Upload
lenga
View
216
Download
1
Embed Size (px)
Citation preview
/ 30
Gas/Surface Interaction Study of Low-Density Ablators in
Sub- and Supersonic Plasmas
!B. Helber
1,2, A. Turchi
1, O. Chazot
1, A. Hubin
2, T. E. Magin
1
!1Aeronautics and Aerospace Department, von Karman Institute for Fluid Dynamics, Belgium
2Research Group Electrochemical and Surface Engineering, Vrije Universiteit Brussel
1
NASA Applied Modeling & Simulation (AMS) Seminar Series June 26, 2014
!based on AIAA 2014-2122
11thAIAA/ASME Joint Thermophysics and Heat Transfer Conference
/ 30
TPM for Atmospheric Reentry
NASA Stardust probe, reentry: Jan. 15, 2006 (12.9 km/s) (AIAA 2008-1202)
2
Future Missions: Ablative TPM Sample return, ISS serving (Dragon, ARV,…), MPCV Atm. reentry speeds > 10km/s Mass loss and surface recession Prediction of material response required High margins decrease payload
New materials (1990’s) Phenolic impregnated carbon fiber preform Very porous low density ablators
/ 30
TPM for Atmospheric Reentry
Gas-Surface Interaction
Complex Multiphysics - Multiscale Problem
3
C248
NH (A−X)
OH (A−X)
CN violet (B−X)
CH (A−X)
C2 Swan
Na
Hβ
Hα
NO777 N lines
Air plasmaNitrogen plasma
Material
Radiation
/ 30
We aim at improvement of
Experimental Methods (VKI)
4
TPS Design / Material (VUB, Airbus DS, ESA)
Material Response Modeling & Validation (VKI, collaborations)
/ 30
In the following
5
GAS - PHASE
MATERIAL
chem. active surface
/ 30
Reactive Surface • surface temperature & emissivity • centerline recession rate • post-ablation topology (SEM)
In the following
5
GAS - PHASE
MATERIAL
chem. active surface
/ 30
(2) Surface ➪ Temperatures / Recession
In the following
5
GAS - PHASE
MATERIAL
chem. active surface
/ 30
(2) Surface ➪ Temperatures / RecessionGas-phase • Ablation species injection • Strong radiators and boundary
layer absorption
In the following
5
GAS - PHASE
MATERIAL
chem. active surface
/ 30
(2) Surface ➪ Temperatures / Recession(3) Gas-phase ➪ BL emission & temp
In the following
5
GAS - PHASE
MATERIAL
chem. active surface
/ 30
(2) Surface ➪ Temperatures / Recession(3) Gas-phase ➪ BL emission & temp(4) Material ➪ Pyrolysis outgassing
In the following
5
GAS - PHASE
MATERIAL
chem. active surface
/ 30
(2) Surface ➪ Temperatures / Recession(3) Gas-phase ➪ BL emission & temp(4) Material ➪ Pyrolysis outgassing
In the following
5
GAS - PHASE
MATERIAL
chem. active surface
(1) Materials and Methods for Ablation Characterization
/ 23
Materials of Investigation
6
Carbon fiber preform (Mersen Scotland Holytown Ltd.) • chopped carbon fibers, fully carbonised • density: 180-210 kg/m3, porosity: 90%
AQ61 (Airbus DS) • low density carbon-phenolic • made of short carbon fibers impregnated → compacted & pyrolyzed • low resin content
Asterm (Airbus DS) • low density carbon-phenolic • rigid graphite felt impregnated → polymerization • precursor similar to carbon fiber reform
no phenol
with phenol
with phenol
/ 23
Carbon fiber preform, non-pyrolyzing (Mersen Scotland Holytown Ltd.)
Materials of Investigation
7
AQ61, carbon-phenolic (AIRBUS DS)
650μm
13μm
/ 30 8
M">>"1"
Shock"
Relaxa/on"zone"
Aerospace"vehicle"nose"
M << 1
Real%flight%situa-on%
Ground%test%
y"Body"
x"
δ"
Ve"
(dU/dx)e"
M"<<"1"
plasma"jet"
TPS"sample"
Stagnation point similarity:!! Hf = Hexp!! pf = pexp!! βf = βexp, β = dU/dx|e
1.2-MW Inductively Coupled Plasmatron: Methodology
/ 30
1.2-MW Inductively Coupled Plasmatron
Gas: Power:
Heat Flux: Pressure:
9
water&cooled+calorimeter+
test+sample+
pitot+probe+
spectrometer+op1cs+
sample+condi1on+
control+system
+
High+speed+camera+
op1cal+access+pyrometer+
op1cal+access+radiometer+
Air, N2, CO2, Ar 1.2-MW > 12 MW/m2
10 mbar - 1 atm
/ 30
1.2-MW Inductively Coupled Plasmatron
Gas: Power:
Heat Flux: Pressure:
9
water&cooled+calorimeter+
test+sample+
pitot+probe+
spectrometer+op1cs+
sample+condi1on+
control+system
+
High+speed+camera+
op1cal+access+pyrometer+
op1cal+access+radiometer+
Air, N2, CO2, Ar 1.2-MW > 12 MW/m2
10 mbar - 1 atm
/ 30
Our interest !
Surface temperature Emissivity Internal Temperature In-situ recession analysis Volumetric recession Chemical composition Temperature estimation
(AIAA 2013-2770)
10
!test!sample!
plasma!torch!
light!collec/on!system!(lens!&!mirrors)!!
exhaust!&!!!!!heat!exchanger!!
reac/ve!boundary!!!!!layer!
op/cal!fibre!ends!
High!speed!camera!
test!chamber!
HR=4000!spectrometer!
Func/on!generator!
2=color!pyrometer!
Techniques for In-Situ Ablation Characterization
/ 30 10
1 2 3
Our interest !
Surface temperature Emissivity Internal Temperature In-situ recession analysis Volumetric recession Chemical composition Temperature estimation
(AIAA 2013-2770)
Techniques for In-Situ Ablation Characterization
/ 30
Three Dedicated Test Campaigns
11
/ 30
1. General ablation tests: • air and nitrogen • heat fluxes: 1 - 3 MW/m2, ptot = 15 - 200 hPa
Three Dedicated Test Campaigns
11
/ 30
1. General ablation tests: • air and nitrogen • heat fluxes: 1 - 3 MW/m2, ptot = 15 - 200 hPa
2. Grain study: • only air • 0.3 - 1 MW/m2, p = 15hPa
Three Dedicated Test Campaigns
11
with-grain through-grain cylindricaltc 5mmtc 10mm
/ 30
1. General ablation tests: • air and nitrogen • heat fluxes: 1 - 3 MW/m2, ptot = 15 - 200 hPa
2. Grain study: • only air • 0.3 - 1 MW/m2, p = 15hPa
3. High-heat flux tests (supersonic)
Three Dedicated Test Campaigns
110 5 10 15 200
2
4
6
8
10
Time, s
Hea
t flu
x, M
W/m
2
with-grain through-grain cylindricaltc 5mmtc 10mm
/ 30
Volumetric Ablation (shape change)Non-pyrolyzing carbon-preform
−30 −20 −10 0 10 20 300
10
20
30
40
50
original shape
ablated shape
recession
Radius, mm
Hei
ght,
mm
Subsonic, 0.3MW/m2, 15hPa
−30 −20 −10 0 10 20 30
original shape
ablated shape
recession
Radius, mm
Subsonic, 0.3MW/m2, 15hPa
−30 −20 −10 0 10 20 30
original shape
ablated shape
recession
Radius, mm
Supersonic, 9MW/m2, 80hPa
• linear (axial) recession up to r = 20mm
• small shape change ➟ constant boundary conditions
• edge ablation (shoulder) due to peak heating
• shape change ➟ increase of surface temperature
• high centreline ablation • iso-q shape
➟ caused by shock or nozzle (35mm)
1212
/ 30
Surface Temperature Distribution by IR-imaging
13
1000
1400
1800
2200
1000
1400
1800
2200
1000
1400
1800
2200
1000
1400
1800
2200
Test start Test end
cylindrical
hemispherical
Tstag increase
qcw = 1MW/m2, ps = 15hPa
/ 30
Test Sample Shape Affects Temperatures
14
0 20 40 60 80 1000
500
1000
1500
2000
2500
Time from injection, sTe
mpe
ratu
re, K
0 20 40 60 80 1000
500
1000
1500
2000
2500
Time from injection, s
Tem
pera
ture
, K
qcw = 0.3MW/m2 qcw = 1.0MW/m2
/ 30
Test Sample Shape Affects Temperatures
14
hemispherical: quasi-steady
cylindrical: increasing
0 20 40 60 80 1000
500
1000
1500
2000
2500
Time from injection, sTe
mpe
ratu
re, K
0 20 40 60 80 1000
500
1000
1500
2000
2500
Time from injection, s
Tem
pera
ture
, K
cylindrical: lower internal heating
qcw = 0.3MW/m2 qcw = 1.0MW/m2
/ 30
Fiber Direction Slightly Affects Temperatures
15
0 20 40 60 80 1000
500
1000
1500
2000
2500
Time from injection, sTe
mpe
ratu
re, K
0 20 40 60 80 1000
500
1000
1500
2000
2500
Time from injection, s
Tem
pera
ture
, K
w-g t-g
/ 30
Fiber Direction Slightly Affects Temperatures
15
0 20 40 60 80 1000
500
1000
1500
2000
2500
Time from injection, sTe
mpe
ratu
re, K
0 20 40 60 80 1000
500
1000
1500
2000
2500
Time from injection, s
Tem
pera
ture
, K
through-grain: lower Tswith-grain: higher Ts w-g t-g
with-grain: higher internal temperature • unexpected (lower conduction in axis direction) • but: higher conduction in radial direction ⇨ stronger sidewall heating
/ 30
Emissivity: 0.86 - 0.97
16
1600 1800 2000 2200 24000.75
0.8
0.85
0.9
0.95
1
Temperature, K
Emis
sivi
ty, −
PG1
PG2
PG3
PG4
PG5
PG6
Gray body emissivity (8� 9µm, T):
"8�9µm,T =
B(IR)
B
bb(Pyrometer)
Planck’s law (spectral radiance):
B�(T ) =2hc2
�5
1
ehc
�kBT � 1[
Wm2.sr.nm
]
400 500 600 700 8000
2
4
6
8
10
12
Wavelength, nm
Inte
nsity
, W/(m
2 .sr.n
m)
Measured: T = 1724K, ps = 15mbar
Experimental data95% Conf. boundPlanck 1724K, ε = 0.90Planck 1744K, ε = 0.90
/ 30
Emissivity: 0.86 - 0.97
16
1600 1800 2000 2200 24000.75
0.8
0.85
0.9
0.95
1
Temperature, K
Emis
sivi
ty, −
PG1
PG2
PG3
PG4
PG5
PG6
Gray body emissivity (8� 9µm, T):
"8�9µm,T =
B(IR)
B
bb(Pyrometer)
Planck’s law (spectral radiance):
B�(T ) =2hc2
�5
1
ehc
�kBT � 1[
Wm2.sr.nm
]
400 500 600 700 8000
2
4
6
8
10
12
Wavelength, nm
Inte
nsity
, W/(m
2 .sr.n
m)
Measured: T = 1724K, ps = 15mbar
Experimental data95% Conf. boundPlanck 1724K, ε = 0.90Planck 1744K, ε = 0.90
w-g
/ 30
In-situ Recession Analysis (HSC)
17
0 20 40 60 800
2
4
6
8
Time, s
Rec
essi
on, m
m
Preform
2180K
2848K1724K
>3100K
(15mbar)
0 20 40 60 800
2
4
6
8
Time, s
Rec
essi
on, m
m
AQ61
2884K
2167K>3100K
(15mbar)
➟ diffusion limited at 15mbar between 2000K and 3000K
/ 30
In-situ Recession Analysis (HSC)
17
0 20 40 60 800
2
4
6
8
Time, s
Rec
essi
on, m
m
Preform
2180K
2848K1724K
>3100K
(15mbar)
0 20 40 60 800
2
4
6
8
Time, s
Rec
essi
on, m
m
AQ61
2884K
2167K>3100K
(15mbar)
➟ diffusion limited at 15mbar between 2000K and 3000K
high T: carbon-phenolic
/ 30
In-situ Recession Analysis (HSC)
17
2347K1686K
2307K
1724K
0 20 40 60 800
2
4
6
8
Time, s
Rec
essi
on, m
m
Preform
2180K
2848K1724K
>3100K
(15mbar)
0 20 40 60 800
2
4
6
8
Time, s
Rec
essi
on, m
m
AQ61
2884K
2167K>3100K
(15mbar)
(15mbar)
w-g
t-g
➟ diffusion limited at 15mbar between 2000K and 3000K
Tsurface
high T: carbon-phenolic
0 20 40 60 8002468
Time, s
Rec
essi
on, m
m
Preform
/ 30
In-situ Recession Analysis (HSC)
17
2347K1686K
2307K
1724K
0 20 40 60 800
2
4
6
8
Time, s
Rec
essi
on, m
m
Preform
2180K
2848K1724K
>3100K
(15mbar)
0 20 40 60 800
2
4
6
8
Time, s
Rec
essi
on, m
m
AQ61
2884K
2167K>3100K
(15mbar)
(15mbar)
w-g
t-g
higher recession
➟ diffusion limited at 15mbar between 2000K and 3000K
Tsurface
high T: carbon-phenolic
0 20 40 60 8002468
Time, s
Rec
essi
on, m
m
Preform
/ 30
Ablation Regimes of Preform and AQ61
18
2000 2500 3000 35000
50
100
150
200
250
Temperature, K
Rec
essi
on ra
te, µ
m/s
Preform 15hPaPreform 80hPaPreform 200hPaAQ61 15hPaAQ61 80hPaAQ61 200hPa
/ 30
Ablation Regimes of Preform and AQ61
➟ diffusion limited ablation and sublimation regime➟ recession not much influenced by pressure! (AIAA 2012-2876)
18
2000 2500 3000 35000
50
100
150
200
250
Temperature, K
Rec
essi
on ra
te, µ
m/s
Preform 15hPaPreform 80hPaPreform 200hPaAQ61 15hPaAQ61 80hPaAQ61 200hPa
/ 30
Ablation Regimes of Preform and AQ61
➟ diffusion limited ablation and sublimation regime➟ recession not much influenced by pressure! (AIAA 2012-2876)➟ strong recession in N2 for T>3000K ➟ sublimation
comparison num. model: talk A. Turchi 18
2000 2500 3000 35000
50
100
150
200
250
Temperature, K
Rec
essi
on ra
te, µ
m/s
Preform 15hPaPreform 80hPaPreform 200hPaAQ61 15hPaAQ61 80hPaAQ61 200hPaPreform N2AQ61 N2
/ 30
Post-Oxidation Micrographs
Carbon preform oxidation
19
AQ61 oxidation
/ 30
Ablation / Pyrolysis Product Contaminated BL
Detection of contamination products originating from phenol 1. pyrolysis ➟ C2, CH, H, NH, OH 2. ablation ➟ C, CN
20
200 250 300 350 400 450 500 550 600 650 700 750 800 850 900 950
100
101
102
103
wavelength, nm
inte
nsity
, cou
nts/
s
Emission spectra of carbon−phenolic ablation in air and nitrogen plasma
C248
NH (A−X)
OH (A−X)
CN violet (B−X)
CH (A−X)
C2 Swan
Na
Hβ
Hα
NO777 N lines
Air plasmaNitrogen plasma
/ 30
Boundary Layer Radiation Profiles
CN Production: • gas phase: CO + N ⇌ CN + O • wall: Cw + Nw ⟶ CN
Experimental: Spatial CN violet emission (AIAA 2013-2770)
21
01
23
360 380400 420
20
40
60
80
dist. surf., mmλ, nm
I, W
/(m2 .s
r.nm
)
/ 30
Boundary Layer Radiation Profiles
CN Production: • gas phase: CO + N ⇌ CN + O • wall: Cw + Nw ⟶ CN
Experimental: Spatial CN violet emission (AIAA 2013-2770)
21
01
23
360 380400 420
20
40
60
80
dist. surf., mmλ, nm
I, W
/(m2 .s
r.nm
)
0 1 2 3 4 5 6 70
200
400
600
800
1000
1200
Distance from surface, mm
I λ1λ2 [W
/(m2 .s
r)]
T = 2180K, ps = 15mbar
Spectrometer 1
Spectrometer 2Spectrometer 3
/ 30
Boundary Layer Radiation Profiles
CN Production: • gas phase: CO + N ⇌ CN + O • wall: Cw + Nw ⟶ CN
Experimental: Spatial CN violet emission (AIAA 2013-2770)
21
01
23
360 380400 420
20
40
60
80
dist. surf., mmλ, nm
I, W
/(m2 .s
r.nm
)
0 1 2 3 4 5 6 70
200
400
600
800
1000
1200
T = 2180K, ps = 15mbar
Distance from surface, mm
I λ1λ2 [W
/(m2 .s
r)]
Exp. dataPolynomial fit95% Conf. bnd
/ 30
VKI: 1D Stagnation line description w/ surface ablation (A. Turchi AIAA 2014-2125)
22
species diffusionmass blowing HOT GAS
MATERIAL
CONTROL VOLUME
chem. active surface
Surface Mass Balance (SMB)
[1] Kendall et al., NASA CR 1060 (1968)![2] A. Munafò, PhD Thesis, Ecole Central Paris, 2014
Approach for ablation modelling (Kendall et al.[1])
/ 30
VKI: 1D Stagnation line description w/ surface ablation (A. Turchi AIAA 2014-2125)
22
species diffusionmass blowing HOT GAS
MATERIAL
CONTROL VOLUME
chem. active surface
convectedenthalpy
convective flux
HOT GAS
MATERIAL
enthalpy by diffusion radiation re-radiation
material conductionenthalpy char mass loss
Surface Mass Balance (SMB)Surface Energy Balance (SEB)
[1] Kendall et al., NASA CR 1060 (1968)![2] A. Munafò, PhD Thesis, Ecole Central Paris, 2014
Approach for ablation modelling (Kendall et al.[1])
/ 30
Boundary condition from experiments & plasma free-stream Experimental data for validation
GOAL: Coupling 1-D SL-code & material code (PhD Candidate P. Schrooyen)
VKI: 1D Stagnation line description w/ surface ablation (A. Turchi AIAA 2014-2125)
22
species diffusionmass blowing HOT GAS
MATERIAL
CONTROL VOLUME
chem. active surface
convectedenthalpy
convective flux
HOT GAS
MATERIAL
enthalpy by diffusion radiation re-radiation
material conductionenthalpy char mass loss
Surface Mass Balance (SMB)Surface Energy Balance (SEB)
[1] Kendall et al., NASA CR 1060 (1968)![2] A. Munafò, PhD Thesis, Ecole Central Paris, 2014
Approach for ablation modelling (Kendall et al.[1])
/ 30
Boundary Layer Radiation Profiles
Simulate line-of-sight measurement
Numerical: Simplified approach using Specair slab
23
boundary layer
slab width Δyi at xi
stagn. line solution χi, Ti, pi,
SPECAIR
locations xi
ablating surface
x
y
Ii(λ)
/ 30
Boundary Layer Radiation Profiles
Simulate line-of-sight measurement
Numerical: Simplified approach using Specair slab
23
boundary layer
slab width Δyi at xi
stagn. line solution χi, Ti, pi,
SPECAIR
locations xi
ablating surface
x
y
Ii(λ)
/ 30
Boundary Layer Radiation Profiles
Simulate line-of-sight measurement
Numerical: Simplified approach using Specair slab
23
boundary layer
slab width Δyi at xi
stagn. line solution χi, Ti, pi,
SPECAIR
locations xi
ablating surface
x
y
Ii(λ) Perspective: Radiation Coupling (PhD Candidate J.B. Scoggins)
/ 30
Comparison of Boundary Layer Radiation ProfilesExperimental - Numerical
24
0 1 2 3 4 5 6 70
200
400
600
800
1000
1200
T = 2020K, ps = 200mbar
Distance from surface, mm
I λ1λ2 [W
/(m2 .s
r)]
Exp. dataPolynomial fit95% Conf. bndNum. data
/ 30
Comparison of Boundary Layer Radiation ProfilesExperimental - Numerical
24
0 1 2 3 4 5 6 70
200
400
600
800
1000
1200
T = 2020K, ps = 200mbar
Distance from surface, mm
I λ1λ2 [W
/(m2 .s
r)]
Exp. dataPolynomial fit95% Conf. bndNum. data
0 1 2 3 4 5 6 70
2000
4000
6000
8000
10000
12000
T = 2783K, ps = 200mbar
Distance from surface, mm
I λ1λ2 [W
/(m2 .s
r)]
Exp. dataPolynomial fit95% Conf. bndNum. data
/ 30
Comparison of Boundary Layer Radiation ProfilesExperimental - Numerical
24
0 1 2 3 4 5 6 70
200
400
600
800
1000
1200
T = 2020K, ps = 200mbar
Distance from surface, mm
I λ1λ2 [W
/(m2 .s
r)]
Exp. dataPolynomial fit95% Conf. bndNum. data
0 1 2 3 4 5 6 70
2000
4000
6000
8000
10000
12000
T = 2783K, ps = 200mbar
Distance from surface, mm
I λ1λ2 [W
/(m2 .s
r)]
Exp. dataPolynomial fit95% Conf. bndNum. data
/ 30
Comparison of Boundary Layer Radiation Profiles
Locations of maxima BL thickness Order of magnitude
Experimental - Numerical
24
0 1 2 3 4 5 6 70
200
400
600
800
1000
1200
T = 2020K, ps = 200mbar
Distance from surface, mm
I λ1λ2 [W
/(m2 .s
r)]
Exp. dataPolynomial fit95% Conf. bndNum. data
0 1 2 3 4 5 6 70
2000
4000
6000
8000
10000
12000
T = 2783K, ps = 200mbar
Distance from surface, mm
I λ1λ2 [W
/(m2 .s
r)]
Exp. dataPolynomial fit95% Conf. bndNum. data
- no nitridation in model - strong assumption of constant
properties over slab
/ 30
Pyrolysis-Gas Blowing Rate Determination
mpg + mc = (ρV)w
!
mpg = mtot -
25
−30 −20 −10 0 10 20 300
10
20
30
40
50
original shape
ablated shape
recession
Radius, mm
Hei
ght,
mm
Subsonic, 0.3MW/m2, 15hPa
(Vabl ˙ ρc)
Carbon Preform (non-pyrol.): ➟ mc = mtot = Vabl ˙ ρc
Non-pyrolyzing carbon-preform
/ 30
Mass Loss Carbon Preform: Weighed vs HSC
26
1 2 3 4 5 6 7 8 9 10 110
2
4
6
8
10
Uncertainty HSC
Test case, #
Tota
l mas
s lo
ss, g
weighedestim. HSC
discrepancy: - water - initial density - damage by
deinstallation
/ 30
AQ61 Pyrolysis-Gas Blowing Rates
27
−30 −20 −10 0 10 20 300
10
20
30
40
50
original shape
ablated shape
recession
Radius, mm
Hei
ght,
mm
Subsonic, 0.3MW/m2, 15hPa
Main challenges: Side-wall outgassing, non-1D effects, too-long test times
T p m %AQ1 2167 15 1.12 23AQ6 2884 15 1.77 44
AQ7 2906 200 2.26 60
STA (Simultaneous Thermal Analysis, VKI): charred AQ61: ρc = 80-85% ρv
➟ compare to num. model
/ 30
Conclusions
28
(1) Materials and Methods • hemispherical samples • HSC imaging ➞ volume recession ➞ (4) • IR-camera: emissivity
(2) Char blowing rates • higher recession for fibers through-grain • diffusion limited ablation & sublimation (P+AQ61) • Nitrogen: sublimation and nitridation of surface (SEM)
(3) BL emission • steady ablation process • num. estimation: order of magn., location of maxima, BL thickness
(4) Pyrolysis outgassing • Vol. ablation + TGA ➞ ṁpg
/ 30
Future Work
29
Material: • simultaneous TGA/DSC at VKI of resin, AQ61, Asterm (ongoing) • additional SEM (fiber direction study)
!Modeling:
• rebuild experiments with thermal response model (e.g. SAMCEF Amaryllis, or PATO)
• rebuild boundary layer emission with updated model (nitridation, recombination ➞ talk A. Turchi)
• compare experimental pyrolysis outgassing rates to model
/ 30
AcknowledgementsFunding and materials supply:
30
In particular: N.N. Mansour (NASA ARC),
J. Lachaud (UC Santa Cruz), F. Panerai (University of Kentucky) for informative support !
Jean-Marc Bouilly & Gregory Pinaud (Airbus Defence & Space) !VKI Plasmatron & Ablation Team !VUB SURF research team
/ 30
Oxidation of Preform & AQ61 in air
Carbon preform oxidation
Oxidation of Preform and AQ61
31
AQ61 oxidation
/ 30 32
Preform & AQ61 in nitrogenNitridation Preform
/ 30 32
Preform & AQ61 in nitrogenNitridation Preform
/ 30 33
AQ61 nitrogenAQ61 nitrogen
Preform & AQ61 in nitrogenNitridation AQ61
/ 30 33
AQ61 nitrogenAQ61 nitrogen
Preform & AQ61 in nitrogenNitridation AQ61
/ 30
APPENDIX: Combined Rebuilding Procedure
• Input: Boundary layer parameter (LTE CFD computation) & measurements from experiments
• Procedure: Iteration on boundary layer edge temperature Te: ⇒ qw
n = qwexp = qw(γ, Tw, pe, he, β)
• Output: Edge enthalpy He, boundary layer chemistry, (catalycity) 34
M"<<"1"TPS"sample"
Ground'test'measurements'Navier0Stokes0domain'EM0field'
domain'
Coupled'domain' Boundary'layer'parameter'
VKI'ICP'code'(LTE'assumpCon)'
qw,'Tw,'ps,'pd'
Boundary Layer Solver
/ 30
Complex Multiphysics - Multiscale problem
Gas-phase • Ablation species injection • Strong radiators and boundary
layer absorption !Gas-surface interaction • Surface reactions & recombination • Recession rate !Material • Pyrolysis gases production and
outgassing
chemical(species((diffusion(
surface(recession(
virgin(material(
pyrolysis((zone(
porous(char(
hot(radia7ng(gas(
boundary(layer(
convec7ve((heat(flux(
radia7on(flux((
shock(heated(gas((T(~(10,000K)(
heat(transfer(
mechanical(erosion(
pyrolysis(gases(
reac7on(products(
OH( OH(
35
Coupled phenomena
/ 30
CN Radiation Simulation for Temperature EstimationNon-equilibrium?
36
370 380 390 400 410 420 4300
0.2
0.4
0.6
0.8
1
wavelength [nm]
norm
aliz
ed in
tens
ity [−
]
ASTERM, ps = 15mbar, TS = 2130K
ν′=0→ν′′=0
ν′=3→ν′′=3
Experimental spectrum
370 380 390 400 410 420 4300
0.2
0.4
0.6
0.8
1
wavelength [nm]no
rmal
ized
inte
nsity
[−]
ASTERM, ps = 100mbar, TS = 2097K
ν′=0→ν′′=0
ν′=3→ν′′=3
Experimental spectrum
/ 30
CN Radiation Simulation for Temperature EstimationNon-equilibrium?
36
370 380 390 400 410 420 4300
0.2
0.4
0.6
0.8
1
wavelength [nm]
norm
aliz
ed in
tens
ity [−
]
ASTERM, ps = 15mbar, TS = 2130K
Trot = 9281K ± 640K
Tvib = 14912K ± 1100K
Experimental spectrumSPECAIR simulation
370 380 390 400 410 420 4300
0.2
0.4
0.6
0.8
1
wavelength [nm]no
rmal
ized
inte
nsity
[−]
ASTERM, ps = 100mbar, TS = 2097K
Trot = 6311K ± 350K
Tvib = 7878K ± 320K
Experimental spectrumSPECAIR simulation
Non-thermal vibrational level distribution at low pressure (AIAA 2013-2770) ➟ Thermal non-equilibrium? ➟ Deviation from Boltzmann distribution?
/ 30
Boundary Layer Temperature ProfileNon-equilibrium at the wall?
37
0 1 2 3 4 5 2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
distance from surface [mm]
tem
pera
ture
[K]
ps = 15mbar, TS = 2130K
TrotTvib
0 1 2 3 4 5 2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
distance from surface [mm]te
mpe
ratu
re [K
]
ps = 100mbar, TS = 2097K
TrotTvib