Gas Laws and Ideal Gases 1

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    Topic 3 Thermal physics

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    The kinetic theory of gases and the

    gas laws

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    Kinetic theory/ideal gas

    We can understand the behaviour of

    gases using a very simple model, that of

    an ideal gas!

    The model makes a

    few simple assumptions"

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    #deal gas assumptions

    $ The particles of gas %atoms or molecules&

    obey 'ewton(s laws of motion!

    )ou should know theseby now*

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    #deal gas assumptions

    $ The particles in a gas move with a range

    of speeds

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    #deal gas assumptions

    $ The volume of the individual gas particles

    is very small compared to the volume of

    the gas%or the volume of the container&

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    #deal gas assumptions

    $ The collisions between the particles and

    the walls of the container and between the

    particles themselves are elastic %no kinetic

    energy lost&

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    #deal gas assumptions

    $ There are no forces between the particles

    %e+cept when colliding&! This means that

    the particles only have kinetic energy%no

    potential&o you remember what internal

    energy is-

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    #deal gas assumptions

    $ The duration of a collision is small

    compared to the time between collisions!

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    .ressure reminder

    .ressure is defined as the normal

    %perpendicular& force per unit area

    . 0 1/

    #t is measured in .ascals, .a %'!m2&

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    .ressure reminder

    What is origin of the pressure of a gas-

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    .ressure reminder

    4ollisions of the gas particles with the side

    of a container give rise to a force, which

    averaged of billions of collisions per

    second macroscopically is measured as

    the pressure of the gas

    4hange of

    momentum

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    The behaviour of gases

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    The behaviour of gaseshttp5//phet!colorado!edu/sims/ideal2gas/gas2properties!6nlp

    When we heat a gas at constant volume,

    what happens to the pressure- Why-

    7et(s do it* )es, 6ust

    not today" am sorry

    for bursting your

    bubble! 8a 8a

    http://phet.colorado.edu/sims/ideal-gas/gas-properties.jnlphttp://phet.colorado.edu/sims/ideal-gas/gas-properties.jnlp
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    The behaviour of gaseshttp5//phet!colorado!edu/sims/ideal2gas/gas2properties!6nlp

    When we heat a gas at constant volume,

    what happens to the pressure- Why-

    . 9 T%if T is in

    Kelvin&

    http://phet.colorado.edu/sims/ideal-gas/gas-properties.jnlphttp://phet.colorado.edu/sims/ideal-gas/gas-properties.jnlp
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    The behaviour of gases

    When we compress

    %reduce the volume&

    a gas at constant

    temperature, what

    happens to the

    pressure- Why-

    7et(s do it*

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    The behaviour of gases

    When we compress

    %reduce the volume&

    a gas at constant

    temperature, whathappens to the

    pressure- Why-

    p: 0 constant

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    The behaviour of gases

    When we heat a gas a constant pressure,

    what happens to its volume- Why-

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    The behaviour of gases

    When we heat a gas a constant pressure,

    what happens to its volume- Why-

    : 9 T %if T is in

    Kelvin&

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    ;+plaining the behaviour of

    gases#n this way we are e+plaining the

    macroscopicbehaviour of a gas %the

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    The gas laws

    We have found e+perimentally that"

    t constant temperature, the pressure of

    a fi+ed mass of gas is inversely

    proportional to its volume!

    p 9 =/: or p: 0 constant

    This is known as >oyle(s law

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    The gas laws

    t constant pressure, the volume of afi+ed mass of gas is proportional to its

    temperature"

    : 9 T or :/T 0 constantThis is known as 4harle(s law

    If T is in Kelvin

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    The gas laws

    t constant volume, the pressure

    of a fi+ed mass of gas is

    proportional to its temperature"

    p 9 T or p/T 0 constant

    This is known as the .ressure law

    If T is in Kelvin

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    The ey combining these three laws

    p: 0 constant

    :/T 0 constant

    p/T 0 constant

    We get p:/T 0 constant

    ?rp=:= 0 p: T= T

    Remember, T

    must be inKelvin

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    n e+ample

    t the top of @ount ;verest the temperature is

    around ABK, with atmospheric pressure around

    3!3 + =BC.a! t seas level these values are

    3BBK and =!B + =BA

    .a respectively! #f thedensity of air at sea level is =! kg!m23, what is

    the density of the air on @ount ;verest-

    .hysics, .atrick 1ullick, 8einemann

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    n e+ample

    t the top of @ount ;verest the temperature is around ABK, with atmosphericpressure around 3!3 + =BC.a! t seas level these values are 3BBK and =!B + =BA.arespectively! #f the density of air at sea level is =! kg!m23, what is the density of the airon @ount ;verest-

    Take =kg of air at sea level

    :olume 0 mass/density 0 =/=! 0 B!D3 m3!

    Therefore at sea level

    p=0 =!B + =BA.a, :=0 B!D3 m3, T=0 3BBK!

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    n e+ample

    t the top of @ount ;verest the temperature is around ABK, with atmospheric

    pressure around 3!3 + =BC.a! t seas level these values are 3BBK and =!B + =BA.a

    respectively! #f the density of air at sea level is =! kg!m23, what is the density of the air

    on @ount ;verest-

    Therefore at sea level

    p=0 =!B + =BA.a, :=0 B!D3 m3, T=0 3BBK!

    t the top of @ount ;verest

    p0 3!3 + =BC.a, :0 - m3, T=0 ABK!

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    n e+ample

    t the top of @ount ;verest the temperature is around ABK, with atmosphericpressure around 3!3 + =BC.a! t seas level these values are 3BBK and =!B + =BA.arespectively! #f the density of air at sea level is =! kg!m23, what is the density of the airon @ount ;verest-

    Therefore at sea level p=0 =!B + =BA.a, :=0 B!D3 m3, T=0 3BBK!

    t the top of @ount ;verest p0 3!3 + =BC.a, :0 - m3, T=0 ABK!

    p=:=/T=0 p:/T

    %=!B + =BA.a + B!D3 m3&/3BBK 0 %3!3 + =BC.a + :&/ABK

    :0 != m3,

    This is the volume of =kg of air on ;verest

    ensity0 mass/volume 0 =/!= 0 B!CD kg!m23!

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    p: 0 constant

    T

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    The e

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    Hample for more

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    Hample iploma A th;dition

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    Hample

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    Muestions*

    .age =D=

    Muestions , C, , L

    .age =D

    Muestions =, =3, =N!