For inspection purposes only. Consent of copyright owner … · APPENDIX 2 - Raw Data, Sampling Equations & Charts Opinions and interpretations expressed herein are outside the scope

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

Environmental Efficiency

A2-1

70 Montrose Avenue, Hillington Park, Glasgow, G52 4LAT: 0800 328 1821 (or + 44 161 432 3286 from overseas)

E: [email protected] Exova Catalyst Ireland Contact: John Healey (07826 916 681)

Mill LaneGlenside Works

Sun Chemical Inks Ltd

Dublin 20Palmerstown

Stack Reference

Industrial Emissions Licence: P0241-01

Stack Emissions Testing Report Commissioned by

Installation Name & Address

Team Leader

Team Leader

TE1 TE2 TE3 TE4MM 10 1061

MCERTS Level 2

Stephen DickReport Approved by

MM 10 1061MCERTS Level 2

Signature of Report Approver

Version 1

23rd March 2017

Job Reference NumberCEK-2474

Dates of the Monitoring Campaign

Report Written byStephen Dick

25th March 2017Report Date

TE1 TE2 TE3 TE4

Version

CAT-RT (Version BQ)CEK-2474 Environmental Efficiency - Sun Chemical - A2-1 Report Q1 2017

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EPA Export 05-06-2017:03:17:03

TITLE PAGE

CONTENTS

Summary of Sampling Deviations

EXECUTIVE SUMMARY

Monitoring Objectives

Monitoring Results

Monitoring Dates & Times

Process Details

Monitoring & Analytical Methods

Sampling Location

Plant Photos / Sample Points

APPENDIX 1 - Monitoring Personnel & List of Equipment

APPENDIX 2 - Raw Data, Sampling Equations & Charts

Opinions and interpretations expressed herein are outside the scope of Exova Catalyst Ireland's ISO 17025 accreditation.

9

3

5

6

8

CONTENTS

4

2

7

This test report shall not be reproduced, except in full, without the written approval of Exova Catalyst Ireland.

The testing performed fully meets the technical requirements in Irish EPA Guidance Note, AG2.

CAT-RT (Version BQ)Page 2 of 18

Sun Chemical Inks LtdPalmerstownA2-1

Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017


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Overall Aim of the Monitoring Campaign

Special Requirements

Target Parameters

Exova Catalyst Ireland were commissioned by Environmental Efficiency to carry out stack emissions testing for Sun Chemical Inks Ltd on the A2-1 at Palmerstown.

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the Site's Permit.

There were no special requirements.

Total VOCs (as Carbon)

MONITORING OBJECTIVES

Executive Summary(Page 1 of 7)

Sun Chemical Inks Ltd, PalmerstownA2-1

23rd March 2017





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EPA Export 05-06-2017:03:17:03

where MU = Measurement Uncertainty associated with the Result

Parameter

Total VOCs (as Carbon) ¹ - -Stack Gas TemperatureStack Gas Velocity

¹

- -NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM THE PRELIMINARY VELOCITY TRAVERSE.

¹ Reference Conditions (REF) are: 273K, 101.3kPa, without correction for water vapour content.1 ELV for Total VOCs (as Carbon) applies at mass flows > 500 g/hr.

10400-

Sun Chemical Inks Ltd, Palmerstown

23rd March 2017

+/-Units Result

Concentration

MULimit 1

+/-

m³/hr 4676m³/hr 230

Executive Summary

Mass Emission

MONITORING RESULTS

A2-1

UnitsResult LimitMU

67.51.58

0.208.17m/s9.38

4444

°C

(Page 2 of 7)

15.2

Volumetric Flow Rate (ACTUAL)

-mg/m³ 7.86150 g/hr

242Volumetric Flow Rate (REF)





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EPA Export 05-06-2017:03:17:03

Parameter

R1 -R2 -R3 -R1

All results are expressed at the respective reference conditions.1 ELV for Total VOCs (as Carbon) applies at mass flows > 500 g/hr.

Result Limit 1

16.10 15015.59 15013.88 150

Date(s)Mass Emission

10:45 - 10:50

MONITORING DATE(S) & TIMES

mins

A2-123rd March 2017

Executive Summary

Sampling

(Page 3 of 7)

Units


Times

mg/m³ 23/03/2017

Velocity & Volumetric Flow Rate 23/03/2017

Units DurationConcentration Sampling

g/hrg/hr 12:05 - 12:34mg/m³

11:05 - 11:34Total VOCs (as Carbon)

303030

11:35 - 12:0471.5

23/03/201723/03/2017

61.769.3

g/hrmg/m³







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Standard Operating Conditions

Value


Feedstock (if applicable)

Capacity (of 100%) and Tonnes / HourContinuous or Batch Process

N/A

Process Status

A2-123rd March 2017

Abatement SystemAbatement System Running Status

Plume Appearance

None

Parameter

(Page 4 of 7)Executive Summary

PROCESS DETAILS

None Visible

Extraction from Process

N/A

Batch Process

Liquid Inks Production

N/A

Fuel





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YesEN 12619:2013 YesCAT-TP-20Yes CAT

CAT 0.32 mg/m³Total VOCs (as Carbon)Yes 1.2 m/s

(with short name reference as appears in the table above)

Flame Ionisation Detection by Sick 3006 FIDVelocity & Vol. Flow Rate

ANALYSIS LABORATORIES

MCERTS17025

Testing

Executive Summary

Procedure TestingLabISO

Lab

(Page 5 of 7)

Testing ISOStandard

Monitoring

ParameterProcedure

AnalyticalTechnical


Analysis

Analysis17025

Analysis

LOD(Average)

AnalyticalTechnique

A2-1

Deviation

MONITORING & ANALYTICAL METHODS

23rd March 2017

EN 16911-1 (MID) CAT-TP-41

SUMMARY OF SAMPLING DEVIATIONS

Parameter Run

All All There are no deviations associated with the sampling employed.

Pitot Tube and Thermocouple





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Duct Characteristics Location of Sampling Platform

Platform Details

Sampling Location / Platform Improvement Recommendations

cm

-

Permanent

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

-

Sufficient working area to manipulate probe and operate the measuring instruments

Type0.45

Parameter

There are no obstructions present which hamper insertion of sampling equipment

Yes

-

Executive Summary(Page 6 of 7)

Units

Vertical

Yes

Platform has chains / self closing gates at top of laddersYes

Safe Access Available

General Platform Information

Permanent / Temporary PlatformInside / Outside

Circular

Value

All platforms should be designed in accordance with the requirements in EPA Guidance Note AG1 and EN 15259.

Value

Platform has vertical base boards (approx. 0.25m high)

Width

YesNo

SUITABILITY OF SAMPLING LOCATION

Outside

No

0-

m²m

Sample Port Size

m

0.16

Orientation of Duct

Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements

Port Depth

Yes

Area

Hole

Easy Access Available

Depth

Value

EN 15259 Homogeneity Test Requirements

Sampling Plane Validation Criteria (from EN 15259)

Where NM = Not Measured as no Isokinetic sampling was performed.

NM

Units --

-

NM

--

NM

-

-

-

--m/s

Maximum Angle of Swirl

-Lowest Gas Velocity

m/s-

7.70-

-

Required

-

Compliant-

Yes-NM NM

No Local Negative Flow

Mean Velocity-

-

-

All platforms should be designed in accordance with the requirements in EPA Guidance Note AG1 and EN 15259.

Pa

-

-

> 5 Pa Yes

0.00

-

Criteria in EN 15259

--

There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.

51.7

Yes

-

Traverse 1

m/s-8.17

< 3 : 1Ratio of Above 1.11°

-

8.550.00

Highest Gas Velocity: 1 Yes

NM0.00

--

-NM0.00

-

Lowest Differential Pressure





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PLANT PHOTOS

(Page 7 of 7)

SAMPLE POINTS

Executive Summary

= combustion gases sample point

Line A

A1





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EPA Export 05-06-2017:03:17:03

APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDICES

APPENDIX CONTENTS





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EPA Export 05-06-2017:03:17:03

Bioaerosols Temperature Logger -Electronic Refrigerator -

StopwatchServomex 4900

-

-

-

Position

CAT 3.94-

-

CAT 21S.28

MCERTS Number

-

-

Gasmet DX4000

Horiba PG-250

MM 10 1061 TE1 TE2 TE3 TE4Team Leader James Jackson MCERTS Level 2 MM 15 1356 TE1 & TE4

Eco Physics CLD 822Mh

-

Miscellaneous Items

ABB AO2020-URAS26

CAT 8.4-

- 1m Heated Line (2)Heated Probe (2)

Equipment Type

Control Box DGM (2)

-

Stephen Dick MCERTS Level 2

Mass Flow Controller (2) CAT 6.12

Equipment I.D.

STACK EMISSIONS MONITORING PERSONNEL

APPENDIX 1

15m Heated Line (1)

CAT 17.4

-

Heated Probe (1)

--

-

--

Mass View (2)

CAT 12.72

-Stack Thermocouple (2)

Mass View (1) -

500g / 1Kg Check Weights CAT 17.4Last Impinger Arm -Callipers

- 20m Heated Line (1)

Tubes Kit Thermocouple -

20m Heated Line (2)

-

Stack Thermocouple (1)

Gasmet Sampling System-

Extractive Sampling

LIST OF EQUIPMENT

MCERTS Accreditation

5m Heated Line (1)

-

-

Umbilical (2) Servomex 5200MP

Bernath 3006 FID

-

-

CAT 14.53

Single Channel Heater Controller

-

JCT JCC P1 Cooler

CAT 13.24

Mass Flow Controller (1)

Stack Thermocouple (3)

Technical Endorsements

Team Leader

S-Pitot (2) -

Equipment Type

Easylogger EN-EL-12 Bit

CAT 20.8

Equipment Type

CAT 4.934Barometer

Digital Manometer (2)

-

S-Pitot (1)

L-Pitot-

Digital Temperature Meter

Heated Probe (3) -CAT 6.11 -

Site Balance

Ankersmid APP100

Equipment I.D.

1m Heated Line (3)

Control Box DGM (1) CAT 3.94

Oven Box (1)

-Laboratory BalanceTape Measure CAT 16.3

-Oven Box (2)

Equipment I.D.Digital Manometer (1)Horiba PG-350E

Instrumental Analysers

CAT 23.22

Umbilical (1)Box Thermocouples (2)Box Thermocouples (1)

CAT 11.4Easylogger EN-EL-12 Bit -

Dual Channel Heater Controller -

1m Heated Line (1)

Name

METHODS & TECHNICAL PROCEDURES USED

Parameter

Total VOCs (as Carbon)EN 16911-1 (MID) CAT-TP-41Velocity & Vol. Flow Rate

Technical ProcedureStandard

CAT-TP-20EN 12619:2013





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EPA Export 05-06-2017:03:17:03

General Stack Details

Stack Gas Composition & Molecular Weights

CO₂ (Estimated)

O₂ (Estimated)

Moisture (H₂O) (Estimated)

NOTE: Moisture has been estimated as no moisture test was performed on the date(s) of testing

Where: p = M / 22.41

pi = r x p

Calculation of Stack Gas Densities

Stack Diameter / Depth, DmStack Width, W

Stack Details (from Traverse)

APPENDIX 2

Stack Area, A

-

Volume

kPakPa

0.84

Value

0.45

99.6

Average Stack Gas Temperature, Ta

-0.030

°C

Average Stack Static Pressure, Pstatic

-

58.2

Molar Conc

m²

PRELIMINARY STACK SURVEY: CALCULATIONS

MassComponent

Units

Pa

Fraction Density

Dry

0.01206

20.80 32.00

Conc

0.16

Average Pitot Tube Calibration Coefficient, Cp

ppm kg/m³

Average Stack Gas Pressure

Conc Conc

MWet

r% v/v

1.50 18.02

kg/m³

9.4

Average Barometric Pressure, Pb

m

0.7914 28.01

1.96350.06

79.14 0.9891377.95

0.0006

p pi

--

0.20800.06

N₂1.4277 0.29696-

0.00118

0.0150

20.49

% v/v

-

0.8037-1.2498

44.01

Calculation of Stack Gas Densities

Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)

P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)

P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)

P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)

Calculation of Stack Gas Volumetric Flowrate, Q

Gas Volumetric Flowrate (from Traverse)

kg/m³

m³/hrGas Volumetric Flowrate (Actual)

Units

1.50

kg/m³

m³/hr

Total Pressure

Average Wet Density (Actual), P ActualW

Determinand

Actual

kg/m³

101.3

Result

1.287

9.499.6

Dry Density (STP), P STD

4444

Result

°C

m³/hr

REF ¹

1.216

Dry Density (Actual), P Actual

m³/hr

Temperature

Units

Gas Volumetric Flowrate (STP, Wet)

MoisturekPa

Gas Volumetric Flowrate (STP, Dry)

Units

1.50

kg/m³ 1.280

Duct gas flow conditions

44444676

1.223

Wet Density (STP), P STW

Gas Volumetric Flowrate REF ¹

%

-0.0

4377





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EPA Export 05-06-2017:03:17:03

Parameter Parameter

Date of Survey Initial Pitot Leak CheckTime of Survey Final Pitot Leak CheckAtmospheric Pressure Orientation of DuctAverage Stack Static Pressure Pitot Tube, Cp

Result of Pitot Stagnation Test Number of Lines AvailableAre Water Droplets Present? Number of Lines UsedDevice Used

1.217

1

23/03/2017

Value

-

Units

0.84

S-Type Pitot with KIMO MP 200 (500Pa)

99.6Pass

Mean

0.11

9.43

9.4

8.38

7.70

Wet Density

Pa

-

-

TraversePoint --° -°C

-30.0

Depth

-

Velocity

Units

APPENDIX 2

Pass

-

-

(1 of 1)

1

Value

∆P --

-30 -

--10:45 - 10:50

Sampling Line A

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)

-

Vertical

Pass

m/sPa

1.216

mSTATIC (Units: Pa)

-

4

-1.216

-

51.72

0.42

Tempkg/m³

8.55

8.170.031

1.2169.40.34

63.7

-56.3 9.3

-

58.2 -

-61.2

-Swirl

No

kPa

-

-

-

- -

1.2168.04

9.4

--

---

-

- -

-

-

-

-

--

-

--

-

- --

-- -

--

-

--

-

-

-

- - -- - -

-

- -

-----

-

- -

-

-

-

-

-

---

---

-

--- -

-

---

--

----





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EPA Export 05-06-2017:03:17:03

u(Tc) 1.441

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)

Standard uncertainty associated with the stack temperature

-Pa

m/s

-

u(φCO₂,d) 0.002

Standard uncertainty associated with the local velocities

u(Cf)

u(cal) 0.353

%

- Static PressureStandard uncertainty associated with the density in the duct

u(φH₂O) 0.077u(φO₂,w) 0.627

APPENDIX 2

1.216

Standard uncertainty associated with the mean velocity

20.488- 0.059

u(φO₂,d) 0.637

u(φCO₂,w) 0.002

Standard uncertainty associated with the mean velocity (95% Confidence), relative

- φCO₂,w- Oxygen, dry- Carbon Dioxide, dry

u(fit) 0.043

Standard Uncertainty associated with the mean local dynamic pressures-

- Resolution- Calibration

u(M) 0.00003

0.128u(v) 0.104

Uc(v)

- Drift- Lack of Fit

- Water Vapour- Oxygen, wet- Carbon Dioxide, wet

-

Standard uncertainty associated with the mean velocity (95% Confidence)

- Overall corrections to dynamic measurementsStandard uncertainty associated with the molar mass of the gas- φO₂,w

u(vi)

Ku(pc) 175.696 Pa

u(patm) 175.692u(pstat) 1.216

u(ρ) 0.00657

Standard Uncertainty on the coefficient of the Pitot Tube

m/sUc,rel(v) 2.50

0.205

Performance characteristics (Uncertainty Components) UnitsValueUncertaintyu(k) 0.005

u(∆pi) Pau(res) 0.00087

0.480

Standard uncertainty associated with the absolute pressure in the duct- Atmospheric Pressure

u(drift) 0.083

- 15236- 123.4

Uc,rel(qV,w) 5.17

%241.9 m³/hr

- u²(qV,w)0.00070

- u²(a)/a²- u²(qV,w)/q²V,w

-

Standard uncertainty associated with the mean velocity (95% Confidence), relative

0.00053-

Uc(qV,w)

%

Uc,rel(v) 2.50

- u(qV,w)Standard uncertainty associated with the volume flow rate (95% Confidence), relative

Standard uncertainty associated with the volume flow rate (95% Confidence)





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EPA Export 05-06-2017:03:17:03

Sample Runs

- - - -

- - - -

- - - -

- - - -

- - - -

General Sampling Information

Parameter Run 2

Value

Heated Head Filter Used

Span Gas Type Propane In Synthetic Air (5 Grade)

7.9 7.7 7.9

Parameter

Yes

1.6 1.6

Heated Line Temperature

CYC 1.0156a

mg/m³

1.6

15.2

CAT-TP-20

180°C

Span Gas Expiry Date

16.1

Filtration Type / Size 0.1µm Glass Fibre

Run 3Run 1

Standard

23/01/2020

Uncertainty

69.3 61.7

15.6

A2-1

TOTAL VOCs (as CARBON): RESULTS SUMMARY

67.5

1.6

APPENDIX 2

Mass Emission

Concentration

g/hr 71.5

Units

Probe Material Titanium

Uncertainty ±mg/m³

Mean

13.9

Span Gas Reference Number


±g/hr 8.0

EN 12619:2013Technical Procedure

FORMAT: Number Used / Number Required

FORMAT: Number Used / Number Required

Reference Conditions

Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.

A1

N/ASpan Gas Set Point (ppm) 80.40

Span Gas Start Pressure (bar) 35Gas Cylinder Concentration (ppm)

Number of Sampling Lines Used

Sample Point I.D.'s

Span Gas Uncertainty (%)

Span Gas Expiry Date

80.4

23/01/2020

Number of Sampling Points Used 1 / 1

Synthetic Air (5 Grade)Zero Gas Type

1 / 1





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EPA Export 05-06-2017:03:17:03

Graphical Trend of Data

APPENDIX 2

TOTAL VOCs (as CARBON): DATA TREND

COVER ME WITH CHART/S

0.0

20.0

40.0

60.0

80.0

100.0

120.0

140.0

11:0

5

11:0

6

11:0

7

11:0

8

11:0

9

11:1

0

11:1

1

11:1

2

11:1

3

11:1

4

11:1

5

11:1

6

11:1

7

11:1

8

11:1

9

11:2

0

11:2

1

11:2

2

11:2

3

11:2

4

11:2

5

11:2

6

11:2

7

11:2

8

11:2

9

11:3

0

11:3

1

11:3

2

11:3

3

11:3

4

Conc

entr

atio

n (m

g/m

³)

Total VOCs At Reference Conditions

- Run 1

100.0

120.0

140.0

Conc

entr

atio

n (m

g/m

³)


- Run 2

0.0

20.0

40.0

60.0

80.0

11:3

5

11:3

6

11:3

7

11:3

8

11:3

9

11:4

0

11:4

1

11:4

2

11:4

3

11:4

4

11:4

5

11:4

6

11:4

7

11:4

8

11:4

9

11:5

0

11:5

1

11:5

2

11:5

3

11:5

4

11:5

5

11:5

6

11:5

7

11:5

8

11:5

9

12:0

0

12:0

1

12:0

2

12:0

3

12:0

4

Conc

entr

atio

n (m

g/m

³)

0.0

20.0

40.0

60.0

80.0

100.0

120.0

140.0

12:0

5

12:0

6

12:0

7

12:0

8

12:0

9

12:1

0

12:1

1

12:1

2

12:1

3

12:1

4

12:1

5

12:1

6

12:1

7

12:1

8

12:1

9

12:2

0

12:2

1

12:2

2

12:2

3

12:2

4

12:2

5

12:2

6

12:2

7

12:2

8

12:2

9

12:3

0

12:3

1

12:3

2

12:3

3

12:3

4

Conc

entr

atio

n (m

g/m

³)


- Run 3





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EPA Export 05-06-2017:03:17:03

Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

- Yes

-

Zero Down Sampling Line (Pre)

-0.80ppm4.02

Units

ppm

Sampling Times -

ppm

11:35 - 12:04

79.00

CAL

1

Run 2

11:05 - 11:34

0.40

80.4 80.4100 100Instrument Range ppm 100

0.40

YesAllowable Zero Drift ± ppm

Run 1

ppm79.00Span Down Sampling Line (Post)

Run 3

APPENDIX 2

23/03/2017

4.02

0.40

4.02

80.4

Span Drift

Zero Down Sampling Line (Post) ppm

ppm 0.00

Span Down Sampling Line (Pre)

Units

-0.40

0.00

Zero Drift Acceptable

Run 2

79.0079.00ppm 79.00

Span Gas Value

Zero Drift

-0.40

4.02-0.80

4.02-

Run 3Units

°C

Test Conditions

Run Ambient Temperature Range 13 - 10.5 13 - 10.5

Yes

Span Drift AcceptableAllowable Span Drift ± ppm

Run 3

0.00

CAL

1

4.02Yes

13 - 10.5

YesYes

Run 1 Run 2

Run 1

TOTAL VOCs (as CARBON): SAMPLING DETAILS & QUALITY ASSURANCE

-0.40

79.00

23/03/2017Sampling Dates

Units Run 1 Run 2

Parameter

12:05 - 12:34

-0.80

23/03/2017

Run 3

Method Deviations

1 2 3

- - -

- - -

- - -

- - -

- - -

Nature of Deviation

(x = deviation applies to the associated run)

°C

Run Number

There are no deviations associated with the sampling employed.

Run Ambient Temperature Range 13 - 10.5 13 - 10.5 13 - 10.5





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Combined interference 0.45

RUN 1 RUN 2 RUN 3 UnitsStandard deviation of repeatability at zero

Range Used [A]

mg/m³Lower of [A] or [B]

2.00 2.00

45 45

15.0 15.0 15.0 mg/m³Cal gas conc. 129.1 129.1

0.45

use rep at span use rep at span use rep at span

Lack of fit 0.01

0.45

mg/m³Cal gas conc. 80.4 80.4 80.4 ppm

0.01

Performance characteristic

Performance characteristics

-1.01 -1.01 % full scaleSpan drift 0.00 0.00

1.60 1.60 % of full scale

45

mg/m³

ppm to mg/m³MCERTS Range [B] 15.0

% range0.50 0.50 0.50 % full scale/10V

Losses in the line (leak) 1.74 1.74 1.74 % of valueUncertainty of calibration gas 2.00 2.00 2.00 % of value

30

0.30 0.30

129.1 mg/m³

% of value/kPa

1.61

2.00

15.0 15.0

Measured concentrationTGN M2 Allowable MULimit value

% full scale

Conversion 1.61 1.61

Dependence on voltage

Standard deviation of repeatability at span level

0.00 0.00 % full scaleDeviation from linearity 0.08 0.08

15.0 %16.34 15.82 14.09 mg/m³ (STP, dry)

100.0

150.0 mg/m³ (REF)15.0 15.0

150.0

RUN 1 RUN 2 RUN 3 UnitsResponse time

Performance characteristics RUN 1 Units

TOTAL VOCs (as CARBON): MEASUREMENT UNCERTAINTY CALCULATIONS

RUN 3

160.6 160.6

Repeatability at zero

APPENDIX 2

RUN 2

1.40

mg/m³

150.0

Repeatability at span level 0.00

-

ppm

0.301.40 1.40 % full scale/10KAmbient temperature dependence

Range Used 100.0 100.0160.6

secondsNumber of readings in measurement

Atmospheric pressure dependence

30

0.00 0.00 0.000.01 mg/m³

0.08 % of valueZero drift -1.01

30

0.00 % full scaleVolume or pressure flow dependence 1.60

k =

mg/m³

N/A

Expanded uncertainty (with O₂) - at 95% Confidence N/A N/A N/A % at ELV

Overall Allowable uncertainty (with O₂) - at 95% Confidence N/AN/A N/A

mg/m³

Expanded uncertainty (with O₂) - at 95% Confidence

Result 16.34 15.82 14.09 mg/m³Combined uncertainty 0.82 0.82

RUN 1 RUN 2

mg/m³

mg/m³Losses in the line (leak) 0.16

0.20

RUN 3 Units

Dependence on voltage 0.06

0.18 0.16

Atmospheric pressure dependence 0.01 0.01 0.01 mg/m³

Lack of fit 0.01 0.01

0.00 mg/m³

N/A N/A % at ELVResult of Compliance with Uncertainty Requirement in M2

Result of Compliance with Uncertainty Requirement in M2 COMPLIANT COMPLIANT

Requirement for SRM is that Uncertainty should be <15% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 15% + the uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.

COMPLIANT -

N/A N/A N/A

-

RUN 2 RUN 3 Units% of Value

RUN 1

0.06 0.06

RUN 1 RUN 2 RUN 3 Units

1.61 1.60 mg/m³

Uncertainty corrected to std conds. (O₂) 1.62 1.61 1.60 mg/m³ (REF)

Expanded uncertainty (no O₂) - at 95% Confidence 9.89 10.19 11.33 % of Value

0.01Drift -0.75 -0.75 -0.75Volume or pressure flow dependence 0.00 0.00

Measurement uncertainty

0.16 0.14 mg/m³Uncertainty of calibration gas 0.19

Expanded uncertainty (no O₂) - at 95% Confidence 1.08 1.07 1.06 % at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence 15.0 15.0 15.0

mg/m³Combined interference (from MCERTS Certificate) 0.04 0.04 0.04

0.20 0.20

0.81 mg/m³

% at ELV

Ambient temperature dependence

Expanded uncertainty 1.96 1.62





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For inspection purposes only. Consent of copyright owner … · APPENDIX 2 - Raw Data, Sampling Equations & Charts Opinions and interpretations expressed herein are outside the scope