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Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

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Page 1: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 2: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 3: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 4: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 5: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 6: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 7: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 8: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 9: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 10: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 11: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 12: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 13: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 14: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 15: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 16: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 17: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 18: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 19: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

ANNEXURE :20

Page 20: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 21: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

Multi Laboratory, 28 B/1 (SP), 28 B/2 (SP), IInd Main Road, Opposite to State Bank of India, Ambattur Industrial Estate, Chennai - 600 058, Tel: 91-44-66081600 SGS India Pvt. Ltd.

Regd & Corp. Off : SGS House, 4B, A.S. Marg, Vikhroli (West), Mumbai-400083. Tel : (022) 25798421 to 28 Fax : (022) 25798431 to 35 www.sgs.com

Member of the SGS Group (SGS SA)

Test Report

SAMPLE NOT DRAWN BY LABORATORY Print Date :

16/10/2019

Sample / Report No : CG19-017560.001 JOE No : CG19-017560

Report Control No : CGR0001108254 Sample described by customer as : PET COKE

Customer Name : Customer Address :

: City : Postal Code : State : Country :

NIRMA LIMITED SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA

Sample Type : PET COKE Received : 11/10/2019 Sample Qty. Recd. : 2.5GM Item Code : WLABJWUN0188 Test Start : 11/10/2019 Test End Date : 16/10/2019 Group : Solid Fuels : Coke

Test/Parameter

Method Result Unit

DISCIPLINE: CHEMICAL

Cobalt (as Co)

ASTM D 6357 : 2011 0.14 % (w/w)

Nickel (as Ni) ASTM D 6357 : 2011 11.83 % (w/w)

Mercury (as Hg) ASTM D 6357 : 2011 ND (DL :0.5) mg/kg

Per pro SGS India Private Ltd

L_SIVAKUMAR

Authorized Signatory

****End of Report****

Page 1 of 1 This document is issued by the Company under its General Conditions of Service printed overleaf or available on request and accessible at http://www.sgsgroup.in/en-GB/Terms-and-Conditions.aspx for electronic documents www.sgs.com/terms_e-document.htm. Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein. Any holder of this document is advised that information containe hereon reflects the Company’s findings at the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole responsibility is to its Client and this document does not exonerate parties to

Unless otherwise stated the results shown in this test report refer only to the sample(s) tested and such sample(s) are retained for 7 days (in case of perishable items) and 30 days for all other samples. The samples from regulatory bodies are to be retained as specified. This document cannot be reproduced except in full, without prior written approval of the Company.

For any feedback or complaint please write to us at [email protected].

Page 22: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 23: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 24: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 25: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

Multi Laboratory, 28 B/1 (SP), 28 B/2 (SP), IInd Main Road, Opposite to State Bank of India, Ambattur Industrial Estate, Chennai - 600 058, Tel: 91-44-66081600 SGS India Pvt. Ltd.

Regd & Corp. Off : SGS House, 4B, A.S. Marg, Vikhroli (West), Mumbai-400083. Tel : (022) 25798421 to 28 Fax : (022) 25798431 to 35 www.sgs.com

Member of the SGS Group (SGS SA)

Test Report

SAMPLE NOT DRAWN BY SGS INDIA PVT. LTD. Print Date :

20/02/2019

Sample / Report No : CG19-002805.001

Report Control No : CGR0001003737

JOE No : CG19-002805

Sample described by customer as : INDONESIAN COAL

Customer Name : Customer Address :

: Postal Code : State : Country :

NIRMA LIMITED 2147, Modern Bunglow, Near N.C.C Office Krishnanagar, Waghawadi Road 364002 Gujarat INDIA

Sample Type : INDONESIAN COAL Received : 15/02/2019 Sample Qty. Recd. : APPROX. 500G Test Start : 15/02/2019 Test End Date : 20/02/2019

Test/Parameter Method Result Unit

Nickel (as Ni) Cobalt (as Co)

ASTM D 6357 : 2011

ASTM D 6357 : 2011

114.89

48.45

ppm

ppm

Per pro SGS India Private Ltd

L_SIVAKUMAR

Authorized Signatory

****End of Report****

Page 1 of 1 This document is issued by the Company under its General Conditions of Service printed overleaf or available on request and accessible at http://www.sgsgroup.in/en-GB/Terms-and-Conditions.aspx for electronic documents www.sgs.com/terms_e-document.htm. Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein. Any holder of this document is advised that information containe hereon reflects the Company’s findings at the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole responsibility is to its Client and this document does not exonerate parties to

Unless otherwise stated the results shown in this test report refer only to the sample(s) tested and such sample(s) are retained for 7 days (in case of perishable items) and 30 days for all other samples. The samples from regulatory bodies are to be retained as specified. This document cannot be reproduced except in full, without prior written approval of the Company.

For any feedback or complaint please write to us at [email protected].

Page 26: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 27: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

Annexure-21

Page 28: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

Annexure 22

Page 29: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 30: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:
Page 31: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

-------------------------------------------------------------------------------------------------------------------------------------------

Dr KC Pathak 1 of 4 AGM - Quality Assurance (Ph No: 8980026334)

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Sodium Bicarbonate (Baking Soda)

-------------------------------------------------------------------------------------------------------------------------------------------

SECTION 1: NAME & HAZARD SUMMARY

SECTION 2: INGREDIENTS % OSHA PEL

SECTION 3: PHYSICAL DATA

Annexure 23

Page 32: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

-------------------------------------------------------------------------------------------------------------------------------------------

Dr KC Pathak 2 of 4 AGM - Quality Assurance (Ph No: 8980026334)

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

SECTION 4: FIRE AND EXPLOSION HAZARD DATA

SECTION 5: STABILITY AND REACTIVITY DATA

SECTION 6: HEALTH HAZARD ASSESSMENT

Page 33: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

-------------------------------------------------------------------------------------------------------------------------------------------

Dr KC Pathak 3 of 4 AGM - Quality Assurance (Ph No: 8980026334)

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

SECTION 7 SPILL, LEAK AND WASTE DISPOSAL INFORMATION

SECTION 8 SPECIAL PROTECTION INFORMATION

SECTION 9 TOXICOLOGY

Page 34: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

-------------------------------------------------------------------------------------------------------------------------------------------

Dr KC Pathak 4 of 4 AGM - Quality Assurance (Ph No: 8980026334)

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

SECTION 10 REGULATORY INFORMATION

SECTION 11 • OTHER INFORMATION

Page 35: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 1 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

SODIUM CARBONATE ANHYDROUS MSDS Number: S3242

1. Product Identification

Synonyms: Carbonic acid, disodium salt; disodium carbonate; soda ash CAS No.: 497-19-8 Molecular Weight: 105.99 Chemical Formula: Na2CO3 Product Codes: J.T. Baker: 3602, 3604, 3605, 4502, 4923, 5198, 5834 Mallinckrodt: 1338, 7468, 7521, 7527, 7528, 7698

2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous ----------------------------- ------------ ------- --------- Sodium Carbonate 497-19-8 99 - 100% Yes

3. Hazards Identification

Emergency Overview -------------------------- DANGER! MAY CAUSE EYE BURNS. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT.

J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) -----------------------------------------------------------------------------------------------------------

Page 36: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 2 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Orange (General Storage) -----------------------------------------------------------------------------------------------------------

Potential Health Effects ----------------------------------

Inhalation: Inhalation of dust may cause irritation to the respiratory tract. Symptoms from excessive inhalation of dust may include coughing and difficult breathing. Excessive contact is known to cause damage to the nasal septum. Ingestion: Sodium carbonate is only slightly toxic, but large doses may be corrosive to the gastro-intestinal tract where symptoms may include severe abdominal pain, vomiting, diarrhea, collapse and death. Skin Contact: Excessive contact may cause irritation with blistering and redness. Solutions may cause severe irritation or burns. Eye Contact: Contact may be corrosive to eyes and cause conjuctival edema and corneal destruction. Risk of serious injury increases if eyes are kept tightly closed. Other symptoms may appear from absorption of sodium carbonate into the bloodstream via the eyes. Chronic Exposure: Prolonged or repeated skin exposure may cause sensitization. Aggravation of Pre-existing Conditions: No information found.

4. First Aid Measures

Page 37: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 3 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Note to Physician: Consider endoscopy in all suspected cases of sodium carbonate poisoning. Perform blood analysis to determine if dehydration, acidosis, or other electrolyte imbalances occurred.

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard. Explosion: Not considered an explosion hazard, but sodium carbonate may explode when applied to red-hot aluminum. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire.

Annexure No.23

Page 38: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 4 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal.

7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection:

Page 39: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 5 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: White powder or granules. Odor: Odorless. Solubility: 45.5 g/100 ml water @ 100C (212F) Specific Gravity: 2.53 pH: 11.6 Aqueous solution % Volatiles by volume @ 21C (70F): 0

Boiling Point: Decomposes. Melting Point: 851C (1564F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Page 40: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 6 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

Stability: Stable under ordinary conditions of use and storage. Hygroscopic. Readily absorbs moisture from the air. Solutions are strong bases. Hazardous Decomposition Products: Oxides of carbon and sodium oxide. Hazardous Polymerization: Will not occur. Incompatibilities: Fluorine, aluminum, phosphorous pentoxide, sulfuric acid, zinc, lithium, moisture, calcium hydroxide and 2,4,6-trinitrotoluene. Reacts violently with acids to form carbon dioxide. Conditions to Avoid: Moisture, heat, dusting and incompatibles.

11. Toxicological Information

For Sodium Carbonate: Oral rat LD50: 4090 mg/kg; inhalation rat LC50: 2300 mg/m3/2H; irritation eye rabbit: 50 mg severe; investigated as a mutagen, reproductive effector. --------\Cancer Lists\------------------------------------------------------ ---NTP Carcinogen--- Ingredient Known Anticipated IARC Category ------------------------------------ ----- ----------- ------------- Sodium Carbonate (497-19-8) No No None

12. Ecological Information

Environmental Fate: No information found. Environmental Toxicity: No information found.

Page 41: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 7 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

"As per IATA not regulated "

15. Regulatory Information

--------\Chemical Inventory Status - Part 1\--------------------------------- Ingredient TSCA EC Japan Australia ----------------------------------------------- ---- --- ----- --------- Sodium Carbonate (497-19-8) Yes Yes Yes Yes --------\Chemical Inventory Status - Part 2\--------------------------------- --Canada-- Ingredient Korea DSL NDSL Phil. ----------------------------------------------- ----- --- ---- ----- Sodium Carbonate (497-19-8) Yes Yes No Yes --------\Federal, State & International Regulations - Part 1\---------------- -SARA 302- ------SARA 313------ Ingredient RQ TPQ List Chemical Catg. ----------------------------------------- --- ----- ---- -------------- Sodium Carbonate (497-19-8) No No No No --------\Federal, State & International Regulations - Part 2\---------------- -RCRA- -TSCA- Ingredient CERCLA 261.33 8(d) ----------------------------------------- ------ ------ ------

Page 42: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 8 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

Sodium Carbonate (497-19-8) No No No Chemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No Reactivity: No (Pure / Solid)

16. Other Information

Information based on classification according to CLPLabelling according to Directive 67/548/EEC-1999/45/EC (DSD/DPD) Enumerated in substance list Annex I of Directive 67/548/EEC et sequens Labels

Irritant R-phrases 36 Irritating to eyes

S-phrases (02) (Keep out of the reach of children) 22 Do not breathe dust 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical

advice Full text of any R-phrases referred to under headings 2 and 3: R36 Irritating to eyes Full text of any H-statements referred to under headings 2 and 3: H319 Causes serious eye irritation. (*) = INTERNAL CLASSIFICATION BY BIG PBT-substances = persistent, bioaccumulative and toxic substances DSD Dangerous Substance Directive

Page 43: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 9 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

DPD Dangerous Preparation Directive CLP (EU-GHS) Classification, labelling and packaging (Globally Harmonised System in

Europe)

NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0

Label Hazard Warning: DANGER! MAY CAUSE EYE BURNS. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT.

Label Precautions: Do not get in eyes, on skin, or on clothing. Avoid breathing dust. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling.

Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In all cases, get medical attention.

Product Use: Commercial Use.

Page 44: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED -------------------------------------------------------------------------------------------------------------------------------------------

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

Dr KC Pathak 10 of 10 AGM - Quality Assurance (Ph No: 8980026334) Jan-2019

The information in this safety data sheet is based on data and samples provided to BIG. The sheet was written to the best of our ability and according to the state of knowledge at that time. The safety data sheet only constitutes a guideline for the safe handling, use, consumption, storage, transport and disposal of the substances/preparations/mixtures mentioned under point 1. New safety data sheets are written from time to time. Only the most recent versions may be used. Old versions must be destroyed. Unless indicated otherwise word for word on the safety data sheet, the information does not apply to substances/preparations/mixtures in purer form, mixed with other substances or in processes. The safety data sheet offers no quality specification for the substances/preparations/mixtures in question. Compliance with the instructions in this safety data sheet does not release the user from the obligation to take all measures dictated by common sense, regulations and recommendations or which are necessary and/or useful based on the real applicable circumstances. BIG does not guarantee the accuracy or exhaustiveness of the information provided and cannot be held liable for any changes by third parties. This safety data sheet is only to be used within the European Union, Switzerland, Iceland, Norway and Liechtenstein. Any use outside of this area is at your own risk. Use of this safety data sheet is subject to the licence and liability limiting conditions as stated in your BIG licence agreement or when this is failing the general conditions of BIG. All intellectual property rights to this sheet are the property of BIG and its distribution and reproduction are limited. Consult the mentioned agreement/conditions for details.

Page 45: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

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Dr KC Pathak 1 of 7 AGM - Quality Assurance (Ph No: 8980026334) 01-APR-19

CALCIUM CARBONATE (CaCO3)

1. Product Identification Synonyms: Carbonic acid calcium salt; calcite; aragonite; limestone HS No.: 2530.90-9091 CAS No.: 471-34-1 Molecular Weight: 100.09 Chemical Formula: CaCO3

2. Composition/Information on Ingredients

Ingredient CAS No Percent Hazardous

---------------------- ------------ ------------ ---------

Calcium Carbonate 471-34-1 > 90 No

3. Hazards Identification Emergency Overview --------------------------

CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. NUISANCE DUST. SAF-T-DATA(tm) Ratings (Provided here for your convenience) ----------------------------------------------------------------------------------------- Health Rating: 1 - Slight (Life) Flammability Rating: 1 - Slight Reactivity Rating: 1 - Slight Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Green (General Storage)

Page 46: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

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Dr KC Pathak 2 of 7 AGM - Quality Assurance (Ph No: 8980026334) 01-APR-19

Potential Health Effects ----------------------------------

Inhalation: Excessive concentrations of a nuisance dust may cause nuisance condition such as coughing, sneezing, and nasal irritation. Ingestion: Non-toxic. Skin Contact: Not expected to be a health hazard from skin exposure.

Eye Contact: Exposure to airborne dust may cause immediate or delayed irritation or inflammation. Chronic Exposure: Excessive oral doses of calcium carbonate may produce alkalosis and hyperkalemia. Aggravation of Pre-existing Conditions: No information found.

4. First Aid Measures Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: If large amounts were swallowed, give water to drink and get medical advice. Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops. Eye Contact: Wash thoroughly with running water. Get medical advice if irritation develops.

Page 47: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

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Dr KC Pathak 3 of 7 AGM - Quality Assurance (Ph No: 8980026334) 01-APR-19

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal.

7. Handling and Storage

Keep in a Covered Stack in Piles, convey through closed conveyer . observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: - OSHA Permissible Exposure Limit (PEL): 15 mg/m3 total dust, 5 mg/m3 respirable fraction for nuisance dusts. - ACGIH Threshold Limit Value (TLV) for Particulates (insoluble or poorly soluble) Not Otherwise Specified (PNOS): 3 mg/m3 respirable particles and 10 mg/m3 inhalable particles.

Page 48: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

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Dr KC Pathak 4 of 7 AGM - Quality Assurance (Ph No: 8980026334) 01-APR-19

Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest.. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen- deficient atmospheres. Skin Protection: Gloves and lab coat, apron or coveralls. Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick- drench facilities in work area.

9. Physical and Chemical Properties

Appearance: White or Reddish brown Stone / Powder Odor:

Odorless

Solubility: 0.001 gm in 100 ml water, soluble in dilute acids. Density: 2.7 - 2.95 pH: No information found.

Page 49: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

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Dr KC Pathak 5 of 7 AGM - Quality Assurance (Ph No: 8980026334) 01-APR-19

% Volatiles by volume @ 21C (70F): 0 Boiling Point:

Not applicable.

Melting Point:

825C (1517F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: When heated to decomposition (825C), emits calcium oxide fumes and liberates carbon dioxide. Hazardous Polymerization: Will not occur. Incompatibilities: Acids, fluorine, magnesium with hydrogen. Conditions to Avoid: Heat, incompatibles.

11. Toxicological Information No LD50/LC50 information found relating to normal routes of occupational exposure.

---NTP Carcinogen--- Ingredient Known Anticipated IARC Category ----------------------------- ----------- ------------- ------------------

Calcium Carbonate (471-34-1) No No None

Page 50: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

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Dr KC Pathak 6 of 7 AGM - Quality Assurance (Ph No: 8980026334) 01-APR-19

12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found.

13. Disposal Considerations Recovery or recycling of Waste should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information Not regulated.

15. Regulatory Information

--------\Chemical Inventory Status - Part 1\- Ingredient TSCA EC Japan Australia ----------------------------- --- ----- ------- ------------

Calcium Carbonate (471-34-1) Yes Yes Yes Yes

Chemical Inventory Status - Part 2\---Canada-- Ingredient Korea DSL NDSL Phil. ----------------------------- -------- ------ ----- ---------

Calcium Carbonate (471-34-1) Yes Yes No Yes Federal, State & International Regulations - Part 1\-- SARA 302- ------SARA 313------ Ingredient RQ TPQ List Chemical Catg. -------------------------------- ----- ---- -------------- Calcium Carbonate (471-34-1) No No No No

Page 51: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

NIRMA LIMITED

Plant : Chemical Complex, Village-Kalatalav, Tal. Bhavnagar, Dist. Bhavnagar 364313 Ph : 0278-2885301-4 Fax : 0278-288319

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Dr KC Pathak 7 of 7 AGM - Quality Assurance (Ph No: 8980026334) 01-APR-19

Federal, State & International Regulations - Part 2\-----------------RCRA- -TSCA- Ingredient CERCLA 261.33 8(d) ----------------------------------------- ------------------ -------------------------

Calcium Carbonate (471-34-1) No No No Chemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No Reactivity: No (Pure / Solid)

Australian Hazchem Code: None allocated. Poison Schedule: None allocated. WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information NFPA Ratings: Health: 0 Flammability: 0 Reactivity: 0 Label Hazard Warning: CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. NUISANCE DUST. Label Precautions: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing dust. Keep container closed. Use with adequate ventilation. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. If irritation develops call a physician. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. Product Use: As a Raw material in Manufacturing of Soda Ash

Page 52: Final draft EIA report · 2019. 12. 4. · SAURASHTRA CHEMICALS DIVISION OF NIRMA LTD BIRLASAGAR, ODEDAR ROAD PORBANDAR 360576 GUJARAT INDIA Sample Type : PET COKE Received 11/10/2019:

Annexure -24