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TECHNOLOGY IS THE SOLUTION Project a-3-019:Carbonate production by sequestration of industrial CO 2 : revalorization of mine and industrial waste Guy Mercier Professeur INRS-ETE 418 654-2633 [email protected] www.ete.inrs.ca/guy-mercier May 28 2014

Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

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Page 1: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

TECHNOLOGY

IS THE SOLUTION

Project a-3-019:Carbonate production by sequestration of

industrial CO2 : revalorization of mine and industrial waste

Guy Mercier Professeur INRS-ETE

418 654-2633 [email protected] www.ete.inrs.ca/guy-mercier

May 28 2014

Page 2: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

© Cleantech - Tous droits réservés 2

Page 3: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

0 $

10 $

20 $

30 $

40 $

50 $

60 $

2014 2017 2020

17 $ 20 $

40 $

PREDICTED VALUE ON THE CARBON MARKET IN QUEBEC

© Cleantech - Tous droits réservés 3

Page 4: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

!   Profit (Cap & Trade) !   Carbon credit !   Green image

co2 PURIFIED AIR +

PRODUCT OF VALUE

C02 CAPTURE PLANT MINE WASTE, WASTE

CONCRETE MAGNESIUM, CARBONATE

4

Page 5: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

© Cleantech - Tous droits réservés 5

Mineral Carbonation

•  Spontaneous and exothermic

Mg3Si2O5(OH)4 + 3CO2 → 3MgCO3 + 2SiO2 + 2H2O

∆rH298 = -137,9kJ/mol ∆rG298 = -5.78kJ/mol

Transport, grinding, reaction, 2 solid liquid separations and the precipitation of carbonate

Page 6: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

2015-2016 Construction of a prototype (3M$)

Summer 2014 Independant FTO, $, Market

August 2014 Finish the Pilot test in a cement plant

Laboratory

Patent pending

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Page 7: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

© Cleantech - Tous droits réservés 7

 Batch mode: Same results as lab 80-95 % CO2 removal

 Continuous mode on gaz flow: No Change

 Very good quality MgCO3

650°C 30 min)

Page 8: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

© Cleantech - Tous droits réservés 8

Page 9: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

!   Sandra Kentish, University de Melbourne !   Ian Gates, University of Calgary !   Greg Dipple UBC !   Emmanuelle Cecchi, Nassima Kemache, Louis-César

Pasquier !   Students; Sanoop Kumar P. Veetil, Alia Ben

Ghachem, Ikbel Mouedhen, C. Beaulieu, C. Dimet

Industrial partners

!   Sigma Devtech !   Kusto Group !   Holcim Canada !   Cliffs Natural

Resources Inc.

GUY MERCIER

JEAN-FRANÇOIS BLAIS

Scientific team

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Page 10: Guy Mercier TECHNOLOGY Professeur INRS-ETE IS THE SOLUTION · Sandra Kentish, University de Melbourne ! Ian Gates, University of Calgary Greg Dipple UBC Emmanuelle Cecchi, Nassima

Magnesium process; profitable, market 20 Mt Waste concrete, slag; 20-40 $/t, market few billions t per year Prototype and Develop the calcium base process Apply in the Oil & Gas industry (Partneship with the industry) Posters 29-30-31-32

This technology avoid the cost of CO2 purification, rendering it profitable.

© Cleantech - Tous droits réservés 10