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Beloit DPWAttn: Cheryl Simplot2400 Springbrook RoadBeloit, WI 53511
Client:
89834NLS Customer:
Wastewater Project:
213459NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
03/17/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 608 608 364 5722364 2879
Page 1 of 1
COC: 183257 Matrix: WW
COC: 183257 Matrix: WW
COC: 183257 Matrix: TB
Effluent, Comp NLS ID: 771330
Effluent, Grab NLS ID: 771331
Trip Blank NLS ID: 771332
Collected: 02/18/14 00:00 Received: 02/20/14
Collected: 02/19/14 07:36 Received: 02/20/14
Collected: 02/18/14 00:00 Received: 02/20/14
[0.28]NDND370NDNDNDNDyesyessee attachedsee attachedyesyesyessee attachedsee attachedyes
[0.0090][0.0090]191.721see attached
see attached
Result
Result
Result
ug/Lug/Lug/Lmg/Lmg/Lug/Lug/Lug/L
mg/Lmg/Lmg/Lmg/Lmg/L
Units
Units
Units
Antimony, tot. recoverable as Sb by ICP-MSArsenic, tot. recoverable as As by ICP-MSBeryllium, tot. recoverable as Be by ICPHardness, tot. recoverable, (calc/unfilt/icp)Phenols (distillation)Selenium, tot. recoverable as Se by ICP-MSSilver, tot. recoverable as Ag by ICPThallium, tot. recoverable as Tl by ICP-MSMetals digestion - tot. recov.ICPMetals digestion - tot. recov. ICP-MSOrganochlorine Pesticides by EPA 8081/PCBs by EPA 8082Chlorinated Hydrocarbons (water) by EPA 8121Organics Extraction (Water) for Organochlorine Pesticides/PCBsOrganics Extraction (Chlorinated Hydrocarbons)8270 Acid/Base Extraction by 3510CSemi-Volatiles (water) by EPA Method 8270CPAH (water) by EPA Method 8270C - SIMOrganics Extraction PAH (water) EPA 8270C - SIM
Cyanide, amen. to chlorineCyanide, tot. (distilled) as CNNitrogen, NO2 + NO3 as N (unfiltered)Nitrogen, Kjeldahl as N (unfiltered)Nitrogen, tot. as N (unfiltered)VOCs (water) by EPA Method 8260B
VOCs (water) by EPA Method 8260B
Parameter
Parameter
Parameter
11111111
111011
Dilution
Dilution
Dilution
03/04/1403/04/1402/21/1402/21/1403/10/1403/04/1402/21/1403/04/1402/20/1402/25/1403/12/1403/07/1402/21/1402/24/1402/25/1402/27/1402/28/1402/24/14
02/25/1402/25/1402/24/1402/25/1402/25/1402/26/14
02/26/14
Analyzed
Analyzed
Analyzed
0.25*1.0*0.171.0*0.0652.0*0.280.25*
0.00500.00500.250.120.12
0.50*2.0*0.502.0*0.214.0*0.890.50*
0.0150.0150.750.350.35
721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460632021390721026460632021390721026460721026460721026460721026460
721026460721026460721026460721026460721026460721026460
721026460
Lab
Lab
Lab
EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.7, Rev 4.4EPA 200.7, Rev 4.4SW846 9065EPA 200.8, Rev 5.4EPA 200.7, Rev 4.4EPA 200.8, Rev 5.4EPA 200.7MEPA 200.8M, Rev 5.4SW846 8081/8082SW846 8121SW846 3510CSW846 8121SW846 3510CSW846 8270CSW846 8270CEPA 8270C
SM 4500CN-G 20edSM 4500CN-E 20edSM 4500NO3-F 20edEPA 351.2calculationSW846 8260
SW846 8260
Method
Method
Method
LOD = Limit of Detection LOQ = Limit of Quantitation ND = Not Detected (< LOD) 1000 ug/L = 1 mg/LDWB = Dry Weight Basis NA = Not Applicable %DWB = (mg/kg DWB) / 10000MCL = Maximum Contaminant Levels for Drinking Water Samples. Shaded results indicate >MCL.
Values in brackets represent results greater than or equal to the LOD but less than the LOQ and are within a region of "Less-Certain Quantitation". Results greater than or equal to the LOQ are consideredto be in the region of "Certain Quantitation". LOD and/or LOQ tagged with an asterisk(*) are considered Reporting Limits. All LOD/LOQs adjusted to reflect dilution.
Authorized by: R. T. Krueger President________________________________
LOD
LOD
LOD
LOQ
LOQ
LOQ
Reviewed by:
ANALYTICAL RESULTS: Polynuclear Aromatic Hydrocarbons by EPA 8270C SIM Customer: Beloit DPW/Water Resources Division NLS Project: 213459 Project Description: Wastewater Project Title: Template: 8270PAHW Printed: 03/17/2014 17:04
Acenaphthene Acenaphthylene Anthracene Benzo (a) anthracene Benzo (a) pyrene Benzo (b) fluoranthene Benzo (g,h,i) perylene Benzo (k) fluoranthene Chrysene Dibenzo (a,h) anthracene Fluoranthene Fluorene Indeno (1,2,3-cd) pyrene Methyl-1-Naphthalene Methyl-2-Naphthalene Naphthalene Phenanthrene Pyrene Terphenyl-d14 (SURR) Nitrobenzene-d5 (SURR) 2-Fluorobiphenyl (SURR)
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND36%74%72%
111111111111111111
0.0220.0210.0200.0420.0140.0510.0530.0620.0560.0460.0280.0190.0480.0240.0230.0270.0240.028
0.0750.0710.0680.140.0470.170.180.210.190.150.0950.0650.160.0820.0780.0890.0790.095
Sample: 771330 Effluent, Comp Collected: 02/18/14 Analyzed: 02/28/14 - Analytes: 18
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
ANALYTE NAME RESULT LOD LOQ DILUNITS WWB Note
SR S S S
S = This compound is a surrogate used to evaluate the quality control of a method.SR = Surrogate recovery was outside QC limits. Terphenyl-d14 recovered below QC limits.
NOTES APPLICABLE TO THIS ANALYSIS:
Page 1 of 1
ANALYTICAL RESULTS: Semi-Volatile Organic Compounds by EPA 8270C - Water Customer: Beloit DPW/Water Resources Division NLS Project: 213459 Project Description: Wastewater Project Title: Template: 8270WPDES Printed: 03/17/2014 17:04
2-Chlorophenol 2,4-Dichlorophenol 2,6-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 4-Chloro-3-methylphenol 4,6-Dinitro-2-methylphenol 2-Nitrophenol 4-Nitrophenol Pentachlorophenol Phenol 2,3,4,6-Tetrachlorophenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Acenaphthene Acenaphthylene Benzidine Bis(2-chloroethoxy)methane Bis(2-chloroethyl)ether Bis(2-chloroisopropyl)ether Bis(2-ethylhexyl)phthalate 4-Bromophenyl-phenylether Butylbenzylphthalate 2-Chloronaphthalene 4-Chlorophenyl-phenylether 3,3'-Dichlorobenzidine Diethylphthalate Dimethylphthalate Di-n-butylphthalate 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octylphthalate 1,2-Diphenylhydrazine (as Azobenzene) Hexachloroethane Isophorone n-Nitrosodi-n-butylamine n-Nitrosodiethylamine n-nitrosodimethylamine N-Nitrosodiphenylamine n-Nitroso-di-n-propylamine n-Nitrosopyrrolidine Naphthalene Nitrobenzene 1,2,4-Trichlorobenzene 2-Fluorophenol (SURR) Phenol-d5 (SURR) Nitrobenzene-d5 (SURR) 2-Fluorobiphenyl (SURR) 2,4,6-Tribromophenol (SURR) Terphenyl-d14 (SURR)
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND[2.3]NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND37%26%69%72%82%44%
11111111111111111111111111111111111111111111
0.770.520.910.720.921.30.990.560.511.21.41.00.890.720.560.875.00.790.711.00.990.510.890.720.690.850.600.650.690.950.680.770.881.10.650.990.970.711.70.540.530.660.600.73
2.61.83.02.63.14.73.31.81.83.75.23.43.02.41.92.9102.62.43.33.31.73.02.42.22.82.02.22.33.22.32.62.93.82.23.33.32.45.71.81.82.22.02.4
Sample: 771330 Effluent, Comp Collected: 02/18/14 Analyzed: 02/27/14 - Analytes: 44
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
ANALYTE NAME RESULT LOD LOQ DILUNITS Note
CC
S S S S S S
S = This compound is a surrogate used to evaluate the quality control of a method.CC = Continuing calibration verification standard recovery was outside QC limits.
NOTES APPLICABLE TO THIS ANALYSIS:
Page 1 of 2
ANALYTICAL RESULTS: Semi-Volatile Organic Compounds by EPA 8270C - Water Customer: Beloit DPW/Water Resources Division NLS Project: 213459 Project Description: Wastewater Project Title: Template: 8270WPDES Printed: 03/17/2014 17:04 Sample: 771330 Effluent, Comp Collected: 02/18/14 Analyzed: 02/27/14 - Analytes: 44
ANALYTE NAME RESULT LOD LOQ DILUNITS Note
2,4-Dinitrophenol recovery 77%NOTES APPLICABLE TO THIS ANALYSIS:
Page 2 of 2
ANALYTICAL RESULTS: Pesticides by Method 8081 and PCBs by Method 8082 Customer: Beloit DPW/Water Resources Division NLS Project: 213459 Project Description: Wastewater Project Title: Template: OCPCBW Printed: 03/17/2014 17:04
Aldrin Alpha-BHC Beta-BHC Delta-BHC Gamma-BHC Chlordane 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Endrin Aldehyde Heptachlor Heptachlor Epoxide Methoxychlor Toxaphene PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 DBC (SURR)
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND80%
11111111111111111111111111
0.00190.00240.00190.00180.00180.0130.00220.00160.00150.00180.00190.00230.00310.00170.00270.00190.00200.00330.180.0230.0600.0370.0400.0450.0260.034
0.00650.00790.00630.00610.00580.0430.00720.00540.00500.00610.00630.00770.0100.00580.00890.00630.00660.0110.580.0770.200.120.130.150.0860.11
Sample: 771330 Effluent, Comp Collected: 02/18/14 Analyzed: 03/12/14 - Analytes: 26
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
ANALYTE NAME RESULT LOD LOQ DILUNITS Note
CC
S
S = This compound is a surrogate used to evaluate the quality control of a method.CL = The extract was subjected to florisil cleanup before analysis.CC = Continuing calibration verification standard recovery was outside QC limits. 4,4'-DDT recovery 82%
NOTES APPLICABLE TO THIS ANALYSIS:
Page 1 of 1
ANALYTICAL RESULTS: WPDES List by EPA 8260 - Water - (Saturn 2000) Customer: Beloit DPW/Water Resources Division NLS Project: 213459 Project Description: Wastewater Project Title: Template: SATWPDES Printed: 03/17/2014 17:04
Acrolein Acrylonitrile Benzene Bromodichloromethane Bromoform Carbon Tetrachloride Chlorobenzene Dibromochloromethane Chloroethane Chloroform 1,2-Dichlorobenzene 1.3-Dichlorobenzene 1,4-Dichlorobenzene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene 2,3-Dichloro-1-propene Ethylbenzene Bromomethane Chloromethane Methylene chloride 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Vinyl chloride Dibromofluoromethane (SURR) Toluene-d8 (SURR) 1-Bromo-4-Fluorobenzene (SURR)
NDNDNDNDNDNDNDNDND
[0.23]NDND
[0.33]NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND0.89NDNDNDND
107%115%113%
11111111111111111111111111111111111
2.90.630.130.230.200.240.150.181.20.130.290.250.140.130.240.290.100.320.170.160.270.250.140.110.250.260.290.400.300.220.160.150.180.270.17
102.20.470.800.690.840.510.634.20.451.00.880.500.450.861.00.351.10.620.570.960.840.470.370.860.931.01.21.10.770.580.540.600.970.59
Sample: 771331 Effluent, Grab Collected: 02/19/14 Analyzed: 02/26/14 - Analytes: 35
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
ANALYTE NAME RESULT LOD LOQ DILUNITS Note
MD
S S S
S = This compound is a surrogate used to evaluate the quality control of a method.MD = Matrix spike and matrix spike duplicate relative percent difference exceeded QC limits.
NOTES APPLICABLE TO THIS ANALYSIS:
Page 1 of 2
ANALYTICAL RESULTS: WPDES List by EPA 8260 - Water - (Saturn 2000) Customer: Beloit DPW/Water Resources Division NLS Project: 213459 Project Description: Wastewater Project Title: Template: SATWPDES Printed: 03/17/2014 17:04
Acrolein Acrylonitrile Benzene Bromodichloromethane Bromoform Carbon Tetrachloride Chlorobenzene Dibromochloromethane Chloroethane Chloroform 1,2-Dichlorobenzene 1.3-Dichlorobenzene 1,4-Dichlorobenzene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene 2,3-Dichloro-1-propene Ethylbenzene Bromomethane Chloromethane Methylene chloride 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Vinyl chloride Dibromofluoromethane (SURR) Toluene-d8 (SURR) 1-Bromo-4-Fluorobenzene (SURR)
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
113%120%106%
11111111111111111111111111111111111
2.90.630.130.230.200.240.150.181.20.130.290.250.140.130.240.290.100.320.170.160.270.250.140.110.250.260.290.400.300.220.160.150.180.270.17
102.20.470.800.690.840.510.634.20.451.00.880.500.450.861.00.351.10.620.570.960.840.470.370.860.931.01.21.10.770.580.540.600.970.59
Sample: 771332 Trip Blank Collected: 02/18/14 Analyzed: 02/26/14 - Analytes: 35
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
ANALYTE NAME RESULT LOD LOQ DILUNITS Note
S S S
S = This compound is a surrogate used to evaluate the quality control of a method.NOTES APPLICABLE TO THIS ANALYSIS:
Page 2 of 2
ANALYTICAL RESULTS: METHOD - Chlorinated Hydrocarbons by EPA 8121 Customer: Beloit DPW/Water Resources Division NLS Project: 213459 Project Description: Wastewater Project Title: Template: WW8121W Printed: 03/17/2014 17:04
Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Pentachlorobenzene 1,2,4,5-Tetrachlorobenzene 1,4-Dichloronaphthalene (SURR)
NDNDNDNDND
90.9%
11111
0.00100.00200.00200.0100.0020
0.00300.00600.00600.00500.0060
Sample: 771330 Effluent, Comp Collected: 02/18/14 Analyzed: 03/07/14 - Analytes: 5
ug/Lug/Lug/Lug/Lug/L
ANALYTE NAME RESULT LOD LOQ DILUNITS Note
S
S = This compound is a surrogate used to evaluate the quality control of a method.NOTES APPLICABLE TO THIS ANALYSIS:
Page 1 of 1
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