Formulation Isp

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Table of Contents

1. Overview of HI&I Cleaning Formulary

2. ISP Products & Properties in HI&I Cleaning

3. Hand Soap Formulations

3.10 Liquid Hand Soap

4. Laundry Formulations

4.10 Laundry Pre-spotter4.11 Laundry Pre-spotter & Stain Remover4.20 Liquid Laundry Detergent (clear & non-builder)4.21 Heavy Duty Liquid Laundry Detergent4.30 Powder Laundry Detergent (Color-Safe)

4.40 Laundry Detergent Tabs (Formula #1)4.41 Laundry Detergent Tabs (Formula #2)4.50 Fabric Softener (3 Formulations)

5. Dishwashing Formulations

5.10 Manual Liquid Dishwash Detergent5.11 Liquid Dishwash Detergent (Formula #1)5.12 Liquid Dishwash Detergent (Formula #2)

5.15 Ecological Liquid Dishwash Detergent5.20 Automatic Dishwash Liquid Detergent5.30 Dishwash Detergent Tabs5.50 Automatic Dishwash Rinse-Aid (Formula #1)5.51 Automatic Dishwash Rinse-Aid (Formula #2)


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6. Household Cleaning Formulations

6.10 Multipurpose Hard Surface Cleaner

6.20 Multipurpose Alkaline Degreaser6.21 Kitchen Disinfectant Cleaner6.22 Kitchen Degreaser (Formula #1)6.23 Kitchen Degreaser (Formula #2)6.24 Kitchen Degreaser (Formula #3)6.25 Oven Cleaner6.26 Kitchen Cleaning Wipes6.30 Glass Cleaner (Formula #1)6.31 Glass Cleaner (Formula #2)6.32 Glass Cleaning Wipes6.40 Bathroom Cleaner (Formula #1)

6.41 Bathroom Cleaner (Formula #2)6.42 Toilet Bowl Cleaner6.50 Floor Cleaner6.51 Floor Polish (2 Formulations)6.52 Carpet Cleaner6.53 Machine Carpet Cleaner6.55 Silicone Furniture Polish6.60 Windscreen Cleaner6.70 Air Freshener (Formula #1)6.71 Air Freshener (Formula #2 Poppy Fragrance)

7. Industrial & Institutional Cleaners

7.10 Car Wash Shampoo7.11 Car Wash & Wax Cleaner7.12 High Gloss Tire Wax7.13 Liquid Car Polish7.20 Alkaline Grill Cleaner7.30 Metal Cleaner

8. Appendix A: Summary of Chemical Functionalities


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1. Overview of HI&I Cleaning Formulation Guide

This guide is a collection of HI&I (Household, Industrial & Institutional) cleaning formulations

developed by several ISP scientists over the last 10 years. The main purpose of theseformulations was to prepare and test different types of cleaners in order to measure thebenefits of various ISP specialties in many diverse HI&I applications. Thus, mostformulations were developed and tested to measure specific properties and features, withoutany attempt to have a complete evaluation of long-term stability and performance in themanner that commercial cleaners are tested before introduction to the consumer market.

With this background in mind, this guide is not intended as a comprehensive treatise on thecomplex subject of cleaning formulations. Even within a specific cleaning category, thenumber of possible formulations is quite extensive due to differences in water conditions,regional regulations, consumer preferences, performance, affordability, and marketing

strategies. As it is impossible to cover all these combinations, this formulation guidedocuments one to three representative formulations for each cleaning category, that in somecases are specific to the geographic region where the formulation was originally developedand tested.

This guide can be used as a starting reference tool for sales engineers as well as formulatorsthat want to examine how ISP specialties are employed in different cleaning formulations. Itis strongly recommended that formulators use many other sources and ideas to develop,optimize and test their cleaning formulas. Considering the broad nature of cleaningformulations around the globe, it is quite unlikely that any of the formulations found in thisguide can be used as is without any modifications or additional testing. Thus, we

encourage scientists and engineers to use this guide as a starting point in their quest forbetter cleaning formulations and products.

This guide was developed as a collective effort with significant contributions from many ISPscientists around the world. Most of the formulations included in this guide are credited tothe following individuals:

Americas: Frank Fusiak Michael Jurek Purvita Shah

Europe: Jon Virgoe Rob Gibbison J.J. Gulka

Asia-Pacific: Siaw-Ee Loh T.L. Tan

Editor: Sotiri A. Papoulias


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2. ISP Products, Properties & Functionalities in HI&I CleaningISP Overview ISP is a global supplier of water-soluble chemicals including wetting

agents, solvents, thickeners, dye-transfer inhibitors, disintegrants,biocides and other specialties marketed to the HI&I market. Most ISPproducts are environmentally friendly, biodegradable and thus suitable forhousehold, industrial & institutional cleaning formulations.

ISP Product

Summaries

A. Environmentally Friendly Solvents

A-1: M-Pyrol(N-methyl pyrrolidone) Excellent chemical stability

High boiling point (202C)

Good solvency

B. Surface Active AgentsB-1: Surfadone

LP-100(N-octyl pyrrolidone)

B-2: SurfadoneLP-300(N-dodecyl pyrrolidone)

High surface activity at low concentrations: LP-100 (28 dynes/cm at 0.12%) LP-300 (26 dynes/cm at 20ppm)

Synergism with anionic surfactantsLow foaming and rapid wetting

Biodegradable

C. Water-Soluble PolymersC-1: PVP(Poly N-vinyl pyrrolidone)

Soluble in water and many organic solvents

Stabilizes emulsions, dispersions & suspensions

Highly effective dye-complexing agent

Viscosity modifier for aqueous systems

C-2: Gantrez

(Methyl vinyl ether / Maleic Anhydride Copolymer) Highly soluble in water

Stable in acidic and alkaline conditions

Effective binder for zinc, calcium and magnesium ions

Surface active in aqueous solution

Dispersing, coupling and stabilizing properties

Thickener for aqueous and organic solvent

C-3: Antara430(N-vinyl pyrrolidone and Styrene Copolymer)(Antara 430 is marketed as Polectron

in the U.S.)

Opacifier of thermoplastic latex

Excellent mechanical and chemical stability Forms transparent, thermoplastic films

Broad compatibility with other lattices

D. BiocidesD-1: Integra44 (Aqueous sodium hydroxymethyl glycinate)

Broad spectrum antimicrobial activity

Effective against bacteria and fungi

Active from pH 3.5 to 12

EPA registered


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3 Hand Soap Formulations

3.10 Liquid Hand Soap

Formulation

Ingredients Weight %

01. Sodium lauryl ether sulphate 70% paste02. Surfadone LP-300 (ISP)03. EmpigenBB04. Sodium Chloride05. Integra 44 (ISP)06. Dye07. Fragrance08. Water09. Citric acid

15.001.002.001.500.15q.s.q.s.

up to 100to pH 7.0

Formulation Instructions1. Dissolve sodium lauryl ether sulphate, Surfadone LP-300 and Empigen BB in water.2. Add NaCl. Adjust pH to 6.5~7.0 with citric acid or caustic soda.3. Add Integra 44, dye and fragrance.

Suppliers

01 Sodium lauryl ether sulphate 70% paste Huntsman, Rhodia03 Empigen BB (Lauryl dimethyl betaine) Huntsman, Rhodia02, 05 Surfadone LP-300, Integra 44 ISPOthers Dye, fragrance and Sodium Chloride Local supplier

The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or impliedas to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendationto practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.


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4 Laundry Cleaning Formulations

4.10 Laundry Pre-Spotter

Formulation


01. UnisanSS505302. GantrezAN 149 (ISP)03. Nonylphenol ethoxylate (9EO)04. Surfadone

LP-100 (ISP)05. M-PyrolSolvent (ISP)06. Sodium tripolyphosphate07. Integra

44 (ISP)08. Dye09. Fragrance10. Water

6.200.501.000.503.000.500.15q.s.q.s.

up to 100

Formulation Instructions1. Dissolve Unisan SS5053 in water.2. Add Gantrez AN 149 and sodium tripolyphosphate, stir until all dissolved.3. Add nonylphenol ethoxylate (9EO), Surfadone LP-100, n-methyl pyrrolidone (M-Pyrol)

and Integra 44 and mix until homogeneous.4. Add dye and fragrance.

Suppliers

01. Unisan SS5053 (sodium alkyl benzene sulphonate 50% paste) Huntsman, Rhodia03. Nonylphenol ethoxylate 9EO Huntsman, Rhodia06. Sodium tripolyphosphate Rhodia, Haifa02, 04 Gantrez AN 149, Surfadone LP-100 ISP05, 07 M-Pyrol, Integra 44 ISPOthers Dye and fragrance Local supplier



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4.11 Laundry Pre-Spotter & Stain RemoverFormulation

Weight %Ingredients

Formula A Formula B

01. Surfadone LP-100 (ISP) 2 402. Gafac BX-660 (80%, Rhodia) 4 ---03. Tetrapotassium Pyrophosphate 4 ---04. Ammonium Hydroxide (28%) 8 105. Isopropanol 8 206. Dipropylene Glycol Monomethyl Ether 2 1007. Perchloroethylene --- 2208. Alipal HP-433 (Rhodia) --- 4009. Triethanolamine --- 510. Water 72 17

Formulation Instructions1. Charge water to a clean, dry vessel.2. Add remaining raw materials in the order shown and mix until homogenous.

Performance DataThe above formulae were tested for stain removal ability versus a commercial European pre-wash onpre-stained 65/35 polyester/cotton swatches. For the commercial pre-wash, label use instructionswere followed prior to laundering. The soiled test swatches were evaluated after pre-treatment only,not after machine laundering. The percent removal was estimated visually after rinsing with water.

% Stain Removal

Stain Type Commercial Brand Formula A Formula BWine 20 60 85

Chocolate Pudding 20 40 75

Motor Oil 5 15 75

Lipstick 5 70 60

Grass / Humus / Blood 0 40 20

Blood 0 0 0

The test results & formulations above show that Surfadone LP-100 can provide performance superior toa contemporary solvent pre-wash product. This superior performance can be obtained with or withoutchlorinated solvents, demonstrating that Surfadone can be used to develop solvent-free formulas.



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4.20 Liquid Laundry Detergent(Clear & non-builder)Formulation


01. Unisan

SS5053

02. Tinopal CBS-X (Optical brightener)03. Sodium lauryl ether sulphate 70% paste04. Nonylphenol ethoxylate (9EO)

05. Surfadone LP-100 (ISP)06. PVP K-30 (ISP)07. Soda ash

08. Integra 44 (ISP)09. Dye10. Fragrance11. Water

25.600.0515.003.001.000.501.000.15q.s.q.s.

up to 100

Formulation Instructions1. Dissolve Unisan SS5053 in water.2. Add Tinopal CBS-X, soda ash and PVP K-30.3. Add sodium lauryl ether sulphate, nonylphenol ethoxylate 9EO and Surfadone LP-100,

stir until all ingredients are dissolved.4. Add Integra 44, dye and fragrance.

Suppliers01. Unisan SS5053 (Sodium alkyl benzene sulphonate Huntsman, Rhodia02. Tinopal CBS-X (Optical brightener) Ciba03. Sodium lauryl ether sulphate 70% paste Huntsman, Rhodia04. Nonylphenol ethoxylate 9EO Huntsman, Rhodia05, 06, 08 Surfadone LP-100, PVP K-30 and Integra 44 ISPOthers: Soda ash, dye and fragrance Local supplier



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4.21 Heavy Duty Liquid Laundry Detergent

Formulation


Part A

01. UnisanSS 505302. Lauryl alcohol ethoxylate (7EO) or KB7

03. Surfadone LP-100 (ISP)04. PVP K-30 (ISP)

05. Gantrez AN 149 (ISP)06. Glycerin07. Water

Part B08. Sodium sulphate09. Sodium tripolyphosphate

10. Antara

430 (Polectron) (ISP)11. Integra 44 (ISP)

12. Water

14.002.001.000.501.007.20

26.00

0.7022.00.500.15

25.00

Formulation InstructionsPart A1. Dissolve Unisan SS-5053 in water2. Add KB7, LP-100, PVP K-30, Gantrez AN 149 and glycerinPart B1. Dissolve sodium sulphate and sodium tripolyphosphate in water2. Mix part A and B, followed by Integra 44 and Antara (Polectron) 430

Suppliers

01 Unisan SS 5053 (sodium alkyl benzene sulphonic 50% paste) Rhodia, Huntsman02 Lauryl alcohol ethoxylate (KB7) Huntsman, Rhodia06 Glycerin Kao, Henkel03, 04, 05 Surfadone LP-100, PVP K-30, Gantrez AN-149 ISP10, 11 Antara 430 and Integra 44 ISP08, 09 Sodium sulphate and sodium tripolyphosphate Local supplier



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4. Laundry Cleaning Formulations

4.30 Powder Laundry Detergent(Color-Safe)

Formulation


01 NaPAS or NaLAS Surfactant 6.3402 Nonionic Surfactant 7EO 14.26

03 Hardened tallow soap 2.21

04 Zeolite MAP (anhydrous basis) 40.14

05 Sodium citrate (2aq) 21.93

06 Sodium carbonate (light) 1.26

07 Sodium carboxymethylcellulose (70%) 0.98

08 EDTMP (DEQUEST 2047) 1.4309 Protease (SAVINASE 6.0T 1635 GU/mg) 1.2010 Lipase (LIPOLASE 100T 287 LU/mg) 0.28

11 Amylase (TERMAMYL *60T 4.3 MU/mg) 0 or 0.0612 Antifoam granule 3.15

13 Fragrance 0.45

14 CHROMABOND S-100 or S-400 (ISP) 0.03 - 1.015 Minor other additives to 100.00

Powder Bulk density 800-900 g/l

Formulation InstructionsSee Instructions in Formulation Reference: Research Disclosure, July 1998, Number 41175



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4.40 Laundry Detergent Tabs (Formula #1)

Formulation


Base Powder01. Sodium linear alkylbenzene sulfonate02. C13-15 fatty alcohol 7EO03. C13-15 fatty alcohol 3EO04. Soap05. Zeolite A2406. Sodium acetate trihydrate07. Sodium carbonate08. Sodium Carboxymethylcellulose09. Moisture & impurities

Laundry Tab Formula10. Base Powder (see composition above)11. Sodium percarbonate granules12. TAED granules13. Anti-foam granules14. Perfume, enzymes, etc.15. HPA tripolyphosphate16. DISINTEX-600 (ISP disintegrating agent)17. Sodium carbonate

20.86.03.21.646.45.96.90.98.3

45.015.03.43.23.520.02-5

balance to 100.0

Formulation Instructions1. Prepare base powder with ingredients listed above.2. Mix base powder and remaining tab formula ingredients in a V-mixer for 30 minutes.3. Press mixed powder at 2.4 Tons pressure using dry compression to make 40 gr tablets.

(lab tabs were pressed with Carver Automated Press at 100 psi and 1sec. dwell time)4. Individual tabs were tested by submerging in 3 liters of DI water agitated at 700 rpm

until complete dissolution enabled tab granules to pass through a metal gauze cage.

Reference: Patents WO 98/55590, WO 00/32741



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4.41 Laundry Detergent Tabs(Formula #2)

Formulation


Base Powder01. C25Alkylethoxy 502. Glucose Amide03. Zeolite A04. Sodium carbonate05. DISINTEX-600 (ISP-tab disintegrating agent)06. Moisture, others

Laundry Tab Formula10. Base Powder (see above list of ingredients)11. Percarbonate12. NaSKS-613. Carbonate14. Polycarbonate15. Sulfate16. Zeolite A17. NaAS18. NaAE3S19. Na LAS20. TAED21. Citric acid monohydrate22. Enzymes23. Optical Brightener

24. SOREZ-100 (ISP soil release agent)25. Carboxymethylcellulose (soil anti-redeposition)26. Perfume, others

18.06.050.08.010.08.0

20.018.011.07.03.06.011.07.02.01.05.03.01.00.25

0.50.351.0

Formulation Instructions1 Prepare base powder with ingredients listed above.2 Mix base powder and remaining tab formula ingredients in a V-mixer for 30 minutes.3 Press mixed powder at 2.4 Tons pressure using dry compression to make 40 gr. tablets.

(lab tabs were pressed using a Carver Automated Press at 100 psi and 1sec. dwell time)4 Individual tabs were tested by submerging in 3 liters of DI water agitated at 700 rpm until

complete dissolution enabled tab granules to pass through a metal gauze cage.

Reference: Patent - WO 99/36493



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4. Laundry Cleaning Formulations

4.50 Fabric Softener (3 Formulations)

Formulation

Weight %Ingredients

Formula A Formula B Formula C

01. Adogen 44202. Arquad 2HT-7503. Integra 44 (ISP)04. Surfadone LP-100 (ISP)05. Surfadone LP-300 (ISP)06. Dye07. Fragrance08. Water

6.70-

0.150.50

-q.s.q.s.

up to 100

6.70-

0.15-

1.0q.s.q.s.

up to 100

-6.670.15

-0.30q.s.q.s.

up to 100

Formulation Instructions

1. Warm Adogen 442 to 55C, then add into water and stir well at 55C.

2. Cool to 35C.3. Add Surfadone, Integra 44, fragrance and dye.

Suppliers

01 Adogen 442 Goldschmidt02 Arquad 2HT-75 Akzo Nobel03, 04, 05 Surfadone LP-100, LP-300 and Integra 44 ISP

06, 07 Dye and fragrance Local supplier



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5 Dishwashing Formulations

5.10 Manual Liquid Dishwash DetergentFormulation


01. Deionized Water 70.0002. Dodecyl Benzene Sulphonic Acid (DDBSA) 10.50

03. Sodium Hydroxide (50%) 3.00

04. Sodium Lauryl Sulphate (29%) 13.00

05. Lauryl Dimethyl Amine oxide (30%) 2.00

06. Surfadone LP-100 (ISP) 1.5007. Fragrance, Dye, Preservative etc. q.s.

Formulation Instructions1. Charge the mixing vessel with water, and commence stirring.2. Add the DDBSA while mixing and SLOWLYadd the sodium hydroxide solution.

(Caution- this is an exothermic reaction. Cool the mixing vessel if necessary)3. Check & adjust the pH to neutral with either more sodium hydroxide or phosphoric acid,

as needed.4. While stirring, add the remaining ingredients in the order given and mix until homogenous.

Suppliers

02 Nansa SSA Albright & Wilson Americas04 Empicol LX28 Albright & Wilson Americas

05 Ammonyx LO Stepan06 Surfadone LP-100 ISP07 Fragrance, dye, preservatives Local supplier

Additional Formulation InformationDetergency is provided by a blend of DDBS and SLS surfactants.

Amine oxide acts as a foam stabilizer / booster, and may in addition help to reduce the skinirritation potential of the DDBS.

Surfadone LP-100 improves the wetting performance of the aqueous solution, aids thepenetration and solubilization of greasy soils and in conjunction with the other surfactantsincreases the viscosity of the product, removing the need for electrolyte or thickeners.



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5.11 Liquid Dishwash Detergent (Formula #1)

Formulation


01. Alkyl benzene sulphonic acid (LABSA)02. Caustic soda 50%03. Sodium lauryl ether sulphate 70%04. Coco/diethanol amide

05. Surfadone LP-300 (ISP)06. Sodium Chloride

07. Integra 44 (ISP)08. Dye09. Lemon Fragrance10. Citric acid11. Water

9.802.555.801.001.000.400.15q.s.q.s.

to pH 7.0up to 100

Formulation Instructions1. Add caustic soda to water.2. Add alkyl benzene sulphonic acid, stir until all neutralized.3. Add sodium lauryl ether sulphate, coco-diethanol amide and Surfadone LP-300, and

stir until all ingredients are dissolved.4. Add Integra 44, dye, lemon and citric acid.5. Add sodium chloride.

Suppliers:

01. Alkyl benzene sulphonic acid (LABSA) LG Chemicals, Rhodia03. Sodium lauryl ether sulphate 70% paste Rhodia, Huntsman04. Coco-diethanol amide Huntsman, Henkel05, 07 Surfadone LP-300 and Integra 44 ISPOthers Caustic soda, sodium chloride, dye, fragrance Local supplier



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5.12 Liquid Dishwash Detergent (Formula #2)

Formulation


01. SLES - Sodium lauryl ether sulphate (70%)02. Coconut diethanolamine


05. Integra 44 (ISP)06. Dye07. Fragrance08. Citric acid to pH 7.009. Water

15.01.01.02.5

0.15q.s.q.s.q.s.

up to 100

Formulation Instructions1. Charge the water into the vessel.2. Add SLES, stir with mechanical stirrer until all dissolved.3. Add coconut diethanolamine and Surfadone LP-300, stir until all dissolved.4. Add Integra 44, dye and fragrance, stir all until homogeneous.5. Add Sodium Chloride6. Adjust pH to 6.8~7.0 with citric acid (or caustic soda).

Suppliers:

01 Sodium lauryl ether sulphate (70%) Rhodia02 Coconut diethanolamine Rhodia

03, 05 Surfadone LP-300 and Integra 44 ISP04, 07, 08 NaCl, Citric acid, dye and fragrance Local supplier



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5.15 Ecological Liquid DishwashDetergent

Formulation


01. Sodium lauryl ether sulphate 70%02. Empigen BB (lauryl dimethyl betaine)03. Empilan KB9 (lauryl alcohol eth25oxylate (9EO))04. Empigen OB (lauryl dimethyl amine oxide)


07. Integra 44 (ISP)08. Dye09. Lemon Fragrance10. Citric acid11. Water

16.96.51.03.51.01.0

0.15q.s.q.s.

to pH 7up to 100

Formulation Instructions1. Charge water to the vessel.2. Add SLES stir until all dissolved.3. Add Empigen BB, Empilan KB9 and Empigen OB, stir until all dissolved.4. Add Integra 44, dye and lemon fragrance.5. Add NaCl.6. Adjust pH to 6.8~7.0 with citric acid or NaOH.

Suppliers

01 Sodium lauryl ether sulphate 70% Rhodia, Huntsman02 Empigen BB (lauryl dimethyl betaine) Huntsman, Kao03 Empilan KB9 (lauryl alcohol ethoxylate (9EO)) Huntsman, Rhodia04 Empigen OB (lauryl dimethyl amine oxide) Huntsman, Rhodia05, 07 Integra 44, Surfadone LP-100 ISP06, 09, 10 NaCl, citric acid, dye and lemon Local supplier



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5.20 Automatic Liquid Dishwash Detergent

Formulation


01. Eltesol SX pellets (sodium xylene sulphonate)02. Sodium metasilicate03. Empilan KA590 (C9-11 alcohol ethoxylate (5EO, 90%)

04. Surfadone LP-100 (ISP)05. Potassium hydroxide (pellets)

06. Gantrez AN 169 (ISP)07. EDTA08. Tetrapotassium pyrophosphate09. Isopropyl alcohol


6.54.01.01.03.00.850.1515.03.00.15q.s.q.s.

up to 100

Formulation Instructions1. Dissolve Eltesol SX pellet, sodium metasilicate, KOH, EDTA and tetrapotassium

pyrophosphate in water.2. Add Empilan KA 590, Surfadone LP-100 and Gantrez AN-169.3. Add isopropyl alcohol, and the remaining ingredients, stir until clear.

Suppliers

01 Eltesol SX pellet (Sodium xylene sulphonic pellet) Huntsman03 Empilan KA 590 (C9-11 alcohol ethoxylate (5EO) 90% liquid) Huntsman04, 06, 10 Surfadone LP-100, Gantrez AN 169 and Integra 44 ISPOthers EDTA, KOH, Tetrapotassium Pyrophosphate,

Isopropyl Alcohol, Dye, Fragrance, Sodium Metasilicate Local supplier



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5.30 Dishwash Detergent Tablets

Formulation


Base Powder01. STTP02. Sodium Carbonate03. Sodium Sulfate04. Sodium Metasilicate05. Sodium Sterate06. C13-15 fatty alcohol 9EO

Dishwashing Tab Formula07. Base Powder (see composition above)08. DISINTEX-200 Disintegrating Aid (ISP)

40.032.819.36.40.80.7

98.02.0

Formulation Instructions1. Prepare base powder with ingredients listed above.2. Mix base powder and Disintex-200 disintegrating agent in a V-mixer for 30 minutes.3. Press mixed powder at 11 tons pressure using dry compression to make 20 gr. tablets.

(lab tabs were pressed using a Carver Automated Press at 387 psi and 1 sec. Dwell time)4. Individual tabs were tested by submerging in 3 liters of DI water agitated at 700 rpm until

complete dissolution enabled tab granules to pass through a metal gauze cage.



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5.50 Automatic Dishwash Rinse Aid (Formula #1)

Formulation


01. Deionized water 79.00

02. Synperonic LFRA 30 12.00

03. Synperonic LFRA 260 3.00

04. Surfadone LP-100 (ISP) 2.0005. Sodium Cumene Sulphonate (40%) 4.00

06. Dye, Preservative, etc. q.s.

Formulation Instructions1. Charge the mixer with the deionized water and commence stirring.2. Add the ingredients in the order listed above with stirring, mix until homogeneous.

Note: The level of Sodium Cumene Sulphonate has been selected to give a cloud pointof around 45oC, but this can be altered by changing the level of SCS used.

Suppliers

02. Synperonic LFRA 30 ICI Surfactants Americas03. Synperonic LFRA 260 ICI Surfactants Americas04. Surfadone LP-100 ISP05 Eltesol SC40 Albright & Wilson Americas

Formulation InformationThe two Synperonic LFRA surfactants (Fatty Alcohol EO/PO adducts of proprietary formula)have been selected to give a blend of wetting and defoaming properties. The blend propertiescan be altered by varying the ratio of wetting (LFRA 30) & defoaming (LFRA 260) ingredients.

Surfadone LP-100 acts in combination with the nonionic blend to greatly reduce the surfacetension of the formulation when dispersed in aqueous solution, and hence improve thepotential of this solution to form a continuous thin film on the surface of the rinsed items. Thisin turn reduces the drying time, and helps to reduce the amount of streaking and smearingseen on the dried articles. Surfadone LP-100 has no effect on the amount of foaming causedby the formulation.

Sodium Cumene Sulphonate acts as a Hydrotrope, to ensure that the cloud point of theformulation is high enough to prevent separation occurring under warm conditions.



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5.51 Automatic Dishwash Rinse-Aid (Formula #2)

Formulation


01. Empilan PF7158 (alcohol-ethoxylate-propoxylate copolymer)

02. Surfadone LP-100 (ISP)03. Citric acid04. Isopropyl alcohol05. Eltesol SX pellet (sodium xylene sulphonate)

06. Integra 44 (ISP)

07. Dye08. Fragrance09. Water

30.02.58.08.01.5

0.15q.s.q.s.

up to 100

Formulation Instructions1. Charge water into the vessel.2. Add Eltesol SX and citric acid, stir until dissolved.3. Add Empilan PF7158 and Surfadone LP-100, stir until dissolved.4. Add isopropyl alcohol.5. Add Integra 44, dye and fragrance.

Suppliers:

01 Empilan PF7158 (alcohol-ethoxylate-propoxylate copolymer) Huntsman, Rhodia05 Eltesol SX pellet (sodium xylene sulphonate pellet) Huntsman, Huls02, 06 Surfadone LP-100, Integra 44 ISPOthers Isopropyl alcohol, citric acid, dye, fragrance Local supplier



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6 Household Cleaning Formulations

6.10 Multi-purpose Hard Surface Cleaner

Formulation


01. LABSA (Linear alkyl benzene sulphonic acid)02. Caustic soda 50%

03. Surfadone LP-100 (ISP)04. M-Pyrol Solvent (ISP)05. Integra

44 (ISP)06. Dye07. Fragrance08. Water

6.01.51.51.00.15q.s.q.s.

up to 100

Formulation Instructions1. Charge water into the vessel.2. Add caustic soda 50%.3. Add LABSA, stir until all dissolved.4. Add Surfadone LP-100, M-Pyrol, Integra 44, dye and fragrance.

Suppliers:

01. LABSA (Linear alkyl benzene sulphonic acid) Rhodia, LG Chemical03, 04, 05 Surfadone LP-100, M-Pyrol, Integra 44 ISP02, 06, 07 Caustic soda, dye and fragrance Local supplier



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6.20 Multipurpose Alkaline Degreaser

Formulation


01. Tetrapotassium pyrophosphate

02. Surfadone LP-300 (ISP)03. LABSA (Linear alkyl benzene sulphonic acid)04. Caustic soda 50%05. Eltesol SX pellet

06. M-Pyrol Solvent (ISP)


5.01.01.50.54.52.00.15q.s.q.s.

up to 100

Formulation Instructions1. Charge water into the vessel.2. Add caustic soda, followed by LABSA, stir until all neutralized.3. Add tetrapotassium pyrophosphate, Eltesol SX pellet, stir until dissolved.4. Add Surfadone LP-300, stir until all dissolved.5. Add the remaining components and stir well to homogeneous.

Suppliers:

01 Tetrapotassium pyrophosphate Rhodia03 LABSA (Linear alkyl benzene sulphonic acid) Rhodia, Huntsman05 Eltesol SX pellet (Sodium xylene sulphonate) Huntsman02, 06, 07 Surfadone LP-300, M-Pyrol, Integra 44 ISP08, 04, 09 Dye, Caustic Soda and Fragrance Local supplier



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6.21 Kitchen Disinfectant Cleaner

Formulation


01. Empigen BAC 80 (benzalkonium 80%)

02. Surfadone LP-100 (ISP)03. Tetrapotassium pyrophosphate04. Ethylene diamine tetraacetate, sodium salt (EDTA)05. Dye06. Fragrance07. Water

2.01.53.00.2q.s.q.s.

up to 100

Formulation Instructions1. Charge water into the vessel.2. Add tetrapotassium pyrophosphate and EDTA, stir until all dissolved.3. Add Empigen BAC 80, stir until homogeneous.4. Add Surfadone LP-100, stir until dissolved.5. Add dye and fragrance.

Suppliers

01 Empigen BAC 80 Huntsman02. Surfadone LP-100 ISP03. Tetrapotassium pyrophosphate Rhodia04, 05, 06 EDTA, dye & fragrance Local supplier



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6. Household Cleaning Formulations

6.22 Kitchen Degreaser (Formula #1)

Formulation


01. SLES (Sodium lauryl ether sulphate 70%)

02. Surfadone LP-100 (ISP)03. Surfadone

LP-300 (ISP)04. Propylene glycol methyl ether

05. M-Pyrol Solvent (ISP)

06. EDTA


08. Blue dye09. Fragrance10. Water

1.00.30.13.03.03.00.15q.s.q.s.

up to 100

Formulation Instructions1. Charge water into the vessel.2. Add EDTA, stir until all dissolved.3. Add SLES, stir until all dissolved.4. Add Surfadone LP-100 and 300.5. Add the remaining component and stir until homogeneous.

Suppliers:

01. SLES (Sodium lauryl ether sulpahte 70%) Huntsman, Henkel04. Propylene glycol methyl ether Dow and Lyodell02, 03 Surfadone LP-100, Surfadone LP-300 ISP06, 07 M-Pyrol and Integra 44 ISPOthers EDTA, dye, fragrance Local supplier



27/52


6.23 Kitchen Degreaser (Formula #2)Formulation


01. Deionized Water 87.6502. Sodium Lauryl Ether Sulphate (27%) 2.50

03. C13Alcohol / 9EO 0.75

04. Propylene Glycol Methyl Ether 3.00

05. M-PyrolSolvent (ISP) 3.00

06. Na3NTA (38%) 3.00

07. Surfadone LP-300 (ISP) 0.1008. Dye, Fragrance, Preservative etc. q.s.

Formulation Instructions1. Introduce the water and commence stirring.2. Add the SLES with stirring.3. Add the alcohol ethoxylate. Stir until homogenous.4. Add the remaining ingredients with stirring.

Suppliers

02 Empimin KSN27 Albright and Wilson Americas03 Synperonic 13/8 ICI Surfactants Americas04 Dowanol PM Dow05, 07 M-Pyrol, Surfadone LP-300 ISP

08 Na3NTA, dye, fragrance, preservative Local Supplier

Additional Formulation InformationThe two surfactants provide a range of detergency properties - wetting, foaming etc. The nonionicis particularly effective on oils and greases, providing soil removal and emulsification propertiesand helping to prevent redeposition.

Surfadone LP-300 acts in conjunction with the surfactants, improving the wetting properties, andaiding the penetration of the surfactants into the soils. The solvents increase the cleaning effect byhelping to dissolve hydrophobic soils. The glycol ethers offer anti-redeposition properties.

The complexing agent (NTA) improves the tolerance of the formulation (particularly the anionicsurfactant) to the presence of water hardness ions. In addition, it improves the cleaning effect,notably on particulate soils.



28/52


6.24 Kitchen Degreaser (Formula #3)Formulation


01. Deionized Water 87.6502. Sodium Lauryl Ether Sulphate (27%) 2.50

03. C13Alcohol / 9EO 0.75


05. M-Pyrol Solvent (ISP) 3.0006. Na4EDTA (38%) 3.00

07. Surfadone LP-300 (ISP) 0.1008. Dye, Fragrance, Preservative etc. q.s.

Formulation Instructions1. Introduce the water and commence stirring.2. Add the SLES with stirring.3. Add the alcohol ethoxylate. Stir until homogenous.4. Add the remaining ingredients with stirring.

Suppliers

02 Empimin KSN27 Albright & Wilson Americas03 Synperonic 13/8 ICI Surfactants Americas04 Dowanol PM Dow

05, 07 M-Pyrol, Surfadone LP-300 ISP06, 08 Na4EDTA, Dye, Fragrance, Preservative Local Supplier

Additional Formulation InformationThe two surfactants provide a range of detergency properties - wetting, foaming etc. Thenonionic is particularly effective on oils and greases, providing soil removal and emulsificationproperties and helping to prevent redeposition.

Surfadone LP-300 acts in conjunction with the surfactants, improving the wetting properties,and aiding surfactant penetration into the soils. The solvents increase the cleaning effect byhelping to dissolve hydrophobic soils. The glycol ethers offer anti-redeposition properties.

The complexing agent (EDTA) improves the tolerance of the formulation (particularly theanionic surfactant) to the presence of water hardness ions. In addition, it improves thecleaning effect, notably on particulate soils.



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6.25 Oven Cleaner

Formulation


01. Deionized Water 72.3002. M-Pyrol Solvent (ISP) 20.0003. Gantrez S97-BF (ISP) 0.5004. C9-11Alcohol / 8EO (Synperonic 918) 2.00

05. Surfadone LP-300 (ISP) 0.2006. Monoethanolamine 5.00

Formulation Instructions1. Charge the mixing vessel with the water, and commence stirring.2. Premix Gantrez S97-BF in some M-Pyrol to form slurry, and add to mixer.3. Use the remaining M-Pyrol to rinse the premix vessel into the mixer, to ensure that all the

Gantrez S97-BF is added.4. Add the Alcohol Ethoxylate and Surfadone LP-300 with stirring.5. Finally add Monoethanolamine. The neutralization of the acidic functionalities causes the

polymer to swell, resulting in a clear, viscous solution.6. Continue stirring to ensure the polymer becomes fully hydrated.

Suppliers

04 Synperonic 918 ICI Surfactants Americas02, 03, 05 M-Pyrol, Gantrez S97-BF, Surfadone LP-100 ISP06 Monoethanolamine Local Supplier

Additional Formulation InformationSurface activity is provided by the combination of the nonionic surfactant and the SurfadoneLP-300, giving the formulation the ability to wet greasy surfaces. Surfadone LP-300 has alsothe ability to penetrate into oily and greasy soils, thus helping to dislodge them from thesurfaces.

Once in solution, the M-Pyrol, Surfadone LP-300 and the nonionic surfactant in combinationwith the alkalinity from the MEA act to solubilize and emulsify the soils to leave a cleansurface.

Gantrez S97-BF is present to add viscosity to the formulation, helping it to cling to thesurfaces being cleaned and hence maximize the contact time.



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6.26 Kitchen Cleaning Wipes

Formulation


01. Deionized Water02. Isopropyl Alcohol (IPA)03. M-Pyrol Solvent (ISP)04. Surfadone LP-100 (ISP)05. Sodium Cocoyl Glutamate06. Sodium Hydroxide (10% aqueous solution)07. Integra 44 (ISP)08. Fragrance

91.652.002.001.501.501.180.150.02


1. Add the ingredients in the order listed, stirring thoroughly after each addition.2. Apply to wipe substrate in a 1:1 weight ratio.

Suppliers

03, 04, 07 M-Pyrol, Surfadone LP-100, Integra-44 ISPOthers IPA, Sodium Cocoyl Glutamate, NaOH, fragrance Local Supplier



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6.30 Glass Cleaner (Formula #1)

Formulation


01. Surfadone LP-100 (ISP)02. Dipropylene glycol methyl ether03. Isopropyl alcohol

04. Integra 44 (ISP)05. Dye06. Water

0.151.09.0

0.15q.s.

up to 100

Formulation Instructions1. Mix all components and stir mixture until homogeneous.

Suppliers:

02. Dipropylene glycol methyl ether Lyondell, Dow01, 04 Surfadone LP-100 and Integra 44 ISP03, 05. Isopropyl alcohol (IPA) and Dye Local supplier



32/52


6.31 Glass Cleaner(Formula #2)Formulation


01. Deionized Water 90.7902. Isopropanol alcohol (IPA) 5.00


04. Magnesium Lauryl Ether Sulphate (27%) 0.02

05. Monoethanolamine 0.15

06. Ammonia (28%) 0.15

07. Surfadone LP-300 (ISP) 0.0108. Fragrance, Dye, Preservative, etc. q.s.

Formulation Instructions1. Charge the mixing vessel with the water, and commence stirring.2. Add the remaining ingredients with stirring in the order given above.

Suppliers

03. Dowanol PM Dow04. Empicol EGC Albright & Wilson Americas07. Surfadone LP-300 ISPOthers IPA, PG/ME, MLES, Monoethanolamine, etc Local Supplier

Additional Formulation InformationIsopropyl alcohol and glycol ether give the volatility necessary for fast drying.

MgLES aids wetting of the surface. Tests show that the magnesium salts are more efficient thanthe corresponding sodium salts in reducing the amount of streaking or smearing. Nitrogenousbuffers (in this case MEA) also help in this regard. Ammonia as a co-buffer aids removal ofgreasy soils, and is also easily volatilized, promoting streak-free appearance.

Surfadone LP-300 acts as a co-solvent for removing greasy soils, and in addition promoting thesolubility of fragrances where necessary. The tremendous wetting power of Surfadone LP-300 inconjunction with the anionic enables excellent coverage of the surface to be achieved whilst using

very low levels of non-volatile components - reducing the amount of smearing and streaking.



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6.32 Glass Cleaning Wipes

Formulation


01. Deionized Water02. Isopropyl Alcohol (IPA)03. Dipropylene Glycol Methyl Ether04. Integra 44 (ISP)05. Surfadone LP-100

89.709.001.000.150.15


1. Add the ingredients in the order listed, stirring thoroughly after each addition.2. Spray onto wipes and package in air-tight containers.

Suppliers

04, 05 Integra 44, Surfadone LP-100 ISPOthers IPA, Dipropylene Glycol Methyl Ether Local Supplier



34/52

Household Cleaning Formulations6.40 Bathroom Cleaner (Formula #1)

Formulation


01. Deionized Water02 Lauryl Dimethyl Amine oxide (30%)03 Glycolic Acid (65%)04 Acetic Acid (Glacial)05 Alkyl Dimethyl Benzyl Ammonium Chloride (50%)

06 Surfadone LP-100 (ISP)07 Fragrance, Dye, Preservative etc.

89.602.003.001.501.402.50q.s.

Formulation Instructions1. Charge the mixing vessel with the water and commence stirring.2. Add the remaining ingredients with stirring in the order given above.

Suppliers

02. Ammonyx LO Stepan05. Empigen BAC Albright & Wilson Americas06. Surfadone LP-100 ISPOthers Glycolic Acid, Acetic Acid, etc. Local Supplier

Additional Formulation InformationThe acidic nature of the formulation aids in the break-down and dissolution of hardness salt

based soils, such as limescale and soap scum.

Detergency and surface activity are provided by the combination of the amine oxide andSufadone LP-100. The amine oxide also acts as a coupler for the formulation - it has beenfound that if the amount of coupler used is increased to more than is actually necessary tosolubilize the other ingredients, a remarkable increase in the cleaning ability of the formulationis observed.

It has also been observed that the Surfadone LP100 has the ability to reduce soap scumdeposition on surfaces.

The quaternary ammonium chloride is present to give the formulation a bactericidal effect.



35/52


6.41 Bathroom Cleaner (Formula #2)

Formulation


01. Deionized Water02. Sodium Lauryl Sulphate (29%)03. C9-11Alcohol / 8EO04. Phosphoric Acid (85%)

05. Surfadone LP-100 (ISP)06. Citric Acid Monohydrate07. Glycolic Acid (65%)08. Magnesium Sulphate Heptahydrate09. Fragrance10. Dye, Preservative etc.

to 10013.003.000.100.0251.503.501.50

0 - 1.0q.s.

Formulation Instructions1. Charge the mixing vessel with the water and commence stirring.2. Add the anionic and nonionic surfactants, and stir until completely dispersed.3. Add the remaining ingredients, except the Fragrance, with stirring.4. Adjust the pH to 3.0 (Use NaOH if required)5. Stir in the Fragrance to form a clear microemulsion.

Suppliers

02. Empicol LX28 Albright & Wilson Americas03. Synperonic 918 ICI Surfactants Americas05. Surfadone LP-100 ISP

Others All other ingredients Local Supplier

Additional Formulation InformationDetergency is provided by the blend of nonionic and anionic surfactants. The acidic nature of theformulation aids in the break down and dissolution of hardness salt based soils, such as limescale andsoap scum.

The combination of phosphoric acid, carboxylic acid and Surfadone LP100 protects certain surfacesfrom acid etching. It is suggested that a complex forms, which can attach to negatively chargedsurfaces and hence reduce acid attack. Surfadone LP100 addition reduces the soap scum depositionon surfaces.

The inclusion of magnesium ions and the fragrance are necessary to enable a microemulsionto form. The levels of the two can be varied - in addition the type of fragrance used will also affect theamount required for the microemulsion to form. It has also been suggested that the inclusion of a smallamount of magnesium ions improves the cleaning efficiency of the product, particularly in soft waterareas.



36/52


6.42 Toilet Bowl Cleaner

Formulation

Weight %Ingredients

Formula A Formula B

01. Deionized Water 71.0 74.402. Mulgofen ON-870 (Rhodia) 1.0 0.6

03. Gantrez AN-169 (ISP) 3.0 2.004. Hydrochloric Acid (37%) 25.0 23.0

Viscosity (cps) 1200 130

Formulation Instructions1. Charge water to a clean, dry vessel.

2. Add Mulgofen ON-870 to the water and mix until homogenous.3. Add Gantrez AN-169 slowly to the water/surfactant mix and heat to 70-80C.

Stir until a thick gel results. (Note: Make up any water loss and cool to 40C.)4. Add the hydrochloric acid and mix well until homogenous.

Suppliers

02. Mulfogen ON-870 Rhodia03. Gantrez AN-169 ISP04. Hydrochloric Acid Local Supplier

Additional Formulation InformationThe acidic nature of the formulation aids in the breakdown of hardness salt based soils, suchas limescale and soap scum.

The Gantrez AN:ethoxylated surfactant partial ester imparts thickening emulsion and freeze-thaw stability and surface activity to aid in the cleaning ability of the formulation. The estercomplex of Gantrez AN will not form if the order of addition is reversed.



37/52


6.50 Floor Cleaner

Formulation

Ingredients Weight (%)

Part A01. Unisan SS505302. Water

Part B

03. Antara 430 (Polectron) (ISP)

04. WaterPart C

05. Sodium tripolyphosphate06. Nonylphenol ethoxylate 9EO

07. Integra 44 (ISP)08. Dye

09. Fragrance

5.1081.80

0.109.55

1.002.300.15q.s.q.s.

Formulation Instructions1. Part A: Dissolve Unisan SS5053 in water.2. Part B: Disperse Antara 430 in water.3. Part C: Mix Parts A, B and C well.

Suppliers

01. Unisan SS5053 (Sodium alkylbenzene sulphonate 50% paste) Huntsman, Rhodia03, 07 Antara 430 (Polectron), Integra-44 ISP

05. Sodium tripolyphosphate Rhodia06. Nonylphenol ethoxylate 9EO Huntsman, Rhodia08, 09 Dye and fragrance Local supplier



38/52


6.51 Floor Polish (2 Formulations)

Formulation

Weight %Ingredients

Formula A Formula B

01. Surfactant FC-120

02. Surfadone LP-300 (ISP)03. Wacker SRE04. Ethylene glycol methyl ether05. Dipropylene glycol methyl ether

06. 2-Pyrol Solvent (ISP)07. M-Pyrol

Solvent (ISP)08. Dibutyl phthalate09. Tributoxy ethyl phosphate


11. Primal B-92412. Primal E-153113. Michem ME 3923514. Water

0.040.030.101.003.341.20

-1.131.130.15

37.315.927.59

up to 100

0.040.030.101.003.34

-1.201.131.130.15

37.315.927.59

up to 100

Formulation Instructions1. Mix chemicals in the following order: Water, Surfactant FC-120, Surfadone LP-300,

Wacker SRE, Ethylene glycol methyl ether, Dipropyl glycol methyl ether, 2-Pyrol orM-Pyrol, Dibutyl phthalate, Tributoxy ethyl phosphate and Integra 44. Agitate for afew minutes.

2. Slowly add Primal B-924 with constant stirring and continue to stir for 30 minutes.3. Slowly add Primal E-1531 with constant stirring and continue to stir for 10 minutes.4. Slowly add Michem ME 39235 with constant stirring and continue to stir for 1 hour.5. Allow standing for a day before use.

Suppliers

01. Surfactant FC-120 3M, Ciba02,06,07,10 Surfadone LP-300, 2-Pyro, M-Pyrol, Integra-44 ISP03. Wacker SRE (defoamer) Wacker, Dow Corning04. Ethylene glycol methyl ether Dow (Union Carbide)05. Dipropylene glycol methyl ether Dow (Union Carbide)08. Dibutyl phthalate Eastman09. Tributoxy ethyl phosphate Rhodia, FMC11. Primal B-924 (acrylic binder) Rohm & Haas12. Primal E-1531 (alkali soluble resin) Rohm & Haas13. Michem ME 39235 (wax emulsion) Michelman

The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or impliedas to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation topractice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.


39/52


6.52 Carpet Cleaner

Formulation


01. Sodium lauryl sulphate02. Coco/diethanol amide

03. Surfadone LP-100 (ISP)04. Isopropyl alcohol


10.002.001.0010.000.15q.s.q.s.

up to 100

Formulation Instructions1. Dissolve sodium lauryl sulphate in water.2. Add coco/diethanolamide, isopropyl alcohol and Surfadone LP-100.3. Add Integra 44, dye and fragrance, mix until homogenous.

Suppliers

01. Sodium lauryl sulphate Huntsman, Henkel02. Coco-diethanol amide Huntsman, Henkel03, 05 Surfadone LP-100 and Integra 44 ISP04, 06, 07 Isopropyl alcohol, dye and fragrance Local supplier



40/52


6.53 Machine Carpet Cleaner

Formulation


01. Eltesol SX 40 (sodium xylene sulphonate 40%)

02. Surfadone LP-100 (ISP)03. Tetrapotassium Pyrophosphate04. Butyl Carbitol05. EDTA 38%

06. Integra 44 (ISP)07. Dye08. Fragrance09. Phosphoric acid (85%)10. Water

6.501.007.508.000.500.15q.s.q.s.

to pH 7up to 100

Formulation Instructions1. Dissolve all solids in water.2. Then add the remaining ingredients and mix until homogenous.

Suppliers

01. Eltesol SX 40 (sodium xylene sulphonate 40%) Huntsman02, 06 Surfadone LP-100 and Integra 44 ISP04. Butyl Carbitol Dow, HuntsmanOthers Tetrapotassium pyrophosphate, phosphoric acid

EDTA, dye and fragrance Local supplier



41/52


6.55 Silicone Furniture Polish

Formulation


01. KELGIN HV (ISP)02. Mineral Spirits03. Carnauba Wax04. Cardis 319 Wax05. Paraffin Wax06. SF96-300 Silicone Fluid07. Span 6008. Tween 6009. Dowcide A (preservative)10. Water

0.3020.001.001.502.504.001.501.500.10

up to 100

Formulation Instructions1. Dissolve KELGIN HV in cold water with gradual addition and good agitation.2. Take the KELGIN HV solution and add Dowcide A and Tween 60.3. Heat a mixture of all other ingredients to 170 F.4. Heat the Kelgin solution (Step 1) to 170 F.5. Mix hot solutions from Steps 3 and Step 4 until homogeneous.

Suppliers

01. Kelgin HV (Sodium Alginate thickener) ISP04. Cardis 319 Wax Warwick Wax Company06. SF96-300 Silicone Fluid General Electric

07, 08 Span 60, Tween 60 (emulsifying agents) Atlas Powder Company09. Dowcide A (preservative) Dow Chemical02, 03, 05 Mineral Spirits, Carnauba Wax & Paraffin Wax Local supplier

Additional Formulation Information

Kelgin HV is a refined industrial grade of sodium alginate, which is a valuable ingredient to alltypes of liquid polishes. This excellent thickening, stabilizing and suspending agent, providesthe following important properties:

Ease of Solution in either hot or cold water, without any prolonged period of hydration;

Uniformity to assure superior and dependable thickening performance; Improved Stability for most finished polish formulations;



42/52

6 Household Cleaners

6.60 Windscreen Cleaner

Formulation


01. Dipropylene glycol methyl ether

02. M-Pyrol Solvent (ISP)03. Surfadone LP-100 (ISP)04. Isopropyl alcohol05. Silwet 7608 (Silicone surfactant)

06. Integra 44 (ISP)07. Dye08. Water

6.010.0

110.00.20.15q.s.

up to 100

Formulation Instructions1. Mix all components, stir until homogeneous.

Suppliers

01. Dipropylene glycol methyl ether Dow, Lyondell05. Silwet 7608 (silicone surfactant) Crompton03, 02, 06 Surfadone LP-100, M-Pyrol, Integra 44 ISP04, 07 Isopropyl alcohol, dye Local supplier



43/52


6.70 Air Freshener (Formula #1)

Formulation


01. Isopropyl alcohol

02. Surfadone LP-300 (ISP)03. Lemon fragrance04. Dye (Green)


06. Water

5.000.102.00q.s.0.15

up to 100

Formulation Instructions1. Add isopropyl alcohol, and Surfadone LP-300 to the lemon fragrance.2. Add water, followed by dye and Integra 44.

Suppliers

02, 05 Surfadone LP-300 and Integra 44 ISP01, 03, 04 Isopropyl Alcohol, lemon fragrance and dye Local supplier



44/52


6.71 Air Freshener (Formula #2 -Poppy Fragrance)

Formulation


Phase A01. Water02. Preservative03. Sodium Hexametaphosphate (Calgon)

Phase B04. Glycerine05. Manugel GHB (ISP)

Phase C06. Poppy Fragrance (Independent Fragrance Company)07. Polysorbate 80

Phase D08. Water09. Calcium Sulphate Dihydrate (Terra Alba)10. Sodium Hexametaphosphate (Calgon)

69.250q.s.

0.060

5.0002.000

20.0001.000

1.7000.3400.150

Formulation Instructions1. Phase A: Dissolve Phase A Calgon in water and add then add preservative.2. Phase B: Slurry Manugel GHB alginate in glycerine and add to Phase A with mixing.

Mix for 10-15 minutes until alginate thickener is fully hydrated.3. Phase C: Mix the poppy fragrance and the Polysorbate 80 solubilizer.

Add Phase C to Phase AB with high speed mixing until homogenized.4. Phase D: Dissolve the Phase D Calgon in the water and then slurry the Terra Alba.

5. Inject Phase D into Phase ABC and mix with high shear for 10 seconds.6. Place into suitable containers and leave to set for at least four hours.

Suppliers

03. Sodium Hexametaphosphate (Calgon) Calgon Corporation05. Manugel GHB (Alginate) ISP06. Poppy Fragrance Independent Fragrance CompanyOthers All other ingredients Local Supplier



45/52

7 Industrial & Institutional Cleaners

7.10 Car Wash Shampoo

Formulation

Weight %Ingredients

Non-Wax Wax

01. Triethanolamine salt of alkyl benzene sulphonic acid (TS-6053)

02. Surfadone LP-300 (ISP)03. Coco/diethanol amide04. Integra 44 (ISP)

05. M-PyrolSolvent (ISP)06. Dye07. Fragrance08. Water

30.002.002.000.15

-q.s.q.s.

up to 100

30.002.002.000.15

2q.s.q.s.

up to 100

Formulation Instructions1. Dissolve TS 6053, Coco-diethanol amide and Surfadone LP-300 in water.2. Add the M-Pyrol solvent.3. Add Integra 44, dye and fragrance.

Suppliers

01. Triethanolamine salt of alkyl benzene sulphonic acid Huntsman, Stepan03. Coco-diethanol amide Huntsman, Henkel02, 04, 05 Surfadone LP-300, Integra 44 and M-Pyrol ISP06, 07 Dye and fragrance Local supplier



46/52


7.11 Car Wash & Wax Cleaner

Formulation

Weight %Ingredients

Non-Wax Wax

01. Triethanolamine salt of alkyl benzene sulphonic acid (TS 6053)

02. Surfadone LP-300 (ISP)03. Coco/diethanol amide

04. Integra 44 (ISP)05. Carnauba wax

06. M-PyrolSolvent (ISP)07. Dye08. Fragrance09. Water

30.00

2.002.000.151.00

-q.s.q.s.

up to 100

30.00

1.001.000.151.00

2q.s.q.s.

up to 100

Formulation Instructions1. Dissolve TS 6053, Coco/diethanol amide and Surfadone LP-300 in water.2. Add carnauba wax and M-Pyrol.3. Add Integra 44, dye and fragrance.

Suppliers

01. Triethanolamine salt of alkyl benzene sulphonic acid Huntsman, Stepan03. Coco/diethanol amide Huntsman, Henkel05. Carnauba wax Bronson & Jacob02, 04, 06 Surfadone LP-300, Integra 44 and M-Pyrol ISP07, 08 Dye and fragrance Local supplier



47/52


7.12 High Gloss Tire Wax

Formulation


01. L45 (350 cts)02. L45 (1000 cts)

03. Surfadone LP-300 (ISP)04. Emulsifier

05. Antara 430 (ISP)06. Gantrez AN 169 (ISP)07. Water

25.005.000.506.001.000.80

up to 100

Formulation Instructions1. Add emulsifier and Surfadone LP-300 to L45, mix well2. Add Antara 430, Gantrez AN 169 and water, mix well.

Suppliers

01, 02 Dimethicone 350 cts and 1000 cts (L45) Crompton, Dow Corning04. Emulsifier Mutiara Chemical Trading03, 05, 06 Surfadone LP-300, Antara 430, Gantrez AN 169 ISP



48/52


7.13 Liquid Car Polish

Formulation


01. Light Mineral Oil02. Carnauba Wax03. Glycerine04. Celite 31505. Calgon06. KELGIN HV (ISP)07. Dowcide A (preservative)08. Pluronic L4409. Water

16.001.404.1010.200.200.500.130.67

up to 100

Formulation Instructions1. Dissolve KELGIN HV in cold water by gradual addition and good agitation.2. Take the KELGIN HV solution and add Calgon, Pluronic L44, Dowcide A and Glycerine.3. Add Celite 315 to the liquid mixture and heat up to 140 F.4. In another container, dissolve the carnauba wax in mineral oil.5. Add the hot liquid mixture of Step 3 slowly to the Step 4 solution with good agitation.6. Cool the resulting product, pass through a colloid mid and package.

Suppliers

04. Cellite 315 (diatomaceous earth) Johns-Manville Corp.05. Calgon Calgon Corporation

06. Kelgin HV (Sodium Alginate thickener) ISP07. Dowcide A (preservative) Dow Chemical08. Pluronic L44 (emulsifying agent) BASF01, 02, 03 Light Mineral Oil, Carnauba Wax & Glycerine Local supplier

Additional Formulation InformationVarious simple modifications of the above formula should produce a polish which wouldsatisfy all product requirements. Durability of the polished film may be changed with the typeof abrasive used together with wax constituent variations. The gloss of the polished film maybe enhanced with the addition of silicone oil, variation of the wax constituent, or variations inthe oil content. Finally, drying time may be altered by the addition of mineral spirits.

The percentage of KELGIN HV required should remain relatively constant for mostmodifications of the given formula, but in a few cases it may be necessary to alter the quantityslightly to obtain the desired results. It is suggested that the 0.5% level is tried first and then,if necessary, altered in the direction indicated.



49/52


7.20 Alkaline Grill Cleaner

Formulation


01. Caustic soda 50%

02. Gantrez AN 149 (ISP)03. Mackam OAB04. Water

20.001.001.00

up to 100

Formulation Instructions1. Add caustic soda to water.2. Add Mackam OAB, followed by Gantrez AN 149.

Suppliers

01. Caustic soda (50%) Local supplier02. Gantrez AN 149 ISP03. Mackam OAB (Amine oxide stable in acid) McIntyre, Rhodia



50/52


7.30 Metal Cleaner

Formulation


01. Phosphoric acid 85%

02. M-PyrolSolvent (ISP)03. Water

12.004.00

up to 100

Formulation Instructions1. Add acid to M-Pyrol and water with continuous stirring.2. A slight exothermic reaction will occur.3. Mix all ingredients until you have a homogenous cleaner solution.

Suppliers

01. Phosphoric acid (85%) Rhodia02. M-Pyrol Solvent ISP



51/52

Appendix A: Summary of Chemical Functionalities

Chemical names Functionalities

01 Caustic soda or NaOH pH adjuster

02 Alkyl benzene sulphonates.Alkali earth salts

Dispersant, detergency and foaming

03 Sodium lauryl ether sulphonate Emulsifier, surfactant (shampoo), textile auxilliary

04 Sodium lauryl sulphate Emulsifier, foaming agent, wetting agent05 Methanol Co-solvent

06 Coconut acid diethanolamide Foam booster, stabilizer, emulsifier, thickener

07 NaCl Filler, salting-out reagent

08 Citric acid Buffering agent, pH adjuster

09 Nonylphenol ethoxylate Emulsifier, surfactant, wetting agent, defoaming agent

10 Lauryl alcohol ethoxylate Emulsifier

11 Glycerol or glycerin Humectant, solvent

12 Sodium tripolyphosphate Detergent builder, softening agent

13 Adogen/quaternary ammonium salts Emulsifier, dispersant, softener, antistat

14 Silwet or dimethicone copoly Surfactant, dispersant, emulsifier, leveling agent15 IPA Disinfectant

16 Sodium xylene sulphonate Hydrotrope (heavy duty detergent)

17 Empilan or ethoxylate ether\ester Emulsifier, foamer, wetting agent, dispersant

18 EDTA Chelating agent, metal deactivator, anti-oxidant

19 Phosphoric acid Etchant, acidulant

20 Tetrasodium pyrophosphate Detergent builder, sequesterant

21 Triethanolamine alkylbenzenesulphonate

Pigment dispersant, surfactant, dry cleaningdetergent

22 Carnauba wax Car, floor or shoe polish, paraffin wax modifier

23 Dimethyl lauryl amine oxide Foam booster, stabilizer

24 Sodium metasilicate Detergent builder, stabilizer of peroxide bleach25 Briquest or phosphonic acid Powder detergent, peroxide stabilizer, scale inhibitor

26 Benzalkonium chloride Disinfectant

27 Propylene glycol monomethyl ether Coalescing solvent

28 Hexylene glycol Solvent

29 Dipropylene glycol Solvent

30 Soda Ash or sodium carbonate Neutralizing agent, pH adjuster

31 Tinopal Fluorescent whitening agent

32 Arquat/quaternary ammonium salts Emulsifier, foaming agent, wetting agent, softener

33 Acusol or acrylic acid Thickener, detergent polymer, emulsion stabilizer,suspending agent

34 Mackam or sulfosuccinate Surfactant

35 Ethylene glycol methyl ether Solvent

36 Dibutyl phthalate Plasticizer

37 Tributoxy ethyl phosphate Coalescing solvent, antifoamer

38 Primal Pigment dispersant



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GLOBAL LOCATIONS FOR SALES & CUSTOMER SERVICE

WORLD HEADQUARTERS

INTERNATIONAL SPECIALTY PRODUCTS1361 Alps Road, Wayne, New Jersey 07470, USATel: 973-628-4000

www.ispcorp.com [email protected]

AFRICA

Tel: +49 (0) 2236 9649-237Fax: +49 (0) 2236 [email protected]

AUSTRIATel: +43 (0) 1 360 27-71220Fax: +43 (0) 1 360 [email protected]

BELGIUMTel: +32 (0) 2 626-49 30/34Fax: +32 (0) 2 626-49 [email protected]

BULGARIATel: +359 (0) 2 958-2596Tel/Fax: +359 (0) 2 [email protected]

CZECH REPUBLIC

Tel: +420 (0) 2 72 123-332Fax: +420 (0) 2 72 [email protected]

FRANCETel: +33 (0) 1 49 93 21-58/59Fax: +33 (0) 1 49 93 [email protected]

GERMANYTel: +49 (0) 2236 9649-260/64/66Fax: +49 (0) 2236 [email protected]

HUNGARYTel: +36 (0) 1 385-8288Fax: +36 (0) 1 [email protected]

ITALY

Tel +39 (0) 2 75 419-642Fax: +39 (0) 2 75 [email protected]

NETHERLANDSTel: +31 (0) 20 65 45-361Fax: +31 (0) 20 65 [email protected]

NORDEN(Denmark, Estonia, Iceland,Finland, Norway, Sweden)Tel: +46 (0) 8 519 920-10Fax: +46 (0) 8 519 [email protected]

SWITZERLAND

Tel: +41 (0) 1 439 53-66Fax: +41 (0) 1 439 [email protected]

TURKEY(Also Middle East)Tel: +90 (0) 216 485-0972Fax: +90 (0) 216 [email protected]@ispcorp.com

UKTel: +44 (0) 207 519-5054/55Fax: +44 (0) 207 [email protected]

POLAND

Tel: +48 (0) 22 556 25 20Fax: +48 (0) 22 556 25 [email protected]

RUSSIATel: +7 095 232-0214Fax: +7 095 [email protected]

SPAIN(Also Portugal)Tel: +34 91 375-3026Fax: +34 91 [email protected]

CUSTOMER SERVICE:

Toll Free: 1 (800) 622-4423Fax: 1 973 [email protected]

SAMPLE CENTER:Toll Free: 1 (800) [email protected]

CANADA

Tel: +1 905 607-2392Toll Free: 1 (800) 465-5094Fax: +1 905 [email protected]

WESTERN REGION

SHERMAN OAKS, CALIFORNIAToll Free: 1 (800) 505-8984Fax: +1 [email protected]

EASTERN REGION

WAYNE, NEW JERSEYToll Free: 1 (877) 389-3083Fax: 1 973 [email protected]

CENTRAL REGION

LOMBARD, ILLINOISTel: 1 630 932-4022Toll Free: 1 (800) 323-2272Fax: 1 630 [email protected]

VENEZUELATel: + 58 212 991-4545 + 58 212 992-9703 + 58 212 991-7775Fax: + 58 212 [email protected]

MEXICOTel: + 52 55 5589-0721Fax: + 52 55 [email protected]

COLOMBIATel: + 57 (1) 638-6203Fax: + 57 (1) 616-3030/[email protected]

BRAZILTel: + 55 11 3649-0469Fax: + 55 11 [email protected]

ARGENTINATel: + 54 11 4314-8971/0659/ 3293Fax: + 54 11 [email protected]

TAIWAN

Tel: +8862 2508-0212Fax: +8862 [email protected]

THAILANDTel: +662 267-8103Fax: +662 [email protected]

KOREA

Tel: +822 554-6622/6934Fax: +822 [email protected]

MALAYSIATel: +603 5513-1448/28/98Fax: +603 [email protected]

PHILIPPINESTel: +632 848-7188Fax: +632 [email protected]

SINGAPORETel: +656 223-3778Fax: +656 226-0853

[email protected]

MUMBAI, INDIA

Tel: +9122 2837-0472Tel: +9122 2839-2624Tel: +9122 [email protected]

INDONESIATel: +6221 530-7181/82Fax: +6221 [email protected]

OSAKA, JAPANTel: +816 6838-5544Fax: +816 [email protected]

TOKYO, JAPANTel: +813 5566-8661

Fax: +813 [email protected]

GUANGZHOU, CHINA


SHANGHAI, CHINATel: +8621 6249-3900Fax: +8621 [email protected]

HONG KONGTel: +852 2881-6108Fax: +852 [email protected]

HYDERABAD, INDIATel: +9140 2335-1009Fax: +9140 2335-1009

[email protected]

N.S.W. AUSTRALIA


VICTORIA, AUSTRALIATel: +613 9899-5082Fax: +613 [email protected]

BEIJING, CHINATel: +8610 6515-6265Fax: +8610 [email protected]

CHENGDU, CHINATel: +8628 8557-1040Fax: +8628 8557-2313

[email protected]

INTERNATIONAL SPECIALTY PRODUCTS

USA & CANADA REGIONAL SALES OFFICES

LATIN AMERICA CUSTOMER SERVICE

EUROPE & AFRICA CUSTOMER SERVICE

ASIA PACIFIC CUSTOMER SERVICE

Documents

Formulation Isp