Global Automotive Declarable Substance List (GADSL) · 2015-09-17 · Definitions Substances Chemical elements or chemical compounds as parts of materials or preparations Preparations

2010 GADSL Version 1.0 Page 1 of 42

Global Automotive Declarable Substance List (GADSL)

1. GADSL Objectives Major objectives of automotive product development include continuous improvements in quality, safety, and the reduction of environmental impact throughout vehicle life cycle. As much as possible, these objectives should be achieved in an efficient, cost effective way to optimize consumer value. A large number of construction, operational and processing materials are used in the automotive manufacturing chain, and their selection and proper use can have significant impact on these objectives. To meet these objectives, an ongoing dialogue and information flow within the global automotive supply chain, including automobile manufacturers, tier suppliers and material suppliers has been established, called the Global Automotive Stakeholder Group (GASG). Early information and dialogue up and down the supply chain will help facilitate compliance with current and future regulations, as well as take into account customer requirements to ensure sustainable products. Optimized handling of relevant information flow can help automobile manufacturers meet existing and projected reporting requirements in a consistent, understandable and efficient way. The GASG organization consists of three regions, Americas, Europe/Africa/Middle East, and Asia/Pacific. Regional membership and participation is open to all stakeholders in the automotive supply chain. Each of the three regions nominates six members to sit on the governing body of the GASG, called the Steering Committee (SC). The SC meets annually or more at its prerogative to decide on the GADSL and to provide a transparent and open process for decision making. The product of the GASG dialogue is the Global Automotive Declarable Substance List (GADSL). The GADSL covers declaration of certain information about substances relevant to parts and materials supplied by the supply chain to automobile manufacturers. The information is applicable to the use of these parts or materials in the production of a vehicle up to its usage and relevant to the vehicle’s re-use or waste disposal. Revision Date Revision Comment 2010-02-01 2010 update of the substance list according to agreed dossiers.

2010 changes are highlighted in gray.


The intent of GADSL is to become the company specific list for declaration of parts composition within the automotive industry. It provides a definitive list of substances requiring declaration with the target to minimize individual requirements and ensure cost-effective management of declaration practice along the complex supply chain. The scope is to cover declarable substances in the flow of information relevant to parts and materials supplied throughout the automotive value chain, from production to the end of life phase. The GADSL only covers substances that are expected to be present in a material or part that remains in the vehicle or part at point of sale. This approach is a voluntary industry initiative designed to ensure integrated, responsible and sustainable product development by automobile manufacturers and their supply chain. Its purpose is to minimize individual requirements and ensure cost-effective management of declaration practice along the large and complex global supply chain. 2. Application of the GADSL The use of certain substances in vehicle parts may be a risk factor to human health and the environment. Information exchange along the vehicle supply chain helps manage those potential risks while also meeting customer requirements. The GADSL is used to enhance further dialogue and cooperation along the supply chain on the benefits and potential risks of certain substances or groups of substances in a specified use within vehicle parts/materials. Declaration of a substance does not mean, however, that the substance is prohibited from being used in vehicle parts or is to be de-selected from use. Any declaration process using the GADSL must respect the framework formulated in this preface. Definitions Substances Chemical elements or chemical compounds as parts of materials or

preparations Preparations Mixtures, composed of two or more substances Materials Chemical elements, chemical compounds or preparations thereof in

finished state used to manufacture products/articles Products/articles Materials, which have been transformed during production to take a

specific shape, surface or form, which has a greater influence on their function than their chemical composition does.

Parts Single components made up of one or more homogenous

material(s)


Criteria for Declarable Substances The decision to list a substance on the GADSL is based on the following criteria:

• The substance should be expected to be present in a material or part in the vehicle. Either of the following conditions should apply: � The substance is regulated1, or is projected to be regulated by a governmental

agency or authority, or � It is demonstrated, by testing under OECD (Organization for Economic

Cooperation & Development) guidelines for testing chemicals, conducted under Good Laboratory Practice (according to the OECD Principles on Good Laboratory Practice as revised in 1997), that the substance may be associated with a significant hazard to human health and/or the environment, and its presence in a material or part in a vehicle may create a significant risk to human health and/or the environment. Other scientifically valid methodology, based on the weight of evidence, may also be considered.

• A substance that causes a functional problem in vehicle design may be included if its presence in a vehicle part exceeds a level shown to be problematic by an international industry standard test2.

• Reportable threshold levels will be based on the lowest level required by regulation or reasonably required by scientific evaluation.

Declarable Substance Classification A reportable substance when present in a material or part in a vehicle will be shown on the GADSL with a classification of “P” or “D”, defined as follows: Depending on its specific application, the same substance could be classified “P” in one end use, and “D” in another end use. When this is the case, both classifications for the substance will be shown on the GADSL with examples under the application column. Declaration thresholds are defined by specific application of the substance in automotive parts. Any reportable substance below the declaration level does not have to be reported. These levels, unless otherwise indicated, are 0.1 g/100g (weight %) of non-separable, homogeneous materials, not on the total content in the component or assembly. P = Prohibited A substance designated “P” is either prohibited by regulation for use in certain applications or may not exceed regulated threshold limits.

1 Due to potential effects on human health or the environment related to the Automotive industry

2 Examples would be emissions, like odor testing or fogging. Currently there are numerous tests.

Development of a quantitative industry standard test would reduce resource requirement and uncertainty for the supply chain.


D = Declarable A substance designated “D” must be declared if it exceeds the defined threshold limits. Reason Codes Reason codes have been developed to explain why a substance has been included in the GADSL. Each declarable substance will be listed with one of the following reason codes to facilitate dialog within the supply chain: LR = Legally Regulated A substance legally regulated because its use in a vehicle part or material poses a significant risk to health and or the environment. FA = For Assessment A substance projected to be regulated by government agencies, upon decision by the GASG Steering Committee. FI = For Information A substance tracked for information purposes only, upon decision by the GASG Steering Committee. After discussion at the GASG Steering Committee and on an exceptional basis, an automobile manufacturer may include an individual substance or family of substances on the list under this (FI) reason code. LR, FA and FI substances should not be construed to mean that the substance is prohibited from being used in a vehicle part, or is to be de-selected from use. Substance families: If all members of a substance family are “D” or “P” the entry “All members” is listed after the family name. The entry “substance name, selected” means: This substance family refers to a limited list of single substances, which meet the criteria for being declarable or prohibited. In certain cases substance families have the classification "D, except". This means that all substances within that family are declarable except those that are listed directly below labeled with "P" (e.g. Polybrominated Diphenyl Ethers). CAS numbers for individual substances of a chemical family or group on the GADSL are listed in the Reference List which is part of GADSL. This list is available on the GADSL website. A 2006 priority of the GASG will be to review individual substances identified by CAS numbers on the reference list against GADSL criteria. The sole purpose of this reference list is to facilitate communication and declaration relating to the GADSL within the automotive supply chain to the automobile manufacturers.


3. GADSL Validity The valid GADSL will be the current English version on http://www.gadsl.org. The content of the GADSL and its application does not relieve parties in the supply chain from obligation to comply with all existing relevant regional and national regulations in their business to business dealings. 4. Change Management Process The GADSL will be updated and published annually in February according to improved knowledge in order to achieve a high standard of product safety and environment protection. At the latest 12 months after the publication date, any declaration should be performed according to this updated version. Requested changes to the GADSL must be received by July 15 each year in order to be considered for the next version. For this input, comments and questions please contact one of the persons listed on the GADSL website. 5. Listed substances The table on the following pages shows the substances that are covered by the GADSL. Any substance name that has "all members" after the name is to be considered as a group name covering several individual substances. Every attempt has been made to include a complete list of the members of the family. For a listing of those potentially individual relevant substances, please refer to the "Reference List" that can be found on the GADSL website. Any substance where the substance name is followed by the word “selected” means that the list in the reference list will not be a complete listing but will show only those members that are to be reported, whether they are classified as “P” or “D.” 6. Use of GADSL GADSL was created by GASG. GADSL is intended to be a public document, freely available to third parties. GADSL may be duplicated or reproduced without the express permission of GASG. Companies and trade associations along the automotive value chain are free to communicate GADSL and any updates thereto. GASG and its members assume no liability whatsoever for GADSL, its content or any reliance on GADSL. Please note that this document is constantly evolving and is updated every year in February.


7. Abbreviations Used EU-D European Union Directive including amendment and adaptation

directives: EU-D 76/769/EEC: Directive on the approximation of the laws, regulations and administrative provisions of the Member States relating to restrictions on the marketing and use of certain dangerous substances and preparations EU-D 2000/53/EC: Directive on end-of life vehicles

EU-R EU Regulation including amendment and adaptation regulations: EU-R 2009/1005: Regulation of the European Parliament and of the Council of 16 September 2009 on substances that deplete the ozone layer (Text with EEA relevance) EU-R 1272/2008/EEC: Directive on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labeling of preparations made from dangerous substances

US-EPA US-EPA Regulations on Class 1 and Class 2 Ozone Depleting

Substances (ODS) Under section 602 of the Clean Air Act, published on January 19, 1996 in the U.S. Federal Register

2009 GADSL Version 1.0 Only valid with the GADSL-preface

Page 7 of 42

Substance

CAS-No. Classi-fication

Reason code

Application

Source (Legal

requirements regulations)

Generic examples

Threshold (0,1% if not

stated otherwise)

1 Acetaldehyde 75-07-0 D FI EU-R

1272/2008/EEC

Emitted substance from polymer components

2 Acetamide 60-35-5 D FI EU-R

1272/2008/EEC

Solvent additive, stabilizer for

softening agents

3 Acetamide, N-Methyl- 79-16-3 D FI

Classified as toxic to reproduction

class 2 according to EU-R 1272/2008

Present in capacitors, used in automobile

parts

4 Acetonitrile 75-05-8 D FI EU-R

1272/2008/EEC Component in high-capacity capacitors

5 Acrylamide 79-06-1 D FI EU-R

1272/2008/EEC

Production of polyacrylamide

(residual monomer)

6 Acrylonitrile 107-13-1 D FI EU-R

1272/2008/EEC

Production of plastics,

resins and rubbers e.g. ABS (residual

monomer)

7 Amines, carcinogenic, which are formed from Azo-dyes, selected

P LR EU-D 2002/61/EC

In dyes for textiles etc.

30 ppm


Page 8 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

8 Amines, which can form carcinogenic Nitrosamines, selected

D FI

Legally regulated according to

German TRGS 615. Limit for all

secondary Amines in volatile corrosion

inhibitors, which can form

carcinogenic Nitrosamines.

Volatile corrosion inhibitors include

papers, plastic films and oils.

Polyurethane foams, corrosion inhibitors, lubricants, rubber,

colorants, herbicides

9 4-Aminobiphenyl and its salts, all members

P LR EU-R

1272/2008/EEC EU-D 76/769/EEC

0,01%

10 Ammonium Perchlorate 7790-98-9 D FI Pyrotechnical

compound Pyrotechnical compound

11 Aniline and its salts, all members D FI EU-R

1272/2008/EEC

Pigments, sulfonamides, isocyanate - plastics

12 Antimonytrioxide (Diantimonytrioxide)

1309-64-4 D FI EU-R

1272/2008/EEC

Flame retardant for plastics and rubber/latex, opacifier, friction material component


Page 9 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

13

9,10-Anthracenedione, 1-[(5,7-dichloro-1,9-dihydro-2-methyl-9-oxopyrazolo[5,1-b]quinazolin-3-yl)azo]- (Pigment Red 251)

74336-60-0 D FI

Canada Gazette Vol. 140, No. 49 - December 9, 2006

(Canadian Challenge). The

Canadian Challenge is

regulated under the Part 5, Section 71,

of the Canadian Environmental Protection Ac t, 1999 (CEPA,

1999).

0.1%, Report any

intentionally added content.

No testing required.

14 Aromatic amines, selected D FI

Impurities in textile and leather paints, antioxidants in lubricants, rubber/latex, plastics

0,1%

15 Arsenic and its compounds, all members

D FA EU-R

1272/2008/EEC EU-D 76/769/EEC

Paints, smelted materials, biocides (including wood treatment), leather and textile finishes, glasses, pyrotechnic objects, metal finishes, electronics

0.01% (unless present in

metals & alloys, then the

declaration limit is 0,05%).


Page 10 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

16 Asbestos Fibres, all members P LR

EU-D 76/769/EEC Definition of

asbestos fiber for counting purpose by OSHA in 1992;

Particle with a length >5 µm, a

diameter of <3µm and aspect ratio

(length:width)>3：1

Friction pads, gaskets, insulations

Any intentionally

added content

17 Asbestos Minerals, all members D FI

Potential to form Asbestos fibres

(see entry Asbestos fibers)

Friction pads, gaskets, insulations

Any intentionally

added content

18 Barium compounds (organic or water soluble), selected

D FI EU-R

1272/2008/EEC

Colour pigments, stabilizers for PVC, lubricant additives

1%

19 Benzidine and its salts, all members P LR

EU-R 1272/2008/EEC

EU-D 76/769/EEC & Canadian Toxic

Substances Regulation 2005

0.01%, see details for Canada specific

20 Benzene 71-43-2 P LR

All applications except those listed below

EU-D 76/769/EEC Fuel constituent, raw material/contaminant in other chemicals

0,01%

20.1 D FA Additive in

Fuels 0,1%


Page 11 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

21

Benzenamine, N-phenyl-, reaction products with styrene and 2,4,4-trimethylpentene

68921-45-9

D FI






1999).

0.1%, Report any



22 1,4-Benzenediamine, N,N’ -mixed phenyl and tolyl derivs

68953-84-4 D FI

The Canadian Challenge is

regulated under the Part 7, Division 3, of the Canadian Environmental Protection Ac t,

1999 (CEPA, 1999)

0.1%, Report any



23 2-Benzothiazolesulphenamide, N, N-dicyclohexyl-

4979-32-2 D FI

Japan (Chemical Substances control

Law) Type I Monitoring Chemical Substance

Any intentionally

added content must be reported

24 Beryllium and its compounds, all members

D FI EU-R

1272/2008/EEC

Electric contacts, relays and switches; electronics


Page 12 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

25 Biocidal coatings / biocidal additives, selected

D FA EU-D

2032/2002/EEC

Biocidal and biostatic treatments of polymers, textiles, and other components susceptible to microbiological attack (e.g. mobile air conditioning systems)

Any intentionally

added content

26 Bis(chloromethyl) ether (BCME) 542-88-1 P LR

Prohibition of Certain Toxic Substances

Regulations, 2005 (SOR/SOR/2005-41. Published in Canada Gazette

Part II, 2006-11-29 Vol. 140, No. 24

surface treatment of vulcanized rubber to increase adhesion, and in the manufacture of flame-retardant fabrics (ATSDR 1989).

Any intentionally

added content

27 Butadiene , 1,3- 106-99-0 D FI EU-R

1272/2008/EEC

Manufacturing of synthetic rubber for tires, as homopolymerisate (BR), as copolymerisate with Styrene (SBR) or Acrylonitrile (NR), starting product of Sulfolane, Chloroprene, Hexadiamine, softeners, Tetrahydrophthalic acid anhydride, residual monomer in ABS


Page 13 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

28 Cadmium and its compounds, all members

P LR

All applications except those listed below.

EU-D 2000/53/EEC EU-R

1272/2008/EEC EU-D 76/769/EEC

Surface protection of metals, stabilizers in polymers, pigments, in paints and plastics, electronics

0,01%, Any intentionally

added content must be reported.

28.1 D LR

Valid exemptions according to current ELV

Annex II

EU-D 2008/689

29 Chlorinated hydrocarbons, selected D, except FA EU-R

1272/2008/EEC Leather, paints, rubbers, adhesives

1,1,1 Trichloroethane 71-55-6 P LR EU-D 94/60

Tetrachloromethane (Tetrachlorocarbon)

56-23-5 P LR Montreal Protocol

30 Chlorinated or Brominated Dioxins or Furans, all members

P LR ChemVerbotsV Impurities in products Content above

10 ppb

31

Chlorinated Paraffins, Short & Medium Chain Length (SCCP, MCCP), all members Note that the use of specific CAS numbers for these substances differs throughout the world. Example CAS numbers are provided below; however, other CAS numbers may be used that are not specific to chain length. Therefore, please consult your MSDS and supplier to determine product-specific chain length.

D/P Flame retarding substances

1%

31.1 Short Chained Chlorinated paraffines

(SCCP) P LR EU-D 76/769/EEC

31.2 Medium Chained Chlorinated

paraffines (MCCP) D FI UK DEFRA


Page 14 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

32 Chloroaniline 106-47-8 D FI EU-R

1272/2008/EEC

Hardener or cross linking agent for polymers and epoxy resins

33 Chloromethyl methyl ether (CMME) 107-30-2 P LR



Part II, 2006-11-29 Vol. 140, No. 25

surface treatment of vulcanized rubber to increase adhesion, and in the manufacture of flame-retardant fabrics (ATSDR 1989).

Any intentionally

added content

34 Chloro-fluoro-carbons (CFC) and other Ozone depleting substances, all members

P LR EU-R 2009/1005, EPA ODP class 1

Coolants, propellants, cleaners,solvents, impregnating agents, blowing agents (PU production)

35 Chromium(VI)-salts, all members P LR


EU-R 1272/2008/EEC

EU-D 2000/53/EEC

Chromium pigments, chromated surfaces e.g. "Chromium Yellow", corrosion inhibitors, residues from dying and leather tanning.



35.1 D LR


Annex II

EU-D 2008/689


Page 15 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

36 Cobalt and its compounds, all members

D FI

Cobalt

compounds and alloys, excluding cobalt in

steels

EU-R 1272/2008/EEC

Hard metals, galvanic Zn-Co-plating, element in metals

37 Colophony (Rosin), selected D FI

ACGIH Worldwide - Documentation of the TLVs and BEIs

with other Worldwide

Occupational Exposure Values;

2003.

Solders, adhesives, sealants

38 Copper (metallic) 7440-50-8 D FI

Dispersive applications (Brake and

Friction linings)

Substance of Concern in

dispersive friction material

applications due to environmental

impact potential

Alloys, Wiring, Friction linings, Electronics

39 Cyclododecane, hexabromo- (HBCD)

25637-99-4 D FI EU-D 1907/2006

EEC Flame retardant

40 Cyclohexane 110-82-7 D FA EU Regulation

552/2009

Neoprene based adhesives. Nonwoven fabrics, tyres and sealings.


Page 16 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

41 2-Cyclohexen-1-one, 3,5,5-trimethyl- 78-59-1 D FI






1999).

0.1%, Report any



42 Cyclopentasiloxane, decamethyl- 541-02-6 D FI






1999).

0.1%, Report any




Page 17 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

43 Cyclotetrasiloxane, heptamethylphenyl-

10448-09-6 D FI






1999).

0.1%, Report any



44 Cyclotetrasiloxane, octamethyl- 556-67-2 D FI






1999).

0.1%, Report any




Page 18 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

45 Decanedioic acid, bis(1,2,2,6,6-pentamethyl-4-piperidinyl)ester

41556-26-7 D Fi

Canadian Priority List in 2008, and

Producers, importers and

related industry in Canada have to

submit information on production or import amount.

0.1%, Report any



46 Diamino-diphenyl-methane (4,4 -Diaminodi- phenylmethane)

101-77-9 P LR EU-R

1272/2008/EEC

Preliminary and intermediate product of resins, adhesives, dyes, curing agent, accelerator.

47 Dichloropropanol (1,3-Dichloro-2-propanol)

96-23-1 D FI EU-R

1272/2008/EEC

Solvent for anti-wrinkle agents and flame retardants in textiles, and in the production of epoxy resins

48 Dimethylformamide (N,N-Dimethylformamide)

68-12-2 D FI 1999/137/EC 91/689/EEC

Diorganotin compounds, Selected D FI EU-R

1272/2008/EEC Stabilizer for polymers

Dibutyltin Compounds, All members D FI REACH EU

directive 1907/2006 49

Dioctyltin Compounds, All members D FI REACH EU

directive 1907/2006


Page 19 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

50 Dodecachloropentacyclo 1, 3, 4-Metheno-1H-cyclobuta(cd)pentalene, Mirex

2385-85-5 P LR



Part II, 2006-11-29 Vol. 140, No. 24

Flame retardant in plastics, rubber, paint, paper, and

electrical goods from 1959 to 1972. Mirex was sold as a flame retardant under the

trade name Dechlorane, and

chlordecone was also known as Kepone.

Any intentionally

added content

51 Epichlorohydrin (1-Chloro-2,3-epoxy-propane)

106-89-8 D FI EU-R

1272/2008/EEC Residual monomers in epoxy resins

52 Ethanol, 2-(2-methoxyethoxy)- 111-77-3 D FI






1999)..

0.1%, Report any



53 1-ethenylpyrrolidin-2-one (2-Pyrrolidione, 1-ethenyl-)

88-12-0 D FI



1999 (CEPA, 1999)

0.1%, Report any




Page 20 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

54 Ethyl-/ Methyl-Glycols and their Acetates

D FI EU-R

1272/2008/EEC

55 Fatty acids, C6-19-branched, Zinc salts

68551-44-0 D FI

Canada Gazette Vol. 140, No. 49 - December

9, 2006 (Canadian Challenge). The

Canadian Challenge is regulated under the Part

5, Section 71, of the Canadian Environmental

Protection Ac t, 1999 (CEPA, 1999).

0.1%, Report

any intentionally

added content. No testing required.

56 Fluorotelomers, selected

Some substances

may not have

CAS#s

D FA

EPA created a Voluntary Stewardship Program to reduce facility emissions and product content of

PFOA, its higher homologues, and related

chemicals including precursors (see column B) on a global basis by 95 percent no later than year-end 2010, and to

work toward eliminating emissions and product

content of these materials by year-end 2015. In addition the

Canadian governmental agencies are also

working on a similar program which is

expected to take effect later in 2007

Present at low levels in telomeric products used as surface treatments for oil, soil, and water repellency and stain/dirt resistance for textile fabrics and carpet in the automotive sector.


Page 21 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

57 Formaldehyde 50-00-0 D FI EU-R

1272/2008/EEC

Residues and degradation products of plastics (aminoplasts, urea- and melamine resins, foam plastics, vulcanization accelerators, basis for synthetic tannins, biocides, adhesives, formed woods

Any intentionally added content of

formaldehyde

Formaldehyde in any material, which is may be emitted under reasonable and foreseeable

conditions, must be qualitatively indicated.

Impurities of

formaldehyde above 0,1 % has to

be declared.

58 2-Furancarboxaldehyde 98-01-1 D FI






1999).

0.1%, Report any



59 Halons, all members P LR EU-R 594/91/EEC Fire extinguishers


Page 22 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

60 Hexachlorobenzene 118-74-1 D FI



Part II, 2006-11-29 Vol. 140, No. 24

as a peptizing agent in the production of nitroso compounds and rubber for tires

≥ 10 ppb

60.1 P LR ≥ 20 ppb

61 Hexachloro-1,3-butadiene (HCBD) 87-68-3 P LR



Part II, 2006-11-29 Vol. 140, No. 24

Used mainly as an intermediate in the

manufacture of rubber compounds. It

is also used in the production of

lubricants

Any intentionally

added content

62 Hexachlorocyclohexane, gamma isomer, Lindane

58-89-9 D FI GefStoffV with Annex IV Nr. 5

Insecticide, substance in wood protecting compounds


Page 23 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

63 Hexanedioic acid, bis(2-ethylhexyl) ester

103-23-1 D FI






1999).

0.1%, Report any



64 Hexanoic acid, 2-ethyl- 149-57-5 D FI






1999).

0.1%, Report any




Page 24 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

65 Hydrazine 302-01-2 D FI EU-R

1272/2008/EEC

Residual monomers in plastics, pigments and adhesives, antioxidants stabilizing of Amines, Phenols, in oils, greases, natural latex; blowing agents for foamed plastics

66 Hydrobromofluorocarbons; HBFC's, all members

P LR

Montreal Protocol; EU Regulation (EU-R 2009/1005); US EPA Class I ODS

Refrigerant

67 Hydrochlorofluorocarbons; HCFC's, all members

P FA


Montreal Protocol; EU Regulation (EU-R 2009/1005); US EPA Class II ODS

Refrigerant

67.1 D LR

servicing vehicles

produced prior to December 2001 (where

legally permitted)

68 Hydrofluorocarbons; HFC's, all members

P LR


Kyoto Protocol Refrigerant

68.1 D FA All vehicle-

related refrigerants


Page 25 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

69 Lead and its compounds, all members P LR



1272/2008/EEC

Lead as component in metals and alloys: e.g. bearing metals, steel, brass, aluminium processed in automated machines. Lead compounds, e.g. lead-containing stabilizers and pigments, corrosion inhibitors etc.



69.1 D LR


Annex II

EU-D 2008/689

70 Mercury and its compounds, all members

P



1272/2008/EEC EU-D 76/769/EEC

Metallic mercury, and inorganic and organic mercury compounds used in high intensity discharge (HID) lamps, electric switches, luminescent material for instrument lighting, pyrotechnic initiators etc.



70.1 D LR


Annex II

EU-D 2008/689


Page 26 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

71 Methanol 67-56-1 D FI

Norway, Sweden (SFS 1985:840;

SFS 1986:8), Denmark, Finland

Window Washer fluid applications

72 2-Methoxyethanol 109-86-4 P LR

Prohibited as impurity in Diethylene

glycol methyl ether and in hard parts



Part II, 2006-11-29 Vol. 140, No. 24

Prohibited ≥ 0.5% w/w in Diethylene

glycol methyl ether. Any

intentionally added content in hard parts

73 Methylacrylamidomethoxy-acetate 77402-03-0 D FI EU-R

1272/2008/EEC production of polymers

74 1-methylpyrrolidin-2-one (2-Pyrrolidinone, 1-methyl )

872-50-4 D FI

EU-R 1272/2008 /EEC as toxic for

reproduction class 2.

75 Mineral Fibers (Natural or Synthetic) except Continuous Filament Fibres, all members

D FI

World Health Organization for

definition of respirable fiber,

and IARC monograph 81, 2002, for Man-Made vitreous

fibers

Friction lining, screens, re-enforcements, insulation, cables

All fibers or fibrils 5 microns

or less, in diameter, with

a length:diameter ratio equal to or

greater than 3:1

76 Monomethyldibromodiphenylmethane 99688-47-8 D FI EU Directive 76/769/EEC

Residues and decomposition products in production of polymers


Page 27 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

77 Monomethyldichlorodiphenylmethane 81161-70-8 D FI EU Directive 76/769/EEC

Residues and decomposition products in production of polymers

78 Monomethyltetrachlorodiphenylmethane

76253-60-6 D FI EU Directive 76/769/EEC

Residues and decomposition products in manufacture of polymers

79 Naphthalene 91-20-3 D FI

EU Directive 1272/2008/EEC,

carcinogen category 3. Limited

evidence of a carcinogenic effect.

Polyester coating, PVC

80 2-Naphthalenol, 1-[(4-methyl-2-nitrophenyl)azo]- (Pigment Red 3)

2425-85-6 D FI






1999).

0.1%, Report any



81 2-Naphthylamine and its salts, all members

P LR EU-R

1272/2008/EEC EU-D 76/769/EEC


0,01%


Page 28 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

82 Nickel and its compounds, all members

D FI EU-D 76/769/EEC

Welding electrodes, flame spraying, special materials, component in metals

83 Nitrites, all members D FI EU-R

1272/2008/EEC

Additives in engine coolants, vulcanising agents in rubber products, anticorrosion surface additive. Reaction product precursor for potentially carcinogenic N-nitroso- compounds

84 4-Nitrobiphenyl and its salts, all members

P LR EU-R

1272/2008/EEC EU-D 76/769/EEC


0,01%

85 Nitrocellulose 9004-70-0 D FI Pyrotechnical



Page 29 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

86 N-Nitrosamines, selected D/P FA

legally regulated according to

German TRGS 552 limit for workplace

air (value 1 µg/m3), TRGS 615 limit for volatile corrosion

inhibitors and TRGS 905

classified as carcinogenic class 1. Legally regulated

for corrosion inhibition in papers,

plastic films and oils via limiting the corresponding sec. amines to 0,5 %.

Polyurethane foams and corrosion

inhibitors

87 Nonylphenol 25154-52-3 D FI

EU Directives 1272/2008/EEC,

76/769/EEC, Toxic for reproduction-

Category 3. Possible risk of

harm to the unborn child. Possible risk of impaired fertility

Residues on metals, leather and textiles

from their processing.

88 Nonylphenol ethoxylates, all members D FI EU-D 2003/53/EC Surfactants, leather processing


Page 30 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

89 7-Oxa-3,20-diazadispiro[5.1.11.2]-heneicosan-21-one, 2,2,4,4-tetramethyl-

64338-16-5 D FI

Canadian Priority List in 2008, and

Producers, importers and

related industry in Canada have to

submit information on production or import amount.

Type 2 Monitoring Substance in Japan, that is,

persistent substance.

Producers and importers of this

substance in Japan have to report its

amount to Japanese Authority

90 Pentachlorobenzene 608-93-5 P LR



Part II, 2006-11-29 Vol. 140, No. 24

Flame retardant Any

intentionally added content

91 Pentachlorophenol (PCP) and its salts, all members

P LR EU-R

1272/2008/EEC EU-D 76/769/EEC

Wood preservative, salts used in leather treatment, stabilizer for latex


Page 31 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

92 Perchlorates, all members

D FA

California Assemby Bill No. 826 - Perchlorate

Contamination Prevention Act;

implemented July 1, 2006.

http://www.dtsc.ca.gov/HazardousWas

te/Perchlorate/

Pyrotechnical compound

93

Perfluorooctane sulfonates C8F17SO2X (X = OH, Metal salt, halide, amide, and other derivatives including polymers), all members

P LR

76/769/EEC 2006/122EEC

(Prohibited from July 1st 2008)

Surface coatings, Surfactants,

Ingredient in the textile protective

treatment. May not be placed on the

market or used as a substance or constituent of

preparations or in products or parts.


Page 32 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

94 PFOA and its salts, Perfluorooctanoic acids C8F15O2X (X = H, NH4, and Metal salts), all members

D FA

In January 2006, the EPA created a Voluntary Stewardship Program to reduce facility emissions and product content of

PFOA, its higher homologues, and related

chemicals including precursors on a global basis by 95 percent no

later than year-end 2010, and to work toward eliminating

emissions and product content of these

materials by 2015. In addition the Canadian

governmental agencies are also working on a

similar program which is expected to take effect later in 2007. Norway has recently issued a regulation for PFOA in consumer products and several US states (New Jersey, Minnesota) have

issued drinking water guidelines for PFOA.

USEPA has also established drinking water limits in the Parkersburg, WVA

vicinity . The EU has issued a directive on PFOS and has PFOA

under review.

Fluoropolymers are used to make

automotive components,

including fuel hoses, gaskets, wire

insulations, bearings. PFOA is used as a polymerization aid

and it is not expected to be present at

greater than trace levels in the

components made from fluoropolymers

0.1% by mass in components

made from fluoropolymers


Page 33 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

95 Phenol 108-95-2 D FI EU-R

1272/2008/EEC

Residual monomer in phenolic resins, epoxy resins, anti-oxidant in phenol derivatives, decomposition product in polymeric materials, wooden materials and textiles

96 Phenol, 2-(2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethlethyl)-

3846-71-7 P LR Japan (Chemical

Substances control Law)

UV Stabilizer in plastics for trim parts,

etc.

97 Phenol, 2,4,6-tris(1,1-dimethylethyl)-

732-26-3 D FI Japan (Chemical


Petrochemical products

98 Phenol, 2-(5-chloro-2H-benzotriazol-2-yl)-4,6-bis(1,1'-dimethylethyl)-

3864-99-1 D FI

Japan (Chemical Substances control

Law) Type I Monitoring Chemical Substance

Any intentionally

added content must be reported

99 Phenylendiamines and its salts, all members

D FI

EU-R 1272/2008/EEC

EU-D 76/769/EEC Japan (Chemical


Dyes, chemical intermediate,

Petrochemical additive


Page 34 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

100

Phosphonium, triphenyl(phenylmethyl)-, salt with 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[phenol] (1:1)

75768-65-9 D FI






1999).

0.1%, Report any



101 Phosphoric acid tributylester 126-73-8 D FI






1999).

0.1%, Report any



102 Phosphoric acid, tris(2-methylphenyl) ester

78-30-8 D FI

1272/2008/EWG, toxic and

dangerous for the environment

103 Phthalates, selected D FA EU-D 76/769/EEC Plasticiser


Page 35 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

104 Polyamine Curing Agents, selected D FI

Not currently regulated but

releasable hexamines are

relevant to vehicle interior air quality

105 Polybrominated biphenyls (PBB), all members

P LR EU-D 76/769/EEC

0,1%

Polybrominated diphenyl ethers (PBDE), all members

D, except FI EU-D 2003/11/EC Flame Retardant

Tetrabromodiphenylether 40088-47-9 P LR

Pentabromodiphenyl ether ('Penta') 32534-81-9 P LR

Hexabromodiphenylether 36483-60-0 P LR

Heptabromodiphenylether and 68928-80-3 P LR

106

Octabromodiphenyl ether ('Octa') 32536-52-0 P LR

107 Polybrominated Terphenyls ( PBT ), all members

D FI Flame retardants in plastics and textiles.

108 Polychlorinated Biphenyls ( PCB ), all members

P LR EU-D 76/769/EEC

Insulation fluid in electrical systems, switch boards transformers and condensers, in wood and paper impregnation, as a softening agent

0.005%

109 Polychlorinated Naphthalenes, all members

D FI Japan (Chemical


Petrochemical additive


Page 36 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

110 Polychlorinated Terphenyls ( PCT ), all members

P LR ChemVerbotsV

Insulation fluid in electrical systems, switch boards transformers and condensers, in wood and paper impregnation, as a softening agent

0,001%


Page 37 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

111.1 Polycyclic aromatic hydrocarbons (PAH; PCAH) in extender oils and extender oils in tyres, selected

D LR Extender oils and extender oils in tyres

EU-D 2005/69/ EC Extender oils and extender oils in tyres

1. Extender oils shall not be placed on the market and used for the production of tyres or parts of tyres, if they contain: — more than 1 mg/kg BaP, or — more than 10 mg/kg of the sum of all listed PAHs. These limits are regarded as kept, if thepolycyclic aromatics (PCA) extract is less than 3 % by mass, as measured by the Institute of Petroleum standard IP346: 1998 2. Furthermore, the tyres and treads for retreading manufactured after 1 January 2010 may not be placed on the market if they contain extender oils exceeding the limits indicated in paragraph 1. These limits are regarded as kept, if the vulcanised rubber compounds do not exceed the limit of 0,35 % Bay protons as measured and calculated by ISO 21461


Page 38 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

111.2 Polycyclic aromatic hydrocarbons (PAH; PCAH) in polymers, selected

D FI Polymers EU-D 2008/1272/

EC Polymers,

20 ppm for Benzo(a)pyrene and 200 ppm for the sum of 8 PAH according

to GADSL Reference list

112 Propanol, 2-methoxy- 1589-47-5 D FI



1999 (CEPA, 1999)

0.1%, Report any



113 Radioactive substances (including scrap metal contaminants)

D FI EU-D 96/29/

Euratom High intensity discharge lamps

Above Background

radiation

114 Selenium and its compounds, all members

D FI Japan (Waste Disposal and

Cleansing Law)

Photoelectronic device, Glass colorant and decolorant, Free-cutting steel, Semiconductor

115 Silica, Crystalline 14808-60-7 D FA

IARC Group 1 Carcinogen, US

National Toxicology Program Probable Human carcinogen

Any



Page 39 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

116

Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, reaction products with ammonia, octamethylcyclotetrasiloxane and silica

68937-51-9 D FI



1999 (CEPA, 1999)

0.1%, Report any



117 Siloxanes and Silicones, di-Methyl, hydrogen-terminated

70900-21-9 D FI



1999 (CEPA, 1999)

0.1%, Report any



118 Siloxanes and Silicones, Me 3,3,3-trifluoropropyl, Methyl vinyl,hydroxy-terminated

68952-02-3 D FI



1999 (CEPA, 1999)

0.1%, Report any



119 Sodium azide 26628-22-8 D FI Pyrotechnical


120 Styrene ( Vinyl benzene ) 100-42-5 D FI EU-R

1272/2008/EEC

Residual monomer in ABS-, Polystyrene-, SMC-, UPE-resin

121 Styrene oxide (Epoxy styrene) 96-09-3 D FI EU-R

1272/2008/EEC Residual monomer

122 Sulfur Hexafluoride 2551-62-4 P FA

Substance of concern due to global warming

potential

Vehicle applications (e.g. tire inflator systems)


Page 40 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

123 Tetrabromobisphenol A (TBBPA) 79-94-7 D FI EU risk

assessment Flame retardants in polymers, textiles etc.

124 Tetrachlorobenzene, all members 12408-10-5 84713-12-2

P LR



Part II, 2006-11-29 Vol. 140, No. 24

Any


125 Methane, tetrafluoro- 75-73-0 P LR

Statutory Order no. 552 of 2 July 2002

of the Danish Ministry of the Environment

pressure accumulator

126 Thallium and its compounds, all members

D FI EU-R

1272/2008/EEC Electric components, sensors

127 Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-

137-26-8 D FI Japan:(Waste Disposal and

Cleaning Law)

Vulcanization accelerator for rubber

128 Toluene 108-88-3 D FI

EU Directives 1272/2008/EEC,

76/769/EEC, Toxic for reproduction-

Category 3. Possible risk of

harm to the unborn child.

Residues in adhesives and paints.

129 o-Toluidine generating substances, selected

95-53-4 D FI EU-R 1272/2008/EEC, EU-D 76/769/EEC

1,5%

130 Tris(2-chloroethyl)phosphate 115-96-8 D FI EU-R

1272/2008/EEC Flame retardant


Page 41 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

131 Trichlorophenol and its salts, all members

D FI EU-R

1272/2008/EEC

Biocide (e.g. preservative for leather and textiles)

132 Trichloropropane ( 1,2,3 - Trichloropropane )

96-18-4 D FI EU-R

1272/2008/EEC

As solvent and as trifunctional cross-linking agent e.g. for polysulphide elastomers

133 Trimethylphosphate 512-56-1 D FI ( EU-D

76/769/EEC) Flame retardant

134 Triorganotin compounds, all members P LR


1272/2008/EEC

Biocides

135 Triphenylphosphate 115-86-6 D FI Flame retardant

under review Flame retardant

136 Tris-(1-aziridinyl) phosphine oxide 545-55-1 P LR EU-D 83/264/EEC Flame retardant

137 Tris(2,3-dibromopropyl)phosphate [TRIS]

126-72-7 P LR EU-D 79/663/EEC Flame retardant

138 Vanadium(V) oxide 1314-62-1 D FI






1999).

0.1%, Report any




Page 42 of 42

Substance


Reason code

Application

Source (Legal


Generic examples


stated otherwise)

139 Vinyl chloride 75-01-4 P LR EU-R

1272/2008/EEC Residual monomer in polymers

Threshold 5ppm vinyl

chloride monomer in materials

Documents

Global Automotive Declarable Substance List (GADSL) · 2015-09-17 · Definitions Substances Chemical elements or chemical compounds as parts of materials or preparations Preparations