Summary

Hazardous substances – Pictograms (different types)

NFPA – National Fire Protection Association

– Statements (H- and P- )

– Hazard classes

– Physical, Health, Environment

– Case study (video)

– ….

1

Safety Data Sheets - SDS

Safety data sheets include information about

– properties of the substance (or mixture),

– hazards

– instructions for handling,

– disposal

– transport

– first-aid,

– fire-fighting

– exposure

– control measures.

The requirements for the compilation of the safety

data sheets are specified in Annex II of REACH.

This information can be found in the main body of the safety data sheet

or in the annexed exposure scenarios (where applicable).

Material Safety data sheets

http://www.ilo.org/legacy/english/protection/safework/cis/products/icsc/dtasht/index.htm

BEFORE AND AFTER GHS - CLP

Safety data sheets

BEFORE

AFTER

http://echa.europa.eu/web/guest/information-on-chemicals/cl-inventory-database

A table comparing MSDS/SDS content/format is provided in Appendix A of the guidance document

The major differences between MSDS and SDS is that

SDS (GHS) are globally used in EU

https://www.osha.gov/dsg/hazcom/ghsguideoct05.pdf

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Labels and Safety data sheets

Do hazardous chemicals require a GHS label and Safety Data Sheet, in all cases?

6

Safety data sheets

1. Identification of the substance or mixture and of the supplier

2. Hazards identification 3. Composition / information on ingredients 4. First aid measures 5. Firefighting measures 6. Accidental release measures 7. Handling and storage 8. Exposure controls/personal protection 9. Physical and chemical properties 10. Stability and reactivity 11. Toxicological information 12. Ecological information 13. Disposal considerations

14. Transport information 15. Regulatory information 16. Other information including information on preparation and

revision of the SDS

3. Composition / information on ingredients

• Substance Chemical identity.

• Common name, synonyms, etc.

• CAS number, EC number, etc.

• Impurities and stabilizing additives which are themselves classified and which contribute to the classification of the substance.

• Mixture The chemical identity and concentration or concentration ranges of all ingredients which are hazardous within the meaning of the GHS and are present above their cutoff levels.

5. Firefighting measures

• Suitable (and unsuitable) extinguishing media.

• Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products).

• Special protective equipment and precautions for firefighters.

8. Exposure controls/personal protection

• Control parameters, e.g., occupational exposure limit values or biological limit values.

• Appropriate engineering controls.

• Individual protection measures, such as personal protective equipment.

9. Physical and chemical properties

• Appearance (physical state, color, etc.).

• Odor.

• Odor threshold.

• pH.

• Melting point/freezing point.

• Initial boiling point and boiling range.

• Flash point.

• Evaporation rate.

• Flammability (solid, gas).

• Upper/lower flammability or explosive limits.

• Vapor pressure.

• Vapor density.

• Relative density.

• Solubility(ies).

• Partition coefficient:

n-octanol/water.

• Autoignition temperature.

• Decomposition temperature.

11. Toxicological information

• Concise but complete and comprehensible description of the various

toxicological (health) effects and the available data used to identify those

effects, including: information on the likely routes of exposure (inhalation,

ingestion, skin and eye contact);

• Symptoms related to the physical, chemical and toxicological characteristics;

• Delayed and immediate effects and also chronic effects from short- and long-

term exposure;

• Numerical measures of toxicity (such as acute toxicity estimates).

12. Ecological information

• Ecotoxicity (aquatic and terrestrial, where available).

• Persistence and degradability.

• Bioaccumulative potential.

• Mobility in soil.

• Other adverse effects.

Description of waste residues and information on their safe handling and methods of disposal, including the disposal of any contaminated packing.

13. Disposal considerations

BEFORE

VER INFORMÇÃO IMPORTANTE NO VERSO

ICSC: 0000

Pictogram

Nº CAS ………. Nº RETSQ ………. Nº FISQ ………. Nº ONU ………. Nº das CE ……….

NAME

Molecular Weight

RISKS Hazards/Symptoms PREVENTION First aid / Extinguihers

FIRE

EXPLOSION

EXPOSITION

Breading

Skin

Yies

Oral

Spillage Store Labelling

Other information

ICSC: 0000 AVDERTÊNCIA LEGAL IMPORTANTE NO VERSO

NOTAS

D A D O S I

M P O R T A N T E S

ESTADO FÍSICO PERIGOS QUÍMICOS VALORES LIMITE DE EXPOSIÇÃO OCUPACIONAL

VIAS DE EXPOSIÇÃO: RISCOS POR INALAÇÃO: EFEITOS DA EXPOSIÇÃO DE CURTA DURAÇÃO: EFEITOS DA EXPOSIÇÃO DE LONGA DURAÇÃO OU REPETIDA:

PROPRIEDADES FÍSICAS

DADOS AMBIENTAIS

O consumo de bebidas alcoólicas aumenta os efeitos nocivos.

INFORMAÇÕES ADICIONAIS

Programa Internacional de Segurança Química - Comunidades Europeias, 1992 ICSC: 0000 NOME

ADVERTÊNCIA LEGAL Nem a CEE nem nenhuma pessoa actuando em nome da CEE ou do PISQ são responsáveis pelo uso que possa ser feito desta informação. esta ficha traduz a opinião colectiva da comissão internacional do PISQ e pode nem sempre reflectir os IMPORTANTE requesitos da legislação nacional relativa a esta matéria. O utilizador deve, pois, verificar se as fichas estão conformes com a legislação nacional rspectiva.

BEFORE

Database of Self-classified Substances

17 February 2012 (launched)

European Chemicals Agency (ECHA) launches the 'Classification and Labeling Inventory' of chemicals on the EU market

ACETONE

https://echa.europa.eu/web/guest/information-on-chemicals/cl-inventory-database

Find information on hazardous characteristics of substances

https://www.osha.gov/chemicaldata/

https://echa.europa.eu/information-on-chemicals

The suppliers are obliged to provide a safety data sheet in the case of

substances classified as hazardous according to CLP

From 1 June 2015

Persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB), as defined in REACH (Annex XIII) or included in the candidate list of substances of very high concern.

Mixtures classified as dangerous (according to the Dangerous Preparations Directive)

Hazardous Substances according to CLP

Basic concepts for safe use of chemicals

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Adequate information and understanding about every chemical in the workplace Clearly established policy on the safe use of chemicals in the workplace, providing the framework for both organizational and operational control measures; Management of hazards involving all (it starts before the receipt of the chemical and continues without interruption, ending when the chemical is modified (reacts) and/or excess is re-used, neutralized or destroyed.

Labels are essential for general information on hazards

Be aware of dangerous substances

LABEL

IRRITANT

CORROSIVE

TOXIC

ENVIRONMENT

Overview of main topics, till now

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Labeling and Packing

Transport

Globally Harmonized System of Classification and Labeling of Chemicals

What is

"Purple Book"

• Define health, physical and environmental hazards of

chemicals;

• Create classification processes that use available data on chemicals for comparison with the defined hazard criteria; and

• Communication of hazard information, and protection measures on

LABELS and SAFETY DATA SHEETS (SDS)

The GHS itself is not a regulation or a standard, it is a document that establishes agreed hazard classification and communication provisions with explanatory information on how to apply the system.

LABELS and SAFETY DATA SHEETS (SDS)

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Safety outreach

SUBSTANCE HAZARD EXPOSURE PPE SPILLAGE 1st

AID

RELEVANT INFORMATION

SUBSTANCE

HAZARD EXPOSURE PPE

SPILLAGE

1st

AID

NITRIC ACID

CORROSIVE SKIN, RESPIRATORY SYSTEM

GLOVES WEAR MASK

…… ………

….. …..

Choose a chemical substance

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SUBSTANCE HAZARD EXPOSURE PPE SPILLAGE 1st

AID

https://www.sigmaaldrich.com https://www.carloerbareagents.com/en/safety/data-sheet https://solvchem.com/products/sds-archive/