FINAL ANALYTICAL TAGA REPORT5f TAGA Target Compound Summary in µg/m 3 for Unit 5 Survey, File: 64MSMS00118 Acquired on 23 June 2016 at 14:36:58 6a Unit 7 Survey One Floor Plan, 64MSMS00119

Prepared by: Lockheed Martin/SERAS

€� L Danielle McCall SERAS Task Leader

Kevin Taylor SERAS Program Manager

FINAL ANALYTICAL TAGA REPORT GRAND RAPIDS VAPOR INTRUSION ER

GRAND RAPIDS, MICHIGAN AUGUST 2016

U.S. EPA Work Assignment No.: SERAS-301 LOCKHEED MARTIN Work Order No.: SER00301

U.S. EPA Contract No.: EP-W-09-031

Date

Submitted to

David B. Mickunas

U.S. EPNERT

Analyzed and Prepared by:

Brian Kanupp

SERAS-301-DFARl-082616-TAGA

SERAS-301-DFAR1-082616-TAGA iii

TABLE OF CONTENTS

PAGE

LIST OF TABLES......................................................................................................................................................... v

LIST OF FIGURES ...................................................................................................................................................... vi

1.0 INTRODUCTION. .......................................................................................................................................... 1

2.0 METHODOLOGY .......................................................................................................................................... 1

2.1 Mass Spectrometer/Mass Spectrometer General Theory .................................................................. 1

2.2 TAGA Procedure .............................................................................................................................. 1

2.2.1 TAGA Mass Calibration ..................................................................................................... 2

2.2.2 TAGA Response Factor Measurements .............................................................................. 2

2.2.3 Transport Efficiency ........................................................................................................... 2

2.2.4 TAGA Air Monitoring ........................................................................................................ 3

2.3 Meteorological Monitoring ............................................................................................................... 3

3.0 TAGA AIR MONITORING RESULTS ......................................................................................................... 3

3.1 Unit Surveys...................................................................................................................................... 3

3.2 TAGA File Event Summaries ........................................................................................................... 4

3.3 Graphical Presentations ..................................................................................................................... 4

3.4 TAGA Target Compound Summaries............................................................................................... 4

4.0 DISCUSSION OF RESULTS ........................................................................................................................ 4

4.1 Unit 1 Survey One, 64MSMS00113 ................................................................................................. 4


4.3 Unit 3 Survey, 64MSMS00115 ......................................................................................................... 5

4.4 Unit 4 Survey, 64MSMS00116 ......................................................................................................... 5

4.5 Unit 5 Survey, 64MSMS00118 ......................................................................................................... 5


4.7 Unit 7 Survey Two, 64MSMS00120................................................................................................. 5

4.8 Unit 8 Survey, 64MSMS00121 ......................................................................................................... 5

4.9 Unit 9 Survey, 64MSMS00126 ......................................................................................................... 6

4.10 Unit 10 Survey, 64MSMS00127 ....................................................................................................... 6

4.11 Unit 11 Survey, 64MSMS00128 ....................................................................................................... 6

4.12 Unit 14 Survey, 64MSMS00129 ....................................................................................................... 6


4.14 Unit 12 Survey One, 64MSMS00132 ............................................................................................... 7

4.15 Unit 13 Survey, 64MSMS00138 ....................................................................................................... 7

4.16 Unit 15 Survey, 64MSMS00139 ....................................................................................................... 7

4.17 Unit 16 Survey One, 64MSMS00142 ............................................................................................... 7


4.19 Unit 16 Survey Two, 64MSMS00148............................................................................................... 7

4.20 Unit 12 Survey Two, 64MSMS00149............................................................................................... 8

4.21 Unit 7 Survey Three, 64MSMS00150............................................................................................... 8

4.22 Unit 16 Survey Three, 64MSMS00156............................................................................................. 8

4.23 Unit 17 Survey, 64MSMS00161 ....................................................................................................... 8

4.24 Unit 18 Survey, 64MSMS00162 ....................................................................................................... 8

4.25 Unit 19 Survey, 64MSMS00163 ....................................................................................................... 8

4.26 Unit 20 Survey, 64MSMS00164 ....................................................................................................... 8

SERAS-301-DFAR1-082616-TAGA iv

5.0 QUALITY ASSURANCE/QUALITY CONTROL ........................................................................................ 9

5.1 Intermediate Response Factor for Ion Pairs ...................................................................................... 9

5.2 Error Bars ............................................................................................................................ 10

5.3 Ion Pair Detection and Quantitation Limits .................................................................................... 10

5.4 Compound Detection and Quantitation Limits ............................................................................... 11

APPENDIX A Standard Gas Cylinder Certification

APPENDIX B Compiled Meteorological Data

APPENDIX C TAGA Calibration Data

SERAS-301-DFAR1-082616-TAGA v

LIST OF TABLES

TABLE

1 Summary of Transport Efficiencies Measured on 23 June 2016 to 01 July 2016

2 Summary of Meteorological Conditions during Monitoring, 23 June 2016 to 01 July 2016

3 Summary of Response Factors and Error Bars in ppbv for 23 June 2016 to 01 July 2016

4 Summary of Response Factors and Error Bars in µg/m3 for 23 June 2016 to 01 July 2016

5 Summary of Detection and Quantitation Limit Data in ppbv for 23 June 2016 to 01 July 2016

6 Summary of Detection and Quantitation Limit Data in µg/m3 for 23 June 2016 to 01 July 2016

SERAS-301-DFAR1-082616-TAGA vi

LIST OF FIGURES

FIGURE

1a Unit 1 Survey One Floor Plan, 64MSMS00113

1b TAGA File Event Summary, File: 64MSMS00113 Acquired on 23 June 2016 at 10:17:26, Title: Unit 1

Survey One

1c Unit 1 Survey One in ppbv for Tetrachloroethene and Trichloroethene

1d TAGA Target Compound Summary in ppbv for Unit 1 Survey One, File: 64MSMS00113 Acquired on 23

June 2016 at 10:17:26

1e Unit 1 Survey One in µg/m3 for Tetrachloroethene and Trichloroethene

1f TAGA Target Compound Summary in µg/m3 for Unit 1 Survey One, File: 64MSMS00113 Acquired on 23

June 2016 at 10:17:26



Survey One



June 2016 at 11:28:12



June 2016 at 11:28:12

3a Unit 3 Survey Floor Plan, 64MSMS00115


Survey

3c Unit 3 Survey in ppbv for Tetrachloroethene and Trichloroethene

3d TAGA Target Compound Summary in ppbv for Unit 3 Survey, File: 64MSMS00115 Acquired on 23 June

2016 at 12:35:38

3e Unit 3 Survey in µg/m3 for Tetrachloroethene and Trichloroethene

3f TAGA Target Compound Summary in µg/m3 for Unit 3 Survey, File: 64MSMS00115 Acquired on 23 June

2016 at 12:35:38



Survey



SERAS-301-DFAR1-082616-TAGA vii

2016 at 12:58:32



2016 at 12:58:32



Survey



2016 at 14:36:58



2016 at 14:36:58



Survey One



June 2016 at 16:49:37



June 2016 at 16:49:37

7a Unit 7 Survey Two Floor Plan, 64MSMS00120


Survey Two

7c Unit 7 Survey Two in ppbv for Tetrachloroethene and Trichloroethene

7d TAGA Target Compound Summary in ppbv for Unit 7 Survey Two, File: 64MSMS00120 Acquired on 23

June 2016 at 17:36:21

7e Unit 7 Survey Two in µg/m3 for Tetrachloroethene and Trichloroethene

7f TAGA Target Compound Summary in µg/m3 for Unit 7 Survey Two, File: 64MSMS00120 Acquired on 23

June 2016 at 17:36:21



SERAS-301-DFAR1-082616-TAGA viii

Survey



2016 at 17:57:56



2016 at 17:57:56



Survey



2016 at 08:18:07



2016 at 08:18:07



Survey



2016 at 09:12:49


10f TAGA Target Compound Summary in µg/m3 for Unit 10 Survey, File: 64MSMS00127 Acquired on 24

June 2016 at 09:12:49



Survey



2016 at 12:30:03



SERAS-301-DFAR1-082616-TAGA ix

June 2016 at 12:30:03



Survey



2016 at 13:11:39



June 2016 at 13:11:39



Survey Two



June 2016 at 15:56:40



June 2016 at 15:56:40



Survey One



June 2016 at 16:38:33


14f TAGA Target Compound Summary in µg/m3 for Unit 12 Survey One, File: 64MSMS00132 Acquired on

24 June 2016 at 16:38:33



Survey



SERAS-301-DFAR1-082616-TAGA x

2016 at 10:08:24



June 2016 at 10:08:24



Survey



2016 at 10:34:13



June 2016 at 10:34:13



Survey One



June 2016 at 11:57:08


17f TAGA Target Compound Summary in µg/m3 for Unit 16 Survey One, File: 64MSMS00142 Acquired on

28 June 2016 at 11:57:08



Survey Two



June 2016 at 12:48:27



June 2016 at 12:48:27



SERAS-301-DFAR1-082616-TAGA xi

Survey Two



June 2016 at 10:54:34


19f TAGA Target Compound Summary in µg/m3 for Unit 16 Survey Two, File: 64MSMS00148 Acquired on

29 June 2016 at 10:54:34



Survey Two



June 2016 at 12:13:04


20f TAGA Target Compound Summary in µg/m3 for Unit 12 Survey Two, File: 64MSMS00149 Acquired on

29 June 2016 at 12:13:04

21a Unit 7 Survey Three Floor Plan, 64MSMS00150


Survey Three

21c Unit 7 Survey Three in ppbv for Tetrachloroethene and Trichloroethene

21d TAGA Target Compound Summary in ppbv for Unit 7 Survey Three, File: 64MSMS00150 Acquired on 29

June 2016 at 13:14:42

21e Unit 7 Survey Three in µg/m3 for Tetrachloroethene and Trichloroethene

21f TAGA Target Compound Summary in µg/m3 for Unit 7 Survey Three, File: 64MSMS00150 Acquired on

29 June 2016 at 13:14:42

22a Unit 16 Survey Three Floor Plan, 64MSMS00156


Survey Three

22c Unit 16 Survey Three in ppbv for Tetrachloroethene and Trichloroethene

22d TAGA Target Compound Summary in ppbv for Unit 16 Survey Three, File: 64MSMS00156 Acquired on

30 June 2016 at 13:22:56

22e Unit 16 Survey Three in µg/m3 for Tetrachloroethene and Trichloroethene

22f TAGA Target Compound Summary in µg/m3 for Unit 16 Survey Three, File: 64MSMS00156 Acquired on

SERAS-301-DFAR1-082616-TAGA xii

30 June 2016 at 13:22:56


23b TAGA File Event Summary, File: 64MSMS00161 Acquired on 01 July 2016 at 07:49:37, Title: Unit 17

Survey


23d TAGA Target Compound Summary in ppbv for Unit 17 Survey, File: 64MSMS00161 Acquired on 01 July

2016 at 07:49:37



July 2016 at 07:49:37



Survey



2016 at 08:43:38



July 2016 at 08:43:38



Survey



2016 at 10:36:49



July 2016 at 10:36:49



Survey



SERAS-301-DFAR1-082616-TAGA xiii

2016 at 10:56:43



July 2016 at 10:56:43

SERAS-301-DFAR1-082616-TAGA 1

1.0 INTRODUCTION

The Environmental Protection Agency (EPA)/Environmental Response Team (ERT) issued Work

Assignment (WA) Number SERAS-301, Grand Rapids Vapor Intrusion ER(Site) in Grand Rapids,

Michigan(MI), to Lockheed Martin under the Scientific, Engineering, Response, and Analytical Services

(SERAS) contract. As an element of this WA, SERAS personnel were to conduct target compound

monitoring using the ECA Trace Atmospheric Gas Analyzer (TAGA) IIe, to assist EPA Region 5 in its

investigation of residential and commercial indoor air quality.

The TAGA air monitoring events conducted on 23 June 2016 to 01 July 2016 were screening in nature. Air

monitoring for tetrachloroethene (PCE) and trichloroethene (TCE) was performed in accordance with the

SERAS Standard Operating Procedure (SOP) # 1711, Trace Atmospheric Gas Analyzer (TAGA) IIe

Operation. Real-time monitoring for the target compounds was performed using a selected ion technique.

2.0 METHODOLOGY

2.1 Mass Spectrometer/Mass Spectrometer General Theory

The ECA TAGA IIe is based upon the Perkin-Elmer API 365 mass spectrometer/mass

spectrometer (MS/MS) and is a direct air-monitoring instrument capable of detecting, in real time,

trace levels of many organic compounds in ambient air. The technique of triple quadrupole

MS/MS is used to differentiate and quantitate compounds.

The initial step in the MS/MS process involves simultaneous chemical ionization of the

compounds present in a sample of ambient air. The ionization produces both positive and

negative ions by donating or removing one or more electrons. The chemical ionization is a "soft"

ionization technique, which allows ions to be formed with little or no structural fragmentation.

These ions are called parent ions. The parent ions with different mass-to-charge (m/z) ratios are

separated by the first quadrupole (the first MS of the MS/MS system). The quadrupole scans

selected m/z ratios allowing only the parent ions with these ratios to pass through the quadrupole.

Parent ions with m/z ratios different from those selected are discriminated electronically and fail to

pass through the quadrupole.

The parent ions selected in the first quadrupole are accelerated through a collision cell containing

uncharged nitrogen molecules in the second quadrupole. A portion of the parent ions entering the

second quadrupole fragments as they collide with the nitrogen molecules. These fragment ions are

called daughter ions. This process, in the second quadrupole, is called collision induced

dissociation. The daughter ions are separated according to their m/z ratios by the third quadrupole

(the second MS of the MS/MS system). The quadrupole scans selected m/z ratios, allowing only

the daughter ions with these ratios to pass through the quadrupole. Daughter ions with m/z ratios

different from those selected are discriminated electronically and fail to pass through the

quadrupole. Daughter ions with the selected m/z ratios are then counted by an electron multiplier.

The resulting signals are measured in ion counts per second (icps) for each parent/daughter ion

pair selected. The intensity of the icps for each parent/daughter ion pair is directly proportional to

the ambient air concentration of the organic compound that produced the ion pair. All of the ions

discussed in this report have a single charge. The m/z ratios of all of the ions discussed are equal

to the ion masses in atomic mass units (amu). Therefore, the terms parent and daughter masses are

synonymous with parent and daughter ion m/z ratios.

2.2 TAGA Procedure

The TAGA was used to analyze indoor air during stationary monitoring events. Indoor

monitoring utilized a 300-foot corrugated Teflon® sampling hose. The proximal end was attached

to the TAGA source inlet, while the distal end was taken inside a unit. Air was continuously

drawn through the hose at a set flow rate and transported to the TAGA source during the


monitoring event.

2.2.1 TAGA Mass Calibration

At the beginning of the monitoring period, a gas mixture containing benzene, toluene,

xylenes, tetrachloroethene, trichloroethene, 1,1-dichloroethene, and vinyl chloride was

introduced by a mass flow controller (MFC) into the sample air flow (SAF). The tuning

parameters for the first quadrupole at 30, 78, 106, 130, and 166 amu, and the third

quadrupole at 30, 78, 105, 129, and 166 amu were optimized for sensitivity and mass

assignment. The peak widths were limited between 0.55 amu and 0.85 amu. The mass

assignments were set to the correct values within 0.15 amu.

2.2.2 TAGA Response Factor Measurements

The TAGA was calibrated for the target compounds at the beginning, middle, and end of

each day. The calibration system consisted of a regulated gas cylinder containing a gas

standard mixture of the target compounds connected to an in-line MFC. The MFC was

calibrated with a National Institute of Standards and Technology (NIST) traceable flow

rate meter. The gas standard certification is presented in Appendix A. The gas standard

containing a known mixture of target compounds, certified by the supplier, was regulated

at preset flow rates, and diluted with ambient air. The dilution of the gas standard

resulted in known analyte concentrations. The calibration consisted of a zero point and

five known concentrations obtained by setting the MFC to 0, 10, 20, 40, 80, and 90

milliliters per minute (mL/min) with the SAF at 1,500 milliliters per second (mL/sec).

The approximate concentration range of standards introduced into the TAGA was

between 1 and 25 parts per billion by volume (ppbv). Utilizing the analytes’

concentrations, gas flow rates, and air sampling flow rates, the response factors (RFs), in

units of ion counts per second per part per billion by volume (icps/ppbv), were calculated

for each ion pair by using a least-square-fit algorithm to calculate the slope of its curve.

The coefficient of correlation was checked for each ion pair's RF to ensure that it was

greater than 0.90. The RF of each analyte was used to quantify the target compounds in

ambient air and the intermediate response factor (IRF) was calculated between pairs of

calibrations. Both, the RF and IRF, were used to quantify target compounds in ambient

air.

2.2.3 Transport Efficiency

The transport efficiency and residence time for the target compounds through the 300-

foot length of corrugated Teflon® sampling hose was determined prior to and at the

conclusion of indoor air monitoring activities each day. The transport efficiency was

determined by introducing a known concentration of the target compounds into the

proximal end and then into the distal end of the sampling hose. The signal intensity of

each ion pair for each compound was measured in icps and the percent (%) transport

efficiency calculated using the equation below:

100xhosetheofendproximaltheatintensitysignal

hosetheofenddistaltheatintensitysignalefficiencytransport% =

A transport efficiency of 85% is considered acceptable and results are summarized in

Table 1.

The residence time is the interval, in seconds; it takes the air sample to travel the length

of the sampling hose. The residence time, which reflects a time difference between the


sampling and the instrument response, is incorporated in the offset. The offset, which is

the total number of sequences acquired during the residence time, is applied to the

monitoring files (Figures 1b to 26b, Figures 1c to 26c, Figures 1d to 26d, Figures 1e to

26e, and Figures 1f to 26f). Therefore, the observations and instrument responses are

temporally coordinated.

2.2.4 TAGA Air Monitoring

TAGA monitoring was performed by continuously drawing air through the Teflon® hose

at a flow-rate of approximately 1,500 mL/sec. The air was then passed through a glass

splitter where the pressure gradient between the mass spectrometer core and the

atmosphere causes a sample flow of approximately 10 mL/min into the ionization source

through a heated transfer line. The flow into the TAGA source was controlled so that the

ionization source pressure was maintained at an optimum value of approximately 1.9 torr.

The remaining airflow was drawn through the air pump and vented from the TAGA bus.

Monitoring was performed in the parent/daughter ion-monitoring mode. As monitoring

proceeded, the operator pressed letter keys (flags), alphabetically on a computer

keyboard, to denote events or locations during the monitoring event. This information

was also recorded on an event log sheet. The intensity of each parent/daughter ion pair

monitored by the TAGA was recorded in a permanent file on the computer’s hard drive.

One set of recorded measurements of all the ion pairs is called a sequence.

At the beginning of each unit survey, a one-minute pre-entry ambient data segment was

collected. At the operator's signal, the sampler then entered the unit while holding the

distal end of the hose at breathing height. The sampler proceeded to each room in the

unit where one-minute data segments were collected. After the rooms in the unit were

monitored, a one-minute post-exit ambient data segment was collected. Upon completion

of the one-minute post-exit ambient data segment, the instrumentation was challenged

with the calibration standard, which was introduced at 30 mL/min (approximately 6.7

ppbv), to verify that the system was functioning properly.

2.3 Meteorological Monitoring

United States Department of Commerce, National Oceanic and Atmospheric Administration,

National Climatic Data Center provided the meteorological data for 22 June 2016 to 02 July 2016.

Data were collected at the Gerald R. Ford International Airport in Grand Rapids, MI. The airport

is located approximately 7.9 miles southeast of the Site. Meteorological data, such as wind speed,

wind direction, and rainfall, are summarized in Table 2 for the periods during which monitoring

occurred. The compiled meteorological data are presented in Appendix B. The reported data for

rainfall is an average of the data recorded during the hour preceding the time recorded in the table.

The reported meteorological data for wind speed and direction represent a five-minute average

collected prior to the time recorded in the table. Because of the distance of the meteorological

monitoring location from the study location and the short averaging period, care should be

exercised in relating meteorological conditions existing at the Site

3.0 TAGA AIR MONITORING RESULTS

The TAGA was used to survey indoor air in residential and commercial units at the Site.

3.1 Unit Surveys

Figures 1a through 26a, present the approximate floor plans of each unit. The monitoring

locations marked by letters are the "flags" that the TAGA operator placed into the file. These

"flags" mark events and are carried through the rest of the data presentation.


3.2 TAGA File Event Summaries

Figures 1b through 26b present the TAGA file event summaries. These are the observations made

during the file acquisition by the TAGA operator, along with the times from the TAGA file and

the letter "flags" used to mark the data, which are recorded by the TAGA computer.

3.3 Graphical Presentations

Figures 1c through 26c and Figures 1e through 26e are the graphical representations of the TAGA

files. For Figures 1c through 26c, a graph of each target compound concentration is presented

with ppbv plotted on the vertical axis, and time into the acquisition, in minutes, on the horizontal

axis. For Figures 1e through 26e, a graph of each target compound concentration is presented

with micrograms per cubic meter (µg/m3) plotted on the vertical axis, and time into the

acquisition, in minutes, on the horizontal axis. The target compound concentration was calculated

by averaging the concentrations obtained from the ion pairs that were monitored for each target

compound. There are two horizontal lines on each graph. The lower line is set at the detection

limit (DL) for the compound. The higher line is set at the concentration equal to the quantitation

limit (QL) for the target compound. When high concentrations are represented, the lower DL line

may not be readily discerned. Transient, momentary spikes above the QL line are occasionally

observed. These spikes, electronic in nature, do not affect average concentrations. They may be

distinguished from elevated concentrations because the spikes are only present for one sequence

and are often only present for one ion pair of the monitored compound.

3.4 TAGA Target Compound Summaries

Figures 1d through 26d for ppbv and Figures 1f through 26f, in µg/m3 present the TAGA target

compound summaries. These figures contain the concentrations of the target compounds averaged

over time, at the various locations logged into the TAGA file event summaries.

4.0 DISCUSSION OF RESULTS

The TAGA target compound summaries are represented in Figures 1d through 26d and 1f through 26f.

During each survey, a one-minute average was measured in each room, or at various locations within a

room. Only the highest average concentrations above the QL are listed below. In several of the units the

concentration of tetrachloroethene exceeded the calibration range. These concentrations are flagged with

an “E” and the results are considered estimated.

On 27 June 2016, a decrease in instrument sensitivity required the TAGA instrument to be taken offline for

routine maintenance. As a result, no end of day transport efficiency was performed. The post-analysis

spike for each unit survey performed on 27 June 2016 was within 30 percent (%) of the expected value.

The effect on data quality is determined to be minimal.

4.1 Unit 1 Survey One, 64MSMS00113

Unit 1 was surveyed on 23 June 2016 at 10:17:26 and is represented in Figures 1a through 1f. The

average wind speed and direction at the airport for the five-minute period ending at 10:53 were 11

miles per hour (mph) from 70 degrees. There was no precipitation during the preceding hour. The

highest average concentration of tetrachloroethene was detected at 16 ppbv (110 µg/m3) in the

depression in the floor at the east side of the church between flags R and S. Trichloroethene was

not detected above the QL at any of the monitoring locations.


Unit 2 was initially surveyed on 23 June 2016 at 11:28:12 and is represented in Figures 2a through


2f. The average wind speed and direction at the airport for the five-minute period ending at 11:53

were 11 mph from 50 degrees. There was no precipitation during the preceding hour. The highest

average concentration of tetrachloroethene was detected at 2.9 ppbv (19 µg/m3) at the manhole

cover between flags A1 and B1. Trichloroethene was not detected above the QL at any of the

monitoring locations.

4.3 Unit 3 Survey, 64MSMS00115



mph from 60 degrees. There was no precipitation during the preceding hour. The average

concentrations of tetrachloroethene and trichloroethene were not detected above their quantitation

limits at any of the monitoring locations.




mph from 60 degrees. There was no precipitation during the preceding hour. Tetrachloroethene

was not detected above the QL at any of the monitoring locations. The highest average

concentration of trichloroethene was detected at 0.38 ppbv (2.0 µg/m3) in bedroom two between

flags P and Q.




mph from 80 degrees. There was no precipitation during the preceding hour. The average

concentrations of tetrachloroethene and trichloroethene were not detected above their QLs at any

of the monitoring locations.


Unit 7 was initially surveyed on 23 June 2016 at 16:49:37 and is represented in Figures 6a through

6f. The average wind speed and direction at the airport for the five-minute period ending at 16:53


average concentration of tetrachloroethene was detected at 5.0 ppbv (28 µg/m3) at floor drain one

between flags E1 and F1. Trichloroethene was not detected above the QL at any of the monitoring

locations.

4.7 Unit 7 Survey Two, 64MSMS00120

Unit 7 was surveyed for the second time on 23 June 2016 at 17:36:21and is represented in Figures

7a through 7f. The average wind speed and direction at the airport for the five-minute period

ending at 17:53 were 9 mph from 80 degrees. There was no precipitation during the preceding

hour. The highest average concentration of tetrachloroethene was detected at 140 ppbv (780

µg/m3) at floor drain two between flags E and F. The concentration of tetrachloroethene exceeded

the calibration range during the survey. These concentrations are flagged with an “E” in Figures

7d and 7f and are considered estimated. The highest average concentration of trichloroethene was

detected at 2.8 ppbv (12 µg/m3) at floor drain two between flags E and F.





mph from 80 degrees. There was no precipitation during the preceding hour. The highest average

concentration of tetrachloroethene was detected at 2.0 ppbv (11 µg/m3) at crack one in the floor

between flags I1 and J1. Trichloroethene was not detected above the QL at any of the monitoring

locations.




mph from 80 degrees. There was no precipitation during the preceding hour. The highest average

concentration of tetrachloroethene was detected at 90 ppbv (610 µg/m3) at the inside of the first

floor depressurization line between flags N1 and O1. The concentration of tetrachloroethene

exceeded the calibration range during the survey. These concentrations are flagged with an “E” in

Figures 9d and 9f and are considered estimated. Trichloroethene was not detected above the QL at

any of the monitoring locations.


Unit 10 was surveyed on 24 June 2016 at 09:12:49 and is represented in Figures 10a through 10f.

The average wind speed and direction at the airport for the five-minute period ending at 09:53


average concentration of tetrachloroethene was detected at 17 ppbv (110 µg/m3) in copy room one

between flags J and K. Trichloroethene was not detected above the QL at any of the monitoring

locations.





average concentration of tetrachloroethene was detected at 45 ppbv (300 µg/m3) at open sampling

port one between flags S and T. The concentration of tetrachloroethene exceeded the calibration

range during the survey. These concentrations are flagged with an “E” in Figures 11d and 11f and

are considered estimated. Trichloroethene was not detected above the QL at any of the monitoring

locations.




were 8 mph from 80 degrees. There was no precipitation during the preceding hour. The average

concentrations of tetrachloroethene and trichloroethene were not detected above their QLs at any

of the monitoring locations.


Unit 1 was surveyed for a second time on 24 June 2016 at 15:56:40 and is represented in Figures



hour. The highest average concentration of tetrachloroethene was detected at 1.0 ppbv (6.9 µg/m3)

in office two between flags R and S. Trichloroethene was not detected above the QL at any of the




Unit 12 was initially surveyed on 24 June 2016 at 16:38:33 and is represented in Figures 14a

through 14f. The average wind speed and direction at the airport for the five-minute period ending

at 16:53 were 3 mph from variable directions. There was no precipitation during the preceding

hour. The highest average concentration of tetrachloroethene was detected at 100 ppbv (680

µg/m3) at the cleanout between flags I1 and J1. The concentration of tetrachloroethene exceeded

the calibration range during the survey. These concentrations are flagged with an “E” in Figures

14d and 14f and are considered estimated. The highest average concentration of trichloroethene

was detected at 0.47 ppbv (2.5 µg/m3) at the cleanout between flags I1 and J1.




were 14 mph from 280 degrees. There was no precipitation during the preceding hour. The

average concentrations of tetrachloroethene and trichloroethene were not detected above their QLs

at any of the monitoring locations.








Unit 16 was initially surveyed on 28 June 2016 at 11:57:08 and is represented in Figures 17a

through 17f. The average wind speed and direction at the airport for the five-minute period ending

at 11:53 were 6 mph from 330 degrees. There was no precipitation during the preceding hour.

The highest average concentration of tetrachloroethene was detected at 27 ppbv (180 µg/m3) at the

manhole between flags J1 and K1. Trichloroethene was not detected above the QL at any of the



Unit 2 was surveyed for the second time on 28 June 2016 at 12:48:27 and is represented in Figures



hour. The highest average concentration of tetrachloroethene was detected at 1.7 ppbv (11 µg/m3)

at the manhole cover between flags A1 and C1. Trichloroethene was not detected above the QL at

any of the monitoring locations.


Unit 16 was surveyed for the second time on 29 June 2016 at 10:54:34 and is represented in

Figures 19a through 19f. The average wind speed and direction at the airport for the five-minute

period ending at 10:53 were 7 mph from 30 degrees. There was no precipitation during the

preceding hour. The highest average concentration of tetrachloroethene was detected at 5.8 ppbv

(39 µg/m3) at the manhole between flags J1 and K1. Trichloroethene was not detected above the

QL at any of the monitoring locations.



Unit 12 was surveyed for the second time on 29 June 2016 at 12:13:04 and is represented in

Figures 20a through 20f. The average wind speed and direction at the airport for the five-minute

period ending at 12:53 were 6 mph from 350 degrees. There was no precipitation during the


(31 µg/m3) at the outdoor drain between flags E2 and F2. Trichloroethene was not detected above

the QL at any of the monitoring locations.

4.21 Unit 7 Survey Three, 64MSMS00150

Unit 7 was surveyed for the third time on 29 June 2016 at 13:14:42 and is represented in Figures


ending at 13:53 were 3 mph from variable directions. There was no precipitation during the


(12 µg/m3) in the crawl space between flags Y and Z. Trichloroethene was not detected above the

QL at any of the monitoring locations.

4.22 Unit 16 Survey Three, 64MSMS00156

Unit 16 was surveyed for the third time on 30 June 2016 at 13:22:56 and is represented in Figures



hour. The highest average concentration of tetrachloroethene was detected at 7.0 ppbv (48 µg/m3)

at the manhole between flags N and O. Trichloroethene was not detected above the QL at any of

the monitoring locations.


Unit 17 was surveyed on 01 July 2016 at 07:49:37 and is represented in Figures 23a through 23f.



highest average concentration of tetrachloroethene was detected at 0.39 ppbv (2.7 µg/m3) in

bedroom three between flags W and X. Trichloroethene was not detected above the QL at any of



















highest average concentration of tetrachloroethene was detected at 4.0 ppbv (27 µg/m3) at the hole

through the floor between flags O and P. Trichloroethene was not detected above the QL at any of


5.0 QUALITY ASSURANCE/QUALITY CONTROL

The compound parent/daughter ion pairs used are listed below.

Compound Parent Ion Mass Daughter Ion Mass

Tetrachloroethene 164 129



Trichloroethene 130 95



Tables 3 and 4 document the RFs and IRFs generated during the calibration procedure for the individual

ion pairs. The RFs and IRFs were used to quantitate the ion pair concentrations.

The summaries of detection and quantitation limit data for the monitoring periods (Sections 5.3 and 5.4 and

Tables 5 and 6) document the concentration, in ppbv for Table 5 and µg/m3 for Table 6, required for a

compound's ion pair to be considered detectable and quantifiable during the specified monitoring period.

The DL is defined as three times the standard deviation (SD) of the concentration for a compound's ion pair

measured in an ambient air sample. The QL is defined as 10 times the SD of the concentration for the same

conditions. The detection and quantitation limits for a compound result from averaging the appropriate

detection and quantitation limits of the compound's ion pairs.

5.1 Intermediate Response Factor for Ion Pairs

Response factors were generated from two calibration events, as described in the procedure

(Section 2.2.2.). Table 3 contains the RFs in units of icps/ppbv and Table 4 contains the RFs in

units of icps/µg/m3. The initial and final RFs were used to calculate the IRFs, which were used to

calculate the reported concentration results.

The following equation was used to calculate the IRFs found in Tables 3 through 6.

)RF(RF

)RF2(RFIRF

21

21

+

×

=

where:

IRF = Intermediate response factor (icps/concentration)

RF1 = The RF for an ion pair measured during the first calibration event (icps/concentration)

RF2 = The RF for the same ion pair measured during the second calibration event

(icps/concentration)

For example, the entry for the 164/129 ion pair of tetrachloroethene from Table 3 for files

64MSMS00111 and 64MSMS00117 acquired on 23 June 2016 is:

RF1 = 274.02 icps/ppbv



therefore,

IRF=2(274.02x384.37)

(274.02+384.37)=

210,650.13

658.39=319.947 icps/ppbv

The result, 319.95 icps/ppbv, is the IRF reported in Table 3 and used in Table 5.

5.2 Error Bars

The potential maximum concentration percent deviations for each target compound are presented

in Tables 3 for ppbv and Table 4 for µg/m3 and are called “error bars” for simplicity. They

represent the potential bias in the concentration due to changes in the sensitivity of the TAGA

instrument. Errors bars were calculated using the following equation:

100)RF(RF

RFRFbarerror

21

21×

+

−

=

where:

error bar = Maximum concentration percent deviation

RF1 = The RF for an ion pair measured during the first calibration event


RF2 = The RF for the same ion pair measured during the second calibration event






%8.16100)37.384(274.02

384.37274.02barerror =×

+

−

=

The % error bar calculated for the 164/129 ion pair of tetrachloroethene is 16.8% for files

64MSMS00111 and 64MSMS00117 acquired on 23 June 2016.

The above calculation was repeated for each ion pair. The error bars for each compound’s ions

were averaged to give a single value for the compound. This averaged error bar can be applied to

the samples analyzed between the two calibrations of the monitoring period.

5.3 Ion Pair Detection and Quantitation Limits

The DLs and QLs were calculated using the SD of the compound's ion pair intensity measured in

an ambient air sample and its RF or IRF. The SD reflects the variability of the instrument’s

response to the ambient air sample.

The following equation was used to calculate the DLs found in Table 5 and Table 6:

IRForRF

SD3DL

×

=


where:

DL = Detection limit for an ion pair (concentration)

SD = Standard deviation of the ion intensity measured in an ambient air sample (icps)

RF or IRF = Response factor or intermediate response factor for an ion pair (icps/concentration)



SD = 8.2052 icps

IRF = 319.95 icps/ppbv

ppbv0.0769319.95

8.20523DL =

×

=

The following equation was used to calculate the QLs found in Table 5 and Table 6:

IRForRF

SD10QL

×

=

where:

QL = Quantitation limit for an ion pair (concentration)

SD = Standard deviation of the ion intensity measured in an ambient air sample (icps)

RF or IRF = Response factor or intermediate response factor for an ion pair (icps/concentration)



SD = 8.2052 icps

IRF = 319.95 icps/ppbv

ppbv0.256319.95

8.205210QL =

×

=

5.4 Compound Detection and Quantitation Limits

Averaging the respective DLs and QLs of the target compound’s ion pairs generated the DLs and

QLs found in Table 5 and Table 6.

The following equation was used to calculate the compound's DL:

n

DLDLDLDL

n21c

+++

=

K

where:

DLc = Detection limit for a compound (concentration)

DL1 = Detection limit for the first ion pair (concentration)

DL2 = Detection limit for the second ion pair (concentration)

DLn = Detection limit for the nth ion pair (concentration)


n = Number of ion pairs to be averaged

For example, the entries for the 164/129, 166/129, and 166/131 ion pairs of tetrachloroethene from

Table 5 for files 64MSMS00111 and 64MSMS00117 acquired on 23 June 2016 is:

ppbv0.09223

0.2766

3

0.0677 0.1320.0769DLc ==

++

=

This result, 0.0922 ppbv, rounded to 0.092 ppbv is the DL for tetrachloroethene found in Table 5.

The following equation was used to calculate the compound's QL:

n

QLQLQLQL

n21c

K++

=

where:

QLc = Quantitation limit for a compound (concentration)

QL1 = Quantitation limit for the first ion pair (concentration)

QL2 = Quantitation limit for the second ion pair (concentration)

QLn = Quantitation limit for the nth ion pair (concentration)

n = Number of ion pairs to be averaged

For example, the entries for the 164/129, 166/129, and 166/131 ion pairs of tetrachloroethene from

Table 5 for files 64MSMS00111 and 64MSMS00117 acquired on 23 June 2016 is:

ppbv0.3073

0.922

3

0.226 0.4400.256QLc ==

++

=

This result, 0.307 ppbv, rounded to 0.31 ppbv is the QL for tetrachloroethene found in Table 5.

SERAS-301-DFAR1-082616-TAGA

TABLES


TABLE 1

Summary of Transport Efficiencies Measured on 23 June 2016 to 01 July 2016

Grand Rapids Vapor Intrusion ER

Grand Rapids, Michigan

August 2016

Transport Efficiency for 23 June 2016 09:33:17

File: 64MSMS00112

Start Sequence: 334 740

End Sequence: 429 840

Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)

Tetrachloroethene 164/129 1691.6 1753.0 104



Average Tetrachloroethene Transport Efficiency: 106

Trichloroethene 130/95 1651.5 1744.9 106



Average Trichloroethene Transport Efficiency: 106


File: 64MSMS00123



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)






Trichloroethene 132/95 775.69 770.31 99.3



PM/DM = Parent Mass/Daughter Mass

icps = ion counts per second

% = Percent


TABLE 1 (continued)




August 2016


File: 64MSMS00125



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)










File: 64MSMS00134



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)

Tetrachloroethene 164/129 2013.7 1945.6 96.6



Average Tetrachloroethene Transport Efficiency: 97.1




Average Trichloroethene Transport Efficiency: 99.1



% = Percent


TABLE 1 (continued)




August 2016


File: 64MSMS00137



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)










File: 64MSMS00141



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)











% = Percent


TABLE 1 (continued)




August 2016


File: 64MSMS00145



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)










File: 64MSMS00147



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)











% = Percent


TABLE 1 (continued)




August 2016


File: 64MSMS00152



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)










File: 64MSMS00154



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)











% = Percent


TABLE 1 (continued)




August 2016


File: 64MSMS00158



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)









Transport Efficiency for 01 July 2016 07:06:31

File: 64MSMS00160



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)











% = Percent


TABLE 1 (continued)




August 2016

Transport Efficiency for 01 July 2016 14:25:37

File: 64MSMS00166



Compound PM/DM

Proximal

Intensity

(icps)

Distal

Intensity

(icps)

Transport

Efficiency

(%)











% = Percent


TABLE 2

Summary of Meteorological Conditions during Monitoring, 23 June 2016 to 01 July 2016



August 2016

File Location Date Start Time

Wind

Speed

(mph)

Wind

Direction

(degrees)

Rainfall

(inches)

64MSMS00113 Unit 1 Survey 06/23/2016 10:17:26 11 70

64MSMS00114 Unit 2 Survey One 06/23/2016 11:28:12 11 50

64MSMS00115 Unit 3 Survey 06/23/2016 12:35:38 16 60

64MSMS00116 Unit 4 Survey 06/23/2016 12:58:32 16 60

64MSMS00118 Unit 5 Survey 06/23/2016 14:36:58 11 80


64MSMS00120 Unit 7 Survey Two 06/23/2016 17:36:21 9 80

64MSMS00121 Unit 8 Survey 06/23/2016 17:57:56 9 80

64MSMS00126 Unit 9 Survey 06/24/2016 08:18:07 10 80

64MSMS00127 Unit 10 Survey 06/24/2016 09:12:49 6 110

64MSMS00128 Unit 11 Survey 06/24/2016 12:30:03 8 80

64MSMS00129 Unit 14 Survey 06/24/2016 13:11:39 8 80


64MSMS00132 Unit 12 Survey One 06/24/2016 16:38:33 3 VR

64MSMS00138 Unit 13 Survey 06/27/2016 10:08:24 14 280

64MSMS00139 Unit 15 Survey 06/27/2016 10:34:13 17 270

Wind direction is the direction from which the wind is blowing.

mph = Miles per hour

VR = Variable direction


TABLE 2 (continued)

Summary of Meteorological Conditions during Monitoring, 23 June 2016 to 01 July 2016



August 2016

File Location Date Start Time

Wind

Speed

(mph)

Wind

Direction

(degrees)

Rainfall

(inches)





64MSMS00150 Unit 7 Survey Three 06/29/2016 13:14:42 3 VR

64MSMS00156 Unit 16 Survey Three 06/30/2016 13:22:56 11 240

64MSMS00161 Unit 17 Survey 07/01/2016 07:49:37 13 330

64MSMS00162 Unit 18 Survey 07/01/2016 08:43:38 18 320

64MSMS00163 Unit 19 Survey 07/01/2016 10:36:49 20 360

64MSMS00164 Unit 20 Survey 07/01/2016 10:56:43 20 360


mph = Miles per hour

VR = Variable direction


TABLE 3

Summary of Response Factors and Error Bars in ppbv for 23 June 2016 to 01 July 2016



August 2016

Calibration Files: 64MSMS00111 and 64MSMS00117 on 23 June 2016

Used for Survey Files: 64MSMS00113, 64MSMS00114, 64MSMS00115, and 64MSMS00116

Compound PM/DM

Initial

Response

Factor

(icps/ppbv)

Final

Response

Factor

(icps/ppbv)

Intermediate

Response

Factor

(icps/ppbv)

Error Bar

(%)

Tetrachloroethene 164/129 274.02 384.37 319.95 16.8



Average: 16

Trichloroethene 130/95 262.49 358.01 302.90 15.4



Average: 15

Calibration Files: 64MSMS00117MD and 64MSMS00122 on 23 June 2016

Used for Survey Files: 64MSMS00119, 64MSMS00120, and 64MSMS00121

Compound PM/DM

Initial

Response

Factor

(icps/ppbv)

Final

Response

Factor

(icps/ppbv)

Intermediate

Response

Factor

(icps/ppbv)

Error Bar

(%)




Average: 2.6




Average: 4.2



ppbv = parts per billion by volume

% = Percent


TABLE 3 (continued)




August 2016



Compound PM/DM

Initial

Response

Factor

(icps/ppbv)

Final

Response

Factor

(icps/ppbv)

Intermediate

Response

Factor

(icps/ppbv)

Error Bar

(%)




Average: 1.3




Average: 1.4


Used for Survey Files: 64MSMS00131 and 64MSMS00132

Compound PM/DM

Initial

Response

Factor

(icps/ppbv)

Final

Response

Factor

(icps/ppbv)

Intermediate

Response

Factor

(icps/ppbv)

Error Bar

(%)




Average: 14




Average: 10




% = Percent


TABLE 3 (continued)




August 2016



Compound PM/DM

Initial

Response

Factor

(icps/ppbv)

Final

Response

Factor

(icps/ppbv)

Intermediate

Response

Factor

(icps/ppbv)

Error Bar

(%)




Average: 30




Average: 32



Compound PM/DM

Initial

Response

Factor

(icps/ppbv)

Final

Response

Factor

(icps/ppbv)

Intermediate

Response

Factor

(icps/ppbv)

Error Bar

(%)




Average: 10




Average: 11




% = Percent


TABLE 3 (continued)




August 2016


Used for Survey Files: 64MSMS00156

Compound PM/DM

Initial

Response

Factor

(icps/ppbv)

Final

Response

Factor

(icps/ppbv)

Intermediate

Response

Factor

(icps/ppbv)

Error Bar

(%)




Average: 7.7




Average: 5.0

Calibration Files: 64MSMS00159 and 64MSMS00165 on 01 July 2016


Compound PM/DM

Initial

Response

Factor

(icps/ppbv)

Final

Response

Factor

(icps/ppbv)

Intermediate

Response

Factor

(icps/ppbv)

Error Bar

(%)




Average: 3.7




Average: 1.2




% = Percent


TABLE 4

Summary of Response Factors and Error Bars in µg/m3 for 23 June 2016 to 01 July 2016


August 2016



Compound PM/DM

Initial

Response

Factor

(icps/µg/m3)

Final

Response

Factor

(icps/µg/m3)

Intermediate

Response

Factor

(icps/µg/m3)

Error Bar

(%)




Average: 16




Average: 15



Compound PM/DM

Initial

Response

Factor

(icps/µg/m3)

Final

Response

Factor

(icps/µg/m3)

Intermediate

Response

Factor

(icps/µg/m3)

Error Bar

(%)




Average: 2.6




Average: 4.2



µg/m3 = micrograms per cubic meter

% = Percent


TABLE 4 (continued)



August 2016



Compound PM/DM

Initial

Response

Factor

(icps/µg/m3)

Final

Response

Factor

(icps/µg/m3)

Intermediate

Response

Factor

(icps/µg/m3)

Error Bar

(%)




Average: 1.3




Average: 1.4



Compound PM/DM

Initial

Response

Factor

(icps/µg/m3)

Final

Response

Factor

(icps/µg/m3)

Intermediate

Response

Factor

(icps/µg/m3)

Error Bar

(%)




Average: 14




Average: 10




% = Percent


TABLE 4 (continued)



August 2016



Compound PM/DM

Initial

Response

Factor

(icps/µg/m3)

Final

Response

Factor

(icps/µg/m3)

Intermediate

Response

Factor

(icps/µg/m3)

Error Bar

(%)




Average: 30




Average: 32



Compound PM/DM

Initial

Response

Factor

(icps/µg/m3)

Final

Response

Factor

(icps/µg/m3)

Intermediate

Response

Factor

(icps/µg/m3)

Error Bar

(%)




Average: 10




Average: 11




% = Percent


TABLE 4 (continued)



August 2016



Compound PM/DM

Initial

Response

Factor

(icps/µg/m3)

Final

Response

Factor

(icps/µg/m3)

Intermediate

Response

Factor

(icps/µg/m3)

Error Bar

(%)




Average: 7.7




Average: 5.0



Compound PM/DM

Initial

Response

Factor

(icps/µg/m3)

Final

Response

Factor

(icps/µg/m3)

Intermediate

Response

Factor

(icps/µg/m3)

Error Bar

(%)




Average: 3.7




Average: 1.2




% = Percent


TABLE 5

Summary of Detection and Quantitation Limit Data in ppbv for 23 June 2016 to 01 July 2016



August 2016



Compound PM/DM

Intermediate

Response

Factor

(icps/ppbv)

Standard

Deviation

(icps)

Detection

Limit

(ppbv)

Quantitation

Limit

(ppbv)




Average: 0.092 0.31




Average: 0.084 0.28



Compound PM/DM

Intermediate

Response

Factor

(icps/ppbv)

Standard

Deviation

(icps)

Detection

Limit

(ppbv)

Quantitation

Limit

(ppbv)




Average: 0.048 0.16




Average: 0.085 0.28





TABLE 5 (continued)




August 2016



Compound PM/DM

Intermediate

Response

Factor

(icps/ppbv)

Standard

Deviation

(icps)

Detection

Limit

(ppbv)

Quantitation

Limit

(ppbv)




Average: 0.14 0.45




Average: 0.12 0.41



Compound PM/DM

Intermediate

Response

Factor

(icps/ppbv)

Standard

Deviation

(icps)

Detection

Limit

(ppbv)

Quantitation

Limit

(ppbv)




Average: 0.12 0.41




Average: 0.070 0.23





TABLE 5 (continued)




August 2016

Calibration File: 64MSMS00136 at 08:20:36 on 27 June 2016


Compound PM/DM

Response

Factor

(icps/ppbv)

Standard

Deviation

(icps)

Detection

Limit

(ppbv)

Quantitation

Limit

(ppbv)




Average: 0.12 0.41




Average: 0.23 0.78



Compound PM/DM

Intermediate

Response

Factor

(icps/ppbv)

Standard

Deviation

(icps)

Detection

Limit

(ppbv)

Quantitation

Limit

(ppbv)




Average: 0.081 0.27




Average: 0.081 0.27





TABLE 5 (continued)




August 2016



Compound PM/DM

Intermediate

Response

Factor

(icps/ppbv)

Standard

Deviation

(icps)

Detection

Limit

(ppbv)

Quantitation

Limit

(ppbv)




Average: 0.049 0.16




Average: 0.053 0.18



Compound PM/DM

Intermediate

Response

Factor

(icps/ppbv)

Standard

Deviation

(icps)

Detection

Limit

(ppbv)

Quantitation

Limit

(ppbv)




Average: 0.15 0.51




Average: 0.11 0.36





TABLE 5 (continued)




August 2016



Compound PM/DM

Intermediate

Response

Factor

(icps/ppbv)

Standard

Deviation

(icps)

Detection

Limit

(ppbv)

Quantitation

Limit

(ppbv)




Average: 0.11 0.36




Average: 0.084 0.28





TABLE 6

Summary of Detection and Quantitation Limit Data in µg/m3 for 23 June 2016 to 01 July 2016



August 2016



Compound PM/DM

Intermediate

Response

Factor

(icps/µg/m3)

Standard

Deviation

(icps)

Detection

Limit

(µg/m3)

Quantitation

Limit

(µg/m3)




Average: 0.63 2.1




Average: 0.45 1.5



Compound PM/DM

Intermediate

Response

Factor

(icps/µg/m3)

Standard

Deviation

(icps)

Detection

Limit

(µg/m3)

Quantitation

Limit

(µg/m3)




Average: 0.33 1.1




Average: 0.46 1.5





TABLE 6 (continued)




August 2016



Compound PM/DM

Intermediate

Response

Factor

(icps/µg/m3)

Standard

Deviation

(icps)

Detection

Limit

(µg/m3)

Quantitation

Limit

(µg/m3)




Average: 0.92 3.1




Average: 0.66 2.2



Compound PM/DM

Intermediate

Response

Factor

(icps/µg/m3)

Standard

Deviation

(icps)

Detection

Limit

(µg/m3)

Quantitation

Limit

(µg/m3)




Average: 0.83 2.8




Average: 0.37 1.2





TABLE 6 (continued)




August 2016

Calibration File: 64MSMS00136 at 08:20:36 on 27 June 2016


Compound PM/DM

Response

Factor

(icps/µg/m3)

Standard

Deviation

(icps)

Detection

Limit

(µg/m3)

Quantitation

Limit

(µg/m3)




Average: 0.84 2.8




Average: 1.3 4.2



Compound PM/DM

Intermediate

Response

Factor

(icps/µg/m3)

Standard

Deviation

(icps)

Detection

Limit

(µg/m3)

Quantitation

Limit

(µg/m3)




Average: 0.55 1.8




Average: 0.44 1.5





TABLE 6 (continued)




August 2016



Compound PM/DM

Intermediate

Response

Factor

(icps/µg/m3)

Standard

Deviation

(icps)

Detection

Limit

(µg/m3)

Quantitation

Limit

(µg/m3)




Average: 0.33 1.1




Average: 0.28 0.95



Compound PM/DM

Intermediate

Response

Factor

(icps/µg/m3)

Standard

Deviation

(icps)

Detection

Limit

(µg/m3)

Quantitation

Limit

(µg/m3)




Average: 1.0 3.4




Average: 0.58 1.9





TABLE 6 (continued)




August 2016



Compound PM/DM

Intermediate

Response

Factor

(icps/µg/m3)

Standard

Deviation

(icps)

Detection

Limit

(µg/m3)

Quantitation

Limit

(µg/m3)




Average: 0.73 2.4




Average: 0.45 1.5





FIGURES


Figure 1a Unit 1 Survey One Floor Plan, 64MSMS00113


Figure 1b

TAGA File Event Summary

File: 64MSMS00113 Acquired on 23 June 2016 at 10:17:26

Title: Unit 1 Survey One

Flag Offset Time Offset Sequence Description

A 2.7 256 Start of the pre-entry ambient

B 3.7 352 End of the pre-entry ambient

C 5.2 500 Entering the unit

D 5.7 544 Start of the breezeway

E 6.7 640 End of the breezeway

F 7.0 663 Start of bathroom one

G 8.0 760 End of bathroom one

H 8.3 790 Start of base of toilet in bathroom one

I 9.3 886 End of base of toilet in bathroom one

J 9.7 922 Start of bathroom two

K 10.9 1036 End of bathroom two

L 11.1 1058 Start of sink drain in bathroom two

M 12.1 1152 End of sink drain in bathroom two

N 12.3 1176 Start of base of toilet in bathroom two

O 13.4 1273 End of base of toilet in bathroom two

P 14.0 1331 Start of the east side of main church

Q 15.0 1427 End of the east side of main church

R 15.6 1481 Start of the depression in floor at the east side of church

S 16.5 1576 End of the depression in floor at the east side of church

T 16.8 1598 Start of the west side of main church

U 17.9 1701 End of the west side of main church

V 18.4 1755 Start of office one

W 19.5 1855 End of office one

X 20.1 1917 Start of the raised pulpit

Y 21.2 2014 End of the raised pulpit

Z 21.5 2044 Start of office two

A1 22.5 2139 End of office two

B1 23.1 2201 Start of the furnace room

C1 24.5 2329 End of the furnace room

D1 25.5 2431 Exiting the unit

E1 29.0 2762 Start of the post-exit ambient

F1 30.0 2859 End of the post-exit ambient

G1 31.2 2969 Start of 30 mL/min spike

H1 32.2 3065 End of 30 mL/min spike


Figure 1c Unit 1 Survey One in ppbv for Tetrachloroethene and Trichloroethene

A B CD

EF

GH

I J KL

MN

OP QR

ST

UV

WX

YZ

A1B1

C1 D1 E1 F1 G1H1

0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

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QL

DL

Tetrachloroethene (64MSMS00113)

Un

its i

n p

pb

v

Time in minutes

A B CD

EF

GH

I J KL

MN

OP QR

ST

UV

WX

YZ

A1B1

C1 D1 E1 F1 G1H1

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0 5 10 15 20 25 30

QL

DL

Trichloroethene (64MSMS00113)

Un

its i

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pb

v

Time in minutes


Figure 1d

TAGA Target Compound Summary in ppbv for Unit 1 Survey One


Tetrachloroethene Trichloroethene

Detection Limits - DL: 0.092 0.084

Quantitation Limits - QL: 0.31 0.28

Flags Description Tetrachloroethene Trichloroethene

A - B Pre-entry ambient DL=0.092 DL=0.084

D - E Breezeway 11 DL=0.084

F - G Bathroom one 8.9 0.085J

H - I Base of toilet in bathroom one 7.9 DL=0.084

J - K Bathroom two 12 0.097J

L - M Sink drain in bathroom two 12 0.10J

N - O Base of toilet in bathroom two 9.1 DL=0.084

P - Q East side of main church 15 0.12J

R - S Depression in floor at the east side of church 16 0.13J

T - U West side of main church 14 0.12J

V - W Office one 8.9 0.087J

X - Y Raised pulpit 15 0.13J

Z - A1 Office two 15 0.13J

B1 - C1 Furnace room 11 0.12J

E1 - F1 Post-exit ambient 0.20J DL=0.084

G1 - H1 30 mL/min spike 5.8 5.7

Concentrations are given in parts per billion by volume (ppbv)

J = Concentration detected below the quantitation limit


Figure 1e Unit 1 Survey One in µg/m3 for Tetrachloroethene and Trichloroethene

A B CD

EF

GH

I J KL

MN

OP QR ST

UV

WX

YZ

A1B1

C1 D1 E1 F1 G1H1

0

25

50

75

100

125

0 5 10 15 20 25 30

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD

EF

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I J KL

MN

OP QR ST

UV

WX

YZ

A1B1

C1 D1 E1 F1 G1H1

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Time in minutes


Figure 1f

TAGA Target Compound Summary in µg/m3 for Unit 1 Survey One







D - E Breezeway 71 DL=0.45

F - G Bathroom one 60 0.46J

H - I Base of toilet in bathroom one 54 DL=0.45

J - K Bathroom two 79 0.52J

L - M Sink drain in bathroom two 80 0.54J

N - O Base of toilet in bathroom two 62 DL=0.45

P - Q East side of main church 99 0.63J

R - S Depression in floor at the east side of church 110 0.70J

T - U West side of main church 98 0.66J

V - W Office one 60 0.47J

X - Y Raised pulpit 99 0.69J

Z - A1 Office two 100 0.67J

B1 - C1 Furnace room 75 0.63J

E1 - F1 Post-exit ambient 1.3J DL=0.45

G1 - H1 30 mL/min spike 39 31

Concentrations are given in micrograms per cubic meter (µg/m3)





Figure 2b








D 6.2 587 Start of the living room

E 7.4 705 End of the living room

F 7.7 730 Start of bedroom

G 8.7 828 End of bedroom

H 9.1 865 Start of the dining room

I 10.2 968 End of the dining room

J 10.6 1011 Start of the kitchen

K 11.6 1108 End of the kitchen

L 11.9 1130 Start screening under the kitchen sink

M 12.9 1233 End screening under the kitchen sink

N 13.4 1281 Start of the bathroom

O 14.5 1377 End of the bathroom

P 14.9 1422 Entering the basement

Q 15.3 1455 Start of the sub-slab port

R 17.0 1620 End of the sub-slab port

S 17.3 1645 Start of the dry sump

T 18.3 1741 End of the dry sump

U 18.6 1768 Start of the basement

V 19.6 1868 End of the basement

W 20.3 1937 Start of the water line

X 21.4 2036 End of the water line

Y 22.0 2098 Start of the crawl space

Z 23.0 2193 End of the crawl space

A1 23.6 2244 Start of the manhole cover

B1 25.1 2394 End of the manhole cover

C1 25.8 2455 Exiting the basement








A B C D EF

GH

I J KL

MN

OP

Q RS

TU

V W XY ZA1 B1C1 D1

E1 F1 G1H1

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9

10

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QL

DL


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its i

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pb

v

Time in minutes

A B C D EF

GH

I J KL

MN

OP

Q RS

TU

V W XY ZA1 B1C1 D1

E1 F1 G1H1

0.00

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QL

DL


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its i

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pb

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Time in minutes


Figure 2d








D - E Living room DL=0.092 DL=0.084

F - G Bedroom DL=0.092 DL=0.084

H - I Dining room DL=0.092 DL=0.084

J - K Kitchen 0.10J DL=0.084

L - M Screening under the kitchen sink 0.19J DL=0.084

N - O Bathroom DL=0.092 DL=0.084

Q - R Sub-slab port 1.5 DL=0.084

S - T Dry sump 1.6 DL=0.084

U - V Basement 0.90 DL=0.084

W - X Water line 0.74 DL=0.084

Y - Z Crawl space 0.79 DL=0.084

A1 - B1 Manhole cover 2.9 DL=0.084

E1 - F1 Post-exit ambient DL=0.092 DL=0.084

G1 - H1 30 mL/min spike 6.9 6.9





A B C D EF

GH

I J KL

MN

OP

Q RS

TU

V W XY ZA1 B1C1 D1

E1 F1 G1H1

0

10

20

30

40

50

60

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QL

DL


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its i

n µ

g/m

3

Time in minutes

A B C D EF

GH

I J KL

MN

OP

Q RS

TU

V W XY ZA1 B1C1 D1

E1 F1 G1H1

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DL


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its i

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g/m

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Time in minutes


Figure 2f









F - G Bedroom DL=0.63 DL=0.45

H - I Dining room DL=0.63 DL=0.45


L - M Screening under the kitchen sink 1.3J DL=0.45

N - O Bathroom DL=0.63 DL=0.45

Q - R Sub-slab port 9.9 DL=0.45

S - T Dry sump 11 DL=0.45


W - X Water line 5.0 DL=0.45


A1 - B1 Manhole cover 19 DL=0.45






Figure 3a Unit 3 Survey Floor Plan, 64MSMS00115


Figure 3b



Title: Unit 3 Survey







F 7.5 714 Start of the kitchen

G 8.5 811 End of the kitchen

H 8.8 838 Start screening under the kitchen sink

I 9.8 935 End screening under the kitchen sink

J 10.2 973 Start of the laundry room

K 11.2 1070 End of the laundry room

L 11.4 1090 Start of the bathroom

M 12.4 1185 End of the bathroom

N 13.5 1290 Start of the garage

O 14.5 1385 End of the garage

P 15.5 1479 Exiting the unit

Q 16.5 1568 Start of the post-exit ambient

R 17.5 1671 End of the post-exit ambient

S 19.7 1879 Start of 30 mL/min spike

T 20.7 1975 End of 30 mL/min spike


Figure 3c Unit 3 Survey in ppbv for Tetrachloroethene and Trichloroethene

A B CD

EF

GH

I J KL

M N O P Q R S T

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

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QL

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Time in minutes

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EF

GH

I J KL

M N O P Q R S T

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QL

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Time in minutes


Figure 3d

TAGA Target Compound Summary in ppbv for Unit 3 Survey








F - G Kitchen DL=0.092 DL=0.084

H - I Screening under the kitchen sink DL=0.092 DL=0.084

J - K Laundry room DL=0.092 DL=0.084

L - M Bathroom DL=0.092 DL=0.084

N - O Garage DL=0.092 DL=0.084

Q - R Post-exit ambient DL=0.092 DL=0.084

S - T 30 mL/min spike 6.9 7.2



Figure 3e Unit 3 Survey in µg/m3 for Tetrachloroethene and Trichloroethene

A B CD

EF

GH

I J KL

M N O P Q R S T

0.0

0.5

1.0

1.5

2.0

2.5

3.0

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QL

DL


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its i

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g/m

3

Time in minutes

A B CD

EF

GH

I J KL

M N O P Q R S T

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its i

n µ

g/m

3

Time in minutes


Figure 3f

TAGA Target Compound Summary in µg/m3 for Unit 3 Survey








F - G Kitchen DL=0.63 DL=0.45

H - I Screening under the kitchen sink DL=0.63 DL=0.45

J - K Laundry room DL=0.63 DL=0.45

L - M Bathroom DL=0.63 DL=0.45

N - O Garage DL=0.63 DL=0.45


S - T 30 mL/min spike 47 39



Figure 4 a Unit 4 Survey Floor Plan, 64MSMS00116


Figure 4b










F 6.7 643 Start of the kitchen

G 7.8 743 End of the kitchen

H 8.3 787 Start of the laundry room

I 9.3 889 End of the laundry room

J 9.6 919 Start of bathroom one

K 10.7 1019 End of bathroom one

L 11.1 1062 Start of bathroom two

M 12.1 1155 End of bathroom two

N 12.5 1192 Start of bedroom one

O 13.5 1290 End of bedroom one

P 14.4 1376 Start of bedroom two

Q 15.5 1473 End of bedroom two

R 15.9 1514 Start of the garage

S 17.0 1622 End of the garage

T 17.8 1698 Exiting the unit

U 20.4 1940 Start of the post-exit ambient

V 21.5 2047 End of the post-exit ambient

W 23.5 2241 Start of 30 mL/min spike

X 24.5 2336 End of 30 mL/min spike



A B CD

EF

GH I J KL

MN

O P QR

S T U V W X

0.0

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Time in minutes

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EF

GH I J KL

MN

O P QR

S T U V W X

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DL


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its i

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pb

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Time in minutes


Figure 4d








D - E Living room 0.12J 0.17J

F - G Kitchen 0.12J 0.24J

H - I Laundry room 0.12J 0.28J

J - K Bathroom one 0.12J 0.28

L - M Bathroom two 0.11J 0.28

N - O Bedroom one 0.15J 0.31

P - Q Bedroom two 0.13J 0.38

R - S Garage 0.12J 0.33

U - V Post-exit ambient DL=0.092 DL=0.084

W - X 30 mL/min spike 6.9 7.2





A B CD

EF

GH I J KL

MN

O P QR

S T U V W X

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DL


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g/m

3

Time in minutes

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EF

GH I J KL

MN

O P QR

S T U V W X

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Time in minutes


Figure 4f








D - E Living room 0.80J 0.93J

F - G Kitchen 0.81J 1.3J

H - I Laundry room 0.78J 1.5J

J - K Bathroom one 0.82J 1.5

L - M Bathroom two 0.76J 1.5

N - O Bedroom one 1.0J 1.7

P - Q Bedroom two 0.91J 2.0

R - S Garage 0.83J 1.8

U - V Post-exit ambient DL=0.63 DL=0.45

W - X 30 mL/min spike 47 39






Figure 5b








D 4.4 424 Start of the kitchen

E 5.5 521 End of the kitchen

F 5.7 544 Start of the bathroom

G 6.7 638 End of the bathroom

H 7.1 675 Start of the closet

I 8.1 768 End of the closet

J 8.3 795 Start of the living room

K 9.4 897 End of the living room

L 9.6 914 Start of the dining room

M 10.6 1011 End of the dining room

N 11.3 1074 Entering the basement

O 11.7 1117 Start of the south side of basement

P 12.8 1216 End of the south side of basement

Q 13.1 1244 Start of the north side of basement

R 14.1 1339 End of the north side of basement

S 14.4 1368 Start of the sub-slab port

T 15.4 1465 End of the sub-slab port

U 15.8 1506 Start of sump two

V 16.8 1603 End of sump two

W 17.0 1623 Start of sump one

X 18.0 1718 End of sump one

Y 18.5 1763 Start of the furnace drain

Z 19.5 1856 End of the furnace drain

A1 20.3 1929 Start of the DEQ vapor point

B1 21.3 2031 End of the DEQ vapor point









A B CD

EF

GH

IJ KL

MNO

PQ

RS

TU

VW

XY

Z A1 B1 C1D1

E1 F1 G1 H1

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EF

GH

IJ KL

MNO

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Z A1 B1 C1D1

E1 F1 G1 H1

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Time in minutes


Figure 5d








D - E Kitchen 0.078J DL=0.085

F - G Bathroom 0.087J 0.096J

H - I Closet 0.12J 0.13J

J - K Living room 0.099J 0.12J

L - M Dining room 0.098J 0.12J

O - P South side of basement 0.11J 0.11J

Q - R North side of basement 0.11J 0.12J

S - T Sub-slab port 0.12J 0.11J

U - V Sump two 0.12J 0.12J

W - X Sump one 0.11J 0.12J

Y - Z Furnace drain 0.11J 0.11J

A1 - B1 DEQ vapor point 0.11J 0.11J


G1 - H1 30 mL/min spike 7.3 7.3





A B CD

EF

GH

IJ KL

MNO

PQ

RS

TU

VW

XY

Z A1 B1 C1D1

E1 F1 G1 H1

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Z A1 B1 C1D1

E1 F1 G1 H1

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Figure 5f








D - E Kitchen 0.43J DL=0.46

F - G Bathroom 0.48J DL=0.46

H - I Closet 0.67J 0.55J

J - K Living room 0.55J 0.51J

L - M Dining room 0.54J 0.52J

O - P South side of basement 0.62J 0.49J

Q - R North side of basement 0.59J 0.53J

S - T Sub-slab port 0.64J 0.49J

U - V Sump two 0.64J 0.54J

W - X Sump one 0.63J 0.51J

Y - Z Furnace drain 0.59J 0.49J

A1 - B1 DEQ vapor point 0.59J 0.49J








Figure 6b










F 7.3 698 Start of bedroom one

G 8.3 795 End of bedroom one

H 8.7 828 Start of closet one

I 9.7 925 End of closet one

J 10.1 965 Start of the bathroom

K 11.1 1060 End of the bathroom



N 13.0 1238 Start of bedroom two

O 14.0 1330 End of bedroom two

P 14.2 1354 Start of closet two

Q 15.2 1449 End of closet two

R 15.8 1509 Start of bedroom three

S 16.9 1609 End of bedroom three

T 17.2 1634 Start of the kitchen

U 18.0 1715 End of the kitchen

V 18.3 1741 Entering the basement

W 19.4 1850 Start of the crawl space

X 20.3 1934 End of the crawl space

Y 20.9 1987 Start of the storage area

Z 21.9 2083 End of the storage area

A1 22.3 2128 Start of the recessed area

B1 23.4 2226 End of the recessed area

C1 23.7 2258 Start of the sub-slab port

D1 24.9 2369 End of the sub-slab port

E1 24.9 2375 Start of floor drain one

F1 26.2 2494 End of floor drain one

G1 26.8 2556 Start of hole one at the east side of basement

H1 27.9 2654 End of hole one at the east side of basement


Figure 6b (continued)





I1 28.2 2686 Start of hole two at the east side of basement

J1 29.6 2823 End of hole two at the east side of basement

K1 30.9 2938 Start of the crack in floor

L1 31.9 3038 End of the crack in floor

M1 32.2 3065 Start of cut pipe one

N1 33.2 3164 End of cut pipe one

O1 33.5 3194 Start of cut pipe two

P1 34.6 3291 End of cut pipe two

Q1 35.2 3351 Start of the basement

R1 36.2 3448 End of the basement

S1 36.9 3511 Exiting the basement

T1 37.8 3603 Start of the entryway

U1 39.2 3736 End of the entryway

V1 39.5 3757 Exiting the unit

W1 40.2 3828 Start of the post-exit ambient

X1 41.3 3933 End of the post-exit ambient

Y1 42.7 4069 Start of 30 mL/min spike

Z1 43.7 4165 End of 30 mL/min spike



A B CD

EF

GH

IJ KL

MN

OP

QR

ST

UV

WX

Y ZA1

B1C1

D1E1F1

G1H1

I1 J1 K1L1

M1N1O1

P1Q1

R1S1

T1 U1V1 W1

X1Y1Z1

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A B CD

EF

GH

IJ KL

MN

OP

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WX

Y ZA1

B1C1

D1E1F1

G1H1

I1 J1 K1L1

M1N1 O1

P1Q1

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T1 U1V1 W1

X1Y1Z1

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Figure 6d








D - E Living room 0.055J DL=0.085

F - G Bedroom one 0.21 DL=0.085

H - I Closet one 0.23 DL=0.085

J - K Bathroom 0.10J DL=0.085

L - M Dining room DL=0.048 DL=0.085

N - O Bedroom two 0.13J DL=0.085

P - Q Closet two 0.12J DL=0.085

R - S Bedroom three DL=0.048 DL=0.085

T - U Kitchen 0.053J DL=0.085

W - X Crawl space 3.1 0.11J

Y - Z Storage area 2.6 0.10J

A1 - B1 Recessed area 2.0 0.099J

C1 - D1 Sub-slab port 2.3 0.094J

E1 - F1 Floor drain one 5.0 0.11J

G1 - H1 Hole one at the east side of basement 2.8 0.091J

I1 - J1 Hole two at the east side of basement 1.9 DL=0.085

K1 - L1 Crack in floor 2.8 0.099J

M1 - N1 Cut pipe one 2.0 0.10J

O1 - P1 Cut pipe two 2.3 0.11J

Q1 - R1 Basement 2.0 0.099J

T1 - U1 Entryway 0.15J DL=0.085

W1 - X1 Post-exit ambient DL=0.048 DL=0.085

Y1 - Z1 30 mL/min spike 7.8 7.6





A B CD

EF

GH

IJ KL

MN

OP

QR

ST

UV

WX

Y ZA1

B1C1

D1E1

F1G1

H1I1

J1 K1L1

M1N1 O1

P1Q1

R1S1

T1 U1V1 W1

X1 Y1Z1

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A B CD

EF

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IJ KL

MN

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Y ZA1

B1C1

D1E1F1

G1H1

I1 J1 K1L1

M1N1 O1

P1Q1

R1S1

T1 U1V1 W1

X1Y1Z1

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Figure 6f









F - G Bedroom one 1.2 DL=0.46

H - I Closet one 1.3 DL=0.46

J - K Bathroom 0.58J DL=0.46


N - O Bedroom two 0.74J DL=0.46



T - U Kitchen DL=0.33 DL=0.46

W - X Crawl space 17 0.47J

Y - Z Storage area 14 DL=0.46

A1 - B1 Recessed area 11 DL=0.46

C1 - D1 Sub-slab port 13 DL=0.46

E1 - F1 Floor drain one 28 0.47J

G1 - H1 Hole one at the east side of basement 15 DL=0.46

I1 - J1 Hole two at the east side of basement 11 DL=0.46

K1 - L1 Crack in floor 15 DL=0.46

M1 - N1 Cut pipe one 11 DL=0.46

O1 - P1 Cut pipe two 13 0.47J

Q1 - R1 Basement 11 DL=0.46

T1 - U1 Entryway 0.84J DL=0.46

W1 - X1 Post-exit ambient DL=0.33 DL=0.46

Y1 - Z1 30 mL/min spike 43 33




Figure 7a Unit 7 Survey Two Floor Plan, 64MSMS00120


Figure 7b



Title: Unit 7 Survey Two





D 6.5 621 Entering the basement

E 7.0 665 Start of floor drain two

F 8.3 795 End of floor drain two

G 9.7 927 Exiting the basement

H 11.2 1066 Exiting the unit

I 11.9 1130 Start of the post-exit ambient

J 12.9 1227 End of the post-exit ambient

K 13.9 1322 Start of 30 mL/min spike

L 14.9 1418 End of 30 mL/min spike


Figure 7c Unit 7 Survey Two in ppbv for Tetrachloroethene and Trichloroethene

A B C D E F G H I J K L

0

50

100

150

200

250

300

350

400

0.0 2.5 5.0 7.5 10.0 12.5 15.0

QLDL


Un

its i

n p

pb

v

Time in minutes


0

1

2

3

4

5

6

7

8

9

10

11

0.0 2.5 5.0 7.5 10.0 12.5 15.0

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 7d

TAGA Target Compound Summary in ppbv for Unit 7 Survey Two







E - F Floor drain two 140E 2.8

I - J Post-exit ambient 0.36 DL=0.085

K - L 30 mL/min spike 7.8 7.5



E = Concentration detected above the calibration range


Figure 7e Unit 7 Survey Two in µg/m3 for Tetrachloroethene and Trichloroethene


0

250

500

750

1000

1250

1500

1750

2000

2250

0.0 2.5 5.0 7.5 10.0 12.5 15.0

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Un

its i

n µ

g/m

3

Time in minutes


0

5

10

15

20

25

30

35

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45

0.0 2.5 5.0 7.5 10.0 12.5 15.0

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 7f

TAGA Target Compound Summary in µg/m3 for Unit 7 Survey Two







E - F Floor drain two 780E 12

I - J Post-exit ambient 2.0 DL=0.46

K - L 30 mL/min spike 43 33







Figure 8b










F 6.0 575 Start of the storage area

G 7.0 671 End of the storage area



J 9.0 855 Start of the side room

K 10.0 952 End of the side room

L 10.4 986 Start of the kitchen

M 11.4 1082 End of the kitchen



P 12.9 1228 Start of the utility closet

Q 13.9 1325 End of the utility closet

R 15.6 1488 Start of the drain pipe

S 16.7 1592 End of the drain pipe

T 17.3 1647 Entering the basement

U 17.6 1676 Start of the basement

V 18.6 1769 End of the basement

W 19.1 1815 Start of the sub-slab port

X 20.0 1909 End of the sub-slab port

Y 20.6 1963 Start of crawl space one

Z 21.6 2058 End of crawl space one

A1 22.4 2137 Start of crawl space two

B1 23.4 2232 End of crawl space two

C1 23.8 2267 Start of water line one

D1 24.9 2367 End of water line one

E1 25.9 2470 Start of the south to north screening along west wall

F1 28.0 2670 End of the south to north screening along west wall

G1 28.3 2691 Start of the storage room

H1 29.3 2788 End of the storage room







I1 29.7 2829 Start of crack one in floor

J1 31.3 2978 End of crack one in floor

K1 32.2 3069 Start of crawl space three

L1 33.3 3168 End of crawl space three

M1 33.7 3207 Start of crack two in floor

N1 34.7 3308 End of crack two in floor

O1 35.4 3371 Start of crawl space four

P1 36.4 3467 End of crawl space four

Q1 36.9 3510 Start of water line two

R1 38.0 3616 End of water line two

S1 39.6 3768 Start of five feet below surface

T1 40.8 3884 End of five feet below surface

U1 41.9 3985 Exiting the basement

V1 42.5 4050 Exiting the unit

W1 43.5 4146 Start of the post-exit ambient

X1 44.7 4252 End of the post-exit ambient

Y1 46.4 4414 Start of 30 mL/min spike

Z1 47.4 4514 End of 30 mL/min spike



AB CD

EF

GH

IJ

KL

MN

OP

Q R ST

U VW

XY

ZA1B1 C1

D1E1

F1G1

H1I1

J1K1

L1M1

N1O1

P1Q1

R1 S1T1U1

V1W1

X1 Y1Z1

0

1

2

3

4

5

6

7

8

9

10

11

0 5 10 15 20 25 30 35 40 45

QL

DL


Un

its i

n p

pb

v

Time in minutes

AB CD

EF

GH

IJ

KL

MN

OP

Q R ST

U VW

XY

ZA1B1 C1

D1E1

F1G1

H1I1

J1K1

L1M1

N1O1

P1Q1

R1 S1T1U1

V1W1

X1 Y1Z1

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0 5 10 15 20 25 30 35 40 45

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 8d







A - B Pre-entry ambient 0.055J DL=0.085


F - G Storage area 0.12J DL=0.085

H - I Dining room 0.11J DL=0.085

J - K Side room 0.12J 0.089J

L - M Kitchen 0.11J DL=0.085

N - O Bathroom 0.096J DL=0.085

P - Q Utility closet 0.13J DL=0.085

R - S Drain pipe 0.079J DL=0.085


W - X Sub-slab port 0.93 DL=0.085

Y - Z Crawl space one 0.69 DL=0.085

A1 - B1 Crawl space two 0.84 DL=0.085

C1 - D1 Water line one 1.2 DL=0.085

E1 - F1 South to north screening along west wall 0.92 DL=0.085

G1 - H1 Storage room 0.86 DL=0.085

I1 - J1 Crack one in floor 2.0 DL=0.085

K1 - L1 Crawl space three 0.71 DL=0.085

M1 - N1 Crack two in floor 1.1 DL=0.085

O1 - P1 Crawl space four 0.35 DL=0.085

Q1 - R1 Water line two 0.22 DL=0.085

S1 - T1 Five feet below surface 0.72 DL=0.085

W1 - X1 Post-exit ambient 0.068J DL=0.085

Y1 - Z1 30 mL/min spike 7.3 7.3





AB CD

EF

GH

IJ

KL

MN

OP

Q R ST

U VW

XY

ZA1B1 C1

D1E1

F1G1

H1I1

J1K1

L1M1

N1O1

P1Q1

R1 S1T1U1

V1W1

X1 Y1Z1

0

10

20

30

40

50

60

0 5 10 15 20 25 30 35 40 45

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

AB CD

EF

GH

IJ

KL

MN

OP

Q R ST

U VW

XY

ZA1B1 C1

D1E1

F1G1

H1I1

J1K1

L1M1

N1O1

P1Q1

R1 S1T1U1

V1W1

X1 Y1Z1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0 5 10 15 20 25 30 35 40 45

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 8f









F - G Storage area 0.65J DL=0.46


J - K Side room 0.64J DL=0.46

L - M Kitchen 0.62J DL=0.46


P - Q Utility closet 0.72J DL=0.46

R - S Drain pipe 0.44J DL=0.46


W - X Sub-slab port 5.1 DL=0.46

Y - Z Crawl space one 3.8 DL=0.46

A1 - B1 Crawl space two 4.7 DL=0.46

C1 - D1 Water line one 6.4 DL=0.46

E1 - F1 South to north screening along west wall 5.1 DL=0.46

G1 - H1 Storage room 4.7 DL=0.46

I1 - J1 Crack one in floor 11 DL=0.46

K1 - L1 Crawl space three 3.9 DL=0.46

M1 - N1 Crack two in floor 6.0 DL=0.46

O1 - P1 Crawl space four 1.9 DL=0.46

Q1 - R1 Water line two 1.2 DL=0.46

S1 - T1 Five feet below surface 4.0 DL=0.46

W1 - X1 Post-exit ambient 0.38J DL=0.46

Y1 - Z1 30 mL/min spike 40 32






Figure 9b








D 12.9 1228 Start of the hallway

E 13.9 1323 End of the hallway

F 14.2 1348 Start of the base of green room door

G 15.2 1443 End of the base of green room door

H 15.5 1477 Start of bathroom one

I 16.5 1573 End of bathroom one

J 16.9 1607 Start of bathroom two

K 17.9 1704 End of bathroom two



N 19.5 1858 Start of the side gallery

O 20.5 1954 End of the side gallery

P 20.8 1981 Start of the closet

Q 21.8 2078 End of the closet

R 22.2 2113 Start of main gallery one

S 23.6 2243 End of main gallery one

T 24.1 2297 Start of main gallery two

U 25.1 2392 End of main gallery two

V 25.5 2424 Start of main gallery three

W 26.5 2525 End of main gallery three

X 26.9 2565 Entering the basement

Y 27.3 2603 Start of the basement

Z 28.4 2705 End of the basement

A1 28.7 2736 Start of the sump

B1 30.4 2898 End of the sump

C1 31.2 2966 Start of the inside of toilet

D1 32.2 3063 End of the inside of toilet

E1 33.1 3149 Start of the washer drain line

F1 34.1 3242 End of the washer drain line

G1 34.3 3266 Start of the floor drain

H1 35.4 3374 End of the floor drain







I1 36.8 3504 Start of the basement depressurization line

J1 37.8 3601 End of the basement depressurization line

K1 38.9 3706 Exiting the basement

L1 39.5 3763 Start of the first floor depressurization line

M1 40.6 3864 End of the first floor depressurization line

N1 41.0 3906 Start of the inside of first floor depressurization line

O1 42.1 4007 End of the inside of first floor depressurization line

P1 43.7 4158 Exiting the unit

Q1 45.6 4337 Start of the post-exit ambient

R1 46.7 4448 End of the post-exit ambient

S1 48.3 4596 Start of 30 mL/min spike

T1 49.6 4721 End of 30 mL/min spike



AB CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX Y

ZA1

B1C1

D1E1

F1G1

H1I1

J1K1L1

M1N1O1

P1 Q1R1

S1T1

0

50

100

150

200

250

300

0 5 10 15 20 25 30 35 40 45 50

QLDL


Un

its i

n p

pb

v

Time in minutes

AB CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX Y

ZA1

B1C1

D1E1

F1G1

H1I1

J1K1L1

M1N1O1

P1 Q1R1

S1T1

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

1.1

1.2

0 5 10 15 20 25 30 35 40 45 50

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 9d








D - E Hallway DL=0.14 DL=0.12

F - G Base of green room door DL=0.14 DL=0.12

H - I Bathroom one DL=0.14 DL=0.12

J - K Bathroom two DL=0.14 DL=0.12

L - M Kitchen DL=0.14 DL=0.12

N - O Side gallery DL=0.14 DL=0.12

P - Q Closet DL=0.14 DL=0.12

R - S Main gallery one DL=0.14 DL=0.12

T - U Main gallery two DL=0.14 DL=0.12

V - W Main gallery three DL=0.14 DL=0.12

Y - Z Basement 0.36J DL=0.12

A1 - B1 Sump 0.32J DL=0.12

C1 - D1 Inside of toilet 0.33J DL=0.12

E1 - F1 Washer drain line 0.35J DL=0.12

G1 - H1 Floor drain 0.36J DL=0.12

I1 - J1 Basement depressurization line 0.36J DL=0.12

L1 - M1 First floor depressurization line DL=0.14 DL=0.12

N1 - O1 Inside of first floor depressurization line 90E 0.14J

Q1 - R1 Post-exit ambient 0.30J DL=0.12

S1 - T1 30 mL/min spike 7.3 6.6






AB CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX Y

ZA1

B1C1

D1E1

F1G1

H1I1

J1K1L1

M1N1O1

P1 Q1R1

S1T1

0

250

500

750

1000

1250

1500

1750

2000

0 5 10 15 20 25 30 35 40 45 50

QLDL


Un

its i

n µ

g/m

3

Time in minutes

AB CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX Y

ZA1

B1C1

D1E1

F1G1

H1I1

J1K1L1

M1N1O1

P1 Q1R1

S1T1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

6.0

0 5 10 15 20 25 30 35 40 45 50

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 9f








D - E Hallway DL=0.92 DL=0.66

F - G Base of green room door DL=0.92 DL=0.66

H - I Bathroom one DL=0.92 DL=0.66

J - K Bathroom two DL=0.92 DL=0.66


N - O Side gallery DL=0.92 DL=0.66

P - Q Closet DL=0.92 DL=0.66

R - S Main gallery one DL=0.92 DL=0.66

T - U Main gallery two DL=0.92 DL=0.66

V - W Main gallery three DL=0.92 DL=0.66

Y - Z Basement 2.4J DL=0.66

A1 - B1 Sump 2.2J DL=0.66

C1 - D1 Inside of toilet 2.2J DL=0.66

E1 - F1 Washer drain line 2.3J DL=0.66

G1 - H1 Floor drain 2.4J DL=0.66

I1 - J1 Basement depressurization line 2.5J DL=0.66

L1 - M1 First floor depressurization line DL=0.92 DL=0.66

N1 - O1 Inside of first floor depressurization line 610E 0.73J

Q1 - R1 Post-exit ambient 2.1J DL=0.66

S1 - T1 30 mL/min spike 49 36







Figure 10b








D 31.5 3001 Start of the hallway

E 32.6 3103 End of the hallway

F 33.1 3152 Start of the common area

G 34.1 3249 End of the common area

H 34.6 3296 Start of office one

I 35.7 3396 End of office one

J 36.2 3447 Start of copy room one

K 37.2 3545 End of copy room one

L 37.9 3612 Start of bathroom one

M 39.0 3710 End of bathroom one

N 39.1 3726 Start of floor drain one

O 40.2 3823 End of floor drain one

P 41.4 3945 Start of the conference room

Q 42.4 4040 End of the conference room

R 43.6 4155 Start of the elevator shaft base of door

S 44.7 4253 End of the elevator shaft base of door

T 45.2 4304 Start of bathroom two

U 46.2 4399 End of bathroom two

V 46.4 4415 Start of floor drain two

W 48.0 4572 End of floor drain two

X 51.5 4907 Start of the rear entryway

Y 52.6 5010 End of the rear entryway

Z 53.1 5053 Entering the second floor

A1 55.1 5248 Start of the second floor landing

B1 56.1 5343 End of the second floor landing

C1 58.9 5611 Start of office two

D1 60.9 5793 End of office two

E1 61.4 5844 Start of office three

F1 63.7 6065 End of office three

G1 64.0 6096 Start of office four

H1 65.1 6195 End of office four







I1 65.4 6225 Start of office five

J1 66.4 6323 End of office five

K1 66.8 6357 Start of office six

L1 67.9 6461 End of office six

M1 69.9 6650 Start of office seven

N1 70.9 6748 End of office seven

O1 71.2 6779 Start of office eight

P1 72.2 6872 End of office eight

Q1 72.5 6902 Start of copy room two

R1 73.5 6999 End of copy room two

S1 73.8 7025 Start of the file room

T1 74.9 7129 End of the file room

U1 75.8 7218 Start of the reception area

V1 76.8 7313 End of the reception area

W1 78.3 7453 Exiting the second floor

X1 79.2 7539 Entering the basement

Y1 80.2 7638 Start of basement one

Z1 81.1 7721 End of basement one

A2 81.5 7759 Start of floor drain three

B2 82.5 7853 End of floor drain three

C2 82.7 7873 Start of floor drain four

D2 83.7 7970 End of floor drain four

E2 84.6 8056 Start of the depressurization line one

F2 85.7 8157 End of the depressurization line one

G2 86.9 8268 Start of the vapor barrier

H2 87.9 8368 End of the vapor barrier

I2 88.3 8403 Start of the mini vent

J2 89.3 8502 End of the mini vent

K2 90.2 8582 Start of the break in separation wall

L2 91.2 8678 End of the break in separation wall

M2 92.1 8765 Start of the top of separation wall

N2 93.1 8863 End of the top of separation wall

O2 93.6 8914 Start of the bottom of separation wall

P2 94.8 9023 End of the bottom of separation wall







Q2 95.5 9088 Start of basement two

R2 96.6 9195 End of basement two

S2 97.2 9252 Start of the side room

T2 98.2 9345 End of the side room

U2 99.5 9474 Start of the crack in floor

V2 100.5 9569 End of the crack in floor

W2 101.1 9622 Start of basement three

X2 102.1 9717 End of basement three

Y2 102.4 9752 Start of the sewer drain pipe

Z2 103.6 9858 End of the sewer drain pipe

A3 105.8 10069 Start of the base of J plug west side

B3 107.0 10189 End of the base of J plug west side

C3 109.0 10372 Start of base of depressurization line two

D3 110.0 10470 End of base of depressurization line two

E3 112.2 10677 Start of inside depressurization line two

F3 113.4 10791 End of inside depressurization line two

G3 114.9 10938 Start of the J plug east side

H3 116.2 11059 End of the J plug east side

I3 116.9 11125 Start of inside depressurization line three

J3 117.9 11224 End of inside depressurization line three

K3 121.3 11549 Start of crack in wall between basement two and three

L3 122.8 11687 End of crack in wall between basement two and three

M3 125.2 11922 Start of top of wall between basement two and three

N3 126.9 12077 End of top of wall between basement two and three

O3 129.7 12350 Exiting the basement


Q3 133.4 12702 Start of the post-exit ambient

R3 135.3 12880 End of the post-exit ambient

S3 137.7 13110 Start of 30 mL/min spike

T3 138.7 13206 End of 30 mL/min spike



AB

CD EF

GHIJ

KLMN

OPQ

RSTUVW

XYZ

A1B1C1

D1E1F1G1

H1I1J1K1L1

M1N1O1P1Q1R1S1

T1U1V1W1

X1Y1Z1A2B2C2

D2E2F2G2H2

I2J2K2

L2M2N2O2P2

Q2R2S2T2U2

V2W2X2Y2Z2

A3B3C3

D3E3F3

G3H3I3J3

K3L3M3

N3O3P3

Q3R3

S3T3

0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

0 25 50 75 100 125

QL

DL


Un

its i

n p

pb

v

Time in minutes

AB

CD EF

GHIJ

KLMN

OPQ

RSTUVW

XYZ

A1B1C1

D1E1F1G1

H1I1J1K1L1

M1N1O1P1Q1R1S1

T1U1V1W1

X1Y1Z1A2B2C2

D2E2F2G2

H2I2J2K2L2

M2N2O2P2Q2R2

S2T2U2V2

W2X2Y2Z2A3

B3C3D3

E3F3G3

H3I3J3

K3L3M3

N3O3P3

Q3R3

S3T3

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

1.1

1.2

0 25 50 75 100 125

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 10d








D - E Hallway 1.8 DL=0.12

F - G Common area 12 DL=0.12

H - I Office one 14 0.13J

J - K Copy room one 17 0.16J

L - M Bathroom one 15 0.14J

N - O Floor drain one 15 0.14J

P - Q Conference room 13 0.13J

R - S Elevator shaft base of door 11 DL=0.12

T - U Bathroom two 14 0.14J

V - W Floor drain two 14 0.13J

X - Y Rear entryway 9.2 DL=0.12

A1 - B1 Second floor landing 7.1 DL=0.12

C1 - D1 Office two 5.1 DL=0.12

E1 - F1 Office three 4.6 DL=0.12

G1 - H1 Office four 4.5 DL=0.12

I1 - J1 Office five 4.2 DL=0.12

K1 - L1 Office six 4.2 DL=0.12

M1 - N1 Office seven 4.1 DL=0.12

O1 - P1 Office eight 4.2 DL=0.12

Q1 - R1 Copy room two 4.2 DL=0.12

S1 - T1 File room 4.5 DL=0.12

U1 - V1 Reception area 4.0 DL=0.12

Y1 - Z1 Basement one 7.0 DL=0.12

A2 - B2 Floor drain three 8.2 DL=0.12

C2 - D2 Floor drain four 7.7 DL=0.12

E2 - F2 Depressurization line one 7.6 DL=0.12

G2 - H2 Vapor barrier 4.3 DL=0.12

I2 - J2 Mini vent 2.1 DL=0.12




Figure 10d (continued)







K2 - L2 Break in separation wall 6.8 DL=0.12

M2 - N2 Top of separation wall 6.9 DL=0.12

O2 - P2 Bottom of separation wall 6.9 DL=0.12

Q2 - R2 Basement two 8.9 DL=0.12

S2 - T2 Side room 6.6 DL=0.12

U2 - V2 Crack in floor 12 DL=0.12

W2 - X2 Basement three 12 DL=0.12

Y2 - Z2 Sewer drain pipe 11 DL=0.12

A3 - B3 Base of J plug west side 11 DL=0.12

C3 - D3 Base of depressurization line two 12 DL=0.12

E3 - F3 Inside depressurization line two 3.8 DL=0.12

G3 - H3 J plug east side 10 DL=0.12

I3 - J3 Inside depressurization line three 5.7 DL=0.12

K3 - L3 Crack in wall between basement two and three 4.0 DL=0.12

M3 - N3 Top of wall between basement two and three 4.9 DL=0.12

Q3 - R3 Post-exit ambient DL=0.14 DL=0.12

S3 - T3 30 mL/min spike 7.1 6.7




AB

CD EF

GHIJ

KLMN

OPQ

RSTUVW

XYZ

A1B1C1

D1E1F1G1

H1I1J1K1L1

M1N1O1P1Q1R1S1

T1U1V1W1

X1Y1Z1A2B2C2

D2E2F2G2

H2I2J2K2L2

M2N2O2P2Q2R2

S2T2U2V2

W2X2Y2Z2A3

B3C3D3

E3F3G3

H3I3J3

K3L3M3

N3O3P3

Q3R3

S3T3

0

25

50

75

100

125

150

0 25 50 75 100 125

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

AB

CD EF

GHIJ

KLMN

OPQ

RSTUVW

XYZ

A1B1C1

D1E1F1G1

H1I1J1K1L1

M1N1O1P1Q1R1S1

T1U1V1W1

X1Y1Z1A2B2C2

D2E2F2G2

H2I2J2K2L2

M2N2O2P2Q2R2

S2T2U2V2

W2X2Y2Z2A3

B3C3D3

E3F3G3

H3I3J3

K3L3M3

N3O3P3

Q3R3

S3T3

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

6.0

0 25 50 75 100 125

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 10f








D - E Hallway 12 DL=0.66

F - G Common area 78 DL=0.66

H - I Office one 93 0.68J

J - K Copy room one 110 0.84J

L - M Bathroom one 100 0.74J

N - O Floor drain one 100 0.74J

P - Q Conference room 87 0.67J

R - S Elevator shaft base of door 76 DL=0.66

T - U Bathroom two 95 0.73J

V - W Floor drain two 97 0.71J

X - Y Rear entryway 62 DL=0.66

A1 - B1 Second floor landing 48 DL=0.66

C1 - D1 Office two 34 DL=0.66

E1 - F1 Office three 31 DL=0.66

G1 - H1 Office four 31 DL=0.66

I1 - J1 Office five 28 DL=0.66

K1 - L1 Office six 28 DL=0.66

M1 - N1 Office seven 28 DL=0.66

O1 - P1 Office eight 28 DL=0.66

Q1 - R1 Copy room two 28 DL=0.66

S1 - T1 File room 31 DL=0.66

U1 - V1 Reception area 27 DL=0.66

Y1 - Z1 Basement one 48 DL=0.66

A2 - B2 Floor drain three 55 DL=0.66

C2 - D2 Floor drain four 53 DL=0.66

E2 - F2 Depressurization line one 51 DL=0.66

G2 - H2 Vapor barrier 29 DL=0.66

I2 - J2 Mini vent 14 DL=0.66




Figure 10f (continued)







K2 - L2 Break in separation wall 46 DL=0.66

M2 - N2 Top of separation wall 47 DL=0.66

O2 - P2 Bottom of separation wall 47 DL=0.66

Q2 - R2 Basement two 61 DL=0.66

S2 - T2 Side room 45 DL=0.66

U2 - V2 Crack in floor 83 DL=0.66

W2 - X2 Basement three 80 DL=0.66

Y2 - Z2 Sewer drain pipe 77 DL=0.66

A3 - B3 Base of J plug west side 74 DL=0.66

C3 - D3 Base of depressurization line two 78 DL=0.66

E3 - F3 Inside depressurization line two 26 DL=0.66

G3 - H3 J plug east side 68 DL=0.66

I3 - J3 Inside depressurization line three 38 DL=0.66

K3 - L3 Crack in wall between basement two and three 27 DL=0.66

M3 - N3 Top of wall between basement two and three 34 DL=0.66

Q3 - R3 Post-exit ambient DL=0.92 DL=0.66

S3 - T3 30 mL/min spike 48 36





Figure 11b








D 5.9 563 Start of breezeway one

E 6.9 660 End of breezeway one

F 7.2 682 Start of the stairwell

G 8.2 777 End of the stairwell

H 8.7 825 Start of the base of elevator door

I 9.7 926 End of the base of elevator door

J 10.0 953 Start of the main hallway

K 10.8 1025 End of the main hallway

L 11.7 1113 Start of breezeway two

M 12.7 1210 End of breezeway two

N 14.0 1331 Exiting the unit

O 15.0 1432 Start of electrical room one

P 16.2 1540 End of electrical room one

Q 16.5 1567 Start of base of sampling port one

R 17.5 1669 End of base of sampling port one

S 17.9 1705 Start of open sampling port one

T 18.8 1794 End of open sampling port one

U 19.1 1816 Exiting the electrical room one

V 26.3 2505 Ambient location

W 29.4 2800 Entering the electrical room two

X 29.6 2822 Start of electrical room two

Y 30.8 2933 End of electrical room two

Z 31.1 2965 Start of the floor drain

A1 32.1 3057 End of the floor drain

B1 32.3 3077 Start of base of sampling port two

C1 33.4 3177 End of base of sampling port two

D1 33.9 3230 Exiting the electrical room two







A B CD

EF

GH

IJ

K L M N O PQ

RS

TU

V WX

YZ

A1B1

C1D1

E1F1 G1H1

0

25

50

75

100

125

0 5 10 15 20 25 30 35 40

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B CD

EF

GH

IJ

K L M N O PQ

RS

TU

V WX

YZ

A1B1

C1D1

E1F1 G1H1

0.00

0.25

0.50

0.75

1.00

1.25

1.50

0 5 10 15 20 25 30 35 40

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 11d








D - E Breezeway one 0.17J DL=0.12

F - G Stairwell DL=0.14 DL=0.12

H - I Base of elevator door 0.19J DL=0.12

J - K Main hallway 0.21J DL=0.12

L - M Breezeway two 0.22J DL=0.12

O - P Electrical room one DL=0.14 DL=0.12

Q - R Base of sampling port one DL=0.14 DL=0.12

S - T Open sampling port one 45E 0.32J

X - Y Electrical room two DL=0.14 DL=0.12

Z - A1 Floor drain DL=0.14 DL=0.12

B1 - C1 Base of sampling port two DL=0.14 DL=0.12


G1 - H1 30 mL/min spike 6.6 6.4






A B CD

EF

GH

IJ

K L M N O PQ

RS

TU

V WX

YZ

A1B1

C1D1

E1F1 G1H1

0

100

200

300

400

500

600

700

800

0 5 10 15 20 25 30 35 40

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD

EF

GH

IJ

K L M N O PQ

RS

TU

V WX

YZ

A1B1

C1D1

E1 F1 G1H1

0

1

2

3

4

5

6

7

0 5 10 15 20 25 30 35 40

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 11f








D - E Breezeway one 1.2J DL=0.66

F - G Stairwell DL=0.92 DL=0.66

H - I Base of elevator door 1.3J DL=0.66

J - K Main hallway 1.4J DL=0.66

L - M Breezeway two 1.5J DL=0.66

O - P Electrical room one DL=0.92 DL=0.66

Q - R Base of sampling port one DL=0.92 DL=0.66

S - T Open sampling port one 300E 1.7J

X - Y Electrical room two DL=0.92 DL=0.66

Z - A1 Floor drain DL=0.92 DL=0.66

B1 - C1 Base of sampling port two DL=0.92 DL=0.66









Figure 12b








D 6.5 620 Start of the store

E 7.5 715 End of the store

F 8.1 772 Start of the salon

G 9.1 869 End of the salon

H 10.8 1025 Start of the rear salon

I 11.8 1128 End of the rear salon



L 14.9 1420 Start of the storage room

M 15.9 1515 End of the storage room

N 17.3 1643 Exiting the unit

O 18.6 1767 Start of the post-exit ambient

P 19.6 1865 End of the post-exit ambient

Q 21.2 2015 Start of 30 mL/min spike

R 22.2 2111 End of 30 mL/min spike



A B C D E F G H I J K L M N O P Q R

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5

QL

DL


Un

its i

n p

pb

v

Time in minutes


0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 12d








D - E Store DL=0.14 DL=0.12

F - G Salon DL=0.14 DL=0.12

H - I Rear salon DL=0.14 DL=0.12

J - K Bathroom DL=0.14 DL=0.12

L - M Storage room DL=0.14 DL=0.12

O - P Post-exit ambient DL=0.14 DL=0.12

Q - R 30 mL/min spike 6.5 6.5





0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

6.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

6.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 12f








D - E Store DL=0.92 DL=0.66

F - G Salon DL=0.92 DL=0.66

H - I Rear salon DL=0.92 DL=0.66


L - M Storage room DL=0.92 DL=0.66

O - P Post-exit ambient DL=0.92 DL=0.66

Q - R 30 mL/min spike 44 35



Figure 13a Unit 1 Survey Two Floor Plan , 64MSMS00131


Figure 13b








D 5.0 477 Start of the breezeway

E 6.0 574 End of the breezeway

F 6.4 606 Start of bathroom one

G 7.4 703 End of bathroom one

H 7.9 752 Start of bathroom two

I 8.9 847 End of bathroom two

J 9.5 902 Start of the east side of church

K 10.6 1006 End of the east side of church

L 10.9 1040 Start of the floor depression

M 12.1 1151 End of the floor depression

N 12.7 1205 Start of office one

O 13.7 1301 End of office one

P 14.1 1339 Start of the raised pulpit

Q 15.1 1437 End of the raised pulpit

R 15.6 1489 Start of office two

S 17.1 1624 End of office two

T 17.8 1692 Start of the west side of church

U 18.8 1794 End of the west side of church

V 19.5 1859 Start of the furnace room

W 20.5 1954 End of the furnace room

X 21.1 2008 Exiting the unit

Y 22.1 2107 Start of the post-exit ambient

Z 23.5 2237 End of the post-exit ambient

A1 25.2 2400 Start of 30 mL/min spike

B1 26.2 2496 End of 30 mL/min spike



A B CD EF

GH I J KL

MN

OP

QR S T U V WX

Y Z A1 B1

0.00

0.25

0.50

0.75

1.00

1.25

1.50

1.75

2.00

2.25

2.50

0 5 10 15 20 25

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B CD EF

GH I J KL

MN

OP

QR S T U V WX

Y Z A1 B1

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0 5 10 15 20 25

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 13d








D - E Breezeway DL=0.12 DL=0.070

F - G Bathroom one 0.12J DL=0.070

H - I Bathroom two 0.33J DL=0.070

J - K East side of church 0.75 DL=0.070

L - M Floor depression 0.88 DL=0.070

N - O Office one 0.79 DL=0.070

P - Q Raised pulpit 0.86 DL=0.070

R - S Office two 1.0 DL=0.070

T - U West side of church 0.82 DL=0.070

V - W Furnace room 0.82 DL=0.070

Y - Z Post-exit ambient DL=0.12 DL=0.070

A1 - B1 30 mL/min spike 6.6 6.3





A B CD EF

GH I J KL

MN

OP

QR S T U V WX

Y Z A1 B1

0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

0 5 10 15 20 25

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD EF

GH I J KL

MN

OP

QR S T U V WX

Y Z A1 B1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0 5 10 15 20 25

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 13f








D - E Breezeway DL=0.83 DL=0.37

F - G Bathroom one 0.84J DL=0.37

H - I Bathroom two 2.2J DL=0.37

J - K East side of church 5.1 DL=0.37

L - M Floor depression 6.0 DL=0.37

N - O Office one 5.4 DL=0.37

P - Q Raised pulpit 5.8 DL=0.37

R - S Office two 6.9 DL=0.37

T - U West side of church 5.6 DL=0.37

V - W Furnace room 5.6 DL=0.37

Y - Z Post-exit ambient DL=0.83 DL=0.37

A1 - B1 30 mL/min spike 45 34




Figure 14a Unit 12 Survey One Foor Plan, 64MSMS00132


Figure 14b








D 4.8 458 Start of the foyer

E 5.8 557 End of the foyer

F 6.8 647 Start of the waiting area

G 7.9 750 End of the waiting area

H 9.1 869 Start of the north side of church

I 10.7 1015 End of the north side of church

J 11.1 1055 Start of the south side of church

K 12.1 1151 End of the south side of church

L 12.6 1201 Start of the raised pulpit

M 13.6 1297 End of the raised pulpit

N 14.4 1370 Start of the first lady's office

O 15.5 1474 End of the first lady's office

P 16.1 1532 Start of closet one

Q 17.1 1627 End of closet one

R 18.8 1791 Start of the pastor's office

S 20.1 1913 End of the pastor's office

T 20.4 1946 Start of closet two

U 21.4 2041 End of closet two

V 22.9 2181 Start of the waiting area baseboard

W 26.8 2549 End of the waiting area baseboard

X 27.4 2611 Entering the basement

Y 28.3 2695 Start of bathroom one

Z 29.3 2793 End of bathroom one

A1 29.7 2830 Start of the pipe through floor

B1 30.8 2928 End of the pipe through floor

C1 31.2 2971 Start of bathroom two

D1 32.2 3070 End of bathroom two

E1 32.6 3108 Start of the waste pipe through the floor

F1 33.7 3208 End of the waste pipe through the floor

G1 34.4 3271 Start of the supply room

H1 36.2 3442 End of the supply room







I1 36.6 3480 Start of the cleanout

J1 37.8 3596 End of the cleanout

K1 40.5 3860 Start of the prayer room

L1 41.7 3974 End of the prayer room

M1 43.2 4117 Start of the kitchen

N1 44.4 4224 End of the kitchen

O1 45.1 4291 Start of the classroom

P1 46.4 4413 End of the classroom

Q1 47.1 4480 Start of the office

R1 48.1 4581 End of the office

S1 50.2 4778 Start of the boiler room

T1 51.2 4875 End of the boiler room

U1 51.6 4910 Start of the sub-slab port

V1 52.6 5008 End of the sub-slab port

W1 53.2 5065 Start of the concreted sump

X1 54.2 5162 End of the concreted sump

Y1 55.9 5325 Start of the classroom

Z1 56.7 5397 End of the classroom

A2 57.6 5479 Start of the kitchen

B2 59.2 5636 End of the kitchen

C2 59.5 5663 Start of the gas line through the floor

D2 61.0 5805 End of the gas line through the floor

E2 61.5 5851 Start of the water drain

F2 62.9 5984 End of the water drain

G2 63.5 6044 Start of abandoned water line through the floor

H2 64.7 6161 End of abandoned water line through the floor

I2 65.3 6215 Start of the water line through wall

J2 66.6 6339 End of the water line through wall

K2 67.8 6450 Start of the sink cabinet

L2 68.9 6561 End of the sink cabinet

M2 73.9 7039 Start of the supply room

N2 75.1 7150 End of the supply room

O2 76.9 7316 Exiting the basement








Q2 78.3 7458 Start of the drain pipe

R2 79.6 7573 End of the drain pipe

S2 80.4 7650 Start of the storage area

T2 81.3 7742 End of the storage area

U2 83.4 7938 Start of the post-exit ambient

V2 84.4 8035 End of the post-exit ambient

W2 86.8 8267 Start of 30 mL/min spike

X2 88.1 8390 End of 30 mL/min spike



AB

CD E

FG

HI

JKL M

NOPQ

RS

TU

V WX Y

ZA1B1C1D1E1

F1G1

H1I1J1

K1L1

M1N1O1

P1Q1R1

S1T1U1

V1W1X1

Y1Z1A2

B2C2D2E2

F2G2H2

I2J2

K2L2

M2N2 O2

P2Q2

R2S2T2

U2V2

W2X2

0

250

500

750

1000

1250

0 10 20 30 40 50 60 70 80 90

QLDL


Un

its i

n p

pb

v

Time in minutes

AB

CD E

FG

HIJ

KL

MN O

PQ

RS

TU

V WX Y

ZA1B1C1D1E1

F1G1

H1I1J1

K1L1

M1N1O1

P1Q1R1

S1T1U1

V1W1X1

Y1Z1A2

B2C2D2E2

F2G2H2

I2J2

K2L2

M2N2 O2

P2Q2

R2S2T2

U2V2

W2X2

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50 60 70 80 90

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 14d








D - E Foyer DL=0.12 DL=0.070

F - G Waiting area 0.88 DL=0.070

H - I North side of church DL=0.12 DL=0.070

J - K South side of church DL=0.12 DL=0.070

L - M Raised pulpit DL=0.12 DL=0.070

N - O First Lady's office 0.29J DL=0.070

P - Q Closet one 0.31J DL=0.070

R - S Pastor's office DL=0.12 DL=0.070

T - U Closet two DL=0.12 DL=0.070

V - W Waiting area baseboard 0.64 DL=0.070

Y - Z Bathroom one 0.44 DL=0.070

A1 - B1 Pipe through floor 0.80 DL=0.070

C1 - D1 Bathroom two 0.31J DL=0.070

E1 - F1 Waste pipe through the floor 0.65 DL=0.070

G1 - H1 Supply room 4.0 0.083J

I1 - J1 Cleanout 100E 0.47

K1 - L1 Prayer room 1.9 DL=0.070

M1 - N1 Kitchen 5.8 0.077J

O1 - P1 Classroom 2.8 DL=0.070

Q1 - R1 Office 1.8 DL=0.070

S1 - T1 Boiler room 1.2 DL=0.070

U1 - V1 Sub-slab port 2.4 DL=0.070

W1 - X1 Concreted sump 1.5 DL=0.070

Y1 - Z1 Classroom 2.5 DL=0.070

A2 - B2 Kitchen 5.3 0.082J

C2 - D2 Gas line through the floor 5.8 0.078J

E2 - F2 Water drain 9.6 0.090J

G2 - H2 Abandoned water line through the floor 5.9 0.081J





Figure 14d (continued)







I2 - J2 Water line through wall 6.5 0.089J

K2 - L2 Sink cabinet 4.1 DL=0.070

M2 - N2 Supply room 2.9 0.073J

Q2 - R2 Drain pipe 11 DL=0.070

S2 - T2 Storage area 0.35J DL=0.070

U2 - V2 Post-exit ambient DL=0.12 DL=0.070

W2 - X2 30 mL/min spike 5.6 5.4





AB

CD E

FG

HI

JKL M

NOPQ

RS

TU

V WX Y

ZA1B1C1D1E1

F1G1

H1I1J1

K1L1

M1N1O1

P1Q1R1

S1T1U1

V1W1X1

Y1Z1A2

B2C2D2E2

F2G2H2

I2J2

K2L2

M2N2 O2

P2Q2

R2S2T2

U2V2

W2X2

0

1

2

3

4

5

6

7

8

9

0 10 20 30 40 50 60 70 80 90

QLDL


Un

its i

n µ

g/m

3 (

Th

ou

san

ds)

Time in minutes

AB

CD E

FG

HI

JKL M

NOPQ

RS

TU

V WX Y

ZA1B1C1D1E1

F1G1

H1I1J1

K1L1

M1N1O1

P1Q1R1

S1T1U1

V1W1X1

Y1Z1A2

B2C2D2E2

F2G2H2

I2J2

K2L2

M2N2 O2

P2Q2

R2S2T2

U2V2

W2X2

0

5

10

15

20

25

30

35

40

45

0 10 20 30 40 50 60 70 80 90

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 14f








D - E Foyer DL=0.83 DL=0.37

F - G Waiting area 5.9 DL=0.37

H - I North side of church DL=0.83 DL=0.37

J - K South side of church DL=0.83 DL=0.37

L - M Raised pulpit DL=0.83 DL=0.37

N - O First Lady's office 2.0J DL=0.37

P - Q Closet one 2.1J DL=0.37

R - S Pastor's office DL=0.83 DL=0.37

T - U Closet two DL=0.83 DL=0.37

V - W Waiting area baseboard 4.3 DL=0.37

Y - Z Bathroom one 3.0 DL=0.37

A1 - B1 Pipe through floor 5.4 DL=0.37

C1 - D1 Bathroom two 2.1J DL=0.37

E1 - F1 Waste pipe through the floor 4.4 DL=0.37

G1 - H1 Supply room 27 0.45J

I1 - J1 Cleanout 680E 2.5

K1 - L1 Prayer room 13 DL=0.37

M1 - N1 Kitchen 40 0.41J

O1 - P1 Classroom 19 DL=0.37

Q1 - R1 Office 12 DL=0.37

S1 - T1 Boiler room 7.8 DL=0.37

U1 - V1 Sub-slab port 16 DL=0.37

W1 - X1 Concreted sump 10 DL=0.37

Y1 - Z1 Classroom 17 DL=0.37

A2 - B2 Kitchen 36 0.44J

C2 - D2 Gas line through the floor 40 0.42J

E2 - F2 Water drain 65 0.49J

G2 - H2 Abandoned water line through the floor 40 0.43J





Figure 14f (continued)







I2 - J2 Water line through wall 44 0.48J

K2 - L2 Sink cabinet 28 DL=0.37

M2 - N2 Supply room 20 0.39J

Q2 - R2 Drain pipe 78 DL=0.37

S2 - T2 Storage area 2.4J DL=0.37

U2 - V2 Post-exit ambient DL=0.83 DL=0.37

W2 - X2 30 mL/min spike 38 29






Figure 15b








D 4.7 445 Start of the salon

E 5.7 542 End of the salon

F 6.0 570 Start of the bathroom

G 7.0 669 End of the bathroom

H 7.3 696 Start of the spa room

I 8.3 789 End of the spa room

J 8.6 818 Start of the storage room

K 9.7 926 End of the storage room

L 10.3 983 Start of the break room

M 11.3 1080 End of the break room

N 11.6 1105 Start of the furnace room

O 12.6 1202 End of the furnace room




S 19.4 1843 Start of the 30 mL/min spike

T 20.2 1928 End of the 30 mL/min spike



A B C D EF

GH

I J K L MN

O P Q R S T

0.00

0.25

0.50

0.75

1.00

1.25

1.50

1.75

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B C D EF

GH

I J K L MN

O P Q R S T

0.00

0.25

0.50

0.75

1.00

1.25

1.50

1.75

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 15d








D - E Salon 0.13J DL=0.23

F - G Bathroom DL=0.12 DL=0.23

H - I Spa room 0.13J DL=0.23

J - K Storage room 0.13J 0.24J

L - M Break room DL=0.12 DL=0.23

N - O Furnace room DL=0.12 DL=0.23







A B C D EF

GH

I J K L MN

O P Q R S T

0

1

2

3

4

5

6

7

8

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B C D EF

GH

I J K L MN

O P Q R S T

0

1

2

3

4

5

6

7

8

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 15f








D - E Salon 0.91J DL=1.3

F - G Bathroom DL=0.84 DL=1.3

H - I Spa room 0.88J DL=1.3

J - K Storage room 0.91J 1.3J

L - M Break room DL=0.84 DL=1.3

N - O Furnace room DL=0.84 DL=1.3








Figure 16b








D 4.2 405 Start of office one

E 5.3 501 End of office one

F 5.5 524 Start of office two

G 6.5 620 End of office two

H 6.9 656 Start of office three

I 8.1 769 End of office three

J 8.3 794 Start of the furnace room

K 9.3 889 End of the furnace room

L 9.8 932 Start of the bathroom

M 10.8 1031 End of the bathroom

N 11.1 1053 Start of the seam on the floor

O 12.1 1149 End of the seam on the floor








A B C D EF

GH I J K L MN

O P Q R S T

0.00

0.25

0.50

0.75

1.00

1.25

1.50

1.75

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B C D EF

GH I J K L MN

O P Q R S T

0.00

0.25

0.50

0.75

1.00

1.25

1.50

1.75

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 16d








D - E Office one 0.20J DL=0.23

F - G Office two 0.19J DL=0.23

H - I Office three 0.21J DL=0.23

J - K Furnace room DL=0.12 DL=0.23

L - M Bathroom 0.19J DL=0.23

N - O Seam on the floor 0.19J DL=0.23

Q – R Post-exit ambient DL=0.12 DL=0.23

S – T 30 mL/min spike 5.6 6.0





A B C D EF

G H I J K L MN

O P Q R S T

0

1

2

3

4

5

6

7

8

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B C D EF

G H I J K L MN

O P Q R S T

0

1

2

3

4

5

6

7

8

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 16f




Detection Limits – DL: 0.84 1.3

Quantitation Limits – QL: 2.8 4.2


A – B Pre-entry ambient DL=0.84 DL=1.3

D – E Office one 1.4J DL=1.3

F – G Office two 1.3J DL=1.3

H – I Office three 1.4J DL=1.3

J – K Furnace room DL=0.84 DL=1.3

L – M Bathroom 1.3J DL=1.3

N – O Seam on the floor 1.3J DL=1.3








Figure 17b










F 9.8 931 Start of the dining room

G 10.8 1028 End of the dining room

H 11.1 1055 Start of bedroom one

I 12.1 1150 End of bedroom one

J 12.3 1175 Start of closet one

K 13.3 1270 End of closet one



N 15.0 1429 Start of the laundry room

O 16.1 1529 End of the laundry room



R 18.2 1734 Start of closet two

S 19.2 1830 End of closet two

T 19.7 1875 Start of the bathroom

U 20.7 1970 End of the bathroom

V 21.2 2022 Start of bedroom three

W 22.2 2118 End of bedroom three


Y 24.2 2306 Entering the basement

Z 24.7 2356 Start of basement room one

A1 25.8 2459 End of basement room one

B1 26.1 2489 Start of basement room two

C1 27.1 2584 End of basement room two

D1 27.5 2622 Start of the crawl space

E1 28.5 2717 End of the crawl space

F1 29.0 2757 Start of the sub-slab port

G1 30.0 2854 End of the sub-slab port

H1 30.8 2936 Start of the pipe through the floor







I1 31.9 3033 End of the pipe through the floor

J1 32.3 3079 Start of the manhole

K1 33.6 3195 End of the manhole

L1 34.2 3257 Start of dirt wall in basement room two

M1 35.2 3352 End of dirt wall in basement room two

N1 36.7 3498 Exiting the basement

O1 38.0 3617 Start of post-exit ambient

P1 39.4 3750 End of post-exit ambient

Q1 43.1 4100 Start of the 30 mL/min spike

R1 44.1 4196 End of the 30 mL/min spike



A B CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX

YZ

A1B1 C1

D1E1F1

G1H1

I1J1 K1

L1M1N1

O1P1 Q1

R1

0

5

10

15

20

25

30

35

40

45

50

0 5 10 15 20 25 30 35 40 45

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX

YZ

A1B1 C1

D1E1F1

G1H1

I1J1 K1

L1M1N1

O1P1 Q1

R1

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0 5 10 15 20 25 30 35 40 45

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 17d








D - E Living room 1.7 DL=0.081

F - G Dining room 1.8 DL=0.081

H - I Bedroom one 1.7 DL=0.081

J - K Closet one 1.6 DL=0.081

L - M Kitchen 1.7 DL=0.081

N - O Laundry room 0.40 DL=0.081

P - Q Bedroom two 1.6 DL=0.081

R - S Closet two 1.4 DL=0.081

T - U Bathroom 1.8 DL=0.081

V - W Bedroom three 1.6 DL=0.081

Z - A1 Room one 3.8 DL=0.081

B1 - C1 Room two 4.2 DL=0.081

D1 - E1 Crawl space 4.9 DL=0.081

F1 - G1 Sub-slab port 3.9 DL=0.081

H1 - I1 Pipe through the floor 7.9 DL=0.081

J1 - K1 Manhole 27 0.17J

L1 - M1 Dirt wall in basement room two 4.5 DL=0.081

O1 - P1 Post-exit ambient 0.12J DL=0.081

Q1 - R1 30 mL/min spike 8.7 9.0





A B CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX

YZ

A1B1 C1

D1E1F1

G1H1

I1J1 K1

L1M1N1

O1P1 Q1

R1

0

50

100

150

200

250

300

0 5 10 15 20 25 30 35 40 45

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX

YZ

A1B1 C1

D1E1F1

G1H1

I1J1 K1

L1M1N1

O1P1 Q1

R1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

6.0

0 5 10 15 20 25 30 35 40 45

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 17f








D - E Living room 11 DL=0.44

F - G Dining room 12 DL=0.44

H - I Bedroom one 12 DL=0.44

J - K Closet one 11 DL=0.44

L - M Kitchen 11 DL=0.44


P - Q Bedroom two 11 DL=0.44


T - U Bathroom 12 DL=0.44

V - W Bedroom three 11 DL=0.44

Z - A1 Room one 25 DL=0.44

B1 - C1 Room two 28 DL=0.44

D1 - E1 Crawl space 33 DL=0.44

F1 - G1 Sub-slab port 26 DL=0.44

H1 - I1 Pipe through the floor 54 DL=0.44

J1 - K1 Manhole 180 0.92J

L1 - M1 Dirt wall in basement room two 31 DL=0.44

O1 - P1 Post-exit ambient 0.83J DL=0.44

Q1 - R1 30 mL/min spike 59 49






Figure 18b










F 8.7 825 Start of the bedroom

G 9.7 920 End of the bedroom



J 11.4 1085 Start of the kitchen

K 12.6 1204 End of the kitchen

L 13.0 1234 Start of screening under the kitchen sink

M 14.1 1339 End of screening under the kitchen sink




Q 16.4 1561 Start of the basement

R 17.4 1656 End of the basement



U 19.2 1832 Start of the crawl space

V 20.3 1929 End of the crawl space

W 20.8 1976 Start of the dry sump

X 21.8 2072 End of the dry sump

Y 22.3 2126 Start of the water line

Z 23.3 2221 End of the water line

A1 23.7 2254 Start of the manhole cover

B1 25.8 2456 Opening the manhole cover

C1 26.6 2529 End of the manhole cover

D1 27.2 2587 Exiting the basement

E1 27.6 2629 Exiting the unit

F1 28.2 2684 Start of the post-exit ambient

G1 29.2 2779 End of the post-exit ambient

H1 31.6 3007 Start of the 30 mL/min spike







I1 32.6 3103 End of the 30 mL/min spike



A B CD

EF

GH

IJ KL

MN

OP Q

RS

TU

VW

XY

ZA1

B1C1

D1E1 F1

G1 H1I1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

0 5 10 15 20 25 30 35

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B CD

EF

GH

IJ KL

MN

OP Q

RS

TU

VW

XY

ZA1

B1C1

D1E1 F1

G1 H1I1

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0 5 10 15 20 25 30 35

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 18d









F - G Bedroom 0.13J 0.094J



L - M Screening under the kitchen sink 0.58 DL=0.081


Q - R Basement 0.90 DL=0.081

S - T Sub-slab port 0.91 DL=0.081

U - V Crawl space 0.80 DL=0.081

W - X Dry sump 1.3 DL=0.081

Y - Z Water line 0.76 DL=0.081

A1 - C1 Manhole cover 1.7 DL=0.081

F1 - G1 Post-exit ambient DL=0.081 DL=0.081

H1 - I1 30 mL/min spike 8.6 9.2





A B CD

EF

GH

IJ KL

MN

OP Q

RS

TU

VW

XY

ZA1

B1C1

D1E1 F1

G1 H1I1

0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

25.0

0 5 10 15 20 25 30 35

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD

EF

GH

IJ KL

MN

OP Q

RS

TU

VW

XY

ZA1

B1C1

D1E1 F1

G1 H1I1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

6.0

0 5 10 15 20 25 30 35

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 18f









F - G Bedroom 0.90J 0.51J



L - M Screening under the kitchen sink 3.9 DL=0.44


Q - R Basement 6.1 DL=0.44

S - T Sub-slab port 6.1 DL=0.44

U - V Crawl space 5.4 DL=0.44

W - X Dry sump 8.8 DL=0.44

Y - Z Water line 5.2 DL=0.44

A1 - C1 Manhole cover 11 DL=0.44

F1 - G1 Post-exit ambient DL=0.55 DL=0.44

H1 - I1 30 mL/min spike 58 49






Figure 19b














J 19.6 1862 Start of closet one

K 20.6 1959 End of closet one



N 22.3 2121 Start of the laundry room

O 23.3 2216 End of the laundry room



R 25.2 2400 Start of closet two

S 26.2 2497 End of closet two

T 26.7 2543 Start of the bathroom

U 27.7 2640 End of the bathroom

V 28.4 2705 Start of bedroom three

W 29.4 2801 End of bedroom three


Y 31.3 2981 Entering the basement

Z 31.7 3019 Start of basement room one

A1 32.7 3114 End of basement room one

B1 33.1 3152 Start of basement room two

C1 34.1 3247 End of basement room two

D1 34.5 3284 Start of the crawl space

E1 35.6 3388 End of the crawl space

F1 36.3 3455 Start of the sub-slab port

G1 37.3 3552 End of the sub-slab port

H1 37.5 3574 Start of the pipe through floor







I1 38.6 3671 End of the pipe through floor

J1 38.8 3695 Start of the manhole

K1 40.1 3815 End of the manhole

L1 42.2 4018 Exiting the basement

M1 44.3 4218 Start of the post-exit ambient

N1 45.3 4314 End of the post-exit ambient

O1 48.9 4652 Start of the 30 mL/min ambient

P1 49.9 4748 End of the 30 mL/min ambient



A B CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX

YZ

A1B1C1

D1E1

F1G1H1

I1J1

K1 L1 M1N1

O1P1

0

1

2

3

4

5

6

7

8

9

10

0 5 10 15 20 25 30 35 40 45 50

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX

YZ

A1B1C1

D1E1

F1G1H1

I1J1

K1 L1 M1N1

O1P1

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0.50

0.55

0.60

0 5 10 15 20 25 30 35 40 45 50

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 19d







A - B Pre--entry ambient DL=0.049 DL=0.053

D - E Living room 2.2 DL=0.053

F - G Dining room 2.2 DL=0.053

H - I Bedroom one 2.3 DL=0.053

J - K Closet one 2.1 DL=0.053

L - M Kitchen 2.2 0.054J


P - Q Bedroom two 2.1 DL=0.053


T - U Bathroom 2.1 0.055J

V - W Bedroom three 2.0 DL=0.053

Z - A1 Basement room one 4.7 0.055J

B1 - C1 Basement room two 3.7 DL=0.053

D1 - E1 Crawl space 4.2 DL=0.053

F1 - G1 Sub-slab port 4.7 DL=0.053

H1 - I1 Pipe through floor 5.6 0.058J

J1 - K1 Manhole 5.8 DL=0.053

M1 - N1 Post-exit ambient 0.080J DL=0.053

O1 - P1 30 mL/min spike 6.9 6.9





A B CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX

YZ

A1B1C1

D1E1

F1G1H1

I1J1

K1 L1 M1N1

O1P1

0

10

20

30

40

50

60

0 5 10 15 20 25 30 35 40 45 50

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD

EF

GH

IJ

KL

MN

OP

QR

ST

UV

WX

YZ

A1B1C1

D1E1

F1G1H1

I1J1

K1 L1 M1N1

O1P1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0 5 10 15 20 25 30 35 40 45 50

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 19f







A - B Pre--entry ambient DL=0.33 DL=0.28

D - E Living room 15 DL=0.28

F - G Dining room 15 DL=0.28

H - I Bedroom one 15 DL=0.28

J - K Closet one 14 DL=0.28

L - M Kitchen 15 0.29J


P - Q Bedroom two 14 DL=0.28

R - S Closet two 12 DL=0.28

T - U Bathroom 14 0.29J

V - W Bedroom three 13 DL=0.28

Z - A1 Basement room one 32 0.30J

B1 - C1 Basement room two 25 DL=0.28

D1 - E1 Crawl space 28 DL=0.28

F1 - G1 Sub-slab port 32 DL=0.28

H1 - I1 Pipe through floor 38 0.31J

J1 - K1 Manhole 39 DL=0.28

M1 - N1 Post-exit ambient 0.54J DL=0.28

O1 - P1 30 mL/min spike 47 37






Figure 20b








D 7.7 736 Start of the foyer

E 8.7 831 End of the foyer

F 9.1 863 Start of the waiting area

G 10.1 958 End of the waiting area

H 10.5 999 Start of the north side of the church

I 11.6 1104 End of the north side of the church

J 11.9 1137 Start of the south side of the church

K 12.9 1232 End of the south side of the church

L 13.4 1272 Start of the raised pulpit

M 14.4 1367 End of the raised pulpit

N 15.3 1454 Start of the first lady's office

O 16.3 1553 End of the first lady's office

P 16.5 1569 Start of closet one

Q 17.5 1666 End of closet one

R 18.0 1713 Start of the pastor's office

S 19.0 1810 End of the pastor's office

T 19.2 1829 Start of closet two

U 20.2 1926 End of closet two


W 21.8 2073 Start of bathroom one

X 22.8 2168 End of bathroom one

Y 23.0 2192 Start of the pipe through the floor

Z 24.1 2294 End of the pipe through the floor

A1 24.5 2335 Start of bathroom two

B1 25.5 2430 End of bathroom two

C1 25.7 2449 Start of the waste pipe through the floor

D1 26.7 2546 End of the waste pipe through the floor

E1 27.0 2575 Start of the supply room

F1 28.1 2671 End of the supply room

G1 28.5 2709 Start of the cleanout

H1 29.8 2838 End of the cleanout







I1 30.4 2895 Start of the opened cleanout

J1 32.4 3082 End of the opened cleanout

K1 33.2 3157 Start of the prayer room

L1 34.2 3252 End of the prayer room

M1 34.7 3300 Start of the kitchen

N1 35.7 3403 End of the kitchen

O1 36.1 3438 Start of the floor drain

P1 37.2 3542 End of the floor drain

Q1 37.4 3563 Start of the abandoned water line

R1 38.4 3657 End of the abandoned water line

S1 39.7 3783 Start of the pantry

T1 40.7 3879 End of the pantry

U1 41.0 3907 Start of the office

V1 42.1 4010 End of the office

W1 42.5 4047 Start of the classroom

X1 43.6 4150 End of the classroom

Y1 44.2 4209 Start of the boiler room

Z1 45.2 4305 End of the boiler room

A2 45.4 4320 Start of the sub-slab port

B2 46.4 4420 End of the sub-slab port



E2 49.7 4729 Start of the outdoor drain

F2 50.9 4845 End of the outdoor drain

G2 51.2 4870 Start of the storage area

H2 52.2 4967 End of the storage area

I2 53.4 5085 Start of the post-exit ambient

J2 54.4 5182 End of the post-exit ambient

K2 56.2 5350 Start of the 30 mL/min spike

L2 57.2 5441 End of the 30 mL/min spike



AB CD

EF

GH

IJ

KL

MN

OP

QR

ST

UVW

XY

ZA1

B1C1D1E1

F1G1

H1I1

J1K1

L1M1

N1O1P1Q1

R1S1

T1U1V1

W1X1Y1

Z1A2B2

C2D2

E2F2G2

H2I2

J2 K2L2

0

1

2

3

4

5

6

7

8

9

10

0 5 10 15 20 25 30 35 40 45 50 55

QL

DL


Un

its i

n p

pb

v

Time in minutes

AB

CD

EF

GH

IJ

KL

MN

OP

QR

ST

UVW

XY

ZA1

B1C1D1E1

F1G1

H1I1

J1K1

L1M1

N1O1P1Q1

R1S1

T1U1V1

W1X1Y1

Z1A2B2

C2D2

E2F2G2

H2I2

J2 K2L2

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0.50

0.55

0.60

0 5 10 15 20 25 30 35 40 45 50 55

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 20d








D - E Foyer 0.15J DL=0.053

F - G Waiting area 0.16J DL=0.053

H - I North side of church 0.11J DL=0.053

J - K South side of church 0.11J DL=0.053

L - M Raised pulpit 0.11J DL=0.053

N - O First Lady's office 0.40 DL=0.053

P - Q Closet one 0.40 DL=0.053

R - S Pastor's office 0.26 DL=0.053

T - U Closet two 0.86 DL=0.053

W - X Bathroom one 0.64 DL=0.053

Y - Z Pipe through the floor 0.90 0.065J

A1 - B1 Bathroom two 0.47 DL=0.053

C1 - D1 Waste pipe through the floor 0.71 DL=0.053

E1 - F1 Supply room 0.59 DL=0.053

G1 - H1 Cleanout 3.5 0.061J

I1 - J1 Opened cleanout 1.7 DL=0.053


M1 - N1 Kitchen 0.30 DL=0.053

O1 - P1 Floor drain 1.3 DL=0.053

Q1 - R1 Abandoned water line 1.7 DL=0.053

S1 - T1 Pantry 0.31 DL=0.053

U1 - V1 Office 0.37 DL=0.053

W1 - X1 Classroom 0.42 DL=0.053

Y1 - Z1 Boiler room 1.2 DL=0.053

A2 - B2 Sub-slab port 1.8 0.054J

E2 - F2 Outdoor drain 4.5 DL=0.053

G2 - H2 Storage area 0.21 DL=0.053

I2 - J2 Post-exit ambient DL=0.049 DL=0.053

K2 - L2 30 mL/min spike 7.0 7.1





AB CD

EF

GH

IJ

KL

MN

OP

QR

ST

UVW

XY

ZA1

B1C1D1E1

F1G1

H1I1

J1K1

L1M1

N1O1P1Q1

R1S1

T1U1V1

W1X1Y1

Z1A2B2

C2D2

E2F2G2

H2I2

J2 K2L2

0

10

20

30

40

50

60

70

0 5 10 15 20 25 30 35 40 45 50 55

QL

DL


Un

its i

n p

pb

v

Time in minutes

AB

CD

EF

GH

IJ

KL

MN

OP

QR

ST

UVW

XY

ZA1

B1C1D1E1

F1G1

H1I1

J1K1

L1M1

N1O1P1Q1

R1S1

T1U1V1

W1X1Y1

Z1A2B2

C2D2

E2F2G2

H2I2

J2 K2L2

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0 5 10 15 20 25 30 35 40 45 50 55

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 20f








D - E Foyer 1.0J DL=0.28

F - G Waiting area 1.1J DL=0.28

H - I North side of church 0.77J DL=0.28

J - K South side of church 0.77J DL=0.28

L - M Raised pulpit 0.76J DL=0.28

N - O First Lady's office 2.7 DL=0.28

P - Q Closet one 2.7 DL=0.28

R - S pastor's office 1.8 DL=0.28

T - U Closet two 5.8 DL=0.28

W - X Bathroom one 4.3 DL=0.28

Y - Z Pipe through the floor 6.1 0.35J

A1 - B1 Bathroom two 3.2 DL=0.28

C1 - D1 Waste pipe through the floor 4.8 DL=0.28

E1 - F1 Supply room 4.0 DL=0.28

G1 - H1 Cleanout 24 0.33J

I1 - J1 Opened cleanout 12 DL=0.28


M1 - N1 Kitchen 2.0 DL=0.28

O1 - P1 Floor drain 9.0 DL=0.28

Q1 - R1 Abandoned water line 11 DL=0.28

S1 - T1 Pantry 2.1 DL=0.28

U1 - V1 Office 2.5 DL=0.28

W1 - X1 Classroom 2.9 DL=0.28

Y1 - Z1 Boiler room 8.2 DL=0.28

A2 - B2 Sub-slab port 13 0.29J

E2 - F2 Outdoor drain 31 DL=0.28

G2 - H2 Storage area 1.5 DL=0.28


K2 - L2 30 mL/min spike 47 38




Figure 21a Unit 7 Survey Three Floor Plan, 64MSMS00150


Figure 21b



Title: Unit 7 Survey Three







F 10.2 967 Start of the bedroom

G 11.6 1106 End of the bedroom

H 11.8 1126 Start of closet one

I 12.8 1220 End of closet one







P 17.2 1642 Start of closet two

Q 18.3 1739 End of closet two

R 18.7 1784 Start of bedroom three

S 19.7 1878 End of bedroom three

T 20.0 1900 Start of the kitchen

U 21.0 1997 End of the kitchen


W 22.1 2108 Start of the basement

X 23.2 2205 End of the basement

Y 23.5 2240 Start of the crawl space

Z 24.5 2333 End of the crawl space

A1 25.0 2378 Start of the sub-slab port

B1 26.0 2478 End of the sub-slab port

C1 26.3 2500 Start of floor drain one

D1 27.3 2597 End of floor drain one

E1 28.1 2678 Start of floor drain two

F1 29.1 2774 End of floor drain two

G1 30.1 2870 Exiting the basement

H1 30.9 2946 Exiting the unit







I1 32.6 3106 Start of the post-exit ambient

J1 33.7 3204 End of the post-exit ambient

K1 36.3 3457 Start of the 30 mL/min spike

L1 37.3 3552 End of the 30 mL/min spike


Figure 21c Unit 7 Survey Three in ppbv for Tetrachloroethene and Trichloroethene

A B CD

EF

GH

I J KL

MN

OP

QR

ST

UV

W XY

ZA1

B1C1

D1E1

F1G1H1

I1 J1 K1L1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0 5 10 15 20 25 30 35

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B CD

EF

GH

I J KL

MN

OP

QR

ST

UV

W XY

ZA1

B1C1

D1E1

F1G1H1

I1 J1 K1L1

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0.50

0.55

0.60

0 5 10 15 20 25 30 35

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 21d

TAGA Target Compound Summary in ppbv for Unit 7 Survey Three








F - G Bedroom one DL=0.049 DL=0.053

H - I Closet one DL=0.049 DL=0.053



N - O Bedroom two DL=0.049 DL=0.053




W - X Basement 0.94 DL=0.053


A1 - B1 Sub-slab port 1.0 DL=0.053

C1 - D1 Floor drain one 1.5 DL=0.053

E1 - F1 Floor drain two 1.0 DL=0.053


K1 - L1 30 mL/min spike 6.7 6.7




Figure 21e Unit 7 Survey Three in µg/m3 for Tetrachloroethene and Trichloroethene

A B CD

EF

GH

I J KL

MN

OP

QR

ST

UV

W XY

ZA1

B1C1

D1E1

F1G1H1

I1 J1 K1L1

0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

20.0

22.5

25.0

0 5 10 15 20 25 30 35

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD

EF

GH

I J KL

MN

OP

QR

ST

UV

W XY

ZA1

B1C1

D1E1

F1G1H1

I1 J1 K1L1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0 5 10 15 20 25 30 35

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 21f

TAGA Target Compound Summary in µg/m3 for Unit 7 Survey Three








F - G Bedroom one DL=0.33 DL=0.28

H - I Closet one DL=0.33 DL=0.28



N - O Bedroom two DL=0.33 DL=0.28




W - X Basement 6.4 DL=0.28

Y - Z Crawl space 12 DL=0.28

A1 - B1 Sub-slab port 7.1 DL=0.28

C1 - D1 Floor drain one 10 DL=0.28

E1 - F1 Floor drain two 6.8 DL=0.28


K1 - L1 30 mL/min spike 46 36




Figure 22a Unit 16 Survey Three Floor Plan, 64MSMS00156


Figure 22b







C 5.4 512 Entering the basement

D 6.4 612 Start of basement room one

E 7.4 709 End of basement room one

F 7.9 752 Start of basement room two

G 8.9 850 End of basement room two

H 9.1 863 Start of the crawl space

I 10.1 960 End of the crawl space

J 10.5 999 Start of the sub-slab port

K 11.5 1093 End of the sub-slab port

L 11.8 1121 Start of the pipe through floor

M 12.8 1215 End of the pipe through floor

N 13.1 1251 Start of the manhole

O 14.6 1388 End of the manhole

P 15.3 1454 Exiting the basement






Figure 22c Unit 16 Survey Three in ppbv for Tetrachloroethene and Trichloroethene

A B C D E F GH

I J KL

MN

O P Q R S T

0.0

2.5

5.0

7.5

10.0

12.5

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B C D E F GH

I J KL

MN

O P Q R S T

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 22d

TAGA Target Compound Summary in ppbv for Unit 16 Survey Three







D - E Basement room one 3.2 DL=0.11

F - G Basement room two 3.2 DL=0.11

H - I Crawl space 2.6 DL=0.11

J - K Sub-slab port 3.4 DL=0.11

L - M Pipe through floor 3.6 DL=0.11

N - O Manhole 7.0 DL=0.11





Figure 22e Unit 16 Survey Three in µg/m3 for Tetrachloroethene and Trichloroethene

A B C D E F GH

I J KL

MN

O P Q R S T

0

10

20

30

40

50

60

70

80

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B C D E F GH

I J KL

MN

O P Q R S T

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

6.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 22f

TAGA Target Compound Summary in µg/m3 for Unit 16 Survey Three







D - E Basement room one 22 DL=0.58

F - G Basement room two 22 DL=0.58

H - I Crawl space 18 DL=0.58

J - K Sub-slab port 23 DL=0.58

L - M Pipe through floor 24 DL=0.58

N - O Manhole 48 DL=0.58







Figure 23b


File: 64MSMS00161 Acquired on 01 July 2016 at 07:49:37



















Q 16.6 1579 Start of the basement

R 17.6 1675 End of the basement



U 20.1 1917 Start of the drain

V 21.1 2012 End of the drain

W 21.7 2070 Start of bedroom three

X 22.7 2166 End of Bedroom three

Y 24.1 2294 Exiting the basement

Z 25.2 2399 Exiting the unit

A1 26.7 2540 Start of the post-exit ambient

B1 27.9 2659 End of the post-exit ambient

C1 30.1 2864 Start of the 30 mL/min spike

D1 31.1 2961 End of the 30 mL/min spike



A B CD

EF GH

IJ KL

MN

OP

Q R S T U VW X Y Z A1 B1 C1 D1

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0 5 10 15 20 25 30

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B CD

EF GH

IJ KL

MN

OP


0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0 5 10 15 20 25 30

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 23d









F - G Dining room DL=0.11 DL=0.084

H - I Bedroom one DL=0.11 DL=0.084



N - O Bedroom two DL=0.11 0.089J

Q - R Basement 0.17J DL=0.084

S - T Sub-slab port 0.26J DL=0.084

U - V Drain 0.28J DL=0.084

W - X Bedroom three 0.39 DL=0.084

A1 - B1 Post-exit ambient DL=0.11 DL=0.084

C1 - D1 30 mL/min spike 6.4 6.7




Figure 23e Unit 17 Survey in µg/m3 Tetrachloroethene and Trichloroethene

A B CD

EF GH

IJ KL

MN

OP


0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

6.0

0 5 10 15 20 25 30

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD

EF GH

IJ KL

MN

OP


0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

6.0

0 5 10 15 20 25 30

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 23f










H - I Bedroom one DL=0.73 DL=0.45



N - O Bedroom two DL=0.73 0.48J

Q - R Basement 1.2J DL=0.45

S - T Sub-slab port 1.8J DL=0.45

U - V Drain 1.9J DL=0.45

W - X Bedroom three 2.7 DL=0.45


C1 - D1 30 mL/min spike 43 36






Figure 24b







C 31.5 2995 Start of Room 103

D 32.5 3092 End of Room 103

E 34.9 3322 Start of Room 102

F 35.9 3419 End of Room 102

G 36.6 3485 Start of Room 102A

H 37.6 3582 End of Room 102A

I 37.8 3598 Start of drain one

J 38.8 3693 End of drain one

K 39.0 3712 Start of drain two

L 40.0 3806 End of drain two

M 41.7 3973 Start of Room 106

N 42.8 4072 End of Room 106

O 43.0 4092 Start of drain three

P 44.0 4188 End of drain three

Q 45.6 4344 Start of Room 107

R 46.6 4439 End of Room 107

S 49.1 4672 Start of drain four

T 50.1 4772 End of drain four

U 50.4 4796 Start of drain five

V 51.4 4896 End of drain five

W 52.1 4961 Start of the grease trap

X 53.1 5053 End of the grease trap

Y 54.1 5151 Start of the closet in Room 107

Z 55.2 5256 End of the closet in Room 107

A1 56.0 5329 Start of drain six

B1 57.0 5426 End of drain six

C1 58.3 5546 Start of Room 109

D1 59.3 5645 End of Room 109



G1 68.4 6510 Start of the 30 mL/min spike

H1 69.4 6605 End of the 30 mL/min spike



AB

CD

EF

GHI

JK

L MN O

P QR

STU

VW

XY

ZA1

B1C1

D1 E1F1

G1H1

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0 10 20 30 40 50 60 70

QL

DL


Un

its i

n p

pb

v

Time in minutes

AB

CD

EF

GHI

JK

L MN O

P QR

STU

VW

XY

ZA1

B1C1

D1 E1F1

G1H1

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0 10 20 30 40 50 60 70

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 24d








C - D Room 103 DL=0.11 DL=0.084

E - F Room 102 DL=0.11 DL=0.084

G - H Room 102A DL=0.11 DL=0.084

I - J Drain one DL=0.11 DL=0.084

K - L Drain two DL=0.11 DL=0.084

M - N Room 106 DL=0.11 DL=0.084

O - P Drain three DL=0.11 DL=0.084

Q - R Room 107 DL=0.11 DL=0.084

S - T Drain four DL=0.11 DL=0.084

U - V Drain five DL=0.11 DL=0.084

W - X Grease trap DL=0.11 DL=0.084

Y - Z Closet in room 107 DL=0.11 DL=0.084

A1 - B1 Drain six DL=0.11 DL=0.084

C1 - D1 Room 109 DL=0.11 DL=0.084


G1 - H1 30 mL/min spike 5.9 6.3




AB

CD

EF

GHI

JK

L MN O

P QR

STU

VW

XY

ZA1

B1C1

D1 E1F1

G1H1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

0 10 20 30 40 50 60 70

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

AB

CD

EF

GHI

JK

L MN O

P QR

STU

VW

XY

ZA1

B1C1

D1 E1F1

G1H1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

0 10 20 30 40 50 60 70

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 24f








C - D Room 103 DL=0.73 DL=0.45

E - F Room 102 DL=0.73 DL=0.45

G - H Room 102A DL=0.73 DL=0.45

I - J Drain one DL=0.73 DL=0.45

K - L Drain two DL=0.73 DL=0.45

M - N Room 106 DL=0.73 DL=0.45

O - P Drain three DL=0.73 DL=0.45

Q - R Room 107 DL=0.73 DL=0.45

S - T Drain four DL=0.73 DL=0.45

U - V Drain five DL=0.73 DL=0.45

W - X Grease trap DL=0.73 DL=0.45

Y - Z Closet in room 107 DL=0.73 DL=0.45

A1 - B1 Drain six DL=0.73 DL=0.45

C1 - D1 Room 109 DL=0.73 DL=0.45







Figure 25b












H 8.6 820 Start of the kitchen

I 9.6 915 End of the kitchen

J 10.1 966 Entering the basement

K 10.5 1001 Start of the basement

L 11.5 1098 End of the basement

M 11.8 1123 Start of the sub-slab port

N 12.8 1220 End of the sub-slab port

O 13.4 1279 Exiting the basement








A B CD

EF

GH

I J K LM

N O P Q R S T

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B CD

EF

GH

I J K LM

N O P Q R S T

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 25d










H - I Kitchen DL=0.11 DL=0.084

K - L Basement DL=0.11 DL=0.084

M - N Sub-slab port DL=0.11 DL=0.084






A B CD

EF

GH

I J K LM

N O P Q R S T

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD

EF

GH

I J K LM

N O P Q R S T

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 25f











K - L Basement DL=0.73 DL=0.45








Figure 26b












H 6.9 660 Start of the kitchen

I 7.9 755 End of the kitchen

J 8.8 835 Entering the basement

K 9.4 893 Start of basement room one

L 10.4 987 End of basement room one

M 11.5 1095 Start of the sub-slab port

N 12.5 1188 End of the sub-slab port

O 12.7 1211 Start of the hole through the floor

P 14.3 1360 End of the hole through the floor

Q 14.9 1417 Start of the hallway

R 15.9 1515 End of the hallway

S 16.8 1596 Start of the laundry room

T 17.7 1690 End of the laundry room

U 18.1 1726 Start of the storage room

V 19.1 1821 End of the storage room

W 19.4 1847 Start of basement room two

X 20.4 1943 End of basement room two

Y 20.9 1988 Exiting the basement

Z 21.5 2051 Exiting the unit

A1 22.6 2151 Start of the post-exit ambient

B1 23.6 2247 End of the post-exit ambient

C1 25.4 2415 Start of the 30 mL/min spike

D1 26.4 2510 End of the 30 mL/min spike



A B CD

E F GH

I J K L M NO

P Q R S TU

VW

XY Z A1 B1 C1 D1

0.0

2.5

5.0

7.5

10.0

12.5

15.0

17.5

0 5 10 15 20 25

QL

DL


Un

its i

n p

pb

v

Time in minutes

A B CD

E F GH

I J K L M NO

P Q R S TU

VW

XY Z A1 B1 C1 D1

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0 5 10 15 20 25

QL

DL


Un

its i

n p

pb

v

Time in minutes


Figure 26d











K - L Basement room one DL=0.11 DL=0.084


O - P Hole through the floor 4.0 DL=0.084

Q - R Hallway 0.15J DL=0.084

S - T Laundry room DL=0.11 DL=0.084

U - V Storage room DL=0.11 DL=0.084

W - X Basement room two DL=0.11 DL=0.084


C1 - D1 30 mL/min spike 6.2 6.4





A B CD

E F GH

I J K L M NO

P Q R S TU

VW

XY Z A1 B1 C1 D1

0

25

50

75

100

125

0 5 10 15 20 25

QL

DL


Un

its i

n µ

g/m

3

Time in minutes

A B CD

E F GH

I J K L M NO

P Q R S TU

VW

XY Z A1 B1 C1 D1

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

0 5 10 15 20 25

QL

DL


Un

its i

n µ

g/m

3

Time in minutes


Figure 26f











K - L Basement room one DL=0.73 DL=0.45


O - P Hole through floor 27 DL=0.45

Q - R Hallway 0.99J DL=0.45

S - T Laundry room DL=0.73 DL=0.45

U - V Storage room DL=0.73 DL=0.45

W - X Basement room two DL=0.73 DL=0.45


C1 - D1 30 mL/min spike 42 34




APPENDIX A

Standard Gas Cylinder Certification


Final Analytical TAGA Report

August 2016



APPENDIX B

Compiled Meteorological Data



August 2016

Local Climatological Data-Hourly Observations Table

Gerald R. Ford International Airport, Grand Rapids, MI

Elevation: 803 ft. above sea level

Latitude: 42.882

Longitude: -85.523

22 June through 02 July 2015


Date

Time

(LST)

Dry Bulb

Temperature

(F)

Dew point

Temperature

(F)

Relative

Humidity

%

Wind

Speed

(MPH)

Wind

Direction

Station

Pressure

(in. Hg)

Precipitation

Total (inches)

06/22/2016 53 65 50 59 6 250 29.03

06/22/2016 153 64 50 61 6 240 29.03

06/22/2016 253 63 50 63 5 260 29.04

06/22/2016 353 63 51 65 3 280 29.04

06/22/2016 453 59 51 75 3 180 29.05

06/22/2016 553 60 52 75 0 0 29.08

06/22/2016 653 62 54 75 3 120 29.08

06/22/2016 753 68 53 59 3 120 29.09

06/22/2016 853 73 55 53 0 0 29.09

06/22/2016 953 77 53 43 6 80 29.07

06/22/2016 1053 81 49 33 5 50 29.06

06/22/2016 1153 78 49 36 5 130 29.08

06/22/2016 1253 82 51 34 7 140 29.05

06/22/2016 1353 82 50 33 7 230 29.05

06/22/2016 1453 86 51 30 5 VR 29.04

06/22/2016 1553 86 52 31 0 0 29.03

06/22/2016 1653 83 58 43 9 210 29.02

06/22/2016 1753 79 58 49 7 220 29.02

06/22/2016 1853 78 60 54 7 220 29.00

06/22/2016 1953 76 61 60 5 270 29.00

06/22/2016 2053 75 61 62 0 0 28.98

06/22/2016 2153 74 62 66 5 60 28.98

06/22/2016 2253 73 57 57 7 60 28.97

06/22/2016 2353 72 57 59 3 100 28.97

06/23/2016 53 71 56 59 6 70 28.97

06/23/2016 153 68 55 63 6 50 28.96

06/23/2016 253 68 55 63 9 50 28.95

06/23/2016 353 66 56 70 13 60 28.96

06/23/2016 453 63 54 73 8 60 28.98

06/23/2016 553 63 54 73 7 90 28.99

06/23/2016 653 63 52 68 10 60 29.00

06/23/2016 753 63 49 60 10 40 29.01

06/23/2016 853 64 50 61 8 50 29.03

06/23/2016 953 67 52 59 5 10 29.06

06/23/2016 1053 69 54 59 11 70 29.04

06/23/2016 1153 70 55 59 11 50 29.06


LST = Local standard time MPH = Miles per hour

F = Fahrenheit in. Hg = inches of mercury

% = Percent VR = Variable direction




Latitude: 42.882

Longitude: -85.523



Date

Time

(LST)

Dry Bulb

Temperature

(F)

Dew point

Temperature

(F)

Relative

Humidity

%

Wind

Speed

(MPH)

Wind

Direction

Station

Pressure

(in. Hg)

Precipitation

Total (inches)

06/23/2016 1253 78 54 44 16 60 29.05

06/23/2016 1353 81 54 39 15 60 29.07

06/23/2016 1453 80 55 42 11 80 29.08

06/23/2016 1553 81 54 39 11 70 29.08

06/23/2016 1653 81 54 39 10 60 29.08

06/23/2016 1753 80 54 41 9 80 29.08

06/23/2016 1853 78 53 42 15 50 29.08

06/23/2016 1953 74 53 48 9 50 29.1

06/23/2016 2053 72 51 48 8 60 29.12

06/23/2016 2153 70 49 47 7 90 29.14

06/23/2016 2253 69 48 47 6 60 29.14

06/23/2016 2353 68 49 51 6 60 29.15

06/24/2016 53 64 49 58 6 80 29.16

06/24/2016 153 61 49 65 5 30 29.17

06/24/2016 253 60 49 67 5 60 29.18

06/24/2016 353 57 49 75 0 0 29.18

06/24/2016 453 56 48 75 6 50 29.19

06/24/2016 553 57 49 75 5 50 29.21

06/24/2016 653 63 48 58 6 50 29.22

06/24/2016 753 69 47 46 5 60 29.25

06/24/2016 853 73 44 35 10 80 29.25

06/24/2016 953 77 45 32 6 110 29.26

06/24/2016 1053 80 44 28 10 150 29.26

06/24/2016 1153 82 44 26 7 110 29.26

06/24/2016 1253 85 43 23 8 80 29.26

06/24/2016 1353 85 42 22 6 VR 29.25

06/24/2016 1453 87 44 22 5 VR 29.24

06/24/2016 1553 86 42 21 6 100 29.23

06/24/2016 1653 86 42 21 3 VR 29.23

06/24/2016 1753 85 43 23 5 110 29.22

06/24/2016 1853 82 45 27 5 90 29.21

06/24/2016 1953 79 49 35 5 110 29.21

06/24/2016 2053 74 51 45 5 260 29.23

06/24/2016 2153 72 52 50 3 330 29.25

06/24/2016 2253 70 51 51 0 0 29.25

06/24/2016 2353 64 53 68 3 220 29.26




% = Percent VR = Variable direction




Latitude: 42.882

Longitude: -85.523



Date

Time

(LST)

Dry Bulb

Temperature

(F)

Dew point

Temperature

(F)

Relative

Humidity

%

Wind

Speed

(MPH)

Wind

Direction

Station

Pressure

(in. Hg)

Precipitation

Total (inches)

06/25/2016 53 62 53 73 0 0 29.26

06/25/2016 153 62 54 75 3 40 29.24

06/25/2016 253 60 52 75 3 140 29.25

06/25/2016 353 59 52 78 3 150 29.25

06/25/2016 453 58 52 81 3 140 29.26

06/25/2016 553 60 53 78 6 170 29.26

06/25/2016 653 67 56 68 6 170 29.28

06/25/2016 753 74 53 48 10 170 29.29

06/25/2016 853 79 51 38 10 180 29.29

06/25/2016 953 83 54 37 11 170 29.28

06/25/2016 1053 84 53 34 10 210 29.28

06/25/2016 1153 86 53 32 9 180 29.26

06/25/2016 1253 88 53 30 8 160 29.26

06/25/2016 1353 88 52 29 11 180 29.26

06/25/2016 1453 89 53 29 10 160 29.24

06/25/2016 1553 90 55 31 14 150 29.22

06/25/2016 1653 89 56 33 15 160 29.21

06/25/2016 1753 88 57 35 10 190 29.2

06/25/2016 1853 86 58 39 10 170 29.19

06/25/2016 1953 81 59 47 8 160 29.17

06/25/2016 2053 76 59 56 7 180 29.18

06/25/2016 2153 75 59 58 7 140 29.21

06/25/2016 2253 72 60 66 7 170 29.2

06/25/2016 2353 71 60 68 8 160 29.18

06/26/2016 53 73 59 62 9 170 29.16

06/26/2016 153 72 59 64 8 180 29.16

06/26/2016 253 75 59 58 10 180 29.13

06/26/2016 353 74 60 62 11 190 29.12

06/26/2016 453 74 61 64 9 190 29.12

06/26/2016 553 75 63 66 10 200 29.12

06/26/2016 653 79 66 65 14 210 29.13

06/26/2016 753 80 66 62 11 210 29.13

06/26/2016 836 81 67 63 18 250 29.17

06/26/2016 853 77 67 71 16 290 29.19 T

06/26/2016 911 73 69 87 10 300 29.19

06/26/2016 947 73 70 90 6 250 29.19




% = Percent T = Trace precipitation




Latitude: 42.882

Longitude: -85.523



Date

Time

(LST)

Dry Bulb

Temperature

(F)

Dew point

Temperature

(F)

Relative

Humidity

%

Wind

Speed

(MPH)

Wind

Direction

Station

Pressure

(in. Hg)

Precipitation

Total (inches)

06/26/2016 953 73 69 87 6 250 29.18 0.11

06/26/2016 1035 73 71 93 13 160 29.14

06/26/2016 1050 73 72 97 13 160 29.12

06/26/2016 1053 73 71 93 13 150 29.12 0.11

06/26/2016 1153 77 70 79 9 170 29.11 T

06/26/2016 1253 82 69 65 9 260 29.15

06/26/2016 1353 85 67 55 8 260 29.15

06/26/2016 1453 88 67 50 14 240 29.13

06/26/2016 1553 85 65 51 14 280 29.12

06/26/2016 1653 81 66 60 14 260 29.11

06/26/2016 1753 82 67 61 13 250 29.11

06/26/2016 1853 81 67 63 8 230 29.11

06/26/2016 1953 79 68 69 8 220 29.1

06/26/2016 2053 76 68 76 8 220 29.11

06/26/2016 2153 74 68 82 8 220 29.12

06/26/2016 2253 73 67 82 7 220 29.13

06/26/2016 2353 73 67 82 10 250 29.14

06/27/2016 53 71 66 84 9 250 29.14

06/27/2016 153 70 65 84 8 240 29.13

06/27/2016 253 69 63 81 8 240 29.12

06/27/2016 353 67 62 84 7 250 29.12

06/27/2016 453 67 61 81 6 220 29.12

06/27/2016 553 68 61 78 6 220 29.12

06/27/2016 653 73 62 69 8 250 29.13

06/27/2016 753 78 63 60 11 250 29.14

06/27/2016 853 82 61 49 13 270 29.13

06/27/2016 953 84 59 43 14 280 29.12

06/27/2016 1053 86 58 39 17 270 29.12

06/27/2016 1153 86 58 39 16 290 29.12

06/27/2016 1253 86 55 35 21 270 29.12

06/27/2016 1353 85 54 35 24 270 29.12

06/27/2016 1453 83 55 38 22 300 29.13

06/27/2016 1553 83 56 40 21 310 29.13

06/27/2016 1653 81 56 42 18 300 29.12

06/27/2016 1753 80 55 42 14 320 29.12

06/27/2016 1853 78 54 44 11 320 29.14




% = Percent T = Trace precipitation




Latitude: 42.882

Longitude: -85.523



Date

Time

(LST)

Dry Bulb

Temperature

(F)

Dew point

Temperature

(F)

Relative

Humidity

%

Wind

Speed

(MPH)

Wind

Direction

Station

Pressure

(in. Hg)

Precipitation

Total (inches)

06/27/2016 2153 70 56 61 7 320 29.18

06/27/2016 2253 69 56 63 9 330 29.18

06/27/2016 2353 69 56 63 6 340 29.19

06/28/2016 53 68 56 66 11 340 29.19

06/28/2016 153 67 54 63 13 350 29.19

06/28/2016 253 65 52 63 15 330 29.2

06/28/2016 353 63 49 60 11 330 29.21

06/28/2016 453 59 49 70 8 310 29.23

06/28/2016 525 58 49 72 11 320 29.24

06/28/2016 553 58 48 70 15 330 29.25

06/28/2016 653 59 49 70 15 330 29.25

06/28/2016 753 60 49 67 10 330 29.26

06/28/2016 853 61 49 65 8 320 29.26

06/28/2016 953 63 49 60 6 300 29.26

06/28/2016 1053 63 50 63 10 350 29.26

06/28/2016 1153 67 50 55 6 330 29.26

06/28/2016 1233 68 50 53 8 350 29.26

06/28/2016 1253 68 51 55 8 360 29.26

06/28/2016 1353 70 50 49 10 330 29.25

06/28/2016 1453 71 50 48 7 350 29.24

06/28/2016 1553 73 50 44 9 320 29.24

06/28/2016 1653 75 48 39 6 360 29.22

06/28/2016 1753 76 41 29 10 350 29.22

06/28/2016 1853 74 39 28 8 20 29.22

06/28/2016 1953 70 40 34 7 30 29.22

06/28/2016 2053 65 41 42 7 330 29.22

06/28/2016 2153 63 46 54 10 330 29.24

06/28/2016 2253 61 46 58 7 340 29.25

06/28/2016 2353 58 46 65 7 360 29.25

06/29/2016 53 56 44 64 6 360 29.24

06/29/2016 153 54 42 64 0 0 29.23

06/29/2016 253 55 41 59 3 310 29.24

06/29/2016 353 53 41 64 6 270 29.26

06/29/2016 453 53 42 66 3 350 29.26

06/29/2016 553 53 44 72 6 20 29.26

06/29/2016 653 57 44 62 6 10 29.26




% = Percent




Latitude: 42.882

Longitude: -85.523



Date

Time

(LST)

Dry Bulb

Temperature

(F)

Dew point

Temperature

(F)

Relative

Humidity

%

Wind

Speed

(MPH)

Wind

Direction

Station

Pressure

(in. Hg)

Precipitation

Total (inches)

06/29/2016 753 63 44 50 3 VR 29.28

06/29/2016 853 68 45 44 5 330 29.28

06/29/2016 953 72 44 37 7 340 29.26

06/29/2016 1053 74 41 31 7 30 29.26

06/29/2016 1153 77 38 25 5 340 29.26

06/29/2016 1253 78 36 22 6 350 29.24

06/29/2016 1353 80 34 19 3 VR 29.23

06/29/2016 1453 81 36 20 8 260 29.23

06/29/2016 1553 81 37 21 9 310 29.21

06/29/2016 1653 80 44 28 13 290 29.2

06/29/2016 1753 78 44 30 11 280 29.2

06/29/2016 1853 75 44 33 10 290 29.2

06/29/2016 1953 72 43 35 7 290 29.19

06/29/2016 2053 69 43 39 7 300 29.19

06/29/2016 2153 66 45 47 8 290 29.22

06/29/2016 2253 63 45 52 8 290 29.22

06/29/2016 2353 59 47 65 5 280 29.21

06/30/2016 53 59 47 65 0 0 29.2

06/30/2016 153 54 47 77 0 0 29.2

06/30/2016 253 53 47 80 5 170 29.19

06/30/2016 353 52 47 83 3 170 29.18

06/30/2016 453 52 48 86 3 210 29.19

06/30/2016 553 55 49 80 3 160 29.21

06/30/2016 653 59 51 75 3 150 29.2

06/30/2016 753 67 48 51 5 210 29.21

06/30/2016 853 74 41 31 6 VR 29.2

06/30/2016 953 77 42 29 6 VR 29.18

06/30/2016 1053 79 45 30 10 230 29.18

06/30/2016 1153 82 46 28 7 190 29.16

06/30/2016 1253 79 49 35 11 250 29.14

06/30/2016 1353 78 50 38 11 240 29.12

06/30/2016 1453 81 49 33 13 260 29.11

06/30/2016 1553 81 46 29 17 250 29.1 T

06/30/2016 1653 81 44 27 8 230 29.1 T

06/30/2016 1753 80 46 30 14 250 29.09

06/30/2016 1853 78 46 32 7 270 29.07




VR = Variable direction T = Trace precipitation

% = Percent




Latitude: 42.882

Longitude: -85.523



Date

Time

(LST)

Dry Bulb

Temperature

(F)

Dew point

Temperature

(F)

Relative

Humidity

%

Wind

Speed

(MPH)

Wind

Direction

Station

Pressure

(in. Hg)

Precipitation

Total (inches)

06/30/2016 1953 75 47 37 9 250 29.08

06/30/2016 2053 70 48 46 6 240 29.07

06/30/2016 2153 69 50 51 5 170 29.06

06/30/2016 2253 69 50 51 9 220 29.05

06/30/2016 2353 69 52 55 7 190 29.04

07/01/2016 53 69 54 59 10 210 29.02

07/01/2016 151 64 59 84 15 320 29.03

07/01/2016 153 64 59 84 11 310 29.03 0.1

07/01/2016 200 63 60 90 10 300 29.03

07/01/2016 203 63 60 90 9 330 29.02

07/01/2016 218 63 60 90 8 340 29.02

07/01/2016 226 63 60 90 8 360 29

07/01/2016 236 63 60 90 3 350 29.01

07/01/2016 253 63 60 90 6 320 29.02 0.19

07/01/2016 353 62 59 90 0 0 29.02

07/01/2016 425 63 60 90 7 290 29.04

07/01/2016 430 63 60 90 7 290 29.04

07/01/2016 441 63 60 90 8 280 29.04

07/01/2016 453 63 59 87 10 300 29.04

07/01/2016 553 63 58 84 13 310 29.06

07/01/2016 645 64 56 75 13 330 29.09

07/01/2016 653 64 56 75 13 320 29.09

07/01/2016 732 64 56 75 17 320 29.1

07/01/2016 753 64 56 75 13 330 29.11

07/01/2016 826 63 55 75 13 330 29.12

07/01/2016 853 63 54 73 18 320 29.13

07/01/2016 953 67 53 61 14 340 29.14

07/01/2016 1053 70 52 53 20 360 29.15

07/01/2016 1153 70 52 53 13 320 29.16

07/01/2016 1203 72 51 48 15 330 29.16

07/01/2016 1253 73 49 43 14 340 29.18

07/01/2016 1353 74 49 41 15 320 29.18

07/01/2016 1453 74 48 40 16 350 29.19

07/01/2016 1553 75 47 37 10 290 29.19

07/01/2016 1653 75 46 36 14 300 29.19

07/01/2016 1753 72 46 40 13 340 29.21




% = Percent




Latitude: 42.882

Longitude: -85.523



Date

Time

(LST)

Dry Bulb

Temperature

(F)

Dew point

Temperature

(F)

Relative

Humidity

%

Wind

Speed

(MPH)

Wind

Direction

Station

Pressure

(in. Hg)

Precipitation

Total (inches)

07/01/2016 1853 71 46 41 13 360 29.23

07/01/2016 1953 68 46 45 8 360 29.23

07/01/2016 2053 64 46 52 7 330 29.25

07/01/2016 2153 63 45 52 5 320 29.26

07/01/2016 2253 61 46 58 6 280 29.28

07/01/2016 2353 60 46 60 6 290 29.28

07/02/2016 53 57 46 67 3 260 29.28

07/02/2016 153 54 47 77 6 250 29.28

07/02/2016 253 55 48 77 6 280 29.28

07/02/2016 353 54 48 80 0 0 29.28

07/02/2016 453 53 47 80 0 0 29.28

07/02/2016 553 53 49 86 0 0 29.29

07/02/2016 653 55 50 83 3 180 29.31

07/02/2016 753 59 53 81 0 0 29.31

07/02/2016 853 67 51 57 5 240 29.34

07/02/2016 953 74 46 37 6 240 29.31

07/02/2016 1053 76 49 39 8 290 29.31

07/02/2016 1153 78 47 34 3 VR 29.29

07/02/2016 1253 75 47 37 7 320 29.28

07/02/2016 1353 79 48 34 9 260 29.28

07/02/2016 1453 76 48 37 10 250 29.28

07/02/2016 1553 76 50 40 16 250 29.28

07/02/2016 1653 76 49 39 13 270 29.26

07/02/2016 1753 75 46 36 11 290 29.26

07/02/2016 1853 72 47 41 9 290 29.26

07/02/2016 1953 71 48 44 9 270 29.26

07/02/2016 2053 67 48 51 7 280 29.28

07/02/2016 2153 63 49 60 3 270 29.28

07/02/2016 2253 63 51 65 6 280 29.28

07/02/2016 2353 62 53 73 6 290 29.28




VR = Variable direction % = Percent


APPENDIX C

TAGA Calibration Data



August 2016

Method InformationMethod Name: PCE/TCE CALIBRATIONLast Modified: Thu, Jun 23, 2016, 7:41:24Comment:

Command Description Time Reps Duration Total Time(sec) (min) (hh:mm:ss)

Scan 0.630 4285 45.000 00:45:00Mode: Profile

Thres�: 0.1 x 10 E1 cps

Pause: 0.1 sec

Expt:� MacHD3064:Instrument:expt:PCE+TCE

State: MacHD3064:Instrument:state:LPCI2016JUN23 PCE+TCE

Q1 Cal: MacHD3064:Instrument:calibration:Q1 Calib LPCI 20121102


Active Device Methods:

Device Type: LC Pump

Device Name: MKS 146 Single

ROM Version: ROM version cannot be checked.

Comment: ROM version cannot be checked.

Solvents: 1

Solvent name: Solvent A %

Timed events: 0

Device specific parameters: 2

Gradient: 1=Step, 2=Linear 1.0000

Gradient: 1=Step, 2=Linear

Gradient resolution (sec) 5.0000

Gradient resolution in seconds

Timed steps: 9

Min. Pressure : 0.0000

Max. Pressure : 100.0000

Step T.Time (min) Dura.(min) Flow (µL/min) Sol.1

0 -0.10 0.10 0.00 100.00

1 0.00 3.00 0.00 100.00

2 3.00 2.00 90.00 100.00

3 5.00 2.00 10.00 100.00

4 7.00 2.00 20.00 100.00

5 9.00 2.00 40.00 100.00

6 11.00 2.00 80.00 100.00

7 13.00 2.00 90.00 100.00

8 15.00 2.00 0.00 100.00

Sample Control, Version 1.4Computer: TAGAFile: PCE/TCE CALIBRATION

Page 1 of 5Printed: Thu, Jun 23, 2016, 7:41:33

Path: MacHD3064:Instrument:T…s ƒ:Acquisition Methods:

Experiment InformationExperiment Name: PCE+TCELast Modified: Fri, Mar 25, 2016, 10:37:35Scan Type: MRM Mass Defect: 0 mmu/100amuScan Time: 00:00.630 secs Pause Time: 5.000 msec�Peak Hopping : DisabledQ2 Purge : DisabledComment: Cal. Gas Bottle Number 2

Mass Range InformationQ1 Mass(amu) Q3 Mass(amu) Dwell(msec)

164.000 129.000 100.000

Q1 Mass(amu) Q3 Mass(amu) Dwell(msec)166.000 129.000 100.000





Sample Control, Version 1.4Computer: TAGAFile: PCE+TCE

Page 2 of 5Printed: Thu, Jun 23, 2016, 7:41:33Path: MacHD3064:Instrument:expt:

State File InformationLast Modified: Thu, Jun 23, 2016, 7:37:09

Analog ParametersNC 0.000TEM 80.000OR 0.000RNG 0.000Q0 -5.399IQ1 -6.099ST -15.600RO1 -6.100IQ2 -13.000RO2 -35.000IQ3 -38.000RO3 -40.500DF -390.000CEM 1700.000

On/Off ParametersPOL OffNEB OffCUR 4CAD 7

Q1 Peak Resolution TableMass Peak Mass Shift

30.000 0.04075.000 0.060

100.000 0.063120.000 0.070180.000 0.089300.000 0.120


30.000 0.04260.000 0.047

100.000 0.047150.000 0.047180.000 0.047

Sample Control, Version 1.4Computer: TAGAFile: LPCI2016JUN23 PCE+TCE

Page 3 of 5Printed: Thu, Jun 23, 2016, 7:41:33Path: MacHD3064:Instrument:state:

Calibration File InformationType: Q1 CalibrationLast Modified: Fri, Nov 2, 2012, 14:24:38

Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146

Sample Control, Version 1.4Computer: TAGAFile: Q1 Calib LPCI 20121102


Path: MacHD3064:Instrument:calibration:


Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




Method InformationMethod Name: PCE/TCE MONITORINGLast Modified: Thu, Jun 23, 2016, 7:41:53Comment:




Pause: 0.1 sec






Sample Control, Version 1.4Computer: TAGAFile: PCE/TCE MONITORING





164.000 129.000 100.000












30.000 0.04075.000 0.060

100.000 0.063120.000 0.070180.000 0.089300.000 0.120


30.000 0.04260.000 0.047

100.000 0.047150.000 0.047180.000 0.047




Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




BioMultiView 1.3 Thursday, June 23, 2016 9:26 page 1 of 16/23/16.9.03.09Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Thu, Jun 23, 2016 at 9:03:09; Exp. Comment: Cal. Gas Bottle Number 2

2.47e4 cpsTIC: from 64MSMS00111

% % MultiView -- © 1996, SCIEX, a division of MDS Health Group.% % Original concept:% Dr. Ron Bonner% Dr. Lyle Burton% % Development:% Dr. Lyle Burton% Yves Legault% Shengping Ma% % With the help of:% Dr. Victoria Barclay% Scott Champ% Rob McDermid%

0.65

4.91

7.16 9.01

13.64 15.07

20.11

5 10 15 20Time, min

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

11000

12000

13000

14000

15000

16000

17000

18000

19000

20000

21000

22000

23000

24000

Inte

nsity,

cp

s

Filename: 64MSMS00111 et al.

Compound name:TETRACHLOROETHENE

Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:

Date: Thursday, June 23, 2016 9:24:59

Num. ions: 3

Num. concs. 6

Level 1 Level 2 Level 3 Level 4 Level 5 Level 6

Ctr Pt.(min): 1.50 6.53 16.50 19.00 12.50 14.26

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 273.978168 97.5635566 286.560299

Intercept: -25.643308 -7.0558845 -25.7761

Correlation: 0.99980436 0.99989199 0.99959917

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 4.79166667 2.08333333 4.27083333

2.22 579.270833 204.375 611.666667

4.44 1211.97917 429.166667 1278.85417

8.89 2336.04167 850.729167 2433.95833

17.78 4820 1713.125 5001.25

20 5505.3125 1961.25 5797.60417

Calibration Curve for TETRACHLOROETHENE

-1000

0

1000

2000

3000

4000

5000

6000

7000

0 5 10 15 20 25

Concentration (ppbv)

164.00/129.00

166.00/129.00

166.00/131.00


Compound name:TRICHLOROETHENE

Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.53 16.50 19.00 12.50 14.26

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 262.550963 80.8521083 159.845652

Intercept: -19.418492 -10.61649 -12.527595

Correlation: 0.99990365 0.99977779 0.99993751

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 3.125 1.25 0.625

2.19 540 168.854167 336.25

4.38 1156.35417 343.229167 691.145833

8.76 2228.54167 673.958333 1361.875

17.51 4578.75 1399.47917 2782.60417

19.7 5171.14583 1597.5 3150.625

Calibration Curve for TRICHLOROETHENE

-1000

0

1000

2000

3000

4000

5000

6000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00111 et al.Sample Name BOD Calibration - PCE/TCE 062316Date Thursday, June 23, 2016 9:26:12Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00

Name TETRACHLOROETHENETETRACHLOROETHENETETRACHLOROETHENETRICHLOROETHENETRICHLOROETHENETRICHLOROETHENEQ1 Mass 164.00 166.00 166.00 130.00 132.00 132.00Q3 Mass 129.00 129.00 131.00 95.00 95.00 97.00Slope 273.98 97.56 286.56 262.55 80.85 159.85Intercept -25.64 -7.06 -25.78 -19.42 -10.62 -12.53Intensity 4.79 2.08 4.27 3.13 1.25 0.63Int SD 8.21 5.01 7.50 6.38 4.41 2.83Concentration 0.11 0.09 0.10 0.09 0.15 0.08Conc SD 0.03 0.05 0.03 0.02 0.05 0.02Compound Conc 0.10 0.10Compound SD 0.02 0.02Det. Limit 0.09 0.15 0.08 0.07 0.16 0.05Compound DL 0.11 0.10




1.33

4.034.99

7.32 8.24

9.57

14.71

2 4 6 8 10 12 14 16Time, min

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

22000

24000

26000

28000

30000

32000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.27 8.14 10.15 12.24 14.15

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 384.293457 136.229308 395.240461

Intercept: -49.179622 -18.947145 -58.095721

Correlation: 0.99981138 0.99958259 0.99981149

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 3.54166667 0.41666667 3.85416667

2.22 822.57732 295.773196 832.989691

4.44 1625.36082 577.319588 1675.46392

8.89 3298.02083 1156.66667 3358.22917

17.78 6727.91667 2368.02083 6938.4375

20 7721.875 2753.22917 7920.625


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.27 8.14 10.15 12.24 14.15

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 357.972728 110.159787 217.969851

Intercept: -48.476425 -17.370941 -33.955472

Correlation: 0.99986169 0.99954887 0.99975893

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 4.89583333 1.77083333 1.04166667

2.19 740.103093 236.185567 457.731959

4.38 1485.15464 441.134021 895.56701

8.76 3039.79167 933.229167 1831.04167

17.51 6180.10417 1880.72917 3751.35417

19.7 7066.97917 2190.52083 4311.66667


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00117 et al.Sample Name MOD Calibration - PCE/TCE 062316Date Thursday, June 23, 2016 13:53:43Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00





0.49

2.59

4.45

7.18

11.53

13.14

19.47

5 10 15 20Time, min

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

22000

24000

26000

28000

30000

32000

34000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 9.02 11.34 14.05 16.50 19.07

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 401.647482 143.959334 417.623194

Intercept: 4.04731989 -0.2732127 11.821661

Correlation: 0.99993042 0.99994761 0.99987639

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 11.875 2.1875 12.3958333

2.22 913.229167 331.666667 976.354167

4.44 1811.5625 636.979167 1884.79167

8.89 3500.83333 1256.5625 3647.08333

17.78 7134.47917 2566.66667 7388.54167

20 8072.16495 2881.64948 8433.60825


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 9.02 11.34 14.05 16.50 19.07

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 394.49929 118.871352 235.70937

Intercept: 4.87299616 -5.8913911 -9.584835

Correlation: 0.9998421 0.99991911 0.99984487

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 5.52083333 2.29166667 1.5625

2.19 914.583333 258.229167 527.395833

4.38 1750.41667 517.1875 1021.35417

8.76 3369.16667 1011.14583 2010.41667

17.51 6874.6875 2075.9375 4085.41667

19.7 7841.85567 2345.36082 4680.51546


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00122 et al.Sample Name EOD Calibration - PCE/TCE 062316Date Thursday, June 23, 2016 19:09:28Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00

Name TETRACHLOROETHENETETRACHLOROETHENETETRACHLOROETHENETRICHLOROETHENETRICHLOROETHENETRICHLOROETHENEQ1 Mass 164.00 166.00 166.00 130.00 132.00 132.00Q3 Mass 129.00 129.00 131.00 95.00 95.00 97.00Slope 401.65 143.96 417.62 394.50 118.87 235.71Intercept 4.05 -0.27 11.82 4.87 -5.89 -9.58Intensity 11.88 2.19 12.40 5.52 2.29 1.56Int SD 15.03 5.27 13.59 8.57 5.52 4.19Concentration 0.02 0.02 0.00 0.00 0.07 0.05Conc SD 0.04 0.04 0.03 0.02 0.05 0.02Compound Conc 0.01 0.04Compound SD 0.02 0.02Det. Limit 0.11 0.11 0.10 0.07 0.14 0.05Compound DL 0.11 0.09

Method InformationMethod Name: PCE/TCE CALIBRATIONLast Modified: Fri, Jun 24, 2016, 6:52:45Comment:




Pause: 0.1 sec










Solvents: 1


Timed events: 0






Timed steps: 9




0 -0.10 0.10 0.00 100.00

1 0.00 3.00 0.00 100.00

2 3.00 2.00 90.00 100.00

3 5.00 2.00 10.00 100.00

4 7.00 2.00 20.00 100.00

5 9.00 2.00 40.00 100.00

6 11.00 2.00 80.00 100.00

7 13.00 2.00 90.00 100.00

8 15.00 2.00 0.00 100.00


Page 1 of 5Printed: Fri, Jun 24, 2016, 6:54:22




164.000 129.000 100.000








Path: MacHD3064:Instrument:expt:

State File InformationLast Modified: Fri, Jun 24, 2016, 6:41:44




30.000 0.04575.000 0.057

100.000 0.060120.000 0.067180.000 0.090300.000 0.120


30.000 0.04260.000 0.047

100.000 0.047150.000 0.047180.000 0.047



Path: MacHD3064:Instrument:state:


Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




Method InformationMethod Name: PCE/TCE MONITORINGLast Modified: Fri, Jun 24, 2016, 6:54:52Comment:




Pause: 0.1 sec











164.000 129.000 100.000









State File InformationLast Modified: Fri, Jun 24, 2016, 6:41:44




30.000 0.04575.000 0.057

100.000 0.060120.000 0.067180.000 0.090300.000 0.120


30.000 0.04260.000 0.047

100.000 0.047150.000 0.047180.000 0.047





Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




BioMultiView 1.3 Friday, June 24, 2016 7:15 page 1 of 16/24/16.6.56.02Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Fri, Jun 24, 2016 at 6:56:02; Exp. Comment: Cal. Gas Bottle Number 2



1.04 2.42

3.33 4.28

7.76

9.30

11.54

13.89

2 4 6 8 10 12 14 16Time, min

2000

4000

6000

8000

10000

12000

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16000

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20000

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28000

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32000

34000

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38000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:

Date: Friday, June 24, 2016 7:12:54

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.27 8.20 10.10 12.24 14.15

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 418.313615 150.503249 436.36648

Intercept: -30.090015 -13.556378 -13.136705

Correlation: 0.99988564 0.99972005 0.99993915

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 18.0208333 6.14583333 17.3958333

2.22 920.416667 345 989.0625

4.44 1807.70833 636.354167 1888.125

8.89 3591.77083 1276.5625 3810.3125

17.78 7421.04167 2657.08333 7735.625

20 8369.16667 3023.85417 8752.08333


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:

Date: Friday, June 24, 2016 7:13:35

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.27 8.20 10.10 12.24 14.15

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 418.982992 136.578491 272.052343

Intercept: -8.3735695 -5.0695406 -15.778625

Correlation: 0.99989011 0.99981541 0.9998784

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 13.2291667 5.625 5.9375

2.19 955.416667 302.291667 604.375

4.38 1796.5625 583.333333 1162.70833

8.76 3598.95833 1178.33333 2310.20833

17.51 7290 2357.91667 4735.10417

19.7 8308.95833 2717.91667 5380.625


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00124 et al.Sample Name BOD Calibration - PCE/TCE 062416Date Friday, June 24, 2016 7:14:08Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00





0.77 1.61

2.61

3.99 4.81

8.53

10.52

13.68

15.78 18.00

5 10 15Time, min

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

22000

24000

26000

28000

30000

32000

34000

36000

38000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:

Date: Friday, June 24, 2016 13:55:42

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.76 9.06 11.44 14.12 16.80

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 406.134895 154.819509 446.22641

Intercept: 31.7696199 2.48898223 21.4818943

Correlation: 0.99982556 0.99981265 0.99989113

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 9.47916667 3.125 7.60416667

2.22 958.645833 354.166667 1045

4.44 1825.52083 691.875 1976.04167

8.89 3676.5625 1370 4015.625

17.78 7146.45833 2715.83333 7867.91667

20 8233.125 3136.45833 9013.95833


0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:

Date: Friday, June 24, 2016 13:56:19

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.76 9.06 11.44 14.12 16.80

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 433.922923 140.845099 277.529084

Intercept: 20.4204953 8.45460685 6.28074186

Correlation: 0.99983978 0.99973865 0.99979032

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 5 1.45833333 1.35416667

2.19 1004.89583 336.041667 642.291667

4.38 1908.64583 618.4375 1213.33333

8.76 3832.91667 1242.1875 2427.60417

17.51 7513.64583 2433.33333 4793.22917

19.7 8655.72917 2819.27083 5541.25


0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00130 et al.

Sample Name MOD Calibration - PCE/TCE 062416

Date Friday, June 24, 2016 13:56:53

Time Range 1.00 to 2.00 min

Conc Units: ppbv

Num Ions 6.00

Name TETRACHLOROETHENETETRACHLOROETHENETETRACHLOROETHENETRICHLOROETHENETRICHLOROETHENETRICHLOROETHENE

Q1 Mass 164.00 166.00 166.00 130.00 132.00 132.00

Q3 Mass 129.00 129.00 131.00 95.00 95.00 97.00

Slope 406.13 154.82 446.23 433.92 140.85 277.53

Intercept 31.77 2.49 21.48 20.42 8.45 6.28

Intensity 9.48 3.13 7.60 5.00 1.46 1.35

Int SD 12.26 7.01 13.36 7.81 4.10 4.26

Concentration -0.05 0.00 -0.03 -0.04 -0.05 -0.02

Conc SD 0.03 0.05 0.03 0.02 0.03 0.02

Compound Conc -0.03 -0.03

Compound SD 0.02 0.01

Det. Limit 0.09 0.14 0.09 0.05 0.09 0.05

Compound DL 0.11 0.06




2.89

3.90

11.7713.10

14.94

18.30

5 10 15 20Time, min

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

11000

12000

13000

14000

15000

16000

17000

18000

19000

20000

21000

22000

23000

24000

25000

26000

27000

28000

29000

30000

31000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:

Date: Friday, June 24, 2016 18:33:55

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.00 7.77 10.32 12.73 15.70 18.04

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 304.498724 118.20427 344.034207

Intercept: 35.8515047 18.08295 48.7598459

Correlation: 0.9997823 0.99991856 0.99984202

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 12.8865979 4.84536082 14.0206186

2.22 710.208333 285.9375 805.416667

4.44 1419.16667 548.645833 1605.20833

8.89 2760.72917 1079.6875 3156.66667

17.78 5360.61856 2101.34021 6085.25773

20 6190.41667 2391.875 6973.33333


0

1000

2000

3000

4000

5000

6000

7000

8000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:

Date: Friday, June 24, 2016 18:35:44

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.00 7.77 10.32 12.73 15.70 18.04

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 354.249485 114.412893 223.053987

Intercept: 23.0346299 1.83953671 18.7106891

Correlation: 0.99977043 0.99990257 0.99989436

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 5.15463918 4.22680412 1.64948454

2.19 805.104167 255.208333 522.1875

4.38 1573.54167 505.208333 990.625

8.76 3171.35417 996.041667 1994.89583

17.51 6119.17526 1985.87629 3882.37113

19.7 7076.14583 2275.72917 4439.79167


0

1000

2000

3000

4000

5000

6000

7000

8000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00133 et al.Sample Name EOD CALIBRATION - PCE/TCE 062416Date Friday, June 24, 2016 18:36:52Time Range 0.50 to 1.50 minConc Units: ppbvNum Ions 6.00

Name TETRACHLOROETHENETETRACHLOROETHENETETRACHLOROETHENETRICHLOROETHENETRICHLOROETHENETRICHLOROETHENEQ1 Mass 164.00 166.00 166.00 130.00 132.00 132.00Q3 Mass 129.00 129.00 131.00 95.00 95.00 97.00Slope 304.50 118.20 344.03 354.25 114.41 223.05Intercept 35.85 18.08 48.76 23.03 1.84 18.71Intensity 12.89 4.85 14.02 5.15 4.23 1.65Int SD 14.14 7.65 15.79 8.91 9.56 4.25Concentration -0.08 -0.11 -0.10 -0.05 0.02 -0.08Conc SD 0.05 0.06 0.05 0.03 0.08 0.02Compound Conc -0.10 -0.04Compound SD 0.03 0.02Det. Limit 0.14 0.19 0.14 0.08 0.25 0.06Compound DL 0.16 0.13

Method InformationMethod Name: PCE/TCE CALIBRATIONLast Modified: Mon, Jun 27, 2016, 7:45:36Comment:




Pause: 0.1 sec










Solvents: 1


Timed events: 0






Timed steps: 9




0 -0.10 0.10 0.00 100.00

1 0.00 3.00 0.00 100.00

2 3.00 2.00 90.00 100.00

3 5.00 2.00 10.00 100.00

4 7.00 2.00 20.00 100.00

5 9.00 2.00 40.00 100.00

6 11.00 2.00 80.00 100.00

7 13.00 2.00 90.00 100.00

8 15.00 2.00 0.00 100.00


Page 1 of 5Printed: Mon, Jun 27, 2016, 7:45:43




164.000 129.000 100.000







Page 2 of 5Printed: Mon, Jun 27, 2016, 7:45:43Path: MacHD3064:Instrument:expt:

State File InformationLast Modified: Mon, Jun 27, 2016, 7:44:33




30.000 0.04175.000 0.057

100.000 0.060120.000 0.067180.000 0.080300.000 0.900


30.000 0.04260.000 0.045

100.000 0.045150.000 0.047180.000 0.047


Page 3 of 5Printed: Mon, Jun 27, 2016, 7:45:43Path: MacHD3064:Instrument:state:


Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




Method InformationMethod Name: PCE/TCE MONITORINGLast Modified: Mon, Jun 27, 2016, 7:46:08Comment:




Pause: 0.1 sec











164.000 129.000 100.000







Page 2 of 5Printed: Mon, Jun 27, 2016, 7:46:15Path: MacHD3064:Instrument:expt:

State File InformationLast Modified: Mon, Jun 27, 2016, 7:44:33




30.000 0.04175.000 0.057

100.000 0.060120.000 0.067180.000 0.080300.000 0.900


30.000 0.04260.000 0.045

100.000 0.045150.000 0.047180.000 0.047


Page 3 of 5Printed: Mon, Jun 27, 2016, 7:46:15Path: MacHD3064:Instrument:state:


Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




BioMultiView 1.3 Monday, June 27, 2016 8:50 page 1 of 16/27/16.8.20.38Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Mon, Jun 27, 2016 at 8:20:36; Exp. Comment: Cal. Gas Bottle Number 2



3.62

5.65

7.07

9.68

18.68

5 10 15 20Time, min

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

22000

24000

26000

28000

30000

32000

34000

36000

38000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:

Date: Monday, June 27, 2016 8:41:49

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 8.32 10.57 13.26 16.12 18.53

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 157.681043 63.1615303 184.588165

Intercept: -34.132456 -4.830897 -21.280542

Correlation: 0.99972949 0.99990252 0.999623

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 2.5 0.9375 4.6875

2.22 327.1875 137.291667 422.291667

4.44 635.833333 267.916667 756.041667

8.89 1323.81443 555.773196 1585.25773

17.78 2779.79167 1109.375 3224.6875

20 3135.20833 1268.125 3723.4375


-500

0

500

1000

1500

2000

2500

3000

3500

4000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:

Date: Monday, June 27, 2016 8:42:31

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 8.32 10.57 13.26 16.12 18.53

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 156.905148 49.9457242 99.2888113

Intercept: -6.355294 -2.2349199 -10.115571

Correlation: 0.9999261 0.99990829 0.99988509

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 8.22916667 1.25 1.04166667

2.19 349.6875 109.583333 214.479167

4.38 656.770833 206.145833 416.666667

8.76 1356.18557 439.072165 839.690722

17.51 2738.95833 875.208333 1727.29167

19.7 3095.83333 979.479167 1956.77083


-500

0

500

1000

1500

2000

2500

3000

3500

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00136 et al.Sample Name BOD Calibration 2 - PCE/TCE 062716Date Monday, June 27, 2016 8:43:08Time Range 0.50 to 1.50 minConc Units: ppbvNum Ions 6.00


Method InformationMethod Name: PCE/TCE CALIBRATIONLast Modified: Tue, Jun 28, 2016, 8:19:53Comment:




Pause: 0.1 sec










Solvents: 1


Timed events: 0






Timed steps: 9




0 -0.10 0.10 0.00 100.00

1 0.00 3.00 0.00 100.00

2 3.00 2.00 90.00 100.00

3 5.00 2.00 10.00 100.00

4 7.00 2.00 20.00 100.00

5 9.00 2.00 40.00 100.00

6 11.00 2.00 80.00 100.00

7 13.00 2.00 90.00 100.00

8 15.00 2.00 0.00 100.00


Page 1 of 5Printed: Tue, Jun 28, 2016, 8:20:04




164.000 129.000 100.000







Page 2 of 5Printed: Tue, Jun 28, 2016, 8:20:04Path: MacHD3064:Instrument:expt:

State File InformationLast Modified: Tue, Jun 28, 2016, 8:17:59




30.000 0.04175.000 0.058

100.000 0.060120.000 0.070180.000 0.090300.000 1.000


30.000 0.04360.000 0.044

100.000 0.044150.000 0.047180.000 0.047


Page 3 of 5Printed: Tue, Jun 28, 2016, 8:20:04Path: MacHD3064:Instrument:state:


Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




Method InformationMethod Name: PCE/TCE MONITORINGLast Modified: Tue, Jun 28, 2016, 8:20:25Comment:




Pause: 0.1 sec











164.000 129.000 100.000







Page 2 of 5Printed: Tue, Jun 28, 2016, 8:20:30Path: MacHD3064:Instrument:expt:

State File InformationLast Modified: Tue, Jun 28, 2016, 8:17:59




30.000 0.04175.000 0.058

100.000 0.060120.000 0.070180.000 0.090300.000 1.000


30.000 0.04360.000 0.044

100.000 0.044150.000 0.047180.000 0.047


Page 3 of 5Printed: Tue, Jun 28, 2016, 8:20:30Path: MacHD3064:Instrument:state:


Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




BioMultiView 1.3 Tuesday, June 28, 2016 8:57 page 1 of 16/28/16.8.32.02Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Tue, Jun 28, 2016 at 8:32:01; Exp. Comment: Cal. Gas Bottle Number 2



1.32

2.42

5.53

10.37

13.65

21.31

5 10 15 20Time, min

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Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:

Date: Tuesday, June 28, 2016 8:54:48

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.48 7.31 10.31 14.34 17.85 20.39

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 211.505446 75.434982 220.536634

Intercept: -53.60341 -23.389497 -71.224735

Correlation: 0.99938661 0.99949323 0.99909629

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 1.77083333 0.9375 0.83333333

2.22 440.833333 145.416667 447.916667

4.44 836.666667 298.645833 849.895833

8.89 1765.83333 621.041667 1805.9375

17.78 3655.36082 1309.38144 3788.45361

20 4257.5 1507.1875 4440.83333


-500

0

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1500

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0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.48 7.31 10.31 14.34 17.85 20.39

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 242.975945 74.9347957 147.139537

Intercept: -69.884089 -22.863056 -34.001703

Correlation: 0.9995795 0.99849965 0.99968319

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 4.58333333 0.52083333 2.5

2.19 472.083333 160.104167 292.8125

4.38 928.541667 285 593.125

8.76 2005.52083 595.625 1205.3125

17.51 4161.4433 1260 2546.70103

19.7 4774.47917 1498.64583 2886.25


-1000

0

1000

2000

3000

4000

5000

6000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00140 et al.Sample Name BOD Calibration - PCE/TCE 062816Date Tuesday, June 28, 2016 8:56:49Time Range 0.50 to 1.50 minConc Units: ppbvNum Ions 6.00


BioMultiView 1.3 Tuesday, June 28, 2016 13:47 page 1 of 16/28/16.13.26.45Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Tue, Jun 28, 2016 at 13:26:44; Exp. Comment: Cal. Gas Bottle Number 2



5.08

6.52

8.42

11.89

15.05

18.60

5 10 15 20Time, min

2000

4000

6000

8000

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34000

36000

38000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.73 9.46 12.48 15.24 18.07

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 395.098878 140.086144 411.913537

Intercept: -33.435761 -7.5109955 -54.474212

Correlation: 0.99984183 0.99991859 0.99989637

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 3.95833333 1.14583333 5.3125

2.22 892.1875 316.770833 880.520833

4.44 1683.4375 599.0625 1717.70833

8.89 3390.52083 1219.375 3543.95833

17.78 6970.72917 2499.27083 7281.35417

20 7929.17526 2790.10309 8211.64948


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.73 9.46 12.48 15.24 18.07

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 481.060756 145.357001 289.117981

Intercept: -44.885237 -8.4647586 -29.027768

Correlation: 0.99988122 0.99992448 0.99965861

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 6.77083333 1.5625 2.70833333

2.19 1051.25 322.5 635.3125

4.38 2012.39583 617.395833 1220.10417

8.76 4080.52083 1242.1875 2433.54167

17.51 8364.27083 2534.375 4969.27083

19.7 9490.41237 2868.24742 5755.15464


-2000

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4000

6000

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0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00144 et al.Sample Name EOD Calibration - PCE/TCE 062816Date Tuesday, June 28, 2016 13:50:32Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00


Method InformationMethod Name: PCE/TCE CALIBRATIONLast Modified: Wed, Jun 29, 2016, 8:19:26Comment:




Pause: 0.1 sec










Solvents: 1


Timed events: 0






Timed steps: 9




0 -0.10 0.10 0.00 100.00

1 0.00 3.00 0.00 100.00

2 3.00 2.00 90.00 100.00

3 5.00 2.00 10.00 100.00

4 7.00 2.00 20.00 100.00

5 9.00 2.00 40.00 100.00

6 11.00 2.00 80.00 100.00

7 13.00 2.00 90.00 100.00

8 15.00 2.00 0.00 100.00


Page 1 of 5Printed: Wed, Jun 29, 2016, 8:19:34




164.000 129.000 100.000









State File InformationLast Modified: Wed, Jun 29, 2016, 8:07:04




30.000 0.04575.000 0.058

100.000 0.060120.000 0.070180.000 0.090300.000 1.000


30.000 0.04360.000 0.044

100.000 0.044150.000 0.047180.000 0.047


Page 3 of 5Printed: Wed, Jun 29, 2016, 8:19:34Path: MacHD3064:Instrument:state:


Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




Method InformationMethod Name: PCE/TCE MONITORINGLast Modified: Wed, Jun 29, 2016, 8:24:06Comment:




Pause: 0.1 sec











164.000 129.000 100.000









State File InformationLast Modified: Wed, Jun 29, 2016, 8:07:04




30.000 0.04575.000 0.058

100.000 0.060120.000 0.070180.000 0.090300.000 1.000


30.000 0.04360.000 0.044

100.000 0.044150.000 0.047180.000 0.047


Page 3 of 5Printed: Wed, Jun 29, 2016, 8:24:11Path: MacHD3064:Instrument:state:


Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




BioMultiView 1.3 Wednesday, June 29, 2016 8:49 page 1 of 16/29/16.8.25.12Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Wed, Jun 29, 2016 at 8:25:12; Exp. Comment: Cal. Gas Bottle Number 2



0.51

5.49

8.12

9.63

19.61

5 10 15 20Time, min

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

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26000

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32000

34000

36000

38000

40000

42000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:

Date: Wednesday, June 29, 2016 8:47:03

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 7.59 10.55 13.71 16.59 19.45

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 445.192875 159.140731 456.589053

Intercept: -93.434645 -35.026896 -90.562802

Correlation: 0.99966625 0.9996057 0.99975187

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 3.33333333 1.77083333 2.5

2.22 942.604167 338.4375 969.583333

4.44 1803.29897 625.876289 1844.3299

8.89 3731.25 1349.58333 3852.5

17.78 7794.375 2772.5 8044.58333

20 8906.66667 3188.64583 9093.02083


-2000

0

2000

4000

6000

8000

10000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 7.59 10.55 13.71 16.59 19.45

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 530.54912 162.190275 320.010362

Intercept: -103.82594 -24.061498 -60.072547

Correlation: 0.99972951 0.9998124 0.99973717

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 4.27083333 1.77083333 1.66666667

2.19 1093.95833 335.208333 677.916667

4.38 2128.86598 667.628866 1270.72165

8.76 4430.72917 1374.6875 2674.47917

17.51 9128.95833 2791.875 5529.79167

19.7 1.05E+04 3205.9375 6298.33333


-2000

0

2000

4000

6000

8000

10000

12000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00146 et al.Sample Name BOD Calibration - PCE/TCE 062916Date Wednesday, June 29, 2016 8:48:34Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00


BioMultiView 1.3 Wednesday, June 29, 2016 14:12 page 1 of 16/29/16.13.54.34Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Wed, Jun 29, 2016 at 13:54:34; Exp. Comment: Cal. Gas Bottle Number 2



0.41

3.81 5.14

6.68

7.90 8.97

10.22

13.47

15.40 16.72

5 10 15Time, min

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

22000

24000

26000

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32000

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40000

42000

44000

46000

48000

50000

52000

54000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: DLM

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.61 8.88 11.31 13.71 16.21

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 543.775815 195.398945 568.267896

Intercept: 16.635135 6.92696258 27.6566297

Correlation: 0.99980575 0.99976814 0.99989531

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 7.8125 3.33333333 10.3125

2.22 1289.58333 437.291667 1317.91667

4.44 2428.02083 873.854167 2546.875

8.89 4739.27083 1745.20833 5047.39583

17.78 9816.77083 3539.47917 1.02E+04

20 1.08E+04 3863.02083 1.13E+04


0

2000

4000

6000

8000

10000

12000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.61 8.88 11.31 13.71 16.21

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 666.317593 200.192524 392.084099

Intercept: 46.2511663 3.24816252 29.2370432

Correlation: 0.99987176 0.99990283 0.99993056

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 5.52083333 2.08333333 1.45833333

2.19 1552.29167 450 909.791667

4.38 2988.33333 889.0625 1766.875

8.76 5821.04167 1726.35417 3439.58333

17.51 1.19E+04 3542.5 6948.85417

19.7 1.31E+04 3927.60417 7708.95833


0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00151 et al.Sample Name MOD Calibration - PCE/TCE 062916Date Wednesday, June 29, 2016 14:14:21Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00

Name TETRACHLOROETHENETETRACHLOROETHENETETRACHLOROETHENETRICHLOROETHENETRICHLOROETHENETRICHLOROETHENEQ1 Mass 164.00 166.00 166.00 130.00 132.00 132.00Q3 Mass 129.00 129.00 131.00 95.00 95.00 97.00Slope 543.78 195.40 568.27 666.32 200.19 392.08Intercept 16.64 6.93 27.66 46.25 3.25 29.24Intensity 7.81 3.33 10.31 5.52 2.08 1.46Int SD 8.36 5.74 12.09 8.44 5.01 4.58Concentration -0.02 -0.02 -0.03 -0.06 -0.01 -0.07Conc SD 0.02 0.03 0.02 0.01 0.03 0.01Compound Conc -0.02 -0.05Compound SD 0.01 0.01Det. Limit 0.05 0.09 0.06 0.04 0.08 0.04Compound DL 0.07 0.05

Method InformationMethod Name: PCE/TCE CALIBRATIONLast Modified: Thu, Jun 30, 2016, 7:38:36Comment:




Pause: 0.1 sec










Solvents: 1


Timed events: 0






Timed steps: 9




0 -0.10 0.10 0.00 100.00

1 0.00 3.00 0.00 100.00

2 3.00 2.00 90.00 100.00

3 5.00 2.00 10.00 100.00

4 7.00 2.00 20.00 100.00

5 9.00 2.00 40.00 100.00

6 11.00 2.00 80.00 100.00

7 13.00 2.00 90.00 100.00

8 15.00 2.00 0.00 100.00






164.000 129.000 100.000












30.000 0.04575.000 0.058

100.000 0.060120.000 0.070180.000 0.090300.000 1.000


30.000 0.04360.000 0.044

100.000 0.044150.000 0.047180.000 0.047




Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




Method InformationMethod Name: PCE/TCE MONITORINGLast Modified: Thu, Jun 30, 2016, 7:39:11Comment:




Pause: 0.1 sec











164.000 129.000 100.000












30.000 0.04575.000 0.058

100.000 0.060120.000 0.070180.000 0.090300.000 1.000


30.000 0.04360.000 0.044

100.000 0.044150.000 0.047180.000 0.047




Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160







0.70

4.95

15.81 25.2527.53

5 10 15 20 25 30Time, min

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

22000

24000

26000

28000

30000

32000

34000

36000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.63 8.81 11.25 13.81 16.04

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 370.462384 133.724033 386.842909

Intercept: -33.99698 -12.529764 -39.195034

Correlation: 0.99983154 0.99985224 0.99982529

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 9.79166667 5.83333333 11.25

2.22 823.402062 292.886598 854.43299

4.44 1570.625 561.875 1630.83333

8.89 3188.33333 1159.47917 3327.60417

17.78 6515.9375 2350.72917 6800.20833

20 7444.6875 2685.52083 7770.83333


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.63 8.81 11.25 13.81 16.04

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 441.766327 133.771537 263.319036

Intercept: -38.656769 -8.4053983 -28.76434

Correlation: 0.99980836 0.99991021 0.99981262

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 10.8333333 3.33333333 2.5

2.19 967.628866 289.278351 569.175258

4.38 1847.1875 575.9375 1099.16667

8.76 3762.1875 1137.91667 2230.20833

17.51 7629.375 2329.0625 4546.66667

19.7 8761.25 2642.39583 5214.47917


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00153 et al.Sample Name BOD Calibration - PCE/TCE 063016Date Thursday, June 30, 2016 8:25:42Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00


BioMultiView 1.3 Wednesday, July 13, 2016 15:53 page 1 of 164MSMS00157Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Thu, Jun 30, 2016 at 13:47:11; Exp. Comment: Cal. Gas Bottle Number 2

6.61e4 cpsTIC of +MRM (6 pairs): from 64MSMS00157


6.41

9.24

17.44

19.58

23.24

28.14

30.71

5 10 15 20 25 30Time, min

5000

10000

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20000

25000

30000

35000

40000

45000

50000

55000

60000

65000

Inte

nsity,

cp

s



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 2.50 21.36 23.71 26.28 28.91 31.38

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 309.727946 117.139118 332.723799

Intercept: -30.116752 -18.10595 -19.804014

Correlation: 0.9995937 0.99954707 0.9997666

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 6.25 2.39583333 6.35416667

2.22 685.56701 259.793814 755.154639

4.44 1325.7732 492.989691 1450.82474

8.89 2657.93814 971.443299 2851.75258

17.78 5386.97917 2059.375 5848.4375

20 6274.58333 2352.39583 6712.8125


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

0 5 10 15 20 25


164.00/129.00

166.00/129.00

166.00/131.00



Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 2.50 21.36 23.71 26.28 28.91 31.38

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 405.583415 120.028122 236.465836

Intercept: 3.20085575 -5.9732271 -19.391046

Correlation: 0.99996749 0.99993259 0.99989435

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 6.875 2.39583333 1.77083333

2.19 927.938144 261.340206 517.319588

4.38 1759.27835 515.670103 1002.57732

8.76 3521.23711 1030.92784 2003.50515

17.51 7096.77083 2086.04167 4118.75

19.7 8016.45833 2374.0625 4663.64583


-1000

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25


130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00157 et al.Sample Name EOD Calibration - PCE/TCE 063016Date Thursday, June 30, 2016 14:22:11Time Range 2.00 to 3.00 minConc Units: ppbvNum Ions 6.00

Name TETRACHLOROETHENETETRACHLOROETHENETETRACHLOROETHENETRICHLOROETHENETRICHLOROETHENETRICHLOROETHENEQ1 Mass 164.00 166.00 166.00 130.00 132.00 132.00Q3 Mass 129.00 129.00 131.00 95.00 95.00 97.00Slope 309.73 117.14 332.72 405.58 120.03 236.47Intercept -30.12 -18.11 -19.80 3.20 -5.97 -19.39Intensity 6.25 2.40 6.35 6.88 2.40 1.77Int SD 8.86 5.18 8.22 8.98 6.61 4.59Concentration 0.12 0.18 0.08 0.01 0.07 0.09Conc SD 0.03 0.04 0.02 0.02 0.06 0.02Compound Conc 0.12 0.06Compound SD 0.02 0.02Det. Limit 0.09 0.13 0.07 0.07 0.17 0.06Compound DL 0.10 0.10

Method InformationMethod Name: PCE/TCE CALIBRATIONLast Modified: Wed, Jul 13, 2016, 15:55:21Comment:




Pause: 0.1 sec


State: MacHD3064:Instrument:state:LPCI2016JUL01 PCE+TCE








Solvents: 1


Timed events: 0






Timed steps: 9




0 -0.10 0.10 0.00 100.00

1 0.00 3.00 0.00 100.00

2 3.00 2.00 90.00 100.00

3 5.00 2.00 10.00 100.00

4 7.00 2.00 20.00 100.00

5 9.00 2.00 40.00 100.00

6 11.00 2.00 80.00 100.00

7 13.00 2.00 90.00 100.00

8 15.00 2.00 0.00 100.00


Page 1 of 5Printed: Wed, Jul 13, 2016, 15:56:02




164.000 129.000 100.000









State File InformationLast Modified: Fri, Jul 1, 2016, 6:35:48

Analog ParametersOR 0.000RNG 0.000Q0 -5.399IQ1 -6.099ST -15.600RO1 -6.100IQ2 -13.000RO2 -35.000IQ3 -38.000RO3 -40.500DF -390.000CEM 1700.000

On/Off ParametersPOL OffNEB OffCUR 4CAD 7NC 847249408TEM 1117782016


30.000 0.04575.000 0.058

100.000 0.060120.000 0.070180.000 0.090300.000 1.000


30.000 0.04360.000 0.044

100.000 0.044150.000 0.047180.000 0.047

Sample Control, Version 1.4Computer: TAGAFile: LPCI2016JUL01 PCE+TCE




Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




Method InformationMethod Name: PCE/TCE MONITORINGLast Modified: Wed, Jul 13, 2016, 15:55:31Comment:




Pause: 0.1 sec


State: MacHD3064:Instrument:state:LPCI2016JUL01 PCE+TCE









164.000 129.000 100.000









State File InformationLast Modified: Fri, Jul 1, 2016, 6:35:48

Analog ParametersOR 0.000RNG 0.000Q0 -5.399IQ1 -6.099ST -15.600RO1 -6.100IQ2 -13.000RO2 -35.000IQ3 -38.000RO3 -40.500DF -390.000CEM 1700.000

On/Off ParametersPOL OffNEB OffCUR 4CAD 7NC 847249408TEM 1117782016


30.000 0.04575.000 0.058

100.000 0.060120.000 0.070180.000 0.090300.000 1.000


30.000 0.04360.000 0.044

100.000 0.044150.000 0.047180.000 0.047

Sample Control, Version 1.4Computer: TAGAFile: LPCI2016JUL01 PCE+TCE




Mass DAC78.050 1466

106.080 2002129.910 2459165.870 3146





Mass DAC30.000 55178.050 1473

105.070 1992165.870 3160




BioMultiView 1.3 Friday, July 1, 2016 6:58 page 1 of 17/1/16.6.39.55Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Fri, Jul 1, 2016 at 6:39:55; Exp. Comment: Cal. Gas Bottle Number 2



0.51

5.20

8.59 9.53

10.63

16.49

17.87

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Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:

Date: Friday, July 1, 2016 6:59:08

Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.73 9.19 11.82 14.40 17.19

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 220.644261 80.5069055 232.859359

Intercept: -30.218482 -9.1792059 -22.553232

Correlation: 0.99981615 0.99983617 0.99991745

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 3.125 0.52083333 4.0625

2.22 476.597938 171.649485 508.762887

4.44 921.237113 345.979381 976.494845

8.89 1887.5 691.041667 2026.97917

17.78 3873.33333 1411.5625 4110.10417

20 4423.85417 1617.60417 4656.66667


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Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.73 9.19 11.82 14.40 17.19

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 253.925481 76.060028 147.64236

Intercept: -22.15226 -10.735562 -12.86299

Correlation: 0.99990565 0.99959097 0.99988201

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 4.375 0.72916667 0.9375

2.19 529.793814 169.175258 318.762887

4.38 1080.41237 309.896907 605.876289

8.76 2181.25 633.541667 1285

17.51 4390.83333 1308.75 2554.79167

19.7 5021.66667 1509.6875 2914.58333


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130.00/95.00

132.00/95.00

132.00/97.00

Report File Name 64MSMS00159 et al.Sample Name BOD Calibration - PCE/TCE 070116Date Friday, July 1, 2016 7:00:31Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00


BioMultiView 1.3 Friday, July 1, 2016 14:18 page 1 of 17/1/16.13.55.32Period 1, Expt. 1; Dwell: 100.0 ms; Pause: 5.0 msAcq. Time: Fri, Jul 1, 2016 at 13:55:31; Exp. Comment: Cal. Gas Bottle Number 2



1.73

4.52

6.26

9.95

11.65

14.53

19.75

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Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.88 9.53 12.48 16.05 18.99

Ion 1 Ion 2 Ion 3

Q1 Mass: 164 166 166

Q3 Mass: 129 129 131

Slope: 195.880598 76.7560349 219.972098

Intercept: -34.106169 -7.9543361 -14.66235

Correlation: 0.99966896 0.99981999 0.99988386

Concentrations164.00/129.00166.00/129.00166.00/131.00

0 1.45833333 0.52083333 0.72916667

2.22 431.5625 173.75 486.458333

4.44 802.061856 318.350515 955.051546

8.89 1638.4375 659.375 1895.41667

17.78 3461.04167 1366.66667 3931.77083

20 3907.1134 1527.01031 4373.71134


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Conc. units: ppbv

Width (min): 0.5

User name: BPK

Comment:


Num. ions: 3

Num. concs. 6


Ctr Pt.(min): 1.50 6.88 9.53 12.48 16.05 18.99

Ion 1 Ion 2 Ion 3

Q1 Mass: 130 132 132

Q3 Mass: 95 95 97

Slope: 267.200817 75.7974316 150.804316

Intercept: -15.48866 -4.2404319 -18.982778

Correlation: 0.99992285 0.99988601 0.99984614

Concentrations130.00/95.00132.00/95.00132.00/97.00

0 2.5 0.41666667 0.52083333

2.19 583.333333 168.4375 316.041667

4.38 1147.1134 319.381443 637.010309

8.76 2276.35417 649.791667 1262.08333

17.51 4690.3125 1335.9375 2639.47917

19.7 5246.18557 1482.98969 2954.2268


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Report File Name 64MSMS00165 et al.Sample Name EOD Calibration - PCE/TCE 070116Date Friday, July 1, 2016 14:18:12Time Range 1.00 to 2.00 minConc Units: ppbvNum Ions 6.00


Documents

FINAL ANALYTICAL TAGA REPORT5f TAGA Target Compound Summary in µg/m 3 for Unit 5 Survey, File: 64MSMS00118 Acquired on 23 June 2016 at 14:36:58 6a Unit 7 Survey One Floor Plan, 64MSMS00119