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LITHOGEOCHEMICAL DATABASE FOR THE AUCOIN GOLD PROSPECT, CENTRAL LABRADOR (NTS 13N/6 MAP AREA) H.A.I. Sandeman Open File 013N/06/0143 St. John’s, Newfoundland March, 2015

Government of Newfoundland and Labrador ......1993: U-Pb geochronology and geochemical variation within two Proterozoic mafic dyke swarms, Labrador. Canadian Journal of Earth Sciences,

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  • LITHOGEOCHEMICAL DATABASE FOR

    THE AUCOIN GOLD PROSPECT, CENTRAL

    LABRADOR (NTS 13N/6 MAP AREA)

    H.A.I. Sandeman

    Open File 013N/06/0143

    St. John’s, Newfoundland

    March, 2015

  • NOTE

    Open File reports and maps issued by the Geological Survey Division of the Newfoundland and Labrador

    Department of Natural Resources are made available for public use. They have not been formally edited

    or peer reviewed, and are based upon preliminary data and evaluation.

    The purchaser agrees not to provide a digital reproduction or copy of this product to a third party.

    Derivative products should acknowledge the source of the data.

    DISCLAIMER

    The Geological Survey, a division of the Department of Natural Resources (the “authors and publish-

    ers”), retains the sole right to the original data and information found in any product produced. The

    authors and publishers assume no legal liability or responsibility for any alterations, changes or misrep-

    resentations made by third parties with respect to these products or the original data. Furthermore, the

    Geological Survey assumes no liability with respect to digital reproductions or copies of original prod-

    ucts or for derivative products made by third parties. Please consult with the Geological Survey in order

    to ensure originality and correctness of data and/or products.

    Recommended citation:Sandeman, H.A.I.

    2015: Lithogeochemical database for the Aucoin gold prospect, central Labrador (NTS 13N/6 map

    area). Government of Newfoundland and Labrador, Department of Natural Resources, Geological

    Survey, Open File 013N/06/0143, 89 pages.

  • LITHOGEOCHEMICAL DATABASE FOR

    THE AUCOIN GOLD PROSPECT, CENTRAL

    LABRADOR (NTS 13N/6 MAP AREA)

    H.A.I. Sandeman

    Open File 013N/06/0143

    St. John’s, Newfoundland

    March, 2015

  • CONTENTS

    Page

    INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    NOTES ON DATABASE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    ACKNOWLEDGMENTS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    APPENDIX 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    APPENDIX 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    APPENDIX 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    APPENDIX 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    . . . . . . . 1

    . . . . . . . 2

    . . . . . . . 3

    . . . . . . . 3

    . . . . . . . 4

    . . . . . . . 12

    . . . . . . . 19

    . . . . . . . 26

    i

  • INTRODUCTION

    The Aucoin gold prospect database

    presents lithogeochemical data for a suite

    of rock samples collected from the imme-

    diate vicinity of the Aucoin prospect in the

    NTS 13N/6 map area of central Labrador

    (Figure 1). The rock samples include ten

    collected by Andrew Kerr (GSNL) in the

    summer of 2009 and twenty seven collect-

    ed by the author in the summer of 2010, as

    well as five samples of previously unana-

    lyzed drillcore by Ascot Resources Ltd.

    (Lehtinen and Weber, 1996). The database

    also includes two duplicate analyses

    (HS10-180A and AK09-127B) and partial

    analyses of 8 different international refer-

    ence materials (AGV-1, BS-1, CH-2,

    QLO-1, SDC-1, SU-1A, SY-4 and WGB-

    1). This open-file release incorporates data

    discussed in Sandeman and McNicoll

    (2015).

    The Aucoin gold prospect is located in

    a remote part of central Labrador, approx-

    imately 75 km west of the community of Hopedale. It is situated in the west-central part of NTS

    13N/6 map area and is only accessed through helicopter or fixed-wing air transport.

    Mineralization at Aucoin is spatially associated with a northwest–southeast-trending, curvipla-

    nar shear zone (the Aucoin shear zone) characterized by at least 2 generations of quartz-veins and

    locally strong sericite+carbonate+chlorite alteration. The shear zone crosscuts late Neoarchean

    (ca. 2567 Ma) clinopyroxene+hornblende+ilmenite-magnetite syenite, monzodiorite and monzo-grabbro as well as thin, vertical diabase dykes of presumed Paleoproterozoic age (Cadman et al.,1993). The mineralized zone consists of a network of typically thin (≤10 cm), anastomosing, dis-

    continuous and locally sinusoidal quartz-veins containing local concentrations of pyrite+chal-

    copyrite±galena and accompanied by strong wall rock sericitization, carbonatization and also

    chloritization, depending upon the host lithology. Gold is accompanied by elevated Ag and Te and

    locally, Pb. Gold mineralization is Paleoproterozoic (ca. 1870 Ma) on the basis of 40Ar-39Ar ther-mochronology of a phengite grain-separate concentrate obtained from an altered syenite in the

    immediate structural hangingwall of the Aucoin shear zone. More detailed background informa-

    tion on the setting and origin of the Aucoin gold prospect can be found in the references given

    below, in particular Sandeman and Rafuse (2011) and Sandeman and McNicoll (2015).

    1

    Figure 1. Location of survey area.

  • NOTES ON THE DATABASE

    All location data are presented in Universal Transverse Mercator (UTM), eastings and nor-

    things (Zone 21; NAD27) format. These were determined by a Garmin GPS in conjunction with

    topographic maps and satellite imagery. Samples are prefixed by the collecting geologists’ initials

    where those samples containing the letters AK were collected by Andrew Kerr, and those with the

    letters HS were collected by Hamish Sandeman. The data table (Appendix 1) contains the whole-

    rock geochemical analytical data for the applicable samples along with 2 duplicate analyses

    (Appendix 2) and a number of reference materials utilized for the different analytical methods

    employed (Appendix 3). Major elements are recorded as weight percentages of their oxides. The

    minor-, trace- and rare-earth elemental compositions are given in ppm whereas gold is reported in

    ppb. Where the oxidation state was determined via titration, iron is presented as FeO and Fe2O3,otherwise it is represented as Fe2O3

    T (total: all iron is represented as Fe3+). Volatiles are represent-

    ed as LOI (loss-on-ignition) determined by gravimetric analysis. Instrumental neutron activation

    analyses (INAA) for As, Au, Br, Na (%), Sb and Se were obtained at Becquerel Laboratories using

    their standard techniques (http://www.becquerellabs.com/). All other analyses were completed at

    the Geological Survey’s Geochemical Laboratory. Analytical methods for LOI, FeO, Ag, Be, Cd,

    Co, Cr, Cu, Fe (%), Li, Mn (ppm), Mo, Ni, P (ppm), Pb, Sc, Ti (ppm), V and Zn are after Finch

    (1998) but use a 4-acid digestion of HF-HClO4-HCl plus HNO3 rather than the 3-acid digestion.

    The major and some trace elements (Ba and Zr) were analyzed by ICP-OES (inductively coupled

    plasma - optical emission spectrometry) following lithium borate fusion. The sample rock pow-

    ders were fused at 1000°C for 30 minutes in a graphite crucible using a blend of different lithium

    borates (C. Finch, personal communication, 2014). The molten fusion bead was poured directly

    into a 10% solution of nitric acid and stirred for ~15 minutes until dissolution. The solution was

    then topped-up to a final volume of 100 ml. An aliquot of this solution was measured directly by

    a Thermo Instruments iCap 6500 ICP-OES for major-element and Ba and Zr trace-element abun-

    dances. This original analyte solution was further diluted 20 times, and topped-up to volume with

    a 2% solution of nitric acid and analyzed by a Thermo Instruments X-Series II, Inductively

    Coupled Plasma Mass Spectrometer (ICP-MS) for most other trace- and rare-earth elements.

    Where an element was analyzed using multiple methods, the value determined by the method

    that appears most reliable is presented. Precision and accuracy were evaluated through examina-

    tion of duplicate sample analyses (Appendix 2) and standard reference material (Appendix 3)

    obtained at the same time as the unknowns. For elements not determined, the number -99 has been

    placed in the database, whereas elemental analyses that are below detection limits are presented

    as the estimated detection limit (e.g., 0.1, 1, 5). Please note that some elements may have differ-ing detection limits depending upon interference from other elements.

    External data from eight assessment files have been compiled and are presented in Appendix

    4. These data are from samples analyzed by external laboratories with different digestion methods

    and analytical techniques and may not have been rigorously evaluated for precision and accuracy.

    Refer to the assessment files (see Geofiles column) for the methodology and upper and lowerdetection limits.

    2

  • ACKNOWLEDGMENTS

    Chris Finch and the staff at the Geological Survey of Newfoundland, Howley Building

    Geochemical Laboratories are warmly thanked for their efforts in obtaining the high-quality lith-

    ogeochemical data. Pauline Honarvar assisted greatly with the formatting and cleaning of the data-

    base. The staff of the Geoscience Publications and Information Section are thanked for their

    unstinting efforts.

    REFERENCES

    Cadman, A.C., Heaman, L., Tarney, J., Wardle, R. and Krogh, T.E.

    1993: U-Pb geochronology and geochemical variation within two Proterozoic mafic dyke

    swarms, Labrador. Canadian Journal of Earth Sciences, Volume 30, pages 1490-1504.

    Finch, C.J.

    1998: Inductively coupled plasma-emission spectrometry (ICP-ES) at the Geochemical

    Laboratory. In Current Research. Newfoundland Department of Mines and Energy, Report 98-1, pages 179-193.

    Lehtinen, J. and Weber, J.S.

    1996: Geological, geophysical, geochemical and diamond drilling report on the Aucoin show-

    ing Ascot Property, Labrador (NTS 13N/05, 13N/06, mineral license 3895M, 3896M &

    4663M); NFLD 013N/06/0113.

    Sandeman, H.A. and Rafuse, H.

    2011: The geological setting of Au–Ag–Te mineralization at the Aucoin prospect (NTS 13N/6)

    Hopedale block, Labrador. In Current Research. Newfoundland and Labrador Department ofNatural Resources, Geological Survey, Report 11-1, pages 167-183.

    Sandeman, H.A. and McNicoll, V.J.

    2015: Age and petrochemistry of rocks from the Aucoin gold prospect (NTS 13N/6) Hopedale

    block, Labrador: Late Archean, alkali monzodiorite-syenite hosts Proterozoic orogenic

    Au–Ag–Te mineralization. In Current Research. Newfoundland and Labrador Department ofNatural Resources, Geological Survey, Report 15-1, pages 85-103.

    3

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    92.

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    2748

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    D27

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