HBr,

https://notendur.hi.is/~agust/rannsoknir/Crete/PPT-140707.pptx

Potential curve diagram for HBr and HBr+ (See next slides):

1.4x105

1.3

1.2

1.1

1.0

0.9

0.8

Ene

rgy

/cm

-1

54321

Internuclear Distance / Å

[4P,5s] Rydb.

H + Br**(5s)

H*(n=2)+Br

H+ + Br-

H+Br+ + e

H++Br+e

[B2S+] ..superexcited state

[(3)2P] ..superexcited state

HBr+*(A)

HBr+(X(3/2))

Photoexcitation via V(m+7)

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp

V

F

H

HBr+*(X(1/2))

v+=14v+=12

E

H + Br**

H*+Br

1.4x105

1.2

1.0

0.8

Ene

rgy

/cm

-1

54321

Internuclear Distance / Å

E VB1S

HBr**

HBr+

HBr+*

X2P

A2S

H* +Br

H* +Br*

H+ +Br

H +Br+

H +Br+*

H +Br*

HBr+*

2P

[B2S]Ry

B2S

[2P]Ry

Fig. 5 in manuscript

Gabriel Vazquez; private communication

Gabriel Vazquez; private communication

See next slide

cm-1

30000

40000

60000

50000

H + Br+(3P2)

H + Br+(3P1)

H + Br+(3P0)

3136.4 cm-1NIST

H + Br+(1D2)

H+ + Br (2P3/2)

H+ + Br (2P1/2)3685.24NIST