFID Tags: Materials, Processes, and Devices, Proceedings of the IEEE, 93, 1330 (2005).

[4] M. Mantysalo, P. Mansikkamaki, J. Miettinen, K. Kaija, S. Pienimaa, R. Ronkka, K. Hashizume, A. Kamigori, Y. Matsuba, K. Oyama, N. Terada, H. Saito, M. Kuchiki, M. Tsubouchi, Evaluation of Inkjet Technology for Electronic Packaging and System Integration, Proc. ECTC’07, pg. 89 (2007).

[5] Y. Noguchi, T. Sekitani, and T. Someya, “Organic-transistor-based flexible pressure sensors using ink-jet-printed electrodes and gate dielectric layers,” Appl. Phys. Lett., 89 253507 (2006).

[6] T. Okubo, Y. Kokubo, K. Hatta, R. Matsubara, M. Ishizaki, Y. Ugajin, N. Sekine, N. Kawashima, T. Fukuda, A. Nomoto, T. Ohe, N. Kobayashi, K. Nomoto and J. Kasahara, 10.5-inch VGA All-printed Flexible Organic TFT Backplane for Electrophoretic Displays, Proc. IDW’07, pg. 463 (2007).

[7] T. Arai, N. Sato, K. Yamaguchi, M. Kawasaki, M. Fujimori, T. Shiba, M. Ando, and K. Torii, “Self-Aligned Fabrication Process of Electrode for Organic Thin-Film Transistors on Flexible Substrate Using Photosensitive Self-Assembled Monolayers,” Jpn. J. Appl. Phys., 46(4B), 2700 (2007).

[8] A. Endo, and J. Akedo, “Development of Laser-assisted Inkjet Printing Technology,” Synthesiology, 4, 9 (2011).

[9] T. Tano, H. Tomono, H. Kondoh and K. Fujimura, Organic Thin-film Transistors with a Novel Polyimide Gate Insulator, AMLCD2004 Digest, pg. 37 (2004).

[10] K. Suzuki, K. Yutani, A. Onodera, T. Tano, H. Tomono, A. Murakami, M. Yanagisawa, K. Kameyama and I. Kawashima, A 160 ppi All-printed Organic TFT Backplane for Flexible Electrophoretic Displays, IDW’08 Digest, pg. 1477 (2008).

[11] T. Tano, H. Tomono, A. Onodera, K.Yutani, A. Murakami, and K.Suzuki, Novel Fine Electrode Patterning Using Ink-jet Method and Its Application to All-printed Organic TFT Backplane, Proc.NIP25/DF2009, pg. 631 (2009).

[12] K. Suzuki, K. Yutani, M. Nakashima, A. Onodera, S. Mizukami, M. Kato, T. Tano, and H. Tomono, M. Yanagisawa, and K. Kameyama, A 200 ppi All-printed Organic TFT Backplane for Flexible Electrophoretic Displays, Proc. IDW09, pg. 1581 (2009).

[13] K. Suzuki, K. Yutani, M. Nakashima, A. Onodera, S. Mizukami, M. Kato, T. Tano, and H. Tomono, “Fabrication of All-printed Organic TFT Array on Flexible Substrate ,” J. Photopolym. Sci.Technol., 24, 565 (2011).

[14] A. Onodera, K. Tsuji, T. Shibuya, T. Tano, H. Miura, and K. Suzuki, Fabrication of Organic TFT Array using Ink-jet Printing and Laser Processing, Proc. ICFPE2012, S5-I2(2012)

Author Biography Koei Suzuki received M.S. degree in physical chemistry from Tohoku

University in 1991. He joined Ricoh Research Institute of General Electronics in 1991 and transferred to Research and Development Group at Ricoh in 1993. He started to research Si semiconductor process. Now he is in charge of the research and development of printed electronics. He is a member of ISJ (The Imaging Society of Japan).

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Introductory MaterialCopyrightISBN: 978-0-89208-306-0WelcomeConference ExhibitorsConference CommitteeTable of ContentsWeek At-a-GlanceFloor PlanConference SponsorsSpecial EventsTechnical Papers ProgramKeynote TalksHague, Exploring the Potential of Additive Manufacturing †pg.1Fu, Printing the Next Generation of Point-of-Care†pg.2McCoog, Printing Evolution in a World Dominated†pg.3Umezu, 3 Dimensional Prints (3DP) of Artificial Cell†pg.4

3D Printing SessionKlein, 3D Printing: When and Where Does it Make Sense?†pg.5Ready, 3D Printed Electronics†pg.9Cahill, Selecting Digital Deposition Methods†pg.13Huson, 3D Printing of Self-Glazing Ceramic Materials†pg.14Snyder, Line-on-Line Image Formation Analysis†pg.18

E-Paper SessionTakano, Effects of Tablet Devices on Reading to Support†pg.23Kobayashi, Reflective and Emissive Dual Mode†pg.28Nakamura, Thermo-Switchable Imaging Medium†pg.32

Displays/Solar Cells Interactive PreviewsKosugi, Optimization of Titania Thickness†pg.36Satoh, Luminescent Properties of High Color Rendering†pg.40

Image Permanence and Print Quality SessionBurge, Mitigation of Pollution-Induced Deterioration†pg.44Sekita, Subjective Assessment of Color Naturalness†pg.48Chen, Color Appearance and Spatial Related Color Gamut†pg.52Salesin, The Determination of the Minimum Force†pg.56Ungureanu, Parallel Software Design Enabling High-Speed†pg.60Ju, Black-Box Models for Laser Electrophotographic†pg.66Aqua, Experimental and Analytical Study of Dot Gain†pg.72Pu, A Laser-Imageable Thin Coating Derived†pg.75Shi, The Requirement of Map Digital Printing†pg.78

Digital Fulfillment SessionKuo, Index-based Digital Texture Printing Workflow†pg.81Messier, Automated Surface Texture Classification†pg.85Tence, Xerox's High Temperature, Increased Fluid†pg.92Henry, A New Approach to Colour-Picker Tool Design†pg.98Yin, Solutions of JDF-Workflow Scheduling Problem†pg.102Su, Map Customization Service based on User Interest†pg.107

Functional Materials Interactive PreviewHeinzer, Innovative Multi-Function Printable Film†pg.111

Fusing, Curing, and Drying SessionEichhorn, Determination of Dryness of Water-based†pg.113Hasebe, Estimation of the Fusing Quality based†pg.116Baek, Surface Heating Fuser System for Laser Beam†pg.120

Thermal Printing SessionFukue, Investigation of Transient Temperature Response†pg.124Taniguchi, New Development of Multi-Purpose Heating†pg.130Shi, Effect of Nicotinic Acid as a Toner†pg.135

Security Printing SessionVans, Progressive Barcode Applications†pg.138Ulichney, Circular Coding for Data Embedding†pg.142Hodgson, Challenges in Security Printing†pg.148Collins, Intelligent Material Solutions, Covert Tagging†pg.153

Ink Jet Processes SessionYoshimura, Development of Inkjet Printhead Equipped†pg.158Geile, Bubble Entrapment and Stability in Complex†pg.163Faisal, Novel Reactive Dyes and Their Application†pg.168Wang, Study of Effectors on the Tinting Strength†pg.171Sun, Study on the Effect of Pigment Dispersion†pg.174Zhang, Study on Abrasion Resistance of UV Curing System†pg.178Yang, Influence of Nozzle Control Parameters†pg.182Yamashita, Development of Printing Method†pg.186Kawata, Robot Arm Printer of Electrostatic Inkjet†pg.190Wollman, Spontaneous Capillarity-Driven Droplet†pg.194Lee, Development of 16 Nozzle Electrohydrodynamic†pg.198Eggenhuisen, Large Area Inkjet Printing†pg.203Panchawagh, Imaging Models for Robust Single-Pass†pg.206Tian, The Study of the Affect Factors on the Color†pg.211Huang, Study on Curing Speed of UV-LED Inkjet Ink†pg.215Zhang, Research on the Adherence of the Water-based Ink†pg.219Ellinger, Captive Continuous Inkjet†pg.286Numata, Drying Technology Using Laser Exposure†pg.292Matsumoto, Experimental and Numerical Study†pg.298Hsiao, Evidence of Print Gap Airflow Affecting Web†pg.303Talbot, Internal Flows and Particle Transport†pg.307Kwon, A Vision Measurement Technique for Evaluation†pg.313Yi, Effect of Monomer on Printing Quality of UV-LED†pg.316Zhang, Research on the Relationship between Properties†pg.320Yang, The Research on Fluorescence Intensity†pg.324

Digital Biology SessionBorchers, Bioink Development for Additive Manufacturing†pg.223Beckert, Inkjet Printed Structures for Smart†pg.224Rincon, Macromolecular Imprinting by Sol-Gel Silica†pg.229Rolland, Paper as a Versatile Platform for Low-Cost†pg.234Pirlo, Computer Aided Design and Manufacturing†pg.235Genina, Fabrication of Printed Drug-Delivery Systems†pg.236Herman, Digital Patterning of Glucose Oxidase†pg.239Reyna, Inkjet Bioprinting of Solid Peroxide†pg.240

Hybrid Printing SessionHoskins, Continuous Tone Colour Printing†pg.244Maeda, Study of Sulfide Solutions as Inkjet Inks†pg.249Matsumae, Development of Digital Quasi-Embossing†pg.253Yukawa, Novel Paper Sheets Containing Kapok Fibers†pg.257Elworthy, LumeJet - A New Photonic 'Inkless' Printing†pg.261

Mathematical Modeling SessionKemp, Modeling the Electrostatic Component of Toner†pg.266Morrison, Drop-on-Demand Printing of Complex Liquids†pg.271Harlen, Asymmetric Detachment from Angled Nozzles†pg.277Chen, Laser Scanner Jitter Characterization†pg.281

Toner-Based Processes/Materials SessionMatsumoto, Study of Seed Polymerized Polyester†pg.328Nasu, Paper Modeling in Transfer Process Simulation†pg.332Ahuja, Photoreceptor Defects, Surface Hardness†pg.337Takahashi, Simulation Model to Predict Paper Wrinkle†pg.341Kobaru, A Study of Mottled Images in an Intermediate†pg.345Chen, Effect of Different Rounding Surface Treatment†pg.349Lance, Mechanical Characterization in Printing a†pg.353Forgacs, Theory of Ink Transfer in HP-Indigo Digital†pg.429Tanaka, Electrostatic Adhesion Force Measurement†pg.434Kim, Fusing Quality of Toner with Tunable Thermal†pg.438Tosaki, New Submicron Silica Produced by Hybrid†pg.444Whitney, Charged Particle Adhesion Internal†pg.449Fomitchev, Silica-Polymer Composite Particles†pg.453Li, A Theoretical Study of the Role of Interfacial†pg.458Tyagi, Novel Electrophotographic Toners for Providing†pg.462Lee, Predicting Dynamic Characteristics of the Gear†pg.466Suzuki, Eco-Friendly Aqueous-based Polyester Chemically†pg.519Hoshino, Comparison between Resin Sphere†pg.525Hille, Balanced Aggregation ƒ "Snow Man" Shaped†pg.529

Printed Electronics SessionReinhold, Analysis of Formation of an Individual†pg.354Perelaer, Low Temperature Sintering of Inkjet Printed†pg.359Shin, Rapid Two-Step Metallization for Highly†pg.363Schaefer, High Accuracy Single Layer Touch Sensors Roll†pg.366Hodgson, IEC TC 119 ƒ International Standards†pg.369SanchezRomaguera, UHF Electromagnetic Structures†pg.372Jeschke, Inkjetprinting of Vertically Integrated†pg.377Shou, A Study of Inkjet Printed Line Morphology Using†pg.384Kolbusch, Production Technologies for Large Area†pg.390

Ink Formulation SessionIllsley, Low Migration UV-Curable Inkjet†pg.391Yoshihiro, A New UV Curable Inkjet Ink : Follow-up†pg.395Duana, Effect of Span-80 in n-Hexadecane†pg.398DeMondt, Key Innovations that Allow Low Migration†pg.405

Environmental Sustainability SessionHausmann, Sustainability of Printing Techniques†pg.410Fischer, The New EU Ecolabel for Printed Products†pg.415Schiller, Deinking of Inkjet Prints†pg.418Zhang, Laboratory Scale Two-Loop Deinking Trials†pg.422Tsukada, VOC Elimination in Printers by Means†pg.425

Displays/Solar Cells SessionBuerklin, Industrial Printed Seed-Layer†pg.472Reinhold, Novel Developments in Photonic Sintering†pg.476Stuwe, Etching of PVD Metal Layers for Contact†pg.479Teunissen, Towards High Speed Inkjet Printed Electronic†pg.484Suzuki, High-Resolution Patterning Technologies†pg.489Kang, Photonic Sintering of Inkjet Printed†pg.494

Functional Materials SessionHakola, New Methods for Improving Food Product Safety†pg.498Vilardell, Patterning of Functional Ceramic Oxides†pg.503Boley, The Role of Coalescence in Inkjet Printing†pg.508Boley, Effect of Print Masks on the Functional†pg.514

Systems/Engineering SessionKaneko, New Technology for Improving Image Density†pg.533Snyder, System-Level Inkjet Performance and Reliability†pg.538Aoki, New Effect of AC High Field on Toner Transfer†pg.545

Author Index