GATE Chemical Engineering 1999

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  • 8/20/2019 GATE Chemical Engineering 1999

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    IGATE   1999

    I

    u 'M

    It==:-

    CHEMICAL ENGINEERING

    : =::=====:=:J

    SECTION A

    75 Maltul)

    ONE

    MARKS QUESTIONS

    1 -

    35

    )

    For each

    of

    the followmg questions ( I

    IO

    35

    ),

    fo

    ur

    altemati es -

    A.

    B, C and 0 arll pro1'ided.

    U1dicate the correct answer by writing A, B. C or

    0. ns npproprinte, \£D inst the corresponding

    quest ion number in the

    1n

    the t S I H r book.

    2 ,

    3.

    5

    IMarks : I '

    35

    = 35)

    The system

    of

    equations.

    2x +

    4

    e

    iO

    Sx

    +

    10y= 25

    n

    bas

    no

    w

    1iq

    ue solullQn

    b. has only one solution

    c

    has

    only two

    solution:;

    d. has mtuute solultons

    Four .fnir coins are tossed simu

    lUlilcous

    ly

    The probabi li\)' ~ l a l nt least one head turns

    up is

    1L 1 )6

    b, ISf[ i

    c.

    7

    /fl

    d. 1/R

    a. ll

    b

    c. 2

    d. 3

    I

    The hannonrcseries L ;;

    r

    n. com'erges

    for

    p> 1

    b.

    Ji

    v,;rges

    for

    p

    > I

    c

    co

    m•erges fo r

    r

    < l

    d. v e r g ~ s for p < I

    1\ solution

    of

    spec.fic gmvlly

    J.U

    consrS1s

    of 35% A

    by 11e1ght an

    d the

    ceru

    aioing B

    he speci [tc gmvt

    t)

    of A is U7, he

    speci

    fic

    gr:wtly

    ofB

    i>

    7

    15

    .

    I l l,

    3, 1,

    25

    b I 3

    c. 1,35

    d. I

    .2

    Pu

    ru

    A

    in

    gQS phase

    ~ u e r s

    a reactor 5(\%

    of L

    ts

    A

    is

    con•ened to B Uuougl1 the

    tll{lction

    ~ 3

    B.

    Mole-

    fracnon of A .iu

    the e X

    streaQl iS

    (1, 1/2

    b 1/3

    C,

    1/4

    d. 1/5

    Which uf the

    fo lloWJII l is

    true

    for

    Vtrinl

    equation of sUI o

    a.

    Vinal cocff:ictems are wnve r

    sal

    COilS Ul nLS

    b

    Virial

    coe l'fi

    cient

    B

    represen

    ts

    t h r ~ e

    bod)' onteroctions

    c. V.r"11 coemcrents are funchons ol'

    tempern

    turc on

    ly

    d For some gases, Vi

    rial

    equations and

    ideal gas ~ q u a t i are the s;une

    A g:rs

    mrx tu

    re

    of three

    componen

      S

    br

    o

    u

    gh

    t

    in

    c.ontact

    \ \ ~ l h

    n

    dispcrston

    of

    an

    organic phase in

    wa

    ter. The degrees of

    freedom or the

    system

    are

    a.

    1

    b. 3

    ·

    5

    d, i

    A pr.pe or I D

    4

    m is

    bi

    furcat

    ed

    mto Lwo

    p

    ipes of

    LD . 2 m each. If the m·erage

    velocity

    of warer nowwg

    th

    rough he .main

    prpe IS 5 m/s.

    the

    ave rage 1 elooi Ly

    through

    the birurcared prpes

    1s

    a 20

    ts

    b. I J m/s

    c, 5 /2 m

    /s

    d 5 mls

    In centnfugal pumps . cantallon occurs

    1vben pressure of the impe

    ll

    er eye or vane

    beco

    mes

    Jess

    thnn

    nrmospheric

    pr

    essure

    b. more

    tban

    liq·urd \'apour pressure

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    Lt.

    12.

    13.

    14 .

    15.

    16.

    l7

    c. Otan IJquld

    vp

    pour preeJii

    cicnl

    a. co ntinues IQ increnst:"

    b. on iouef\ to decrease

    c g

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    5.

    26.

    An e n d o t h e r m i ~ second-order rea..:tion l>

    l lllrled

    out

    ln

    •n

    adi:tbati

    c

    pl

    ug

    flo\\

    rcttetor. The rule nl'btalgcnerallon

    maxi

    mum althc inlet o

    flhc

    c o r

    b, m a . ~   u at thce;(fl oflhe

    reactot

    mxximum at the

    e n t e r

    or

    1

    e r e a ~ t o r

    IL c

    of

    where n

    ~ 0.

    is i l c : f i n ~ : d rm ly or

    th.:

    ,•place

    parnmolcr. S

    ct.

    since

    a. the funct ion is e.wont:ni.Jnl

    b

    he L ~ p l o c a - t r a n s f o r m

    Integral af

    ~ n t

    llliS

    finjte vnJu.,: only

    for

    s a

    .:.

    ll1e

    L n 1 l l a ~ e - t r a n s f 0 1 m Integral of

    ""p(nt)

    hru

    initial values onl) ou

    d. lh.: ·fimllllon exp(•ll is

    p i d l . l e - w l ~ e

    continuous only for s a

    A

    sys

    tem

    ilh

    doubt

    .

    pole

    ot

    lit'>

    o

    rigin

    is anstablo

    sin e

    the conusponding tcnn iu

    the lime

    domain

    n. lsa co

    nst ant

    b

    .. grows- e ~ - , > o n e n t i : a U y with

    time.

    c. grows linonrly wiU1 time

    tl.

    aooay• lin.:nrly

    will\ tlmd

    27. A ~ i n u s o i d a variation in d1 :

    inlnJt

    P""•irrg

    through • linear firsl-order system

    a. b

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    questiont 53 to 55

    two itclll i ar

    e indic

    oled

    in the

    lcl\-1\and

    column

    lind oil;

    items in

    h

    e righHmnd

    col umn

    . Each

    item

    in the

    icl

    l-htm

    cl c41umn

    It

    closely ossoeiatod

    \Vith o

    ne of the· items in

    the

    ri

    g

    hr-hnnd I.'Oh

    nnn. F'or e

    nch. < t u e < ~ L i o n

    write

    the

    nppmpriBte mnlch in t)l

    e cQ

    oTe.s-p.w

    r ~ p C L 1

    i v c : ~

    Ute p a r t ~ pressor" of bl,

    (p -

    -

    Pv"') 11]1

    d. l J I

    bois are

    OS

    peo

    stand:trd o l ~ t . i o n

    a, Dp-p)llr

    I '

    b ( l) c

    P

      p)filr

    18

    Jl

    ·

    D

    P-

    p)  J

    18 , ,

    d. [ f/

     

    Jl ~ h

    fL

    2. \Vater

    is

    Oowing

    : l l

    l

    m

    tJ

    trougll a

    (cJf 10 em J.D.)

    "itl\

    o right angle bend.

    The

    l'

    o

    l'l

    c in

    e w t o n ~

    e:

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    2nf). IJ -

     r ,-r, )

    •L 2irk

    T

    To

    • 1 - ]

    Jr,+r,)/2

    44

    . For

    a

    coumer-cm-r.:nt ltJ:OL cKalt:tngcr

    wiU1

    T'to 80

    C. T

    •, =

    60

    C, =50

    C,

    and T

    1

    ,

    =

    )0

    r .

    and

    Inc

    tempermure

    ditlero1ee

    betweeu

    Ule

    IWO >lt'tmms being u.e S3111C

    0 1 ' ) ' 1 \ ' b ~ r c •long z, the direction of flo"

    cof

    the

    hC t

    lluid, the temperature prolile

    1 \ o u l d satisl)

    J T " 'l

    II . l I

    enzene

    und

    wlucnu aJ' 3 and alluu;phcre;

    rc:spdlli ts

    ~ r "

    in olquilibtium, the vfipout t l h ~ e mo le

    lhlction of bcn7.ne ;,

    "' o

    -18.

    -19.

    50

    .

    S

    .

    b. 0,6

    e. o.s

    d,

    0,2

    sura

    For the liquid pbll IU t t : r o o ( t f   i r r e v ~ i b l t

    l'll>cllon A > B, tho.corove,..ioo of A in •

    C'STR lilund

    111 be

    11.3

    Ill "

    "I'"""

    1 iO¢

    this

    mtitl il' trnn5itllln·siatc Ulou

    o

    y

    Ulled

    with

    1 1 1 1 snme

    VA

    lue of EIR l

    a Lli

    b. 2

    \:

     

    2.24

    d. u

    A

    C V 1 J 1 8 l J e followinll

    lTan5fer filnctlons .

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    cxp(-20.r)

    d.

    •'.,-2, - 1

    53 Euch item gJven in the lefl-hlllld rolumn s

    close ly ajsi>Cifilt:li \ 1ith

    a

    specific

    h n r n c t < ~ i listotl in the r i J ~ h l · h u n d

    l u m n

    t.

    lat

    ch

    < .'lch

    of'lhe i t e m

    1 1 ~ L h th

    e

    UIJrfC$ ponding h a r J t l c r i

    l c .

    (\\'rile

    hoth aJts\\c:rs

    in 13nx Nn .53)

    A. 'l'rlnl>'J)IIrl:ni

    of thd

    items listed

    tn

    tltc right-hand column

    Match

    e.1ch

    me

    th

    od

    witl1

    the

    corresponding item

    .

    lWrite both s w e ~ ul H o No. 54 1

    A, Discounted ca•h

    l

    ow

    B. D ~ l l n balance

    I. Depred ation

    2. Jluyout

    po

    riod

    3. l'rolit.1bitit

    y

    annlysis

    -t

    v l l i ~

    \lo luc

    .5 . Annuilv

    (i

    .

    WClr-king

    r l l . a l

    55  l'vlntch each rol)•mer mentioned in the left

    hand

    1 u r n 1 1

    wi01

    Ute corrc:spouding

    cbc"llllenl nature listtd ln the r i f l l ~ h r u u

    colu

    mn.

    (Write both

    n s w ~

    in Box

    Ko

    .

    jS)

    A.

    Pcrs,>

    :><

    B. Rnyon

    I.

    Po

    l

    A O ~ c h a r t d e

    L

    P•l

    lyamtdc

    :;.

    P· hy ltupezold•l

    'Ulc

    ,

    Usc

    J

    tap

    •ize

    of

    0.2.

    O

    hlll

    iJ1

    li

    te

    error b

    {>

    nnds for this

    so lution.

    ( '

    ampule th

    e

    ahsohth>

    error

    of

    the nnm

    eric.1l

    so

    lut

    ion

    hy

    ev

    olualing the

    in

    tegral analyll.u>ll) .

    tA ·

    Solve tb; 6XJ• 6x by the

    fo

    llowing

    met

    b

    10

    to

    . The c ~ > n v e r : s i o u Qf ~ t h ~ oo •

    single pa s through the rc•.ctor is 25 1., l11c

    unrcactcd ethanol is completel) separated

    fi'om the TCI\Ci

    ion

    pro

    du

    cts

    and

    rooycl

    ed

    .

    \Vital

    i• U1e ta

    litl

    of rccy,lc stream Ill the

    fresh 1

    .-e

    d m u \Vhnt

    i•

    the

    ca

    mp

    os ititm of the QU[Iel >1re:tm. lh>m th

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    61

    For

    Ute

    binary ~ y s t e m me thanol (I ) and

    J)cu:tcnc

    (2). the fC< OlllffiOOdcJ

    VaiUilS ol

    the Wi

    l

    90n

    pu

    .mwe lers ul 68

    C

    ur"

    A

    1

    : =

    0.L .5 1 rmd A ~ t - 0 3456 . The vupour

    press"'" ofpur" spedos ut68 Cure Pt -

    68.

    75

    kl'a und P:i"' ~ 11.5.89 kPil ShQ\1

    tho given s : y ~ 1 c

    cHill

    lorm ,UJ

    ll't< otrupe a168 C. ~ u m thuJ Ute VIIJli>Ur

    ll.::ltavcs liko au itle:Jl ,U.S..

    62.

    FI0\1 I'Ule

    or

    I I ' U l ~ r

    llowin l l u t > l l ~ h

    a

    f'lJl

    is being

    UIC'.JS

    UI\:d by usina an uriticu

    rue r•r sl•mu in the Gollowllig figur•

    a What ts l bc e c d o n ol' lluw

    rn

    tho

    pi l"''t

    b. Dcm e an expression tbr vcloolh'

    thruugh tho c•ritic u d y · s t a t ~

    toUJ

    >Crulure

    prolilo

    nut beat

    tmusfcr mte

    for u hollow spbencul contnhter.

    ·

    n _ i w t ~ t

    SU$[Oce

    (nt r = r,} is maintained ut T T,.

    and the ou ter Sllrlllce (at r - r,,) is

    muiutained ut T -

    (,(,

      150 kg of wolc

    r

    is lo

    be

    heated in

    n slcom·

    J 3 C I . e t ~ d

    v-ossel (r('lm 2.5 C IC> 80 C. St.:auo

    ts

    ooutlcJU;ing ut 110 C.

    and

    the hea l

    transfer urea ts 0.15

    nl

    l l o ~

    h 11l

    trnusfer

    coetlicio>nls lbr ~ u d e u s a t i o u

    {•f

    steam and

    heating

    of

    wmer bv couvecuon arc I00(1

    .

    - ,

    Wim· C sud 500 W nt· C ~ s p e c w e l v

    appropn:nc uusteadv balun

    t

    CQm[lO$i

    lion

    nnd

    the exit composition.

    68

    . D ~ t c r m l a t i l l n of c flicicnc, is omucnl in

    plolo column design. llta -gns nod

    liqlllcl

    rn tcs arc

    0 I

    and

    1

    1.25

    kmol s

    r l l s p : : ~ i v e l y

    The tntcrtiwinl nnw for miL« tro

    n

    s tcr is 35

    ·· l t '

    l-

    nr

    ltlluJ· on Ihe

    p utc. Tuc

    re

    st

    doncc

    tnl1u of both the liquid and gas in the

    fm th

    1.onc

    is

    3scoonds,

    The

    liquid phose

    and gn.•

    f'h:JS(l m a s

    transfer ~ u ¢ t l i c i ~ n t s are I <

    10-

    2

    m und

    2 '

    -l (r m " " ~ P " c l i v e l y

    Culculuw

    u, Uquid phMe

    l l U n s f ~ r

    u

    nitS

    b. ]tiS

    phuse

    lnUlsf n unit>

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