Gaia Water

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    Gaia Water & Humic AcidD. Grant New Deer-Turriff UK

    The Gaia Hypothesis, the idea that the Earth is somehow like a living

    organism, seems to lack any convincing supporting evidence.

    Perhaps the most helpful definition of life a is that this is always a multicomponent super-interactive system; alternatively put: life is always todo with symbiosis. Single stand-alone units or species are not favored.Rather, life depends on multiple-unit-multiple-species-interactions. Theessential-to-life interaction subunits and interactions that they engage inare themselves part of life. And this surely includes their environment as

    part of any properly-defined living system. This obviously includes the

    (surface) of the planet Earth. The Gaia Earth in symbiotic relationshipwith the species which inhabit it can therefore be seen as an essential partof this living system.

    The mechanism of this symbiosis of this system currently involves acritical role for the decomposition of detritus produced by livingorganisms to form humic polymers which can also act as feedback water

    buffers which seems to be part of the mechanism used by Gaia to keepthe composition of the sea constant and also can influence the

    composition of the atmosphereb

    .

    Living cells contain various kinds of imperfectly understood surface andextracellular polyelectrolyte surface active systems which, as is now

    pointed out, show unexpectedly closely similar physical and chemical properties to the humic-matter-polyelectrolytes which occur in naturalwaters and soils. This note now further suggests that the similarity of themanner in which humic acid and un-degraded biological polyelectrolytesystems of polyanions exist at the surface of the Earth and the surfaces of living cells could further support the Gaia hypothesis. This similaritycould especially help to re-define the role of the water and water/soillayer of the Earth which contain the said ubiquitous polyanionic(abundant aggregate-polymer-C(O)O - anionic group containing) humicclass of organic substances. This class of material is the most abundantform of organic chemical molecule-class on the surface of the Earth andit also constitutes the principal organic carbon store (being present both inseawater rivers in terrestrial soils and geological sediments).It should be noted that the above soil and natural polyelectrolytes(including humic and fulvic acid salts, (algal) alginates, and (animal)heparin) always may exist naturally as multi-inorganic element matriceswhich are analogous to (human) blood serum and seawater in their multi-

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    Footnotes

    a

    The rigorous definition of what constitutes a living organism depends on the rigorous definition of what constitutes life. A commonly-held belief is that life is expected always to depend on the presenceof carbon compounds especially amino acids which are assembled according to DNA or RNA templatesystems. This clearly greatly restricts thinking to cellular forms terrestrial life of life but this mayinclude the planet surface within an extended definition. If, however, we start from the premise thatthe earth is also a living organism we may require to abandon the idea that life is something to directlydo in its most basic form with DNA and RNA. (The opposite may be the case). Life could to havestarted with pure chemistry. Water chemistry ( cf. WAP Luck). However not pure water but rather water with dissolved electrolytes organic polymers (at the start perhaps something like formose) anddispersed silica sols and other supra-molecular- structure-inducing nano-bubbles. It is of course acommonly held believed that life centrally involves the presence of liquid water. It should be noted thatthis substance has a complex poorly understood intermolecular aggregate structure which resemblessilicate random assemblages. Clearly the surface of the earth, being largely covered with water in theseas and in biota and soil etc . and water absorbed and adsorbed on humic matter on land qualifies as

    part of this kind of definition of life.[Extracellular poly-(inorganic)-phosphates occur throughout biota and organic (associated inorganic)

    polysaccharides occur in bacteria plants and animals. These different chemical polyelectrolyte systems show arange of similarities in their physical chemical behavior in regard to their potential for anti free-radical ( e.g. ex -ionizing radiation) multi metal ion binding (some less abundant metals being strongly sequestered by theseligands) and water activity homeostasis (buffering) potential which includes the ability to support a system of supersaturation of such salts of CaCO 3 which feed back into e.g . atmospheric chemistry in the seas for whichsystem there are parallel actions of e.g. anionic poly-inorganic phosphates and heparan sulfates in animals poly-inorganic phosphates and pectin in plants. Another possible, but less understood, possibility is the manner inwhich polymers elect overt or subtle micro paramagnetic and magnetic particle assemblages at the surfaces of cellsfrom species as far apart as homing pigeons to bacteria which can interact with the earth magnetic field; cf. alsohumic polymers similarly avidly bind paramagnetic ions].The role of such a chemically simple system of water soluble or water layer binding inorganic

    polymers containing only phosphate groups in living organisms, is currently obscure but has beensuggested by Kornberg to have been involved in the first stages of the evolution of living organisms.

    The role of phosphate as in ATP with universal biota triphosphate - diphosphate energy flow roles,seems to have been a major part of the background of this hypothesis. This ATP dependent energysystem has recently been demonstrated (Wiggins) to centrally involve (high density / low density)water structure chemistry as its main engine and such systems can further be suggested in principle notto be restricted to the polyphosphates. They may also occur with polysulfated molecules (similar tothose which are employed as commercial proton conductors) as well as silicates, especially theamorphous silicates. Such systems may be part of the mechanism of how interactions between water and inorganic moieties including solid surfaces in general can provide energy flow control switches.Such activities, it might be suggested also constitute what allows for a primitive logic function. Thissuggests that such primitive logic processor systems to that which biota is subject can occur at thesurfaces of bodies such as planets which also have a water coating or subsurface layer.

    b E.g. by controlling carbonate ion fluxes in the sea. It can be argued thatanthropogenic influences might achieve alteration of global climate bythis mechanism.