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General Catalog 2010 | 2011

General Catalog 2010 | 2011laboaragon.com/docs/marcas/metrohm/Metrohm Catalogo General.pdf · really easy with Metrohm Metrohm AG is the only company whose range of products covers

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Page 1: General Catalog 2010 | 2011laboaragon.com/docs/marcas/metrohm/Metrohm Catalogo General.pdf · really easy with Metrohm Metrohm AG is the only company whose range of products covers

General Catalog 2010 | 2011

Page 2: General Catalog 2010 | 2011laboaragon.com/docs/marcas/metrohm/Metrohm Catalogo General.pdf · really easy with Metrohm Metrohm AG is the only company whose range of products covers

Ion Analysis

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really easy with Metrohm

Metrohm AG is the only company whose range of products covers all important

methods of ion analysis:

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Contents

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pH/conductivity measurement

Potentiometric and thermometric titration

Karl Fischer titration

Dosing

Automation for titrations

Polarography, voltammetry and CVS

Stability measurement

ProcessLab

Ion chromatography

Metrohm Quality Service®

Metrohm Subsidiaries

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pH/Conductivity measurement

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pH/Conductivity measurement

pH/Conductivity measurement

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1 — pH

pH and Ion Meters pH Meter overview PH. 2

826 pH mobile PH. 3 827 pH lab PH. 4 780 pH Meter PH. 5 781 pH/Ion Meter PH. 6 867 pH Module PH. 7

Conductivity meter 856 Conductivity Module PH. 8

Contents

Measuring instruments

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2 — pH

pH Meter overview

Measuring instruments

826 827 780 781 867

Measuring range

pH 0 ...14 (-13 ... +20) 0 ...14 (±20) 0 ...14 (-13 ... +20)

mV ±1200 ±2200 ±1200

Temperature Pt 1000 [°C] -150 ... +250 -150 ... +250 -150 ... +250

Temperature NTC [°C] -5 ... +250 -20 ... +250 -5 ... +250

Concentration � � 10-38... 10+38 10-21... 10+20

Resolution: pH 0.001 0.001 0.001

Resolution: U [mV] 0.1 0.1 0.1

Resolution: T [°C] 0.1 0.1 0.1

pH-calibration (number of buffers) 3 9 5

Stability control (drift display) x x x

Plot function pH/mV/T versus time � x x

Automatic buffer recognition x x x

Saving of calibration data incl. graph only data x x

Automatic temperature compensation x x x

Automatic electrode test � x Touch Control

Remote stirrer control � x x

Handling of intelligent dosing elements � � x

Automatic standard addition � � Dosimat Dosino/Dosimat

Touch Control with color display or tiamoTM � � x

Method memory � x x

Result memory x x x

Print out according to GLP/ISO x x x

GLP/GMP and FDA compliance (21 CFR Part11) � � Touch Control /tiamoTM full

Additional input for intelligent electrodes � � x

Ipol or Upol integrated polarizer � � x

Printer connection IrDA RS232 USB

2 USB connections for sample processor, printer, ... � � x

MSB connection � 1 (stirrer) 4 (stirrer, Dosino)

Sample processor (optional) � remote USB

Line operation with 100 ... 240 V, 50/60 Hz Battery only x x x

Lablink � � x

Language English German/English/Spanish/French Touch Control: German/English/Spanish/French/Chinese

tiamoTM: German/English

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3 — pH

826 pH mobile

The 826 pH mobile is a handy and easy-to-use pH meter with a wireless infrared interface for data trans-fer to a printer or PC. Numerous functions, e.g. input possibilities for user or sample identification, 3-point calibration with automatic buffer recognition and vari-ous monitoring functions allow GLP-compliant work-ing in virtually any location. The memory function can store up to 200 measured values with date, time and sample identification; these can be called up or trans-mitted to a printer or PC at any time. If the 6.0228.020 Primatrode is used, then the 826 pH mobile meets the requirements of protection class IP 67, i.e. even brief immersion in water will not harm the instrument. Power supply is from four LR6, UM3 or AA batteries; in normal operation up to approx. 750 working hours are possible.

Ordering information2.826.0010 826 pH mobile2.826.0020 826 pH mobile with Primatrode2.826.0110 826 pH mobile with carrying case

826 pH mobile

Measuring instruments

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4 — pH

827 pH lab

The 827 pH lab is a handy and very easy to use pH meter with wireless infrared interface for daily rou-tine work in the lab. Numerous functions, e.g. the possibility of entering user and sample identification, 3-point calibration with automatic buffer recognition, automatic measurement and various monitoring func-tions make GLP-compliant working perfectly easy. The memory function can store up to 200 measured values with date, time and sample identification; these can be called up or transmitted to a printer or PC at any time.

Ordering information2.827.0114 827 pH lab; 230 V, EU with Primatrode2.827.0115 827 pH lab; 120 V, US with Primatrode2.827.0117 827 pH lab; 240 V, AUS with Primatrode2.827.0119 827 pH lab; 230 V, UK with Primatrode2.827.0214 827 pH lab; 230 V, EU with Unitrode2.827.0215 827 pH lab; 120 V, US with Unitrode2.827.0217 827 pH lab; 240 V, AUS with Unitrode2.827.0219 827 pH lab; 230 V, UK with Unitrode

827 pH lab

Measuring instruments

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5 — pH

780 pH Meter

The 780 pH Meter is a high-end ph/Ion meter with a wide range of capabilities. In addition to the general pH, potential and temperature measuring functions, the 780 pH Meter is equipped with automatic stirrer control, multipoint calibration with up to 9 buffers, a method memory and various monitoring functions for calibration and service. The automatic GLP-compliant electrode test allows an objective evaluation of the electrode and leaves nothing to chance. Reliable and reproducible results are guaranteed. The large backlit multiline display provides a good overview and facili-tates individual settings. The bidirectional RS 232 inter-face permits data transfer to a printer or PC. A sample changer can be connected via the optional 6.2148.010 Remote Box.

Ordering information2.780.0010 High-precision 780 pH Meter

Options2.140.0200 Impact printer CUSTOM DP40-S4N2.801.0010 801 Magnetic Stirrer2.802.0040 802 Stirrer (propeller stirrer) for

804 Ti Stand2.804.0010 804 Ti Stand without stand rod6.2134.110 Cable RS-232 DB9 socket f – DB9 plug6.2148.010 Remote Box MSB

780 pH Meter

Measuring instruments

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6 — pH

781 pH/Ion Meter

The 781 pH/Ion Meter is a high-end ph/Ion meter with a wide range of capabilities. In addition to the general pH, ion, potential and temperature measuring func-tions, the 781 pH Meter is equipped with automatic stirrer control, multipoint calibration with up to 9 buf-fers (pH mode), a method memory and various moni-toring functions for calibration and service. The auto-matic GLP-compliant electrode test for pH glass elec-trodes allows an objective evaluation of the electrode and leaves nothing to chance. Reliable and reprodu-cible results are therefore guaranteed. The large backlit multiline display provides a good overview and makes individual settings easier. The bidirectional RS 232 inter-face permits data transfer to a printer or PC. A sample changer can be connected via the optional 6.2148.010 Remote Box.

Three different modes are available for ion measure-ment: direct measurement, standard addition or sample addition. With fully automatic standard addi-tion using an optional Dosimat only the concentration of the standard and the required number of addition steps need to be entered, the pH/Ion Meter takes care of everything else. Up to 19 standards can be used for calibration for direct measurements.

Ordering information2.781.0010 781 pH/Ion Meter

Options2.140.0200 Impact printer CUSTOM DP40-S4N2.801.0010 801 Magnetic Stirrer2.802.0040 802 Stirrer (propeller stirrer) for

804 Ti Stand2.804.0010 804 Ti Stand without stand rod6.2134.110 Cable RS-232 DB9 socket f – DB9 plug6.2148.010 Remote Box MSB6.2141.350 Cable Cable Dosimat plus – 781

781 pH/Ion Meter

Measuring instruments

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7 — pH

867 pH Module

With the 867 pH Module pH and ion measurement is possible at the highest level. It can be used as a stand-alone instrument together with a 900 Touch Control or as an extension to a Titrando system.

In addition to the measurement of pH, temperature, mV, I

pol, U

pol and concentration, standard additions

(manual, dos, autodos) can be carried out as well as liquid handling functions (add, prep, empty). The 867 pH Module allows the use of both intelligent electrodes – «iTrodes» – and conventional electrodes. A polarised measuring input is also part of the equip-ment.

The 867 pH Module is a modern pH/ion meter with automatic stirrer control and can be used with intel-ligent dosing elements.

The instrument has 2 USB interfaces for the connection of USB printers, sample changers or barcode readers and 4 MSB interfaces for connecting stirrers or 800 Dosino dosing systems (for adding auxiliary solution or standard addition).

Whether operated by Touch Control as a stand-alone pH meter or tiamo™ full (from 2.0), the 867 pH Mod-ule complies with GLP and FDA requirements.

Ordering information2.867.0010 867 pH Module2.867.0110 867 pH Module with Touch Control2.867.0210 867 pH Module with

tiamo™ 2.2 light

Options2.801.0010 801 Magnetic Stirrer2.802.0040 802 Stirrer (propeller stirrer) for

804 Ti Stand2.804.0010 804 Ti Stand without stand rod2.800.0010 800 Dosino6.2151.000 Cable USB A – mini-DIN 8-pin

867 pH Module with tiamo™

Measuring instruments

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8 — pH

Conductometer856 Conductivity Module

The 856 Conductivity Module can be used as a stand-alone instrument in combination with a 900 Touch Control or as an extension to any Titrando system.

The 856 Conductivity Module can measure with con-ductivity measuring cells of the latest technology, the 5-ring cells. They provide a high linearity without plati-nization of the cell. This guarantees highest precision, and the cell constant, once determined, remains stable over a wide measuring range. In contrast to the 4-ring cells, the electrode can be completely immersed in the beaker. Thus, beakers with different filling heights are no problem and in stirred solutions a rapid homogeni-zation within the cell can occur. Last but not least, the cell is easy to clean due to its removable cap.

With the help of the optional 6.2103.160 Adapter box the classical Metrohm conductivity measuring cells can continue to be used with the instrument.

Thanks to the galvanically separated measuring input, pH and conductivity can be determined in the same beaker without interferences.

The Conductivity Module has 2 USB interfaces for con-nection of USB printers, barcode readers or sample changers and 4 MSB interfaces for stirrers or 800 Dosinos.

Whether operated by Touch Control as a stand-alone pH meter or by tiamo™ full (from 2.0), the 856 Con-ductivity Module complies with GLP and FDA require-ments.

Ordering information2.856.0010 856 Conductivity Module2.856.0110 856 Conductivity Module with

900 Touch Control2.856.0210 856 Conductivity Module with

tiamo™ 2.2 light

Options2.801.0010 801 Magnetic Stirrer6.0915.100 Five-ring conductivity measuring cell,

c = 0.7 cm-1, with integrated Pt 10006.0915.130 Five-ring conductivity measuring cell,

c = 1.0 cm-1 (5-Ring) with integrated Pt 1000

6.0916.040 Conductivity measuring cell, c = 0.1 cm-1, with integrated Pt 1000 – plug N

6.2103.160 Adapter 4 x socket B – plug N6.2151.000 Cable USB A – mini-DIN 8-pin

856 Conductivity Module with 900 Touch Control

Measuring instruments

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9 — pH

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Potentiometric and thermometric titration

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Potentiometric and thermometric titration

Potentiometric and thermometric titration

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1 — Ti

Potentiometric Titrators - overview TI. 3

Titrando Titrando family TI. 4 888 Titrando mit Touch Control TI. 5 888 Titrando with tiamo™ light TI. 5 902 Titrando TI. 5 904 Titrando TI. 5 904 Titrando TI. 6 905 Titrando TI. 6 905 Titrando TI. 6 906 Titrando TI. 6 906 Titrando TI. 7 907 Titrando TI. 7 907 Titrando TI. 7 Surf Titrando Ionic TI. 7 Surf Titrando Two Phase TI. 8 Surf Titrando NIO TI. 8 Plate Titrando TI. 8 Oil Titrando TI. 8 Food Titrando TI. 9 Pharm Titrando TI. 9 900 Touch Control TI. 9 tiamo™ 2.2 light TI. 10 tiamo ™ 2.2 full TI. 10 tiamo ™ 2.2 multi TI. 10 800 Dosino TI. 11 802 Stirrer (propeller stirrer) for 804 Ti Stand TI. 11 804 Ti Stand without stand rod TI. 11 804 Ti Stand with stand TI. 11 805 Dosimat TI. 12 846 Dosing Interface TI. 12 847 USB Lab Link TI. 12 856 Conductivity Module TI. 12 867 pH Module TI. 13

Titrino plus Titrino plus TI. 14 848 Titrino plus TI. 15 Food/Beverage Titrino plus TI. 15 Food/Bev. Titrino plus with printer TI. 15 Salt Titrino plus TI. 15 Salt Titrino plus with printer TI. 16 Oil Titrino plus TI. 16 Oil Titrino plus with printer TI. 16 877 Titrino plus TI. 16 USB Thermal printer Neo's TI. 17 801 Stirrer with support TI. 17 802 Stirrer (propeller stirrer) for 804 Ti Stand TI. 17 804 Ti Stand without stand rod TI. 17 804 Ti Stand with stand TI. 18 869 Compact Sample Changer TI. 18

Contents

Potentiometric titrators

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2 — Ti

Titrotherm 859 Titrotherm TI. 19

Contents

Thermometric titration

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3 — Ti

Potentiometric titrators

Potentiometric Titrators – overview

Potentiometric Titrators Titrino Plus Titrando

870 877 848 888 890 901 902 904 905 906 907

Optional 2nd measuring interface � � � � � yes yes yes yes yes yes

Intelligent Sensor «iTrodes» � � � yes � yes yes yes yes yes yes

Volumetric Karl Fischer Titration yes � � � yes yes � � � yes yes

Ion Measurement / Standardaddition � � � � � � � yes yes yes yes

pH Measurement � yes yes yes � yes yes yes yes yes yes

Endpoint Titration � yes yes yes � yes yes yes yes yes yes

Dynamic Equivalence Point Titration � � yes yes � � � yes yes yes yes

Monotonic Equivalence Point Titration � yes yes yes � � � yes yes yes yes

Liquid Handling � � � � � yes yes yes yes yes yes

STAT Titration � � � � � � yes � � yes yes

Dosino Technology � � � � � yes yes � yes � yes

Software Control � � � yes yes yes yes yes yes yes yes

Touch Control � � � yes yes yes yes yes yes yes yes

Live Display yes yes yes yes yes yes yes yes yes yes yes

Report Printing / LIMS yes yes yes yes yes yes yes yes yes yes yes

Balance Connection via RS232 yes yes yes yes yes yes yes yes yes yes yes

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4 — Ti

Titrando family

Depending on the model, the Titrando supports the titration modes DET (dynamic equivalence point titra-tion), MET (monotonic equivalence point titration), SET (titration to one or two predefined endpoints), KFT (volumetric Karl Fischer titration) and pH-STAT.

Ion meterWith the measuring modes MEAS pH and MEAS CONC not only pH, potential and temperature can be measured. Direct concentration determination and standard addition can also be carried out with ion-selective electrodes.

Comprehensive liquid handlingBasic operations in daily laboratory work, such as pipetting, transferring, dosing, dispensing and diluting become perfectly easy thanks to the liquid handling functions of the Titrando. No matter whether you con-nect the Dosino directly to the Titrando or carry out the liquid handling using a USB Sample Processor, both systems guarantee highest accuracy and precision in the range from 10 �L to 100 mL.

Measuring inputThe measuring interface of the Titrando features a socket for the intelligent electrodes «iTrodes», a high-impedance input and an input for polarisable elec-trodes, as well as a separate reference input and an input for a Pt 1000 or NTC temperature sensor. The resolution of the inputs is 0.1 mV or 0.001 pH. Up to two galvanically separated measuring interfaces can be installed.

MSB connectionWith the four built-in MSBs (Metrohm Serial Bus) up to 4 Dosinos or Dosimats, 4 magnetic or rod stirrers and 4 remote boxes for automation can be controlled. This means that the modular Titrando system is the most flexible titration system on the market. Plug-and-play functionality makes the manual configuration of peripheral devices a thing of the past; the Titrando automatically recognises the connected device.

USB connectionFor communication with balances, printers and other USB-capable devices, two USB ports are available. Laboratory balances can be connected via an RS-232 converter.

The Dosino – dosing on a minimum footprintWith the Titrando dosing is carried out with a Dosino and an intelligent Dosing Unit which is mounted directly onto the reagent bottle. A data chip contains all the information on the reagent and Dosing Unit that is required for titration. The Dosing Unit can be exchanged in no time at all. Each Dosing Unit has its own serial and cylinder numbers and comes with its own individual certificate.

Intelligent electrodes «iTrodes»The built-in memory chip enables storing of important sensor data such as article and serial number, calibra-tion data, calibration history, working life and calibra-tion validity. All sensor data is read in automatically after connection to a Titrando. This prevents editing confusion or errors. If the type of electrode is differ-ent from that defined in the method, then the user is informed. Monitoring functions allow the exclusion of electrodes whose calibration data lies outside the limits or whose calibration has expired.If the sensor is used with different instruments, then the calibration data stored in the chip makes the electrode transferrable; it no longer needs to be reca-librated each time that it is used with different instru-ments.

Straightforward OperationTouch Control is an ergonomic and modern operating unit. You can hold it in your hand, put it on the bench or mount it on the wall. Thanks to the new favorite icons you have direct access to your favorite methods.

Of course, the Titrando can be operated from virtually any PC. The tiamo™ titration software offers not only standard functions for controlling a Titrando, but also numerous other functions, such as a client-server data-base or real parallel titration.

Unlimited automation Increasing numbers of samples, complicated sample preparation steps and unattended overnight operation soon call for the use of a sample changer. The Titrando has the necessary intelligence for controlling sample changers. No matter whether large or small sample capacity, one or two workstations, measuring out the sample, sample preparation, liquid handling, rinsing and calibrating the electrodes – the new USB Sample Processors offer a high degree of automation at a rea-sonable price.

Potentiometric titrators

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5 — Ti

Titrando

888 Titrando mit Touch Control (2.888.0110)

High-end titrator with built-in buret drive. Dynamic (DET) and monotonic (MET) titration, endpoint titration (SET). With four MSB connections, one galvanically separated measuring interface (also for intelligent electrodes «iTrodes») and USB connection. Including 900 Touch Control, 801 Magnetic Stirrer, exchange unit 20 mL and combined pH glass electrode «Ecotrode plus».

888 Titrando with tiamoTM light (2.888.0210)

High-end titrator with built-in buret drive. Dynamic (DET) and monotonic (MET) titration, endpoint titra-tion (SET), measurements. With four MSB connections, one measuring interface (also for intelligent electrodes «iTrodes») and USB connection. Including titration soft-ware tiamoTM light, 801 Magnetic Stirrer, exchange unit 20 mL and combined pH electrode «Ecotrode plus».

902 Titrando (2.902.0010)

High-end titrator for use of intelligent elec-trodes «iTrodes» and up to four 800 Dosino dosing systems. Endpoint titration (SET), enzymatic and pH-STAT titrations (STAT), dosing functions with monitoring (DOS), liquid handling. With four MSB connections, one galvanically separated measuring interface, USB connection.

904 Titrando (2.904.0010)

High-end titrator for use of intelligent electrodes «iTrodes» and built-in buret drive. Dynamic (DET) and monotonic (MET) titration, endpoint titration (SET), measurements with ion-sensitive electrodes (MEAS CONC), dosing functions (DOS), liquid handling. With four MSB connections, one galvanically separated mea-suring interface, USB connection.

Potentiometric titrators

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6 — Ti

904 Titrando (2.904.0020)

High-end titrator for use of intelligent electrodes «iTrodes» and built-in buret drive. Dynamic (DET) and monotonic (MET) titration, endpoint titration (SET), measurements with ion-selective electrodes (MEAS CONC), dosing functions (DOS), liquid handling. With four MSB connections, two galvanically separated mea-suring interfaces, USB connection.

905 Titrando (2.905.0010)

High-end titrator for use of intelligent electrodes «iTrodes» and up to four 800 Dosino dosing systems. Dynamic (DET) and monotonic (MET) titration, end-point titration (SET), measurements with ion-sensitive electrodes (MEAS CONC), dosing functions (DOS), liq-uid handling. With four MSB connections, one galvani-cally separated measuring interface, USB connection.

905 Titrando (2.905.0020)

High-end titrator for use of intelligent electrodes «iTrodes» and up to four 800 Dosino dosing systems. Dynamic (DET) and monotonic (MET) titration, endpoint titration (SET), measurements with ion-sensitive elec-trodes (MEAS CONC), dosing functions (DOS), liquid handling. With four MSB connections, two measuring interfaces, USB connection.

906 Titrando (2.906.0010)

High-end titrator for use of intelligent electrodes «iTrodes» and built-in buret drive. Dynamic (DET) and monotonic (MET) titration, endpoint titration (SET), enzymatic and pH-STAT titrations (STAT), Karl Fischer titration (KFT), measurements with ion-sensitive elec-trodes (MEAS CONC), dosing functions with monitor-ing (DOS), liquid handling. With four MSB connections, one galvanically separated measuring interface, USB connection.

Potentiometric titrators

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7 — Ti

906 Titrando (2.906.0020)

High-end titrator for use of intelligent electrodes «iTrodes» and built-in buret drive. Dynamic (DET) and monotonic (MET) titration, endpoint titration (SET), enzymatic and pH-STAT titrations (STAT), Karl Fischer titration (KFT), measurements with ion-sensi-tive electrodes (MEAS CONC), dosing functions with monitoring (DOS), liquid handling. With four MSB connections, two galvanically separated measuring interfaces, USB connection.

907 Titrando (2.907.0010)

High-end titrator for use of intelligent electrodes «iTrodes» and up to four 800 Dosino dosing systems. Dynamic (DET) and monotonic (MET) titration, end-point titration (SET), enzymatic and pH-STAT titrations (STAT), Karl Fischer titration (KFT), measurements with ion-selective electrodes (MEAS CONC), dosing func-tions with monitoring (DOS), liquid handling. With four MSB connections, one galvanically separated measur-ing interface, USB connection.

907 Titrando (2.907.0020)

High-end titrator for use of intelligent electrodes «iTrodes» and up to four 800 Dosino dosing systems. Dynamic (DET) and monotonic (MET) titration, end-point titration (SET), enzymatic and pH-STAT titrations (STAT), Karl Fischer titration (KFT), measurements with ion-selective electrodes (MEAS CONC), dosing func-tions with monitoring (DOS), liquid handling. With four MSB connections, two galvanically separated measur-ing interfaces, USB connection.

Surf Titrando Ionic (2.905.1010)

The Surf Titrando Ionic is based on the 905 Titrando and offers a complete package for the most common analyses of ionic surfactants. Apart from the titration software tiamoTM light and determination methods described in detail, you will also receive comprehensive accessories for your titrations.

Potentiometric titrators

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8 — Ti

Surf Titrando Two Phase (2.905.1020)

The Surf Titrando Two Phase is based on the 905 Tit-rando and offers a complete package for the most common analyses of ionic surfactants. Apart from the titration software tiamoTM light and determination methods described in detail, you will also receive com-prehensive accessories for your titrations.

Surf Titrando NIO (2.905.2010)

The Surf Titrando NIO is based on the 905 Titrando and offers a complete package for the most common analyses of non-ionic surfactants. Apart from the titration software tiamoTM light and determination methods described in detail, you will also receive com-prehensive accessories for your titrations.

Plate Titrando (2.905.2020)

The Plate Titrando is based on the 905 Titrando and offers a complete package for the most common ana-lyses of plating baths. Apart from the titration software tiamoTM light and determination methods described in detail, you will also receive comprehensive accessories for your titrations.

Oil Titrando (2.905.3010)

The Oil Titrando is based on the 905 Titrando and offers a complete package for the most common analyses of petrochemical products. Apart from the titration soft-ware tiamoTM light and determination methods descri-bed in detail, you will also receive comprehensive accessories for your titrations.

Potentiometric titrators

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9 — Ti

Food Titrando (2.905.4010)

The Food Titrando is based on the 905 Titrando and offers a complete package for the most common ana-lyses of foodstuffs. Apart from the titration software tiamoTM light and determination methods described in detail, you will also receive comprehensive accessories for your titrations.

Pharm Titrando (2.907.1020)

The Pharm Titrando is based on the 907 Titrando and offers a complete package for the most common analyses of pharmaceutical products. Apart from the titration software tiamoTM full and determination me-thods described in detail, you will also receive compre-hensive accessories for your titrations.

Input units and software

900 Touch Control (2.900.0010)

Operating unit for Titrandos, USB Sample Processors,856 Conductivity Module, 867 pH Module and 846 Dos-ing Interface. Touch-sensitive, high-resolution colour display, simple and intuitive user guidance thanks to favorites for fast method access. Built-in ethernet inter-face for direct connection to the internet and USB interface for connection of printers or an USB memory stick.

Potentiometric titrators

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10 — Ti

tiamo™ 2.2 light (6.6056.221)

tiamoTM 2.2 light

PC program for controlling a titration system.

• Up to two instruments can be connected. • Graphical method editor with numerous templates • Layout Manager for display adjustment • Professional database with recalculation • Powerful report generator • No parallel titration, no data export • 1 License • Dialogue language English, German,

tiamo™ 2.2 full (6.6056.222)

Program for controlling complex titration systems.

• Graphical method editor with numerous templates• Layout Manager for display adjustment• Professional database with recalculation• Export to LIMS, NuGenesis, Cyberlab, etc.• Powerful report generator• Complies with FDA 21 CFR Part 11• Parallel titration• 1 Licence• Dialogue language English, German

tiamo™ 2.2 multi (6.6056.223)

Client/server program for controlling complex titration systems.

• Graphical method editor with numerous templates• Layout Manager for display adjustment• Client/server database• Professional database with recalculation• Export to LIMS, NuGenesis, Cyberlab, etc.• Powerful report generator• Complies with FDA 21 CFR Part 11• Parallel titration• 3 Licences• Dialogue language English, German

Potentiometric titrators

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11 — Ti

Titrando – optional accessories

800 Dosino (2.800.0010)

Drive with write/read hardware for intelligent Dosing Units. With fixed cable.

802 Stirrer (propeller stirrer) for 804 Ti Stand (2.802.0040)

Rod stirrer with 6.1909.010 Propeller stirrer.

804 Ti Stand without stand rod (2.804.0010)

Titration stand and controller for 802 Stirrer. The 804 Ti Stand together with the 802 Stirrer provides an alterna-tive to the magnetic stirrer. Without stand.

804 Ti Stand with stand (2.804.0040)

Titration stand and controller for 802 Rod Stirrer. 804 Ti Stand together with the 802 Rod Stirrer provides an alter-native to the magnetic stirrer. Ti Stand with base plate, support rod and electrode holder.

Potentiometric titrators

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12 — Ti

805 Dosimat (2.805.0010)

Dosing device for the Titrando and Sample Processors with read/write hardware for intelligent Exchange Units. With permanently attached cable. Without Exchange Unit.

846 Dosing Interface (2.846.0010)

USB controller for up to four 700/800 Dosino dosing sys-tems or 685/805 Dosimats for dosing or liquid handling tasks. A Touch Control operating unit or the connection to a PC with tiamo™ or MagIC Net™ is required.

847 USB Lab Link (2.847.0010)

847 USB Lab Link – rapid network connection for theTitrando (only for 840 Touch Control).

856 Conductivity Module (2.856.0010)

• 4 MSB connections (for, e.g. stirrer, Dosino)• 2 USB connections (for, e.g. printer, bar code reader)• Possibility for complete automation with, e.g. 814 /

815 sample changer

Conductivity measuring module for upgrading Titrando systems or use as stand alone unit in combination with a 900 Touch Control.

Potentiometric titrators

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13 — Ti

867 pH Module (2.867.0010)

• Measuring of pH, mV, Ipol, Upol, T or concentration • Ion measurement direct or with standard addition • Electrode test in combination with PC/Touch Control• Stand alone or integrated in systems compliant with

21 CFR Part 11 requirements• Use of intelligent and conventional electrodes

possible• 4 MSB connections (for, e.g. stirrer, Dosino)• 2 USB connections (for, e.g. printer, bar code reader)• Can be fully automated, e.g. with 814 / 815 Autosampler

Module for pH/ion measurement as upgrade to a Titrando or stand alone unit in combination with an 900 Touch control.

Potentiometric titrators

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14 — Ti

Titrino plus

The Titrino plus, Metrohm’s new entry-level titrator for potentiometric titration, features an excellent price-performance ratio. A large live display with titration curve, the plug-and-play functionality of exchange unit, stirrer and USB printer, a high-precision measuring input, operation by mouse click – the Titrino plus offers considerably more than you would expect in this price category. With its operator dialogue tailored to the needs of the routine user, the Titrino plus instruments are so simple to use that they can be put into opera-tion in no time at all. Their robustness makes them the ideal titrators for routine determinations in day-to-day laboratory use.

Potentiometric titrationThe 877 Titrino plus supports the titration modes MET (monotonic equivalence point titration) and SET (titra-tion to one or two predefined endpoints). The 848 Titrino plus additionally supports the titration mode DET (dynamic equivalence point titration).

Live Curve for real time control

All Titrino plus models feature a display with live curve, thus the user is always informed about the current state of the titration.

Highest precision thanks to new measuring inputThe Titrino plus is, like the Titrando, equipped with a high-resolution measuring input that guarantees results of outstanding precision.

Easiest installationInstalling a Titrino plus is simple. Exchange unit, stirrer and USB compact printer are recognised and config-ured automatically upon connection.

Mouse or keys – choose your favorite!The Titrino plus can be controlled either by mouse click or keyboard.

For communication with balances or printers a USB port is available. This opens up the world of USB colour printers for report printout and other USB devices. The optional 6.2148.030 RS 232/USB Box allows laboratory balances to be connected and remote operation by a computer.

Intelligent exchange unit for more convenienceThe chip of the intelligent Metrohm exchange unit automatically provides the titrator with the data (cyl-inder volume, type of reagent, titer expiration date...) that is required for carrying out an error-free titration. This means that you are always titrating under optimal conditions and, for example, do not have to repeat measurements because of an expired titer.

Titrino plus

Potentiometric titrators

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15 — Ti

848 Titrino plus (2.848.0010)

Compact titrator for dynamic (DET) and monotonic (MET) titrations with automatic equivalence point rec-ognition as well as endpoint titrations (SET).

Food/Beverage Titrino plus (2.848.1010)

The Food/Beverage Titrino plus offers a complete pack-age for the most common analyses in the food branch.Apart from almost 100 determination methods descri-bed in detail, you also receive the complete accessories required for your titrations.

Food/Bev. Titrino plus with printer (2.848.1020)

The Food/Beverage Titrino plus offers a complete pack-age for the most common analyses in the food indus-try. Apart from almost 100 determination methods described in detail, you also receive all the accessories required for your titrations.

Salt Titrino plus (2.848.2010)

The Salt Titrino plus offers a complete package for ana-lysing chloride in various samples. Apart from several determination methods described in detail, you also receive all the accessories required for your titrations.

Potentiometric titrators

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16 — Ti

Salt Titrino plus with printer (2.848.2020)

The Salt Titrino plus comes with a complete pack-age for the analysis of chloride in various samples. Apart from several determination methods described in detail, you also receive the complete accessories required for your titrations. Including USB Thermo-printer Neo’s.

Oil Titrino plus (2.848.3010)

The Oil Titrino plus offers a complete package for analysing the total acid number (TAN) or total base number (TBN) of petroleum products. Apart from the determination methods described in detail, you also receive all the accessories required for your titrations.

Oil Titrino plus with printer (2.848.3020)

The Oil Titrino plus offers a complete package for the analysis of the total acid number (TAN) or total base number (TBN) of petroleum products. Apart from the determination methods described in detail, you also receive all the accessories required for your titrations. Including USB Thermoprinter Neo’s.

877 Titrino plus (2.877.0010)

Compact titrator for potentiometric endpoint titrations (SET) and monotonic titrations with automatic equiva-lence point determination (MET).

Potentiometric titrators

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17 — Ti

Titrino plus – optional accessories

USB Thermal printer Neo's (2.141.0100)

Compact printer with USB interface, paper width 60 mm (40 characters). Including 6.2151.120 USB cable.

801 Stirrer with support (2.801.0040)

Magnetic stirrer with base plate, support rod and elec-trode holder for use with Titrino plus, Titrandos, Sam-ple Processors, 805 Dosimat and 780/781 pH Meters. With permanently attached cable for MSB (Metrohm Serial Bus).

802 Stirrer (propeller stirrer) for 804 Ti Stand (2.802.0040)

Rod stirrer with 6.1909.010 Propeller stirrer.

804 Ti Stand without stand rod (2.804.0010)

Titration stand and controller for 802 Stirrer. The 804 Ti Stand together with the 802 Stirrer provides an alter-native to the magnetic stirrer. Without stand.

Potentiometric titrators

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18 — Ti

804 Ti Stand with stand (2.804.0040)

Titration stand and controller for 802 Rod Stirrer. 804 Ti Stand together with the 802 Rod Stirrer provides an alternative to the magnetic stirrer. Ti Stand with base plate, support rod and electrode holder.

869 Compact Sample Changer (2.869.0010)

• Affordable automation• Space-saving• Different method templates• Easy to use• A total of 12 positions• Live-display

The 869 Compact Sample Changer provides automa-tion on a minimum footprint.

869 Compact Sample Changer

Potentiometric titrators

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19 — Ti

859 Titrotherm

859 Titrotherm – thermometric titration with Thermoprobe

Thermometric titration is a versatile determination method and an ideal complement to potentiometric titration. In principle it is suitable for any reaction that produces a sufficiently large temperature change in the sample solution. It is particularly suitable for applica-tions for which

• no suitable potentiometric sensor is available,• no suitable reference electrode exists,• the sample would affect or even destroy the indica-

tor electrode,• no suitable solvent is available for potentiometry.

The 859 Metrohm Titrotherm combines innovative sensor technology with the titration know-how from Metrohm. The temperature sensor (Thermistor) is based on semiconductor technology and has a response time of 0.3 s and a resolution of 10–5 K. This makes the Thermoprobe the ideal sensor for thermometric titra-tions, as it can follow any temperature change rapidly and precisely.

The Dosino technology from Metrohm has defined a new standard in volumetric titration. The dosing unit with its drive motor is mounted onto the reagent bot-tle and guarantees maximum precision with minimum space requirements.

The tiamo™ titration software offers not only stan-dard functions , but also numerous other functions that could previously only be dreamed about. This includes the compatibility to all Metrohm USB Sample Processors.

Ordering information2.859.1010 859 Titrotherm complete with tiamoTM

Options6.9011.020 Thermoprobe for 859 Titrotherm6.9011.030 Adapter cable for 859/Plug F6.9011.040 HF resistant Thermoprobe for 859

Titrotherm

Thermometric titration

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Karl Fischer titration

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Karl Fischer titration

Karl Fischer titration

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5 — KF

Introduction to Karl Fischer titration Volumetric KF titrators

Volumetric KF titrators – overview KF. 3 890/901 Titrando KF. 4 870 KF Titrino Plus KF. 5

KF Coulometer Coulometric KF titrators – overview KF. 6

851/852 Titrando KF. 7 756/831 KF Coulometer KF. 8

KF sample preparation 874 USB Oven Sample Processor KF. 9 860 KF Thermoprep KF. 10 KF Evaporator KF. 10 Polytron PT 1300 D KF. 11

KF automation Automated coulometric KF titrations KF. 12 Automated volumetric KF titrations KF. 12 Automated volumetric KF titration including sample preparation KF. 13

Contents

Karl Fischer titration

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6 — KF

Karl Fischer water determination is one of the most fre-quently used laboratory methods world-wide. In con-trast to other water determination methods it is spe-cific, fast and the amount of instrumentation required is very small.

With an application range of 0.1% to 100% water,volumetric Karl Fischer titration is used in a wide variety of industries. The advantage of volumetry is that not only liquid samples but also solid or pasty samples can be put directly into the titration vessel. No matter whether you want to determine water in food, cos-metics or pharmaceutical products, with Metrohm KF titrators you are always right.

As far as quantities in the trace range (10 �g to 10 mg water absolute) are concerned, coulometry is the optimal method to determine water in liquids, solids and gases. Coulometry is also an absolute method and therefore requires no titer determination.

For difficult samples, we offer intelligent solutions for sample preparation, e.g. the KF oven technique or sample pulverisation with a homogeniser included in the system.

Due to high sample throughput the use of automated systems pays for itself very quickly. Metrohm KF auto-mation offers you sophisticated techniques for both volumetric and coulometric KF titration.

Karl Fischer titration

Introduction to Karl Fischer Titration

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7 — KF

Karl Fischer titration

Volumetric KF titrators – overview

Technical speci� cations 870 KFTitrino plus

890Titrando

901Titrando

Volumetric Karl Fischer titration (KFT) yes yes yes

Titration to preset pH/mV endpoints (SET) � � yes

pH calibration and pH measurements (CAL, MEAS) � � yes

Real-time curve display yes yes yes

Prede� ned methods yes yes yes

Parallel titration � � yes (tiamoTM)

Dosing drive for titration Exchange Unit Exchange Unit Dosing Unit

Inputs, interfaces

Second, galvanically separated measuring interface � � option

Automated reagent exchange with Dosino (option) � yes yes

MSB-port for connection of further Dosinos (addition of auxiliary solution, …) � 3 4

MSB-port for connection of further Dosinos (Titration) � � 3

Attachment of stirrer yes yes yes

Sample changer connection � yes yes

Attachment of printer, balance, ... yes, USB yes, USB yes, USB

Optional interfaces optional RS 232C yes, USB yes, USB

Software

tiamoTM � yes (1.3 or higher) yes (2.0 or higher)

Touch Control � yes yes

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8 — KF

Karl Fischer Titrando890/901 Titrando

Karl Fischer titrators for the modern titration lab

Due to their simple and intuitive user guidance, the KF Titrandos are the optimal instruments both for routine work and for demanding applications in development laboratories. With the KF Titrando you have a titration system that can be adapted to meet all imaginable requirements without any compromises at all.

An electrode test and the specially created parameter «Safety stop» prevent the cell from overflowing during conditioning, i.e. conditioning is stopped after a certain time or the addition of a certain amount of KF reagent (Laboratory safety). The sophisticated control algo-rithm of the Titrando is adapted to the characteristics of the Karl Fischer reaction and guarantees results of outstanding precision.

Choose your favorite! Both the 901 Titrando and the 890 Titrando can be used either as a stand-alone system with the 900 Touch Control or via a PC using the tiamo™ software.

901 Titrando

In addition to the Karl Fischer mode (KFT), the 901 Titrando also features the SET mode, allowing titrations to a predefined endpoint. With the high-resolution, galvanically separated measuring interface with addi-tional digital measuring input for intelligent elec-trodes «iTrodes» it is also capable of performing high-precision pH measurements.

Thanks to the four MSB connections, up to four 800 Dosino dosing systems can be connected to the 901 Titrando. These can be used for titration, but also for the automated addition of sample, standard and aux-iliary solutions such as solubility promoters. All liquid handling commands are also available.

Because of its special properties the 800 Dosino is the optimal dosing system for KF titration. Thanks to the «Empty» command the Dosino can be completely emp-tied; as a result opening and cleaning the dosing unit is no longer necessary. In contrast to the exchange unit, repeated rinsing before titre adjustment is no longer necessary; you save both time and reagents.

890 Titrando

The 890 Titrando offers the same high-end features as the 901 Titrando (except digital measuring input), but is limited to the KF mode and titrates only with the well-proven exchange unit. In addition up to three 800 Dosino dosing systems can be connected and used for the automated addition of sample, standard and auxil-iary solutions.

Ordering information2.890.0110 890 Titrando with Touch Control2.890.0210 890 Titrando with tiamoTM light2.901.0010 901 Titrando

Options2.803.0010 803 TI Stand with stirrer and pump2.900.0010 900 Touch Control6.6056.221 tiamo™ 2.2 light6.6056.222 tiamo™ 2.2 full6.6056.223 tiamo™ 2.2 multi6.3026.150 Exchange Unit 5 mL6.3026.210 Exchange Unit 10 mL6.3026.220 Exchange Unit 20 mL2.800.0010 800 Dosino6.3032.120 Dosing Unit 2 mL6.3032.150 Dosing Unit 5 mL6.3032.210 Dosing Unit 10 mL6.3032.220 Dosing Unit 20 mL6.2061.010 Bottle holder for Dosinos

901 Titrando with 803 Ti Stand and Touch Control

Karl Fischer titration

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9 — KF

Karl Fischer Titrino plus870 KF Titrino Plus

• Straightforward installation• Easy operation due to predefined methods• Excellent precision thanks to the high-resolution

measuring input• Live curve for recognizing side-reactions• Overflow protection for increased operating safety• Compact USB printer as an option

The competitively priced 870 Titrino plus is a titrator for volumetric water determination. It can be used to determine water contents from a few ppm up to 100% reliably and accurately in solid, liquid and gas-eous samples. With its operating interface designed for routine users, the 870 Titrino plus is so easy to use that hardly any familiarization is needed at all. Due to its robustness, it is also the ideal titrator for routine determinations. Titration vessel and electrode are included.

Very simple installationInstallation of the 870 Titrino plus is simple. As soon as they are connected, the exchange unit, stirrer and compact USB printer are recognised and configured automatically.

Ready-to-use methods simplify your workYou only have to decide whether you want to carry out a titre, blank value or water determination and then start the titration by pressing just one key. Param-eters need only be adjusted in exceptional cases.

Mouse or keyboard – choose your favorite!The 870 Titrino plus is the first titrator that can be con-trolled either by mouse-click or keyboard – the choice is yours.

Highest precision thanks to new measuring inputJust like the Titrando high-end titrator, the new KF titrator is also equipped with a high-resolution measur-ing input that guarantees results of outstanding preci-sion.

Live curve allows recognition of side-reactionsMetrohm KF titrators feature a display with live curve as standard. This allows the user to recognise side-reactions in good time and take measures to suppress them.

New parameters improve working safetyGreat importance has been given to working safety: The new titrator allows safe handling of hazardous Karl Fischer reagents. The new safety parameter «Condi-tioning options» prevents the titration cell from over-flowing.

Optional:

Intelligent Exchange Unit for more convenienceThe chip of the intelligent Metrohm Exchange Unit automatically provides the titrator with the data (cylin-der volume, type of KF reagent, expiration date of titre, etc.) that are necessary to carry out an error-free titra-tion. This means that you always titrate under optimal conditions.

The 803 KF Titration StandThe 803 KF Titration Stand is used for stirring and for exchanging the used working medium. The built-in pump aspirates off the used titration solution and adds new working medium there being no need to open the cell.

Ordering information2.870.0010 870 KF Titrino plus2.870.1010 870 KF Titrino plus complete2.870.1020 870 KF Titrino plus with printer2.870.2010 870 KF Titrino plus and 860 KF Ther-

moprep

Karl Fischer titration

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10 — KF

Karl Fischer titration

Coulometric KF titrators – overview

Technical speci� cations 756 KF Coulometer 831 KF Coulometer 851 Titrando 852 Titrando

Coulometric Karl Fischer titration (KFC) yes yes yes yes

Volumetric Karl Fischer titration (KFT) � � � yes

Bromine index (BRC) � � yes yes

Titration to preset mV endpoints (MET Ipol, SET Upol) � � � yes

Monotonic equivalence point titration (MET Ipol, MET Upol) � � � yes

Water/time real-time curve display yes yes yes yes

Prede� ned methods yes yes � �

Parallel titration � � � yes (with tiamoTM)

Automatic reagent exchange with Dosino (option) yes yes yes yes

Automatic titration start for coulometry � � yes yes

Inputs, interfaces

MSB-port for connection of further Dosinos (titration) � � � 3

MSB-port for connection of further Dosinos (dosing) � � yes yes

Attachment of stirrer yes yes yes yes

Sample changer connection yes yes yes yes

Attachment of printer and balance RS 232C RS 232C USB (2) USB (2)

Optional interfaces RS 232C RS 232C RS 232C RS 232C

Software

tiamoTM yes yes yes (2.1 or higher) yes (2.1 or higher)

Touch Control � � yes yes

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11 — KF

KF Coulometers851/852 Titrando

Coulometry is the ideal method for water determina-tion in the trace range (10 �g to 10 mg water abso-lute) for analysing liquids, solids and gases. Further-more, coulometry is an absolut method, which is why no titer determination is necessary.

With the 851 Titrando, coulometric titrations can be performed rapidly and easily. The 852 Titrando enables not only coulemetric but also volumetric Karl Fischer titrations.

Bromine indexThe bromine index can be determined with the 851 Titrando and the 852 Titrando. No additional acces-sory parts are required for the measurements. The conventional coulometric titration cell and the genera-tor electrode with diaphragm can also be used for the bromine index determination. Only the anolyte and the catholyte need to be adjusted.

Automatic titration startIt can easily happen that the sample is injected into the titration vessel before starting the titration beforehand. In such cases, the water in the sample is conditioned away and the measurement must be repeated. You don’t have to worry about this potential problem with the 851 Titrando or the 852 Titrando. The instru-ment starts the titration automatically, as soon as the sample is added. Thus, you will save on reagents, sample and, above all, on valuable time.

Dosing Unit and DosinoDosinos and Dosing Units can be connected to the new coulometer at one of the four MSB ports. In combination with the two Titrandos, these can be used for the adding of sample, standard or auxiliary solutions such as solubility promoters. In addition, the replacement of reagents can be automated, which means that the cell does not need to be opened, thus eliminating the possibility of moisture entering it. As a result, long conditioning times following a change of reagent are avoided.

Coulometric and volumetric titrationsIf the water content of the samples should be too high for coulemetric determination, this is not a problemwhen the 852 Titrando is used. The instrument enablesanalysis of samples with water content levels ranging from a few micrograms all the way up to 100%.

Ordering information2.851.0010 851 Titrando with generator electrode

with diaphragm2.851.0020 851 Titrando with diaphragm-genera-

tor electrode and Touch Control oper-ating unit

2.851.0110 851 Titrando with diaphragmless gen-erator electrode

2.851.0120 851 Titrando with diaphragmless gen-erator electrode and Touch Control operating unit

2.852.0050 852 Titrando with generator electrode with diaphragm

2.852.0060 852 Titrando with generator electrode with diaphragm and Touch Control

2.852.0150 852 Titrando with generator electrode without diaphragm

2.852.0160 852 Titrando with diaphragm-less gen-erator cell and Touch Control operating unit

Options2.801.0010 801 Magnetic Stirrer2.803.0010 803 TI Stand with stirrer and pump2.800.0010 800 Dosino2.900.0010 900 Touch Control6.3032.120 Dosing Unit 2 mL6.3032.150 Dosing Unit 5 mL6.3032.210 Dosing Unit 10 mL6.3032.220 Dosing Unit 20 mL6.3032.250 Dosing Unit 50 mL6.6056.221 tiamo™ 2.2 light6.6056.222 tiamo™ 2.2 full6.6056.223 tiamo™ 2.2 multi

852 Titrando with coulometric and volumetric titration cell

Karl Fischer titration

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12 — KF

KF Coulometers756/831 KF Coulometer

The Metrohm KF Coulometers are suitable for precise water determinations in the trace range (1 ppm...10%). They are available with two different types of genera-tor electrodes. The diaphragm-less generator electrode requires only one reagent and is practically mainte-nance-free. The use of the generator electrode with diaphragm is preferred for the following applications: very low water content (< 100 �g water absolute), when ketone reagents are used or with a high content of solubility promoter (> 10%).

With or without printer – choose as you prefer! The 756 KF Coulometer is equipped with a built-in ther-mal printer. However, just like the 831 KF Coulometer, you can also connect an external printer or connect the instrument to a PC, in which case you can choose between the Metrodata Vesuv and tiamo™ software.

Our KF Coulometers come with a complete titration cell and many accessories. KF Coulometers with the diaphragm generator electrode are delivered with the 728 Magnetic Stirrer as part of the accessories.

User benefits:

• Live curve for early recognition of possible side reactions

• Simple operation due to dialogue in German, English, French, Spanish, Italian, Portuguese and Swedish

• Expert or routine mode selectable• Memory for up to 100 methods• With 2 x RS 232C (DB9) data interfaces for connec-

tion of balance, printer and PC

• Possibility of connecting a PC keyboard and barcode reader

• Optional: automatic reagent exchange using Dosing Unit and Dosino

Ordering information2.756.0010 756 KF Coulometer including generator

electrode with diaphragm2.756.0110 756 KF Coulometer including dia-

phragmless generator electrode2.831.0010 831 KF Coulometer including generator

electrode with diaphragm2.831.0110 831 KF Coulometer with diaphragmless

generator electrode

Options2.728.0010 728 Stirrer without stand2.703.0010 703 Ti Stand with stirrer and pump6.5617.000 Reagent changing equipment2.700.0020 700 Dosino2.140.0200 Impact printer CUSTOM DP40-S4N

756 KF Coulometer with 728 Stirrer and additional equipment for automatic reagent exchange

Karl Fischer titration

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13 — KF

Thermal sample preparation874 USB Oven Sample Processor

The 874 Oven Sample Processor opens up new pos-sibilities for water determinations in samples that are either insoluble, cause side reactions or for any other reasons cannot be placed directly into the titration ves-sel. Using the oven method, these problems can be avoided, as the water is separated from the sample matrix.

How the oven technique works: The samples are placed in the oven in hermetically sealed sample vials. Heating the sample releases the water, which is trans-ferred in a stream of carrier gas to the KF cell, where the Karl Fischer titration takes place.

Sample preparation: Sample preparation for the oven technique is very simple. All that has to be done is weighing out the sample into the vial and then seal-ing it. Hermetically sealing the vial with a septum also reliably prevents moisture absorption from the atmo-sphere.

Field of application: The oven method is suitable for liquid and solid samples and can be used with both volumetric and coulometric KF titrators.

Advantages of the oven method at a glance:

• Reproducible analysis conditions for each sample – benefit: much higher precision of results

• Reduction of manual preparation steps to a minimum• Considerable savings in time• No contamination of the oven by the sample, so no

carryover or memory effects

• Improved water release from the sample, because the carrier gas does not just pass over the sample but is led directly through it

• Lower reagent consumption, as the titration solution needs to be changed only at infrequent intervals

874 USB Oven Sample Processor

• USB device – If the 874 USB Oven Sample Processor is connected to a PC the instrument is recognised automatically

• Optimal oven temperature – Running a temperature gradient enables the optimal oven temperature to be defined for each individual sample

• Reagent exchange – an 800 Dosino can be attached directly to one of the MSB ports of the Sample Changer. With a Dosino and a Dosing Unit the reagent exchange can be carried out automatically

With tiamo™ full software and extensive acces-sories, consisting of: 100 sample vials 100 sep-tum seals, 1 crimping tongs.

Ordering information2.874.0010 874 USB Oven Sample Processor2.874.0020 874 USB Oven Sample Processor

customized

874 USB Oven Sample Processor, 851 Titrando

Karl Fischer titration

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14 — KF

860 KF Thermoprep

• Simple handling of the instrument thanks to a clearly arranged menu

• Identical and reproducible conditions for all samples during analysis ensures precise results

• No contamination of the oven and therefore no car-ryover and memory effects

• Simple and fast sample preparation

The 860 KF Thermoprep is designed for thermal sample preparation in Karl Fischer titration.

Numerous substances cannot be analysed by direct Karl Fischer titration as they are not soluble, react with the Karl Fischer reagent or release their water only very slowly or not until heated to high temperatures. Using tightly sealed sample vials, the sample is inserted in the oven. The samples can be subsequently analysed by any volumetric or coulometric KF titrator.

Ordering information2.860.0010 860 KF Thermoprep

860 KF Thermoprep with 756 KF Coulometer

KF Evaporator

The KF Evaporator is used for sample preparation in Karl Fischer titration by means of azeotropic distillation.

As with the oven method, the water is separated from the sample matrix. Because the sample itself remains in the evaporation chamber, the titration vessel and the electrodes are not contaminated. Furthermore, unwan-ted side reactions and matrix effects are avoided.

Ordering information2.136.0200 KF Evaporator

KF Evaporator

Karl Fischer titration

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15 — KF

KF homogenizerPolytron PT 1300 D

With the PT 1300 D you can pulverise and homogenise samples directly in the titration cell. Because sample preparation is carried out directly in the sealed titra-tion vessel, any change of the water content caused by atmospheric humidity is eliminated. Depending on the dispersing tool and type of sample, rotor speeds between 7000 and 30’000 rpm can be set steplessly and exactly. As the Polytron 1300 D is controlled directly either by the Metrohm tiamo™ software or the Touch Control the speed can be varied during the measurement; as a result stirring with an additional magnetic stirrer is not necessary.

Examples of applications for the Polytron 1300 D in sparingly soluble substances:

Candies

Water content is a critical factor during the manufac-ture of candy, even though it is not one of its major components. It determines both the properties of the candy and its taste.

Pharmaceuticals

The water content of drugs influences their active sub-stance release. In pharmaceutical analyses it is there-fore an important parameter. With the Titrando/Poly-tron system, tablets are dissolved in the KF reagent in a short time regardless of their coating in a way which immediately releases their water content.

Meat

Meat usually has a high water content which is nor-mally enclosed in cells. This water can only be released by comminution with a high-frequency homogeniser.

Dried plant material

In plant material, such as tobacco, the majority of the water is enclosed in cells. The easiest way to release it is by using a high-frequency homogeniser.

Ordering information2.136.0100 Polytron PT 1300 D

Options6.9012.000 Dispersing aggregate for Polytron,

125 mm6.9012.010 Dispersing aggregate for Polytron,

157 mm

Karl Fischer titration

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16 — KF

Automated coulometric KF titrations

MATi 4 is a fully automated system for coulometric KF titrations with high sample throughput. The sample rack of the Sample Processor accommodates up to 160 samples in 6-mL-vials. The samples are transferred to an external coulometric cell where KF titration is carried out. The system is controlled by the tiamo™ titration software.

The system consists of:1 x 815 Robotic USB Sample Processor XL1 x 786 Swing Head1 x 851 Titrando1 x 800 Dosino1 x 801 Stirrer

Ordering informationMATi 04 Automated coulometric KF titrations

Automated volumetric KF titrations

Fully automated system for volumetric Karl Fischer water determination in up to 24 samples. The system is controlled by tiamo™ and consists of an 814 USB Sample Processor, an 901 Titrando and numerous accessories.

The samples are weighed out into beakers, sealed to protect them against atmospheric moisture and placed on the rack. Prior to titration the samples are dissolved in a known amount of KF working medium and the water content is then titrated in a second step.

This method is particularly suitable for samples that dissolve quickly in the KF working medium. The solubi-lity can also be improved by using a suitable solubility promoter.

The system consists of:1 x 814 USB Sample Processor1 x 901 Titrando2 x 800 Dosino1 x 741 Stirrer

Ordering informationMATi 10 Automated volumetric KF titrations

Karl Fischer titration

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17 — KF

Automated volumetric KF titration including sample preparation

Fully automated system for volumetric Karl Fischer water determination in up to 53 samples. The system is controlled by tiamo™ and consists of an 815 USB Sample Processor XL, an 901 Titrando and numerous accessories.

The samples are weighed out into beakers, sealed to protect them against atmospheric moisture and placed on the rack. Prior to titration a known amount of KF reagent is added and the sample crushed using a Poly-tron. In a second step the water content is titrated.

With the Polytron the samples are crushed into small pieces and the contained water is released. This method is also suitable for the analysis of hardly solu-ble samples (e.g. tablets). In many cases solubility pro-moters can thus be avoided.

The system consists of:1 x 815 USB Sample Processor XL1 x 901 Titrando1 x Polytron1 x 772 Pump Unit2 x 800 Dosino2 x 786 Swing Head1 x 6.9903.048 Electrode1 x 6.9914.139 Titration head1 x 6.9914.140 Robotic arm1 x 6.9920.141 Sample rack

Ordering informationMATi 11 Automated volumetric KF titration

including sample preparation

Karl Fischer titration

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Dosing

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Dosing

Dosing

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1 — LH

Intelligent Liquid Handling 846 Dosing Interface LH. 6

Dosing, pipetting and manual titration The Dosimats at a glance LH. 2

865 Dosimat plus LH. 3 876 Dosimat plus LH. 4 876 Manual Titrator LH. 5

Contents

Dosing devices

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The Dosimats at a glance

Dosing devices

876 Dosimat plus 876 Manual Titrator 865 Dosimat plus

Steps per cylinder volume 10 000 Pulses 10 000 Pulses 10 000 Pulses

Printer connection (USB) yes yes yes

Remote Interface yes yes yes

Balance Connection via RS232 yes (6.2148.030) yes (6.2148.030) yes (6.2148.030)

Intelligent Exchange unit yes yes yes

Push Button Cable yes yes yes

Manual Dosing (DOS) yes yes yes

Manual Titration yes yes yes

Extended Dosing (XDOS) yes yes yes

Content Dosing (CNT D) � � yes

Liquid Transfer (LQT) � � yes

Tandem Dosing (with 805 Dosimat) yes yes yes

Including 801 Magnetic Stirrer and Stand � yes �

Remote Control via PC yes yes yes

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865 Dosimat plus

Dispensing Unit for manual titration and dosing appli-cations. Including push-button cable for manual dis-pensing control and 6.3026.220 Exchange Unit 20 mL.

A wide variety of instruments can be connected to the USB interface of the Dosimat plus; with a USB hub you can even connect several devices simultaneously (keyboard, mouse, USB compact printer or USB DIN A4 printer, USB stick for methods and data backup). The optional 6.2148.030 RS 232/USB Box allows laboratory balances to be connected and remote control via a personal computer.

The Dosimat plus is suitable for a wide range of appli-cations with its four dosing modes:

DOS (Dosing)

Push-button dosing, particularly suitable for carrying out manual titrations with a color indicator. From the added volume the result can be automatically calcu-lated and a report printed out. Different calculation variables can be defined as parameters beforehand.

XDOS (Extended Dosing)

Adding a fixed volume: the volume and the dosing rate are predefined.Time-controlled dosing: the volume and the time are predefined.Dosing by dosing rate: the dosing rate and the time are predefined.

If continuous dosing without interruption is required then the 865 Dosimat plus can be operated in tandem mode together with an 805 Dosimat.

CNT D (Content dosing):

This mode is used for the preparation of standards and other solutions. From the size of the starting substance (solid or stock solution) and the predefined target concentration, the 865 Dosimat plus automatically determines the volume of solvent to be added. After completing the dosing, a report featuring all the rel-evant information about the prepared solution can be printed out.

LQT (Liquid transfer):

This mode is used for pipetting and diluting liquids.

Ordering information2.865.0010 865 Dosimat plus

Options6.3026.110 Exchange unit / 1 mL6.3026.150 Exchange unit / 5 mL6.3026.210 Exchange unit / 10 mL6.3026.220 Exchange unit / 20 mL6.3026.250 Exchange unit / 50 mL6.1562.060 Pipetting equipment for

Manual Dosing Controller6.1562.140 Pipetting tubing 10 mL for

6.1562.060

865 Dosimat plus

Dosing devices

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876 Dosimat plus

876 Dosimat plus for manual titration and dosing applications. Including push-button cable for manual dis-pensing control and 6.3026.220 Exchange Unit 20mL.

A wide variety of instruments can be connected to the USB interface of the Dosimat plus; with a USB hub you can even connect several devices simultaneously (keyboard, mouse, USB compact printer or USB DIN A4 printer, USB stick for methods and data backup). The optional 6.2148.030 RS 232/USB Box allows laboratory balances to be connected and remote control via a personal computer.

With its two dosing modes the Dosimat plus is ideal for handling classical dosing tasks in the laboratory.

DOS (Dosing)

Push-button dosing, particularly suitable for carrying out manual titrations with a color indicator. From the added volume a result can be automatically calculated and a report printed out. Different calculation variables can be predefined as parameters.

XDOS (Extended Dosing)

Adding a fixed volume: the volume and the dosing rate are predefined.Time-controlled dosing: the volume and the time are predefined.Dosing by dosing rate: the dosing rate and the time are predefined.

If continuous dosing without interruption is required

then the 876 Dosimat plus can be operated in tandem mode together with an 805 Dosimat.

Ordering information2.876.0010 876 Dosimat plus

Options6.3026.110 Exchange unit / 1 mL6.3026.150 Exchange unit / 5 mL6.3026.210 Exchange unit / 10 mL6.3026.220 Exchange unit / 20 mL6.3026.250 Exchange unit / 50 mL

876 Dosimat plus

Dosing devices

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876 Manual Titrator

Manual Titrator with result calculation for titrations with color indicator, with automatic stopcock switch-ing and refill. Including push-button cable for manual dispensing control, Exchange Unit 20 mL and magnetic stirrer.

A wide variety of instruments can be connected to the USB interface of the Dosimat plus; with a USB hub you can even connect several devices simultaneously (keyboard, mouse, USB compact printer or USB DIN A4 printer, USB stick for methods and data backup). The optional 6.2148.030 RS 232/USB Box allows laboratory balances to be connected and remote control via a personal computer.

With its two dosing modes the Dosimat plus is ideal for handling classical dosing tasks in the laboratory.

DOS (Dosing)

Push-button dosing, particularly suitable for carryingout manual titrations with an indicator. From the added volume a result can be automatically calculated and a report printed out. Different calculation variables can be predefined as parameters.

XDOS (Extended Dosing)

Adding a fixed volume: the volume and the dosing rate are predefined.Time-controlled dosing: the volume and the time are predefined.Dosing by dosing rate: the dosing rate and the time are predefined.

If continuous dosing without interruption is required then the 876 Dosimat plus can be operated in tandem mode together with an 805 Dosimat.

Ordering information2.876.0110 876 Manual Titrator plus

Options2.801.0040 801 Magnetic Stirrer with stand2.802.0040 802 Propeller rod stirrer for

804 Titration stand2.804.0010 804 Ti Stand without stand rod2.804.0040 804 Ti Stand with stand6.3026.110 Exchange unit / 1 mL6.3026.150 Exchange unit / 5 mL6.3026.210 Exchange unit / 10 mL6.3026.220 Exchange unit / 20 mL6.3026.250 Exchange unit / 50 mL

876 Manual Titrator

Dosing devices

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6 — LH

846 Dosing Interface

The 846 Dosing Interface can be integrated as a system component and control device in any Metrohm Titrando system. The interface can be operated either by Touch Control or personal computer running the tiamo™software.

Liquid handling tasks such as pipetting, transferring, dosing, dispensing and diluting are perfectly easy thanks to the new liquid handling functions of the Dosing Interface. The system guarantees superior accu-racy and precision in the range from 10 �L to 100 mL, i.e. across four orders of magnitude.

The control device has four MSB connections (MSB = Metrohm Serial Bus) enabling auxiliary and peripheral devices to be operated. These include one each of a dosing drive (700/800 Dosino or 685/805 Dosimat), a stirrer or titration stand, a Remote Box etc. In addi-tion two USB connections are available allowing, e.g.a printer, balance, keypad, barcode reader, USB Sample Processor or other control device to be connected.

Ordering information2.846.0010 846 Dosing Interface2.800.0010 800 Dosino

Options6.3032.120 Dosing unit complete / 2 mL6.3032.150 Dosing unit complete / 5 mL6.3032.210 Dosing unit complete / 10 mL6.3032.220 Dosing unit complete / 20 mL6.3032.250 Dosing unit complete / 50 mL6.2061.010 Bottle holder for Dosinos6.2065.000 Stacking frame for 846 Dosing

Interface.

846 Dosing Interface

Dosing devices

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Automation for titrations

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Automation for titrations

Automation for titrations

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1 — AT

Introduction to automation Sample changer overview AT. 3

Sample Changer 869 Compact Sample Changer AT. 4

USB Sample Processors 814 USB Sample Processor AT. 5 815 Robotic USB Sample Processor XL AT. 6 864 Robotic Balance Sample Processor TAN/TBN AT. 7

Titrosampler 862 Compact Titrosampler AT. 8 855 Robotic Titrosampler AT. 9

Titration systems Automated systems AT. 10 848 Titropackage plus AT. 11 Fully automated water analysis AT. 12 Automated TAN/TBN Analysis AT. 12 Non-aqueous titrations AT. 13 Automated coulometric KF titrations AT. 13 Automated titration of acids and bases AT. 14 Automated titration system for up to 28 samples AT. 14 Automated pipetting and titrating system for up to 100 samples AT. 15 Automated volumetric KF titrations AT. 15 Automated volumetric KF titration including sample preparation AT. 16 Automated COD determination AT. 16 862 Food/Beverage Compact Titrosampler AT. 17 862 Food/Beverage Compact Titrosampler with printer AT. 17 862 Salt Compact Titrosampler AT. 18 862 Salt Compact Titrosampler with printer AT. 18 Robotic Chloride Analyzer AT. 19 Robotic Acid-Base Analyzer AT. 19 Robotic TAN/TBN Analyzer AT. 20 Robotic Fluoride Analyzer AT. 20 Robotic Transfer Analyzer AT. 21

Sample preparation systems Sample preparation in overview AT. 22

Robotic Soliprep AT. 23

Peripheral devices for automation Membrane pumps AT. 24 Peristaltic pumps AT. 25 849 Level Control AT. 26 731 Relay Box AT. 27 Swing Heads AT. 28 741 Stirrer AT. 29 802 Stirrer AT. 29

Contents

Automation in titration

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The automation of potentiometric measuring methods has gained in importance, as nowadays single deter-minations hardly ever meet the required standards. In contrast to manual determinations, fully automatic ones are more precise, reliable and save time.

Facing large numbers of samples, users are soon forced to consider automating frequent and repetitive analyses, as this allows qualified personnel to be used more efficiently. Even with small series or many differ-ent analyses, automation can be used to achieve faster and more reproducible results.

A uniform sample preparation procedure, which can only be guaranteed by a fully automated system, ensures that results remain identical even over a longer period of time – regardless of the user. Typical prepa-ration steps in daily laboratory routine such as liquid handling (pipetting, transferring), diluting, adding, ther-mostatting, degassing, milling, filtering, filling off and many more can be carried out fully automatically just like the subsequent analysis.

An issue not to be neglected is the safety of labora-tory staff. The routine handling of typical laboratory equipment (pipets, burets, etc.) and the use of aggres-sive chemicals requires the technician's full concentra-tion. Using automated systems in sample preparation minimises contact with hazardous substances and sol-vents, which helps to increase safety at work.

Metrohm offers a large choice of instruments for automating your analytical and sample preparation procedures. On the following pages you will find more information about different sample changers and fully preconfigured analytical systems.

Automation in titration

Introduction of automation

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Automation in titration

862 Compact

Titrosampler

869 Compact

Sample Changer

814 USB Sample Processor

815 Robotic USB Sample Processor XL

855 Robotic

Titrosampler

864 Robotic Balance

Sample Processor

Integrated measuring input yes � � � yes �

Integrated balance � � � � � yes

Work stations 1 1 1 / 2 1 / 2 1 2

Automatic rack recognition yes yes yes yes yes yes

Exchangeable racks � � yes yes yes yes

Titration / measurement directly on the rack yes yes yes yes yes yes

Standard racks 11 x 120 mL 11 x 120 mL

12 x 250 mL16 x 150 mL22 x 120 mL24 x 075 mL

028 x 250 mL034 x 150 mL059 x 120 mL100 x 075 mL160 x 006 mL

028 x 250 mL034 x 150 mL059 x 120 mL100 x 075 mL160 x 006 mL

20 x 120 mL

Thermostated racks � � � yes yes �

Beaker sensor � � yes yes yes yes

Splash protection yes yes yes yes yes yes

Drip pan � � yes yes yes yes

Max. number internal pumps � � 2 / 4 2 / 4 2 �

Max. number external pumps 2 2 2 / 4 2 / 4 1 4

Connector Swing Head � � 1 / 2 1 / 2 1 2

External positions � � 4 / 8 4 / 8 4 8

Pipetting / Sample transfer � � yes yes yes yes

Stirrer connector 1 1 1 / 2 1 / 2 1 2

Connector MSB 1 � 3 3 3 3

Connector Remote yes yes optional optional optional optional

Connector USB � � 2 2 2 2

Connector Mini-USB yes yes � � � �

Stand-alone yes yes optional optional optional �

tiamo™ � � yes yes yes yes

Sample changer overview

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869 Compact Sample Changer

• Affordable automation• Space-saving• Different method templates• Easy to use• A total of 12 positions• Live-display

The 869 Compact Sample Changer provides automa-tion on a minimum footprint.

The 869 Compact Sample Changer offers quick and easy automation of Titrino / Titrino plus applications.

For multiple determinations and small series of sam-ples, this sample changer is exactly the right choice. With a total of 12 positions a wide range of titrations can be carried out fully automatically and the electrode is rinsed and/or conditioned between determinations. In order to keep titrant and solvent consumption as low as possible, narrow sample beakers are used as standard, allowing a waste efficient and fast titration procedure.

The large and clearly arranged live display informs about the status of the sample series and allows the user to interrupt the series to determine samples with higher priority. As lab space is expensive, the 869 Com-pact Sample Changer occupies only the bench space of a typical analytical balance.

Different method templates can be used to com-pile and save application-specific methods. Only four parameters need to be set. In addition, the methods can also be printed out or saved electronically via a USB (OTG) connection. Communication between the Compact Sample Changer and Titrino / Titrino plus takes place via remote signals without an additional control box or PC required.

The titration head of the Sample Changer can accom-modate an 802 Rod Stirrer and two additional elec-trodes. The rod stirrer can be connected directly to the instrument and is also controlled by it. Titrant and aux-iliary reagent can be added from the preinstalled buret tips. On request the 869 Compact Sample Changer can be retrofitted with rinsing and aspiration pumps.

Despite its highly competitive price, the 869 Compact Sample Changer offers maximum safety. The splash protection prevents the operator from accidental con-tact with chemicals.

Ordering information2.869.0010 869 Compact Sample Changer

869 Compact Sample Changer

Automation in titration

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USB Sample Processor814 USB Sample Processor

In modern-day laboratories single determinations no longer meet the requirements. Each and every result has to be confirmed by multiple determinations in order to meet today's tough quality standards. An «automatic» titrator without sample changer is there-fore basically just a semiautomatic titrator because it is not able to carry out a double or threefold determina-tion by itself: each titration requires the user to take action, which is both tedious and time-consuming.

The benefits of a sample changer are not just found in the time saved by lab personnel: automated systems control operation sequences and thus improve repro-ducibility and accuracy. Errors can be reduced to a minimum. The system processes the prepared samples irrespective of the time of day. No matter whether automatic sample preparation, liquid handling or sam-ple processing – the 814 USB Sample Processor mas-ters everything that used to be the exclusive domain of laboratory robots.

Thanks to its compact design, even complex tasks canbe carried out reliably on the smallest possible footprint. Depending on the sample matrix, the titrated sample solution is aspirated and the titration equipment is rinsed using membrane or peristaltic pumps. These are either mounted already inside the instrument or available as accessories.

Depending on the user's preference, the 814 USB Sam-ple Processor can be controlled by Touch Control, the tiamo titration or the MagIC Net™ chromatography software. The method examples provided make creat-ing your own methods perfectly easy.

Ordering information2.814.0010 814 USB Sample Processor (1T/1P)2.814.0020 814 USB Sample Processor (1T/2P)2.814.0030 814 USB Sample Processor (1T/0P)2.814.0110 814 USB Sample Processor (2T/2P)2.814.0120 814 USB Sample Processor (2T/4P)2.814.0130 814 USB Sample Processor (2T/0P)

814 USB Sample Processor with sample rack for 12 x 250 mL

Automation in titration

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Robotic USB Sample Processor815 Robotic USB Sample Processor XL

Maximum sample throughput with minimal effort!

Considering the large number of samples and ever more complicated sample preparation steps, the use of robots becomes more important, even in analytical laboratories. The more working steps that have to be carried out per sample, the more worthwhile is the professional automation of these steps. This is not just a matter of transferring liquids from one beaker to the next in order to analyse the sample – these days cus-tomers expect the simplification of the whole analytical process from sample preparation to carrying out mul-tiple determinations.

Reproducibility and accuracy are key criteria of analyses and thus are one of the main challenges for automa-tion. Basic operations in modern automation such as pipetting, transferring, taking aliquots, dosing and dispensing have become perfectly easy thanks to the Robotic Sample Processor generation.

Using the 786 Swing Head a maximum number of sample vessels can always be placed on the rack enabling even very large series to be processed. Depending on the vessel sizes and the application, this maximum is between 28 and 160 positions (standard racks).

Processing samples in parallel is easy with the Robotic Sample Processor XL. While the pipetted sam-ple volume is being titrated at an external work station (optional), the pH of the next sample waiting for analy-

sis can be determined or the next sample prepared. Thus the time per analysis is reduced to a minimum.

The 815 Robotic USB Sample Processor XL can be con-trolled either by the Touch Control, the tiamo titra-tion or the MagIC Net™ chromatography software. The method examples supplied make method creation perfectly easy.

Ordering information2.815.0010 815 Robotic USB Sample Processor XL

(1T/1P)2.815.0020 815 Robotic USB Sample Processor XL

(1T/2P)2.815.0030 815 Robotic USB Sample Processor XL

(1T/0P)2.815.0110 815 Robotic USB Sample Processor XL

(2T/2P)2.815.0120 815 Robotic USB Sample Processor XL

(2T/4P)2.815.0130 815 Robotic USB Sample Processor XL

(2T/0P)

815 Robotic USB Sample Processor XL with two work stations and one sample rack for 100 x 75 mL

Automation in titration

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864 Robotic Balance Sample Processor TAN/TBN

• Fully automatic weighing of the sample• High-end analyzer with a minimum footprint• Robotic USB Sample Processor - proven technology• Sample preparation and analysis in one system• Saves time by taking over routine tasks• Intelligent liquid handling - transferring, diluting and

more• Reliable, robust and safe• Attractive price• Control software that leaves nothing to be desired

System for the fully automatic preparation and analysis of petrochemical products that need to be weighed in, diluted and titrated.

System includes the following instruments:1 x 864 Robotic Balance Sample Processor XL1 x 905 Titrando3 x 800 Dosino1 x 786 Swing Head1 x 786 Swing Head strengthened1 x 802 Stirrer1 x 843 Pump Station (Peristaltic)

The 864 Robotic Balance Sample Processor TAN/TBN offers fast and convenient sample preparation com-bined with the analysis of petrochemical products in one system.

The sample is placed in a beaker on the sample rack and a portion of it is pipetted and weighed into the

titration beaker fully automatically. After sample transfer and weighing, the sample is diluted with solvent. The TAN or TBN value is then determined by titration. After the analysis the titration beaker is emptied and the titration equipment is cleaned directly inside the beaker.

The sample rack can accommodate 20 sample and titration beakers (6.1459.300) each as well as 20 pipetting tips (6.1562.240) for sample transfer. These 10 mL tips are picked up, filled and stripped off after weighing so that cross-contamination-free sample transfer is absolutely guaranteed. Time and amount of work per sample is minimized. The only thing that needs to be ensured is that enough sample is in the beaker.

The combined automation of sample preparation and analysis in a single system increases reproducibility-and accuracy of results as the sample is weighed in where it will be analysed. If necessary, the equipment can be cleaned more intensely by using an additional external rinsing station combined with a second 843 Pump Station.

The complete preparation and analysis system is con-trolled by the approved titration software tiamo™. Each preparation step (including the sample amount weighed in) is documented in a database as are the titration results for each single sample.

Ordering information2.864.1130 864 Robotic Balance Sample Proces-

sor TAN/TBN

864 Robotic Balance Sample Processor TAN/TBN

Automation in titration

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Compact Titrosampler862 Compact Titrosampler

862 Compact Titrosampler - a titrator and a sample changer combined in a single device - is a fully auto-mated titration station that does not need more space than a typical analytical balance.

In 12 positions different analyses can be carried out fully automatically and the electrodes can be cleaned and/or conditioned after each determination. Due to the large and clearly arranged live display the titration curve is always in view and the actual state of the sample series can be directly followed. Urgent samples can be given preference at any time. Plug-and-play functionality of intelligent dosing unit, stirrer and USB printer, a high-precision measuring input, control via mouse click as well as different dialogue options (expert and routine) leave nothing to be desired.

Highest precision thanks to new measuring input.Just like Titrando, the high-end titrator, the Compact Titrosampler is equipped with a high-resolution mea-suring input that guarantees results of outstanding precision. A wide variety of instruments can be con-nected to the USB interface of the Titrino plus; with a USB hub, several instruments can even be connected simultaneously:

• Numeric keyboard• USB compact printer• Standard USB DIN A4 printer• USB stick for method and data backup

Ordering information2.862.0010 862 Compact Titrosampler2.862.0110 862 Compact Titrosampler with printer

862 Compact Titrosampler with printer

Automation in titration

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Robotic Titrosampler855 Robotic Titrosampler

The most discrete titrator in the world – invisible and yet so flexible.

The 855 Robotic Titrosampler adds a new dimension to automation. The successful combination of a high-performance titrator and perfect laboratory automation covers a wide range of applications. Thanks to this combination of automation and titration, up to 40% of bench space can be saved – while retaining identical functionality and flexibility.

The more demanding the application, the more work-ing steps are necessary prior to the analyis. Those time-consuming sample preparation steps can be left to the Robotic Titrosampler. No matter whether pipetting, transferring or simply diluting samples with solvent – there are hardly any limits to what is possible. With up to three buret connections integrated in the instru-ment, the Robotic Titrosampler offers comprehensive capabilities for liquid handling tasks.

A high-performance titrator based on the proven Tit-rando technology is already built into the Robotic Titrosampler. With the accuracy and precision of the Titrando the Robotic Titrosampler also has the STAT mode in addition to the usual titration modes. Dynamic (DET) and monotonic (MET) titration, endpoint titration (SET), enzymatic and pH-Stat titration (STAT), measure-ments with ion-selective electrodes (MEAS CONC), liq-uid handling (LQH, DOS) are all perfectly easy with the Robotic Titrosampler.

Regarding the variety of possible combinations and numerous different applications it is essential that the traceability of each individual sample be guaranteed. The 855 Robotic Titrosampler, with its connections for intelligent Dosing Units, offers an all-over-documen-tation of your analyses.

The system is controlled via the Touch Control oper-ating unit or the proven tiamo™ titration software.

Ordering information2.855.0010 855 Robotic Titrosampler «Basic»

(1T/1P)2.855.0020 855 Robotic Titrosampler «Basic»

(1T/2P)

855 Robotic Titrosampler «Basic»

Automation in titration

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Automated systems

Benefit from more than 60 years of experience!Metrohm offers far more than just a large variety of different stand-alone instruments. Based on 60 years of experience in application we have put together complete systems that meet a multitude of different requirements. You can choose your Metrohm auto-mated laboratory system quickly and easily – secure in the knowledge that we provide whatever you need.

848 Titropackage plusThe compact and economical system for the automa-tion of potentiometric analyses on the smallest foot-print! This combination of a routine titrator and a very compact sample changer requires very little space and can be brought into operation in a very short time.

MATi systemsThese systems (MATi = Metrohm Automated Titra-tion) have been designed for various standard applica-tions and offer maximum convenience and flexibility. A total of eight different fully automated systems provide the perfect base for analysing your samples.

Compact Titrosampler packagesEach Compact Titrosampler package covers a standard application – on a minimum footprint. The «Food/Bev-erage» and «Salt» packages contain all the accessories needed for the corresponding application, thus allow-ing you to start working immediately – simply install and get going.

Robotic AnalyzersThe Robotic Analyser family consists of different pack-ages, each covering a standard application. Each of these packages offers the perfect system to meet your particular application challenge. The heart of the pack-age is always the 855 Robotic Titrosampler, the space-saving combination of a titrator built into a sample changer. Depending on the application, this titrating analyzer is equipped with the necessary accessories.

Because of the high flexibility offered by Metrohm automation, the systems can be adapted and custom-ized on request.

Automation in titration

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Titrationssysteme848 Titropackage plus

Compact and economical system for automating potentiometric determinations on a minimum foot-print.

Includes the following instruments:1 x 848 Titrino plus1 x 802 Stirrer1 x 869 Compact Sample Changer

848 Titropackage plus contains everything needed for the quick installation of and familiarisation with the system. Numerous predefined titration methods com-bined with the easy control allow it to be used on the spot. The system consists of an 848 Titrino plus, 869 Compact Sample Changer, 802 Rod stirrer with stirring propeller, the Ecotrode Plus and further accessories.

Titrino plus

Titrino plus, Metrohm's entry class in potentiometric titration offers great value for money. A large live dis-play with titration curve, plug-and-play functionality of Exchange Unit, stirrer and USB printer, a high-precision measuring input, operation by mouse click – Titrino plus offers considerably more than the average instru-ment in this price category. With their operating dia-logue tailored to the needs of routine users, the Titrino plus instruments are so easy to use that hardly any familiarization is required. Their robustness makes them the ideal instruments for routine determinations in day-to-day laboratory work.

Compact Sample Changer

For multiple determinations and small series of sam-ples, this sample changer is exactly the right choice. With a total of 12 positions a wide range of titrations can be carried out fully automatically and the electrode rinsed and/or conditioned between determinations. In order to keep titrant and solvent consumption as low as possible, narrow sample beakers are used as stan-dard, thus allowing a waste-efficient and fast titration procedure. The large and clearly arranged live display informs the user about the current status of the sample series and allows the series to be interrupted for the determination of samples with higher priority. As lab space is both scarce and expensive, the 869 Compact Sample Changer needs only the bench space of a typi-cal analytical balance.

Ordering information2.848.0110 848 Titropackage plus2.848.0120 Titropackage plus with printer

848 Titropackage plus

Automation in titration

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MATi systemsFully automated water analysis

Fully automated and PC-controlled system for water analysis equipped with a dosing device enabling the quick and precise transfer of 100 mL water samples. After the conductivity measurement the pH value, alkalinity plus Ca and Mg content are analyzed in an external cell. A maximum of 59 samples can be placed on a rack. The fully automated water analysis system is controlled by the proven tiamo™ titration software.

The system consists of:1 x 815 Robotic USB Sample Processor XL2 x 786 Swing Head1 x 905 Titrando1 x 854 iConnect3 x 800 Dosino1 x 856 Conductivity Module1 x 802 Stirrer1 x 804 Ti Stand

Ordering informationMATi 01 Fully automated water analysis

Automated TAN/TBN Analysis

Computer-controlled and fully automated titration system for direct potentiometric determination of TAN and TBN values in petroleum products in series of up to 59 samples. The analysis follows the ASTM norms D664 and D2896. The system is characterized by the excellent resistance against the solvents used for this apllication. Data is collected and the system con-trolled by the tiamo™ titration software.

The system consists of:1 x 815 Robotic USB Sample Processor XL1 x 786 Swing Head1 x 905 Titrando1 x 854 iConnect2 x 800 Dosino1 x 843 Pump Station1 x 802 Stirrer

Ordering informationMATi 02 Automated TAN/TBN Analysis

Automation in titration

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Non-aqueous titrations

Direct non-aqueous titration of pharmaceutical ingre-dients and other samples in series of up to 59 samples. The system is characterized by its special resistance against solvents. It is controlled by the tiamo™ titra-tion software.

The system consists of:1 x 815 Robotic USB Sample Processor XL1 x 786 Swing Head1 x 905 Titrando1 x 854 iConnect2 x 800 Dosino1 x 843 Pump Station1 x 802 Stirrer

Ordering informationMATi 03 Non-aqueous titrations

Automated coulometric KF titrations

MATi 4 is a fully automated system for coulometric KF titrations with high sample throughput. The sample rack of the Sample Processor accommodates up to 160 samples in 6-mL-vials. The samples are transferred to an external coulometric cell where KF titration is carried out. The system is controlled by the tiamo™titration software.

The system consists of:1 x 815 Robotic USB Sample Processor XL1 x 786 Swing Head1 x 851 Titrando1 x 800 Dosino1 x 801 Stirrer

Ordering informationMATi 04 Automated coulometric KF titrations

Automation in titration

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Automated titration of acids and bases

Fully automated system for the potentiometric titration of acids and bases in series of up to 12 samples. The titration is carried out directly inside the beaker on the rack. Afterwards the electrode is cleaned automatically and the beakers are emptied using the membrane pumps of the Sample Processor. The system is control-led by the user-friendly tiamo™ titration software.

The system consists of:1 x 814 USB Sample Processor1 x 905 Titrando1 x 854 iConnect1 x 800 Dosino1 x 802 Stirrer

Ordering informationMATi 06 Automated titration of acids and bases

Automated titration system for up to 28 samples

Fully automated system for the determination of potentiometric titrations like acid/base/redox and halide titrations in series of up to 28 samples. The system is controlled by the tiamo™ titration software. After the determination the titration equipment is cleaned and the beaker is emptied automatically.

The system consists of:1 x 815 Robotic USB Sample Processor XL1 x 786 Swing Head1 x 905 Titrando1 x 854 iConnect1 x 800 Dosino1 x 802 Stirrer

The electrode must be chosen separately according to the selected application.

Ordering informationMATi 07 Automated titration system for up to

28 samples

Automation in titration

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Automated pipetting and titrating system for up to 100 samples

Automated system for potentiometric titrations of acids and bases. Up to 100 samples can be placed on the sample rack. The sample is pipetted from the sample beaker to the external titration vessel and is analyzed fully automatically. The amount of sample to be pipet-ted can be chosen freely in the range from 0.5 to 9.0 mL. After the titration the external vessel is cleaned thoroughly by means of the membrane pumps of the Sample Processor. The system is controlled by the tiamo™ titration software.

The system consists of:1 x 815 Robotic USB Sample Processor XL1 x 786 Swing Head1 x 905 Titrando1 x 854 iConnect2 x 800 Dosino1 x 802 Stirrer1 x 804 Ti Stand

Ordering informationMATi 08 Automated pipetting and titrating sys-

tem for up to 100 samples

Automated volumetric KF titrations

Fully automated system for volumetric Karl Fischer water determination in up to 24 samples. The system is controlled by tiamo™ and consists of an 814 USB Sample Processor, an 901 Titrando and numerous accessories.

The samples are weighed out into beakers, sealed to protect them against atmospheric moisture and placed on the rack. Prior to titration the samples are dissolved in a known amount of KF working medium and the water content is then titrated in a second step.

This method is particularly suitable for samples that dissolve quickly in the KF working medium. The solubi-lity can also be improved by using a suitable solubility promoter.

The system consists of:1 x 814 USB Sample Processor1 x 901 Titrando2 x 800 Dosino1 x 741 Stirrer

Ordering informationMATi 10 Automated volumetric KF titrations

Automation in titration

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Automated volumetric KF titration including sample preparation

Fully automated system for volumetric Karl Fischer water determination in up to 53 samples. The system is controlled by tiamo™ and consists of an 815 USB Sample Processor XL, an 901 Titrando and numerous accessories.

The samples are weighed out into beakers, sealed to protect them against atmospheric moisture and placed on the rack. Prior to titration a known amount of KF reagent is added and the sample comminuted using a Polytron. In a second step the water content is titrated.

With the Polytron the samples are crushed into small pieces and the contained water is released. This method is also suitable for the analysis of hardly solu-ble samples (e.g. tablets). In many cases solubility pro-moters can thus be avoided.

The system consists of:1 x 815 USB Sample Processor XL1 x 901 Titrando1 x Polytron1 x 772 Pump Unit2 x 800 Dosino2 x 786 Swing Head

Ordering informationMATi 11 Automated volumetric KF titration

including sample preparation

Automated COD determination

Automated system for the potentiometric determina-tion of COD samples in series of up to 21 samples. The titration is carried out directly inside the reaction vessel on the rack. Afterwards the electrode equipment is automatically cleaned using the internal membrane pumps and the reaction tube is emptied. The system is controlled by the titration software tiamo™.

Consists of:1 x 814 USB Sample Processor1 x 905 Titrando1 x 854 iConnect5 x 800 Dosino1 x 741 Stirrer

Ordering informationMATi 12 Automated COD determination

Automation in titration

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Compact Titrosampler packages862 Food/Beverage Compact Titrosampler

• Compact and economical titration automat• Easy installation and control• Intelligent Dosing Unit with monitoring of the titrant• «Ready-to-use»• Highest precision thanks to high resolution measur-

ing input• Live curve• Compact USB printer optional

Compact and economical device for the automatic deter-mination of most potentiometric analyses in the food industry. Equipped with a large number of accessories, the 862 Food/Beverage Compact Titrosampler can be used on the spot.

Winner of the 2009 Silver IBO Design Award!

Consisting of:

1 x 862 Compact Titrosampler1 x 802 Stirrer1 x 800 Dosino

Ordering information2.862.1010 862 Food/Beverage Compact

Titrosampler

862 Food/Beverage Compact Titrosampler with accessories

862 Food/Beverage Compact Titrosampler with printer

• Compact and economical titration automat• Easy installation and control• Intelligent Dosing Unit with monitoring of the titrant• «Ready-to-use»• Highest precision thanks to high resolution measur-

ing input• Live curve• Compact USB printer

Compact and economical device for the automatic determination of most potentiometric analyses in the food industry. Equipped with comprehensive accesso-ries, the 862 Food/Beverage Compact Titrosampler can be used on the spot.

Winner of the 2009 Silver IBO Design Award!

Consisting of:

1 x 862 Compact Titrosampler1 x 802 Stirrer1 x 800 Dosino1 x USB Thermal printer Neo’s

Ordering information2.862.1110 862 Food/Beverage Compact

Titrosampler with printer

862 Food/Beverage Compact Titrosampler with accessories and printer

Automation in titration

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862 Salt Compact Titrosampler

• Compact and economical titration automat• Easy installation and control• Intelligent Dosing Unit with monitoring of the titrant• «Ready-to-use»• Highest precision thanks to high resolution measur-

ing input• Live curve• Compact USB printer optional

The 862 Salt Compact Titrosampler consists of a com-plete package for the analysis of chloride in different samples. The accessories included are exactly suited to this kind of application and allow easy and quick installation.

Winner of the 2009 Silver IBO Design Award!

Consisting of:

1 x 862 Compact Titrosampler1 x 802 Stirrer1 x 800 Dosino

Ordering information2.862.2010 862 Salt Compact Titrosampler

862 Salt Compact Titrosampler with accessories

862 Salt Compact Titrosampler with printer

• Compact and economical titration automat• Easy installation and control• Intelligent Dosing Unit with monitoring of the titrant• «Ready-to-use»• Highest precision thanks to high resolution measur-

ing input• Live curve• Compact USB printer

The 862 Salt Compact Titrosampler consists of a com-plete package for the analysis of chloride in different samples. The included accessories are exactly suited for this kind of application and allow easy and quick installation as well as a clearly arranged documentation of the results by USB printer.

Winner of the 2009 Silver IBO Design Award!

Consisting of:

1 x 862 Compact Titrosampler1 x 802 Stirrer1 x 800 Dosino1 x USB Thermal printer Neos

Ordering information2.862.2110 862 Salt Compact Titrosampler with

printer

862 Salt Compact Titrosampler with accessories and printer

Automation in titration

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Robotic Analyzers

Robotic Chloride Analyzer (2.855.1010)

• Robotic Analyzer• Including optimal electrode and application information• Space-saving due to compact design• Fully automated sample preparation• Highest level of control with simple programming

The complete package for the determination of chloride. Contains all the components required for a fast and fully automated chloride titration on the smallest possible footprint. Instruments, accessories, software and appli-cation know-how – simply all-inclusive.

Including the following instruments:1 x 855 Robotic Titrosampler1 x 772 Pump Unit1 x 802 Rod stirrer2 x 800 Dosino

Robotic Chloride Analyzer

Robotic Acid-Base Analyzer (2.855.1020)

• Robotic Analyzer • Including optimal electrode and application information• Space-saving due to compact design• Fully automated sample preparation• Highest level of control with simple programming

The complete package for the determination of acids or bases. Contains all the components required for a fastand fully automated acid/base titration on the smallest possible footprint. Instruments, accessories, software and application know-how – simply all-inclusive.

Including the following instruments:1 x 855 Robotic Titrosampler1 x 802 Rod stirrer1 x 800 Dosino

Robotic Acid-Base Analyzer

Automation in titration

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Robotic TAN/TBN Analyzer (2.855.2010)

• Robotic Analyzer• Including optimal electrode and application information• Space-saving due to compact design• Fully automatic sample preparation• Highest level of control with simple programming

The complete package for the determination of TAN and/or TBN. Contains everything required for fast and fully automated TAN/TBN titration on the smallest pos-sible footprint. Instruments, accessories, software and application know-how – simply all-inclusive.

Including the following instruments:1 x 855 Robotic Titrosampler1 x 772 Pump Unit1 x 802 Rod stirrer2 x 800 Dosino

Robotic TAN/TBN Analyzer

Robotic Fluoride Analyzer (2.855.2020)

• Robotic Analyzer• Including optimal electrode and application information• Space-saving due to compact design• Fully automatic sample preparation• Highest level of control with simple programming

The complete package for the determination of the fluo-ride content. Contains all the components required for fast and fully automated fluoride determination on the smallest possible footprint. Instruments, accessories, soft-ware and application know-how – simply all-inclusive.

Including the following instruments:1 x 855 Robotic TItrosampler 1 x 802 Rod stirrer2 x 800 Dosino

Robotic Fluoride Analyzer

Automation in titration

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Robotic Transfer Analyzer (2.855.3020)

• Robotic Analyzer• Including optimal electrode and application information• Space-saving due to compact design• Fully automatic sample preparation• Highest level of control with simple programming

The complete package for the determination of acid and base content in large numbers of samples. Contains all the components required for a fast and fully auto-mated acid/base titration on the smallest possible foot-print. Instruments, accessories, software and application know-how – simply all-inclusive.

Including the following instruments:1 x 855 Robotic Titrosampler1 x 802 Rod stirrer1 x 804 TI Stand2 x 800 Dosino

Robotic Transfer Analyzer

Automation in titration

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Automation in titration

weighing in

transferring

dispensing

diluting

dissolving

dosing

pipetting

direct measurement

standard addition

volumetric

coulometric

ICP

AAS

IC

VA

efficient spray nozzles

simple dipping

carryover-free aspiration

diaphragm pumps

solvent-resistant peristaltic pumps

sealed vessel

dilutions

Karl Fischer titration

potentiometrictitration

parallel titrations

ion measurement

open vessel

stirring

heating

cooling

degassing

homogenizing

filtering

extracting

rod stirrer

magnetic stirrer

externally

homogenizer

rod stirrer

magnetic stirrer

with filter exchange

racks forany requirements

max. 999

freely definable

max. 250 mL

Robot-likesample

processing

Sample preparation

rinsing

Applications

flexibility

high mechanicalprecision

positioning

sample volume

general

extendedLiquid Handling

Sample preparation in overview

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Systems for sample preparationRobotic Soliprep

For a long time now Metrohm's automation program has enabled the transfer of titration applications to a fully automated system. The Robotic Soliprep is a new version of the proven 815 Robotic USB Sample Proces-sor which makes daily routine work much easier. The primary field of application of the Robotic Soliprep sys-tems is professional sample preparation.

The Robotic Soliprep family consists of three packages that cover various standard sample preparation steps.

The Robotic Titration Soliprep enables homogenizing and titrating solid samples quickly and conveniently. A maximum of 59 samples can be processed in a single series; any volume between 50 and 100 mL is possible, depending on the application. The sample only needs to be weighed out into the beaker and placed on the sample rack. The sample is then comminuted by the Polytron 1300 D. After homogenization the sample is titrated.

The Robotic Filtration Soliprep enables homogeniz-ing and filtering solid samples fast and with maximum convenience. Up to 24 samples can be placed on the rack. The sample is comminuted by the Polytron 1300 D.During the following preparation steps the Polytron tool is rinsed at the external rinsing station. After homoge-nization an aliquot of the sample is aspirated and then filtered through a standard syringe filter (Luer connec-tion). The Dosino dosing system used for sample trans-port forces the sample through the filter at a constant speed ensuring optimum filtration results. Needle

and filter are changed for each sample and are safety ejected into the collection container after use.

The Robotic Flexible Soliprep enables homogeniz-ing, filtering and diluting solid samples fast and with maximum convenience. Up to 10 samples can be placed on the rack. All further steps are carried out as described for the Robotic Filtration Soliprep. The filtrate can then be pipetted either directly or after additional dilution into septum-sealed vials (11.6 mm).

Once the series has been processed, the samples can be easily removed from the rack in order to place them on the analyzer (e.g. IC or HPLC). The control of this preparation system is carried out by the tiamo™ titra-tion software, which also documents the individual preparation steps for each sample in a database.

Ordering information2.815.1110 815 Robotic Titration Soliprep2.815.2110 815 Robotic Flexible Soliprep2.815.3110 815 Robotic Filtration Soliprep

815 Robotic Filtration Soliprep

Automation in titration

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Peripheral devices for automationMembrane pumps

Titration often requires the pumping of liquids. With automation in particular, the aspiration of the titrated sample solution is very convenient. After the pre-pro-grammed rinsing and aspiration cycles have been car-ried out automatically, the cleaned sample beakers and electrodes used are ready for the next determination. The waste is transferred to a canister for convenient disposal.

The 823 Membrane Pump is a very versatile pump. It has been specially designed for use in factories and laboratories and can be used for a wide range of appli-cations. It is suitable for transferring all types of liquid media and, with its capacity of at least 450 mL/min, opens up a wide range of applications.

The 843 Pump Station (membrane) has two built-in membrane pumps. These can be controlled either via the interface by remote signals or manually by pressing keys.

Both instruments are available in different versions; these mainly differ in the accessories they are supplied with.

Ordering information2.823.0010 823 Membrane Pump Unit2.823.0020 823 Membrane Pump Unit «aspirate»2.823.0030 823 Membrane Pump Unit «rinse»2.843.0020 843 Pump Station (membrane)2.843.0030 843 Pump Station (membrane) - rinse/

aspirate for Compact Sample Changer2.843.0050 843 Pump Station (membrane) - rinse/

aspirate for Sample Processors

843 Pump Station (membrane)

Automation in titration

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Peristaltic pumps

Titration often requires the pumping of liquids. With automation in particular, the aspiration of the titrated sample solution is very convenient. After the pre-pro-grammed rinsing and aspiration cycles have been car-ried out automatically, the cleaned sample beakers and electrodes are ready for the next determination. The waste is transferred to a canister for convenient dis-posal. Membrane pumps cannot be used with liquids that contain solids such as precipitated silver chloride.

In this case a persitatlic pump like the 772 Pump Unit is the preferred choice, as it enables the use of tubing made of different materials, which can be chosen according to the medium to be pumped. The Pump Unit comes with one piece of tubing for aque-ous media and another one for organic solvents as standard.

The 843 Pump Station (peristaltic) has two built-in peristaltic pumps. These can be controlled either via the interface by remote signals or manually by pressing keys.

Both instruments are available in several versions; these mainly differ in the accessories supplied with them.

Ordering information2.772.0110 772 Pump Unit2.772.0120 772 Pump Unit «aspirate»2.772.0130 772 Pump Unit «rinse»2.772.0210 772 Pump Unit for 731/8242.772.0220 772 Pump Unit for 731/824: aspirate2.772.0230 772 Pump Unit for 731/824 «rinse»2.843.0120 843 Pump Station (peristaltic)2.843.0130 843 Pump Station (peristaltic) - rinse/

aspirate for Compact Sample Changer2.843.0150 843 Pump Station (peristaltic) - rinse/

aspirate for Sample Processors

843 Pump Station (peristaltic)

Automation in titration

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26 — AT

849 Level Control

Additional equipment for Sample Processors for moni-toring the filling level of rinsing or waste canisters via Remote. It prevents pumps from running dry and/or canisters from overflowing and is suitable for use with aqueous solutions, solvents and suspensions.

The 849 Level Control can register both high liquid levels (e.g. warning that a waste container is about to overflow) and low liquid levels (e.g. storage container is about to run dry). Thanks to the conductivity mea-surement technique the level sensors can be used in different media.

The sensor signal is registered by the Level Control and transmitted as a signal level to a remote connection of an automated system. This means that the 849 Level Control can be used in all Metrohm systems in which it is possible to scan remote lines.

Ordering information2.849.0010 849 Level Control2.849.0020 849 Level Control MF (for canisters)2.849.0030 849 Level Control MF (for bottles)

849 Level Control with canister

Automation in titration

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731 Relay Box

• Two 115/230 V AC outputs• Two DC outputs• One standard cable is sufficient for communication

with all Metrohm instruments

Additional device for controlling up to four external devices such as pumps or valves with mains connection or direct current consumers via TTL signals, including connection cable for devices with a 25-pin «remote» interface.

Automated systems require the switching of heaters, pumps, valves, thermostats or other external devices. This requires the use of relays to switch mains or low-voltage supplies on and off as necessary. The switching should take place via remote lines from a Titrino, Tit-rando, sample changer or other Metrohm instrument. The Relay Box meets all these requirements on a very small footprint.

The Relay Box provides four voltage outputs. Two 115/230 V AC outputs are used for switching the mains voltage. The maximum power delivery per out-put is 1'150 W, so that the instrument can also be used for providing power to high-consumption devices such as heating baths or thermostats.

In addition, the Relay Box has two DC outputs, whose voltages can be set to 5, 10, 18 or 24V.

Various Metrohm devices can be connected to the Relay Box via their remote interfaces. Regardless of the type of device, a single standard cable is all that is required for communication. The Relay Box scans the 14 input lines and switches the assigned voltage out-puts accordingly.

Ordering information2.731.0010 731 Relay Box

731 Relay Box

Automation in titration

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Swing Heads

Additional equipment for the Robotic Sample Proces-sor XL for transferring / pipetting from smaller sample vessels into larger titration vessels on a rack or into an external titration cell that can be attached to the side of the work station.

With a Swing Head, the number of samples and their sizes can be varied within a wide range. This increased flexibility results from the considerable extension of the range of positions that can be reached on the Sample Processor. The Swing Head works with highest accu-racy: it moves pipette / transfer tips from one position to the next, millimetre by millimetre. Even sample transfer into an external titration cell is carried out fully automati-cally, thus greatly increasing the flexibility of the Sample Processor. While the transferred sample is analyzed in the cell, the next sample is already being prepared; this means an additional gain in time. In addition, the Swing Head can also be equipped with Robotic Arms that can take up and eject tools or serve as a holder for a homogenizer for comminuting tablets.

Ordering information2.786.0010 786 Swing Head with transfer head left2.786.0020 786 Swing Head with transfer head right2.786.0030 786 Swing Head with titration swing arm,

left- or right-swinging2.786.0040 786 Swing Head2.786.0240 786 Swing Head, right-swinging,

reinforced

Reinforced 786 Swing Head

Automation in titration

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741 Stirrer

Magnetic stirrer for sample changers.

The magnetic stirrer is located beneath the sample rack.

Ordering information2.741.0010 741 Stirrer

802 Stirrer

Rod stirrer for sample changer and Sample Processor.

With 6.1909.020 Propeller stirrer 104 mm and fixed cable.

Ordering information2.802.0020 802 Stirrer

802 Stirrer

Automation in titration

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Polarography, voltammetry and CVS

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Polarography, voltammetry and CVS

heavy metals in water up to the measurement of the concentration of organic

Polarography, voltammetry and CVS

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1 — VA

Introduction Metal traces: total metal and species analysis – quick and easy with voltammetry VA. 2 Determination of additives in electroplating baths VA. 3

Instruments for trace analysis and CVS 797 VA Computrace VA. 4

MVA accessory sets MVA-Hg, equipment for mercury determination VA. 5 MVA-As, equipment for arsenic determination VA. 5 MVA-CVS, equipment for CVS VA. 5

Automation in VA 863 Compact VA Autosampler VA. 7 838 Advanced VA Sample Processor VA. 8

MVA – Metrohm VA systems MVA systems for trace analysis

797 VA Computrace system for trace analysis VA. 10 797 VA Computrace system for trace analysis with automatic standard addition VA. 10 Fully automated 797 VA Computrace system for trace analysis VA. 10

MVA systems for CVS 797 VA Computrace system for CVS VA. 11 797 VA Computrace system for CVS with automatic solution addition VA. 11 797 VA Computrace system for fully automated CVS VA. 11

Instruments for sample preparation 705 UV Digester VA. 12

Contents

Instruments for polarography, voltammetry and CVS

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2 — VA

SbIII / SbV 200 pptAsIII / AsV 100 ppt Bi 500 pptCd 50 pptCrIII / CrVI 25 pptCo 50 pptCu 50 pptFeII / FeIII 50 pptPb 50 pptHg 100 pptMoIV / MoVI 50 pptNi 50 pptPt 0.1 pptRh 0.1 pptSeIV / SeVI 300 pptTl 50 pptW 200 pptU 25 pptZn 50 ppt

1 ppt = part per trillion = 1 ng/kg

IntroductionMetal traces: total metal and species analysis – quick and easy with voltammetry

Voltammetry instruments from Metrohm are affordable, have low running costs, compact dimensions and are great in detecting.

Traces of toxic heavy metals can be analyzed at extremely low concentrations without much trouble. The detec-tion limits are all in the ppt range, so that the neces-sary sensitivity can always be achieved. For speciation of analytes voltammetry is the method of choice.

Trace metal analyses can be carried out with the same or better sensitivity for a fraction of the cost of acquir-ing an AAS or ICP instrument. The low running costs are an additional bonus point for voltammetry. Apart from small amounts of reagents only small volumes of pure nitrogen are required. No expensive combustible gases, no reconstruction of the laboratory for special gas supplies and fume hoods, no expensive lamps. And no time-consuming calibration of the analytical system.

Convincing applications

Analysis of metal traces

Total concentration can be determined by both voltam-metry and spectroscopic methods. With voltammetry, however, it is possible to distinguish between the dif-ferent oxidation states of metal ions and to specify the biological availability of heavy metals. Free and bound metal ions can be differentiated from each other. This makes voltammetry an essential tool for environmental analysis. Spectroscopy allows comparable statements

to be made only after complicated separation of metal species. Due to the compact size the instrument can also be used in mobile laboratories.

Samples with a high ionic concentration are not a problem for voltammetry. Voltammetry is also pre-destined for the analysis of:

• water, wastewater and sea water• foodstuffs• salts, pure chemicals• electroplating baths

Specific analysis of organic chemicals

Not only metals but also various organic compounds can be determined by voltammetry. The technique is used in organic chemistry, e.g. for the analysis of contaminants, and in the pharmaceutical industry for the determination of the concentration of the active substance.

Examples of interesting determinations

• 4-carboxybenzaldehyde in terephthalic acid• free styrene in polystyrene• vitamins in fruit and vegetable juices, vitamin

formulations

Determination of anions

Some anions can also be determined by voltammetry. The analysis of the following anions is particularly interesting:

• cyanide• sulfide• nitrite• nitrate• iodide

Typical detection limits in voltammetric trace analysis

Instruments for polarography, voltammetry and CVS

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3 — VA

CVS – Cyclic Voltammetric Stripping Determination of additives in electroplating baths

Cyclic Voltammetric Stripping Analysis (CVS) and Cyclic Pulse Voltammetric Stripping Analysis (CPVS) are wide-spread methods used in the plating industry for the determination of organic additives in electroplating baths. A simple, robust and favorably-priced rotating disk electrode made of platinum is used for these analy-ses; this electrode is built into the VA stand instead of the otherwise used Multi-Mode Electrode.

For many technical coatings, particularly in PCB manu-facture in the electronics industry, this method is an essential part of the production control process. The most important fields of application are acid cop-per baths as well as tin-lead baths. The quantitative determination of the additives is carried out using their influence on the deposition of the main components of the electroplating bath. As the measurement corre-sponds to a process which is similar to the production process, the activity of the additives and therefore their effectiveness in the electroplating process is measured directly.

Quantification of the various types of additives requires special calibration techniques; these are all implemented in the 797 VA Computrace: The so-called brighteners are determined by using the Linear Approximation Technique (LAT) or the Modified Linear Approximation Technique (MLAT). Dilution Titration (DT) is used for the determination of the suppressors.

With CVS or CPVS the concentration of the additives can be determined exactly. The effective concentration of the particular additive in the bath sample is shown directly and printed out in mL additive per liter bath. This means that topping up to achieve the set concen-tration can be carried out very exactly. This guarantees continuous interference-free operation of the unit. Accuracy of analytical results in particular has helped this method to become widely accepted in the electro-plating industry.

Other methods, such as the classical Hull cell method, do not allow the concentration to be determined, but can only be used to assess the quality of the metallic layer that has been deposited.

To carry out the determination one of the pre-installed methods is loaded. After a few parameters have been adapted, the analysis can be started. Ready-to-use methods are included for the most important bath types from leading manufacturers; these methods have been worked out in our application laboratory.

Measuring head with rotating platinum electrode for the determina-tion of additives in plating baths by CVS

Instruments for polarography, voltammetry and CVS

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4 — VA

Instruments for voltammetry and CVS797 VA Computrace

Simple operation

The 797 VA Computrace is a VA Stand with built-in potentiostat/galvanostat connected to a PC via the USB port. Control, data acquisition and evaluation are car-ried out by the PC software supplied, which runs under Microsoft Windows™ 2000, Windows™ XP Profes-sional, Windows™ Vista and Windows™ 7. Due to the well-laid-out program structure the simplicity of opera-tion is unsurpassed. All the methods described in the Metrohm Application Bulletins and Application Notes have already been pre-installed. Method modifications require changing of only a few parameters.

Fields of application

Classical trace analyses

Trace analysis of metal ions or other analytes after cali-bration by standard addition or calibration curve down to the ultratrace range (ppt) is one of the most impor-tant fields of application of the 797 VA Computrace. Evaluation is carried out automatically and can be con-trolled and reprocessed at the PC. Standard additions can, of course, be carried out automatically by using Dosinos.

Determination of additives in electroplating baths

These new methods are the second most important field of application. With the 797 VA Computrace the determination of additives in electroplating baths is possible for the first time. All the necessary techniques for data recording, evaluation and calibration have

been implemented in the software; methods for impor-tant, often used bath chemicals have already been optimized and pre-installed.

Only with the 797 VA Computrace is it possible to carry out CVS analyses and classical trace metal determination with a single instrument. This means that both investment costs and running costs can be reduced, as can the familiarization time for the operat-ing staff.

«Exploratory» mode for method development and training

The «Exploratory» is characterized by an intuitive user interface. This has been reduced to the most important functions that are necessary for carrying out simple electrochemical experiments. After entering a few parameters a voltammogram can be taken; the effects of changing parameter settings on the curve can be seen directly. A direct comparison of the voltammo-grams is the greatest strength of the «Exploratory» mode. It has been specially developed for training pur-poses in electrochemistry, but also helps in developing the optimal method for solving an analytical problem.

Proven working electrodes

The time-proven Multi-Mode Electrode (MME) or rotat-ing disk electrodes made from various materials are used as sensors.

Ordering information2.797.0010 797 VA Computrace for trace analysis2.797.0030 797 VA Computrace for CVS

797 VA Computrace

Instruments for polarography, voltammetry and CVS

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5 — VA

MVA accessory kits

MVA-Hg, equipment for mercurydetermination (6.5327.000)

Complete set of accessories for the determination of mercury as per Application Bulletin 96. Contains rotat-ing gold working electrode, reference electrode, glassy-carbon auxiliary electrode and other accessories.

MVA-As, equipment for arsenic determination (6.5327.010)

Complete set of accessories for the determination of arsenic as per Application Bulletin 226. Contains rotat-ing gold working electrode, reference electrode, glassy-carbon auxiliary electrode and other accessories.

MVA-CVS, equipment for CVS (6.5327.020)

Complete set of accessories for the determination of organic additives in electroplating baths by CVS (cyclic voltammetric stripping). Contains rotating platinum working electrode, reference electrode, platinum auxil-iary electrode and other accessories.

Instruments for polarography, voltammetry and CVS

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6 — VA

Automation in VA

Automation in voltammetry – simple and efficient

Instruments for polarography, voltammetry and CVS

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7 — VA

Compact sample changer for VA863 Compact VA Autosampler

The 863 Compact VA Autosampler is the space-saving and affordable sample changer for voltammetric trace analysis in combination with the 797 VA Computrace. It permits the determination of small series of similar samples with a high degree of accuracy.

Up to 18 samples can be analyzed automatically in a series. The sample solution is transferred from the sample rack of the 863 Compact VA Autosampler to the measuring vessel of the 797 VA Computrace using the built-in peristaltic pump. All auxiliary solutions nec-essary for the voltammetric determination are added from Dosinos during the measuring procedure. The two pumps of the connected 843 Pump Station empty and rinse the vessel after each determination. The 863 Compact VA Autosampler is programmed via the built-in keyboard.

The scope of delivery includes a built-in sample rack,extensive accessories and connection cables for setting up a complete workplace.

Ordering information2.863.0020 863 Compact VA Autosampler

Options2.843.0040 843 VA Membrane Pump Station2.843.0140 843 VA Peristaltic Pump Station

863 Compact VA Autosampler

Instruments for polarography, voltammetry and CVS

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8 — VA

Flexible sample changer for CVS838 Advanced VA Sample Processor

The 838 Advanced VA Sample Processor together with the 797 VA Computrace permits the fully automatic determination of organic additives in electroplating baths by using «Cyclic Voltammetric Stripping» (CVS). Series of brighteners or suppressors can be analyzed unattended in succession. The sample rack provided accommodates up to 56 samples.

The sample solution is transferred from the sample vessel on the rack of the 838 Advanced VA Sample Processor to the measuring vessel of the 797 VA Com-putrace either by using the built-in peristaltic pump for determining brighteners or an 800 Dosino for deter-mining suppressors by dilution-titration technique (DT). Further auxiliary solutions necessary for CVS analysis are automatically added by additional 800 Dosinos. The connected 843 Pump Station empties and rinses the vessel after each determination.

The 838 Advanced VA Sample Processor is equipped with a flexible method editor in order to adapt the analytical sequence to meet the user's requirements. The separate keyboard allows access to the method editor and all other instrument settings. During the determination of a sample series the 838 Advanced VA Sample Processor is remote controlled by the 797 VA Computrace.

The scope of delivery includes accessories, sample rack, keyboard and all accessories for setting up a complete workplace.

Ordering information2.838.0310 838 Advanced VA Sample Processor

Options2.843.0040 843 VA Membrane Pump Station2.843.0140 843 VA Peristaltic Pump Station

838 Advanced VA Sample Processor

Instruments for polarography, voltammetry and CVS

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9 — VA

MVA – Metrohm VA systems

Complete voltammetry systems – customized for each application

The Metrohm MVA systems are complete, ready-to-use packages customized to meet a wide range of require-ments. Just select the package, connect it to a supply of nitrogen and to a PC and you are ready to start.

From a simple-to-operate voltammetric first-user system up to completely unattended, fully automatic analysis systems for process control, you will find the right system for your demands in our portfolio. Each MVA system is supplied with all the necessary accessories. Not included in the scope of delivery are the PC, and, if required, nitrogen and mercury. For special applications the MVA accessory kits (MVA-UV, MVA-Hg, MVA-As and MVA-CVS) can be used together with the basic MVA systems to extend the range of applications.

Instruments for polarography, voltammetry and CVS

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10 — VA

MVA systems with the 797 VA Computrace for classical trace analysis

797 VA Computrace system for trace analysis (MVA-01)

Analysis system for voltammetric trace analysis and training. For manual operation. The system is suitable for quantitative analysis in routine and research labora-tories. Consisting of 797 VA Computrace. Without PC.

797 VA Computrace system for trace analysis with automatic standard addition (MVA-02)

Analysis system for voltammetric trace analysis and training. Consisting of 797 VA Computrace with two 800 Dosinos for automatic addition of auxiliary solu-tions. Without PC.

Fully automated 797 VA Computrace system for trace analysis (MVA-03)

Fully automatic analytical system for voltammetric trace analysis and education. Consists of 797 VA Computrace with 863 Compact VA Autosampler and two 800 Dosinos for automatic addition of auxiliary solutions. Automatic processing of max. 18 samples. This system is the optimum solution for automatic analysis of small series of samples that have to be analyzed for a single or two parameters in one run. Without PC.

Instruments for polarography, voltammetry and CVS

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11 — VA

MVA systems with the 797 VA Computrace for the determination of organic additives in electro-plating baths by CVS

797 VA Computrace system for CVS (MVA-11)

Analysis system for the determination of organic addi-tives in electroplating baths by CVS technique («Cyclic Voltammetric Stripping»). Consisting of 797 VA Com-putrace for CVS. All additions of solutions are carried out manually. Without PC.

797 VA Computrace system for CVS with automatic solution addition (MVA-12)

Analysis system for the determination of organic addi-tives in electroplating baths by CVS technique («Cyclic Voltammetric Stripping»). Consists of 797 VA Compu-trace for CVS with three 800 Dosinos for automatic addition of auxiliary solutions and sample. Without PC.

797 VA Computrace system for fullyautomated CVS(MVA-13)

Analysis system for the determination of organic addi-tives in electroplating baths by CVS technique («Cyclic Voltammetric Stripping»). Consists of 797 VA Compu-trace for CVS, 838 Advanced VA Sample Processor, three 800 Dosinos and rinsing kit. For sample series up to 56 samples. Without PC.

Instruments for polarography, voltammetry and CVS

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12 — VA

Sample preparation for trace analysis705 UV Digester

Digestion is decisive for the reliability of trace and ultra trace analyses in natural sample matrices. The 705 UV Digester is a sample digestion unit proven in prac-tice. It is used for sample preparation in spectroscopy, polarography, voltammetry and ion chromatography to eliminate the organic matrix. ICP-AES, graphite-furnace and flame AAS also benefit from the 705 UV Digester.

The instrument has been designed for the digestion of water samples free from suspended matter that contain low to moderate concentrations of organic material, for example, natural surface waters. Owing to their low content in heavy metals, these samples are very sensitive to contamination. The advantage of UV photolysis is that only a little hydrogen peroxide has to be added and consequently the blank values can be kept very low. Digestion by UV photolysis is based on the photolytic generation of OH radicals, which in turn react with organic compounds and degrade them. Hydrogen peroxide is used as an initiator of the radi-cal reaction. The radiant energy of the mercury lamp is converted to heat and this accelerates the digestion.

• Simultaneous digestion in 12 or 16 quartz sample tubes, depending on the sample volume

• As only minimal amounts of expensive digestion chemicals are needed (typically 50 �L), the blank value is virtually zero

• The costs and the load on the environment are minimal

• The digested solution can be used directly without the need for aliquot sampling or topping up

• The digestion temperature of approx. 90 °C means most effective digestion and practically no losses of volatile elements

Ordering information2.705.0016 705 UV Digester (220V / 60 Hz)2.705.0017 705 UV Digester (220V / 50 Hz)

705 UV Digester

Instruments for polarography, voltammetry and CVS

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Stability measurement

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Stability measurement

Stability measurement

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1 — St

Oxidation stability of fats, oils and fat-containing foods 743 Rancimat ST. 2

Oxidation stability of biodiesel 873 Biodiesel Rancimat ST. 3

Thermal stability of PVC 763 PVC Thermomat ST. 4

Contents

Stability measuring instruments

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2 — St

Oxidation stability of fats, oils and fat-containing foods743 Rancimat

A new era in the determination of the oxidation stability of natural fats and oils

The 743 Rancimat is a modern, PC-controlled instru-ment for the comfortable determination of oxidation stability. Disposable reaction vials reduce the amount of cleaning of the accessories to the absolute minimum. This saves both time and money. In addition, accuracy and reproducibility of results are significantly improved. With the help of the certified temperature sensor in the GLP set it is now possible to adjust the temperature very precisely and reproducibly, which improves the comparability of the results even further. The software of the third Rancimat generation with automatic data recording and evaluation as well as a measurement database allows the management of large amounts of data.

Oxidation stability of natural fats and oils in the food industry

The determination of the oxidation stability of oils and fats is the classical application for the 743 Rancimat. The so-called induction time thus determined char-acterizes the resistance of oils and fats to oxidation. Instead of induction time, the term oil stability index (OSI) is frequently used.

The Rancimat method is an automated version of the previously used and extremely complicated AOM method (Active Oxygen Method). The Rancimat method is used as a standard test in the food indus-

try for quality control during the manufacture of fats and oils or for checking incoming goods in processing industries. In addition to vegetable oils and fats, it is also possible to check the oxidation stability of animal fats such as hog fat, tallow or fish oil. Foodstuffs may contain added antioxidants in order to slow down the oxidative decomposition of the oils and fats. By using the 743 Rancimat it is possible to characterize the effectiveness of antioxidants.

Standards

• AOCS Cd 12b-92 (AOCS – American Oil Chemists' Society): Sampling and analysis of commercial fats and oils: Oil Stability Index

• ISO 6886: Animal and vegetable fats and oils – Determination of oxidative stability (accelerated oxidation test)

• 2.4.28.2-93: Fat stability test on Autoxidation. CDM, Japan

Oxidation stability of fat-containing foods

The 743 Rancimat can also be used for the determina-tion of the oxidation stability of foods containing fats. Examples:

• Instant noodles• Nuts, almonds• Cookies, biscuits• Crackers and similar snacks

Oxidation stability of foodstuffs and cosmetics

In addition to foodstuffs, the oxidation stability of cosmetics or cosmetic additives containing fats can be determined with the 743 Rancimat.

Ordering information2.743.0014 743 Rancimat for oils and fats (230 V)2.743.0015 743 Rancimat for oils and fats (115 V)

Options6.5616.000 GLP Test Set for 743 Rancimat and 763

PVC Thermomat

743 Rancimat with laptop PC

Stability measuring instruments

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3 — St

Oxidation stability of biodiesel873 Biodiesel Rancimat

A new era in the determination of the oxidation stability of biodiesel (FAME)

The 873 Biodiesel Rancimat is tailor-made for the determination of the oxidation stability of biodiesel, diesel fuel and mixtures of biodiesel with diesel fuel. The accessories optimized for this application comprise elongated reaction vessels and special, chemically resis-tant connection tubings. To minimize cleaning expen-diture some of the accessories are disposables. This has the added advantage of significantly improving the accuracy and reproducibility of the measurements. The software offers automatic data recording and evalua-tion as well as a measurement database allowing the comfortable management of large amounts of data.

Oxidation stability of biodiesel (fatty acid methyl esters, FAME)

In addition to other alternative fuels such as ethanol, methanol or biogas (methane), fatty acid methyl esters are becoming commercially available; these are also known as biodiesel, RME (rapeseed oil methyl esters) or FAME (fatty acid methyl esters). As an alternative, fatty acid ethyl esters (FAEE) are used in some coun-tries. Biodiesel has a relatively short storage life as it is slowly oxidized by atmospheric oxygen. The substances produced by this decomposition process can cause motor damage. For this reason oxidation stability is an impor-tant quality criterion for biodiesel and is determined re-gularly during manufacture. By using the 873 Biodiesel

Rancimat this determination can be carried out simplyand reliably. The oxidation process can be slowed down by the addition of antioxidants. The 873 Biodiesel Rancimat can also be used for determining the effec-tiveness of antioxidants.

Standards

• EN 14112 «Fat and oil derivatives – fatty acid methyl esters (FAME) – Determination of the oxidation sta-bility (accelerated oxidation test)»

• EN 15751 «Automotive fuels – Fatty acid methyl esters (FAME) and mixtures with diesel – Determi-nation of the oxidation stability (accelerated oxida-tion test)»

Ordering information2.873.0014 873 Biodiesel Rancimat (230 V)2.873.0015 873 Biodiesel Rancimat (115 V)

Options6.5616.010 GLP Test Set for 873 Biodiesel Rancimat

873 Biodiesel Rancimat

Stability measuring instruments

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4 — St

Thermal stability of PVC763 PVC Thermomat

Automatic determination of the thermal stability of PVC

With the 763 PVC Thermomat Metrohm offers the first fully PC-controlled instrument for the determination of the thermal stability of PVC plastics. The software for data recording and storing in a database with auto-matic evaluation of the curves is included in the scope of delivery. Two heating blocks allow the measurement of 8 samples at one or two different temperatures. Up to four 763 PVC Thermomats can be connected to a PC and operated simultaneously by the included soft-ware. Highest flexibility is achieved by individual man-agement of each sample and heating block. Disposable sample reaction vessels reduce the cleaning procedure to a minimum.

Thermal stability of PVC

Chlorinated plastics based on polyvinylchloride (PVC) decompose at elevated temperatures releasing gaseous HCl. This product of the thermal decomposition is blown off by a stream of nitrogen into the measuring cell filled with distilled water. The thermal stability of PVC materials is defined as the time that elapses until HCl is released, and is determined by measuring the conductivity in the measuring cell.

Standards

• DIN 53381 part 1: Determination of the Thermosta-bility of PVC

• DIN VDE 0472 part 614: Examination of insulated cables - Thermostability

• ISO 182-3: Plastics - Determination of the tendency of PVC based polymers to evolve HCl at elevated temperatures - part 3: Conductometric method

Ordering information2.763.0014 763 PVC Thermomat (230 V)2.763.0015 763 PVC Thermomat (115 V)

Options6.5616.000 GLP Test Set for 743 Rancimat and 763

PVC Thermomat

763 PVC Thermomat

Stability measuring instruments

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ProcessLab

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ProcessLab

ProcessLab

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1 — PL

ProcessLab – an introduction PL. 2 The modular analysis system PL. 3 Analysis techniques and parameters PL. 4 Example of a system for one parameter PL. 5 Example of a system for several parameters PL. 6 Example of a ProcessLab VA/CVS System PL. 7 ProcessLab Base Units and Options PL. 8

Contents

ProcessLab

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2 — PL

ProcessLab – an introduction

ProcessLab is the robust analysis system for routine analysis on the factory floor. Wherever various param-eters have to be measured at several sampling points, ProcessLab is the superior solution. Custom-made for your analytical requirements, ProcessLab guarantees reliable analytical results and safe process control. Moreover, ProcessLab is easy to use.

ProcessLab – the atline analyzer for routine analysis in the plant

In an atline system the sample is taken manually and fed into the system right beside the process line. Thus, various samples from different process stages or units can easily be analysed.

In contrast, in an online system the sample is fed auto-matically to the analyzer using a bypass. Several baths or sampling points can then only be covered at great expense.

ProcessLab – the innovative solution for process monitoring

Due to the proximity to the process, the results for the relevant process parameters are available directly after sampling and on site analysis. Process conditions can be immediately adjusted to keep it within the process window and prevent out-of-spec results. No time is lost on waiting for results from the laboratory. ProcessLab is perfect for quick and independent process monitoring in production facilities.

ProcessLab means

• Simple operation• Robust hardware• Flexibility and modularity• Networking and process integration• Efficient ion analysis

ProcessLab: 100% compatible with Metrohm laboratory equipment

Configured 875 ProcessLab

ProcessLab

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The modular analysis system

ProcessLab is an entirely modular analysis system. As it is customized, it is perfectly adapted to meet your spe-cific analytical and technical process requirements.

Analysis systems with Touch

Each system consists of an analysis module and an operating unit. The analysis module is assembled according to the user’s specific requirements and contains exactly those components that are necessary to carry out the desired task. The operating unit with protected keyboard and touchpad permits easy and convenient operation. For even easier use an operating unit with touch screen is optionally available.

Both the analysis module and the operating unit are mounted in a robust, splash-water-protected housing and are therefore ideally suited for use under rough conditions in production facilities.

Modular wet-chemistry part

The wet-chemistry part of an analysis module is modu-lar in design, just like the electronics part. The two parts are hermetically separated from one another. Modern interfaces such as Ethernet and USB 2.0 allow the spatially separate installation of the analysis mod-ules or the separation of operating unit and analysis module. These are important features for analyses in clean rooms or in hazardous areas.

The system is controlled by a built-in industrial PC and the user-friendly control and monitoring software ProcessLab Manager. Its user-defined interface is easy to comprehend and permits the starting of complex analysis sequences at a single push of a button. These analysis sequences are based on the high-performance software tiamo™ for ProcessLab from Metrohm. Thanks to its compatibility with the tiamo™ software, laboratory methods that have already been developed can be easily and quickly adapted for ProcessLab.

Proven Titrando technology

ProcessLab is also equipped with a Metrohm Dosing & Measuring Controller (MDM). The MDM Controller is a high-end titration system for up to four 800 Dosino dosing systems. Dynamic (DET) and monotonic (MET) titration, endpoint titration (SET), Karl Fischer titra-tion (KFT), measurements with ion-selective electrodes (MEAS CONC) and liquid handling are possible with just one instrument. A maximum of two MDM Control-lers can be built into one analysis module, so that up to eight 800 Dosino dosing systems are supported.

Communication with the process surroundings

Digital and analogue Input/Output components (I/O) allow the system to be easily integrated in the process surroundings. Thus it can react to different input sig-nals, e.g. automatically measure different parameters depending on the sample, trigger an alarm if limits are infringed or transmit measured values as analogue 4...20 mA signals.

With the second Ethernet connection (RJ45) ProcessLab can be easily integrated into a local network or com-pletely operated by remote control. Analysis data can be exported to any LIMS system or made available to a process control system.

Combined modules

The modularity of the system means that several analy-sis modules can be combined to form a single and complete system. This results in simply structured and easily manageable analysis units. Samples can be pro-vided manually or – far more conveniently – by using a sample processor.

Combined system with sample processor

ProcessLab

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Analysis techniques and parameters

Versatile application range

ProcessLab offers numerous analytical and sample preparation techniques and can therefore be used very individually.

• Direct measurement of pH, redox potential and con-ductivity

• Measurements with ion-selective electrodes (ISE)• Potentiometric titration• Karl Fischer titration• Photometry• Voltammetry (VA)• Cyclic voltammetric stripping (CVS)• Liquid handling for sample preparation

In addition to these techniques, third-party instru-ments can be connected and their data stored in the tiamo™ database. This amounts to a considerable expansion of both the range of measurement methods and measurement data storage.

The following parameters can be determined using third-party instruments

• Temperature• Density• Pressure• Refractive index• Viscosity• ...

Thanks to Metrohm’s long-term experience in the field of ion analysis, we are able to determine numerous analytical parameters.

The following parameters are particularly impor-tant for process analysis

• pH• Conductivity• Acid content• Base content• Free and total acidity• Free and total alkalinity• Acid mixtures (e.g. HF/HNO

3)

• Water hardness• Phosphates• Chloride• Chlorine• Ammonia• Nitrite• Fe, Cu, Ni, Zn• Na, Ca, F (with ISE)• Free and total SO

2

• Sulphate• H

2S/Mercaptans

• Hydrogen peroxide• Free fatty acids• Surfactants• Water content• Organic additives (CVS)

Existing tiamo™ laboratory methods can be transferred to ProcessLab easily and quickly.

Operating unit with touch function

ProcessLab

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Example of a system for one parameter

On this and the following pages, a selection of typical ProcessLab systems is presented. Depending on the analyses to be carried out, a simple or a more complex system is used.

The system described consists of a simply constructed analysis module. It contains a measuring vessel with magnetic stirrer, a sample loop for automatic measur-ing of the sample and an 800 Dosino dosing system for the exact addition of a titrant. Also integrated are the necessary peristaltic pumps for automatic rinsing and draining of the measuring vessel. With this setup, the simple and fully automatic determination of one analytical parameter is possible. The sample is mea-sured automatically, transferred to the vessel and the concentration of the analyte is determined titrimetri-cally.

Typical applications

• Acid content in etching and pickling baths in the steel industry

• Metals in plating industry baths• Analyses in ore extracts and metal production• Acid mixtures in the semiconductor industry• Boric acid in surface treatment baths in the semicon-

ductor industry• Quality control of fine chemicals• Acids or bases in the production of raw materials• Active substances in the pharmaceutical industry• Total acidity in fruit juices and concentrates• Parameters in production processes in the food

industry, e.g. chloride, fluoride and iodide

ProcessLab system for one parameter

ProcessLab

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6 — PL

Example of a system for several parameters

The ProcessLab shown consists of two 800 Dosino dosing systems for the exact addition of two titrants. Two or more analytical parameters can thus be exactly and reproducibly determined. This version also allows variable sample sizes to be analyzed with a single sample loop and an 800 Dosino dosing system. The peristaltic pumps are used for the automatic addition of reagents and auxiliary components and for rinsing and cleaning the measuring vessel. The system's mo-dular design means that it can be easily extended.

Typical applications

• Fe2+/Fe3+ as well as free and total acidity in etching and pickling baths

• Cu2+ and H2SO

4 in copper baths

• Ni2+ and boric acid in nickel electroplating baths• Acids and bases in the production of intermediate

and finished products• Quality control of acidic and alkaline products• Free and bound SO

2 in cooking liquors of the paper

industry• Determination of cyanide and alkalinity in process

waters of the steel industry

ProcessLab system for several parameters

ProcessLab

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7 — PL

Example of a ProcessLab VA/CVS System

This ProcessLab system is equipped with a built-in potentiostat/galvanostat 797 VA Computrace, thus covering a further application field. Classical trace analysis can be carried out using voltammetry (VA). In addition, Cyclic Voltammetric Stripping analysis (CVS) can be used for the determination of organic additives in electroplating baths. This version of ProcessLab is controlled by the ProcessLab Manager software that comes with a simplified user interface. It allows the start of defined analysis sequences at the push of a sin-gle button ensuring error-free operation of the system.

Typical VA applications are

• Trace metal ions, e.g. Cu, Cd, Zn and Pb in drinking, sea and waste water

• Metals in salts and high-purity chemicals• Cd, Tl and other metal ions in electrolytes used in

zinc production• Analysis of organics such as 4-carboxybenzaldehyde

in polyterephthalic acid (PET production)• Free styrene in polystyrene

Typical CVS applications are

• Determination of organic additives such as brighten-ers, suppressors and levelers in plating baths, e.g. in acidic copper baths

ProcessLab VA/CVS System

ProcessLab

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8 — PL

ProcessLab Base Units and Options

The 875 ProcessLab features a modular design and consists of a base unit, optionally with additional ex-tension modules. This base unit is a fully functioning device but must be equipped with the wet-chemistry modules as required at the front and additional I/O components inside.

875 ProcessLab Base Units with TFT operating unitProcessLab Base Unit with built-in industrial PC, operat-ing unit with TFT monitor, ProcessLab Manager and tiamo™ for ProcessLab software including basic I/O controller and power supplies.2.875.0010 Door hinges left2.875.0020 Door hinges right

875 ProcessLab Base Units with TFT operating unit and Touch functionProcessLab Base Unit with built-in industrial PC, oper-ating unit with Touch TFT, ProcessLab Manager and tiamo™ for ProcessLab software including basic I/O controller and power supplies.2.875.0510 Door hinges left2.875.0520 Door hinges right

875 ProcessLab Extension ModuleExtension module for extending an 875 ProcessLab Base Unit Titration.2.875.0110 Door hinges left2.875.0120 Door hinges right

875 ProcessLab Base Units VA or CVS with TFT operating unit and Touch functionProcessLab Base Unit with built-in 797 VA Computrace, built-in industrial PC, operating unit with Touch TFT and ProcessLab Manager software including basic I/O controller and power supplies.2.875.0210 VA, door hinges right 2.875.0220 CVS, door hinges right

ProcessLab OptionsA comprehensive range of supplementary modules and components is available

• ProcessLab MDM controller with measurement inputs for connecting various sensors

• ProcessLab MDM Controller conductivity• ProcessLab MDM Controller pH• ProcessLab digital input and output 24 V DC • ProcessLab analogue input and output 4...20 mA • ProcessLab relay output• ProcessLab measuring vessel holder with stirrer and

various measuring vessels• ProcessLab peristaltic pumps with 5 mL/min, 40 mL/

min, 120 mL/min or 320 mL/min• ProcessLab sampling system with associated sam-

pling loops• ProcessLab overflow pipettes in various sizes• ProcessLab solenoid valve module for controlling liq-

uid flows• Container with liquid level sensor in various sizes• ProcessLab reagent cabinet with door hinges left or

right

Please contact your local agency to choose your ProcessLab system for integration into your process. Thanks to its modular design the system can be per-fectly adapted to suit individual requirements.

Open analysis module

ProcessLab

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Ion chromatography

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Ion chromatography

-

Ion chromatography

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1 — IC

850 Professional IC Professional IC 850 introduction IC. 11

Professional IC – ProfIC Systems How to choose the right ProfIC system IC. 13 «ProfIC 1 – Cation» Professional IC system for automated ion chromatography IC. 14 «ProfIC 2 – Cation» Professional IC system with inline ultrafiltration IC. 15

Metrohm inline ultrafiltration and dialysis IC. 16 «ProfIC 3 – Cation» Professional IC system with inline dialysis IC. 17 «ProfIC 4 – Cation» Professional IC system with inline dilution IC. 18 «ProfIC 5 – Cation» Professional IC system with variable sample preconcentration IC. 19 «ProfIC 6 – Cation» Professional IC system with inline dilution and ultrafiltration IC. 20 «ProfIC 7 – Cation» Professional IC system with inline dilution and dialysis IC. 21 «ProfIC 8 – Cation» Professional IC system with inline sample preconcentration

and matrix elimination IC. 22 «ProfIC 9 – Cation» Professional IC system for trace analysis with inline calibration,

sample preconcentration and matrix elimination IC. 23 «ProfIC 15 – Cation» Professional IC system for partial loop injection IC. 24 «ProfIC 1 – Anion» Professional IC system for automated ion chromatography IC. 25

Reproducibility of the suppression IC. 26 Sequential suppression IC. 27

«ProfIC 2 – Anion» Professional IC system with inline ultrafiltration IC. 28 «ProfIC 3 – Anion» Professional IC system with inline dialysis IC. 29 «ProfIC 4 – Anion» Professional IC system with inline dilution IC. 30 «ProfIC 5 – Anion» Professional IC system with variable sample preconcentration IC. 31 «ProfIC 6 – Anion» Professional IC system with inline dilution and ultrafiltration IC. 32 «ProfIC 7 – Anion» Professional IC system with inline dilution and dialysis IC. 33 «ProfIC 8 – Anion» Professional IC system with inline sample preconcentration

and matrix elimination IC. 34 «ProfIC 9 – Anion» Professional IC system for trace analysis with inline calibration,

sample preconcentration and matrix elimination IC. 35 «ProfIC 10 – Anion» Professional IC system with inline sample preconcentration,

matrix elimination and matrix neutralisation IC. 36 «ProfIC 11 – Anion» Professional IC system for trace analysis with inline calibration,

sample preconcentration and matrix elimination IC. 37 «ProfIC 12 – Anion» Professional IC gradient system IC. 38 «ProfIC 15 – Anion» Professional IC system for partial loop injection IC. 39 «ProfIC 1 – AnCat» Professional IC system for automated ion chromatography IC. 40 «ProfIC 2 – AnCat» Professional IC system with inline ultrafiltration IC. 41 «ProfIC 15 – AnCat» Professional IC system for partial loop injection IC. 42

Contents

Professional IC Systems

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2 — IC

850 Professional IC Professional IC Instrument – Introduction IC. 43

Professional IC – Detector 850 Professional IC Detector – iDetector IC. 44 887 Professional UV/VIS Detector IC. 44

Professional IC – Cation Overwiew on 850 Professional IC instruments IC. 45 850 Professional IC Cation IC. 46 850 Professional IC Cation – Prep 1 IC. 46 850 Professional IC Cation – Prep 2 IC. 46

Professional IC – Anion 850 Professional IC Anion IC. 47 850 Professional IC Anion – MSM-HC IC. 47 850 Professional IC Anion – MCS IC. 47 850 Professional IC Anion – MSM-HC – MCS IC. 47 850 Professional IC Anion – MCS – Prep 1 IC. 48 850 Professional IC Anion – MSM-HC – MCS – Prep 1 IC. 48 850 Professional IC Anion – MCS – Prep 2 IC. 48 850 Professional IC Anion – MSM-HC – MCS – Prep 2 IC. 48 850 Professional IC Anion – MCS – Prep 3 IC. 49 850 Professional IC Anion – MSM-HC – MCS – Prep 3 IC. 49

Professional IC – Gradient 850 Professional IC Cation – LP Gradient IC. 49 850 Professional IC Anion – MSM-HC – LP Gradient IC. 49 850 Professional IC Anion – MCS – LP Gradient IC. 50 850 Professional IC Anion – MSM-HC – MCS – LP Gradient IC. 50 850 Professional IC Cation – Gradient IC. 50 850 Professional IC Anion – MSM-HC – Gradient IC. 50 850 Professional IC Anion – MCS – Gradient IC. 51 850 Professional IC Anion – MSM-HC – MCS – Gradient IC. 51

Professional IC – AnCat 850 Professional IC AnCat – non-suppressed IC. 51 850 Professional IC AnCat IC. 51 850 Professional IC AnCat – MCS IC. 52 850 Professional IC AnCat – MSM-HC – MCS IC. 52

Professional IC – Extension Modules Overwiew on 872 Extension Modules IC. 53 872 Extension Module IC Pump IC. 54 872 Extension Module IC Module IC. 54 872 Extension Module Sample Prep IC. 54 872 Extension Module Liquid Handling IC. 54 872 Extension Module Suppression IC. 55 872 Extension Module Suppression – MCS IC. 55

Contents

Professional IC Instruments

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3 — IC

Compact IC Instruments Compact IC – Instruments – Introduction IC. 57 Overwiew on Compact IC Instruments IC. 58

Compact IC pro Instruments 881 Compact IC pro – Cation IC. 59 881 Compact IC pro – Anion IC. 59 881 Compact IC pro – Anion – MCS IC. 59

Compact IC plus Instruments 882 Compact IC plus – Cation IC. 60 882 Compact IC plus – Anion IC. 60 882 Compact IC plus – Anion – MCS IC. 60

Basic IC plus Instruments 883 Basic IC plus IC. 61 883 Basic IC plus Package IC. 61

Contents

Compact IC Instruments

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4 — IC

Alternative IC Components Alternative IC Components – Introduction IC. 63

Heatable Reactors and Column Compartments 886 Professional Reactor IC. 64 886 Professional Thermostat IC. 64

Data Converters 891 Professional Analog Out IC. 64 771 IC Compact Interface IC. 65 771 IC Compact Interface; MagIC Net™ Professional IC. 65 771 IC Compact Interface; MagIC Net™ Compact IC. 65

Electrochemical Detectors 791 VA Detector IC. 66 871 Advanced Bioscan IC. 66

Contents

Additional IC Componets

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5 — IC

Hyphenated Systems IC – Hyphenation IC. 67

IC Hyphenated Systems TitrIC 4 hyphenated IC and titration system IC. 68 TitrIC 5 hyphenated IC and titration system IC. 68 TitrIC 6 hyphenated IC and titration system IC. 69 TitrIC 7 hyphenated IC and titration system IC. 69 IC-MS and IC-ICP/MS Coupling IC. 69 Combustion IC (Mitsubishi) IC. 70 MultiTek Combustion IC (230 V) IC. 70 MultiTek Combustion IC (110 V) IC. 70 PILS, Particle Into Liquid Sampler IC. 70 MARGA, Monitor for Aerosols and Gases in Air IC. 71

Contents

Professional IC – Hyphenated Technologies

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6 — IC

Automation IC. 72

IC Automation – Introduction IC. 73 Overwiew on IC Automation IC. 74 858 Professional Sample Processor IC. 75 858 Professional Sample Processor – Pump IC. 75 858 Professional Sample Processor – Pump – Injector IC. 75 889 IC Sample Center IC. 75 889 IC Sample Center – cool IC. 76 815 Robotic Soliprep for LC IC. 76 863 Compact IC Autosampler IC. 76 More sample processors for IC IC.77

Contents

Automation in Ion Chromatography

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7 — IC

Liquid Handling Liquid handling in IC IC. 79

Liquid handling for IC 800 Dosino IC. 80 845 Eluent Synthesizer with one Dosino IC. 80 845 Eluent Synthesizer with two Dosinos IC. 81 849 Level Control MF (for canisters) IC. 81 849 Level Control MF (for bottles) IC. 82 849 Level Control for Inline Eluent Preparation IC. 82 846 Dosing Interface IC. 82 IC Equipment for dialysis IC. 83 IC Equipment for ultrafiltration IC. 83 IC Equipment for dilution IC. 83 IC Equipment for Rinsing Station to mount on Sample Processor IC. 83 IC Equipment for liquid handling with Dosino IC. 84 IC Equipment for Dosino Gradient IC. 84 IQ/OQ Kit for IC IC. 84 IC Equipment for Liquid Handling Set to PILS IC. 84 Peristaltic pump, 8-channel IC. 85

Contents

Liquid Handling in Ion Chromatography

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8 — IC

811 Online IC Instruments 811 Online IC Process Analyzer (1 channel, 230 V) IC. 87 811 Online IC Process Analyzer (1 channel, 115 V) IC. 87 811 Online IC Process Analyzer (2 channels, 230 V) IC. 87 811 Online IC Process Analyzer (2 channels, 115 V) IC. 87

821 Compact Online IC Instruments 821 Compact Online IC Process Analyzer (230 V) IC. 89 821 Compact Online IC Process Analyzer (115 V) IC. 89

Contents

Online IC

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9 — IC

Professional IC – Software MagIC Net 2.2 Compact CD: 1 Licence IC. 91 MagIC Net 2.2 Professional CD: 1 Licence IC. 91 MagIC Net 2.2 Multi CD: 3 Licences IC. 92 TitrIC 2.0 CD IC. 92

Contents

IC Software

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10 — IC

Professional IC Systems

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11 — IC

850 Professional ICProfessional IC 850 – introduction

Intelligent Ion Chromatography

The 850 Professional IC is the first professional ion chromatography system with intelligent system com-ponents that are optimally matched to one another. The way from the sample to a precise result has now become easier, as the system thinks for itself and makes logical decisions on its own.

• Intelligence in the hardware of the 850 Professional IC,- iPump- iDetector- iReactor- intelligent Dosino

• Intelligence in the MagIC Net™ software• Intelligence in the Metrosep iColumns

These are the intelligent system components that monitor and optimise all functions and, if required, will also document them in an FDA-compatible form. The configuration of the system is as simple as can be, as the components log themselves in automatically and provide the MagIC Net™ software with all the relevant information. The optimal operation of the 850 Profes-sional IC and the results are monitored. If a parameter leaves the predefined range then the user is informed by E-mail or SMS.

The 850 Professional IC is a sophisticated and highly efficient system and yet can be operated simply and intuitively with the MagIC Net™ software. This applies to experienced users and complex applications with

complicated calculations as well as to users who prefer «one-button operation». Any user level is possible.

Innovation, flexibility and very simple operation result from the intelligence of the 850 Professional IC, the 872 Extension Modules, the 858 Professional Sample Processor and the MagIC Net™ software.

Professional IC Systems

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12 — IC

Professional IC – ProfIC Systems

The «ProfIC» systems are packages of Professional IC instruments and accessories tailored to the needs of a particular group of applications. These systems feature all the necessary components required to carry out the respective application completely automatically. The main components are:

- 850 Professional IC- 850 Conductivity Detector- 887 Professional UV/VIS Detector- 858 Professional Sample Processor- 872 Extension Module- 800 Dosino

in the appropriate versions with the corresponding accessories. Not included in the standard equipment are the column, MagIC Net™, sample rack and sample vials. This ensures maximum flexibility of the systems.

Be it the determination of anions in an analytical ser-vice laboratory with a very high sample throughput or the detection of cations in the ultratrace range, such as is required in nuclear power plants, the ProfIC systems offer a custom-made solution for any ever-so-demand-

ing application. More than 20 systems can be called up under http://www.professional-ic.com/. Together with the analytical column and the software they will meet the demands of any application.

Professional IC Systems

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13 — IC

Find the right system for your application in a few steps!

Anions Unloaded ppt ... ppb Inline Calibration ProfIC 9 - Anion

no Inline Calibration ProfIC 5 - Anion

ppb ... ppm Full Loop Injektion ProfIC 1 - Anion

Partial Loop Injektion ProfIC 15 - Anion

ppm ... % ProfIC 4 - Anion

Moderately loaded with particles ppb ... ppm ProfIC 2 - Anion

ProfIC 6 - Anion

ProfIC 3 - Anion

ProfIC 7 - Anion

ProfIC 9 - Anion

ProfIC 8 - Anion

ProfIC 11 - Anion

ProfIC 10 - Anion

ppm ... %

ppb ... ppmLoaded with particles

ppm ... %

Loaded with a dissolved neutral matrix ppt ... ppb

ppb ... ppm

Loaded with a dissolved catonic matrix ppt ... ppb

ppb ... ppm

ProfIC 12 - Anion

ProfIC 1 - AnCat

ProfIC 15 - AnCat

ProfIC 2 - AnCat

Anions with gadient

Unloaded Full Loop Injektion

Partial Loop Injektion

Moderately loaded with particles

Anions and cations

ProfIC 9 - Cation

ProfIC 5 - Cation

ProfIC 1 - Cation

ProfIC 15 - Cation

ProfIC 4 - Cation

ProfIC 2 - Cation

ProfIC 6 - Cation

ProfIC 3 - Cation

ProfIC 7 - Cation

ProfIC 9 - Cation

ProfIC 8 - Cation

Cations ppt ... ppbUnloaded Inline Calibration

no Inline Calibration

Full Loop Injektionppb ... ppm

Partial Loop Injektion

ppm ... %

Moderately loaded with particles ppb ... ppm

ppm ... %

ppb ... ppmLoaded with particles

ppm ... %

ppt ... ppbLoaded with a dissolved neutral matrix

ppb ... ppm

Step 1 Step 2Matrix

Step 3Concentration

Step 4 Result

How to choose the right ProfIC system

Professional IC Systems

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14 — IC

«ProfIC 1 – Cation» – Professional IC system for automated ion chromatography

Professional IC system applying conductivity detection. For the fully automatic determination of cations or anions (non-suppressed). «ProfIC 1» safely masters all routine tasks in ion chromatography. It is simple to use and extremely reliable.

Quality components guarantee very high sensitivity and reproducible results. Particular attention has been given to long service intervals; these can be monitored by the MagIC Net™ software.

«ProfIC 1» contains intelligent system components such as the iPump and the iDetector and provides space for a total of three iColumns.

The 858 Professional Sample Processor provides for sample transfer. Numerous sample racks are available for volumes in the range 0.5...500 mL.

The «ProfIC 1» system is your reliable partner, both in routine operation and for research and development.

Ordering informationProfIC 1 - Cation

«ProfIC 1 – Cation» – Professional IC system for automated ion chromato-graphy

Technical informationComponents1 x 2.850.1010 850 Professional IC1 x 2.850.9010 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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15 — IC

«ProfIC 2 – Cation» – Professional IC system with Inline Ultrafiltration

Professional IC system applying conductivity detection. For the fully automatic determination of cations or anions (non-suppressed) with Metrohm Inline Ultrafil-tration. «ProfIC 2» masters all routine tasks in ion chro-matography. It is easy to use and very reliable.

Quality system components guarantee very high sen-sitivity and reproducible results. Particular attention has been given to long service intervals; these can be monitored by the intelligent MagIC Net™ software.

«ProfIC 2» is equipped with Metrohm Inline Ultrafiltra-tion, which reliably removes particles from the sample and protects the analytical column from particulate contamination. The lifetime of the column is increased significantly. The ultrafiltration cell is equipped with a membrane filter with a pore size of 0.2 �m as standard and is suitable for samples with a light to medium par-ticle load. Inline Ultrafiltration works fully automatically, which saves the time-consuming and expensive use of syringe filters.

The ultrafiltration cell is mounted directly onto the 858 Professional Sample Processor. The bidirectional dual-channel peristaltic pump provides for sample transfer through the ultrafiltration cell and to the Professional IC system. The sample is continuously delivered at a high flow rate. This delays the formation of a filter cake and increases the working life of the membrane. Cross contamination is kept below 0.1%.

Numerous sample racks for volumes 0.5 ... 500 mL are available for the 858 Professional Sample Processor. Ultrafiltration requires at least 5 mL of sample.

«ProfIC 2» contains intelligent system components such as the iPump and the iDetector and offers space for a total of three iColumns.

The «ProfIC 2» system is your reliable partner, both for routine analysis and in research and development.

Ordering informationProfIC 2 - Cation

«ProfIC 2 – Cation» – Professional IC system with inline ultrafiltration

Technical informationComponents1 x 2.850.1010 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.5330.010 IC Equipment for ultrafiltration IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately depending on the specific application.

Professional IC Systems

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16 — IC

Metrohm Inline Ultrafiltration

Modern ion chromatography recommends all samples to be filtered prior to injection. Separation columns with particle sizes below 10 �m require absolutely particle-free sample solutions. Unfiltered solutions can increase pressure on the column that in some cases can radically reduce the lifetime of the column. Manual filtration is usually carried out by means of disposable filter cartridges with a pore size of 0.45 �m or less. These become clogged very quickly, particularly with samples containing very fine particles. Sample chan-gers with filter caps are used as an alternative. Their pore size is often larger than that of disposable filters. However, they are expensive and there is still a risk of clogging.With Metrohm Inline Ultrafiltration, which belongs to the membrane separation techniques, these problems no longer apply. The samples are placed directly on the sample rack. When the samples are processed the sample flow is channelled into the lower chamber of the ultrafiltration cell and passes along the membrane and into the waste container. In the upper chamber of the cell a peristaltic pump creates a vacuum and draws the sample solution through the ultrafiltration memb-rane. The filtered sample solution enters the injection loop and is then injected. Less than 20% of the ori-ginal solution is removed as filtrate, the remainder flows directly into the waste container. This, together with the geometrical arrangement of the cell, virtually eliminates the formation of a filter cake that could block the membrane. Metrohm Inline Ultrafiltration is particularly suitable for samples with a light to medium load, for example drinking water, surface water, waste-water, digestion solutions, extracts.

Ultrafiltration

«Stopped flow» method An equilibrium is achieved between the acceptor solution and the sample solution

Metrohm Inline Dialysis

Highly polluted samples require complex and laborious sample preparation steps before they can be analyzed. Metrohm Inline Dialysis provides a considerable ratio-nalization of the whole process. Samples must meet just one condition: they must be liquid or be able to be brought into liquid form and they need to be largely homogeneous. Larger particles can be removed by centrifuging, if necessary. The sample solution is then dialyzed in the dialysis cell according to the method patented by Metrohm (European Patent 0 820 804, US Patent 5,861,097). Due to this special «Inline Stopped-Flow Dialysis» method a virtually complete dialysis is obtained. This means that the acceptor solution has the same ionic concentration as the original sample (equilibrium dialysis). The acceptor solution is then injected directly into the ion chromatograph where it is analyzed. Whereas in ultrafiltration the sample solu-tion is filtered through the membrane as a result of a difference in pressure, the driving force in dialysis is the difference in concentration between the two sides. The ions to be determined diffuse through the membrane, but no sample solution is forced through the membra-ne. This means that no filter cake is formed that could block the membrane. By means of this technique it is possible to determine anions and cations even in cutting oil emulsions, biodiesel, dairy products or body fluids such as blood and urine.If the system is programmed so that the next sample is dialyzed during the current run, the total analysis takes about the same time as direct injection.

Metrohm Inline Ultrafiltration and dialysis

Professional IC Systems

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17 — IC

«ProfIC 3 – Cation» – Professional IC system with Inline Dialysis

Professional IC system applying conductivity detection. For the fully automatic determination of cations or anions (non-suppressed) with Metrohm Inline Dialysis. «ProfIC 3» safely masters demanding analytical tasks in ion chromatography. It is easy to use and extremely reliable.

«ProfIC 3» features intelligent system components such as the iPump and the iDetector and provides space for a total of three iColumns.

The Professional IC system «ProfIC 3» is equipped with «Inline Stopped Flow Dialysis», which is protected by a Metrohm patent (European Patent 0 820 804, US Patent 5,861,097). This fully automatic sample prepara-tion technique effectively removes particles and colloids from the samples. Emulsions, samples containing fats and proteins, body fluids and strongly polluted waste-water can be reliably analyzed without damaging the analytical column. The driving force behind dialysis is diffusion. Only the ions and not the particles can pass through the dialysis membrane. This increases the life-time of the membrane and, for example, prevents oil droplets from reaching the analytical column through the membrane, as would be the case if filtration was to be used.

The dialysis cell is mounted directly into the 850 Pro-fessional IC. The coordinated operation of the two bidirectional peristaltic pumps at the 858 Professional Sample Processor – Pump and 850 Professional IC – Prep 1 enables the Inline Dialysis, which is controlled by MagIC Net™.

Numerous sample racks for volumes 0.5...500 mL are available for the 858 Professional Sample Processor. Dialysis requires at least 10 mL of the sample.

Ordering informationProfIC 3 - Cation

«ProfIC 3 – Cation» – Professional IC system with Inline Dialysis

Technical informationComponents1 x 2.850.1030 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.5330.000 IC Equipment for dialysis IC column, sample rack, sample vials and MagIC Net™ have to be ordered separately according to the spe-cific application.

Professional IC Systems

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18 — IC

«ProfIC 4 – Cation» – Professional IC system with Inline Dilution

Professional IC system applying conductivity detec-tion. For the fully automatic determination of cations or anions (non-suppressed) in concentrated solutions. «ProfIC 4» can be used to analyze samples whose con-centration is too high to be determined directly.

High ionic concentrations overload the column, which results in poor chromatographic separation and there-fore adversely affects the accuracy of the measurement.

«ProfIC 4» allows automatic Inline Dilution of any sam-ple. Dilution takes place at an external position of the 858 Professional Sample Processor. In combination with transfer tubing the 800 Dosino dosing system car-ries out the high-precision liquid handling steps.

The MagIC Net™ software controls the dilution steps and carries out all calculations, only the dilution factor needs to be entered in the sample table. In addition, the software provides for intelligent dilution, i.e. dilu-tion is carried out automatically depending on the predefined concentration limits. The software monitors the results and makes logical decisions.

«ProfIC 4» features intelligent system components such as the iPump, the iDetector and the 800 Dosino and provides space for a total of three iColumns.

The 858 Professional Sample Processor with Pump car-ries out the sample transfer. Numerous sample racks for volumes 0.5...500 mL are available.

Ordering informationProfIC 4 - Cation

«ProfIC 4 – Cation» – Professional IC system with Inline Dilution

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.801.0010 801 Magnetic stirrer1 x 2.850.1010 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.020 IC Equipment for sample dilution IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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19 — IC

«ProfIC 5 – Cation» – Professional IC system with variable sample preconcentration

Professional IC system applying conductivity detection. For trace analysis of cations and anions (non-supressed). With the «ProfIC 5», concentrations down to the ppb range (�g/L) can be reliably determined. The intelligent 800 Dosino carries out the high-precision sample pre-concentration on the preconcentration column, which replaces the sample loop.

This means that it is possible to preconcentrate and analyse more than 50 mL of the sample instead of the 10...20 �L sample used for direct injection via the sample loop. It is also possible to calibrate the system using the 800 Dosino dosing system. In this case it will suffice to work with the single most concentrated stan-dard, of which varying volumes are transferred to the preconcentration column. This means that trace ana-lyses are possible all the way down to the single-digit ppb range, even in routine analysis.

«ProfIC 5» features intelligent system components such as the iPump, the iDetector and the 800 Dosino dosing system and provides space for a total of three iColumns. The MagIC Net™ software monitors and controls the functions of all components.

The 858 Professional Sample Processor supplies the samples. Transfer takes place with the 800 Dosino. Numerous sample racks are available for volumes 0.5...500 mL. The minimum volume for preconcentra-tion is 0.5 mL.

Ordering informationProfIC 5 - Cation

«ProfIC 5 – Cation» – Professional IC system with variable sample precon-centration

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.850.1010 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0010 858 Professional Sample Processor1 x 6.1014.200 Metrosep I Trap 1 column1 x 6.1825.280 PFA transfer tubing 20 mL1 x 6.2841.100 Rinsing station for Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.040 IC Equipment for liquid handling IC column, preconcentration column, sample rack, sample vials as well as MagIC Net™ have to be order-ed separately according to the particular application.

Professional IC Systems

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20 — IC

«ProfIC 6 – Cation» – Professional IC system with Inline Dilution and Ultrafiltration

Professional IC system applying conductivity detection. For the fully automatic determination of cations or ani-ons (non-suppressed) present in very high concentra-tions and whose matrix contains particles. «ProfIC 6» works with Metrohm Inline Dilution and Ultrafiltration. With this system it is possible to elimi-nate bacteria or inorganic particles from the sample and then dilute it so far that it can be analyzed.

Automatic Inline Dilution of the sample is carried out at an external position of the 858 Professional Sample Processor. The 800 Dosino dosing system provides for the high-precision liquid handling steps in combination with a transfer tubing.

The MagIC Net™ software controls the dilution steps and carries out all calculations, so that only the dilu-tion factor needs to be entered in the sample table. In addition, the software provides for intelligent dilution, i.e. dilution takes place automatically depending on the predefined concentration limits. The software monitors all intelligent system components from the iColumn to the iDetector.

The Metrohm Inline Ultrafiltration included in «ProfIC 6» reliably removes particles from the sample, which pro-tects the analytical column and significantly increases its lifetime. The ultrafiltration cell is equipped with a membrane filter with a pore size of 0.2 �m as standard and is suitable for samples with a light to medium particle load. Inline Ultrafiltration works fully automati-

cally saving the time-consuming and expensive use of syringe filters.

The 858 Professional Sample Processor with Pump car-ries out the sample transfer. Numerous sample racks for volumes 0.5...500 mL are available.

Ordering informationProfIC 6 - Cation

«ProfIC 6 – Cation» – Professional IC system with Inline Dilution and Ultra-filtration

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.801.0010 801 Magnetic Stirrer1 x 2.850.1010 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.010 IC Equipment for ultrafiltration1 x 6.5330.020 IC Equipment for sample dilution IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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21 — IC

«ProfIC 7 – Cation» – Professional IC system with Inline Dilution and Dialysis

Professional IC system applying conductivity detection. For the fully automatic determination of cations or anions (non-suppressed) present in high concentrations and also in critical matrices. Emulsions, samples contai-ning fats and proteins or strongly polluted wastewater are not always compatible with ion chromatography, even after an initial filtration step. This is why «ProfIC 7» is equipped with the inline dialysis system patented by Metrohm (European Patent 0 820 804, US-Patent 5,861,097).

In this way it is possible to determine anions and cations even in cutting oil emulsions, biodiesel, dairy products or body fluids such as blood and urine.

«ProfIC 7» also enables automatic Inline Dilution of the sample. This is carried out at an external position of the 858 Professional Sample Processor. In combination with a transfer tubing, the 800 Dosino dosing system carries out the high-precision liquid handling steps.

The intelligent MagIC Net™ software controls both the dialysis and the dilution steps. MagIC Net™ carries out all calculations, so that only the dilution factor needs to be entered in the sample table. The software also enables intelligent dilution, i.e. dilution takes place automatically depending on the highest concentration limits. The software monitors the results and makes logical decisions.

The 858 Professional Sample Processor provides for sample transfer. Numerous sample racks for volumes 0.5...500 mL are available.

Ordering informationProfIC 7 - Cation

«ProfIC 7 – Cation» – Professional IC system with Inline Dilution and Dialysis

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.801.0010 801 Magnetic stirrer1 x 2.850.1030 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.000 IC Equipment for dialysis1 x 6.5330.020 IC Equipment for sample dilution IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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22 — IC

«ProfIC 8 – Cation» – Professional IC system with Inline Sample Preconcentration and Matrix Elimination

The Professional IC system applying conductivity detection. For the determination of cations or anions (non-suppressed) in difficult matrices. «ProfIC 8» with Metrohm Inline Sample Preconcentration and Matrix Elimination allows chromatography unaffected by matrix influences and guarantees a long lifetime of the analytical column.

A small volume of the sample is transferred fully auto-matically to the preconcentration column. The anions or cations are retained. The matrix can be removed in a rinsing step. The clean sample is then injected into the IC system.

The 850 Professional IC – Prep 2 is equipped with an additional valve for liquid handling. The peristaltic pump transfers the sample and the rinsing solutions. The intelligent MagIC Net™ software controls and monitors the system.

The 858 Professional Sample Processor provides for sample delivery. Numerous sample racks for volumes 0.5...500 mL are available. Only small sample volumes of about 1 mL are normally required for matrix elimi-nation.

Ordering informationProfIC 8 - Cation

«ProfIC 8 – Cation» – Professional IC system with Inline Sample Preconcen-tration and Matrix Elimination

Technical informationComponents1 x 2.850.1050 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0010 858 Professional Sample Processor1 x 6.1602.150 Bottle neck attachment1 x 6.1608.070 Eluent bottle 2 L, GL 45 IC column, preconcentration column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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23 — IC

«ProfIC 9 – Cation» – Professional IC system for trace analysis with Inline Calibration, Sample Preconcentration and Matrix Elimination

Professional IC system applying conductivity detection. For ultratrace analysis in the lowest ppt range (ng/L) of cations or anions (non-suppressed) in complex matri-ces. «ProfIC 9» with Metrohm Inline Sample Preconcen-tration and Matrix Elimination allows chromatography unaffected by matrix influences and guarantees long lifetime for the analytical column.

Metrohm Inline Calibration permits very low concentra-tions – in the lowest ppt range (ng/L) – to be reliably calibrated using a single standard of higher concentra-tion in the ppb range (�g/L).

The sample is transferred to the preconcentration column fully automatically and with high precision by the intelligent 800 Dosino dosing system. The anions or cations are retained. The matrix can be removed in a rinsing step. The clean sample is then injected into the IC system.

The 850 Professional IC – Prep 2 is equipped with an additional valve for liquid handling. The peristaltic pump transfers the standard solution. The intelligent MagIC Net™ software controls and monitors the system.

Calibration and calculation of the results as a function of preconcentration volume is also carried out by the MagIC Net™ software. Even if complex procedures are involved, operating the system is perfectly easy.

The 858 Professional Sample Processor holds the samp-les. Numerous sample racks for volumes 0.5...500 mL are available. Typical preconcentration volumes are between 0.5...100 mL.

Ordering informationProfIC 9 - Cation

«ProfIC 9 – Cation» – Professional IC system for trace analysis with Inline Calibration, Sample Preconcentration and Matrix elimination

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.850.1050 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0010 858 Professional Sample Processor1 x 6.1014.200 Metrosep I Trap 1 column1 x 6.1562.130 Transfer tubing 10 mL1 x 6.2841.100 Rinsing station for Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.040 IC Equipment for liquid handling IC column, preconcentration column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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24 — IC

Professional IC system applying conductivity detection. For the fully automatic determination of cations and anions (non-suppressed) and «Partial Loop Injection».

«Partial Loop Injection» enables concentrated samples to be injected without previous dilution as well as mul-tipoint calibrations using just one standard solution. «ProfIC 15» safely controls all routine tasks in ion chro-matography. It is simple to use and very reliable.

Excellent system components guarantee high sensitivity and reproducible results. Particular attention has been given to long service intervals; these can be monitored by the MagIC Net™ software.

«ProfIC 15» features intelligent system components such as the iPump, the iDetector and the Dosino and provides space for a total of three iColumns.

The 800 Dosino dosing system takes care of the sam-ple transfer. With its high precision liquid handling, par-tial loop injections are performed easily and with high reproducibility. This ensures very accurate results, for example with calibration using just one standard.

For the 858 Professional Sample Processor numerous sample racks are available for volumes in the range 0.5...500 mL.

The «ProfIC 15» is the perfect system configuration, bothfor routine operation and research and development.

«ProfIC 15 – Cation» – Professional IC system for Partial Loop Injection

Ordering informationProfIC 15 - Cation

«ProfIC 15 – Cation» – Professional IC system for Partial Loop Injection

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.850.1010 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0010 858 Professional Sample Processor1 x 6.1825.220 PEEK sample loop 100 �L1 x 6.1831.180 PEEK capillary 0.5 mm i.D., 3 m1 x 6.1841.000 PEEK transfer capillary 2 mL1 x 6.2841.100 Rinsing Station for Sample Processor1 x 6.3032.120 Dosing unit 2 mL1 x 6.5330.040 IC Equipment for Liquid Handling IC column, preconcentration column, sample rack, sample vials as well as MagIC Net™ have to be order-ed separately depending on the particular application.

Professional IC Systems

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25 — IC

«ProfIC 1 – Anion» – Professional IC system for automated ion chromatography

Professional IC system applying conductivity detection. For the fully automatic determination of anions with sequential suppression. «ProfIC 1» safely masters all routine tasks in ion chromatography. It is easy to use and extremely reliable.

Quality components guarantee high sensitivity and reproducible results. Particular attention has been given to long service intervals; these can be monitored by the MagIC Net™ software.

«ProfIC 1» features intelligent system components such as the iPump and the iDetector and provides space for a total of three iColumns.

The anion system is equipped with sequential suppres-sion. This unique combination of chemical and down-stream CO

2 suppression results in very low detection

limits. The flexibility of the carbonate/hydrocarbonate eluent is complemented by the low background con-ductivity of a hydroxide eluent.

The 858 Professional Sample Processor provides for sample transfer. Numerous sample racks are available for volumes in the range 0.5...500 mL.

The «ProfIC 1» system is your reliable partner, both in routine operation and for research and development.

Ordering informationProfIC 1 - Anion

«ProfIC 1 – Anion» – Professional IC system for automated ion chromato-graphy

Technical informationComponents1 x 2.850.2030 850 Professional IC1 x 2.850.9010 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately depending on the specific application.

Professional IC Systems

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26 — IC

1

3

2

4 5 76

Reproducibility of the suppression

Professional IC Systems

For each measurement with the Metrohm Suppressor Module «MSM II», a fresh suppressor cartridge is used. Thus, you can always be sure that you are working with a cation exchanger that delivers its full perfor-mance: today, tomorrow, and even after years of uninterrupted use. The suppressor is characterized by its pressure stability; it is 100% solvent-resistant and impresses with its long working life. As no sensitive membranes are used, the suppressor reaches its equi-librium after a very short time and is then ready for use. That is exactly the reason why we give a 10-year warranty on the «MSM II». The Metrohm Suppressor

Module is favorably-priced and robust. Reproducibility of measurements made with the «MSM II» is excellent as is shown by the chromatograms:

30 injections, separation of standard anions on the Metrosep A Supp 5 - 100/4.0, eluent 1.0 mmol/L NaHCO

3,

3.2 mmol/L Na2CO

3, flow 0.7 mL/min, loop 20 �L,

suppression with the Metrohm Suppressor Module «MSMII», regeneration with 50 mmol/L H

2SO

4, rinsing

with deionized water.

1 Fluoride2 Chloride3 Nitrite4 Bromide5 Nitrate6 Phosphate 7 Sulfate

Ion Fluoride Chloride Nitrite Bromide Nitrate Phosphate Sulfate

Concentration (mg/L) 0.25 0.25 0.25 0.25 0.25 0.25 0.25

Relative standard deviation in % (n=30) 0.17 0.16 0.38 0.31 0.18 0.46 0.25

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27 — IC

Sequential suppression

Professional IC Systems

Sequential suppression is the combination of chemical suppression using the «MSM II» with Metrohm CO

2

Suppression «MCS». In this way anions can be detected with carbonate/ bicarbonate eluents at the low back-ground conductivity of hydroxide eluents.

The removal of the CO2 prevents the carbonate equi-

librium from negatively affecting the peak areas. The benefit for the user: Peak areas thus obtained are up to 50% larger – at the same concentration and for the same sample volume; this means lower detection limits.No carbonate peak also means no annoying interfe-rence with the quantification of certain analyte anions. For example, chloride and carbonate coelute on many polystyrene-divinylbenzene columns. By using the CO

2

suppressor such problems are a thing of the past.The virtual elimination of the injection peak improves the determination of rapidly eluting anions, for exam-ple fluoride. Although the separation of the injection peak and fluoride peak is already very good on poly-alcohol columns, the detection limits can be improved even further by using the CO

2 suppressor. As the injec-

tion peak is practically no longer visible, considerably larger sample volumes can also be injected.

Column: Metrosep A Supp 5 - 100/4.0 (6.1006.510)Eluent: 3.2 mmol/L Na

2CO

3; 1.0 mmol/L NaHCO

3

Flow rate: 0.7 mL/min

Drinking water from Herisau (Switzerland): comparison of suppression with «MSM II» alone (black) and with «MSM II» plus «MCS» (red).

Nr. Ion Conz. (mg/L)

1 Injection peak –

2 Fluoride 0.04

3 Chloride 7.79

4 Carbonate

5 Bromide 0.004

6 Nitrate 7.82

7 Sulfate 5.20

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28 — IC

«ProfIC 2 – Anion» – Professional IC system with Inline Ultrafiltration

Professional IC system applying conductivity detection. For for the fully automatic determination of anions with Metrohm Inline Ultrafiltration. «ProfIC 2» safely masters all routine tasks in ion chromatography. It is easy to use and extremely reliable.

Quality system components guarantee very high sen-sitivity and reproducible results. Particular attention has been given to long service intervals; these can be monitored by the intelligent MagIC Net™ software.

«ProfIC 2» is equipped with Metrohm Inline Ultrafiltra-tion, which reliably removes particles from the sample and effectively protects the analytical column from contamination. The lifetime of the column is increased significantly. The ultrafiltration cell is equipped with a membrane filter with a pore size of 0.2 �m as standard and is suitable for samples with a light to medium par-ticle load. Inline Ultrafiltration works fully automatically and saves the time-consuming and expensive use of syringe filters.

The ultrafiltration cell is mounted directly into the 858 Professional Sample Processor. The bidirectional dual-channel peristaltic pump provides for sample transfer through the ultrafiltration cell and to the Professional IC system. The sample is continuously delivered at a high flow rate. This delays the formation of a filter cake and increases the working life of the membrane. Cross contamination is kept below 0.1%.

Numerous sample racks for volumes 0.5...500 mL are available for the 858 Professional Sample Processor. Ultrafiltration requires at least 5 mL of the sample.

«ProfIC 2» features intelligent system components such as the iPump and the iDetector and provides space for a total of three iColumns.

The anion system is additionally equipped with sequen-tial suppression. This unique combination of chemical and downstream CO

2 suppression results in very low

detection limits. The flexibility of the carbonate/hydro-carbonate eluent is complemented by the low back-ground conductivity of a hydroxide eluent.

The «ProfIC 2» system is your reliable partner, both for routine analysis and in research and development.

Ordering informationProfIC 2 - Anion

«ProfIC 2 – Anion» – Professional IC system with Inline Ultrafiltration

Technical informationComponents1 x 2.850.2030 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.5330.010 IC Equipment for ultrafiltration IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately depending on the specific application.

Professional IC Systems

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29 — IC

«ProfIC 3 – Anion» – Professional IC system with Inline Dialysis

Professional IC system applying conductivity detec-tion. For the fully automatic determination of anions with Metrohm inline dialysis. «ProfIC 3» safely masters demanding analytical tasks in ion chromatography. It is nevertheless simple to use and extremely reliable.

«ProfIC 3» features intelligent system components such as the iPump and the iDetector and provides space for a total of three iColumns.

The Professional IC system «ProfIC 3» is equipped with «Inline Stopped Flow Dialysis», which is protected by a Metrohm patent (European Patent 0 820 804, US-Patent 5,861,097). This fully automatic sample prepara-tion technique effectively removes particles and colloids from the samples to be analyzed. Emulsions, samples containing fats and proteins, body fluids and stron-gly polluted wastewater can be reliably determined without damaging the analytical column. The driving force behind dialysis is diffusion. This means that only the ions and not the particles can pass through the dialysis membrane. This increases the lifetime of the membrane and, for example, prevents oil droplets from reaching the analytical column through the membrane, as would be the case if filtration was to be used.

The dialysis cell is mounted directly into the 850 Pro-fessional IC. The coordinated operation of the two bidirectional peristaltic pumps at the 858 Professional Sample Processor – Pump and 850 Professional IC – Prep 1 enables the dialysis, which is controlled by MagIC Net™.

The anion system is equipped with sequential sup-pression. Very high sensitivity is guaranteed by this unique combination of chemical and downstream CO

2

suppression. The flexibility of the carbonate eluent is complemented by the low background conductivity of a hydroxide eluent.

Numerous sample racks for volumes 0.5...500 mL are available for the 858 Professional Sample Processor. Dialysis requires at least 10 mL of the sample.

Ordering informationProfIC 3 - Anion

«ProfIC 3 – Anion» – Professional IC system with Inline Dialysis

Technical informationComponents1 x 2.850.2110 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.5330.000 IC Equipment for dialysis IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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30 — IC

«ProfIC 4 – Anion» – Professional IC system with Inline Dilution

Professional IC system applying conductivity detection. For the fully automatic determination of anions in con-centrated solutions. «ProfIC 4» can be used to analyze samples with concentration too high to be determined directly.

High Ionic concentrations overload the column, which re-sults in a poor chromatographic separation and there-fore adversely affects the accuracy of the measurement.

«ProfIC 4» allows the automatic Inline Dilution of any sample. Dilution takes place at an external position of the 858 Professional Sample Processor. In combination with transfer tubing the 800 Dosino carries out the high-precision liquid handling steps.

The MagIC Net™ software controls the dilution steps and carries out all calculations, so that only the dilu-tion factor needs to be entered in the sample table. Moreover, the software provides for intelligent dilution, i.e. dilution takes place automatically depending on the highest concentration limits. The software monitors the results and makes logical decisions.

«ProfIC 4» features intelligent system components such as the iPump, the iDetector and the 800 Dosino and provides space for a total of three iColumns.

The anion system is equipped with sequential suppres-sion. This unique combination of chemical and down-stream CO

2 suppression results in very low detection

limits. The flexibility of the carbonate/hydrocarbonate

eluent is complemented by the low background con-ductivity of a hydroxide eluent.

The 858 Professional Sample Processor with Pump pro-vides for the sample transfer. Numerous sample racks for volumes 0.5...500 mL are available.

Ordering informationProfIC 4 - Anion

«ProfIC 4 – Anion» – Professional IC system with Inline Dilution

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.801.0010 801 Magnetic stirrer1 x 2.850.2030 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.020 IC Equipment for sample dilution IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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31 — IC

«ProfIC 5 – Anion» – Professional IC system with variable sample preconcentration

Professional IC system applying conductivity detec-tion. For trace analysis of anions. With the «ProfIC 5», concentrations down to the ppb range (�g/L) can be reliably determined. The intelligent 800 Dosino dosing system carries out the high-precision sample precon-centration on the preconcentration column, which replaces the sample loop.

This means that it is possible to preconcentrate and analyse more than 50 mL of the sample instead of the 10...20 �L sample used for direct injection via the sample loop. The system can be calibrated using the 800 Dosino. In this case it will suffice to work with the single most concentrated standard, of which varying volumes are transferred to the preconcentration column. This allows trace analyis right down to the the single digit ppb range even in routine analysis.

«ProfIC 5» features intelligent system components such as the iPump, the iDetector and the 800 Dosino dosing system and provides space for a total of three iColumns. The MagIC Net™ software monitors and controls the functions of all components.

The anion system is equipped with sequential suppres-sion. This unique combination of chemical and down-stream CO

2 suppression enables very low detection

limits. The flexibility of the carbonate/hydrocarbonate eluent is complemented by the low background con-ductivity of a hydroxide eluent. With the preconcen-tration technique carbonate interference is practically eliminated.

The 858 Professional Sample Processor supplies the samples. Transfer is carried out by the 800 Dosino dosing system. Numerous sample racks are available for volumes 0.5...500 mL. The minimum volume for preconcentration is 0.5 mL.

Ordering informationProfIC 5 - Anion

«ProfIC 5 – Anion» – Professional IC system with variable sample precon-centration

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.850.2030 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0010 858 Professional Sample Processor1 x 6.1014.200 Metrosep I Trap 1 column1 x 6.1562.130 PEEK transfer tubing 10 mL1 x 6.2841.100 Rinsing station for Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.040 IC Equipment for liquid handling

IC column, preconcentration column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the particular application.

Professional IC Systems

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32 — IC

«ProfIC 6 – Anion» – Professional IC system with Inline Dilution and Ultrafiltration

Professional IC system applying conductivity detection. For the fully automatic determination of anions in very high concentrations in matrices containing particles. «ProfIC 6» works with Metrohm Inline Dilution and Ultrafiltration. This system enables users to dilute the sample and eliminate bacteria or inorganic particles prior to analysis.

Automatic Inline Dilution of the sample is carried out at an external position of the 858 Professional Sample Processor. The 800 Dosino dosing system carries out the high-precision liquid handling steps.

The MagIC Net™ software controls the dilution steps and provides for all calculations; only the dilution factor needs to be entered in the sample table. In addition, the software provides for intelligent dilution, i.e. dilu-tion takes place automatically depending on the pre-defined concentration limits. The software monitors all intelligent system components from the iColumn to the iDetector.

The Metrohm Inline Ultrafiltration included in «ProfIC 6»reliably removes particles from the sample protectingthe analytical column and increasing its lifetime signifi-cantly. The ultrafiltration cell is equipped with a mem-brane filter with a pore size of 0.2 �m as standard and is suitable for samples with a light to medium parti-cle load. Inline Ultrafiltration works fully automatically saving the time-consuming and expensive use of syringe filters.

The anion system is equipped with sequential suppres-sion. Very high sensitivity is achieved by this unique combination of chemical and downstream CO

2 sup-

pression. The flexibility of the carbonate/hydrocarbo-nate eluent is complemented by the low background conductivity of a hydroxide eluent.

The 858 Professional Sample Processor with Pump car-ries out the sample transfer. Numerous sample racks for volumes 0.5...500 mL are available.

Ordering informationProfIC 6 - Anion

«ProfIC 6 – Anion» – Professional IC system with Inline Dilution and Ultrafil-tration

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.801.0010 801 Magnetic Stirrer1 x 2.850.2030 850 Professional IC Anion1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.010 IC Equipment for ultrafiltration1 x 6.5330.020 IC Equipment for sample dilution IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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33 — IC

«ProfIC 7 – Anion» – Professional IC system with Inline Dilution and Dialysis

Professional IC system applying conductivity detection. For the fully automatic determination of anions in high concentrations and in critical matrices. Emulsi-ons, samples containing fats and proteins or strongly polluted wastewater are not always compatible with ion chromatography, even after filtration. This is why «ProfIC 7» is equipped with the Inline Dialysis system patented by Metrohm (European Patent 0 820 804, US-Patent 5,861,097).

In this way it is possible to determine anions and cations even in cutting oil emulsions, dairy products or body fluids such as blood and urine.

«ProfIC 7» also enables automatic Inline Dilution of the sample. This takes place at an external position of the 858 Professional Sample Processor. The 800 Dosino carries out the high-precision liquid handling steps.

The intelligent MagIC Net™ software controls both the dialysis and the dilution steps. MagIC Net™ provides for all calculations; only the dilution factor needs to be entered in the sample table. In addition, the software provides for intelligent dilution, i.e. dilution takes place automatically depending on the predefined concen-tration limits. The software monitors the results and makes logical decisions.

The anion system is equipped with sequential suppres-sion. Very high sensitivity is achieved by this unique combination of chemical and downstream CO

2 sup-

pression. The flexibility of the carbonate/hydrocarbo-nate eluent is complemented by the low background conductivity of a hydroxide eluent.

The 858 Professional Sample Processor with Pump car-ries out the sample transfer. Numerous sample racks for volumes 0.5...500 mL are available.

Ordering informationProfIC 7 - Anion

«ProfIC 7 – Anion» – Professional IC system with Inline Dilution and Dialysis

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.801.0010 801 Magnetic Stirrer1 x 2.850.2110 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.000 IC Equipment for dialysis1 x 6.5330.020 IC Equipment for sample dilution IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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34 — IC

«ProfIC 8 – Anion» – Professional IC system with Inline Sample Preconcentration and Matrix Elimination

Professional IC system applying conductivity detection. For the determination of anions in difficult matrices. «ProfIC 8» with Metrohm Inline Sample Preconcen-tration and Matrix elimination allows chromatogra-phy unaffected by matrix influences and guarantees a long lifetime of the analytical column.

A small volume of the sample is transferred fully auto-matically to the preconcentration column. The anions are retained. The matrix can be removed in a rinsing step. The clean sample is then injected into the IC sys-tem.

The 850 Professional IC – Prep 2 is equipped with an additional valve for liquid handling. The peristaltic pump transfers the sample and the rinsing solutions. The intelligent MagIC Net™ software controls and monitors the system.

The anion system is equipped with sequential suppres-sion. This unique combination of chemical and down-stream CO

2 suppression results in very low detection

limits. The flexibility of the carbonate/hydrocarbonate eluent is complemented by the low background con-ductivity of a hydroxide eluent. With the preconcen-tration technique carbonate interference is practically eliminated.

The 858 Professional Sample Processor provides for sample delivery. Numerous sample racks for volumes 0.5...500 mL are available. Only small sample volumes of about 1 mL are normally required for Matrix Elimina-tion.

Ordering informationProfIC 8 - Anion

«ProfIC 8 – Anion» – Professional IC system with Inline Sample Preconcen-tration and Matrix elimination

Technical informationComponents1 x 2.850.2150 850 Professional IC Anion1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0010 858 Professional Sample Processor1 x 6.1602.150 Bottle neck attachment1 x 6.1608.070 Eluent bottle 2 L, GL 45 IC column, preconcentration column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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35 — IC

«ProfIC 9 – Anion» – Professional IC system for trace analysis with Inline Calibration, Sample Preconcentration and Matrix Elimination

Professional IC system applying conductivity detection. For ultratrace analysis in the lowest ppt range (ng/L) of anions in complex matrices. «ProfIC 9» with Metrohm Inline Sample Preconcentration and Matrix Elimination allows chromatography unaffected by matrix influences and guarantees that the analytical column has a long working life.

Metrohm Inline Calibration permits very low concen-trations – in the lowest ppt range – to be reliably cali-brated using a single standard of higher concentration – in the ppb range.

The sample is transferred to the preconcentration columnfully automatically and with high precision by the intelli-gent 800 Dosino dosing system. The anions are retained. The matrix can be removed in a rinsing step. The clean sample is then injected into the IC system.

The 850 Professional IC – Prep 2 is equipped with anadditional valve for liquid handling. The peristaltic pump transfers the standard solution. The intelligent MagIC Net™ software controls and monitors the system.

Calibration and calculation of the results as a function of preconcentration volume are also provided by the MagIC Net™ software. Even if complex procedures are involved, operating the system is perfectly simple.

The anion system is equipped with sequential suppres-sion. Very high sensitivity is achieved by this unique combination of chemical and downstream CO

2 sup-

pression. The flexibility of the carbonate/hydrocarbo-nate eluent is complemented by the low background conductivity of a hydroxide eluent. With the precon-centration technique carbonate interference is practi-cally eliminated.

The 858 Professional Sample Processor holds the samples.Numerous sample racks for volumes 0.5...500 mL areavailable. Typical preconcentration volumes are between 0.5...100 mL.

Ordering informationProfIC 9 - Anion

«ProfIC 9 – Anion» – Professional IC system for trace analysis with Inline Calibration, Sample Preconcentration and Matrix Elimination

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.850.2150 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0010 858 Professional Sample Processor1 x 6.1014.200 Metrosep I Trap 1 Column1 x 6.1562.130 PEEK Transfer tubing 10 mL1 x 6.2841.100 Rinsing station for Sample Processor1 x 6.3032.210 Dosing unit 10 mL1 x 6.5330.040 IC Equipment for liquid handling IC column, preconcentration column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific application.

Professional IC Systems

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36 — IC

«ProfIC 10 – Anion» – Professional IC system with Inline Sample Preconcentration, Matrix Elimination and Matrix Neutralisation

Professional IC system applying conductivity detection. For the determination of anions in difficult matrices. «ProfIC 10» with Metrohm Inline Sample Preconcen-tration, Matrix Neutralisation and Matrix Elimination allows chromatography unaffected by matrix influences and guarantees that the analytical column has a long lifetime.

A small volume of the sample is transferred fully auto-matically to the preconcentration column. On its way it passes through the sample preparation module, where an almost complete cation exchange takes place. This means that it is possible to neutralise both acids and alkalis. The matrix is then removed from the precon-centration column in a rinsing step and the clean and pH-neutral sample injected into the IC system.

For liquid handling, the 858 Professional Sample Pro-cessor – Pump – Injector is equipped with an additio-nal valve. An additional peristaltic pump transfers the sample and rinsing solutions. The intelligent MagIC Net™ software controls and monitors the system.

«ProfIC 10» is equipped with sequential suppression. Very high sensitivity is achieved by this unique combi-nation of chemical and downstream CO

2 suppression.

The flexibility of the carbonate/hydrocarbonate eluent is complemented by the low background conductivity of a hydroxide eluent. With the preconcentration tech-nique, carbonate interference is practically eliminated.

«ProfIC 10» features intelligent system components such as the iPump and the iDetector and provides space for a total of three iColumns.

The 858 Professional Sample Processor – Pump – Injec-tor provides for sample delivery. Numerous sample racks for volumes 0.5...500 mL are available. Only small sample volumes of about 1 mL are normally required for Matrix Elimination and Neutralisation.

Ordering informationProfIC 10 - Anion

«ProfIC 10 – Anion» – Professional IC system with Inline Sample Preconcen-tration, Matrix Elimination and Matrix Neutralisation

Technical informationComponents1 x 2.850.2190 850 Professional IC Anion1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0030 858 Professional Sample Processor1 x 6.1602.150 Bottle neck attachment1 x 6.1608.070 Eluent bottle 2 L, GL 451 x 6.1825.230 PEEK sample loop 10 �L IC column, preconcentration column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the particular applica-tion.

Professional IC Systems

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37 — IC

«ProfIC 11 – Anion» – Professional IC system for trace analysis with Inline Calibration, Sample Preconcentration and Matrix Elimination

Professional IC system applying conductivity detection. For ultratrace analysis of anions in complex matrices. «ProfIC 11» with Metrohm Inline Neutralisation, Sample Preconcentration and Matrix Elimination allows chro-matography unaffected by matrix influences and gua-rantees al long lifetime of the analytical column.

Metrohm Inline Calibration permits very low concentra-tions – in the ppt range (ng/L) – to be reliably calibra-ted using a single standard of higher concentration – in the ppb range (�g/L).

The sample is transferred to the preconcentration column fully automatically and with high precision by the intelligent 800 Dosino dosing system. On its way it passes through the sample preparation module, where complete cation exchange takes place. This means that it is possible to neutralise both acids and bases. The matrix is then removed from the preconcentration column in a rinsing step. The pH-neutral and matrix-free sample is then injected into the IC system. The preconcentration becomes possible as a result of the neutralisation of the sample.

The 850 Professional IC – Prep 3 is equipped with a sample preparation module. Sample and rinsing solu-tion are provided by the 800 Dosino. A valve on the 858 Professional Sample Processor switches between sampling and sample transfer. The 872 Extension Module is used for Inline Calibration. The intelligent MagIC Net™ software controls and monitors the system.

Calibration and calculation of the results as a function of preconcentration volume are also provided by the MagIC Net™ software. Different sample volumes can be conveniently entered in the sample table. Even if complex procedures are involved, operating the system is perfectly easy.

«ProfIC 11» features intelligent system components such as the iPump, the iDetector and the Dosino and provides space for a total of three iColumns. The system is equipped with sequential suppression.

The 858 Professional Sample Processor – Pump – Injec-tor provides for sample delivery. Numerous sample racks for volumes 0.5...500 mL are available.

Ordering informationProfIC 11 - Anion

«ProfIC 11 – Anion» – Professional IC system for trace analysis with Inline Calibration, Sample Preconcentration and Matrix Elimination

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.850.2190 850 Professional IC1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0030 858 Professional Sample Processor1 x 2.872.0050 872 Extension Module Sample Prep1 x 6.1014.200 Metrosep I Trap 1 Column1 x 6.1562.130 PEEK Transfer tubing 10 mL1 x 6.2841.100 Rinsing station for Sample Processor1 x 6.3032.150 Dosing unit 5 mL1 x 6.5330.040 IC Equipment for liquid handling IC column, preconcentration column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the specific applica-tion.

Professional IC Systems

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38 — IC

«ProfIC 12 – Anion» – Professional IC gradient system

Professional IC system applying conductivity detection. For the determination of anions with a binary high-pressure gradient. In addition to step gradients, this system can be used to run any linear, convex or con-cave gradients to work in a time-optimized way.

«ProfIC 12» is equipped with two high-pressure pumps and a very effective passive mixing device. The 872 Extension Module IC Pump can be used to upgrade the system to a quaternary gradient.

«ProfIC 12» works with sequential suppression. This unique combination of chemical and downstream CO

2

suppression results in very low detection limits. The fle-xibility of the carbonate/hydrocarbonate eluent is com-plemented by the low background conductivity of a hydroxide eluent. The removal of carbon dioxide additi-onally reduces baseline drift during the gradient run.

The MagIC Net™ software is used for controlling the system and programming the gradient. All system func-tions, from monitoring the service interval to calibra-tion, can be monitored by MagIC Net™.

«ProfIC 12» features intelligent system components such as two iPumps and the iDetector and provides space for a total of three iColumns.

The 858 Professional Sample Processor – Pump provi-des for for sample delivery. Numerous sample racks for volumes 0.5...500 mL are available.

Ordering informationProfIC 12 - Anion

«ProfIC 12 – Anion» – Professional IC gradient system

Technical informationComponents1 x 2.850.2220 850 Professional IC Anion1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the particular application.

Professional IC Systems

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39 — IC

«ProfIC 15 – Anion» – Professional IC system for Partial Loop Injection

Professional IC system applying conductivity detection. For the fully automatic determination of anions with sequential suppression and Partial Loop Injection capa-bility. «Partial Loop Injection» enables concentrated samples to be injected without previous dilution as well as multipoint calibrations using just one standard solu-tion. «ProfIC 15» safely controls all routine tasks in ion chromatography. It is easy to use and very reliable.

Excellent system components guarantee high sensitivity and reproducible results. Particular attention has been given to long service intervals; these can be monitored by the MagIC Net™ software.

«ProfIC 15» features intelligent system components such as the iPump, the iDetector and the 800 Dosino and provides space for a total of three iColumns.

The anion system is equipped with sequential suppres-sion. This unique combination of chemical and down-stream CO

2 suppression results in very low detection

limits. The flexibility of the carbonate/hydrocarbonate eluent can thus be combined with the low background conductivity of a hydroxide eluent.

The 800 Dosino dosing system provides for the sample transfer. Due to its high precision liquid handling, Par-tial Loop Injections are performed easily and with high reproducibility. This ensures very accurate results, for example with calibration using one single solution.

For the 858 Professional Sample Processor numerous sample racks are available for volumes in the range 0.5...500 mL.

The «ProfIC 15» system is your reliable partner, both for routine operation and in research and development.

Ordering informationProfIC 15 - Anion

«ProfIC 15 – Anion» – Professional IC system for Partial Loop Injection

Technical informationComponents1 x 2.800.0010 800 Dosino1 x 2.850.2030 850 Professional IC Anion1 x 2.850.9010 850 Conductivity Detector1 x 2.858.0010 858 Professional Sample Processor1 x 6.1825.220 PEEK sample loop 100 �L1 x 6.1831.180 PEEK-capillary 0.5 mm i.D., 3 m1 x 6.1841.000 PEEK transfer capillary 2 mL1 x 6.2841.100 Rinsing Station for Sample Processor1 x 6.3032.120 Dosing unit 2 mL1 x 6.5330.040 IC Equipment for Liquid Handling IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the particular application.

Professional IC Systems

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40 — IC

«ProfIC 1 – AnCat» – Professional IC system for automated ion chromatography

Very compact Professional IC system applying conduc-tivity detection for the fully automatic determination of anions and cations. With «ProfIC 1 – AnCat» anions and cations can be determined both in parallel as well as independently. Both systems use the same 858 Pro-fessional Sample Processor with pump, which is con-trolled by the MagIC Net™ software.

The «ProfIC 1 – AnCat» safely performs all routine tasks in ion chromatography. It is simple to operate and very reliable. Excellent system components guarantee low detection limits and reproducible results. Particular attention has been given to long service intervals; these can be monitored with the MagIC Net™ software.

The anion system is equipped with sequential suppres-sion. This unique combination of chemical and down-stream CO

2 suppression results in very low detection

limits. The flexibility of the carbonate/hydrocarbonate eluent is complemented by the low background con-ductivity of a hydroxide eluent.

«ProfIC 1 – AnCat» features two iPumps as well as two iDetectors and provides space for a total of three iColumns in two different temperature ranges.

The 858 Professional Sample Processor – Pump provi-des for the sample transfer. Numerous sample racks for volumes 0.5...500 mL are available.

The «ProfIC 1-AnCat» system is your reliable partner, both for routine operation and in research and deve-lopment.

Ordering informationProfIC 1 - AnCat

«ProfIC 1 – AnCat» – Professional IC system for automated ion chromato-graphy

Technical informationComponents1 x 2.850.3030 850 Professional IC2 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the particular application.

Professional IC Systems

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41 — IC

«ProfIC 2 – AnCat» – Professional IC system with Inline Ultrafiltration

The very compact Professional IC system applying con-ductivity detection for the fully automatic determina-tion of anions and cations with Metrohm Inline Ultra-filtration. With «ProfIC 2 – AnCat» anions and cations can be determined both in parallel as well as inde-pendently in order to save time. Both systems use the same 858 Professional Sample Processor with – pump, which is controlled by the MagIC Net™ software.

The «ProfIC 2 – AnCat» performs all routine tasks in ion chromatography. It is simple to operate and very reliable. Excellent system components guarantee low detection limits and reproducible results. Particular attention has been given to long service intervals; these can be monitored with the MagIC Net™ software.

«ProfIC 2 – AnCat» is equipped with Metrohm Inline Ultrafiltration, which reliably removes particles from the sample protecting the analytical column particulate contamination. The lifetime of the column is signifi-cantly increased. The ultrafiltration cell is equipped with a membrane filter with a pore size of 0.2 �m as stan-dard and is suitable for samples with a light to medium particle load. Inline Ultrafiltration works fully automati-cally saving the time-consuming and expensive use of syringe filters.

The ultrafiltration cell is mounted directly into the 858 Professional Sample Processor. The bidirectional dual-channel peristaltic pump carries out the sample transfer through the ultrafiltration cell and to the Professional IC system.

The anion system is additionally equipped with sequen-tial suppression. This unique combination of chemical and downstream CO

2 suppression results in very low

detection limits. The flexibility of the carbonate/hydro-carbonate eluent is complemented by the low back-ground conductivity of a hydroxide eluent.

«ProfIC 2 – AnCat» features two iPumps as well as two iDetectors and provides space for a total of three iCo-lumns in two different temperature ranges.

Numerous sample racks for volumes 0.5...500 mL are available. Ultrafiltration requires a sample volume of at least 5 mL.

The «ProfIC 2-AnCat» system is your reliable partner, both for routine operation and in research and deve-lopment.

Ordering informationProfIC 2 - AnCat

«ProfIC 2 – AnCat» – Professional IC system with Inline Ultrafiltration

Technical informationComponents1 x 2.850.3030 850 Professional IC2 x 2.850.9010 850 Conductivity Detector1 x 2.858.0020 858 Professional Sample Processor1 x 6.5330.010 IC Equipment for ultrafiltration IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the particular application.

Professional IC Systems

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42 — IC

«ProfIC 15 – AnCat» – Professional IC system for Partial Loop Injection

Very compact Professional IC system applying conduc-tivity detection for the fully automatic determination of anions with sequential suppression and cations with Partial Loop Injection capability.

«Partial Loop Injection» allows concentrated samples to be injected without previous dilution as well as mul-tipoint calibrations using just one standard solution. «ProfIC 15» safely controls all routine tasks in ion chro-matography. It is simple to use and very flexible.

Excellent system components guarantee high sensitivity and reproducible results. Particular attention has been given to long service intervals; these can be monitored by the MagIC Net™ software.

«ProfIC 15 – AnCat» features two iPumps, two Dosi-nos as well as two iDetectors and provides space for a total of three iColumns in two different temperature ranges.

The anion system is equipped with sequential suppres-sion. This unique combination of chemical and down-stream CO

2 suppression results in very low detection

limits. The flexibility of the carbonate/hydrocarbonate eluent is complemented by the low background con-ductivity of a hydroxide eluent.

The 800 Dosino dosing system provides for the sam-ple transfer. Due to its high precision liquid handling, Partial Loop Injections are performed easily and with high reproducibility. This ensures very accurate results,

for example when calibrating using one single standard solution.

For the 858 Professional Sample Processor numerous sample racks are available for volumes in the range 0.5...500 mL.

The «ProfIC 15» is the perfect system configuration, both for routine operation and research and development.

Ordering informationProfIC 15 - AnCat

«ProfIC 15 – AnCat» – Professional IC system for partial loop injection

Technical informationComponents2 x 2.800.0010 800 Dosino1 x 2.850.3030 850 Professional IC2 x 2.850.9010 850 Conductivity Detector1 x 2.858.0010 858 Professional Sample Processor1 x 6.1825.220 PEEK sample loop 100 �L1 x 6.1831.180 PEEK-capillary 0.5 mm i.D., 3 m1 x 6.1841.000 PEEK transfer capillary 2 mL1 x 6.2744.290 T-connector with holder1 x 6.2841.100 Rinsing Station for Sample Processor1 x 6.3032.120 Dosing unit 2 mL1 x 6.5330.040 IC Equipment for Liquid Handling IC column, sample rack, sample vials as well as MagIC Net™ have to be ordered separately according to the particular application.

Professional IC Systems

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43 — IC

Professional IC InstrumentsProfessional IC Instrument – Introduction

850 Professional IC – intelligent ion chromato-graphy

Configuration: configuration of the system could not be easier, as the components log themselves in auto-matically and all the relevant information is available to the MagIC Net™ software.

Monitoring: the system monitors and optimises all functions and, if required, documents them in an FDA-compatible form. Optimal operation of the 850 Profes-sional IC and results are monitored. If a parameter is outside the predefined range, then the user is informed by E-mail or SMS.

Inline sample preparation: the way from sample prepa-ration to precise result has become shorter, as now even complex sample preparation steps can be carried out inline and automatically. The system automati-cally optimises sample preconcentration or dilution as required.

Free choice of detection mode:

The detection mode can be choosen. Therefore no detector is included in the scope of delivery.

- Intelligent pump: iPump - Intelligent detector: iDetector - Intelligent column: iColumn - Intelligent liquid handling with Dosinos- Extension Module

Professional IC Instruments

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44 — IC

850 Professional IC – detectors

850 Professional IC Detector – iDetector (2.850.9010)

Compact and intelligent high performance conductiv-ity detector for intelligent IC Instruments. Outstanding temperature stability, the complete signal processing within the protected detector block and the latest generation of «DSP» – Digital Signal Processing – guar-antee the highest precision of the measurement. No change of measuring ranges – not even automatic – is required due to the dynamic working range.

887 Professional UV/VIS Detector (2.887.0010)

The 887 Professional UV/VIS Detector is an alternative to the conductivity detector and expands the family of intelligent Metrohm detectors. It allows the reliable quantification of components that absorb ultraviolet or visible light. Detection is by a diode array.

Professional IC Instruments

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45 — IC

Overwiew on 850 Professional IC instruments

Professional IC Instruments

Comparison of the different 850 Professional IC instruments

IC Module

Suppression Sample preparation Gradient

MSM MSM-HC MCS Prep 1 Prep 2 Prep 3 HPG LPG

iPump +Valve

PP +MSM

PP +MSM-HC

MCS PPPP +Valve

PP +SPM

iPumpLP-

Device

2.850.1010 Professional IC Cation yes � � � � � � � �

2.850.1030Professional IC Cation � Prep 1

yes � � � yes � � � �

2.850.1050Professional IC Cation � Prep 2

yes � � � � yes � � �

2.850.1210Professional IC Cation � LP Gradient

yes � � � � � � � yes

2.850.1220Professional IC Cation � Gradient

yes � � � � � � yes �

2.850.2010 Professional IC Anion yes yes � � � � � � �

2.850.2030Professional IC Anion � MCS

yes yes � yes � � � � �

2.850.2050Professional IC Anion � MSM-HC

yes � yes � � � � � �

2.850.2070Professional IC Anion � MSM-HC � MCS

yes � yes yes � � � � �

2.850.2110Professional IC Anion � MCS � Prep 1

yes yes � yes yes � � � �

2.850.2120Professional IC Anion � MSM-HC � MCS � Prep 1

yes � yes yes yes � � � �

2.850.2140Professional IC Anion � MSM-HC � MCS � Prep 2

yes � yes yes � yes � � �

2.850.2150Professional IC Anion � MCS � Prep 2

yes yes � yes � yes � � �

2.850.2180Professional IC Anion � MSM-HC � MCS � Prep 3

yes yes yes yes � � yes � �

2.850.2190Professional IC Anion � MCS � Prep 3

yes yes � yes � � yes � �

2.850.2210Professional IC Anion � MCS � LP Gradient

yes � � yes � � � � yes

2.850.2220Professional IC Anion � MCS � Gradient

yes � � yes � � � yes �

2.850.2230Professional IC Anion � MSM-HC � MCS � LP Gradient

yes � yes yes � � � � yes

2.850.2240Professional IC Anion � MSM-HC � MCS � Gradient

yes � yes yes � � � yes �

2.850.2250Professional IC Anion � MSM-HC � LP Gradient

yes � yes � � � � � yes

2.850.2260Professional IC Anion � MSM-HC � Gradient

yes � yes � � � � yes �

2.850.3000Professional IC AnCat � non-suppressed

yes, 2x � � � � � � � �

2.850.3010 Professional IC AnCat yes, 2x yes � � � � � � �

2.850.3030Professional IC AnCat � MCS

yes, 2x yes � yes � � � � �

2.850.3040Professional IC AnCat � MSM-HC � MCS

yes, 2x � yes yes � � � � �

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46 — IC

850 Professional IC – instruments for cation determination

850 Professional IC Cation (2.850.1010)

The 850 Professional IC Cation is an intelligent ion chromatography system for the determination of anions or cations without suppression. It may be com-bined with different detector types.

850 Professional IC Cation – Prep 1 (2.850.1030)

The 850 Professional IC Cation – Prep 1 is an intelligent ion chromatography system for the determination of anions or cations without suppression in combination with sample preparation techniques such as Ultrafiltra-tion and Dialysis. It may be combined with different detector types.

850 Professional IC Cation – Prep 2 (2.850.1050)

The 850 Professional IC Cation – Prep 2 is an intelligent ion chromatography system for the determination of anions or cations without suppression after sample preparation. The system is suitable for the integration of Metrohm Iinline Sample Preconcentration, matrix elimination or inline calibration. It may be combined with different detector types.

Professional IC Instruments

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47 — IC

850 Professional IC instruments for anion determination

850 Professional IC Anion (2.850.2010)

The 850 Professional IC Anion is an intelligent ion chro-matography system for the determination of anions with chemical suppression. It may be combined with different detector types.

850 Professional IC Anion – MSM-HC (2.850.2050)

The 850 Professional IC Anion – MSM-HC is an intelli-gent ion chromatography system for the determination of anions with high-capacity chemical suppression. It may be combined with different detector types.

850 Professional IC Anion – MCS (2.850.2030)

The 850 Professional IC Anion – MCS is an intelligent ion chromatography system for the determination of anions with sequential suppression. It may be combined with different detector types.

850 Professional IC Anion – MSM-HC – MCS (2.850.2070)

The 850 Professional IC Anion – MSM-HC – MCS is an intelligent ion chromatography system for the determi-nation of anions with high-capacity sequential suppres-sion. It may be combined with different detector types.

Professional IC Instruments

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48 — IC

850 Professional IC Anion – MCS – Prep 1 (2.850.2110)

The 850 Professional IC Anion – MCS – Prep 1 is an intelligent ion chromatography system for the deter-mination of anions with sequential suppression in combination with Metrohm Inline Sample Preparation Techniques such as Ultrafiltration or Dialysis. It may be combined with different detector types.

850 Professional IC Anion – MSM-HC – MCS – Prep 1 (2.850.2120)

The 850 Professional IC Anion – MSM-HC – MCS – Prep 1 is an intelligent ion chromatography system for the determination of anions with high-capacity sequen-tial suppression in combination with Metrohm Inline Sample Preparation Techniques such as Ultrafiltration or Dialysis. It may be combined with different detector types.

850 Professional IC Anion – MCS – Prep 2 (2.850.2150)

The 850 Professional IC Anion – MCS – Prep 2 is an intelligent ion chromatography system for the deter-mination of anions with sequential suppression. At the same time it allows fully automatic sample preparation with Metrohm Inline Sample Preconcentration, Inline Matrix Elimination or Inline Calibration. It may be com-bined with different detector types.

850 Professional IC Anion – MSM-HC – MCS – Prep 2 (2.850.2140)

The 850 Professional IC Anion – MSM-HC – MCS – Prep 2 is an intelligent ion chromatography system for the determination of anions with high-capacity sequential suppression. At the same time it allows fully automatic sample preparation with Metrohm Inline Sample Preconcentration, Inline Matrix Elimination or Inline Calibration. It may be combined with different detector types.

Professional IC Instruments

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49 — IC

850 Professional IC Anion – MCS – Prep 3 (2.850.2190)

The 850 Professional IC Anion – MCS – Prep 3 is an intelligent ion chromatography system for the determination of anions with sequential suppression with simultaneous Metrohm Inline Neutralization or Metrohm Inline Cation Removal. It may be combined with different detector types.

850 Professional IC Anion – MSM-HC – MCS – Prep 3 (2.850.2180)

The 850 Professional IC Anion – MSM-HC – MCS – Prep 3 is an intelligent ion chromatography system for the determination of anions with high-capacity sequen-tial suppression with simultaneous Metrohm Inline Neutralization or Metrohm Inline Cation Removal. It may be combined with different detector types.

850 Professional IC instruments with gradient

850 Professional IC Cation – LP Gradi-ent (2.850.1210)

The 850 Professional IC Cation – LP Gradient is an intelligent ion chromatography system with low pres-sure gradient but without suppression. This instrument may be combined with any separation and detection mode requiring no suppression. It may be combined with different detector types.

850 Professional IC Anion – MSM-HC – LP Gradient (2.850.2250)

The 850 Professional IC Anion – MSM-HC – LP Gradi-ent is an intelligent ion chromatography system for the determination of anions using high-capacity chemical suppression and low-pressure gradient. It may be com-bined with different detector types.

Professional IC Instruments

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50 — IC

850 Professional IC Anion – MCS – LP Gradient (2.850.2210)

The 850 Professional IC Anion – MCS – LP Gradient is an intelligent ion chromatography system for the determination of anions using sequential suppression and low-pressure gradient. It may be combined with different detector types.

850 Professional IC Anion – MSM-HC – MCS – LP Gradient (2.850.2230)

The 850 Professional IC Anion – MSM-HC – MCS – LP Gradient is an intelligent ion chromatography system for the determination of anions using high-capacity sequential suppression and low-pressure gradient. It may be combined with different detector types.

850 Professional IC Cation – Gradient (2.850.1220)

The 850 Professional IC Cation – Gradient is an intel-ligent ion chromatography system for high pressure gradients without suppression. This instrument may be combined with any separation and detection method requiring no suppression. It may be combined with dif-ferent detector types.

850 Professional IC Anion – MSM-HC – Gradient (2.850.2260)

The 850 Professional IC Anion – MSM-HC – Gradient is an intelligent ion chromatography system for the determination of anions with high-capacity chemical suppression and binary high-pressure gradient. It may be combined with different detector types.

Professional IC Instruments

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51 — IC

850 Professional IC Anion – MCS – Gradient (2.850.2220)

The 850 Professional IC Anion – MCS – Gradient is an intelligent ion chromatography system for the deter-mination of anions with sequential suppression and binary high-pressure gradient. It may be combined with different detector types.

850 Professional IC Anion – MSM-HC – MCS – Gradient (2.850.2240)

The 850 Professional IC Anion – MSM-HC – MCS – Gradient is an intelligent ion chromatography system for the determination of anions with high-capacity sequential suppression and binary high-pressure gradi-ent. It may be combined with different detector types.

850 Professional IC instruments for anion and cation determination

850 Professional IC AnCat – non-sup-pressed (2.850.3000)

The 850 Professional IC AnCat – non-suppressed is an intelligent ion chromatography system for the deter-mination of anions and cations without suppression. It may be combined with different detector types.

850 Professional IC AnCat (2.850.3010)

The 850 Professional IC AnCat is an intelligent ion chromatography system for the determination of cat-ions without suppression and anions either with or without chemical suppression, as required. It may be combined with different detector types.

Professional IC Instruments

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52 — IC

850 Professional IC AnCat – MCS (2.850.3030)

The 850 Professional IC AnCat – MCS is an intelligent ion chromatography system for the determination of cations without suppression and anions either with or without sequential suppression, as required. It may be combined with different detector types.

850 Professional IC AnCat – MSM-HC – MCS (2.850.3040)

The 850 Professional IC AnCat – MSM-HC – MCS is an intelligent ion chromatography system for the deter-mination of cations without suppression and anions either with or without high-capacity sequential sup-pression, as required. It may be combined with differ-ent detector types.

Professional IC Instruments

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53 — IC

Overwiew on 872 Extension Modules

IC Module

Suppression Sample Preparation Gradient LiquidHandlingMSM MSM-HC MCS Prep 1 Prep 2 Prep 3 HPG LPG

iPump +Valve

PP +MSM

PP +MSM-HC

MCS PPPP +Valve

PP +SPM

iPumpLP-

DevicePP + Valve +

Selection Valve

2.872.0010Extension ModuleIC Pump

� � � � � � � yes � �

2.872.0030Extension ModuleIC Module

yes � � � � � � � � �

2.872.0050Extension ModuleSample Prep

� � � � � yes � � � �

2.872.0060Extension ModuleLiquid Handling

� � � � � � � � � yes

2.872.0110Extension ModuleSuppression

� � yes � � � � � � �

2.872.0120Extension ModuleSuppression � MCS

� � yes yes � � � � � �

Professional IC Instruments

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54 — IC

872 Professional IC Extension Modules

872 Extension Module IC Pump (2.872.0010)

The 872 Extension Module IC Pump is an extension tool for upgrading any 850 Professional IC instrument. It allows an additional IC high-pressure pump «iPump» to be installed in any 850 Professional IC system.

872 Extension Module IC Module (2.872.0030)

The 872 Extension Module IC Module is an extension tool for upgrading any 850 Professional IC instrument. It allows an IC high-pressure pump «iPump» and an injection valve to be installed in any 850 Professional IC system.

872 Extension Module Sample Prep (2.872.0050)

The 872 Extension Module Sample Prep is an extension tool for upgrading any 850 Professional IC instrument. It enables an additional peristaltic pump and injection valve to be installed in any 850 Professional IC system.

872 Extension Module Liquid Handling (2.872.0060)

The 872 Extension Module Liquid Handling is an exten-sion tool for upgrading any 850 Professional IC instru-ment. It enables an additional peristaltic pump, an additional injection valve as well as a 10-port selector valve to be installed in any 850 Professional IC system.

Professional IC Instruments

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55 — IC

872 Extension Module Suppression (2.872.0110)

The 872 Extension Module Suppression is an extension tool for upgrading any 850 Professional IC instrument. It allows to install a complete chemical suppression in any 850 Professional IC system.

872 Extension Module Suppression – MCS (2.872.0120)

The 872 Extension Module Suppression – MCS is an exten-sion tool for upgrading any 850 Professional IC instrument. It allows a complete sequential suppression to be installed in any 850 Professional IC system.

Professional IC Instruments

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56 — IC

Compact IC Instruments

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57 — IC

Compact IC InstrumentsCompact IC – Instruments – Introduction

Compact IC Instruments

Compact intelligence for ion chromatography

881 Compact IC pro – 882 Compact IC plus and 883 Basic IC plus

Intelligent. Safe. Precise.

Metrohm's high-end ion chromatograph is the 850 Professional IC, whose intelligent system components define the standards regarding precision of results and ease of operation. This technology is now avail-able for the Compact IC instruments as well. The 881 Compact IC pro and the 882 Compact IC plus are the ideal choice for users from all fields of application with clearly defined analytical requirements. These instru-ments ensure the rapid and safe determination of anions, cations and polar substances in the �g/L to the g/L range.

All intelligent functions of the Professional IC instru-ment series have been integrated into the 881, 882 and 883 Compact instruments: iPump, iDetector, iColumn technology. They guarantee precise results and help prevent operator errors. The MagIC Net™ chromatography software controls all system compo-nents and monitors all parameters that are relevant to the chromatographic analysis.

The 881 Compact IC pro instruments are equipped with column heater and eluent degasser; the version with sequential suppression comes with an additional sample degasser. The 882 Compact IC plus instruments

do not include these modules. The detection mode can be choosen. Therefore no detector is included in the scope of delivery of the Compact IC instruments.

The 883 Basic IC plus is the ideal instrument for train-ing in higher education. It may be used with the included 850 Professional Conductivity Detector and the MagIC Net™ Basic software.

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58 — IC

MSM MCS ColumnheaterEluent

degasserSample

degasserAutomation capability

815included

Softwareincluded

2.881.0010 � � yes yes � yes � �

2.881.0020 yes � yes yes � yes � �

2.881.0030 yes yes yes yes yes yes � �

2.882.0010 � � � � � yes � �

2.882.0020 yes � � � � yes � �

2.882.0030 yes yes � � � yes � �

2.883.0020 yes � � � � yes � yes

2.883.1020 yes � � � � yes yes yes

Overwiew on Compact IC Instruments

Comparison on the 872 Extension Moduls

Compact IC Instruments

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59 — IC

Compact IC pro instruments

881 Compact IC pro – Cation (2.881.0010)

The 881 Compact IC pro – Cation is an intelligent ion chromatograph in compact design with column heat-ing for the determination of anions, cations or polar substances without suppression. It may be combined with different detector types.

881 Compact IC pro – Anion (2.881.0020)

The 881 Compact IC pro – Anion is an intelligent ion chromatograph in compact design with column heat-ing for the determination of anions or polar substances with chemical suppression. It may be combined with different detector types.

881 Compact IC pro – Anion – MCS (2.881.0030)

The 881 Compact IC pro – Anion – MCS is an intel-ligent ion chromatograph in compact design with column heating for the determination of anions or polar substances with sequential suppression. It may be combined with different detector types.

Compact IC Instruments

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60 — IC

Compact IC plus instruments

882 Compact IC plus – Cation (2.882.0010)

The 882 Compact IC plus – Cation is an intelligent ion chromatograph in compact design without column heating for the determination of anions, cations or polar substances without chemical suppression. It may be combined with different detector types.

882 Compact IC plus – Anion (2.882.0020)

The 882 Compact IC plus – Anion is an intelligent ion chromatograph in compact design without column heating for the determination of anions or polar sub-stances with chemical suppression. It may be combined with different detector types.

882 Compact IC plus – Anion – MCS (2.882.0030)

The 882 Compact IC plus – Anion – MCS is an intel-ligent ion chromatograph in compact design without column heating for the determination of anions or polar substances with sequential suppression. It may be combined with different detector types.

Compact IC Instruments

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61 — IC

Basic IC plus instruments

883 Basic IC plus (2.883.0020)

The 883 Basic IC plus is an intelligent, very compact ion chromatograph for training and routine applica-tions. For determination of cations and anions with and without chemical suppression. Inclusive MagIC Net™ Basic software and text book.

883 Basic IC plus Package (2.883.1020)

Package for the automated analysis with the 883 Basic IC plus. For training and routine analysis. For determi-nation of cations and anions with or without chemical suppression. Including 883 Basic IC plus, 863 Compact IC Autosampler, MagIC Net™ Basic software and text-book.

Compact IC Instruments

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62 — IC

Additional IC Componets

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63 — IC

Alternative IC ComponentsAlternative IC Components – Introduction

Ion Chromatography is established in the laboratoies as a powerful and flexible analysis tool. Alternative IC components enhance the spectrum of analytes that can be detected. They also improve sensitivity and selectivity.

Heatable modules are applied in post-column reaction systems as well as in Metrohm Inline Sample Prepara-tion (MISP). Data converters export or import the chro-matographic data to external integration systems and from external detectors respectively. Electrochemical detectors are used in stand-alone systems or in combi-nation with conductivity detection.

Additional IC Componets

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64 — IC

Heatable Reactors and Column Compartments

886 Professional Reactor (2.886.0110)

The 886 Professional Reactor is a heated module spe-cially designed for pre-column and post-column reac-tion applications. It excels by its ruggedness, the high heating speed and the possibility to run reactions up to 120 °C.

886 Professional Thermostat (2.886.0210)

The 886 Professional Thermostat is a stand-alone Col-umn oven for up to two columns with a maximum length of 150 mm. It excels by its ruggedness, the high heating speed and the possibility to run reactions up to 80 °C.

IC interfaces

891 Professional Analog Out (2.891.0010)

The 891 Professional Analog Out is an additional module for intelligent IC instruments. It allows to transfer analog signals of different chromatographic data to external data systems.

Additional IC Componets

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65 — IC

771 IC Compact Interface (2.771.0010)

Universal analog-digital converter with two channels and 24-bit resolution. Data is transferred to the PC via an RS 232C interface for processing by IC Net or MagIC Net™ software.

771 IC Compact Interface; MagIC Net™Professional (2.771.0110)

IC Compact Interface with MagIC Net™ Professional software. The 771 Compact Interface connects the analog signals of the existing IC instruments (Compact, Modular and Advanced) with the improved capabilities of the client/server and database-based technology of the MagIC Net™ software.

771 IC Compact Interface; MagIC Net™ Compact (2.771.0210)

IC Compact Interface with MagIC Net™ Compact Soft-ware. The 771 Compact Interface connects the ana-logue signals of the existing IC instruments (Compact, Modular and Advanced) to the improved capabilities of the client/server and database-based technology of the MagIC Net™ software.

Additional IC Componets

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66 — IC

Electrochemical detectors

791 VA Detector (2.791.0020)

Amperometric Detector for Ion Chromatography.

Electrochemical (amperometric) detection with the 791 VA Detector is a very sensitive detection method used successfully in both HPLC and ion chromatography. This method is also characterized by its very high selec-tivity: Only easily oxidizable or reducible substances are detected – chloride or sulfate are not detected and do not interfere with the electrochemical determination, even in high concentrations.

The detector can be used in series or in parallel with other detectors that are frequently used in IC or HPLC (e.g. conductivity or UV/VIS detectors).

Numerous electrodes suitable for each amperometric application are available.

871 Advanced Bioscan (2.871.0010)

Pulsed amperometric detector for the highly sensitive determination of sugars, sugar alcohols and sugar acids, polysaccharides and other oxidizable substances.

The 871 Advanced Bioscan extends the IC program from Metrohm by adding carbohydrate analysis to the capabilities of ion chromatography. The heart of the 871 Advanced Bioscan is the pulsed amperometric detector with built-in injector and column heater. The system is controlled by the Metrodata IC Net software.

Besides carbohydrates the 871 Advanced Bioscan is used to determine oxidizable inorganic anions. There are different measuring cells with either gold, silver, platinum or glassy carbon as electrode material avail-able.

Additional IC Componets

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67 — IC

Professional IC – Hyphenated systemsIC – Hyphenation

The capabilities of ion chromatography is expanded considerably when Metrohm IC is coupled with other analytical methods, sample preparation techniques or detection systems.

The possibilities are practically unlimited. Any system which can process aqueous solutions as samples or which provides the same can be coupled with Metrohm IC instruments.

Thus, for example, ion chromotography can be com-bined with Metrohm titrators and measuring instru-ments as hyphenated systems. These TitrIC systems enable users to determine the complete range of rele-vant parameters in water analysis from a single sample. Additional typical examples are the coupling of the IC with MS or ICP-MS, Combustion IC and air monitoring systems.

Professional IC – Hyphenated Technologies

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68 — IC

Professional IC Hyphenated systems

TitrIC 4 hyphenated IC and titration system (TitrIC 4)

TitrIC 4 – the Basic System

Fully automatic system for the direct measuring of temperature, conductivity and pH; the titrimetric deter-mination of p-value, m-value, calcium and magnesium; and the determination of anions by ion chromatography.

The system consists of the 856 Conductivity Module, four 800 Dosino dosing systems, 802 Stirrer (rod stir-rer), 905 Titrando, 815 Robotic USB Sample Processor XL and 881 Compact IC pro with sequential suppres-sion and the 850 Professional Conductivity Detector «iDetector».

TitrIC – the power pack for ion analysis.

TitrIC 5 hyphenated IC and titration system (TitrIC 5)

TitrIC 5 – for the complete analysis of anions and cations.

Fully automatic system for the direct measurement of temperature, conductivity and pH, the titrimetric deter-mination of the p-value and m-value; and the deter-mination by ion chromatography of cations (including calcium and magnesium) and anions.

The system consists of the 856 Conductivity Module, three 800 Dosino dosing systems, 802 Stirrer (rod stir-rer), 855 Robotic Titrosampler, one 881 Compact IC pro without suppression and one 881 Compact IC pro with sequential suppression with one 850 Professional Conductivity Detector «iDetector» each.

TitrIC – the power pack for ion analysis.

Professional IC – Hyphenated Technologies

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69 — IC

TitrIC 6 hyphenated IC and titration system (Titric 6)

TitrIC 6 – the professional solution with sealed sample vessels.

Fully automatic system for the direct measurement of temperature, conductivity and pH; the titrimetric deter-mination of the p-value and m-value; and the determi-nation by ion chromatography of cations (including calcium and magnesium) and anions. The sample changer is equipped with the DisCover function for automatically removing the sample vessel covers.

The system consists of the 856 Conductivity Module, three 800 Dosino dosing systems, 802 Stirrer (rod stir-rer), one 905 Titrando, one 815 Robotic USB Sample Processor XL and one 850 Professional IC with two 850 Professional Conductivity Detectors «iDetectors» for anions (sequential suppression) and cations.

TitrIC – the power pack for ion analysis.

TitrIC 7 hyphenated IC and titration system (TitrIC 7)

TitrIC 7 – the solution for samples containing particles.

Fully automatic system for the direct measurement of temperature, conductivity and pH; the titrimetric deter-mination of the p-value and m-value; and the deter-mination by ion chromatography of cations (including calcium and magnesium) and anions. Particle-contain-ing samples have their particles removed by Metrohm Inline Ultrafiltration prior to determination by ion chro-matography.

The system consists of the 856 Conductivity Module, two 800 Dosino dosing systems, one 802 Stirrer (rod stirrer), one 855 Robotic Titrosampler, one 850 Profes-sional IC – Anion – Prep 2 with one 850 Professional Conductivity Detector «iDetector» for anions and one 872 Extension Module IC Pump with an additional iDe-tector for cation analysis.

TitrIC – the power pack for ion analysis.

IC-MS and IC-ICP/MS Coupling

Combining IC with an electrospray ionization mass spectrometer (ESI-MS) or an inductively coupled plasma mass spectrometer (ICP-MS) solves even complex separation problems while achieving outstanding sen-sitivities and selectivities. These so-called hyphenated techniques provide valuable information for unambigu-ous peak identification and are less prone to matrix influences than IC with conductivity detection.

Professional IC – Hyphenated Technologies

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70 — IC

Combustion IC (Mitsubishi) (CIC)

The Mitsubishi Automatic Quick Furnace AQF-100 – a combustion preparation station – is easily combined with Metrohm ion chromatography equipment. This results in a fully automated combustion system. This opens up a completely new range of samples, from vis-cous to solid, for fast and accurate elemental analysis.

MultiTek Combustion IC (230 V) (2.881.2034)

The complete Combustion IC system. The 881 Com-pact IC pro is combined with the MultiTek Horizontal IC manufactured by PAC. This results in a fully auto-mated combustion system. This opens up a completely new range of samples, from viscous to solid, for fast and accurate elemental analysis.

MultiTek Combustion IC (110 V) (2.881.2035)

The complete Combustion IC system. The 881 Com-pact IC pro is combined with the MultiTek Horizontal IC manufactured by PAC. This results in a fully auto-mated combustion system. This opens up a completely new range of samples, from viscous to solid, for fast and accurate elemental analysis.

PILS, Particle Into Liquid Sampler (2.136.0400)

Particle into Liquid Sampler for the collection of ambi-ent aerosols. Coupling with ion chromatographs allows automatic determination of the ionic composition of the aerosols without requiring additional sample prepa-ration.

Professional IC – Hyphenated Technologies

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71 — IC

MARGA, Monitor for Aerosols and Gases in Air (MARGA)

MARGA is a fully automated online system for the determination of anions and cations in gases and aerosols. The acidic and alkaline gasses are absorbed in water in a «Wet Rotating Denuder» and the aerosols in a «Steam Jet Aerosol Collector» and then analyzed for anion and cation content with two Compact ICs. MARGA is intended for unattended use over a longer period.

MARGA is available from Applikon www.applikon.com.

Professional IC – Hyphenated Technologies

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72 — IC

Automation in Ion Chromatography

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73 — IC

IC AutomationIC Automation – Introduction

Sample changer

Automation in ion chromatography ranges from straight-forward sample intorduction to highly sophis-ticated combined sample preparation. Sample volumes from a few �L up to several mL need to be handled. A number of sample changers for the different applica-tion fields are available.

The 858 Professional Sample Processor is more than just a sample changer. Equipped with pumps, high-pressure valve and Dosino dosing systems, it greatly enhances capabilities in inline sample preparation and liquid handling.

In addition to the 858 Professional Sample Processor, the 889 IC Sample Center, and the 863 Compact IC Sample the 814 and 815 Sample Processors are avail-able from the titration product line.

Metrohm inline sample preparation(MISP)

Samples such as milk, chocolate, soda lye, biodiesel or strongly polluted wastewater require sample prepara-tion before they can be analysed by IC. The 850 Pro-fessional IC together with the 858 Professional Sample Processor offers numerous possibilities for completely automating Inline Sample Preparation, e.g. Ultrafiltra-

tion, Dialysis, Preconcentration, Matrix Elimination, Matrix Neutralisation and Inline Calibration.

IC Equipment for liquid handling

MISP made easy: The IC equipment sets contain all the necessary modules for the relevant sample preparation method. This means that you can be certain that the method will work properly.

Automation in Ion Chromatography

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74 — IC

Overwiew on IC Automation

858 863 889 814 815

Positions on sample rackVariable: � 999

11 mL Vials: 148Fixed rack,

with 36 positionsVariable: � 3840,7 mL Vials: 96

Variable: � 99911 mL Vials: 148

Variable: � 99911 mL Vials: 228

External position yes no no yes yes

Sample deliveryDual channel

peristaltic pumpor 800 Dosino

Dual channelperistaltic pumpor 800 Dosino

Microliter syringe 800 Dosino 800 Dosino

Injection valve yes, as Option no yes no no

MSB 3x no no 3x 3x

Sample volume 0.5 � 500 mL 0.5 � 11 mL 0.001 � 10 mL 0.5 � 500 mL 0.5 � 500 mL

«MISP» All techniques Limited selection Limited selection Some techniques Some techniques

Automation in Ion Chromatography

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75 — IC

IC automation – instruments

858 Professional Sample Processor (2.858.0010)

The 858 Professional Sample Processor processes samples with volumes ranging from 500 �L to 500 mL. Sample transfer is carried out either by using the peri-staltic pump of the 850 Professional IC system or by an 800 Dosino.

858 Professional Sample Processor – Pump (2.858.0020)

The 858 Professional Sample Processor – Pump pro-cesses samples with volumes ranging from 500 �L to 500 mL. Sample transfer is carried out either by using the built-in bidirectional dual-channel peristaltic pump or by an 800 Dosino.

858 Professional Sample Processor – Pump – Injector (2.858.0030)

The 858 Professional Sample Processor – Pump – Injec-tor processes samples with volumes ranging from 500 �L to 500 mL. Sample transfer is carried out either by using the built-in bidirectional dual-channel peristaltic pump or by an 800 Dosino. Additionally a six-port injection valve is available for sample preparation pur-poses.

889 IC Sample Center (2.889.0010)

The 889 IC Sample Center is a robust autosampler for high sample throughput. Optimized for the challenges of modern analytical labs, the 889 IC Sample Center uses the x-y-z principle and a high-resolution dosing for sample introduction. A double needle system allows the use of vials with caps or septa. A PEEK-injector completes the automation of the 889 IC Sample Cen-ter. The 889 IC Sample Center is the perfect automa-tion tool when only very little sample is available.

Automation in Ion Chromatography

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76 — IC

889 IC Sample Center – cool (2.889.0020)

The 889 IC Sample Center is the perfect automation tool if only very little sample is available. Additional to the 889 IC Sample Center it is equipped with a cooling function and is therefore the perfect autosampler for biochemical and/or thermally instable samples.

815 Robotic Soliprep for LC (2.815.4110)

The 815 Robotic Soliprep for Liquid Chromatography is a complete system for the fully automated preparation of samples that have to be dissolved, homogenized, diluted or filtered prior to analysis. The system includes the following instruments:

1 x 815 Robotic USB Sample Processor XL1 x 136 Polytron with power supply1 x 772 Pump Unit2 x 786 Swing Head2 x 800 Dosino

863 Compact IC Autosampler (2.863.0010)

The 863 Compact IC Autosampler is the ideal automa-tion solution for routine analysis. Using the 863 Com-pact IC Autosampler all Metrohm ion chromatographs can be automated.

Automation in Ion Chromatography

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77 — IC

Additional Sample Processors for the IC

Even more choice and flexibility!

MagIC Net™ allows users to run USB Sample Proces-sors from our titration portfolio. This translates into virtually unlimited capabilities in automating your ion chromatographic analyses. Whether small or big sample beakers, whether at room temperature or under cooling conditions, whether you use a sample processor with one or two towers, our answer to your demands in ion chromatography always is:

Yes, we can!

The benefits of using a sample processor are not lim-ited to saving time: Automated systems control repeti-tive operation steps improving both reproducibility and accuracy. Errors can be almost completely elimi-nated. Day or night, your sample series are processed with maximum precision. Whether automated sample preparation, liquid handling or sample analysis – this new generation of sample processors features capabili-ties hitherto available only in robots.

Apart from MagIC Net™ and depending on your preferences the USB Sample Processor can also be con-trolled by Touch Control, PC Control or by our titra-tion software tiamo™.

Ordering information2.814.0010 814 USB Sample Processor (1T/1P)2.814.0020 814 USB Sample Processor (1T/2P)2.814.0030 814 USB Sample Processor (1T/0P)2.814.0110 814 USB Sample Processor (2T/2P)2.814.0120 814 USB Sample Processor (2T/4P)2.814.0130 814 USB Sample Processor (2T/0P)2.815.0010 815 Robotic USB Sample Processor XL

(1T/1P)2.815.0020 815 Robotic USB Sample Processor XL

(1T/2P)2.815.0030 815 Robotic USB Sample Processor XL

(1T/0P)2.815.0110 815 Robotic USB Sample Processor XL

(2T/2P)2.815.0120 815 Robotic USB Sample Processor XL

(2T/4P)2.815.0130 815 Robotic USB Sample Processor XL

(2T/0P)2.815.2110 815 Robotic Flexible Soliprep2.815.3110 815 Robotic Filtration Soliprep2.136.0654 MultiTek Autosampler 10 �L (230 V)2.136.0655 MultiTek Autosampler 10 �L (110 V)2.136.0664 MultiTek Autosampler 25 �L (230 V)2.136.0665 MultiTek Autosampler 25 �L (110 V)

814 USB Sample Processor with sample rack for 12 x 250 mL

Automation in Ion Chromatography

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78 — IC

Liquid Handling in Ion Chromatography

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79 — IC

Liquid handlingLiquid handling in IC

Sample injection – Inline Sample Preparation

In the beginning there was the syringe – and manual sample injection is still being used. However, in most cases the samples are injected automatically into the ion chromatograph. This starts with a simple peristal-tic pump, which pumps the samples solution to the injector. Additional modules such as valves, filtration and dialysis cells, neutralisation modules etc. clear the way for Inline Sample Preparation. The use of the 800 Dosino as a module for sample transfer and in particu-lar as a means for exactly measuring out several solu-tions and differing volumes, increase these capabilities even further. Logical and flexible dilution – i.e. free choice of the dilution factor as well as further dilution should the result be outside the calibration range – is only one of the many applications feasible with the 800 Dosino.

Automatic eluent preparation

The time-consuming manual preparation of eluents can be automated. Metrohm offers a variety of possibilities for this purpose.

Thus, for example, the 845 Eluent Synthesizer takes over this task and generates eluents from up to four freely selectable concentrates and one main compo-nent. Compared to the traditional, i.e. manual prepara-tion of eluents, the fully automated system guarantees precise mixtures and excellent «batch-to-batch» repro-ducibility in «Mix Control».

On the other hand, the eluent can also be prepared inline. To this and, the 849 Level Control is connected, e.g. to the 850 Professional IC System. The inline elu-ent preparation proceeds parallel to the determina-tion. The system enables running ion chromotographic analyses continuously for more than one month.

Tests with 250 �g/L standard injections over a time period of about 20 days proved an excellent stability of the retention time. After more than 800 injections the relative standard deviations were 0.55 and 0.41 for anion and cation eluents. Running the test for 24 hours the relative standard deviation of the retention times were even better than 0.09 and 0.08, respec-tively.

The error-prone and time-consuming eluent prepara-tion can be automated at low additional cost.

IC Equipment for liquid handling

MISP made easy. The IC equipment sets contain all the necessary parts for the relevant sample preparation method. This means that you can be certain that the method will work properly.

Liquid Handling in Ion Chromatography

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80 — IC

Liquid Handling for IC

800 Dosino (2.800.0010)

Drive with write/read hardware for intelligent dosing units. With fixed cable.

845 Eluent Synthesizer with one Dosino (2.845.0010)

The 845 Eluent Synthesizer eliminates the time-con-suming manual preparation of the eluents and stan-dards used in ion chromatography. The 845 Eluent Syn-thesizer facilitates work in research, analysis and quality assurance. Automation helps to reduce costs. It allows using one main component, for example ultrapure water, and four concentrates.

Liquid Handling in Ion Chromatography

845 Eluent Synthesizer with two Dosinos (2.845.0020)

The 845 Eluent Synthesizer eliminates the time-con-suming manual preparation of the eluents and stan-dards used in ion chromatography. The 845 Eluent Syn-thesizer facilitates work in research, analysis and quality assurance. Automation helps to reduce costs. It allows using one main component, for example ultrapure water, and four concentrates.

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81 — IC

849 Level Control MF (for canisters) (2.849.0020)

• Increases laboratory safety• Ensures supply of eluents, auxiliary, regenerant and

rinsing solution• Protects pumps from running dry• For universal use• Simple assembling and configuration• Works at very low conductivities

Additional equipment for Metrohm instruments. For monitoring the filling level of bottles for eluent, aux-iliary or waste solutions via remote control. The 849 Level Control prevents pumps from running dry and/or canisters from overflowing and is suitable for use with aqueous solutions, solvents and suspensions.

The metal-free sensor works in solutions with very low conductivity. Therefore it may be used in ion chroma-tography.

Liquid Handling in Ion Chromatography

849 Level Control MF (for bottles) (2.849.0030)

• Inline Eluent Preparation• Increases laboratory safety• Ensures supply of eluents, regenerant and rinsing

solution • Protects pumps from running dry• For universal use• Simple assembling and configuration• Also works in ultrapure water

Additional equipment for Metrohm instruments. For automatic generation of eluents «Eluent Production on Demand» as well as for monitoring the filling level of bottles for eluent or auxiliary solutions via remote control. It prevents pumps from running dry and/or canisters from overflowing and is suitable for use with aqueous solutions, solvents and suspensions.

The metal-free sensor works in solutions with very low conductivity. It may therefore be used in ion chroma-tography, in particular also with ultrapure water.

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82 — IC

849 Level Control for Inline Eluent Preparation (2.849.1030)

• «Inline Eluent Preparation»• Increases laboratory safety• Ensures supply of eluents • Protects pumps from running dry• For universal use• Simple assembling and configuration• Works for all types of eluents

Additional equipment for Metrohm instruments. For automatic generation of eluents «Eluent Preparation». Includes Level Control and Dosino as well as all of the accessory parts required for Inline Eluent Preparation. MagIC Net is required to control the system.

846 Dosing Interface (2.846.0010)

USB controller for up to four 700/800 Dosino dos-ing systems or 685/805 Dosimats for dosing or liquid handling tasks. A Touch Control control unit or the connection to a PC with tiamo™ or MagIC Net™ is required.

Liquid Handling in Ion Chromatography

IC Equipment for dialysis (6.5330.000)

Accessories kit for Inline Dialysis. To be used with the 858 Professional Sample Processor and an additional 2-channel peristaltic pump.

IC Equipment for ultrafiltration (6.5330.010)

Accessories kit for Inline Ultrafiltration. To be used with the 858 Professional Sample Processor.

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83 — IC

IC Equipment for dilution (6.5330.020)

Accessories kit for Inline Sample dilution. To be used with the 858 Professional Sample Processor, the 800 Dosino and the 801 Stirrer.

IC Equipment for Rinsing Station to mount on Sample Processor (6.5330.030)

Accessories kit to connect a Rinsing Station to the 858 Professional Sample Processor. The rinsing water may be fed using either a peristaltic pump or a Dosino.

Liquid Handling in Ion Chromatography

IC Equipment for liquid handling with Dosino (6.5330.040)

Accessories kit for the connection of a Dosino to intel-ligent IC instruments for liquid handling.

IC Equipment for Dosino Gradient (6.5330.050)

Accessories kit for the setup of a gradient system con-siting of an isocratic IC system and one Dosino.

IQ/OQ Kit for IC (6.5333.000)

The IQ/OQ Kit for IC contains all parts and standard solutions required for IQ/OQ in IC.

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84 — IC

IC Equipment for Liquid Handling Set for PILS (6.5335.000)

Accessories kit for PILS (Particle Into Liquid Sampler)

Liquid Handling in Ion Chromatography

Peristaltic pump, 8-channel (2.136.0500)

8-channel Peristaltic pump for PILS (Particle Into Liquid sampler) for transferring any auxiliary solution.

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85 — IC

811 Online IC Instruments

Metrohm know-how as a solid basis

For decades, Metrohm instruments have been used for monitoring production processes. The 811 Online IC and the 821 Compact Online IC benefit from this expe-rience and open up new prospects in online analysis.

Flexibility is everything

The Metrohm Online ICs can be adapted to any IC application. The 1-channel version permits the deter-mination of anions or cations, whereas the 2-channel version of the 811 Online IC can determine anions and cations simultaneously. A 10-way sampling valve is available for each channel. This can be freely pro-grammed; samples from ten different continuously flowing production streams can be brought to each channel. The Online ICs are controlled by a built-in industrial PC. After programming, the instruments are operated by mouse-click. Various calibration routines or sample sequences can be called up. Numerous ions can be determined in each sample stream and the results recorded. The Online ICs are network compat-ible; this means that they can export data and receive

remote control commands. Distance does not matter as diagnoses and parameter settings can be carried out virtually from everywhere via the built-in modem. The user carries out the calibration and system settings; these are password-protected with several access levels available. The 811 Online IC has been designed with a clear focus on simplicity, which means that it can be operated by non-chemists.

Online IC

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86 — IC

811 Online IC instruments

811 Online IC Process Analyzer (1 channel, 230 V) (2.811.0014)

1-Channel online ion chromatograph with inline cali-bration and sample preconcentration for the deter-mination of cations and anions with and without suppression down to the ultra-trace range. 10 indepen-dent sample flows. 230 V.

811 Online IC Process Analyzer (1 channel, 115 V) (2.811.0015)

1-Channel online ion chromatograph with inline cali-bration and sample preconcentration for the analysis of cations and anions with and without suppression down to the ultra-trace range. 10 independent sample flows. 115 V.

811 Online IC Process Analyzer (2 channels, 230 V) (2.811.0024)

2-Channel online ion chromatograph with inline cali-bration and sample preconcentration for simultaneous analysis of cations and anions with and without sup-pression down to the ultra-trace range. 10 indepen-dent sample flows. 230 V.

811 Online IC Process Analyzer (2 channels, 115 V) (2.811.0025)

2-Channel online ion chromatograph with inline cali-bration and sample preconcentration for simultaneous determination of cations and anions with and without suppression down to the ultra-trace range. 10 indepen-dent sample flows. 115 V.

Online IC

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87 — IC

821 Compact Online IC Instruments

The 821 Compact Online IC is the little brother of the 811 Online IC. In comparison to laboratory instruments the term «Compact» is, of course, relative. The size and weight of the Online IC systems are still considerable, which makes sense considering their use in the produc-tion sector.

The 821 Compact Online IC extends the range of industry-conform Metrohm online ion chromatography systems. A maximum of 10 different sample streams can be freely selected and analyzed. The 821 Compact Online IC allows anions to be reliably determined with or without chemical suppression down to the lower ppb range as well as cations. Simple operation, high degree of data security, almost complete insensitivity to power cuts and precise results even under rough con-ditions, e.g. on factory floor, are guaranteed.

Online IC

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88 — IC

821 Compact Online IC instruments

821 Compact Online IC Process Analyzer (230 V) (2.821.0014)

Compact Online IC system for the sequential determina-tion of anions or cations from up to 10 sample flows. Equipped with Metrohm Suppressor Module, industrial PC, UPS, modem, control cards. For 230 V.

821 Compact Online IC Process Analyzer (115 V) (2.821.0015)

Compact Online IC system for the sequential determina-tion of anions or cations from up to 10 sample flows. Equipped with Metrohm Suppressor Module «MSM», industrial PC, UPS, modem, control cards. For 115 V.

Online IC

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89 — IC

Professional IC – SoftwareMagIC Net™

MagIC Net™ software for intuitive and simple operation

It's MagIC!Clear symbols, well-laid-out user interface, intuitive operation, «one-button IC»: That is MagIC Net™.

Complete system monitoring, control cards for mea-surements, convenient database functions: that is MagIC Net™ too, the intelligent software – Swiss Made – for controlling and monitoring Metrohm ion chromatography systems.

The MagIC Net™ chromatography software controls the chromatographs of the Professional and Compact IC families and records all data obtained. MagIC Net™ is currently offered in four different versions:

• MagIC Net™ Professional supports the complete range of intelligent ion chromatographs and sample changers. It can be used to control all peripheral devices for inline sample preparation and liquid han-dling as well as any other Metrohm or third-party instruments.

• MagIC Net™ Compact features the complete functions of the MagIC Net™ Professional version, however, only the Compact IC instruments plus one sample changer for automation can be run by the Compact version.

• MagIC Net™ Multi provides the complete func-tions of MagIC Net™ Professional as a client-server installation.

• MagIC Net™ Basic is a version especially for the 883 Basic IC plus and dedicated to the demands of education. MagiIC Net™ Basic is part of the instru-ment.

All three versions are characterized by their well-laid-out user interface, clear symbols and intuitive opera-tion. The control and monitoring functions of the MagIC Net™ software are unique: system parameters, service intervals and expiration dates as well as the results of samples and standards can be checked. If a limit is exceeded, defined reactions such as sending a message by E-mail or mobile phone or switching off the system can be triggered. Thanks to the modern data management of MagIC Net™ the user can always keep control, as all necessary information is available immediately.

All intelligent components are automatically recog-nized, monitored and controlled:

- 850 Professional Conductivity Detector- 887 Professional UV/VIS Detector- 850 Professional IC - 872 Extension Module - 886 Professional Reactor / Thermostat- 881 Compact IC pro- 882 Compact IC plus- 883 Basic IC plus- 858 Professional Sample Processor - 889 IC Sample Center- 863 Compact IC Autosampler- 800 Dosinos- iColumns- 891 Professional Analog Out- 771 Compact Interface- 814/815 Robotic USB Sample Processoren- 846 Dosing Interface

With flexible programming of sequences in the time programs, combined with logical decisions and almost unlimited calculation options MagIC Net™ opens up the whole world of ion chromatography. From simple routine applications up to highly complex combinations of various sample preparation techniques.

IC Software

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90 — IC

MagIC Net™ versions

MagIC Net 2.2 Compact CD: 1 Licence (6.6059.221)

Professional PC program for controlling one intelligent Compact IC instrument and one autosampler or one 771 Compact Interface. The software permits control, data acquisition, evaluation and monitoring as well as report generation for ion chromatographic analyses.

Graphic user interface for routine operations, extensive database programs, method development, configura-tion and manual system control, highly flexible user administration, efficient database operations, extensive data export functions, individually configurable report generator, control and monitoring of all system com-ponents and the chromatographic results.

MagIC Net™ Compact complies with FDA regulation 21 CFR Part 11 as well as GLP.

Dialogue languages: German, English, French, Spanish, Chinese, Korean, Japanese and more.

1 licence.

MagIC Net 2.2 Professional CD: 1 Licence (6.6059.222)

Professional PC program for controlling intelligent Professional IC systems, Compact IC instruments and their peripherals such as different autosamplers, 800 Dosinos dosing systems, 771 Compact Interface, etc. The software permits control, data acquisition, evalu-ation and monitoring as well as report generation for ion chromatographic analyses.

Graphic user interface for routine operations, extensive database programs, method development, configura-tion and manual system control, highly flexible user administration, efficient database operations, extensive data export functions, individually configurable report generator, control and monitoring of all system com-ponents and the chromatographic results.

MagIC Net™ Professional complies with FDA regula-tion 21 CFR Part 11 as well as GLP.

Dialogue languages: German, English, French, Spanish, Chinese, Korean, Japanese and more.

1 licence.

IC Software

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91 — IC

MagIC Net 2.2 Multi CD: 3 Licences (6.6059.223)

Professional PC program for controlling intelligent Pro-fessional IC systems, Compact IC instruments and their peripherals such as different autosamplers, 800 Dosino, 771 Compact Interface, etc. The software permits control, data acquisition, evaluation and monitoring as well as report generation for ion chromatographic analyses.

Graphic user interface for routine operations, extensive database programs, method development, configura-tion and manual system control; highly flexible user administration, efficient database operations, extensive data export functions, individually configurable report generator, control and monitoring of all system com-ponents and the chromatographic results.

MagIC Net™ Multi complies with FDA regulation 21 CFR Part 11 as well as GLP.

Dialogue languages: German, English, French, Spanish, Chinese, Korean, Japanese and more.

Client-Server version with 3 licences.

TitrIC 2.0 CD (6.6062.000)

Software package for combined IC and Titration sys-tems for combination with tiamo and MagIC Net™.

IC Software

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Metrohm Quality Service®

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Dependable measurement results – for the entire lifetime of your instruments

No matter whether you do water analysis with the 850 Professional IC, trace analysis with VA, bath analysis with ProcessLab or determine the water content in pharmaceuticals using Karl Fischer titration – Metrohm Quality Service® makes sure that you can depend 100% on your measurement results – for the entire lifetime of your instruments.

Preventive maintenance – as necessary as with your carThere is no question – preventive maintenance pro-longs the operating life of your analysis systems. Our qualified service technicians have a proven training record.

They speak your language and perform maintenance work wherever you need them, worldwide. You can choose from a wide variety of contracts. A full service contract, for instance, guarantees carefree working, gives you cost control and includes fully conform compliance documentation.

Metrohm Quality Service®

Metrohm Quality Service®

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Regulatory ComplianceDue to the large number of different laboratory devices and analytical instruments, compliance with legal provisions for companies operating in regu lated industries is very time-consuming. Here Metrohm Compliance Service® provides valuable support. We are your experienced and trustworthy partner and provide you with everything you need to comply with regulations - fast and efficiently. Our qualification and validation documents, as well as our services, comply with FDA requirements and those of other regulatory authorities.

Thanks to Metrohm Quality Service® you obtain reliable measurement results. For the entire lifetime of your instruments!

We look forward to a trusting partnership.

Metrohm Quality Service®

Application support -

graphs, validation brochures, posters and technical articles

our specialistsProfessional training

Certified calibration, for example of dosing and exchange units Remote maintenanceBack-up supportEmergency service, e.g. express on-site repair

Swiss-made spare partsWorldwide stockkeepingLongterm prove of investment

Metrohm repair shops all over the world and one central repair shop at the manufacturer’s facilities in Switzerland

Metrohm Quality Service®

More services

Customer benefitFast and professional solutions for all application problems.

Competent users make an essential contribution to the dependability of analytical results.Precise measurement results

Rapid solution of software problemsHigh data securityShort response time and hence fast problem solvingLess downtimesSustained repair successShort delivery timesSpare parts available for 10 years after an instrument series goes out of productionLess downtimesFast repairs, less downtimes

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Metrohm Subsidiaries

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If there is no Metrohm subsidiary in your country please contact:

Metrohm International HeadquartersOberdorfstrasse 68 9101 Herisau Switzerland Phone +41 71 353 8585 Fax +41 71 353 8901 [email protected]

A Albania – Primalab d.o.o.Breg pri Polzeli 45bSI-3313 PolzelaSlovenijaPhone +386 3 7050 980Fax +386 3 5722 [email protected]

Algeria – Metrohm France SASB.P. 90003891942 Courtaboeuf-CedexFrancePhone +33 (1) 6486 9700Fax +33 (1) 6486 [email protected]

Argentina – Supertec S.A.Piedras 1930C1140 ABP Buenos AiresArgentinaPhone +54 (11) 4307 2141Fax +54 (11) 4307 [email protected]

Australia – MEP Instruments Pty. Ltd.P.O. Box 1880Macquarie CentreNorth Ryde, NSW 2113AustraliaPhone +61 (2) 9878 6900Fax +61 (2) 9878 [email protected]

Austria – Metrohm Inula GmbHShuttleworthstrasse 251210 WienAustriaPhone +43 (1) 405 6235 0Fax +43 (1) 405 6235 [email protected]

BBahamas – Metrohm USA Inc.6555 Pelican Creek CircleRiverview, FL 33578USAPhone +1 (813) 316 4700Fax +1 (813) 316 [email protected]

Bahrain – Yousuf Mahmood Husain W.L.L.P.O. Box 23ManamaBahrainPhone +973 17276176Fax +973 [email protected]

Bangladesh – Overseas Marketing Corporation

Pvt. Ltd.Unique Trade Center, 15th Level8, Panthapath, Dhaka – 1215Phone +88 02 8154510Fax +88 02 [email protected]

Belgium – Metrohm Belgium N.V.Blancefloerlaan 179G2050 Antwerpen LOBelgiumPhone +32 (3) 281 3331Fax +32 (3) 281 [email protected]

Belize – ScancoApdo. 747-6150Santa AnaSan JoséCosta RicaPhone +506 (2234) 1358Fax +506 (2234) [email protected]

Bhutan – Metrohm India Ltd.New No. 13, Old No. 4/1, 1st AvenueIndira Nagar, AdyarChennai – 600 020IndiaPhone +91 (44) 2441 0444Fax +91 (44) 2443 [email protected]

Metrohm worldwide

Metrohm Subsidiaries

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BBolivia – Metrohm Pensalab Ltda. BrasilRua Minerva, 167CEP 05007-030 Perdizes – São Paulo/SPBrasilPhone +55 (11) 3868 6599Fax +55 (11) 3868 [email protected]

Bosnia and Herzegovina – Primalab d.o.o.Breg pri Polzeli 45bSI-3313 PolzelaSlovenijaPhone +386 3 7050 980Fax +386 3 5722 [email protected]

Brasil – Metrohm Pensalab Ltda.Rua Minerva, 167CEP 05007-030 Perdizes – São Paulo/SPBrasilPhone +55 (11) 3868 6599Fax +55 (11) 3868 [email protected]

Brunei – Metrohm Malaysia Sdn. Bhd.833, Lobby C, Block AKelana Centre PointJalan SS7/19, Kelana Jaya47301 Petaling Jaya, SelangorMalaysiaPhone +60 3 7880 7480Fax +60 3 7880 [email protected]

Bulgaria – Metrohm Bulgaria EOOD72, Ami Bue str., 1st floor, office N0 6BG - 1612 SofiaBulgariaPhone +359 2 953 4064 +359 2 953 6326Fax +359 2 851 [email protected]

CCambodia – Metrohm Siam Ltd.979/111-115 S.M. Tower 33 FloorPhahonyothin Road, SamsennaiPhayathaiBangkok 10400ThailandPhone +66 (2) 298 0864Fax +66 (2) 298 [email protected]

CCanada – Brinkmann Instruments Corp.4160 Sladeview Crescent #6Mississauga, Ontario L5L 0A1CanadaPhone +1 (905) 569 0664Fax +1 (905) 569 [email protected]

Canary Islands – Gomensoro S.A. Spainc/Aguacate, No. 1528044 MadridSpainPhone +34 (91) 508 6586Fax +34 (91) 508 [email protected]

Chile – Melvyn Becerra & Cia. Ltda.Dr. Torres Boonen 834Casilla 16312 Correo 9ProvidenciaSantiagoChilePhone +56 (2) 209 3492Fax +56 (2) 205 [email protected]

China/Beijing – Metrohm China Ltd.Room 716, Tower 3Henderson Centre18 Jianguomennei Da JieBeijing 100005ChinaPhone +86 (10) 651 700 06Fax +86 (10) 651 796 [email protected]

China/Chengdu – Metrohm China Ltd.Room 805, Block BChengdu Chamber of Commerce TowerNo. 100 NiuwangmiaoduanDongdajie StreetJinjiang DistrictChengdu 610021ChinaPhone +86 (28) 861 323 53Fax +86 (28) 861 246 [email protected]

Metrohm Subsidiaries

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CChina/Guangzhou – Metrohm China Ltd.Room 29HHuihua Commercial & Trade Building80 Xianlie Zhong RoadGuangzhou 510070ChinaPhone +86 (20) 376 179 02Fax +86 (20) 376 160 [email protected]

China/Hong Kong – Metrohm China Ltd.Room 806-808, 8/F. Westlands Centre20 Westlands RoadQuarry BayHong KongPhone +852 (2967) 6552Fax +852 (2967) [email protected]

China/Shanghai – Metrohm China Ltd.4/F, Building 4658 Jinzhong RoadChangning DistrictShanghai 200335ChinaPhone +86 (21) 526 000 05Fax +86 (21) 627 883 [email protected]

Columbia – Polco S.A.Apartado aereo 95325MedellinColombiaPhone +57 (4) 230 5767Fax +57 (4) 230 [email protected]

Costa Rica – ScancoApdo. 747-6150Santa AnaSan JoséCosta RicaPhone +506 (2234) 1358Fax +506 (2234) [email protected]

Croatia – Primalab d.o.o.Ulica Matije Gupca 12/a49210 ZaborPhone +386 (3) 7050 980Fax +386 (3) 5722 [email protected]

CCyprus – Biotronics Ltd.7, Megalou Alexandrou Ave.2233 Latsia, NicosiaCyprusPhone +357 (22) 467 890Fax +357 (22) 764 [email protected]

Czech Republic – Metrohm Ceska republika s.r.oNa Harfe 935/5c190 00 Praha 9CzechPhone +420 246 063 433Fax +420 246 063 [email protected]

DDenmark – Metrohm Nordic ApSPostbox 14782600 GlostrupDenmarkPhone +45 7020 0561Fax +45 (7020) [email protected]

EEcuador – Eng. José M. Jalil HaasPasaje Fray Joaquín Auz 181 (E7-08) y Últimas NoticiasP.O. Box 17-12-137QuitoEcuadorPhone +593 (2) 224 4583Fax +593 (2) 244 [email protected]

Egypt – AnalyticsP.O. Box 3606th October City 12451GizaEgyptPhone +20 (2) 835 2793Fax +20 (2) 835 [email protected]

El Salvador – ScancoApdo. 747-6150Santa AnaSan JoséCosta RicaPhone +506 (2234) 1358Fax +506 (2234) [email protected]

Metrohm Subsidiaries

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EEstonia – Metrohm Nordic OYKoskelontie 19 B02920 EspooFinlandPhone +358 (10) 7786 800Fax +358 (9) 8190 [email protected]

FFinland – Metrohm Nordic OYKoskelontie 19 B02920 EspooFinlandPhone +358 (10) 7786 800Fax +358 (9) 8190 [email protected]

France – Metrohm France SASB.P. 3891942 Courtaboeuf-CedexFrancePhone +33 (1) 6486 9700Fax +33 (1) 6486 [email protected]

GGermany – Deutsche Metrohm GmbH & Co.In den Birken 370794 FilderstadtGermanyPhone +49 (711) 770 880Fax +49 (711) 770 [email protected]

Germany – Deutsche METROHM Prozessanalytik

GmbH & Co. KGIn den Birken 170794 Filderstadt (Plattenhardt)GermanyPhone +49 (711) 77088 900Fax +49 (711) 77088 [email protected]

Greece – Alfa Analytical Instruments4 Danais Street15344 GerakasAthensGreecePhone +30 (210) 957 3172Fax +30 (210) 951 [email protected]

Metrohm Subsidiaries

GGuatemala – ScancoApdo. 747-6150Santa AnaSan JoseCosta RicaPhone +506 (2234) 1358Fax +506 (2234) [email protected]

HHonduras – ScancoApdo. 747-6150Santa AnaSan JoséCosta RicaPhone +506 (2234) 1358Fax +506 (2234) [email protected]

Hong Kong – Metrohm China Ltd.Room 806-808, 8/F., Westlands Centre20 Westlands RoadQuarry BayHong KongPhone +852 (2967) 6552Fax +852 (2967) [email protected]

Hungary – Metrohm Magyarország kftRepülo

„téri út 2.

1112 BudapestHungaryPhone +36 (1) 248 0046Fax +36 (1) 248 [email protected]

IIceland – Kemia SFSudurlandsbraut 10108 ReykjavikIceland Phone +354 (588) 9495Fax +354 (588) [email protected]

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IIndia/Bangalore – Metrohm India Ltd.Plot No. 48, 2nd Floor, 13th Cross2nd Main Road, VyalikavalMalleswaramBangalore – 560 003IndiaPhone +91 (80) 2356 2659 Fax +91 (80) 2356 [email protected]

India/Baroda – Metrohm India Ltd.205 – 206, 2nd Floor, Emerald Complex77, Urmi Society, B.P.C. RoadAlkapuriBaroda – 390 007IndiaPhone +91 (265) 233 8331Fax +91 (265) 234 [email protected]

India/Bhopal – Metrohm India Ltd.401, 3rd Floor, Sarika ApartmentsG-2/118, 119 Gulmohar ColonyBhopal – 462 039IndiaMobil +91 93290 55565www.metrohm.in

India/Chandigarh – Metrohm India Ltd.SCO 83-84, 2nd FloorCabin No. 5, Sector 34-AChandigarh – 160 022IndiaPhone +91 (172) 463 7719Fax +91 (172) 463 [email protected]

India/Chennai – Metrohm India Ltd.Plot No. 3 & 4, «Origin Sri Towers»3rd & 4th floor, Fourrts AvenueAnnai Indira Nagar, ThoraipakkamChennai – 600 096IndiaPhone +91 (44) 4044 0440Fax +91 (44) 4044 [email protected]

India/Hyderabad – Metrohm India Ltd.Door # 308, 5th FloorBhuvana Towers91, S. D. RoadSecunderabad – 500 003IndiaPhone +91 (40) 2781 2441 / 2781 2451 Fax +91 (40) 2781 2461 [email protected]

IIndia/Kolkata – Metrohm India Ltd.P-224, CIT RoadScheme VII (M)Kolkata – 700 054IndiaPhone +91 (33) 3257 6449 / 2358 7583Fax +91 (33) 2337 [email protected]

India/Lucknow – Metrohm India Ltd.Asha Bhawan, 27/11-A1st Floor, Gokhle MargLucknow – 226 001IndiaPhone +91 (522) 407 0204Fax +91 (522) 401 [email protected]

India/Mumbai – Metrohm India Ltd.Unit No. 205/206, Building. No. 5Sector 3, Millennium Business ParkMahapeNavi Mumbai – 400 709IndiaPhone +91 (22) 2778 1026 / 2778 1027Fax +91 (22) 2778 [email protected]

India/New Delhi – Metrohm India Ltd.2/15, 3A 3rd FloorWest Patel NagarNew Delhi – 110 008IndiaPhone +91 (11) 2588 0851Fax +91 (11) 2588 [email protected]

India/Pune – Metrohm India Ltd.B-3, B-4, 2nd FloorMangalmurty ComplexNext to Big BazarSinhagad RoadPune – 411 030IndiaPhone +91 (20) 2425 1711Fax +91 (20) 2425 [email protected]

Indonesia – PT. MetrohmMenara Batavia 3rd FloorJl. K.H. Mas Mansyur Kav. 126Jakarta 10220IndonesiaPhone +62 (21) 572 7318Fax +62 (21) 572 [email protected]

Metrohm Subsidiaries

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IIran – Sarmad Teb Co., LTD49 Shadab Str.Sepahbod Gharani Tehran 15989IranPhone (+98) 21-8880 11 02Fax (+98) 21-8889 06 [email protected]

Ireland – Metrohm Ireland Ltd.Unit F7 Riverview Business ParkNangor RoadClondalkinDublin 12IrelandPhone +353 (1) 450 9668Fax +353 (1) 450 [email protected]

Israel – Dr. Uri Golik Instrumentation34 Kibbutz Galuyot Street66550 Tel AvivIsraelPhone +972 (3) 518 7555Fax +972 (3) 518 [email protected]

Italy – Metrohm Italiana S.R.L.Via G. Di Vittorio 521040 Origgio VAItalyPhone +39 (02) 9673 0707Fax +39 (02) 9673 [email protected]

Italy/Rome – Metrohm Italiana S.R.L.Via degli Olmetti, 39/E00060 Formello (RM)ItalyPhone +39 (06) 9075 182Fax +39 (06) 9040 [email protected]

JJamaica – Metrohm USA Inc.6555 Pelican Creek CircleRiverview, FL 33578USAPhone +1 (813) 316 4700Fax +1 (813) 316 [email protected]

JJapan – Metrohm Japan Ltd.7-18, 2-Chome, IkenohataTaito-KuTokyo 110-0008JapanPhone +81 (3) 5814 4161Fax +81 (3) 5814 [email protected]

Jordan – SENA EstablishmentP.O. Box 2840Tla‘a Ali, Um El Semaq & Khalda Str.Mustafa Majed Al Odwan Building No. 3611821 AmmanJordanPhone +962 (6) 556 1391Fax +962 (6) 556 [email protected]

KKenya – Laborama Ltd.P.O. Box 43113Kijabe Street00100 NairobiKenyaPhone +254 (2) 215 373Fax +254 (2) 218 [email protected]

Kazakhstan – Distrilaboffice 858, Samal-2 districtBusiness Centre «Satti»050059 AlmatyPhone +7 (727) 2506362Fax +7 (727) [email protected]

Korea – Hwashin Instrument Co. Ltd.738-24, Yeoksam-dongGangnam-guSeoul 135-080KoreaPhone +82 (2) 3450 5605Fax +82 (2) 3450 [email protected]

Korea – JL Science Co. (IC only)1254 Shintree-Technotown # 606Shinjung 3 Dong, Yangcheon GuSeoul 158-073KoreaPhone +82 (2) 2065 6996Fax +82 (2) 2699 [email protected] www.jlscience.com

Metrohm Subsidiaries

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KKosovo – Primalab d.o.o.Breg pri Polzeli 45bSI-3313 PolzelaSlovenijaPhone +386 3 7050 980Fax +386 3 5722 [email protected]

Kuwait – Metrohm Middle East (FZC)B2 / 21SAIF Zone (Sharjah Airport International Free Zone)P.O. Box [email protected]

Kyrgystan – Distrilab Kasachstanoffice 858, Samal-2 districtBusiness Centre «Satti»050059 AlmatyPhone +7 (727) 2506362Fax +7 (727) [email protected]

LLaos – Metrohm Siam Ltd.979/111-115 S.M. Tower 33 FloorPhahonyothin Road, SamsennaiPhayathaiBangkok 10400ThailandPhone +66 (2) 298 0864Fax +66 (2) 298 [email protected]

Latvia – Metrohm Polska sp. z o.o.Centralna 2705-816 OpaczPolandPhone +48 22 723 02 91, +48 22 723 02 27Fax +48 22 723 01 [email protected]

Lebanon – Numelab SARLLE 457 – New NaccacheP.O.Box 70-410Antelias, LebanonPhone +961 1 396677Fax +971 1 [email protected]

LLibya – Interchimie Tunesia SARLImmeuble «espace de Tunis», C 3-4Rue 8011, Montplaisir1082 Tunis BelvédèreTunesiaPhone +216 (71) 950 055Fax +216 (71) 950 [email protected]

Lithuania – Metrohm Polska sp. z o.o.Centralna 2705-816 OpaczPolandPhone +48 22 723 02 91, +48 22 723 02 27 +48 22 723 01 [email protected]

Luxembourg – Metrohm Belgium N.V.Blancefloerlaan 179G2050 Antwerpen LOBelgiumPhone +32 (3) 281 3331Fax +32 (3) 281 [email protected]

MMalaysia – Metrohm Malaysia Sdn. Bhd.833, Lobby C, Block AKelana Centre PointJalan SS7/19, Kelana Jaya47301 Petaling Jaya, SelangorMalaysiaPhone +60 (3) 7880 7480Fax +60 (3) 7880 [email protected]

Malta – Technoline Ltd.Edgar Bernard StreetGzira GZR 06MaltaPhone +356 (21) 344 345Fax +356 (21) 343 [email protected]

Mexico – MAS Instrumentos S.A. de C.V.Calzada de Tlalpan No. 4261Col. Bosques de TetlameyaC.P. 04730México, D.F.MexicoPhone +52 (55) 5424 7350Fax +52 (55) 5424 [email protected]

Metrohm Subsidiaries

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MMoldavia – Metrohm Analytics Romania SRLStr. Emil Racovita nr. 25, Et. 1, Apt. 4, Sector 4RO-041753 - BucurestiRomaniaPhone +40 21 460 03 61Fax +40 21 460 03 [email protected]

Montenegro – Primalab d.o.o.Breg pri Polzeli 45bSI-3313 PolzelaSlovenijaPhone +386 3 7050 980Fax +386 3 5722 [email protected]

Morocco – Sobovat S.A.185, Rue Oussama Ibnou Zaid(Ex rue de Jura)Maârif – Casablanca 21 100MoroccoPhone +212 (22) 230 185Fax +212 (22) 981 [email protected]

Myanmar – Metrohm Siam Ltd.979/111-115 S.M. Tower 33 FloorPhahonyothin Road, SamsennaiPhayathaiBangkok 10400ThailandPhone +66 (2) 298 0864Fax +66 (2) 298 [email protected]

NNepal – Metrohm India Ltd.New No. 13, Old No. 4/1, 1st AvenueIndira Nagar, AdyarChennai – 600 020IndiaPhone +91 (44) 2441 0444Fax +91 (44) 2443 [email protected]

Netherlands – Applikon Analytical B.V.Postbus 1493100 AC SchiedamNetherlandsPhone +31 (10) 298 3555Fax +31 (10) 437 [email protected]

NNew Zealand – MEP Instruments Ltd.2 B, Unit D, Building 25 Ceres Court North Shore City, 0630New ZealandPhone +64 (9) 912 1330 Fax +64 (9) 912 [email protected]

Nicaragua – ScancoApdo. 747-6150Santa AnaSan JoséCosta RicaPhone +506 (2234) 1358Fax +506 (2234) [email protected]

Nigeria – Astac Nigeria Ltd.P.O. Box 8803IkejaLagosNigeriaPhone +234 (1) 496 3662Fax +234 (1) 496 [email protected]

Norway – Metrohm Nordic ASSandviksveien 261363 HøvikNorwayPhone +47 6710 3630Fax +47 6710 [email protected]

OOman – Business International Group L.L.C.Po Box 1268Seeb, Postal Code 111Sultanate of OmanPhone +96824814752Fax [email protected]

Metrohm Subsidiaries

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Metrohm Subsidiaries

PPakistan – Shah & SonsOffice #11, 3rd Floor, 109-WSardar Begum PlazaJinnah AvenueBlue AreaIslamabadPakistanPhone +92 (51) 227 3557Fax +92 (51) 227 [email protected]

Panama – ScancoApdo. 747-6150Santa AnaSan JoséCosta RicaPhone +506 (2234) 1358Fax +506 (2234) [email protected]

Paraguay – Supertec S.A. ArgentinienPiedras 1930C1140 ABP Buenos AiresArgentinaPhone +54 (11) 4307 2141Fax +54 (11) 4307 [email protected]

Peru – Kessel S.A.C.Apartado 552Lima-1PeruPhone +51 (1) 219 2800Fax +51 (1) 219 [email protected]

Philippines – Dynalab Corp.Unit 905 Atlanta CenterAnnapolis St., Greenhills1502 San Juan, Metro ManilaPhilippinesPhone +63 (2) 723 4710Fax +63 (2) 721 [email protected]

Poland – Metrohm Polska sp. z o.o.Centralna 2705-816 OpaczPolandPhone +48 22 723 02 91, +48 22 723 02 27 +48 22 723 01 [email protected]

PPortugal – MT BrandãoRua de Serralves, 5994150-708 Porto, Portugal PortugalPhone +351 22 616 73 70Fax +351 22 616 73 [email protected]

Portugal – Potencial ZeroRua João de Freitas Branco no 25-2 Dto.1500-714 LisboaPortugalPhone +351 9627 [email protected]

Puerto Rico – Metrohm USA Inc.6555 Pelican Creek CircleRiverview, FL 33578USAPhone +1 (813) 316 4700Fax +1 (813) 316 [email protected]

QQatar – Metrohm Middle East (FZC)B2 / 21SAIF Zone (Sharjah Airport International Free Zone)P.O. Box [email protected]

RRomania – Metrohm Analytics Romania SRLStr. Emil Racovita nr. 25, Et. 1, Apt. 4, Sector 4RO-041753 - BucurestiRomaniaPhone +40 21 460 03 61Fax +40 21 460 03 [email protected]

Russia – AVRORA Ltd.P. O. Box 33 CIS-119071MoscowRussiaPhone +7(495)258-8305/06/07, ext 445, 446Fax +7(495)[email protected]

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SSaudi Arabia – Naizak Lab SystemsKhashoggi Building, 9th FloorDhahran StreetP.O. Box 4Dammam 31411Saudi ArabiaPhone +966 (3) 889 2085Fax +966 (3) 889 [email protected]

Serbia – Primalab d.o.o.Breg pri Polzeli 45bSI-3313 PolzelaSlovenijaPhone +386 3 7050 980Fax +386 3 5722 [email protected]

Singapore – Metrohm Singapore Pte Ltd.31 Toh Guan Road East#06-08 LW Techno CentreSingapore 608608SingaporePhone +65 6 872 2215Fax +65 6 872 [email protected] www.metrohm.com.sg

Slovakia – Metrohm Slovensko s.r.o.Galvaniho 12/B821 04 BratislavaSlovakiaPhone +421 (2) 2062 0100Fax +421 (2) 3352 0220office@metrohm. skwww.metrohm.sk

Slovenija – Primalab d.o.o.Breg pri Polzeli 45bSI-3313 PolzelaSlovenijaPhone +386 3 7050 980Fax +386 3 5722 [email protected]

South Africa – Metrohm South Africa (Pty) Ltd.1Woodmead drive Woodmead Estate, building 12 Woodmead (Sandton)South AfricaPhone +27 (11) 804 0030Fax +27 (11) 804 [email protected] www.metrohm.co.za

SSpain – (Except Catalonia & Balearic Islands) –

Gomensoro S.A.c/Aguacate, No. 1528044 MadridSpainPhone +34 (91) 508 6586Fax +34 (91) 508 [email protected]

Spain – (Catalonia & Balearic Islands) –

Massó Analitica S.A.Carrer Montsià, 4Parc de Negocis Mas Blau I08820 El Prat de Llobregat (Barcelona)SpainPhone +34 (93) 285 9797Fax +34 (93) 219 [email protected]

Sri Lanka – Metrohm Middle East (FZC)B2 / 21SAIF Zone (Sharjah Airport International Free Zone)P.O. Box 120747SharjahUAEPhone +971 (6) 5575 991Fax +971 (6) 5575 [email protected]

Surinam – CENATEC CA Tecnología de LaboratorioAv. Sucre, Los Dos Caminos, Torre Centro Boyacá,Piso 23,Apartado 60913,Caracas 1060RIF : J- 00143737-1Phone (0212)2841110 – 2853361 – 2847533 – 2856373 – 2843244Fax (0212) 2858803 – [email protected]

Sweden – Metrohm Nordic ASBox 1106516111 BrommaSwedenPhone +46 (8) 5648 4480Fax +46 (8) 5648 [email protected]

Switzerland – Metrohm Schweiz AGBleiche West4800 ZofingenSwitzerlandPhone +41 (62) 745 28 28Fax +41 (62) 745 28 [email protected]

Metrohm Subsidiaries

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SSyria – Droguerie SyrieKostaki Homsi Str. suite 106/3P.O. Box 5441AleppoSyriaPhone +963 (21) 229 9000Fax +963 (21) 229 [email protected]

TTaiwan – Hammer Trading Co. Ltd.3rd Fl., 48 Kaifeng Street, Sec. 2Taipei 108TaiwanPhone +886 (2) 2361 0011Fax +886 (2) 2311 [email protected]

Thailand – Metrohm Siam Ltd.979/111-115 S.M. Tower 33 FloorPhahonyothin Road, SamsennaiPhayathaiBangkok 10400ThailandPhone +66 (2) 298 0864Fax +66 (2) 298 [email protected]

Trinidad/Tobago – Southern Systems Ltd.3 & 5 Hilda Lazzari TerraceLes Efforts EastSan FernandoTrinidad / West IndiesPhone +1 (868) 652 0283Fax +1 (868) 653 [email protected]

Tunesia – Interchimie SARLImmeuble «Espace de Tunis», C 3-4Rue 8011, Montplaisir1082 Tunis BelvédèreTunesiaPhone +216 (71) 950 055Fax +216 (71) 950 [email protected]

Turkey – YançoFecri Ebcioglu SokakDeniz Apt. No. 26/5 Levent80600 IstanbulTurkeyPhone +90 (212) 279 2036Fax +90 (212) 280 [email protected]

TTurkmenistan – Distrilab Kasachstanoffice 858, Samal-2 districtBusiness Centre «Satti»050059 AlmatyPhone +7 (727) 2506362Fax +7 (727) [email protected]

UUAE – Metrohm Middle EastB2 / 21SAIF Zone (Sharjah Airport International Free Zone)P.O. Box 120747SharjahUAEPhone +971 (6) 5575 991Fax +971 (6) 5575 [email protected]

Ukraine – UNILABZapadynskaya Str., 5, office 005Kiev, 04123UkrainePhone/Fax +38 044 430 48 45; +38 044 430 01 71+38 044 430 49 89; +38 044 430 00 62+38 044 430 51 [email protected]

United Kingdom – Metrohm U. K. Ltd.Metrohm HouseEvenwood CloseDaresbury CourtRuncornCheshireWA7 1LZUKPhone +44 (1) 928 579600Fax +44 (1) 928 [email protected]

Uruguay – Supertec S.A. ArgentinaPiedras 1930C1140 ABP Buenos AiresArgentinaPhone +54 (11) 4307 2141Fax +54 (11) 4307 [email protected]

Metrohm Subsidiaries

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YYemen – Al Falah TradingP.O.Box 7477Al MansoorahAdenPhone +967 2 345 073Fax +967 2 [email protected]

ZZimbabwe – Metrohm South Africa (Pty) Ltd.1Woodmead driveWoodmead Estate, building 12Woodmead (Sandton)SüdafrikaPhone +27 (11) 804 0030Mobil +27 (78) 643 7113 (Ravi)Fax +27 (11) 804 [email protected]

UUSA – Metrohm USA, Inc.6555 Pelican Creek CircleRiverview, FL 33578USAPhone +1 (813) 316 47001-866-METROHM (toll-free)Fax +1 (813) 316 [email protected]

Uzbekiststan – Distrilab Kasachstanoffice 858, Samal-2 districtBusiness Centre «Satti»050059 AlmatyPhone +7 (727) 2506362Fax +7 (727) [email protected]

VVenezuela – CENATEC CA Tecnología de LaboratorioAv. Sucre, Los Dos Caminos, Torre Centro Boyacá,Piso 23,Apartado 60913,Caracas 1060RIF : J- 00143737-1Phone (0212)2841110 – 2853361 – 2847533 – 2856373 – 2843244Fax (0212) 2858803 – [email protected]

Vietnam/Danang – Hoa Y CO., Ltd.305-C Ngo Quyen StSon Tra DistDanangVietnamPhone +84 (511) 393 3942Fax +84 (511) 393 [email protected]

Vietnam/Hanoi – Hoa Y CO., Ltd.255/12, Vong StHanoiVietnamPhone +84 (4) 3628 4271Fax +84 (4) 3640 [email protected]

Vietnam/Ho Chi Minh – Hoa Y CO., Ltd.06 Yen The Street, Ward 2Tan Binh DistrictHo Chi Minh CityVietnamPhone +84 (8) 3848 8523Fax +84 (8) 3848 [email protected]

Metrohm Subsidiaries

Page 246: General Catalog 2010 | 2011laboaragon.com/docs/marcas/metrohm/Metrohm Catalogo General.pdf · really easy with Metrohm Metrohm AG is the only company whose range of products covers
Page 247: General Catalog 2010 | 2011laboaragon.com/docs/marcas/metrohm/Metrohm Catalogo General.pdf · really easy with Metrohm Metrohm AG is the only company whose range of products covers
Page 248: General Catalog 2010 | 2011laboaragon.com/docs/marcas/metrohm/Metrohm Catalogo General.pdf · really easy with Metrohm Metrohm AG is the only company whose range of products covers

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