Gregory J. Grant · Biographical Sketch, 1/29/13 Page 1 Gregory J. Grant Department of Chemistry The University of Tennessee at Chattanooga Chattanooga, TN 37403 423-425-4143 Awards

Biographical Sketch, 1/29/13 Page 1

Gregory J. Grant

Department of Chemistry

The University of Tennessee at Chattanooga

Chattanooga, TN 37403

423-425-4143

Awards and Offices Held: ACS National Award for Research at an Undergraduate Institution, 2011. UTC Outstanding Research Award, 2011. Outstanding Research Award; College of Arts and Sciences, UTC, 2009. Guest Co-Editor, Special Issue of Main Group Chemistry, 2008. Chair, SERMACS Regional Board, 2007. Guest Editor, Special Issue of Journal of Chemical Crystallography on Crystallography at PUIs, 2003. DAAD (Deutscher Akademischer Austausch Dienst) Fellowship, 2001. Camille and Henry Dreyfus Foundation Scholar Award (Second Award), 1999. University of Tennessee National Alumni Award Teaching Award, 1999. Alpha Scholastic Honorary Society, UTC, 1999. Outstanding Research Award; College of Arts and Sciences, UTC, 1996. Camille and Henry Dreyfus Foundation Scholar Award; 1992. UTC Council of Scholars; 1992. Outstanding Scholarship Award; College of Arts and Sciences, UTC, 1990. Outstanding Professor Award; presented by Student Government Association, UTC, 1987. Distinguished Service Award; presented by Chattanooga Section, American Chemical Society, 1986. Outstanding Teacher Award; College of Arts and Sciences; UTC, 1986. Secretary-Treasurer; Chattanooga Section, American Chemical Society, 1984-1985.

Publications (undergraduate co-authors indicated with asterisk):

62. “The crystal structure of {[Pt(9S3)Cl2]2[Pt(9S3)2]}Cl2 • 4 H2O: An improved synthesis of [Pt(9S3)Cl2]”;

Grant, G.J.; Biggers, D.E.; Naik, R.D.; Noll, Bruce C.; J. of Chem. Crystallography, 2011 (in press). 61. “Ruthenium(II) Thiacrown Complexes: Synthesis, Electrochemistry, DFT, and X-ray Diffraction Studies of

[Ru(15S5)Cl](PF6)”; Janzen, D.E.; VanDerveer, D.G.; Mehne, L.F.; Grant, G.J.; Inorganica Chimica Acta,

2010, 364, 55-60. Solicited for Special Issue for Professor Arnold L. Rheingold. 60. “Platinum group metal thiacrown complexes as precursors for self-assembly reactions”; Grant, G.J.; Naik,

R.D.*; Benefield, D.E.*; Janzen, D.E., VanDerveer, D.G.; Supramolecular Chemistry, 2010, 22, 109-121. 59. “Antimony-Carbon Bond Activation in a Pt(II) Complex: The Crystal Structure of

[Pt(9S3)(SbPh3)(Ph)](PF6)”; Grant, G.J.; Benefield, D.E.*; VanDerveer, D.G.; J. of Organometallic Chem.,

2010, 695, 634-636.

58. “Thiacrown Pt(II) Complexes with Group 15 Donor Ligands”; Grant, G.J.; Benefield, D.E.*; VanDerveer,

D.G.; Dalton Trans., 2009, 1872-1882. 57. “Hg(II) and Cd(II) Complexes with Mixed Donor Macrocyclic Thioethers: The Oxophobicity of Mercury(II)”; Grant, G.J.; Botros, M.E.*; Hassler, J.S.* Janzen, D.E.; Grapperhaus, C.A.; O’Toole, Martin G.

VanDerveer, D.G.; Polyhedron, 2008, 27, 3097-3104. 56. “Cyclometallated Pt(II) and Pd(II) Complexes with a Trithiacrown Ligand”; Janzen, D.E.; VanDerveer, D.G.;

Mehne, L.F.; da Dilva Fihlo, A.A.; Bredas, J.-L.; Grant, G.J.; Dalton Trans., 2008, 1872-1882. 55. “Contrasting Arsine and Phosphine Coordination Behavior: Heteroleptic Palladium(II) Complexes with Triphenylarsine and a Crown Thioether”; Grant, G.J.; Biggers, D.E.*; VanDerveer, D.G.; Main Group


Chemistry, 2007, 6, 249-261. 54. “Fixation of Atmospheric Carbon Dioxide by a Cadmium(II) Macrocyclic Complex”; Janzen, D.E.; Botros,

M.E.*; VanDerveer, D.G.; Grant, G.J.; Dalton Trans., 2007, 5316-5321. 53. “Synthesis and Structure of a platinum(II) molecular square incorporating four fluxional thiacrown ligands:

The crystal structure of [Pt([9]aneS3)4(4,4’-bipy)4](OTf)8”; Janzen, D.E.; Patel, K.N.*; VanDerveer, D.G.;

Grant, G..J.; Chem. Comm., 2006, 3540-3542. 52. “Synthesis and Structural Studies of Ruthenium(II) 12S4 Complexes with 4,4'-Bipyridine: The Crystal

Structures of [Ru(12S4)(bpy)Cl](Cl).H2O and [{Ru(12S4)Cl}2--(bpy)](PF6)2 . 2 CH3CN”; Janzen, D.E.;

Chen, W.*; Mehne, L.F.; VanDerveer, D.G.; Grant, G.J.; Inorg. Chem. Commun., 2006, 9, 992-995. 51. “1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis(hexafluorophosphate): Hexafluorophosphate acting as a

Pseudohalide”; Janzen, D.E.; Botros, M.E.*; Helton, G.P.*; VanDerveer, D.G.; Grant, G.J.; Acta Cryst. E,

2006, 62 (4), o1550---o1552. 50. “Cadmium-113 NMR Studies on Homoleptic Complexes containing Thioether Ligands"; Helm, M.L. Lee, J.P.

Hill, L.L.; VanDerveer, D.G., Grant, G.J., J. Chem. Soc., Dalton Trans. 2006, 3534-3543.

49. “Mercury(II) Complexes of Thiacrowns and Related Macrocyclic Ligands: Grant, G.J; Invited Chapter for

Structure and Bonding, “Recent Developments in Mercury Science”; D.A. Atwood, Editor, Springer Berlin;

2006; 107-142. 48. “π-π Interactions in Diimine Pt(II) complexes with Thiacrown Ligands: The Crystal Structure of (1,4,7-

trithiacyclononane)(3,4,7,8-tetramethyl-1,10-phenanthroline)platinum(II) Hexafluorophosphate"; Janzen, D.E.;

Patel, K.P.; VanDerveer, D.G.; Grant, G.J Journal of Chemical Crystallography, 2006, 36, 83.

47. “Cationic five-Coordinate Pt(II) Complexes as Donors in the Formation of Pt->Ag Dative Bonds”; Janzen,

D.E.; Mehne, L.F.; VanDerveer, D.G.; Grant, G.J. Inorganic Chemistry, 2005, 44, 8182-8184. 46. “199-Hg NMR Chemical Shifts in Thiacrown and Related Macrocyclic Complexes”; Helm, M.L.;

Helton, G.P; VanDerveer, D.G.; Grant, G.J. Inorganic Chemistry, 2005, 44, 5696-5705. 45. "Synthetic, Electrochemical, and Structural Studies of Mixed Sandwich Rh(III) and Ir(III) Complexes

Involving Cp* and Tridentate Macrocycles"; Grant, G.J.; Lee, J.P.; Helm, M.L.; VanDerveer, D.G.;

Pennington, W.T.; Mehne, L.F; Klinger, D.W. J. of Organometallic Chem., 2005, 690, 629-639. 44. "Anion and Solvent Effects Upon the Structures of Platinum(II) Complexes with Thiacrown Ligands"; Grant,

G.J.; Chen, W.; Goforth, A.M.; Baucom, C.L.; Patel, K.; Repovic, P.; VanDerveer, D.G.; Pennington, W.T.;

European J. of Inorg. Chem. 2005, 479-485. 43. “Heteroleptic Platinum(II) Complexes with Crown Thioethers and Diimine Ligands: The Crystal Structures of

[Pt(9S3)(2,2’-bipy)](PF6)2 and [Pt(9S3)(4,4-dimethyl-2,2’-bipy)](PF6)2•2.5 CH3NO2"; Grant, G.J.., Patel,

K.N., Helm, M.L., Mehne, L.F. Klinger, D.W., VanDerveer, D.G., Polyhedron, 2004, 23, 1361-1369. 42. "Homoleptic Pt(II) and Pd(II) Complexes of 1,5,9-Trithiacyclododecane"; Grant, G.J.; Goforth, A.M.;

VanDerveer, D.G.; Pennington, W.P. Inorg. Chim. Acta, 2004, 357, 2107-2114. 41. “Chiral Effects on a Fluxional Ligand: Chiral Diphosphine Platinum(II) Complexes with Thiacrowns”;

Grant, G.J.; Pool, J.P.; VanDerveer, D.G. J. Chem. Soc., Dalton Trans., 2003, 3981-3984. 40. “Mercury Complexes with Thiacrowns: The Crystal Structure of Bis(1,4,7-

Trithiacyclodecane)mercury(II) hexafluorophosphate”; Helm, M.L.; VanDerveer, D.G.; Grant, G.J.; J.

Chem. Cryst., 2003, 33, 625. Special Issue on Structures of Hg Complexes.


39. "Heavy Metal Complexes of Macrocyclic Trithioethers"; Grant, G.J.; Helm, M.L, Combs, C.M;

Loveday, K.D.; Bentzen, E.L. Rogers, R.D.; VanDerveer, D.G.; J. of Chem. Cryst. 2003, 33, 445. Solicited manuscript for issue: " Crystallographic Research by Faculty at Predominately Undergraduate Institutions: A Selective Survey".

38. "Homoleptic Group 12 Metal Complexes of Macrocyclic Thioethers"; Helm, M.L.; Combs, C.M.;

VanDerveer, D.G.; Grant, G.J. Inorg. Chim. Acta, 2002, 338C, 182. 37. "Synthetic and Structural Studies of Platinum(II) Complexes Containing Macrocyclic Trithioethers and

Achiral Diphosphine Ligands "; Grant, G.J., Galas, D.F., Poullaos, I.M.; Carter, S.M.; VanDerveer,

D.G. J. Chem. Soc., Dalton Trans, 2002, 15, 2973. 36. "Heteroleptic Platinum(II) Complexes with Crown Thioether and Phosphine Ligands: The Crystal

Structures of [Pt(9S3)(PPh3)Cl](PF6)•CH3NO2 and [Pt(10S3)(PPh3)Cl](PF6)"; Grant, G.J., Galas,

D.F., VanDerveer, D.G. Polyhedron, 2002, 21, 879. 35. "Metal Binding Studies with Macrocyclic Hexathiaethers"; Grant, G.J.; Brandow, C.G.; Bruce, C.W.

Bryant, M.A.; Kirk, R.M.; Lee,S.D.; Rickerd, K.R.; Mehne, L.F. Journal of Het. Chem., 2001, 38, 1281. Solicited manuscript for special dedicatory issue to Gerald Bradshaw.

34. "Heteroleptic Platinum(II) Complexes of Macrocyclic Thioethers and Halides"; Grant, G.J.; Brandow,

C.G.; Galas, D.F.; Davis, J.P.; Pennington, W.T.; Zubkowski, J.D.; Valente, E.J. Polyhedron, 2001, 20, 3333.

33. " Synthetic, Electrochemical, and Structural Studies on Heterobimetallic Crown Thioether Complexes

with Group 10 Metals"; G.J. Grant, S.M. Carter, A.L. Russell, I.M. Poullaos, and D.G. VanDerveer J.

Organometal. Chem., 2001, 637-639, 683. Special issue for the 50th anniversary of the discovery of ferrocene.

32. "Research in the Undergraduate Environment-- What Lessons Can Be Learn From Successful

Entrepreneurs?"; Grant, G.J., Haynes, P.J.; Council on Undergraduate Research Quarterly, 2001, June, 180.

31. "Complexation and Conformational Analysis Studies of Eleven-Membered Ring Crown Trithioethers";

Grant, G.J.; Shoup, S.S.; Baucom, C. L.; Setzer, W.N. Inorganica Chimica Acta, 2001, 317, 91. Solicited manuscript for special issue on Macrocyclic Coordination Complexes.

30. "Heteroleptic Platinum(II) Complexes with Crown Thioether and Phosphine Ligands I."; Grant, G.J.;

Poullaos, I.M.; Galas, D.F.; VanDerveer, D.G.; Zubkowski, J.D.; Valente, E.J.; Inorganic Chemistry,

2001, 40, 564.

29. "Transition Metal Complexes with Oxathia Crown Ethers"; Grant, G.J.; Jones, M.W. ; VanDerveer,

D.G..; Pennington, W T..; Mehne, L.F.; Inorganica Chimica Acta, 2000, 300, 250. Solicited manuscript for Special 300th Issue of Inorganica Chimica Acta.

28. "Mixed Sandwich Compounds of Crown Thioether Ligands" Grant, G.J.; Salupo-Bryant, T.; Holt, L.A.;

Morrissey, D. Y.; Gray, M.J.; Zubkowski, J.D.; Valente, E.J.; Mehne, L.F.; J. of Organometallic

Chem., 1999, 587, 207. 27. "The Crystal Structure of the Macrocyclic Hexathioether 1,4,7,11,14,17-Hexathiacycloeicosane:

Implications for Metal Complexation " Setzer, W.N.; Grant, G.J.; Meehan, E.J.; Ahsahr, S.; Forsythe, E.L.; Lee, S.D.; Kirk., R.M.; Tang, Y.; Liou, Show-Yee; Yang, C.R.; Wu, C.K.; J. of Molecular

Recognition and Inclusion Phenomena, 1999, 35, 649-656. 26. "Platinum Group Metal Complexes of Macrocyclic Oxa-thiaethers"; Grant, G.J.; Galas,, D.F.; Jones,


M.W.; Loveday, K.D.; Pennington, W T.; Schimek, G.L.; Eagle, C.T.; VanDerveer, D.G.. Inorganic

Chemistry, 1998, 37, 5299-5305. 25. "Synthesis and Structural Studies of Hydrophilic Mesocyclic Trithioethers" Setzer, W.N.; Liou, S.-Y.; Easterling, G.E.; Simmons, R.C.; Gullion, L.M.; Meehan, E.J.; Grant, G.J.; Gray, G.M. Heteroatom

Chemistry, 1998, 9, 123-128. 24. "Cobalt(III) Complexes of Crown Thioethers: The Crystal Structure of (1,4,7,11,14, 17 Hexathiacycloeicosane)cobalt(III) Tetrafluoroborate Dihydrate" Grant, G.J.; Shoup, S.S.; Hadden,

C.E.; VanDerveer, D.G.; Inorganica Chimica Acta, 1998, 274, 192-200.

23. "Crown Thioether Complexes of Palladium(II) and Platinum(II)" Grant, G.J., Spangler, N.J., Setzer, W.N., VanDerveer, D.G., Mehne, L.F. solicited manuscript for special issue on Macrocyclic

Coordination Complexes, Inorganica Chimica Acta., 1996, 246, 31-40. 22. "The Synthesis and Structure of Bis(1,4,7- trithiacyclodecane)ruthenium(II) Perchlorate: The Meso Diastereoisomer"; Grant, G. J.; McCosar, B.M.; Setzer, W.N.; Zubkowski, J.D.; Valente, E.J ;

Inorg. Chim. Acta, 1996, 244, 73-77.

21. "Crown Thioether Complexes of Chromium(III), Vanadium(III), and Rhenium(III)" Grant, G.J., Rogers, K.E.;

Setzer, W.N.; VanDerveer, D.G. Inorg. Chim. Acta, 1995, 234, 35-45. 20. "Mercury: Inorganic and Coordination Chemistry" in the Encyclopedia of Inorganic Chemistry; Grant, G.J.,

1994. John Wiley and Sons, Inc. 19. "Crown Thioether Complexes of Iron(II)"; Grant, G.J.; Isaac, S.M.; Setzer, W.N.; VanDerveer, D.G.

Inorganic Chemistry. 1993, 32, 4294-4296. 18. "The Crystal and Molecular Structure of (1,4,7,10,13- Pentathiacyclopentadecane)Cadmium(II) Perchlorate Hydrate; A Seven-Coordinate Cadmium" Setzer, W.N.; Tang, Y.; Grant, G.J.; VanDerveer, D.G. Inorganic

Chemistry, 1992, 31, 1116. 17. "Synthesis and Studies of Mesocyclic and Macrocyclic Polythioether Ligands" Setzer, W.N.; Grant, G.J. Trends

in Organic Chemistry, 1991, 2, 199-213. 16. "General Chemistry Laboratory Manual", 4th Ed.; Grant, G.J.; Meyer, G.M.; Sheffield Publishing Company:

Salem, Wisconsin; 1991. 15. "The Synthesis and Crystal Structure of bis(1,4,7-Trithiacyclodecane)palladium(II) Hexafluorophosphate"

Grant, G.J., Sanders, K.A.; Setzer, W.N.; VanDerveer, D.G. Inorg. Chem., 1991, 30, 4053. 14. "Synthesis and X-ray Crystal Structures of Heavy-Metal Complexes of 1,5,9,13- Tetrathiacyclohexadecane"

Setzer, W.N.; Tang, Y.; Grant, G.J.; VanDerveer, D.G. Inorg. Chem., 1991, 30, 3652. 13. "Transition Metal Complexes of 1,4,7-Trithiacyclononane; An Experiment for Advanced Inorganic

Laboratory" Grant, G.J.; Mauldin, P.M.; Setzer, W.N. J. Chem. Educ.; 1991, 68, 605-607. 12. "Benzene Trisulfide, The Largest Field Strength Thioether: Its Nickel(II) Complex" Grant, G.J.;

Grant, C.D.; Setzer, W.N. Inorganic Chemistry, 1991, 30, 252. 11. "Conformational Analysis of 1,4,7-Trithiacyclodecane and Related Compounds" Setzer, W.N.; Guo, Q.;

Meehan, E.J., Jr.; Grant, G.J. Heteroatom Chemistry, 1990; 1, 425 - 431. 10. "Synthesis of Mesocyclic and Macrocyclic Polythioethers Using the Cesium Dithiolate Technique" Setzer, W.N.; Afshar, S.; Burns, N.L.; Ferrante, L.A.; Hester, A.M.; Meehan, E.J.; Grant, G.J.; Isaac, S.M.;

Laudeman, C.P.; Lewis, C.M.; VanDerveer, D.G. Heteroatom Chemistry, 1990; 1, 375 -387.


9. "1,4,7-Trithiacyclononane as a Tridentate Ligand for Complexation of Heavy-Metal Ions" Setzer, W.N.; Guo, Q.; Grant, G.J.; Hubbard, J.; Glass, R.S.; VanDerveer, D.G. Heteroatom

Chemistry, 1990; 1, 317- 325. 8. "Synthesis and Complexation Studies of Ten-Membered Ring Trithioethers" Setzer, W.N.; Cacioppo, E.L.; Guo, Q.; Grant, G.J.; Kim. D.D.; Hubbard, J.L.; VanDerveer, D.G.; Inorganic

Chemistry 1990, 29, 2672 - 2681. 7. "Zerovalent Molybdenum(0) Complexes of Mesocyclic and Macrocyclic Crown Thioethers"

Grant, G.J.; Carpenter, J.P.; Setzer, W.N.; VanDerveer, D.V Inorganic Chemistry, 1989, 28 , 4128-4132.

6. "The Crystal and Molecular Structure of 1,4,7,11,14,17-Hexathiacycloeicosan-9,19-dione--A Macrocyclic Diketothioether" Setzer, W.N.; Cacioppo, E.L.; Grant, G.J.; Glass, R.S.

Phosphorus, Sulfur, and Silicon, 1989, 45, 223-229. 5. "General Chemistry Laboratory Manual", 3rd Ed.; Grant, G.J.; Meyer, G.M.; Sheffield

Publishing Company: Salem, Wisconsin; 1988. 4. "General Chemistry Laboratory Manual", 2nd Ed.; Grant, G.J.; Meyer, G.M.; Ginn Publishing

Company: Springfield, Massachusetts; 1986. 3. "General Chemistry Laboratory Manual", 1st Ed.; Grant, G.J.; Meyer, G.M.; Ginn Publishing

Company: Springfield, Massachusetts; 1985. 2. "Chiral Cobalt(III) Complexes of Symmetrical Hexaazamacrocycles", Royer, D.J. ; Grant, G.J.;

VanDerveer, D.G.; and Castillo, M.J Inorganic Chemistry, 1982, 21, 1902. 1. "Preparation of Tribenzo[21]aneN6: A Metal Template Synthesis", Grant, G.J.; Royer, D.J.

The Journal of the American Chemical Society, 1981, 103, 867.

Presented Papers (Author is Underlined): 251. Gregory J. Grant, “Thirty Years of Thiacrowns”, Award Address to the Division of Inorganic Chemistry,

presented at the 241st National Meeting of the American Chemical Society, Anaheim, CA. March 27 – 31, 2011. Paper 390.

250. Zachary T. Perry, Gregory J. Grant, “Square/triangle equilibria in Pt(II) and Pd(II) thiacrown

supramolecular complexes” ; Symposium poster session for Division of Inorganic Chemistry, presented at the 241st National Meeting of the American Chemical Society, Anaheim, CA. March 27 – 31, 2011. Paper 382.

249. Hitesh V. Vashi, Gregory J. Grant; “Advancements in the Self-Assembly of Molecular Rhodium(III)

Thioether Complexes as Vertices”; Symposium poster session for Division of Inorganic Chemistry, presented at the 241st National Meeting of the American Chemical Society, Anaheim, CA. March 27 – 31, 2011. Paper 379.

248. Natalie N. Talbott, Gregory J. Grant, “Synthesis and characterization of elongated square pyramidal

complexes of platinum(II) involving thioethers and diimines”; Symposium poster session for Division of Inorganic Chemistry, presented at the 241st National Meeting of the American Chemical Society, Anaheim, CA. March 27 – 31, 2011. Paper 381.

247. John P. Lee, Gregory J. Grant, Daron E. Janzen, Donald G. VanDerveer, “Carbon and oxygen linkage

isomers of acetate in Pd(II) thiacrown complexes”; Symposium poster session for Division of Inorganic


Chemistry, presented at the 241st National Meeting of the American Chemical Society, Anaheim, CA. March 27 – 31, 2011. Paper 380.

246. Gregory J. Grant, “Lords of the Thioether Rings”, Symposium talk, presented at the 241st National

Meeting of the American Chemical Society, Anaheim, CA. March 27 – 31, 2011. Paper 605. 245. Gregory J. Grant, “Lords of the Thioether Rings”, invited seminar; presented to the Chattanooga Section

of the American Chemical Society, Chattanooga, TN, January 19, 2011. 244. Zachary T. Perry, Gregory J. Grant, Rishi D. Naik, Markus Germann, Thomas Blake, “Square/triangle equilibria in platinum(II) thiacrown supramolecular complexes” presented at the 2010 International Chemical Conference of Pacific Basin Societies; Honolulu, HI, December 15-20, 2010. Division of Inorganic Chemistry, Paper Number 986. 243. Hitesh V. Vashi, Gregory J. Grant; “Advancements in Self-Assembly of Molecular Rhodium(III) Cubes and Squares” presented at the 2010 International Chemical Conference of Pacific Basin Societies; Honolulu, HI, December 15-20, 2010. Division of Inorganic Chemistry, Paper Number 1010. 242. Natalie N. Talbott, Gregory J. Grant, , “Ligand donor/acceptor effects for platinum(II) and palladium(II) thiacrown complexes” presented at the 2010 International Chemical Conference of Pacific Basin Societies; Honolulu, HI, December 15-20, 2010. Division of Inorganic Chemistry, Paper Number 999. 241. Gregory J. Grant, Daron E. Janzen; “Ruthenium(II) thiacrown complexes” presented at the 2010 International Chemical Conference of Pacific Basin Societies; Honolulu, HI, December 15-20, 2010. Division of Inorganic Chemistry, Paper Number 1053. 240. Gregory J. Grant, Desiree A. Benefield, “Square pyramid or trigonal bipyramid? Pentacoordination in heteroleptic thiacrown complexes of platinum(II); presented at the 239th National Meeting of the American Chemical Society, San Francisco, Ca. March 21-25, 2010; Division of Inorganic Chemistry, Coordination Chemistry: Characterization and Applications, Paper 416. Selected for Sci-Mix. 239. Marko Bajic, Gregory J. Grant, “Ru(II) Thioether Complexes in Self-Assembled Molecular Structures”,

presented at the 239th National Meeting of the American Chemical Society, San Francisco, Ca. March 21-25, 2010; Undergraduate Research Poster Session, Inorganic Chemistry, Paper 754.

238. Hitesh V. Vashi, Gregory J. Grant; “Advancements in Self-Assembly of Molecular Rhodium(III) Cubes

and Squares” presented at the 239th National Meeting of the American Chemical Society, San Francisco, Ca. March 21-25, 2010; Undergraduate Research Poster Session, Inorganic Chemistry, Paper 755.

237. Natalie N. Talbott, Gregory J. Grant, “Advancements in Platinum and Palladium 1,4,7-

Trithiacyclononane Chemistry”; presented at the 239th National Meeting of the American Chemical Society, San Francisco, Ca. March 21-25, 2010; Undergraduate Research Poster Session, Inorganic Chemistry, Paper 756.

236. Gregory J. Grant, “Lords of the Thioether Rings: Squares, Triangle, Square Pyramids, and Triangular Bipyramids in Pt(II) Thiacrown Chemistry,” invited departmental seminar; presented to the Department of Chemistry and Biochemistry, Auburn University, Auburn, AL, November 12, 2009. 235. Marko Bajic Gregory J. Grant; “Ru(II) Thioether Complexes in Self-Assembled Molecular Structures”,

presented at the 61st Southeastern Regional Meeting of the American Chemical Society, San Juan, Puerto Rico, Oct. 21 -25 2009; Undergraduate Research Oral Presentations III, Paper 347.

234. Hitesh V. Vashi, Gregory J. Grant; “Advancements in Self-Assembly of Molecular Rhodium(III)

Cubes and Squares” at the 61st Southeastern Regional Meeting of the American Chemical Society, San Juan, Puerto Rico, Oct. 21 -25 2009; Undergraduate Research Oral Presentations III, Paper 346.


233. Natalie N. Talbott, Gregory J. Grant, ““Advancements in Platinum and Palladium 1,4,7-Trithiacyclononane Chemistry”; presented at the 61st Southeastern Regional Meeting of the American Chemical Society, San Juan, Puerto Rico, Oct. 21 -25 2009; Undergraduate Research Poster Session I, Paper 282.

232. Gregory J. Grant, Rishi D. Naik, Desiree A. Benefield, “Squares, Triangles, Square Pyramids, and

Trigonal Bipyramids: Heteroleptic Thiacrown Complexes with Platinum(II)”; presented at the 61st Southeastern Regional Meeting of the American Chemical Society, San Juan, Puerto Rico, Oct. 21 -25 2009; Division of Inorganic Chemistry, Symposium “Current Trends in Inorganic Chemistry”, Paper 165.

231. Gregory J. Grant, “Lords of the Thioether Rings: Squares, Triangle, Square Pyramids, and Triangular Bipyramids in Pt(II) Thiacrown Chemistry,” invited departmental seminar; presented to the Department of Chemistry, Eastern Illinois University, Charleston, IL, Sept. 14, 2009. 230. Rishi D. Naik, Gregory J. Grant; “Progress towards self-assembled platinum(II) molecular squares”, presented at the 237

th National Meeting of the American Chemical Society, Salt Lake City, UT; March

22 -26, 2009. Division of Inorganic Chemistry, Paper #175. Selected for SciMix 229. Desiree A. Biggers, Gregory J. Grant; “Effects of Group 15 Donor Ligands in Platinum Thiacrown Complexes”, presented at the 237

th National Meeting of the American Chemical Society, Salt Lake City,

UT; March 22 -26, 2009. Division of Inorganic Chemistry, Paper #174. 228. Marko Bajic Gregory J. Grant; “Ru(II) Thioether Complexes in Self-Assembled Molecular Squares”, presented at the 237

th National Meeting of the American Chemical Society, Salt Lake City,

UT; March 22 -26, 2009. Division of Chemical Education, Undergraduate Poster Session, Paper #606. 227. Hitesh V. Vashi, Gregory J. Grant; “Self-Assembled Molecular Squares and Cubes Using Group 9 Metal Ions”, presented at the 237

th National Meeting of the American Chemical Society, Salt Lake

City, UT; March 22 -26, 2009. Division of Chemical Education, Undergraduate Poster Session, Paper #607. 226. Gregory J. Grant, Maikel E. Botros, Jared S. Hassler; " Heavy Metal Complexes with Mixed Donor Macrocyclic Ligands” presented at the 60

h Southeastern Regional Meeting of the American Chemical

Society, Nashville, TN.; Nov. 12-15, 2008; Division of Inorganic Chemistry, Paper #47. 225. Rishi D. Naik, Gregory J. Grant; “Progress towards self-assembled platinum(II) molecular squares”, presented at the 60

h Southeastern Regional Meeting of the American Chemical Society,

Nashville, TN.; Nov. 12-15, 2008; Division of Inorganic Chemistry, Paper #53. 224. Desiree A. Biggers, Gregory J. Grant; “Effects of Group 15 Donor Ligands in Platinum Thiacrown Complexes”, presented at the 60


Nashville, TN.; Nov. 12-15, 2008; Division of Inorganic Chemistry, Paper #52. 223. Marko Bajic Gregory J. Grant; “Ru(II) Thioether Complexes in Self-Assembled Molecular Squares and Cubes”, presented at the 60


Nashville, TN.; Nov. 12-15, 2008; Undergraduate Oral Presentations II, Paper #824. This talk won a prize for the top oral presentation by an undergraduate student at the SERMACS Meeting. 222. Hitesh V. Vashi, Gregory J. Grant; “Self-Assembled Molecular Squares and Cubes Using Group 9 Metal Ions”, presented at the 60

h Southeastern Regional Meeting of the American Chemical

Society, Nashville, TN.; Nov. 12-15, 2008; Undergraduate Posters II, Paper #796. 221. Gregory J. Grant, Maikel E. Botros, Jared S. Hassler; " Homoleptic Hg(II) and Cd(II) complexes with mixed donor macrocyclic ligands: The oxophobicity of mercury(II)” presented at the 235

th National

Meeting of the American Chemical Society, New Orleans, LA; April 6- 10, 2008. Division of Inorganic Chemistry, Paper #174. Selected for SciMix.


220. Rishi D. Naik, Gregory J. Grant; “Progress towards self-assembled platinum(II) molecular squares”, presented at the 235

th National Meeting of the American Chemical Society, New Orleans, LA; April 6-

10, 2008. Division of Chemical Education, Undergraduate Poster Session, Paper #1212. 219. Marko Bajic Gregory J. Grant; “Platinum Thiacrown Complexes with Substituted Diimine Ligands”, presented at the 235

th National Meeting of the American Chemical Society, New Orleans, LA; April 6-

10, 2008. Division of Chemical Education, Undergraduate Poster Session, Paper #1210. 218. Desiree A. Biggers, Gregory J. Grant; “Comparison of Platinum and Palladium Heteroleptic Complexes with 1,4,7-Trithiacyclononane and Group 15 Donor Ligands”, presented at the 235

th National Meeting of

the American Chemical Society, New Orleans, LA; April 6- 10, 2008. Division of Chemical Education, Undergraduate Poster Session, Paper #1112. 217. Rishi D. Naik, Gregory J. Grant; “Progress towards self-assembled platinum(II) molecular squares”, presented at the 59

th Southeastern Regional Meeting of the American

Chemical Society, Greenville, SC.; October 24-26, 2007, Undergraduate Program, Oral Presentations, Paper #718. Selected for prize as top undergraduate presentations. 216. Marko Bajic Gregory J. Grant; “Platinum Thiacrown Complexes with Substituted Diimine Ligands”, presented at the 59


Chemical Society, Greenville, SC.; October 24-26, 2007, Undergraduate Program, Posters I, Paper #662. 215. Desiree A. Biggers, Gregory J. Grant; “Comparison of Platinum and Palladium Heteroleptic Complexes with 1,4,7-Trithiacyclononane and Group 15 Donor Ligands”, presented at the 59

th Southeastern

Regional Meeting of the American Chemical Society, Greenville, SC.; October 24-26, 2007, Undergraduate Program, Posters I, Paper # 667. 214. Gregory J. Grant, Daron E. Janzen; "From Marocycles to Nanowagons: Heteroleptic Platinum Thiacrown Complexes” presented at the 59


Chemical Society, Greenville, SC, October 24-26, 2007, Symposium “S and Se in the SE””; Paper #90. 213. Maikel E. Botros, Daron E. Janzen, Gregory J. Grant, “Carbon dioxide fixation by a cadmium(II) macrocyclic complex” presented at the 233

rd National Meeting of the American Chemical Society,

Chicago, IL, March 25-29, 2007. Division of Inorganic Chemistry,. Division of Inorganic Chemistry, Paper Number 864. Selected for SciMix. 212. Rishi D. Naik, Gregory J. Grant, Daron E. Janzen; “Progress towards self-assembled platinum(II) and rhodium(III) molecular squares”, presented at the 233

rd National Meeting of the American

Chemical Society, Chicago, IL, March 25-29, 2007. Division of Chemical Education, Undergraduate Poster Session, Paper #1233.

211. Emily R. Hassler, Gregory J. Grant, Daron E. Janzen; “Platinum(II) Complexes of Crown Thioethers with Chiral and Achiral Diamine Ligands”, presented at the 233

rd National Meeting of the American

Chemical Society, Chicago, IL, March 25-29, 2007. Division of Chemical Education, Undergraduate Poster Session, Paper #1229. 210. Jared R. Hassler, Gregory J. Grant, Daron E. Janzen; “Cadmium(II) and Mercury(II) Complexes with Mixed Oxathiacrown Ligands” presented at the 233

rd National Meeting of the American Chemical

Society, Chicago, IL, March 25-29, 2007. Division of Chemical Education, Undergraduate Poster Session, Paper #1183. 209. Daron E. Janzen, Gregory J. Grant, D.A. da Silva Filno, Larry F. Mehne, Donald G. VanDerveer:

“Orthometallated Thiacrown Complexes of Pt(II) and Pd(II)” presented at the 233rd

National Meeting of the American Chemical Society, Chicago, IL, March 25-29, 2007. Division of Inorganic Chemistry,. Division of Inorganic Chemistry, Paper Number 246.


208 Gregory J. Grant, Daron E. Janzen, Ketankumar N. Patel; "The Synthesis and Structure of a Self-Assembled Pt(II) Molecular Square Incorporating Four Fluxional Thiacrown Ligands” presented at the 233

rd National

Meeting of the American Chemical Society, Chicago, IL, March 25-29, 2007. Division of Inorganic Chemistry, Paper #235. Selected for SciMix.

207. Gregory J. Grant; “Lords of the Thioether Rings: Heavy Metals Complexes of Thiacrown Ligands"; invited departmental seminar; presented to the Department of Chemistry, The University of Memphis, Memphis, TN. March 16, 2007. 206. Maikel E. Botros, Gregory J. Grant, Daron E. Janzen; “Complexation Studies of Heavy Metals with

Mixed Donor Macrocyclic Ligands: Carbon Dioxide Fixation in a Cd(II) Complex” presented at the 58th

Southeastern Regional Meeting of the American Chemical Society, Augusta, GA, November 1-4, 2006,

Undergraduate Research Talks, Paper #513. 205. Emily R. Hassler, Gregory J. Grant, Daron E. Janzen; “Platinum(II) Complexes of Crown Thioethers with

Chiral and Achiral Diamine Ligands”, presented at the 58th

Southeastern Regional Meeting of the American Chemical Society, Augusta, GA, November 1-4, 2006, Undergraduate Posters III, Paper #729.

204. Jared R. Hassler, Gregory J. Grant, Daron E. Janzen; “Cadmium(II) and Mercury(II) Complexes with

Mixed Oxathiacrown Ligands” presented at the 58th

Southeastern Regional Meeting of the American Chemical Society, Augusta, GA, November 1-4, 2006, Undergraduate Posters III, Paper #730.

203. Rishi D. Naik, Gregory J. Grant, Daron E. Janzen; “Progress towards self-assembled platinum(II) and

rhodium(III) molecular squares”, presented at the 58th

Southeastern Regional Meeting of the American Chemical Society, Augusta, GA, November 1-4, 2006, Undergraduate Posters III, Paper #727. Selected for prize (top ten posters).

202. Gregory J. Grant, Monte L. Helm, Lensey L. Hill, John P. Lee; "113Cd NMR Analysis of Thiacrown Complexes"; presented at the 232nd National Meeting of the American Chemical Society, San Francisco, CA, Sept.. 10-14, 2006, Division of Inorganic Chemistry, Paper Number 333. 201. Gregory J. Grant, Daron E. Janzen, Ketankumar N. Patel; "The Synthesis, Characterization, and Structure of a

Self-Assembled Pt(II) Molecular Square Incorporating a Thiacrown Ligand. A Molecular "Nanowagon"; presented at the First Joint International Symposium on Macrocyclic and Supramolecular Chemistry;

Victoria, British Columbia; June 25-30, 2006; Paper Number 79. 200. Weinan Chen, Gregory J. Grant, Daron E. Janzen; “Towards the Preparation of a Ruthenium Square: The Synthesis and Characterization of Ru(II) tetrathiacrown complexes with 4,4'-bipyridine"; presented at the 231st National Meeting of the American Chemical Society, Atlanta, GA, March 26-30, 2006. Division of Inorganic Chemistry, Paper Number 600. Selected for SciMix. 199. Maikel E. Botros, Gregory J. Grant, Daron E. Janzen; “Complexation Studies of Mercury(II) and Cadmium(II) with Hexadentate Thiacrown and Azacrown Ligands”; presented at the 231st National Meeting of the American Chemical Society, Atlanta, GA, March 26-30, 2006. Division of Chemical Education, Undergraduate Research Poster Session, Paper Number 888. 198. Emily R. Hinson, Gregory J. Grant, Daron E. Janzen; “Platinum(II) Complexes of Crown Thioethers with Chiral and Achiral Diphosphine Ligands”; presented at the 231st National Meeting of the American Chemical Society, Atlanta, GA, March 26-30, 2006. Division of Chemical Education, Undergraduate Research Poster Session, Paper Number 929. 197. Daron E. Janzen, Gregory J. Grant: “Orthometallated Pt(II) Thiacrown Complexes and metal-metal d8-

d10 Dative Bonds”; presented at the 231st National Meeting of the American Chemical Society, Atlanta, GA, March 26-30, 2006. Division of Inorganic Chemistry, Paper Number 192. Selected for SciMix.

196. Gregory J. Grant, Daron E. Janzen, Ketankumar Patel: “Platinum(II) Thiacrown Complexes with Diimine Ligands” presented at the 231st National Meeting of the American Chemical


Society, Atlanta, GA, March 26-30, 2006. Division of Inorganic Chemistry, Paper Number 99. 195. Gregory J. Grant; “Lords of the Thioether Rings: Mercury(II) and Platinum(II) Complexes of Thiacrown Ligands"; invited departmental seminar; presented to the Department of Chemistry, The University of Kentucky, Lexington, KY, Feb. 24, 2006. 194. Maikel E. Botros, Gregory J. Grant, Daron E. Janzen; “Complexation Studies of Mercury(II) and Cadmium(II) with Mixed Donor Macrocyclic Ligands” presented at the 2005 International Chemical Conference of Pacific Basin Societies; Honolulu, HI, December 15-20, 2005. Division of Inorganic Chemistry, Paper Number 210. 193. Emily R. Hinson, Gregory J. Grant, Daron E. Janzen; “Platinum(II) Complexes of Crown Thioethers with Chiral and Achiral Diamine Ligands”, presented at the 2005 International Chemical Conference of Pacific Basin Societies; Honolulu, HI, December 15-20, 2005. Division of Inorganic Chemistry, Paper Number 208. 192. Weinan Chen, Gregory J. Grant, Daron E. Janzen; “Preparation of the Corners of a Self-Assembled Molecular Cube with Group 9 Metal Thiacrown Complexes” presented at the 2005 International Chemical Conference of Pacific Basin Societies; Honolulu, HI, December 15-20, 2005. Division of Inorganic Chemistry, Paper Number 207. 191. Daron E. Janzen, Gregory J. Grant; “Octahedral Pt(II) Complexes: Orthometallated Pt(II) Thiacrown Complexes and Pt-Ag Dative Bonds” presented at the 2005 International Chemical Conference of Pacific Basin Societies; Honolulu, HI, December 15-20, 2005. Division of Inorganic Chemistry, Paper Number 234. 190. Gregory J. Grant, Daron E. Janzen, Ketankumar Patel; “A Molecular Nanowagon: The Synthesis and

Characterization of a Self-Assembled Platinum(II) Molecular Square Containing a Thiacrown Ligand” presented at the 2005 International Chemical Conference of Pacific Basin Societies; Honolulu, HI, December 15-20, 2005. Division of Inorganic Chemistry, Paper Number 276.

189. Maikel E. Botros, Gregory J. Grant, Daron E. Janzen; “Complexation Studies of Mercury(II) and Cadmium(II) with Hexadentate Thiacrown and Azacrown Ligands” presented at the 57

th Southeastern

Regional Meeting of the American Chemical Society, Memphis, TN, November 1-4, 2005.. Undergraduate Research Posters, Paper Number 560. 188. Emily R. Hinson, Gregory J. Grant, Daron E. Janzen; “Platinum(II) Complexes of Crown Thioethers with Chiral and Achiral Diamine Ligands” , presented at the 57

th Southeastern Regional Meeting of the

American Chemical Society, Memphis, TN, November 1-4, 2005.. Undergraduate Research Posters, Paper Number 562. 187. Weinan Chen, Gregory J. Grant, Daron E. Janzen; “Preparation of a Ruthenium Square: The Synthesis and Characterization of [Ru(12S4)Cl(bipy)](PF6) & [{Ru(12S4)Cl}2(bipy)](PF6)”, presented at the 57th Southeastern Regional Meeting of the American Chemical Society, Memphis, TN, November 1-4, 2005. Undergraduate Research Talks, Paper Number 534. 186. Daron E. Janzen, Gregory J. Grant; “Integration of X-ray Crystallography into the Undergraduate Curriculum Using Mercury Software” presented at the 57th Southeastern Regional Meeting of the American Chemical Society, Memphis, TN, November 1-4, 2005. Division of Chemical Education, Paper Number 327. 185. Gregory J. Grant, Daron E. Janzen, Ketankumar Patel; “Platinum(II) Thiacrown Complexes with Diimine Ligands” presented at the 57th Southeastern Regional Meeting of the American Chemical Society, Memphis, TN, November 1-4, 2005. Division of Inorganic Chemistry, Paper Number 79. 184. Daron E. Janzen, Gregory J. Grant; “Five and Six Coordinate Pt(II) Complexes: Orthometallated Pt(II) Thiacrown Complexes and Pt-Ag Dative Bonds” presented at the 57th Southeastern Regional Meeting of


the American Chemical Society, Memphis, TN, November 1-4, 2005. Division of Inorganic Chemistry, Paper Number 78. 183. Gregory J. Grant; “Lords of the Thioether Rings: Mercury(II) and Platinum(II) Complexes of Thiacrown Ligands"; invited departmental seminar; presented to the Department of Chemistry, The University of Richmond, Richmond, VA Sept. 16, 2005. 182. Daron E. Janzen, Gregory J. Grant; “Octahedral Pt(II) Complexes: Orthometallated Pt(II) Thiacrown Complexes and Pt-Ag Dative Bonds” presented at the 230th National Meeting of the American Chemical

Society, Washington, DC, August 28- Sept, 1, 2005. Division of Inorganic Chemistry, Paper Number 106.

181. Gregory J. Grant; “Lords of the Thioether Rings: Mercury(II) and Platinum(II) Complexes of Thiacrown

Ligands"; invited departmental seminar; presented to the Department of Chemistry, Clemson University Clemson, SC April 28, 2005.

180. Gregory J. Grant, Monte L. Helm, Gregory P. Helton, Lensey L. Hill; "199Hg and 113Cd NMR Analysis of Macrocyclic Thioether Complexes” presented at the 229th National Meeting of the American

Chemical Society, San Diego, CA, March, 13-17, 2005. Division of Inorganic Chemistry, Paper Number 705. Selected for SciMix.

179. Maikel E. Botros, Gregory J. Grant, “Synthesis of the Mixed Donor Macrocycle, 9S2N, 7-aza-1,4- dithiacyclcononane”; presented at the 229th National Meeting of the American Chemical Society, San Diego, CA, March 13-17, 2005. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 545. 178. Emily R. Hinson, Gregory J. Grant, “Platinum(II) Complexes of Crown Thioethers with Chiral Diphosphine and Diamine Ligands” presented at the 229th National Meeting of the American Chemical Society, San Diego, CA, March 13-17, 2005. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 1067. 177. Weinan Chen, Gregory J. Grant, “Preparation of a Self-Assembled Molecular Cube using Trivalent Transition Metal Complexes” presented at the 229th National Meeting of the American Chemical Society, San Diego, CA, March 13-17, 2005. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 1068. 176. Ketankumar N. Patel, Gregory J. Grant, “Synthesis and Characterization of a Self-Assembled Platinum(II) Molecular Square” presented at the 229th National Meeting of the American Chemical Society, San Diego, CA, March 13-17, 2005. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 1088. 175. Gregory J. Grant: "Research in the Undergraduate College Environment: What Lessons Can We Learn

from Successful Entrepreneurs?"; presented at the February Meeting of the UTC Sigma Xi Club, Feb. 21, 2005.

174. Gregory J. Grant, Monte L. Helm, Gregory P. Helton, Lensey L. Hill “Applications of 199Hg NMR Spectroscopy in Heavy Metal Complexes of Thiacrown Ligands” presented at the 56th Southeastern Regional Meeting of the American Chemical Society, Research Triangle, NC, November 10-13, 2004. Symposium on Mercury Immobilization in Soil and Water, Environmental Chemistry and Public Health Issues. Paper Number 742. 173. Maikel E. Botros, Gregory J. Grant, “Synthesis of the Mixed Donor Macrocycle, 9S2N, 7-aza-1,4- dithiacyclcononane” presented at the 56th Southeastern Regional Meeting of the American Chemical Society, Research Triangle, NC, November 10-13, 2004. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 874. 172. Emily R. Hinson, Gregory J. Grant, “Platinum(II) Complexes of Crown Thioethers with Chiral


Diphosphine and Diamine Ligands” presented at the 56th Southeastern Regional Meeting of the American Chemical Society, Research Triangle, NC, November 10-13, 2004. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 713. 171. Weinan Chen, Gregory J. Grant, “Preparation of a Self-Assembled Molecular Cube using Trivalent Transition Metal Complexes” presented at the 56th Southeastern Regional Meeting of the American Chemical Society, Research Triangle, NC, November 10-13, 2004. Undergraduate Research Poster

Session, Division of Chemical Education Paper Number 715. This poster won 1st place in Inorganic

Chemistry. 170. Ketankumar N. Patel, Gregory J. Grant, “Synthesis and Characterization of a Self-Assembled Platinum(II) Molecular Square” presented at the 56th Southeastern Regional Meeting of the American Chemical Society, Research Triangle, NC, November 10-13, 2004. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 712. 169. Gregory J. Grant, John P. Lee, Monte L. Helm: “Mixed Sandwich Rh(III and Ir(III) Complexes Containing Cp* and Tridentate Macrocycles” presented at the 56th Southeastern Regional Meeting of the American Chemical Society, Research Triangle, NC, November 10-13, 2004. Division of Inorganic Chemistry, Paper Number 433. 168. Gregory J. Grant, Monte L. Helm, Gregory P. Helton, Lensey L. Hill; "199Hg and 113Cd NMR Analysis of Macrocyclic Thioether Complexes” presented at the 29th International Symposium on Macrocyclic Chemistry; Cairns, Queensland, Australia, July 4 –8, 2004. Paper Number P18. 167. Gregory J. Grant, "Crystallization of Conformational Diastereoisomers” presented at the 227

th National

Meeting of the American Chemical Society, Anaheim, CA; March 28-April 1, 2004. Division of Inorganic Chemistry. Paper Number 288. Selected for SciMix. 166. Weinan Chen, Gregory J. Grant, “Binuclear Rhodium and Molybdenum Complexes with Trithioethers”

presented at the 227th

National Meeting of the American Chemical Society, Anaheim, CA; March 28 – April 1, 2004 Undergraduate Research Poster Session, Division of Chemical Education Paper

Number 376. 165. Ketankumar N. Patel, Monte L. Helm, Gregory J. Grant, “Platinum(II) Complexes with Crown

Thioether and Polypyridine Ligands” presented at the 227th

National Meeting of the American Chemical Society, Anaheim, CA; March 28 – April 1, 2004 Undergraduate Research Poster Session, Division of Chemical Education Paper Number 427.

164. Gregory P. Helton, Monte L. Helm, Gregory J. Grant, “Complexation Studies of Crown Thioethers

Bound to the Heavy Metal Ion Mercury(II)” presented at the 227th

National Meeting of the American Chemical Society, Anaheim, CA; March 28 – April 1, 2004 Undergraduate Research Poster Session, Division of Chemical Education Paper Number 388.

163. Lensey L. Hill, Monte L. Helm, Gregory J. Grant, “Complexation Studies of Cadmium(II) with Crown Thioether Ligands” presented at the 227

th National Meeting of the American Chemical Society,

Anaheim, CA; March 28 – April 1, 2004 Undergraduate Research Poster Session, Division of Chemical Education Paper Number 387. 162. Weinan Chen, Gregory J. Grant, “Binuclear Rhodium and Molybdenum Complexes with Trithioethers” presented at the 55th Southeastern Regional Meeting of the American Chemical Society, Atlanta, GA, November 16-19, 2003. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 1007. 161. Ketankumar N. Patel, Monte L. Helm, Gregory J. Grant, “Platinum(II) Complexes with Crown Thioether and Polypyridine Ligands” presented at the 55th Southeastern Regional Meeting of the American Chemical Society, Atlanta, GA, November 16-19, 2003. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 971. 2

nd Prize Poster.


160. Gregory P. Helton, Monte L. Helm, Gregory J. Grant, “Complexation Studies of Crown Thioethers Bound to the Heavy Metal Ion Mercury(II)” presented at the 55th Southeastern Regional Meeting of the American Chemical Society, Atlanta, GA, November 16-19, 2003. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 288. 159. Lensey Hill, Monte L. Helm, Gregory J. Grant, “Complexation Studies of Cadmium(II) with Crown Thioether Ligands” presented at the 55th Southeastern Regional Meeting of the American Chemical Society, Atlanta, GA, November 16-19, 2003. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 970. 158. Gregory J. Grant, Andrea M. Goforth: “Homoleptic Pt(II) and Pd(II) Complexes of 1,5,9- Trithiacyclododecane"; presented at the 55th Southeastern Regional Meeting of the American Chemical Society, Atlanta, GA, November 16-19, 2003. Division of Inorganic Chemistry, Paper Number 394. 157. Gregory J. Grant, "Lords of the Thioether Rings: Group 10 Metal Complexes of Thiacrown Ligands";

invited departmental seminar; presented to the Department of Chemistry and Biochemistry, The University of Oklahoma, Norman, OK, April 17, 2003.

156. Gregory J. Grant, Andrea M. Goforth: “Homoleptic Pt(II) and Pd(I) Complexes of 1,5,9- Trithiacyclododecane"; presented at the 225th National Meeting of the American Chemical Society, New Orleans, LA, March 23-27, 2003. Division of Inorganic Chemistry, Paper Number 377. Selected for SciMix. 155. John P. Lee, Monte L. Helm, Gregory J. Grant, “Synthesis and Characterization of Mixed Sandwich Group 9 Transition Metal Complexes.” presented at the 225th National Meeting of the American Chemical Society, New Orleans, LA, March 23-27, 2003. Division of Inorganic Chemistry, Paper Number 525. 154. Ketankumar N. Patel, Monte L. Helm, Gregory J. Grant, “Platinum(II) Complexes with Crown Thioether and Polypyridine Ligands” presented at the 225th National Meeting of the American Chemical Society, New Orleans, LA, March 23-27, 2003. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 687. 153. Gregory P. Helton, Monte L. Helm, Gregory J. Grant, “Complexation Studies of Crown Thioethers Bound to the Heavy Metal Ion Mercury(II)” presented at the 225th National Meeting of the American Chemical Society, New Orleans, LA, March 23-27, 2003. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 561. 152. Lensey Hill, Monte L. Helm, Gregory J. Grant, “Synthesis and Characterizations of Crown Thioether Complexes of Cadmium(II)” presented at the 225th National Meeting of the American Chemical Society, New Orleans, LA, March 23-27, 2003. Undergraduate Research Poster Session, Division of Chemical Education Paper Number 717. 151. Gregory J. Grant: "Research in the Undergraduate College Environment: What Lessons Can We Learn from Successful Entrepreneurs?"; presented at the December Meeting of the American Chemical Society, Chattanooga Section; December 5, 2002. 150. Monte L. Helm, Gregory J. Grant, “Multinuclear NMR Studies Involving Heavy Metal Complexes of Crown Thioethers.” Invited oral presentation for Symposium on “Heavy Metal Remediation” at the 54

th Southeast Regional Meeting of the ACS, Charleston, SC, November 13-16, 2002. Paper Number

303. 149. John P. Lee, Monte L. Helm, Gregory J. Grant, “Synthesis and Characterization of Mixed Sandwich Group 9 Transition Metal Complexes.” presented at the 54

th Southeast Regional Meeting of the

American Chemical Society, Charleston, SC, November 13-16, 2002. Paper Number 796.


148. Ketankumar N. Patel, Monte L. Helm, Gregory J. Grant, “Platinum(II) Complexes with Crown Thioether and Polypyridine Ligands.” presented at the 54


American Chemical Society, Charleston, SC, November 13-16, 2002. Paper Number 792. 147. Gregory P. Helton, Monte L. Helm, Gregory J. Grant, “Complexation Studies of Crown Thioethers Bound to the Heavy Metal Ion Mercury(II).” presented at the 54


American Chemical Society, Charleston, SC, November 13-16, 2002. Paper Number 797. 146. Lensey Hill, Monte L. Helm, Gregory J. Grant, “Synthesis and Characterizations of Crown Thiotether Complexes of Cadmium(II).” presented at the 54


American Chemical Society, Charleston, SC, November 13-16, 2002. Paper Number 859. 145. Gregory J. Grant, "A Tale of Two Ligands – Heterobimetallic Complexes Involving Crown Thioethers and Diphosphine”; Invited oral presentation for Symposium on “Organometallics: Ferrocenes and Related Ligands” at the 54

th Southeast Regional Meeting of the American Chemical Society, Charleston, SC,

November 13-16, 2002. Paper Number 456. 144. Gregory J. Grant, "Homoleptic and Heteroleptic Macrocyclic Complexes with Platinum(II) and Palladium(II)”; Invited oral presentation for Symposium on “Recent Advances in Macrocyclic and Supramolecular Ligands” at the 54

th Southeast Regional Meeting of the American Chemical Society,

Charleston, SC, November 13-16, 2002. Paper Number 298. 143. Monte L. Helm, Gregory J. Grant, "Homoleptic Group 12 Metal Complexes of Macrocyclic Thioethers: The Crystal Structures of Bis(1,4,7-Trithiacyclodecane)M(II)( Perchlorate: M= zinc(II), Cadmium(II), Mercury(II)"; 224th National Meeting of the American Chemical Society, Division of Inorganic Chemistry, Boston, MA, August 18-22, 2002. Paper Number 473. 142. Monte L. Helm, Gregory J. Grant; "Structures of Crystals: An Inorganic Laboratory for Undergraduates"

invited poster presentation for Symposium on "Teaching Crystallography:" at the 224th National Meeting of the American Chemical Society, Division of Chemical Education, Boston, MA, August 18-22, 2002. Paper Number 66.

141. Gregory J. Grant; "Heteroleptic Bimetallic Complexes Involving Crown Thioether and Diphosphinoferrocene Ligands” presented at the 35th International Conference on Coordination Chemistry; Heidelberg, Germany July 21-26 2002. Paper Number P4.035 140. Gregory J. Grant; "Heteroleptic Bimetallic Complexes Involving Crown Thioethers and Diphosphines”

presented at the 27th International Symposium on Macrocyclic Chemistry; Park City, Utah, June 23-27, 2002. Paper Number PA31.

139. Gregory J. Grant, Monte L. Helm, Charles M. Comb; "Heavy Metal Complexes of Trithiacrowns” invited oral presentation at the 27th International Symposium on Macrocyclic Chemistry; Park City, Utah, June 23-27, 2002. Paper Number PA32. 138. Gregory J. Grant; "Hetereoleptic Platinum(II) Complexes Involving Crown Thioethers with Chiral and Achiral

Disphosphines” presented at the 53rd Southeast Regional Meeting of the American Chemical Society. Savannah, GA; September 23-26, 2001. Division of Inorganic Chemistry, Paper Number 283.

137. Gregory J. Grant; "The Inorganic Laboratory – A Twenty Year Perspective” presented at the 53rd Southeast

Regional Meeting of the American Chemical Society. Savannah, GA; September 23-26, 2001. Paper Number 267. Division of Inorganic Chemistry, Symposium on Advanced Inorganic Laboratory.

136. Gregory J. Grant ""Are Two Ligands Really Better Than One? Heteroleptic Platinum(II) Complexes Involving Crown Thioether Ligands"; invited departmental seminar; presented to the Institute for Organic Chemistry , The Friedrich-Alexander-University of Erlangen-Nuremberg, Erlangen, Germany. March 3, 2001


135. Gregory J. Grant, Jaime P. Davis: "Platinum(II) Crown Thioether Complexes with Chiral Phosphine Ligands"; presented at the 2000 International Chemical Conference of Pacific Basin Societies; Honolulu, HI; December 14-19, 2000. Division of Inorganic Chemistry, Paper Number 828.

134. Andrea M. Goforth, Gregory J. Grant: "Synthesis of Precious Metal Complexes Containing Crown Thioether Ligands". presented at the 2000 International Chemical Conference of Pacific Basin Societies; Honolulu, HI;

December 14-19, 2000. Division of Inorganic Chemistry, Paper Number 883. 133. Gregory J. Grant; "Are Two Ligands Really Better Than One? " Mixed Ligand Platinum(II) Complexes

Involving Crown Thioether Ligands" presented at the 52nd Southeast/56th Southwest Combined Regional Meeting of the American Chemical Society. New Orleans, LA, December 6-8, 2000. Division of Inorganic Chemistry, Paper Number 215.

132. Andrea M. Goforth, Gregory J. Grant: "Synthesis of Precious Metal Complexes Containing Crown Thioether

Ligands", presented at the 52nd Southeast/56th Southwest Combined Regional Meeting of the American Chemical Society. New Orleans, LA, December 6-8, 2000. Undergraduate Research Symposium, Paper Number 664.

131. Kerry L. Robinson, Gregory J. Grant: "Complexation of Ruthenium(II) with Macrocyclic Hexathioethers",

presented at the 52nd Southeast/56th Southwest Combined Regional Meeting of the American Chemical Society. New Orleans, LA, December 6-8, 2000. Undergraduate Research Symposium, Paper Number 694.

130. Gregory J. Grant; "Are Two Ligands Really Better Than One? Mixed Ligand Platinum(II) Complexes Involving Crown Thioether Ligands"; invited departmental seminar; presented to the Department of Chemistry, The University of Alabama, Tuscaloosa, AL. Oct. 27, 2000. 129. Gregory J. Grant, Jaime P. Davis,: "Heteroleptic Platinum(II) Crown Thioether Complexes with

Chiral Phosphine Ligands". presented at the 34th International Conference on Coordination Chemistry; Edinburgh, Scotland UK; July 9-14, 2000. Paper Number 83.

128. Gregory J. Grant: "Jahn-Teller Distortions in Copper(II) Complexes of Tridentate Cyclononane Ligands" presented at the 34th International Conference on Coordination Chemistry; Edinburgh, Scotland UK; July 9-14, 2000. Paper Number 84. 127. Gregory J. Grant, Jaime P. Davis,: "Heteroleptic Platinum(II) Crown Thioether Complexes with Chiral Phosphine Ligands". presented at the XXV International Symposium On Macrocyclic Chemistry, St. Andrews, Scotland, UK, July 2-7, 2000. Paper Number P23. 126. Gregory J. Grant: "Jahn-Teller Distortions in Copper(II) Complexes of Tridentate Cyclononane Ligands". presented at the XXV International Symposium On Macrocyclic Chemistry, St. Andrews, Scotland, UK, July 2-7, 2000. Paper Number P22. 125. Andrea B. Mitchell, Gregory J. Grant: "Synthesis of Precious Metal Complexes Containing Crown Thioether Ligands". presented at the 219th National ACS Meeting in San Francisco, CA. March 26-30, 2000. , Division of Chemical Education, Paper Number 726. 124. Jaime A. Pool, Gregory J. Grant: "Platinum(II) Crown Thioether Complexes with Chiral Phosphine

Ligands". presented at the 219th National ACS Meeting in San Francisco, CA. March 26-30, 2000.

Division of Inorganic Chemistry, Paper Number 150. 123. Gregory J. Grant: "Jahn-Teller Distortions in Copper(II) Complexes of Tridentate Cyclononane Ligands". presented at the 219 th National ACS Meeting in San Francisco, CA

March 26-30, 2000; Division of Inorganic Chemistry. Paper Number 90. 122. Gregory J. Grant: ""How Does a C-O Bond Differ from a C-S Bond? Transition Metal Complexes of Thioethers and Oxathioethers" invited departmental seminar; presented to the Department of Chemistry, The University of North Carolina at Charlotte, Charlotte, NC Feb. 21, 2000


121. Gregory J. Grant: ""National Science Foundation Programs Targted at PUIs" invited seminar; presented to

UTC Arts and Science Faculty, sponsored by Grants and Program Review, The University of Tennessee at Chattanooga, Chattanooga, TN. Nov. 17, 1999.

120. Gregory J. Grant: "Research in the Small College Environment: What Lessons Can We Learn from

Successful Entrepreneurs?"; presented at the 51st Southeastern Regional ACS Meeting; Knoxville, TN; Oct. 17 -20, 1999. Symposium on Starting and Sustaining Quality Research in a Small College Context. Paper Number 191.

119. Andrea B. Mitchell, Gregory J. Grant: "Synthesis of Precious Metal Complexes Containing Crown

Trithioether Ligands".; presented at the 51st Southeastern Regional ACS Meeting; Knoxville, TN; Oct. 17 -

20, 1999, Division of Inorganic Chemistry. Paper Number 270.. 118. Jaime P. Davis, Gregory J. Grant: "Platinum(II) Crown Thioether Complexes with

Chiral Phosphine Ligands"; presented at the 51st Southeastern Regional ACS Meeting; Knoxville, TN; Oct. 17 -20, 1999, Division of Inorganic Chemistry. Paper Number 279.

117. Jaime P. Davis, Gregory J. Grant: "Platinum(II) Crown Thioether Complexes with Chiral Phosphine Ligands".; presented at the 51st Southeastern Regional ACS Meeting; Knoxville,

TN; Oct. 17 -20, 1999; Undergraduate Research Talks. Paper Number 31. 116. Gregory J. Grant: ""How Does a C-O Bond Differ from a C-S Bond? Transition Metal Complexes of

Thioethers and Oxathioethers" invited departmental seminar; presented to the Department of Chemistry, East Tennessee State University, Johnson City, TN; September 17, 1999.

115. Clairalyn L. Baucom, Gregory J. Grant: "Platinum Group Metal Complexes of Crown Thioether Ligands" presented at the 217th National ACS Meeting; Anaheim, CA; March 21-25, 1999 . Division of Chemical Education. Paper Number 208. 114. Shawn M. Carter, Gregory J. Grant: "Mixed Sandwich Complexes Using Transition Metals and Crown Thioethers"; presented at the 217th National ACS Meeting; Anaheim, CA; March 21-25, 1999 . Division of Chemical Education. Paper Number 191. 113. Jaime A. Pool, Gregory J. Grant: "Platinum(II) Crown Thioether Complexes with Chiral Phosphine Ligands".; presented at the 217th National ACS Meeting; Anaheim, CA; March 21-25, 1999 . Division of Chemical Education. Paper Number 246. 112. Ivan M. Poullaos, Gregory J. Grant: "Platinum(II) Crown Thioether Complexes with Phosphine Ligands"; presented at the 217th National ACS Meeting; Anaheim, CA; March 21-25, 1999 . Division of Inorganic Chemistry. Paper Number 275. Selected for SciMix Poster Session. 111. Gregory J. Grant: ""How Does a C-O Bond Differ from a C-S Bond? Precious Metal Complexes of Thioethers and Oxathioethers" invited departmental seminar presented to the Department of Chemistry, Appalachian State University, Boone, NC; November 13, 1998. 110. Gregory J. Grant: "Introduction of Chemical Instrumentation in the First Semester Freshman Laboratory"; presented at the 50th Southeastern Regional ACS Meeting; Raleigh, NC; Nov. 4-7, 1998. Division of Chemical Education. Paper Number 144.

109. Clairalyn L. Baucom, Gregory J. Grant: "Platinum Group Metal Complexes of Crown Thioether Ligands" presented at the 50th Southeastern Regional ACS Meeting; Raleigh, NC; Nov. 4-7, 1998. Division of Inorganic Chemistry. Paper Number 287. 108. Shawn M. Carter, Gregory J. Grant: "Mixed Sandwich Complexes Using Transition Metals


and Crown Thioethers"; presented at the 50th Southeastern Regional ACS Meeting; Raleigh, NC; Nov. 4-7, 1998. Division of Inorganic Chemistry. Paper Number 290. 107. Jaime A. Pool, Gregory J. Grant: "Platinum(II) Crown Thioether Complexes with Chiral Phosphine Ligands". presented at the 50th Southeastern Regional ACS Meeting; Raleigh, NC; Nov. 4-7, 1998. Division of Inorganic Chemistry. Paper Number 311. 106. Ivan M. Poullaos, Gregory J. Grant: "Platinum(II) Crown Thioether Complexes with Phosphine Ligands"; presented at the 50th Southeastern Regional ACS Meeting; Raleigh, NC; Nov. 4-7, 1998. Division of Inorganic Chemistry. Paper Number 312.

105. G.J. Grant; " Platinum Group Metal Complexes of Macrocyclic Mixed Oxa-Thia Ligands"; presented at the 1998 Inorganic Gordon Conference; Newport, R.I., July 19 -24, 1998. Paper Number 25. 104. David F. Galas; G. J. Grant: "Platinum(II) Complexes of Crown Thioether and Mixed Oxathia Ligands: Analysis by Nuclear Magnetic Resonance and X-ray Crystallography"; presented at the XXIII International Symposium on Macrocyclic Chemistry; Turtle Bay, Hawaii, June 7-12, 1998. Paper Number PSA-34. 103. I. M. Poullaos; G.J. Grant: "A Platinum(II Crown Thioether Complex with the Diphosphine Ligand 1,1'-Bis(Diphenylphosphino)ferrocene: Formation of a Heterobimetallic Complex"; presented at the XXIII International Symposium on Macrocyclic Chemistry; Turtle Bay, Hawaii, June 7-12, 1998. Paper Number PSB-22. 102. G.J. Grant: "Platinum Group Metal Complexes of Crown Thioethers and Mixed Oxa-thia Ligands"; invited departmental seminar presented to the Department of Chemistry, Mississippi State University, Starkville, MS; April, 17, 1998. 101. G.J. Grant: "Platinum Group Metal Complexes of Crown Thioethers and Mixed Oxa-thia Ligands"; invited departmental seminar presented to the Department of Chemistry, George Washington University, Washington, D.C. November 23, 1997. 100. G.J. Grant: "FT-NMR in Undergraduate Instruction and Research"; presented at the 49th Southeastern Regional ACS Meeting; Roanoke, VA; Oct. 19-22, 1997; Division of Chemical Education. Paper Number 51. 99. David F. Galas; G. J. Grant: "Platinum(II) Complexes of Crown Thioether and Mixed Oxathia Ligands: Analysis by NMR"; presented at the 49th Southeastern Regional ACS Meeting; Roanoke, VA; Oct. 19- 22, 1997; Division of Inorganic Chemistry. Paper Number 81. 98. C. L. Baucom; G. J. Grant: "Platinum Group Metal Complexes of Crown Thioether Ligands"; presented at the 49th Southeastern Regional ACS Meeting; Roanoke, VA; Oct. 19-22, 1997; Division of Inorganic Chemistry. Paper Number 275. 97. I. M. Poullaos; G. J. Grant: "Platinum(II) Crown Thioether Complexes with Phosphine Ligands"; presented at the 49th Southeastern Regional ACS Meeting; Roanoke, VA; Oct. 19-22, 1997; Division of Inorganic Chemistry. Paper Number 274. 96. Grant, G.J.: "FT-NMR in Undergraduate Instruction and Research"; presented at the 214th National ACS Meeting; Las Vegas, NV; Sept. 7-11, 1997; Division of Chemical Education. Paper Number 205. 95. I. Poullaos; G. J. Grant: "Platinum(II) Crown Thioether Complexes with Phosphine Ligands"; presented at the 214th National ACS Meeting; Las Vegas, NV; Sept. 7-11, 1997; Division of Inorganic Chemistry. Paper Number 76. 94. D. F. Galas; G. J. Grant: "Platinum(II) Complexes of crown thioether and mixed oxa-thia ligands:


Analysis by Nuclear Magnetic Resonance"; presented at the 214th National ACS Meeting; Las Vegas, NV; Sept. 7-11, 1997; Division of Inorganic Chemistry. Paper Number 77. 93. G.J. Grant; "Cobalt(III) Complexes of Crown Hexathioethers" presented at the 213th National ACS Meeting ; San Francisco, CA; April 13 -17, 1997; Division of Inorganic Chemistry. Paper Number 296. 92. D. F. Galas; G. J. Grant: "Platinum(II) Complexes of crown thioether and mixed oxa-thia ligands: Analysis by

Nuclear Magnetic Resonance"; presented at the 213th National ACS Meeting; San Francisco, CA; April 13 -17, 1997; Division of Inorganic Chemistry. Paper Number 295.

91. D. F. Galas; G. J. Grant: "Nuclear Magnetic Resonance Analysis of Transition Metal Complexes with Crown Thioether Ligands"; presented at the 48th Southeastern Regional ACS Meeting ; Greenville, SC; Nov. 10 -13, 1996. Paper Number 2 90. I. Poullaos; G. J. Grant: "Selective Complexation of Transition Metal Ions Using Crown Thioethers"; presented at the 48th Southeastern Regional ACS Meeting; Greenville, SC; Nov. 10 -13, 1996. Paper Number 4. 89. G. J. Grant; Transition Metal Complexes with Crown Thioether and Mixed Oxa-Thia Crown Ligands"; invited seminar presented at the Department of Chemistry, The University of Memphis Memphis, TN; November 1, 1996. 88. G. J. Grant; "Precious Metal Complexes with Crown Thioether and Mixed Oxa-Thia Crown Ligands"; presented at the 31st International Conference on Coordination Chemistry in Vancouver, BC; August 18-23, 1996. Paper Number 5P98. 87. K.D. Loveday; G. J. Grant: "Selective Complexation of Transition Metal Ions Using Thioethers"; presented the 211th National ACS Meeting in New Orleans; March 24-28, 1996. Division of Inorganic Chemistry; Paper Number 441. 86. G. J. Grant; Transition Metal Complexes with Crown Thioether and Mixed Oxa-Thia Crown Ligands"; invited seminar presented at the Department of Chemistry, The University of Alabama at Birmingham; Birmingham , AL; February 23, 1996. 85. G. J. Grant; Transition Metal Complexes with Mixed Oxa-Thia Crown Ligands"; presented at the 1995 International Chemical Congress of Pacific Basin Societies; Honolulu, HI, December 17-22, 1995. General Inorganic Paper Number 1470. 84. T.A. Salupo; G. J. Grant, L.A. Holt; "Mixed-Sandwich Organometallic Complexes with Thioether Ligands"; presented at the 1995 International Chemical Congress of Pacific Basin Societies; Honolulu, HI, December 17-22, 1995. General Inorganic Paper Number 1460. 83. K.D. Loveday; G. J. Grant: "Complexation of Transition-Metal Ions Using Crown Thioethers and Mixed Oxa-Thia Crown Ligands"; presented the 47th Southeastern Regional/51st Southwestern Joint ACS Meeting in Memphis; Nov. 29 - Dec. 1, 1995,. Division of Inorganic Chemistry; Paper Number 300.

82. C. E. Hadden, G. J. Grant: "59Co and 195Pt NMR as a novel characterization technique of transition metal complexes with crown thioether ligands". presented the 47th Southeastern Regional/51st Southwestern Joint ACS Meeting in Memphis; Nov. 29 - Dec. 1, 1995,. Division of Inorganic Chemistry; Paper Number 301.

81. G. J. Grant; M.W. Jones, K.D. Loveday; "Transition Metal Complexes with Mixed Oxa-Thia Crown Ligands"; presented at the Joint Meeting of the ACS Northwest and Rocky Mountain Regions; Park City, UT; June 14-17, 1995. Division of Inorganic Chemistry; Paper Number 195. 80. T.A. Salupo; G. J. Grant, L.A. Holt; "Mixed-Sandwich Organometallic Complexes with Thioether Ligands"; presented at the Joint Meeting of the ACS Northwest and Rocky Mountain Regions; Park City, UT;


June 14-17, 1995. Division of Inorganic Chemistry; Paper Number 196. 79. W.N. Setzer; G.J. Grant' "Chelation of Toxic Metal Ions by Cyclic Polythioethers"; presented at the Conference and Workshop on the NIH AREA Program; Indianapolis, IN; April 9-10, 1995. 78. G. J. Grant; "Transition Metal Complexes with Macrocyclic Polythioethers and Mixed Oxa-Thia Crown Ligands"; invited seminar; Department of Chemistry, The University of Tennessee at Knoxville, Knoxville, TN. April 7, 1995. 77. G. J. Grant; "Transition Metal Complexes with Mixed Oxa-Thia Crown Ligands"; presented at the 46th Southeastern Regional ACS Meeting ; Birmingham, AL; Oct. 16 -19, 1994. Division of Inorganic Chemistry; Paper Number 66. 76. L. A. Holt; T.A. Salupo; G. J. Grant; "Mixed-Sandwich Organometallic Complexes with Thioether Ligands"; presented at the 46th Southeastern Regional ACS Meeting ; Birmingham, AL; Oct. 16 -19, 1994. Division of Inorganic Chemistry; Paper Number 483. 75. K. D. Loveday; G. J. Grant; "Complexation of Transition-Metal Ions Using Crown Thioethers and Mixed Oxa-Thia Crown Ligands"; presented at the 46th Southeastern Regional ACS Meeting ; Birmingham, AL; Oct. 16 -19, 1994. Division of Inorganic Chemistry; Paper Number 484. 74. G. J. Grant; M. W. Jones: "Transition Metal Complexes of Mixed Oxa-Thia Crown Ligands"; invited paper presented at the 19th International Symposium on Macrocyclic Chemistry; Lawrence, KS; June 13 -17, 1994; Paper Number ST9. 73. G. J. Grant, "Transition Metal Complexes with Crown Polythioether Ligands"; invited paper presented at the 207th National ACS Meeting; San Diego, CA; March 13 -17, 1994; Division of Chemical Education, Dreyfus Symposium; Paper Number 66. 72. C. G. Brandow; G. J. Grant; W. N. Setzer; "Synthesis of Mesocyclic and Macrocyclic Polythioether Ligands"; presented at the 207th National ACS Meeting; San Diego, CA; March 13 -17, 1994; Division of Inorganic Chemistry; Paper Number 93. 71. M. W. Jones; G. J. Grant; W. N. Setzer; "Transition Metal Complexes of Crown Ether- Thioether Ligands"; presented at the 207th National ACS Meeting ; San Diego. CA; March 13 -17, 1994; Division of Inorganic Chemistry; General Poster Session; Paper Number 92. 70. G. J. Grant, W. N. Setzer: "NMR Analysis of Transition Metal Complexes with Crown Thioether Ligands";

presented at the 45th Southeastern Regional Meeting of the American Chemical Society; Johnson City, TN.; October 17 - 20, 1993. Paper Number 152.

69. M.W. Jones, G. J. Grant, W. N. Setzer: "Transition Metal Complexes of Mixed Macrocyclic Ether-Thioether

Ligands"; presented at the 45th Southeastern Regional Meeting of the American Chemical Society; Johnson City, TN.; October 17 - 20, 1993. Paper Number 336.

68. C. G. Brandow, G. J. Grant,, Setzer, W.N.: "Syntheses of Mesocyclic and Macrocyclic Polythioether Ligands";

presented at the 45th Southeastern Regional Meeting of the American Chemical Society; Johnson City, TN.; October 17 -20, 1993.; Paper Number 337.

67. Show-yee Liou; W. N. Setzer; Gregory J. Grant; "Synthesis and Complexation Studies of Hydrophilic Crown

Thioethers"; presented at the 205th National Meeting of the American Chemical Society; March 28 - April 2, 1993; Denver, Colorado; Division of Inorganic Chemistry, Poster Number 284.

66. Gregory Easterling; W. N. Setzer; Gregory J. Grant; "The Synthesis of Mesocyclic Trithioethers Appended

with Functional Groups"; presented at the 205th National Meeting of the American Chemical Society; March 28 - April 2, 1993; Denver, Colorado; Division of Chemical Education, Poster Number 208.


65. Grant, G.J.: "Transition Metal Complexes with Crown Thioethers"; invited seminar presented at the Department of Chemistry; The University of Utah; Salt Lake City, UT; February, 9. 1993.

64. Grant, G.J.: "Transition Metal Complexes with Crown Thioethers"; invited seminar presented at the Department

of Chemistry; Brigham Young University; Provo, UT; January 25, 1993. 63. Grant, G.J.: "Transition Metal Complexes with Crown Thioethers"; invited seminar presented at the Department

of Chemistry; Utah State University; Logan, UT; January 15, 1993. 62. L. F. Mehne; Gregory J. Grant; "Cyclic Voltammetry of Transition Metal Crown Thioether Complexes";

presented at the 44th Southeastern-26th Middle Atlantic Joint Regional Meeting of the American Chemical Society; Arlington, VA.; December 6-9, 1992. Paper Number 277.

61. C. G. Brandow; Gregory J. Grant; William N. Setzer: "Synthesis of Mesocyclic and Macrocyclic Polythioether

Ligands"; presented at the Seventeenth International Symposium on Macrocyclic Chemistry; August 9-14, 1992; Provo, Utah; Poster Number 15.

60. Gregory J. Grant; Nathan J. Spangler; Larry F. Mehne; William N. Setzer "Crown Thioether Complexes with

Palladium(II) and Platinum(II)"; presented at the Seventeenth International Symposium on Macrocyclic Chemistry; August 9-14, 1992; Provo, Utah; Poster Number 39.

59. Myron W. Jones; Gregory J. Grant; William N. Setzer "Transition Metal Complexes of Mixed Macrocyclic

Ether-Thioether Ligands"; presented at the Seventeenth International Symposium on Macrocyclic Chemistry; August 9-14, 1992; Provo, Utah; Poster Number 45.

58. Denise Y. Morrissey; Gregory J. Grant; William N. Setzer "Organometallic Complexes of Macrocyclic

Thioethers"; presented at the Seventeenth International Symposium on Macrocyclic Chemistry; August 9-14, 1992; Provo, Utah; Poster Number 71.

57. William N. Setzer; Show-yee Liou; Gregory J. Grant; "NMR Analysis of Crown Thioethers and Their Metal

Complexes"; presented at the Seventeenth International Symposium on Macrocyclic Chemistry; August 9-14, 1992; Provo, Utah; Poster Number 94.

56. Gregory J. Grant "Transition Metal Complexes with Thioether Ligands"; invited seminar; Department of

Chemistry; Vanderbilt University; Nashville, TN.; May 26, 1992.

55. N.J. Spangler, Grant, G.J., Setzer, W.N.: "Thioether Complexes with Palladium(II) and Platinum(II)";

presented at 203rd National Meeting of the American Chemical Society; San Francisco, CA.; April 5, 1992. Division of Inorganic Chemistry; Paper number 174.

54. B.H. McCosar, Grant, G.J., Setzer, W.N.: Structural Determination of Isomers in Homoleptic and

Trithiocyanato Crown Thioether Complexes"; presented at 203rd National Meeting of the American Chemical Society; San Francisco, CA.; April 5, 1992. Division of Inorganic Chemistry; Paper number 175.

53. S.D. Lee, Grant, G.J., Setzer, W.N.: "Synthesis of Mesocyclic and Macrocyclic Polythioether Ligands";

presented at 203rd National Meeting of the American Chemical Society; San Francisco, CA.; April 5, 1992. Division of Inorganic Chemistry; Paper number 176.

52. Setzer, W.N. and Grant, G.J.: "Molecular Mechanics Conformational Study of Trithiacycloundecanes";

presented at 203rd National Meeting of the American Chemical Society; San Francisco, CA.; April 7, 1992. Division of Organic Chemistry; Paper Number 314.

51. Grant, G.J. and Setzer, W.N.: "Transition Metal Complexes with Macrocyclic Polythioether Ligands";

presented at the 43rd Southeastern Regional Meeting of the American Chemical Society; Richmond, VA.; November 12 -15, 1991. Paper Number 192.


50. Ewing, F.; Campbell, P.S.; Grant, G.J.; and Setzer, W.N.: "Heavy Metal Chelation Therapy Using Crown Thioether Derivatives"; presented at the 43rd Southeastern Regional Meeting of the American Chemical Society; Richmond, VA.; November 12 -15, 1991. Paper Number 447.

49. Spangler, N.J.; Grant, G.J.; and Setzer, W.N.: " Thioether Complexes with Palladium(II) and Platinum(II)";


48. Lee. S.D.; Grant, G.J.; and Setzer, W.N.: "Synthesis of Mesocyclic and Macrocyclic Polythioether Ligands";


47. McCosar, B.H.; Grant, G.J.; and Setzer, W.N.: "Role of Hardness and Softness in Cyclic Thioether

Coordination Chemistry"; presented at the 43rd Southeastern Regional Meeting of the American Chemical Society; Richmond, VA.; November 12 -15, 1991. Paper Number 482.

46. Grant, G.J.: "Transition Metal Complexes with Crown Thioethers"; invited seminar presented at the Department

of Chemistry; Clemson University, Clemson, SC; October 31, 1991. 45. Grant, G.J.: "Transition Metal Complexes with Crown Thioethers"; invited seminar presented at the Department

of Chemistry and Physics; Middle Tennessee State University; Murfreesboro, TN; October 24, 1991. 44. Setzer, W.N. and Grant, G.J.: "Structural Aspects of Heavy-Metal Complexes of Macrocyclic Polythioether

Ligands"; presented at the Sixteenth International Symposium on Macrocyclic Chemistry; Sheffield, England; September 1, 1991.

43. Grant, G.J. and Setzer, W.N.: "Transition Metals Complexes with Tridentate and Hexadentate Thioether

Ligands"; presented at National Meeting of the American Chemical Society; Atlanta, GA.; April 15, 1991. Division of Inorganic Chemistry; Paper Number 140.

42. Setzer, W.N. and Grant, G.J.: "Heavy Metal Complexes with Tridentate and Hexadentate Thioether Ligands"; presented at National Meeting of the American Chemical Society; Atlanta, GA.; April 15, 1991. Division of

Inorganic Chemistry; Paper Number 139. 41. Sanders, K.A.; Grant, G.J.; Setzer, W.N.: "Rhenium(III) and Palladium(II) Complexes of Crown Thioether

Ligands"; presented at National Meeting of the American Chemical Society; Atlanta, GA.; April 15, 1991. Division of Inorganic Chemistry; Paper Number 138.

40. Stoddard, S.L.; Grant, G.J.; Setzer, W.N.: "The Synthesis of Cobalt Coordination Complexes Containing

Crown Thioether Ligands"; presented at National Meeting of the American Chemical Society; Atlanta, GA.; April 15, 1991. Division of Inorganic Chemistry; Paper Number 137.

39. Kirk, R.M.; Grant, G.J.; Setzer, W.N.: "Synthesis of Mesocyclic and Macrocyclic Polythioether Ligands";

presented at National Meeting of the American Chemical Society; Atlanta, GA.; April 15, 1991. Division of Chemical Education; Paper Number 30.

38. Burns, N.L.; Grant, G.J.; Setzer, W.N.: "Synthesis and Complexation Studies of Mesocyclic Trithioethers";

presented at National Meeting of the American Chemical Society; Atlanta, GA.; April 15, 1991. Division of Chemical Education; Paper Number 32.

37. Ferrante, D.; Tarquine, S.S.; Setzer, W.N.; Grant, G.J.: "Mesocyclic Polythioethers as Pharmacologic Chelating

Agents: Synthesis, Complexation, and Toxicity Studies of 1,4,7-Trithiacyclodecan-9-ol and 1,5,9-Trithiacyclodecan-3-ol"; presented at National Meeting of the American Chemical Society; Atlanta, GA.; April 15, 1991. Paper Number 146.


36. Grant, G.J.: "Spontaneous Resolution and Coordination Chemistry: The Role of Serendipity in Research"; invited seminar presented at the Department of Chemistry, The University of Tennessee at Chattanooga, Chattanooga, TN; January 18, 1991.

35. Grant, G.J,; Moyer, T.J.; Rogers, K.E.; Setzer, W.N., "Transition Metals Complexes with Tridentate and

Hexadentate Thioether Ligands" presented at the 42nd Southeastern /46th Southwestern Regional Meeting of the American Chemical Society; New Orleans, LA; December 5 -7, 1990. Paper Number 295.

34. Kirk, R.M.; Grant, G.J.; Setzer, W.N.: "Synthesis of Mesocyclic and Macrocyclic Polythioether Ligands";

presented at the 42nd Southeastern /46th Southwestern Regional Meeting of the American Chemical Society; New Orleans, LA; December 5 -7, 1990. Paper Number 609.

33. Stoddard, S.L.; Grant, G.J.; Setzer, W.N.: "The Synthesis of Cobalt Coordination Complexes Containing Crown

Thioether Ligands"; presented at the 42nd Southeastern /46th Southwestern Regional Meeting of the American Chemical Society; New Orleans, LA; December 5 -7, 1990. Paper Number 611.

32. Sanders, K.A.; Grant, G.J.; Setzer, W.N.: "Rhenium(III) Complexes of Crown Thioether Ligands"; presented at

the 42nd Southeastern /46th Southwestern Regional Meeting of the American Chemical Society; New Orleans, LA; December 5 -7, 1990. Paper Number 610.

31. Tang, Y.; Grant, G.J.; Setzer, W.N.: "Crown Thioethers as Complexing Agents for Heavy Metals"; presented at

the 42nd Southeastern /46th Southwestern Regional Meeting of the American Chemical Society; New Orleans, LA; December 5 -7, 1990. Paper Number 648.

30. Burns, N.L.; Grant, G.J.; Setzer, W.N.: "Synthesis and Complexation Studies of Mesocyclic Trithioethers";

presented at the 42nd Southeastern /46th Southwestern Regional Meeting of the American Chemical Society; New Orleans, LA; December 5 -7, 1990. Paper Number 649.

29. Zhang, Q.; Grant, G.J.; Setzer, W.N.: "Rhodium Complexes of Mesocyclic Trithioethers"; presented at the 42nd

Southeastern /46th Southwestern Regional Meeting of the American Chemical Society; New Orleans, LA; December 5 -7, 1990. Paper Number 650.

28. Grant, G.J.: "Transition Metal Complexes with Tridentate and Hexadentate Thioethers"; invited seminar

presented at the Department of Chemistry; The University of Alabama, Tuscaloosa, AL; September 9, 1990. 27. Grant, G.J.: "The Role of the Laboratory Component in Advanced Inorganic Chemistry"; presented at the 11th

Biennial Conference on Chemical Education; Atlanta, Georgia; August 5-9, 1990; Paper Number 190. 26. Grant, G.J. and Meyer, G.M.: "The Laboratory Component in Second Semester General Chemistry"; presented

at the 11th Biennial Conference on Chemical Education; Atlanta, Georgia; August 5-9, 1990; Paper Number 343.

25. Meyer, G.M. and Grant, G.J.: "Designing a User-Friendly Laboratory for First Semester General Chemistry";

presented at the 11th Biennial Conference on Chemical Education; Atlanta, Georgia; August 5-9, 1990; Paper Number 342.

24. Setzer, W.N. and Grant, G.J.: "Synthesis and Complexation Studies of Mesocyclic Trithioethers"; presented at

the 45th Northwestern / 10th Rocky Mountain Regional Meeting of the American Chemical Society; Salt Lake City, Utah; June 13-15, 1990; Paper Number 138.

23. Grant, G.J.: "Transition Metal Complexes with Tridentate and Hexadentate Thioethers"; invited seminar

presented at the Department of Chemistry; The University of Georgia, Athens, GA; March 5, 1990. 22. Grant, G.J. and Setzer, W.N.: "Transition Metal Complexes of 1,4,7-Trithiacyclodecane"; presented at The

International Chemical Congress of Pacific Basin Societies; Honolulu, HA; December, 17-22 1989. Paper number 64.


21. Isaac, S.M. and Grant, G.J.: "The Synthesis of Mesocyclic and Macrocyclic Thioether Ligands"; presented at The International Chemical Congress of Pacific Basin Societies; Honolulu, HA; December, 17-22 1989. Paper number 56.

20. Rogers, K.E., Carpenter, J.P. and Grant, G.J.: "Crown Thioether Complexes with Transition Metals"; presented

at The International Chemical Congress of Pacific Basin Societies; Honolulu, HA; December, 17-22 1989. Paper number 66.

19. Ferrante, L.A., Setzer, W.N., and Grant, G.J.: "Heavy Metal Complexation Studies of Medium-Sized Ring

Thioethers"; presented at The International Chemical Congress of Pacific Basin Societies; Honolulu, HA; December, 17-22 1989. Paper number 65.

18. Guo,Q., Setzer, W.N., and Grant, G.J.: "Mesocyclic and Macrocyclic Polythioethers as Ligands for Complexing

Heavy Metal Ions"; presented at The International Chemical Congress of Pacific Basin Societies; Honolulu, HA; December, 17-22 1989. Paper number 57.

17. Grant, G.J. and Carpenter, J.P.: "Zerovalent Molybdenum Complexes of Mesocyclic and Macrocyclic Crown

Thioethers"; presented at The 41st Southeastern Regional Meeting of the American Chemical Society; Winston-Salem, NC; October 9-11, 1989. Paper number 318.

16. Grant, G.J. and Kim, D.D.: "Transition Metal Complexes of 1,4,7-Trithiacyclodecane"; presented at The 41st

Southeastern Regional Meeting of the American Chemical Society; Winston-Salem, NC; October 9-11, 1989. Paper number 477.

15. Isaac, S.M. and Grant, G.J.: "The Synthesis of Mesocyclic and Macrocyclic Thioether Ligands"; presented at

The 41st Southeastern Regional Meeting of the American Chemical Society; Winston-Salem, NC; October 9-11, 1989. Paper number 478.

14. Rogers, K.E. and Grant, G.J.: "Crown Thioether Complexes with Transition Metals"; presented at The 41st

Southeastern Regional Meeting of the American Chemical Society; Winston-Salem, NC; October 9-11, 1989. Paper number 480.

13. Kim, D.H. and Grant, G.J.: "The Synthesis of Tridentate Thioether Ligands"; presented at The 40th

Southeastern Regional Meeting of the American Chemical Society; Atlanta, GA; November 9-11, 1988. Paper number 601.

12. Isaac, S.M. and Grant, G.J.: "The Synthesis and Purification of Tridentate and Hexadentate Thioether Ligands";

presented at The 40th Southeastern Regional Meeting of the American Chemical Society; Atlanta, Georgia; November 9-11, 1988. Paper number 602.

11. Carpenter, J.P. and Grant, G.J.; "Thioether Complexes Containing Zerovalent Group VIB Metals"; presented at

The 40th Southeastern Regional Meeting of the American Chemical Society; Atlanta, Georgia; November 9-11, 1988. Paper number 603.

10. Grant, G.J., Laudeman, C.P., and Lewis, C.M: "Transition Metal Complexes with Mesocyclic Thioethers

Containing Mixed Bridges"; presented at The 39th Southeastern Regional Meeting of the American Chemical Society; Orlando, Florida; November 3-6, 1987. Paper number 108.

9. Grant, G.J. and Lewis, C.M. : "Transition Metal Complexes of Macrocyclic Thioethers", presented at The Southeastern Regional Meeting of the Student Affiliates of the American Chemical Society; Richmond, Virginia, March, 1987. Paper number 55. 8. Grant, G.J., Lewis, C.M., and Waggoner, J.W.; "Transition Metal Complexes of Tridentate Thioethers",

presented at The 38th Southeastern Regional Meeting of the American Chemical Society; Louisville, KY; November 3-5, 1986. Paper number 191.


7. Grant, G.J.: "Transition Metal Complexes of Thioethers", invited seminar, Department of Chemistry, the University of Alabama in Huntsville; May 9,1986.

6. Grant G.J. and Downs, C.J.: "Transition Metal Complexes of 2,5,8-Trithianonane"; presented at The First Pan American Chemical Congress; San Juan, Puerto Rico; October, 13-18, 1985. Paper number 0950-2. 5. Grant, G.J. and Downs, C.J.: "Transition Metal Complexes of 2,5,8-Trithianonane"; presented at The 37th

Southeastern/33 rd Southwestern Regional Meeting of the American Chemical Society; Memphis, Tennessee; October 9-11, 1985. Paper number 173.

4. Grant, G.J.: "Adventures in Research at UTC"; invited seminar presented at The Department of Chemistry, The

University of Tennessee at Chattanooga; January, 18, 1985. 3. Grant, G.J., Grant, C.D., Brimmer, J.F., and Coppert, D.M.; "Transition Metal Complexes of Macrocyclic

Thioethers"; presented at The 36th Southeastern Regional Meeting of the American Chemical Society, Raleigh, N.C., October 24-26, 1984. Paper number 303.

2. Grant, G.J., Grant, C.D., Holloway, D.H., Lowe, D. W. and Minnick, B.M.; "Transition Metal Complexes of

Macrocyclic Thioethers"; presented at The 35th Southeastern Regional Meeting of the American Chemical Society; Charlotte, N. C.; November 9-11, 1983. Paper number 382.

1. Grant, G.J.: "Synthesis and Optical Activity of Cobalt(III) Complexes with Macrocyclic Amines" invited

seminar presented at The Department of Chemistry, The University of Tennessee at Chattanooga; September 16, 1981.


Previous Support

External Total Prior and Current External Funding Support = $2.1 M from 28 Grants.

Previous Funding: 26. Research Corporation, Cottrell Grant Program, "The Preparation of Pt(II) and Pd(II) Molecular Squares Containing Thiacrown Ligands"; UTC Direct and Indirect Costs: $36,000/three years (07-01- 07 to 6-30-10). 25. National Science Foundation, RUI Program. "The Complexation of Heavy Metal Ions with Polythioethers and Related Crown Ligands”; UTC Direct and Indirect Costs: $200,000/four years (9-1-03 to 8-31-08). 24. American Chemical Society, The Petroleum Research Fund, ACS-PRF Summer Faculty Research Fellowship; “Complexation Studies of Heavy Metal Ions by Crown Polythioethers and Related Macrocyclic Ligands” UTC Direct and Indirect Costs: $8,000/three months (5-01-06 to 7-31-06). 23. National Science Foundation, MRI Program. "Acquisition of a LC-MS-MS for Research in Biology, Environmental Science, and Chemistry at UT Chattanooga ”; UTC Direct and Indirect Costs: $251,720.00/two years (8-1-05 to 7-31-07). 22. American Chemical Society, Petroleum Research Fund, “Complexation Studies of Heavy Metal Ions by

Crown Polythioethers and Related Macrocyclic Ligands”; UTC Direct and Indirect Costs: $50,000/three years (9-01-03 to 8-31-06).

21. National Science Foundation, MRI Program. "A 400 MHz FT NMR Spectrometer for Research”; UTC Direct and Indirect Costs: $279,999.00/two years (9-1-04 to 8-31-06). 20. Tennessee Water Resource Research Council, “Removal of Toxic Heavy Metals from Wastewater Effluents”; UTC Direct Costs: $13,415/one year (03-01-04 to 02-28-05). 19. The Camille and Henry Dreyfus Foundation; Scholar/Fellow Award for Undergraduate Institutions. "The Development of Polythioether Ligands as Selective Chelators for Heavy Metal Ions"; $85,000/two years. (9-1-2001 to 8-31-2003). 18. The Camille and Henry Dreyfus Foundation, Jean Dreyfus Boissevan Undergraduate Research Scholarship For Excellence in Chemistry; $5500/two years (5-1-01 to 8-31-03). 17. American Chemical Society, Petroleum Research Fund. "Platinum Group Metal Complexes with Crown Thioether Ligands" UTC Direct Costs: $30,000/ two years (8-31-99 to 8-31-2002). 16. DAAD (Deutscher Akademischer Austausch Dienst) Fellowship; “The Development of Crown

Thioether Platinum and Palladium Chain Termini for Molecular Wires”; $1800/one month (2-28-01 to 3-28-01).

15. American Chemical Society, The Petroleum Research Fund, ACS-PRF Summer Faculty Research

Fellowship; " Platinum Group Metal Complexes with Crown Thioether Ligands "; $6,500/one year (5-1-00 to 7-31-00).

14. Research Corporation; Cottrell College Science Award; "Mixed Sandwich Organometallic Complexes Containing Crown Thioether and Mixed Oxa-Thia Ligands"; $25,000.00/two years (7-1-97 to 6-30-99). 13. The Camille and Henry Dreyfus Foundation Special Grant Program in the Chemical Sciences'; "Establishment of an Area Center for Nuclear Magnetic Resonance in Undergraduate Instruction at UTC";


Total Requested and Matching Costs: $30,000/one year (4-1-98 to 3-31-99). 12. Tennessee Water Resources Center. "Removal of Heavy Metal Ions from Wastewater Effluents Using Novel Polythioethers"; $11,329.00/one year (7-1-95 to 6-30-96). 11. The Camille and Henry Dreyfus Foundation; Scholar/Fellow Award for Undergraduate Institutions. "Polynuclear Transition Metal Complexes Containing Macrocyclic Thioether Ligands"; $65,000/two years. (8-25-93 to 8-25-95).

10. National Science Foundation, Instrumentation for Laboratory Instruction Program.

"A 200 MHz FT NMR for Undergraduate Instruction and Research". 1993. Total Requested and Matching Costs: $167,000.00. 9. National Science Foundation, Research at Undergraduate Institutions Programs. "Transition Metal Complexes with Crown Thioether Ligands"; $103,166.00/ three years. (8-1-91 to 7-31-94). 8. American Chemical Society, Petroleum Research Fund. "Transition Metal Complexes with Thioether Ligands" UTC Direct Costs: $20,000/ two years (5-1-91 to 8-31-93).

7. National Science Foundation, Research Opportunity Award; to work with Professor John Gladysz at the

Department of Chemistry at the University of Utah.; $25,000/one year. (9-1-92 to 8-1-93) 6. American Chemical Society, The Petroleum Research Fund, ACS-PRF Summer Faculty Research Fellowship; "Transition Metal Complexes with Mesocyclic Thioethers"; $5,000/one years (5-1-92 to 7-31-92).

5. National Science Foundation, Instrumentation for Laboratory Instruction Program. "An Automated

Polarimeter for Undergraduate Instruction". 1991. Total Requested and Matching Costs: $19,966.00. 4. Southern Regional Educational Board. "Use of X-ray Diffractometer at Georgia Tech" ; $750/ one year (1-1-91-to 5-1-91). 3. Research Corporation, Cottrell College Science Grant Program, Grant Number C-2396. "Transition Metal Complexes with Mesocyclic Thioethers"; $5600/one year (6-1-88 to 6-1-89). 2. National Institutes of Health, AREA (Academic Research Enhancement Award) Grant No. 1 R15 GM 40129- 01; "Chelation of Toxic Metal Ions by Cyclic Polythioethers"; $57,580/two years (5-1-88 to 4-30-90). 1. American Chemical Society, The Petroleum Research Fund, Type B, PRF # 19797-B3; "Transition Metal Complexes with Mesocyclic Thioethers"; $20,000/two years (6-1-88 to 8-31-90).

Internal 30. Several other Internal Grants 29. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Synthesis of a Molecular Nanowagon" $6,500/one year, (6-1-04 to 12-31-04). 28. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Trapping QuickSilver" $6,500/one year, (6-1-03 to 12-31-03). 27. UC FDN Faculty Research Grant, "The Development of New Materials for the Removal of Toxic Heavy Metal Ions From Wastewater Effluents", $3000.00/one year (01-01-03 through 12-31-03). 26. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Heavy Metal Complexes" $4,000/one year, (6-1-02 to 12-31-02). 25. UTC Wheeler Odor Center, “Synthesis of Fragrance Molecules with a Defined Three Dimensional Structure”


and “Enhanced Binding of Odorous Molecules to Metal Centers Through the Use of Extended Polypyridine Systems”; $30,000.00 for three years, joint project with Kyle Knight, (07-01-02 – 6-30-05). 24. The University of Tennessee at Chattanooga, Instructional Excellence Award; "Chemical Structures in 3-D", $899.00/one year (01-01-02 through 12-31-02). 23. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "The Preparation of a Nanocube" $4,000/one year, (6-1-00 to 12-31-00). 22. UTC Wheeler Odor Center, "The Development of Structure-Odor Relationships using Nuclear Magnetic Resonance"; $45,000.00/three years (7-1-97-6-30-2000). 21. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "The Study of Odorous Molecules Using an NMR-active Binding Site" $4,100/one year, (6-1-99 to 12-31-99). 20. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Chiral Phosphine Complexes as Models for Odor Recognition"; $4,100/one year (6-1-98 to 12-31-98). 19. The University of Tennessee at Chattanooga, Group Development Grant; "Chemistry Research Seminars as Part of the Summer Undergraduate Research Program; $1,000/one year (6-1-97- 9-1-97). 18. The University of Tennessee at Chattanooga, Instructional Excellence Award; ""Improvements in Instruction Using Computer Assisted Chemistry (CAChe)"; $1,000/one year (9-1-97 - 6-30-98). 17. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; Chiral Recognition by Platinum- Thioether Fragments: Models for the Anti-Tumor Compound Cisplatin ? $4,100/one year (6-1-97 to 12-31- 97). 16. The University of Tennessee at Chattanooga, UC Foundation Faculty Research Grant; "Removal of Heavy Metal Ions From Wastewater Effluents Using Novel Sulfur Compounds"; $3,000/one year (9-1-97-8-31-98). 15. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; Removal of Heavy Metal Ions from Waste Water Effluents Using Thioethers; $4,100/one year (6-1-96 to 12-31-96). 14. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Analysis of Heavy Metal Complexes Using Nuclear Magnetic Resonance"; $4,100/one year (5-1-95 to 12-31-95). 13. The University of Tennessee at Chattanooga, University of Chattanooga Foundation, Summer Faculty Research Grant; "A Study of Model Compounds for the Anti-Tumor Drug Cisplatin Using Magnetic Resonance"; $5000.00 (5-1-95 - 8-31-95). 12. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; " Half-Sandwich Organometallic Complexes Containing Crown Thioether Ligands"; $4,100/one year (5-1-94 to 8-31-94). 11. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "The Preparation of Unusual Metal Oxidation States Using Crown Thioethers"; $3350/one year (5-1-92 to 8-31-92). 10. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Hormone-Bound Thioether Ligands as Anti-Tumor Agents"; $3250/one year (5-1-91 to 8-31-91). 9. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Early Transition Metal Complexes with Thioethers"; $3250/one year (5-1-90 to 8-31-90). 8. University of Chattanooga Foundation Summer Fellowship; "Heavy Metal Complexation Studies of Thioethers "; $4,000/one year (5-1-90 to 8-31-90). 7. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Early Transition Metal Complexes with Thioethers" ; $3000/one year (5-1-89 to 8-31-89).


6. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Transition Metal Complexes with Thioethers"; $3000/one year (5-1-88 to 8-31-88). 5. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Transition Metal Complexes with Macrocyclic Thioethers"; $2500/one year (5-1-87 to 8-31-87). 4. The University of Tennessee at Chattanooga, Grote-Chemistry Fund; "Transition Metal Complexes Containing Two Novel Macrocyclic Thioethers"; $2500/one year (5-1-86 to 8-31-86). 3. The University of Tennessee at Chattanooga, University of Chattanooga Foundation, Summer Faculty Research Grant; "Metal Compounds Containing Organic Ring Structures of Varying Size"; $4000.00 (5-1-86-8-31-86). 2. The University of Tennessee at Chattanooga, University of Chattanooga Foundation, Faculty Research Grant; "Transition Metal Complexes Containing Two Open Thioethers"; $2007.80 (1-1-85-12-31-85). 1. The University of Tennessee at Chattanooga, University of Chattanooga Foundation, Faculty Research Grant; "The Synthesis of cis- Trithiacyclononatriene via a Metal Assisted Reaction"; $2000.00 (1-1-81-12-31-81).

Current External Support 1. Petroleum Research Fund, Type B Proposal, "Self-Assembly of Molecular Squares From Platinum Group Metal Complexes with Thiacrowns and Related Ligands"; UTC Direct and Indirect Costs: $55,000/three years (07-01-07 to 8-31-10).

2. National Science Foundation, RUI Program. "Two- and Three-Dimensional Coordination Polymers Self-Assembled from Platinum Group Metal Complexes”; UTC Direct and Indirect Costs: $210,000.00/threeyears (8-01-09 to 7-31-12). 3. National Science Foundation, MRI Program. “"Acquisition of a Benchtop Single Crystal X-ray Diffractometer for the University of Tennessee at Chattanooga"; UTC Direct and Indirect Costs: $210,000/three years (5-1-10 to 4-30-13).

Documents

Gregory J. Grant · Biographical Sketch, 1/29/13 Page 1 Gregory J. Grant Department of Chemistry The University of Tennessee at Chattanooga Chattanooga, TN 37403 423-425-4143 Awards