8/13/2019 Final Deva Graph

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Fig .1

Ce(IV) (mol. dm-3)

Fig.2

[LA]Mol.dm-3

35

y = 6.2086x + 8.6857

R2= 0.0109

y = 0.1209x + 1.0391

R2

= 0.9183

0

2

4

6

8

10

12

14

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07

y = 76.7x + 12.799

R2= 0.9738

y = 0.1209x + 1.0391

R2= 0.9183

0

5

10

15

20

25

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.0810-7(-d[ce(IV)/dtmol.dm

-3s-

1

10-4

[-d[Ce(IV)/dt]mol.d

m-3.

Sec

-

8/13/2019 Final Deva Graph

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Fig.3

[LA]-1

Fig.4

[H2SO4]

37

y = 0.0042x + 0.507

R2= 0.9695

y = 0.1209x + 1.0391

R2= 0.9183

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0 10 20 30 40 50 60

y = 0.0205x + 0.9128

R2= 0.6799

y = 0.1209x + 1.0391

R2= 0.9183

0

0.2

0.4

0.6

0.8

1

1.2

1.4

0 5 10 15 20 25

106

[-d[Ce(IV)/dt]mol.dm

-3.

Sec

-1

10-4 [

-d[Ce(IV)/dt]mol.dm

-3.

Sec-

8/13/2019 Final Deva Graph

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Fig.5

[M] x 10-3

Fig.6

Ce4+

39

y = 1.3023x + 0.7657

R2= 0.8712

y = 0.1209x + 1.0391

R2= 0.9183

0

0.5

1

1.5

2

2.5

0 0.2 0.4 0.6 0.8 1

y = 146.65x + 0.6343

R2= 0.9106

y = 0.1209x + 1.0391

R2= 0.9183

0

0.5

1

1.5

2

2.5

0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009

-d[Ce]/dtx10-3

-d[Ce]/dtx10-3

8/13/2019 Final Deva Graph

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Fig.7

[LA]

Fig.8

[LA]-1

41

y = 16.326x + 2.1524

R2= 0.9443

y = 0.1209x + 1.0391

R2= 0.9183

0

0.5

1

1.5

2

2.5

3

3.5

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07

y = 0.0022x + 0.2926

R2= 0.7978

y = 0.1209x + 1.0391

R2= 0.9183

0

0.05

0.1

0.15

0.2

0.25

0.3

0.35

0.4

0.45

0 10 20 30 40 50 60

-d[Ce]/dtx10

-3

-d[Ce]/dtx10

3

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Fig 9.

[LA]-1

Fig.10

[H2SO4]-1

43

y = -0.006x + 0.7049

R2= 0.1491

y = 0.1209x + 1.0391

R2= 0.9183

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

0 10 20 30 40 50 60

y = 0.0028x + 0.3301

R2= 0.6258

y = 0.1209x + 1.0391

R2= 0.9183

0

0.05

0.1

0.15

0.2

0.25

0.3

0.35

0.4

0.45

0 5 10 15 20 25

-d([M]/dt)-1

x1

07

-d([M]/dt)-1

x10-3

8/13/2019 Final Deva Graph

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Fig.11

[H2SO4]-1

Fig.12

Ce(IV)

45

y = 0.0152x + 0.5204

R2= 0.5987

y = 0.1209x + 1.0391

R2= 0.9183

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

0 5 10 15 20 25

y = 11.255x - 0.2003

R2= 0.9732

y = 0.1209x + 1.0391

R2= 0.9183

0

2

4

6

8

10

12

14

0 0.2 0.4 0.6 0.8 1

-d([M]/dt)-1

x10

7

104

[-d[Ce(IV)/dt](mol.dm

-3.S

ec

-1)-

7

8/13/2019 Final Deva Graph

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Fig.13

7[LA]-1

Fig.14

[LA]-1

47

y = 21.863x + 0.8071

R2= 0.9957

y = 0.1209x + 1.0391

R2= 0.9183

0

0.5

1

1.5

2

2.5

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08

y = 0.0104x + 0.3019

R2= 0.9258

y = 0.1209x + 1.0391

R2= 0.9183

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

0 10 20 30 40 50 60

10-3

[-d[Ce(IV)/dt]mol.dm-3.

Sec

-1

10

3[

-d[Ce(IV)/dt]mol.dm

-3

.Sec

-1Sec

-

8/13/2019 Final Deva Graph

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Fig.15

Ce(IV)

Fig.16

[H2SO4]-1

49

y = 11.255x - 0.2003

R2= 0.9732

y = 0.1209x + 1.0391

R2= 0.9183

0

2

4

6

8

10

12

14

0 0.2 0.4 0.6 0.8 1

y = 0.0014x + 0.0879

R2= 0.4995

y = 0.1209x + 1.0391

R2= 0.9183

0

0.2

0.4

0.6

0.8

1

1.2

0 5 10 15 20 25

10-4

[-d[Ce(IV)/dt](mol.dm

-3.

Sec

-1)-

7

10-4

[-d[Ce(IV)/dt]mol.d

m-3.

Sec

-

8/13/2019 Final Deva Graph

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Fig.17

[LA]-1

Fig.18

[H2SO4]-1

51

y = 0.0332x - 0.5322

R2= 0.7985

y = 0.1209x + 1.0391

R2= 0.9183

0

0.2

0.4

0.6

0.8

1

1.2

0 10 20 30 40 50 60

y = 0.0077x + 0.3875

R2= 0.5778

y = 0.1209x + 1.0391

R2= 0.9183

0

0.1

0.2

0.3

0.4

0.5

0.6

0 5 10 15 20 25

104

[-d[Ce(IV)/dt](mol.dm

-3.Sec

-1)-

7

10

7[

-d[Ce(IV)/dt](mol

.dm

-3.

Sec

-1)-

7

8/13/2019 Final Deva Graph

10/22

Fig.19

Ce(IV) (mol. dm-3)

Fig.20

[CE(IV)]-1

(mol. dm-3

)-1

53

y = 1655.9x - 3.4975

R2= 0.9768

y = 0.1209x + 1.0391

R2= 0.9183

0

2

4

6

8

10

12

14

16

18

20

0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009

y = 1881.5x - 3.401

R2= 0.9359

y = 0.1209x + 1.0391

R2= 0.9183

0

5

10

15

20

25

0 0.001 0.002 0.003 0.004 0.005 0.006 0.007 0.008 0.009

10-4

[-d[Ce(IV)/dt]mol.dm-

3.

10-4

[-d[Ce(IV)/dt]mol.dm

-3.

Sec

-1

8/13/2019 Final Deva Graph

11/22

Fig.21

[LA] (mol. dm-3)

Fig.22

[LA] mol. dm-3

55

y = 21.864x + 0.8071

R2= 0.9957

y = 0.1209x + 1.0391

R2= 0.9183

0

0.5

1

1.5

2

2.5

3

3.5

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08

y = 216.68x - 3.1826R = 0.95

y = 0.1209x + 1.0391R2= 0.9183

-2

0

2

4

6

8

10

12

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07

10-3

[-d[Ce(IV)/dt]mol.dm

-3.

Sec

-1

8/13/2019 Final Deva Graph

12/22

Fig.23

[LA] mol. dm-3

Fig.24

[LA]-1

mol. dm-3

57

y = 0.01x + 0.3178

R2= 0.9538

y = 0.1209x + 1.0391

R2= 0.9183

00.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

0 10 20 30 40 50 60

y = 0.011x + 0.3162

R2= 0.9886

y = 0.1209x + 1.0391

R2

= 0.9183

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.91

0 10 20 30 40 50 60

RPX10-8

10

3[

-d[Ce(IV)/dt]mol.dm

-3.

Sec

-1

8/13/2019 Final Deva Graph

13/22

Fig.25

[LA] mol. dm-3

Fig.26

[LA] mol. dm-3

59

y = 0.3152x - 4.6693

R2= 0.795

y = 0.1209x + 1.0391

R2= 0.9183

-2

0

2

4

6

8

10

12

0 10 20 30 40 50 60

y = 0.0193x + 0.1374

R2= 0.9917

y = 0.1209x + 1.0391

R2= 0.9183-1000

-500

0

500

1000

1500

2000

2500

3000

3500

4000

0 10 20 30 40 50 60

10

7[-d[Ce(IV)/dt]-1

(mol.dm

-3.sec

-1)-

1

8/13/2019 Final Deva Graph

14/22

Fig.27

[M] mol dm-3

Fig.28

[M] mol dm-3

61

y = 11.255x - 0.2003

R2= 0.9732

y = 0.1209x + 1.0391

R2= 0.9183

0

5

10

15

20

25

0 0.2 0.4 0.6 0.8 1

y = 0.0647x + 2.0518R = 0.8019

y = 0.1209x + 1.0391R2= 0.9183

0

0.5

1

1.5

2

2.5

3

0 2 4 6 8 1010-4[-d[Ce(IV)/dt]-1

(mol.dm

-3.

1

0-4[-d[Ce(IV)/dt]-1

(mol.dm-3.

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15/22

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Fig.31

[H2SO4]-1

(mol. dm-3

)-1

Fig.32

[H2SO4]-1

(mol. dm-3

)-1

65

y = 0.0077x + 0.3875

R2= 0.5778

y = 0.1209x + 1.0391

R2= 0.9183

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

0 5 10 15 20 25

y = 0.0036x + 0.3502

R2

= 0.5025

y = 0.1209x + 1.0391

R2= 0.9183

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

0 5 10 15 20 25

107[-d[Ce(IV)/dt]-1

(mol.dm

-3.s

ec

-1)-

1

10-4[-d[Ce(IV)/dt]-1

(mol.dm

-3.sec-1)-

1

8/13/2019 Final Deva Graph

17/22

Fig.33.

[Ce](IV) x 10-3

(mol. dm-3

)

Fig.34

[Ce](IV) x mol. dm-3

67

y = 0.1426x + 1.9274R = 0.7694

y = 0.1209x + 1.0391R2= 0.9183

0

0.5

1

1.5

2

2.5

3

3.5

0 2 4 6 8 10

y = 0.2557x + 6.4804R = 0.693

y = 0.1209x + 1.0391R2= 0.9183

7.25

7.3

7.35

7.4

7.45

7.5

7.55

3.4 3.5 3.6 3.7 3.8 3.9 4

RPx10-7

Rpx10-7

8/13/2019 Final Deva Graph

18/22

Variation Of Redutant

Fig.35

[LA] mol. dm-3

Fig.36

[LA] mol. dm-3

69

y = 224.51x - 5.187

R2= 0.9505

y = 0.1209x + 1.0391

R2= 0.9183

-2

0

2

4

6

8

10

12

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08

y = 128.96x + 0.9273

R2= 0.9955

y = 0.1209x + 1.0391

R2= 0.9183

0

2

4

6

8

10

12

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08

RP

X10-8

35oC

30oC

RP

X10-8

35

oC

30oC

8/13/2019 Final Deva Graph

19/22

Fig.37

[LA] mol. dm-3

Fig.38

[LA] mol. dm-3

71

y = 0.0813x - 1.2047

R2= 0.795

y = 0.1209x + 1.0391

R2= 0.9183

-0.5

0

0.5

1

1.5

2

2.5

3

3.5

0 10 20 30 40 50 60

y = 0.005x + 0.0356

R2= 0.9915

y = 0.1209x + 1.0391

R2= 0.9183

0

0.05

0.1

0.15

0.2

0.25

0.3

0 10 20 30 40 50 60

RP

-1X

10

8 35oC

30oC

RP

-1X

10

8

35oC

30oC

8/13/2019 Final Deva Graph

20/22

Fig.39

Fig.40

73

y = 0.656x + 2.9849

R2= 0.901

y = 0.1209x + 1.0391

R2= 0.9183

0

0.5

1

1.5

2

2.5

3

3.5

4

0 0.2 0.4 0.6 0.8 1

y = 1.4479x + 2.1799

R2= 0.9779

y = 0.1209x + 1.0391

R2= 0.9183

0

0.5

1

1.5

2

2.5

3

3.5

4

0 0.2 0.4 0.6 0.8 1

RP

X10-7

RP

X10-7

8/13/2019 Final Deva Graph

21/22

Fig.41

[H2SO4]-1(mol. dm-3)-1

Fig.42

[H2SO4]-1

(mol. dm-3

)-1

75

y = 0.002x + 0.1

R2= 0.5767

y = 0.1209x + 1.0391

R2= 0.9183

0

0.05

0.1

0.15

0.2

0.25

0 5 10 15 20 25

y = 0.0008x + 0.0956

R2= 0.114

y = 0.1209x + 1.0391

R2= 0.9183

0

0.05

0.1

0.15

0.2

0.25

0 5 10 15 20 25

RPx10

8

RPx10

8

8/13/2019 Final Deva Graph

22/22

VI. SUMMARY

1. Oxidation kinetics is followed in the presence and absence of monomer. Rate

constant is increased in both the cases.

2. Two temperatures 30oC & 35oC are followed as the temperature is increases the

rate of the reaction is also increases.

3. Rate of polymerization Rp is calculated as the temperature is increased rate of

polymerization is also increased.

4. The kinetics is followed in the presence of -cyclodextrin since -cyclodextrin It

holds reductant, oxidant and monomer in its cavity and so the reaction isincreased.

5. From the graph Rp increases as we change the concentration of monomer, oxidant,

reductant Rp also increases when the temperature increases. The rate of

polymerization is increases as the concentration of -cyclodextrin. If more amount

of -cyclodextrin the molecule are comes closer to one another and the rate of

polymerization is increases.

76