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C H E M I C A L I N T E R M E D I A T E S
Chem ical Interm ediates
W ith our m arket-leading brands like Bisom er® andTRIM ET®, our chem icals range is designed around a varietyof different needs and challenges.
From resins to architectural finishes, adhesives to paints andcoatings, there is som ething for every application.
B u t w h a t th e y h a v e in c o m m o n is th e ir q u a lity .
3 | CHEM ICAL INTERM EDIATES
GEO ’s Paints & Coatings Division helps form ulators developnew products and solutions across a wide variety of industries.
W e not only deliver specialty m onom ers and polym ers on aglobal scale, but we com bine our practical capability with am ore personal level of service and attention.
C H E M I C A L I N T E R M E D I A T E S
CHEM ICAL INTERM EDIATES | 4
• H y d r o x y M e t h a c r y la t e s – HEM A, HPM A
• P o ly e t h e r M e t h a c r y la te s
• M P E G M e t h a c r y la t e s
• M o n o - fu n c t io n a l M e t h a c r y la t e s – LM A, BZM A,
• D i- fu n c t io n a l M e t h a c r y la te s – TEGDM A, PEGDM A, BDDM A
• T R IM E T ® T M E – T r im e t h y lo le t h a n e
• P o ly e t h e r b a s e d F o a m C o n t r o l A d d it iv e s
• A lly l fu n c t io n a l P o ly e t h e r s
• S p e c ia lt y P o ly e t h e r s a n d P o ly e s te r s
A m o r e p e r s o n a l a p p r o a c hfo r y o u r p o ly m e r s y n th e s is
A t G E O , w e b e lie v e a g r e a te r le v e l o f u n d e r s t a n d in gm e a n s a g r e a t e r le v e l o f s e r v ic e . T h a t ’s w h y o u rc o m p r e h e n s iv e c h e m ic a ls r a n g e is d e s ig n e d a r o u n dy o u r s p e c ifi c n e e d s a n d c h a lle n g e s , fr o m w a te rb a s e d a u to m o t iv e c o a t in g s to lo w V O C c o m p o s ite s .
O ur established processes, product innovation andagile UK and US m anufacturing locations m ean thatwe thrive in the sm all details. W ith GEO , you don’t justget m arket-leading products like Bisom er® SpecialtyM onom ers and TRIM ET® TM E. You get a closerelationship, a can-do attitude and our full attention,whatever the size of your order.
C H E M I C A L I N T E R M E D I A T E S
O u r p r o d u c t s
5 | CHEM ICAL INTERM EDIATES
A p e r s o n a ls e r v ic eO ur people are com m itted,knowledgeable andpassionate about exceedingyour expectations –because we take the tim e tounderstand your applications,we can recom m end theideal solution.
E s ta b lis h e dfa c ilitie sO ur proven processes andm anufacturing facilitiesenable us to deliver at scaleall around the world.
W hatever you need – andwherever you need it –we’re here to help.
P r a c tic a lin n o v a tio nW e’re always looking for newways to m eet your needs.
By spending tim e getting toknow your organisation, ourinnovation is always drivenby you – so new products,im provem ents and ideasdeliver real value.
O u r a p p r o a c h
C H E M I C A L I N T E R M E D I A T E S
CHEM ICAL INTERM EDIATES | 6
Chem ical Interm ediates
Product List �
Applications ��
Chem ical & Physical Properties ��
Chem ical Inventory Registrations ��
Classification & Labelling 20
Food Packaging Regulations ��
BfR Recom m endations ��
FDA �� CFR Approvals ��
Kosher / Halal Certifications 29
7 | CHEM ICAL INTERM EDIATES
Product List
P r o d u c t N a m e C A S # D e s c r ip tio n F e a tu r e s & B e n e fi ts
H Y D R O X Y M O N O M E R S
Bisom er® HEM A ���-��-� Hydroxyethyl m ethacrylate Hydrophilic hydroxy based cross-linker
Bisom er® HPM A �����-��-� Hydroxypropyl m ethacrylate Hydrophobic hydroxy based cross-linker
Bisom er® PEA� �����-��-� Polyethyleneglycol (�) m onoacrylate Hydrophilic, plasticizing, low shrinkage, low PII value
Bisom er® PPA� �����-��-� Polypropyleneglycol (�) m onoacrylate Hydrophobic, plasticizing, low shrinkage, low PII value
Bisom er® PEM � LD �����-��-� Polyethyleneglycol (�)m onom ethacrylate Hydrophilic, non-toxic, plasticizing properties
Bisom er® PPM � LI �����-��-� Polypropyleneglycol (�)m onom ethacrylate Hydrophobic, non-toxic, plasticizing properties
Bisom er® PEM ��P HD �����-��-� Polypropyleneglycolm onom ethacrylate Hydrophobic/-philic balance, plasticizing properties
M O N O -F U N C T IO N A L M O N O M E R S
Bisom er® IDM A �����-��-� Isodecyl m ethacrylate Hydrophobic, internal polym er plasticization
Bisom er® LM A ���-��-� Lauryl m ethacrylate Hydrophobic, internal polym er plasticization
Bisom er® LM A�� SP ���-��-� Lauryl m ethacrylate Hydrophobic, narrow m olecular weight distribution
Bisom er® BZM A ����-��-� Benzyl m ethacrylate Hydrophobic, hardness, im pact resistance, low viscosity
Bisom er® M PEG���M A �����-��-� M ethoxy PEG ��� m ethacrylate Hydrophilic, polym er flexibility,co-polym erisable surfactant
Bisom er® M PEG���M A �����-��-� M ethoxy PEG ��� m ethacrylate Hydrophilic, polym er flexibility,co-polym erisable surfactant
Bisom er® S��W �����-��-� M ethoxy PEG ���� m ethacrylate Hydrophilic, polym er flexibility,co-polym erisable surfactant
Bisom er® S��W �����-��-� M ethoxy PEG ���� m ethacrylate Hydrophilic, polym er flexibility,co-polym erisable surfactant
D I-F U N C T IO N A L M O N O M E R S
Bisom er® BDDM A ����-��-� �,� Butanediol dim ethacrylate Hydrophobic, hardness, abrasion resistance, lowviscosity
Bisom er® TEGDM A ���-��-� Triethyleneglycol dim ethacrylate Hydrophobic, hardness, im pact resistance, low viscosity
Bisom er® PEG���DM A �����-��-� Polyethyleneglycol ���dim ethacrylate Hardness, im pact resistance, low viscosity
Bisom er® EP���DM A ������-��-� Polyalkyleneglycol dim ethacrylate Hydrophobic/-philic balance, im pact strength
Bisom er® EP���DM A ������-��-� Polylalkyleneglycol dim ethacrylate Hydrophobic/-philic balance, im pact strength
CHEM ICAL INTERM EDIATES | 8
Product List
P r o d u c t N a m e C A S # D e s c r ip tio n F e a tu r e s & B e n e fi ts
N E O P E N T Y L P O L Y O L S
TRIM ET® TM E ��-��-� Trim ethylolethane Com pact structure, high hydroxyl content and reactivity
P O L Y M E R IC P O L Y O L S
HA-���� proprietary Acid functional linear polyol Polym eric polyol with dual and selective reactivity
HA-����LV� proprietary Acid functional linear polyol Polym eric polyol with dual and selective reactivity
T R I-R E Z ® P O L Y E S T E R P O L Y O L S (L in e a r )
����-�� proprietary Adipate polyester polyol Non-crystalline UV stable aliphatic polyester
����-�� proprietary Adipate polyester polyol Non-crystalline UV stable aliphatic polyester
����-�� proprietary Adipate/ISO polyester polyol Non-crystalline polyester with good m oisture and UVresistance
����-�� proprietary Adipate/ISO polyester polyol Non-crystalline polyester with good m oisture and UVresistance
T R I-R E Z ® P O L Y E S T E R P O L Y O L (B r a n c h e d )
����A-��� proprietary Adipate/ISO polyester polyol Non-crystalline branched UV stable polyester
M U L T I-F U N C T IO N A L A M IN O A L C O H O L A D D IT IV E
Bisom er® Am ine D��� ���-��-� ��% Aqueous dim ethylam inohydroxypropane
Aqueous azeotrope, im proved dispersion, flow andwetting
A M IN E A C T IV A T O R F O R O R G A N IC P E R O X ID E IN IT IA T IO N
Bisom er® PTE ������-��-� N,N-Bis(�-hydroxyethyl)-para-toluidine Low toxicity, low odour and ease of handling
D I-F U N C T IO N A L A L L Y L M O N O M E R
Bisom er® DALP ���-��-� Diallyl Phthalate Low shrink, plasticizing properties, im pact and heatresistance
9 | CHEM ICAL INTERM EDIATES
Product List
P r o d u c t N a m e C A S # D e s c r ip tio n F e a tu r e s & B e n e fi ts
A L L Y L P A G S
Bisom er® AA E ��� H �����-��-� Allyl alcohol + �.� EO
Reactive interm ediates m ainly for use in the m anufactureof silicone polyethers.
Silicone polyether applications include antifoam s, foamstabilizers, additives for polyurethane, cosm etics and paintadditives
Bisom er® AA E ��� H �����-��-� Allyl alcohol + � EO
Bisom er® AA E ��� H �����-��-� Allyl alcohol + � EO
Bisom er® AA E ��� H �����-��-� Allyl alcohol +�� EO
Bisom er® AA �� ��� H ����-��-� Allyl alcohol + (�� EO & � PO ) randomco-polym er
Bisom er® AA �� ���� H ����-��-� Allyl alcohol + (�� EO & �� PO ) randomco-polym er
Bisom er® AA �� ���� H ����-��-� Allyl alcohol + (�� EO & �� PO )random co-polym e
Bisom er® CA ��� M E �����-��-� Allyl alcohol + � EO with m ethyl cap
Bisom er® CA ��� M E �����-��-� Allyl alcohol + � EO with m ethyl cap
Bisom er® CA ��� M �� �����-��-�Allyl alcohol + (�� EO & � PO ) randomco-polym erwith m ethyl cap
Bisom er® CA ��� M �� �����-��-�Allyl alcohol + (�� EO & �� PO )random co-polym erwith m ethyl cap
CHEM ICAL INTERM EDIATES | 1 0
Applications
P r o d u c t N a m e
H Y D R O X Y M O N O M E R S
Bisom er® HEM A
Bisom er® HPM A
Bisom er® PEA�
Bisom er® PPA�
Bisom er® PEM � LD
Bisom er® PPM � LI
Bisom er® PEM ��P HD
M O N O -F U N C T IO N A L M O N O M E R S
Bisom er® IDM A
Bisom er® LM A
Bisom er® LM A�� SP
Bisom er® BZM A
Bisom er® M PEG���M A
Bisom er® M PEG���M A
Bisom er® S��W
Bisom er® S��W
D I-F U N C T IO N A L M O N O M E R S
Bisom er® BDDM A
Bisom er® TEGDM A
Bisom er® PEG���DM A
Bisom er® EP���DM A
Bisom er® EP���DM A
A d h e
s iv e s
/S e a
la n ts
In d u s
t r ia l
C o a ti
n g s
U V C o
a t in g
s
P o ly m
e r D i
s p e r s
io n s
C o m p o
s ite R e
s in s
C o n c
r e te A d
m ix tu r e
s
E le c t
r o n ic
s / E le
c t ro g
r a p h i
c s
In k s
O p tic a
l
B io m
e d ic a
l
D e n t
a l
R u b b
e r M o d
ifi c a t
io n
T e x t i
le s
O il V is
c o s it
y M o d ifi e
r s
W a t e r T
r e a t m
e n t
Highly recom m ended
1 1 | CHEM ICAL INTERM EDIATES
Applications
P r o d u c t N a m e
A L L Y L P A G S
Bisom er® AA E ��� H
Bisom er® AA E ��� H
Bisom er® AA E ��� H
Bisom er® AA E ��� H
Bisom er® AA �� ��� H
Bisom er® AA �� ���� H
Bisom er® AA �� ���� H
Bisom er® CA ��� M E
Bisom er® CA ��� M E
Bisom er® CA ��� M ��
Bisom er® CA ��� M ��
C h e m
ic a l I
n t e r m
e d ia t
e s
In d u s
t r ia l
C o a ti
n g s
U V C o
a t in g
s
P o ly m
e r D i
s p e r s
io n s
C o m p o
s ite R e
s in s
C o n c
r e te A d
m ix tu r e
s
E le c t
r o n ic
s / E le
c t ro g
r a p h i
c s
In k s
Highly recom m ended
CHEM ICAL INTERM EDIATES | 1 2
Applications & Benefits
P r o d u c t N a m e
N E O P E N T Y L P O L Y O L S
TRIM ET®TM E
P r o d u c t N a m e
P O L Y M E R IC P O L Y O L S
HA-����
HA-����LV�
T R I-R E Z ® P O L Y E S T E R P O L Y O L S (L in e a r )
����-��
����-��
����-��
����-��
T R I-R E Z ® P O L Y E S T E R P O L Y O L (B r a n c h e d )
����A-���
M U L T I-F U N C T IO N A L A M IN O A L C O H O L A D D IT IV E
Bisom er® Am ine D���
A M IN E A C T IV A T O R F O R O R G A N IC P E R O X ID E IN IT IA T IO N
Bisom er® PTE
D I-F U N C T IO N A L A L L Y L M O N O M E R
Bisom er® DALP
A lk y d
s
A d h e
s iv e s
P o ly e
s te r s
S e a la
n ts
P U D s
E x t e r
io r C
o a tin
g s
U ra lk
y d s
In te r i
o r C o
a tin g
s
S i-p o
ly e s t
e r s
S o lv e
n t F r
e e S y
s te m
s
W a te r b
o r n e
R e s in
s
L o w
V is c o
s ity
C o a ti
n g s
S o lv e
n t B
o r n e
R e s in
s
R e a c
tiv e D i
lu e n t
s
U V R e
s is ta
n c e
2 K S y
s te m
s
H y d r
o ly s i
s R e s
is ta n
c e
1 K S y
s te m
s
H e a t
R e s i
s ta n c
e
C o r r o
s io n
R e s is
ta n c
e
H a r d
n e s s
E lo n g
a tio n
C o r r o
s io n
R e s is
ta n c
e
T e n s
ile S tr
e n g th
A d h e
s io n
U V R e
s is ta
n c e
T IO 2 S u
r fa c e
T r e a t
m e n t
H e a t
R e s i
s ta n c
e
Recom m ended
Highly recom m ended
1 3 | CHEM ICAL INTERM EDIATES
Chem ical & Physical Properties
P r o d u c t N a m e
H Y D R O X Y M O N O M E R S
Bisom er® HEM A ��� � ���-��� �� �� �� � �.�
Bisom er® HPM A ��� � ���-��� �� �� �� � �.�
Bisom er® PEA� ��� �� �.��-�.��% -�� ��� �.� �.� ���-���
Bisom er® PPA� ��� �� ���-��� -�� ��� �.� �.�� ���-���
Bisom er® PEM � LD ��� �� ���-��� -�� ��� �.�� �.� ���-���
Bisom er® PPM � LI ��� �� ���-��� -�� �� �.� �.� ���-���
Bisom er® PEM ��P HD ��� �� ���-��� -�� ��� �.� �.� ���-���
M O N O -F U N C T IO N A L M O N O M E R S
Bisom er® IDM A ��� � ��-��� -�� �� �� �.�
Bisom er® LM A ��� � ��-��� -�� ��� �� � �.�
Bisom er® LM A�� SP ��� � ���-��� -�� ��� �� � �.��
Bisom er® BZM A ��� � ��-�� �� �� �� �.�
Bisom er® M PEG���M A ��� �� �.��-�.��% -�� �
Gardner �.� ���-���
Bisom er® M PEG���M A ��� �� �.��-�.��% -�� �.� ��-��
Bisom er® S��W ���� �� ���-���
�Gardner ��-�� ��-��
Bisom er® S��W ���� �� �.��-���%
�Gardner ��-�� ��-��
D I-F U N C T IO N A L M O N O M E R S
Bisom er® BDDM A ��� � ���-��� n/a ��� �� � �.�
Bisom er® TEGDM A ��� �� ���-��� n/a ��� �� � �.�
Bisom er® PEG���DM A ��� �� ���-��� n/a ��� �� � �.�
Bisom er® EP���DM A ���� ��� ��-��� n/a ��� �.� ��-���
Bisom er® EP���DM A ��� ��-��� n/a ��� �.� ���-���
M o la r M
a s s1
V is c o
s ity1 @
2 5 ˚C ,
m P a
.s
In h ib
ito r (M
E H Q ),
p p m
/ %
T g1 , ˚C C o
lo u r,
m a x P t /
C o /
G a r d
n e r
A s s a
y , m in
%
A c id
V a lu e
, m g K
O H /g
W a te r,
m a x %
H y d r
o x y l
V a lu e
,
m g K O H /
g
S a p o
n ifi c a
tio n
V a lu e
, m g K
O H /g
�Typical value� Active com ponent� Total polym erisable content
CHEM ICAL INTERM EDIATES | 1 4
Chem ical & Physical Properties
P r o d u c t N a m e
A L L Y L P A G S
Bisom er® AA E ��� H � ���� ���-��� ���-��� >��� -�
Bisom er® AA E ��� H �� ���� ��-�� ���-��� >��� -�
Bisom er® AA E ��� H �� ���� ��-�� ���-��� >��� �
Bisom er® AA E ��� H �� ���� ��-�� ��-�� ��� �
Bisom er® AA �� ��� H �� ���� ��-�� ��-�� >��� -��
Bisom er® AA �� ���� H �� ���� ��-�� ��-�� ��� -��
Bisom er® AA �� ���� H ��� ��� ��.�-��.� ��-�� ��� -��
Bisom er® CA ��� M E �� ���� ��-�� <�� >��� �
Bisom er® CA ��� M E �� ���� ��-�� <�� >��� ��
Bisom er® CA ��� M �� �� ���� ��-�� <� >��� -��
Bisom er® CA ��� M �� ��� ���� ��-�� <� >��� -��
K in e m
a r ic V
is c o
s ity
@ 4 0
˚C , c S
t
D e n s
ity @
2 0 ˚C ,
k g /m
3
Io d in
e V a lu e
,
g l 2 / 1 0
0 g
H y d r
o x y l
V a lu e
,
m g K O H /
g
F la s h
P o in t
,˚C
P o u r
P o in t
,˚C
�Typical value� Active com ponent� Total polym erisable content
1 5 | CHEM ICAL INTERM EDIATES
Chem ical & Physical Properties
P r o d u c t N a m e
N E O P E N T Y L P O L Y O L S
TRIM ET® TM E ����m in
��.�m ax ���.�� ���
m ax Solid�.�m ax
P O L Y M E R IC P O L Y O L S
HA-���� ���-��� ���-��� ��� ��� ���� ���m ax �� m in ���� Liquid �.�
m ax����-����
HA-����LV� ��-�� ���-��� ��� ��� ���
m ax ���� Liquid �.�m ax
���-���
T R I-R E Z ® P O L Y E S T E R P O L Y O L (B r a n c h e d )
����A-��� �.�m ax
���-��� ��� ��� ���
m ax �� m in ���� Liquid �.�m ax
����-����
T R I-R E Z ® P O L Y E S T E R P O L Y O L S (L in e a r )
����-�� �.�m ax ��-�� ��� ���� ���
m ax �� m in ���� Liquid �.��m ax ��-��
����-�� �.�m ax ��-�� ��� ���� ���
m ax �� m in ���� Liquid �.��m ax ��-��
����-�� �.�m ax ��-�� ��� ���� ���
m ax �� m in ���� Liquid �.��m ax
���-���
����-�� �.�m ax ��-�� ��� ���� ���
m ax �� m in ���� Liquid �.��m ax
���-���
A p p e
a r a n c
e
M o is tu
r e , %
V is c o
s ity
@
2 5 ˚C ,
P o is
e
A c id
V a lu e
,
m g K O H /
g
H y d r
o x y l
V a lu e
,
m g K O H /
g
A c id
E q u iv
a le n
t
w t. H y
d ro x
y l
E q u iv
a le n
t w t .
M o le c u
la r W
e ig h t
,
g / m o le
C o lo u
r, A P
H A
N o n
V o la t
ile , %
D e n s
ity @
2 5 ˚C ,
g /l
CHEM ICAL INTERM EDIATES | 1 6
Chem ical & Physical Properties
P r o d u c t N a m e
A M IN E A C T IV A T O R F O R O R G A N IC P E R O X ID E IN IT IA T IO N
Bisom er® PTE ��� ��Gardner
���-���
M U L T I-F U N C T IO N A L A M IN O A L C O H O L A D D IT IV E
Bisom er® Am ine D��� ��� � � ���(azeo-trope)
��� ��-��.� � ��-�� ��.�� Fully
m iscibleFullym iscible
Fullym iscible
D I-F U N C T IO N A L A L L Y L M O N O M E R
Bisom er® DALP ��� ��� ���
M o la r M
a s s1
V is c o
s ity
1 , m P a
.s
In h ib
ito r (M
E H Q ),
p p m
/ %
B o ilin
g P o
in t , ˚
C
C o lo u
r, m a x
P t /C o
/ G a r d
n e r
A s s a
y , m in
%
A m in e
V a lu e
,
m g K O H /
g
W a te r,
m a x %
p H W a te r
A c e to
n e
M e th a n
o l
Solubility
� Typical value� Active com ponent� M easured @ 20 C̊� Active M onom er� pH of DM AP 100g/litre aqueous @ 20 C̊� % EsterTest m ethods available on request
1 7 | CHEM ICAL INTERM EDIATES
Chem ical Inventory Registrations
P r o d u c t N a m e
H Y D R O X Y M O N O M E R S
Bisom er® HEM A
Bisom er® HPM A
Bisom er® PEA� NDSL
Bisom er® PPA� NDSL
Bisom er® PEM � LD NDSL
Bisom er® PPM � LI
Bisom er® PEM ��P HD
M O N O -F U N C T IO N A L M O N O M E R S
Bisom er® IDM A
Bisom er® LM A
Bisom er® LM A�� SP
Bisom er® BZM A
Bisom er® M PEG���M A NDSL
Bisom er® M PEG���M A NDSL
Bisom er® S��W NDSL
Bisom er® S��W NDSL
D I-F U N C T IO N A L M O N O M E R S
Bisom er® BDDM A
Bisom er® TEGDM A
Bisom er® PEG���DM A
Bisom er® EP���DM A
Bisom er® EP���DM A
R E A C
H *
E UT S
C A
U S A D S
L
C a n a
d aP IC
C S
P h ilip
p A IC S
A u s tr
a lia
K E C I
K o r e a E N
C S
J a p a
n IE S C
S
C h in a
CHEM ICAL INTERM EDIATES | 1 8
Chem ical Inventory Registrations
P r o d u c t N a m e
A L L Y L P A G S
Bisom er® AA E ��� H
Bisom er® AA E ��� H
Bisom er® AA E ��� H
Bisom er® AA E ��� H
Bisom er® AA �� ��� H
Bisom er® AA �� ���� H
Bisom er® AA �� ���� H
Bisom er® CA ��� M E
Bisom er® CA ��� M E
Bisom er® CA ��� M ��
Bisom er® CA ��� M ��
R E A C
H *
E UT S
C A
U S A D S
L
C a n a
d aP IC
C S
P h ilip
p A IC S
A u s t r
a lia
K E C I
K o r e a E N
C S
J a p a
n IE S C
S
C h in a
• Listed or com pliant* The products listed in this catalogue as supplied by GEO Specialty Chem icals in the EU / EEA are in com pliance with therequirem ents of REACH, i.e. relevant substances are either registered, shall be registered by the required deadline, or areexem pt from registration.W e strongly recom m end that you contact GEO prior to purchase for any uses not covered by the Safety Data Sheet and /or Technical Data Sheet.
1 9 | CHEM ICAL INTERM EDIATES
Chem ical Inventory Registrations
T R I-R E Z ® P O L Y E S T E R P O L Y O L (B r a n c h e d )
����A-���
M U L T I-F U N C T IO N A L A M IN O A L C O H O L A D D IT IV E
Bisom er® Am ine D���
A M IN E A C T IV A T O R F O R O R G A N IC P E R O X ID E IN IT IA T IO N
Bisom er® PTE
D I-F U N C T IO N A L A L L Y L M O N O M E R
Bisom er® DALP
T R I-R E Z ® P O L Y E S T E R P O L Y O L S (L in e a r )
����-�� NDSL
����-�� NDSL
����-��
����-��
R E A C
H *
E UT S
C A
U S A D S
L
C a n a
d aP IC
C S
P h ilip
p A IC S
A u s tr
a lia
K E C I
K o r e a E N
C S
J a p a
n IE S C
S
C h in a
Listed or com pliant* The products listed in this catalogue as supplied by GEO Specialty Chem icals in the EU / EEA are in com pliance with the requirem ents of REACH,i.e. relevant substances are either registered, shall be registered by the required deadline, or are exem pt from registration.W e strongly recom m end that you contact GEO prior to purchase for any uses not covered by the Safety Data Sheet and / or Technical Data Sheet.** Significant New Use Rule
P r o d u c t N a m e
N E O P E N T Y L P O L Y O L S
TRIM ET® TM E
P O L Y M E R IC P O L Y O L S
HA-����
HA-����LV�
CHEM ICAL INTERM EDIATES | 2 0
Classification & Labelling
Labelling According to CLP Regulation EC No. 1272/2008
P r o d u c t N a m e G H S P ic to g r a m H a z a r d S ta te m e n ts P r e c a u tio n a r y S ta te m e n ts
H Y D R O X Y M O N O M E R S
Bisom er® HEM A GHS�� H���, H���, H��� P���, P���, P���+P���+P���,P���+P���+P���
Bisom er® HPM A GHS�� H���, H��� P���, P���, P���+P���+P���,P���+P���+P���
Bisom er® PEA� GHS�� H���, H���, H��� P���, P���, P���+P���+P���,P���+P���+P���
Bisom er® PPA� GHS�� GHS�� H���, H��� P���, P���, P���+P���, P���
Bisom er® PEM � LD GHS�� H��� P���, P���, P���+P���
Bisom er® PPM � LI None H��� P���
Bisom er® PEM ��P HD GHS�� GHS�� H���, H���, H���, H���, H��� P���, P���, P���, P���, P���+P���+P���,P���+P���+P���
M O N O -F U N C T IO N A L M O N O M E R S
Bisom er® IDM A GHS�� H��� P���
Bisom er® LM A None None None
Bisom er® LM A�� SP GHS�� GHS�� H���, H���, H���, H��� P���, P���, P���, P���, P���+P���+P���,P���+P���+P���
Bisom er® BZM A GHS�� H���, H���, H���, H��� P���, P���, P���, P���+P���+P���,P���+P���+P���
Bisom er® M PEG���M A None None None
Bisom er® M PEG���M A None None None
Bisom er® S��W None None None
Bisom er® S��W None None None
2 1 | CHEM ICAL INTERM EDIATES
Classification & Labelling
Labelling According to CLP Regulation EC No. 1272/2008
P r o d u c t N a m e G H S P ic to g r a m H a z a r d S ta te m e n ts P r e c a u tio n a r y S ta te m e n ts
D I-F U N C T IO N A L M O N O M E R S
Bisom er® BDDM A GHS�� H��� P���, P���+P���
Bisom er® TEGDM A GHS�� H��� P���, P���+P���
Bisom er® PEG���DM A None None None
Bisom er® EP���DM A GHS�� H���, H���, H��� P���, P���, P���, P���+P���+P���,P���+P���+P���
Bisom er® EP���DM A GHS�� H���, H���, H��� P���, P���, P���, P���+P���+P���,P���+P���+P���
A L L Y L P A G S
Bisom er® AA E ��� H None None None
Bisom er® AA E ��� H None None None
Bisom er® AA E ��� H None None None
Bisom er® AA E ��� H None None None
Bisom er® AA �� ��� H None None None
Bisom er® AA �� ���� H None None None
Bisom er® AA �� ���� H None None None
Bisom er® CA ��� M E None None None
Bisom er® CA ��� M E None None None
Bisom er® CA ��� M �� None None None
Bisom er® CA ��� M �� None None None
CHEM ICAL INTERM EDIATES | 2 2
Classification & Labelling
Labelling According to CLP Regulation EC No. 1272/2008
P r o d u c t N a m e G H S P ic to g r a m H a z a r d S ta te m e n ts P r e c a u tio n a r y S ta te m e n ts
N E O P E N T Y L P O L Y O L S
TRIM ET® TM E None None None
P O L Y M E R IC P O L Y O L S
HA-���� None None None
HA-����LV� None None None
T R I-R E Z ® P O L Y E S T E R P O L Y O L S (L in e a r )
����-�� None None None
����-�� None None None
����-�� None None None
����-�� None None None
T R I-R E Z ® P O L Y E S T E R P O L Y O L (B r a n c h e d )
����A-��� None None None
M U L T I-F U N C T IO N A L A M IN O A L C O H O L A D D IT IV E
Bisom er® Am ine D��� GHS��, GHS��, GHS�� H���, H���, H���, H���, H��� P���, P���, P���, P���, P���+P���+P���,P���+P���+P���, P���+P���+P���
A M IN E A C T IV A T O R F O R O R G A N IC P E R O X ID E IN IT IA T IO N
Bisom er® PTE GHS��, GHS�� H���, H���, H���, H���, H��� P���, P���+P���, P���+P���,P���+P���+P���, P���+P���
D I-F U N C T IO N A L A L L Y L M O N O M E R
Bisom er® DALP GHS��, GHS�� H���, H���, H���, H���, H��� P���, P���, P���, P���, P���+P���,P���+P���, P���, P��� and P���+P���
2 3 | CHEM ICAL INTERM EDIATES
Classification & Labelling Legend
R e fe r e n c e D e s c r ip tio n
H A Z A R D P H R A S E S
H��� Flam m able liquid and vapour
H��� Harm ful if swallowed
H��� Harm ful if in contact with skin
H��� Causes severe skin burns and eye dam age
H��� Causes skin irritation
H��� M ay cause an allergic skin reaction
H��� Causes serious eye dam age
H��� Causes serious eye irritation
H��� Toxic if inhaled
H��� Harm ful if inhaled
H��� M ay cause respiratory irritation
H��� Very toxic to aquatic life
H��� Very toxic to aquatic life with long lasting effects
H��� Toxic to aquatic life with long lasting effects
H��� Harm ful to aquatic life with long lasting effects
CHEM ICAL INTERM EDIATES | 2 4
Classification & Labelling Legend
R e fe r e n c e D e s c r ip tio n
P R E C A U T IO N A R Y S T A T E M E N T S
P��� Do not handle until all safety precautions have been read and understood
P210 Keep away from heat/sparks/open flam es/hot surfaces - No sm oking
P��� Keep container tightly closed
P��� Avoid breathing dust/fum es/gas/m ist/vapours/spray
P��� Do not get in eyes, on skin or on clothing
P��� W ash face, hands and any exposed skin thoroughly after handling
P��� Do not eat, drink or sm oke when using this product
P��� Avoid release to the environm ent
P��� W ear protective gloves/protective clothing/eye protection/face protection
P���+P��� IF SW ALLOW ED: im m ediately call a PO ISO N CENTER or doctor/physician
P���+P��� IF INHALED: rem ove to fresh air and keep at rest in a position com fortable for breathing
P���+P��� IF SW ALLOW ED: call a PO ISO N CENTER or doctor/physician if you feel unwell
P���+P���+P��� IF SW ALLOW ED: rinse m outh. Do NOT induce vom iting
P���+P��� IF O N SKIN: wash with plenty of soap and water
P���+P���+P��� IF IN EYES: rinse continuously with water for several m inutes. Rem ove contact lenses if easy to do. Continue rinsing
P��� Call a PO ISO N CENTER or doctor/physician if you feel unwell
P���+P���+P��� IF O N SKIN (or hair): rem ove/take off all contam inated clothing im m ediately. Rinse skin with water / shower
P���+P��� If skin irritation occurs: get m edical advice/attention
P���+P��� If eye irritation persists: get m edical advice/attention
P���+P��� Take off contam inated clothing and wash it before reuse
P��� Store locked up
P��� Dispose of contents/container at an approved waste disposal plant
2 5 | CHEM ICAL INTERM EDIATES
Classification & Labelling Legend
GHS�� GHS�� GHS��
GHS�� GHS�� GHS��
CHEM ICAL INTERM EDIATES | 2 6
Food Packaging Regulations
P r o d u c t N a m e S w is s O r d in a n c e E U 1 0 /2 0 1 1 * F C N L is tin g
Bisom er® HEM A Y (Part A)
Bisom er® HPM A Y (Part B)
Bisom er® PEA � C
Bisom er® PPA � Y (Part B)
Bisom er® PEM � LD Y (Part B)
Bisom er® PPM � LI Y (Part B)
Bisom er® PEM �� HD Y (Part B)
Bisom er® IDM A Y (Part B)
Bisom er® LM A Y (Part B)
Bisom er® LM A ��SP Y (Part B)
Bisom er® BZM A Y (Part A)
Bisom er® M PEG���M A Y (Part B)
Bisom er® M PEG���M A Y (Part B)
Bisom er® S��W Y (Part B)
Bisom er® S��W Y (Part B)
Bisom er® BDDM A Y (Part A)
Bisom er® TEGDM A Y (Part A)
Bisom er® PEG���DM A Y (Part B)
Bisom er® EP���DM A C
Bisom er® EP���DM A C
Bisom er® Am ine D��� Y (Part B)
Bisom er® PTE C
Bisom er® DALP Y (Part A)
TRIM ET® TM E Y (Part B)
C = m anufactured from listed com ponentsY = product listed* EU Regulation ��/���� on plastic m aterials and articles intended to com e into contact with food.
2 7 | CHEM ICAL INTERM EDIATES
BfR Recom m endations
P r o d u c t N a m e X II X IV X X II X X X IV X X X V I
Bisom er® HEM A Y Y Y
Bisom er® PEA � Y
Bisom er® LM A Y
Bisom er® LM A ��SP Y
Bisom er® BZM A Y Y
Bisom er® M PEG���M A Y
Bisom er® M PEG���M A Y
Bisom er® S��W Y
Bisom er® S��W Y
Bisom er® BDDM A Y Y
Bisom er® PTE Y
Bisom er® DALP Y
BfR Recom m endations:XII. Unsaturated Polyester ResinsXIV. Plastics DispersionsXXII. Polym ers Based on Esters of Acrylic and M ethacrylic Acids, their Copolym ers, and m ixtures of these with other Polym ersXXXIV. Vinylidene Chloride Copolym ers with a Predom inant Content of Polyvinylidene ChlorideXXXVI. Paper and Board for Food Contact
Y = product listed
CHEM ICAL INTERM EDIATES | 2 8
FDA 21 CFR Approvals
P r o d u c t N a m e 1 7 5 .1 0 5 1 7 5 .3 0 0 1 7 5 .3 2 0 1 7 5 .3 6 0 1 7 6 .1 7 0 1 7 6 .1 8 0 1 7 6 .2 1 0 1 7 7 .1 0 1 0 1 7 7 .1 3 9 0 1 7 7 .2 4 2 0 1 7 8 .3 7 1 0 1 7 8 .3 7 2 5
Bisom er® HEM A Y P P Y
Bisom er® HPM A Y P Y
Bisom er® LM A P P P
Bisom er® LM A�� SP P P P
Bisom er® DALP Y Y Y
TRIM ET® TM E Y Y Y Y Y Y Y
Y = product listedP = listed as a com ponent of a polym er
���.��� Adhesives���.��� Resinous and polym eric coatings���.��� Resinous and polym eric coatings for polyolefin film s���.��� Vinylidene chloride copolym er coatings for nylon film���.��� Com ponents of paper and paperboard in contact with aqueous and fatty foods���.��� Com ponents of paper and paperboard in contact with dry food���.��� Defoam ing agents used in the m anufacture of paper and paperboard���.���� Acrylic and m odified acrylic plastics, sem i-rigid and rigid177.1390 Lam inate structures for use at tem peratures of 250 F̊ and above���.���� Polyester resins, cross-linked���.���� Petroleum wax���.���� Pigm ent dispersants
2 9 | CHEM ICAL INTERM EDIATES
Kosher / Halal Certifications
P r o d u c t N a m e K o s h e r (P a r e v e P a s s o v e r ) H a la l
Bisom er® Am ine D���
Bisom er® PEA�
Bisom er® PEM � LD
Bisom er® PEM ��P HD
Bisom er® PPA�
Bisom er® PPM � LI
Bisom er® PTE
Bisom er® AA E ��� H
Bisom er® AA E ��� H
Bisom er® AA E ��� H
Bisom er® AA �� ���� H
Bisom er® AA �� ��� H
CHEM ICAL INTERM EDIATES | 3 0
Notes
3 1 | CHEM ICAL INTERM EDIATES
Notes
D is c la im e r :All inform ation and data, including the form ulations and procedures discussed herein, are believed to be correct. However, this should not be acceptedas a guarantee of their accuracy, and confirm ing tests should be run in your laboratory or plant. No statem ent should be construed as a recom m endationfor any use which would violate any patent rights. Sales of all products are pursuant to term s and conditions included in GEO
S p e c ia lty C h e m ic a ls s a le s d o c u m e n ts .Nothing contained therein shall constitute a guarantee or warranty with respect to the products described or their use. Safety inform ation regarding theseproducts is contained in their
S a fe ty D a ta S h e e ts .Users of these products are urged to review and use this inform ation.
Bisom er®, TRIM ET® and TRI-REZ® are registered tradem arks of GEO Specialty Chem icals, Inc.
w w w .g e o s c .c o m
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