GEA Farm Technologies

Safety Data Sheet according to Regulation (EC) No. 1907/2006

Print date:

Cliniwash

Revision date: 28.05.2014 Revision no.: 1,10

1. Identification of the substance/mixture and of the company/undertaking

Identification of the substance or mixture

CliniwashUse of the substance/mixtureCleaning agentCompany/undertaking identification

SupplierGEA Farm Technologies (UK) Ltd.Wylye Works, Watery Lane, Bishopstrow,GB Warminster, Wiltshire BA12 9HtTelephone: + 44 (0)1985 216444

Responsible Department:For technical or commercial enquiries:Tel: + 44 (0)1985 216444 Fax: + 44 (0)1985 216692e-mail: info.geafarmtechnolgies@geagroup.com24 Hour Emergency Telephone No.For advice on chemical emergencies, spillages, fires or First Aid+44 (0) 870 190 6777 (GEA Farm Technologies)

Responsible for the safety data sheet: sds@gbk-ingelheim.de

2. Hazards identification

ClassificationIndications of danger : IrritantR-phrases:Risk of serious damage to eyes.

3. Composition/information on ingredients

Chemical characterization ( Mixture )Aqueous solution

Hazardous components

EC No. CAS No. Chemical name Quantity Classification

207-838-8

215-687-4

231-556-4

287-494-3

497-19-8 Sodium carbonate < 20 % Xi R36

1344-09-8 Sodium silicate < 20 % Xi R36/37/38

10332-33-9 Sodium perborate < 10 % Xi R37-41

85536-14-7 Alkyl benzenesulfonic acid < 10 % Xn, Xi R22-38-41

68002-97-1 Lauryl alcohol ethoxylate < 5 % Xn, Xi R22-41

Full text of each relevant R phrase can be found in heading 16.

4. First aid measures

General informationRemove and wash contaminated clothing before re-use.Consult a physician.

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Cliniwash

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After inhalationMove to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. If you feel unwell, seek medical advice.After contact with skinWash with water and soap as a precaution. Consult a doctor if skin irritation persists.After contact with eyesRinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical treatment by eye specialist.

After ingestionDo not provoke vomiting. Consult physician. Attention in case of vomiting - acute danger of suffocating, produced by foaming ingredients. Rinse mouth. Make drink some glasses of water. The decision whether to provoke vomiting is to be taken by a physician.

5. Fire-fighting measures

Suitable extinguishing mediaProduct does not burn, fire-extinguishing activities according to surrounding.Extinguishing media which must not be used for safety reasonsFull water jet.Special exposure hazards arising from substance or mixture itself, combustion products, resulting gasesFire may produce: Irritant/corrosive, flammable as well as toxic distillation gases (carbonization gases).Special protective equipment for fire-fightersWear self-contained breathing apparatus and protective suit.Additional informationCool containers at risk with water spray jet.Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

6. Accidental release measures

Personal precautionsEnsure adequate ventilation.Use personal protective clothing.Avoid contact with skin, eyes and clothing. Avoid dust formation.

Environmental precautionsDo not discharge into the drains/surface waters/groundwater.

Methods for cleaning up/taking upPick up mechanically, avoiding dust, and provide disposal in suitable recipients.

7. Handling and storage

HandlingAdvice on safe handlingKeep container tightly closed.Avoid contact with skin, eyes and clothing.Provide appropriate exhaust ventilation at machinery and at places where dust can be generated.

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Cliniwash

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Advice on protection against fire and explosionNo special protective measures against fire required.

StorageRequirements for storage rooms and vesselsKeep containers tightly closed in a dry, well-ventilated place.Protect from atmospheric moisture and water. The product is hygroscopic.Advice on storage compatibilityIncompatible with acids.Further information on storage conditionsKeep away from food, drink and animal feeding stuffs.

8. Exposure controls/personal protection

Exposure limit values

not available

Occupational exposure controlsProvide appropriate exhaust ventilation at machinery and at places where dust can be generated.Protective and hygiene measuresDo not breathe dust. Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke.Avoid contact with skin, eyes and clothing.Remove and wash contaminated clothing before re-use.Respiratory protectionNo personal respiratory protective equipment normally required.Respirator must be worn if exposed to dust.Hand protectionProtective gloves resistant to chemicals made off natural-rubber latex, minimum coat thickness 0.6 mm, permeation resistance (wear duration) approx. 240 minutes, i.e. protective glove <Lapren 706> made by www.kcl.de. This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN 374 carried out under lab conditions.Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the recommendations given by the manufacturer of protective gloves.Eye protectionTightly fitting goggles.Eye wash bottle with pure water.Skin protectionLong sleeved clothing.

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9. Physical and chemical properties

General informationPhysical state:Colour:Odour:

Revision date: 28.05.2014 Revision no.: 1,10

PowderWhitePerfumed (scented)

Important health, safety and environmental informationTest method

pH-Value (at 20 °C): 10 - 11 0,5%

Changes in the physical stateFlash point:

Lower explosion limits:Upper explosion limits:Water solubility:(at 20 °C)

Other informationIgnition temperature:Bulk density: 500 - 600 g/l

10. Stability and reactivity

Conditions to avoidTo avoid thermal decomposition, do not overheat. Exothermic reaction with: Acids.Materials to avoidAcids.Hazardous decomposition productsNot knownFurther informationNo decomposition if stored and applied as directed.

11. Toxicological information

Empirical data on effects on humansRisk of serious damage to eyes.

n.a.

n.a.

> 10 g/L

n.a.

Ingestion causes irritation of upper respiratory system and gastrointestinal disturbance. Watch out. Beware, hazard of foam aspiration. Dust can irritate the upper respiratory tract and the lung. Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product.

12. Ecological information

Persistence and degradabilityThe surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer.Further informationDo not flush into surface water or sanitary sewer system.

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Low hazard to waters.

13. Disposal considerations

Advice on disposalDisposal in accordance with local regulations.

14. Transport information

Other applicable informationNo hazardous material as defined by the transport regulations.

15. Regulatory information

LabellingAdditional advice on labellingAccording to EC-regulations the product is to be labelled as follows:Danger symbols: Xi - Irritant

Xi - Irritant

R phrases41 Risk of serious damage to eyes.S phrases25 Avoid contact with eyes.26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.39 Wear eye/face protection.EU regulatory information 1999/13/EC (VOC):

National regulatory informationWater contaminating class (D):

16. Other information

0 %

1 - slightly water contaminating

Full text of R-phrases referred to under sections 2 and 322 Harmful if swallowed.36 Irritating to eyes.36/37/38 Irritating to eyes, respiratory system and skin.37 Irritating to respiratory system.38 Irritating to skin.41 Risk of serious damage to eyes.Further InformationThe information in this Safety Data Sheet refer to the concentrate, not to the ready to use solution.

Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the product (in this sense consult information on use and on product), but to liberation of major amounts in case of accidents and irregularities.The information describes exclusively the safety requirements for the product(s) and is based on the present level of our knowledge.This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal

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Revision date: 28.05.2014 Revision no.: 1,10

warranty regulations.(n.a. = not applicable; n.d. = not determined)

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)

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