MANAGERS OESGNERSCONSIMANTS

FEDERAL PROGRAMS

DIVISION

FRANKLIN SLAG PILE MDC

SITEMAP

N

M 30+ Feel High Slag Pile CD 20- 25 Feet High Slag Pile

Drainage PaftR302418

Franklin Slag Pile (MDC) Site Philadelphia, Philadelphia County, PA

TDD No. 0001-132 Contract No. 68-S5-3002

Personal data rams were placed on the SATA members who collected the samples. These air monitors were worn during on site and off-site sampling. The highest concentration recorded was 1.019 mg/m3 with the overall average concentration being 0.010 mg/ m3. No readings were recorded on the PID or the micro-R (above background) during the sampling event.

Table 1 Sample Locations

Sample ID Time Location SP-01 1100 Slag pile grit, east of dryer. SP-02 1105 S lag pile grit, northeast of main entrance. SP-03 1115 Slag pile grit, east gate.

SP-03A 1120 Slag pile grit, duplicate of SP-03. SP-04 1130 Bagged product, east gate. SP-05 1230 Soil/girt, Philadelphia Water Dept., by northwest comer of FSP. SP-06 1240 Soil/grit Philadelphia Water Dept., central drainage swale. SP-07 1255 Soil/grit, Delaware Avenue, 20 ft. northeast of MDC/PWD property line. SP-08 1300 Soil/grit, Delaware Avenue storm drain close to Castor Avenue. SP-09 1305 Soil/grit, railroad tracks near FSRC railroad gate.

4.0 ANALYTICAL RESULTS

All samples collected were analyzed for TAL and TCLP metals. One sample, SP-03, was also analyzed for pesticides/PCBs, semivolatile and volatile organic compounds. All samples had TCLP levels of lead that were greater than the RCRA regulatory level of 5 ppm. One sample, SP-04, also had cadmium present at a level greater than the RCRA regulatory level of 1 ppm. Total lead in samples collected from the slag pile and surrounding areas ranged from 4,220 ppm to 6,370 ppm. However, sample SP-04 collected from the bagged product had a total lead value of 22,100 ppm.. See Attachment 6, January 2000 Assessment Analytical Summary Tables, for the analytical results as well as for emergency removal guideline (ERG) levels. ERGs were derived from the 7 October 1999 RBC table.

5.0 FUTURE ACTIONS/RECOMMENDATIONS

On 7 January 2000, the Environmental Protection Agency initiated a $200,000 emergency activation at FSP. Then on 2 February 2000, an Additional Funding Request was approved for temporary stabilization of the slag pile. SATA recommends that during the Removal Actions, a full extent of contamination study be conducted, to assess surface and subsurface soil contamination on site and at neighboring properties, surface water runoff, and groundwater.

6.0 REFERENCES ' ^

Microsoft (Microsoft Corporation). 1998. Streets 98, Version 6.0.

SATA0303898tripreport 5 03/14/00 AR302419

r

Franklin Slag Pile (MDC) Site TCLP Metals Analysis

Sample ID Arsenic Barium Cadmium Chromium Lead Mercury Selenium Silver 3 _B _B

_U _B _B

B

SP-01 0.0034 0.508 0.107 0.0062 7.4 0.00007 0.0058 0.0201 SP-02 0.0034 U 0.75 0.476 0.0117 21.3 0.00007 U 0.0039 0.0092 SP-03 0.0051 0.85 0.34 0.0152 15.4 0.00007 0.0066 0.0126

SP-03A 0.0034 0.694 0.396 0.0128 17.8 0.00007 0.003 U 0.0063 SP-04 0.0034 0.489 3.24 0.0062 6.01 0.00007 U 0.0089 K 0.0039 SP-05 0.0034 0.84 0.33 0.0071 14.4 0.00007 0.0068 0.0087 SP-06 0.0034 0.59 0.315 0.0096 13.2 0.00007 U 0.0058 0.0056 SP-07 0.0034 0.654 0.329 0.062 11.2 0.00007 U 0.0056 0.0052 SP-08 0.0034 0.858 0.326 0.0107 13.7 0.00007 0.0053 0.0106 SP-09 0.0034 0.668 0.513 0.0081 17.2 0.00007 0.0041 0.0155

All units in mg/L

6> ' ̂

AR302420

Franklin Slag Pile (MDC) Site TCL.P Metals Analysis

Sample ID Arsenic Barium Cadmium Chromium Lead Mercury Selenium Silver _Q

_B B

_B J3 _B

B

SP-01 0.0034 U 0.508 B 0.107 0.0062 7.4 0.00007 U 0.0058 0.0201 SP-02 0.0034 U 0.75 0.476 0.0117 21.3 0.00007 0.0039- 0.0092 SP-03 0.0051 0.85 0.34 0.0152 15.4 0.00007 0.0066 0.0126

SP-03A 0.0034 0.894 0.396 0.0128 17.8 0.00007 0.003 0.0063 SP-04 0.0034 U 0.489 3.24 0.0062 6.01 0.00007 U 0.0089 0.0039 SP-05 0.0034 0.84 0.33 0.0071 14.4 0.00007 0.0068 0.0087 SP-06 0.0034 0.59 0.315 0.0096 13.2 0.00007 0.0058 0.0056 SP-07 SP-08

0.0034 U 0.654 0.0034 0.858

0.329 0.326

0.062 11.2 0.00007 U 0.0056 0.0052 0.0107 13.7 0.00007 0.0053 0.0106

SP-09 0.0034 0.668 0.513 0.0081 17.2 0.00007 0.0041 0.0155

All units in mg/L

a - 6 - "

AR302421

Site Name: F r a n k l i n S l a g Pile All units in mg/kg

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sheet

Sample ID: SP-09

CAS# Compound Results RBC ERG RBC Exceedance ERG Exceedance 7429905 Aluminum- 36,000 N 204400 20440000 No No 7440360 Antimony 6.4 N 81.76 8176 No No 7440382 Arsenic 6.9 3.815 381.5 Yes No 7440393 Barium 863 N 14310 1431000 No No 7440417 Beryllium 100 N 408.8 40880 No No 7440439 Cadmium 7.9 N 102.2 10220 No No 7440702 Calcium 42,800 NA NA No No 7440473 Chromium 333 N 613.2 ,61320 No No 7440484 Cobalt 914 N 12260 1226000 No No 7440508 Copper 10,400 N 8176 817600 Yes No 7439896 Iron 170,000 N 61320 6132000 Yes No 7439921 Lead 4,220 400 NL Yes No 7439954 Magnesium 10,500 NA NA No No 7439965 Manganese 3,350 N 4088 408800 No No 7439976 Mercury 0.12 N 61 6100 No No 7440020 Nickel 1,030 N 4088 408800 No • No 7440097 Potassium 2,940 NA NA No No 7782492 Selenium 6.7 N 1022 102200 No No 7440224 Silver 0.92 N 1022 102200 No No 7440235 Sodium 9,620 NA NA No No 7440280 Thallium 0.46 U N 14.31 1431 No No

7440622 Vanadium 36.7 N 1431 143100 No No 7440666 Zinc 53,900 J N 61320 6132000 No No

74908 Cyanide N 4088 408800 No No

Note: RBCs are based on a cancer risk of 10"4 and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERGs are based on a cancer risk of 10"* and a hazard quotient of 10.

Cancet risk applies to carcinogens and hazard quotient applies to non-carcinogens.

fi - G ' (S

AR302422

Site Name: Eranklin Slag. Pile All units in mg/kg

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sheet

Sample ID: SP-08

CAS# Compound Results Q T RBC ERG RBC Exceedance ERG Exceedance

7429905 Aluminum 33,400 N 204400 20440000 No No 7440360 Antimony 11.2 N 81.76 8176 No No 7440382 Arsenic 2.9 3.815 381.5 No No 7440393 Barium 711 N 14310 1431000 No No 7440417 Beryllium 101 N 408.8 40880 No No 7440439 Cadmium 2.1 N 102.2 10220 No No

7440702 Calcium 53,300 NA NA . No No 7440473 Chromium 104 N 613.2 61320 No No 7440484 Cobalt 168 N 12260 1226000 No No 7440508 Copper 11,900 N 8176 817600 Yes No

7439896 Iron 159,000 N 61320 6132000 Yes No

7439921 Lead 5,130 400 NL Yes No

7439954 Magnesium 13,100 NA NA No No

7439965 Manganese 2,990 N 4088 408800 No No

7439976 7440020

Mercury Nickel

0.06 U N 61 6100 1,190 N 4088 408800

No No

No No

7440097 Potassium 2,770 NA NA No No

7782492 Selenium 6.1 N 1022 102200 No No

7440224 Silver 0.53 B N 1022 102200 No No

7440235 Sodium 10,200 NA NA No No

7440280 Thallium 0.51 U N 14.31 1431 No No

7440622 Vanadium 27.1 N 1431 143100 No No

7440666 Zinc 45,100 N 61320 6132000 No No 74908 Cyanide N 4088 408800 No No

Note: RBCs are based on a cancer risk of 10"4 and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERCs are based on a cancer risk of 10"* and a hazard quotient of 10.

Cancer risk applies to carcinogens and hazard quotient applies to non-carcinogens.

4

AR302423

e Name: Franklin Slag Pile i units in mg/kg

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sheet

Sample ID: SP-07

CAS# Compound Results RBC ERG RBC Exceedance ERG Exceedance J429905 Aluminum 35,500 N 204400 20440000 No No .7440360 Antimony 10.6 N 81.76 8176 No No 7440382 Arsenic . 2.5 3.815 381.5 No No 7440393 Barium 587 N 14310 1431000 No No 7440417 Beryllium 106 N 408.8 40880 No No 7440439 Cadmium 3.7 L N 102.2 10220 No No 7440702 Calcium 57,100 NA NA No No 7440473 Chromium 85.2 J N 613.2 61320 No No 7440484 Cobalt 155 N 12260 1226000 No No 7440508 Copper 12,800 N 8176 817600 Yes No 7439896 Iron 155,000 N 61320 6132000 Yes No 7439921 Lead 5,670 400 NL Yes No 7439954 Magnesium 10,300 NA NA No No 7439965 Mang anese 3,410 N 4088 408800 No No 7439976 Mercury 0.06 U N 61 6100 No No 7440020 Nickel 1,020 N 4088 408800 No No 7440097 Potassium 2,750 NA NA No No 7782492 Selenium 6.5 N 1022 102200 No No 7440224 Silver 1.2 B N 1022 102200 No No

i 7440235 Sodium 12;000 NA NA No No

440280 Thallium 0.5 U N 14.31 1431 No No

7440622 Vanadium 26.4 N 1431 143100 No No

7440666 Zinc 52,100 N 61320 6132000 No No 74908 Cyanide N 4088 408800 No No

Note: RBCs are based on a cancer risk of 10"* and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERGs are based on a cancer risk,of 10J and a hazard quotient of 10.

Cancer risk applies to carcinogens and hazard quotient applies to non-carcinogens.

\

/ f t - ( * ' I 3

I

AR302424

Site Name: Franklin Slap Pile All units in mg/kg

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sheet

Sample ID: SP-06

CAS# Compound Results RBC ERG RBC Exceedance ERG Exceedance

7429905 Aluminum 36,700 N 204400 20440000 No No 7440360 Antimony 21.7 N 81.76 8176 No No 7440382 Arsenic 5.5 3.815 381.5 Yes No 7440393 Barium 771 N 14310 1431000 No No 7440417 Beryllium 113 N 408.8 40880 No No 7440439 Cadmium 0.07 U N 102.2 10220 No No 7440702 Calcium 55,300 NA NA No No 7440473 Chromium 130 N 613.2 61320 No No 7440484 Cobalt 203 N 12260 1226000 No No 7440508 Copper 23,500 N 8176 817600 Yes No 7439896 Iron 177,000 N 61320 6132000 Yes No 7439921 Lead 5,810 400 NL Yes No 7439954 Magnesium 11,500 NA NA No No 7439965 , Manganese 3,370 N 4088 408800 No No 7439976 Mercury 0.06 U N 61 6100 No No

7440020 Nickel 2,110 N 4088 408800 No No

7440097 Potassium 2,910 NA NA No No

7782492 Selenium 8.1 N 1022 102200 No No

7440224 Silver 6.9 N 1022 102200 No No

7440235 Sodium 11,400 NA NA No No

7440280 Thallium 0.52 U N 14.31 1431 No No

7440622 Vanadium 25.9 N 1431 143100 No No

7440666 Zinc 50,800 . N 61320 6132000 No No 74908 Cyanide N 4088 408800 No No

Note: RBCs are based on a cancer risk of 10"4 and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERGs are based on a cancer risk of IO"4 and a hazard quotient of 10..

Cancer risk applies to carcinogens and hazard quotient applies to non-carcinogens.

A - 6 -1 •*-

AR302425

Site Name: Franklin Slap Pile All units in mg/kg _

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sbeet

Sample ID: SP-05

CAS# Compound Results Q RBC ERG RBC Exceedance ERG Exceedance 7429905 Aluminum 31,800 J N 204400 20440000 No No 7440360 7440382 7440393

Antimony Arsenic Barium

15.9 N 81.76 8176 3.5 3.815 381.5 599 N 14310 1431000

No No No

No No No

7440417 Beryllium 93 N 408.8 40880 No No 7440439 Cadmium N 102.2 10220 No No 7440702 Calcium 49,800 NA NA No No 7440473 Chromium 107 N 613.2 61320 No No 7440484 Cobalt 158 N 12260 1226000 No No 7440508 Copper 12,100 N 8176 817600 Yes No 7439896 Iron 145,000 N 61320 6132000 Yes No 7439921 Lead 4,900 400 NL Yes No 7439954 Magnesium 11,300 NA • NA No No 7439965 Manganese 2,830 N 4088 408800 No No 7439976 Mercury 0.07 B N 61 6100 No No 7440020 Nickel 1,090 . N 4088 408800 No No 7440097 Potassium 2,520 NA NA No No 7782492 Selenium 6:2 N 1022 102200 No No

7440224 Silver 1.5 B N 1022 102200 No No 7440235 7440280

Sodium Thallium

9,610 NA NA 0.5 U N 14.31 1431

No No

No No

7440622 Vanadium 23.7 N 1431 143100 No No

7440666 Zinc 43,900 N 61320, 6132000 No No 74908 Cyanide N 4088 408800 No No

Note. RBCs are based on a cancer risk of 10 and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERGs are based on a cancer risk of 10J and a hazard quotient of 10.

Cancer nsk applies to carcinogens and hazard quotient applies to non-carcinogens.

ft ' (* "

AR302426

Site Name: franklin Slap Pile All units in nag/kg

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sheet

Sample ID: SP-04

CAS# Compound Results RBC ERG RBC Exceedance ERG Exceedancv. 7429905 Aluminum 29,300 N 204400 20440000 No No 7440360 Antimony 49.3 N 81.76 8176 No No 7440382 Arsenic 40.4 3.815 381.5 Yes No 7440393 Barium 830 N 14310 1431000 No No 7440417 Beryllium 86.1 N 408.8 40880 No No 7440439 Cadmium 250 N 102.2 10220 Yes No 7440702 Calcium 49,400 NA NA No No 7440473 Chromium 112 N 613.2 61320 No No 7440484 Cobalt 205 N 12260 1226000 No No 7440508 7439896

Copper Iron

46,400 N 8176 817600 142,000 N 61320 6132000

Yes Yes

No No

7439921 Lead 22,100 400 NL Yes No

7439954 Magnesium 14,900 NA NA No No.

7439965 Manganese 2,440 N 4088 408800 No No

7439976 Mercury 0.33 N" 61 6100 No No

7440020 Nickel 4,020 N 4088 408800 No No

7440097 Potassium 2,140 NA NA No No

7782492 Selenium 13.7 N 1022 102200 No No

7440224 Silver 15 N 1022 102200 No No

7440235 7440280

Sodium Thallium

11,100 NA NA 0.47 U N 14.31 1431

No No

No No

7440622 Vanadium 24.8 N 1431 143100 No No

7440666 Zinc 84,100 N 61320 6132000 Yes No

74908 Cyanide N 4088 408800 No No

Note: RBCs are baaed on a cancer risk of 10"4 and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERGs are based on a cancer risk of 10"* and a hazard quotient of 10.

Cancer risk applies to carcinogens and hazard quotient applies to non^arcinogens.

A

AR302427-

Industrial Soil - U.S. EPA CLP Semi-Volatile Organic Analysis Data Sheet (continued)

Sice Name:. Eianklin Slag Pile^ All units in mg/kg ,

Sample ID: SP-03

Compound 'Results RBC ERG RBC Exceedance ERG Exceedance 2,4rDinitrophcnol 0.88 U N 408.8 40880 No No

4-Nitrophenol 0.88 U N 1635 163500 No No Dibenzofuran 0.35 U N 817.6 81760 No No

2,4-Dinitrotoluene 0.35 U N *408.8 40880 No No Diethylphthalate 0.35 U N 163500 16350000 No No

4-Chlorophenyl-phcnylether 0.35 U NL NL NL No No Fluorene 0.35 U N 8200 820000 No No

4-Nitroaniline 0.88 U ,N 610 61000 No No 4,6-Dinitro-2-methylphenol 0.88 U N 20.44 2044 No No

N-Nitrosodiphenylamine 0.35 U 1168 116800 No No 4-Bromophenyl-phenylether 0.35 U N 12000 1200000 No No

Hexachlorobenzene 0.35 U 3.577 357.7 No No Pentachlorophenol 0.88 U 47.69 4769 No No

Phenanthrene 0.35 U NL NL NL No No Anthracene 0.35 U N 61000 6100000 No No Carbazole 0.35 U 290 29000 No No

Di-n-butylphthalatc 0.35 U N 20000 2000000 No No Fluoranthene 0.35 U N 8200 820000 No No

Pyrene- 0.35 U N 6100 610000 No No Butylbenzylphthalate 0.35 U N 40880 4088000 No No

3,3Dichlorobenzidine 0.35 U 12.72 1272 No No Benzo(a)anthracenc 0.35 U 7.84 784 No No

Chiysene 0.35 U 780 78000 No No bis(2 • Ethy lhexyl)pbthalate 0.35 U 408.8 40880 No No

Di-n-octylphthalate 0.35 U N 4088 408800 No No Benzo(b)f1uoranthene 0.35 U 7.84 784 No No Benzo(k)fluoranthenc 0.35 U 78.4 7840 No No

Benzo(a)pyrene 0.35 U 0.784 78.4 No No

Indeno( 1,2,3-cd)pyrene 0.35 U 7.84 784 No No

Dibenz(a,h)anthraccne 0.35 U 0.784 78.4 No No B enzo(g,h,i)perylene 0.35 U NL NL NL No No

Note: RBCs are based on a cancer risk of 104 and a hazard quotient of 0.1 and are taken from the 7 October 1999. RBC table.

ERGs are based on a cancer risk of 10"4 and a hazard quotient of 10.

Cancer risk applies to carcinogens and hazard quotient applies to non-carcinOgcns.

f \ - f c - ?

AR302428

Industrial Soil - U.S. EPA CLP Semi-Volatile Organic Analysis Data Sheet

Site Name: Eranklin Slag Pile

All units in mg/kg Sample ID: SP-03

CAS# Compound Results , RBC ERG RBC Exceedance ERG Exceedance 108952 Phenol 0.35 U N 122600 12260000 No No 111444 95578

bis(2-Chloroethyl) ether 0.35 U 5.203 2-Chlorophenol 0.35 U N 1022

520.3 102200

No No

No No

541731 106467

1,3-Dichlorobenzene N 184 18400 1,4-Dichlorobenzenc 238.5 23850

No No

No No

95501 1,2-Dichlorobenzenc N 18400 1840000 No No 95487 2-Methylphenol 0.35 U N 10220 1022000 No No 108601 2,2'-oxybis( 1 -Chloropropane) 0.35 U 82 8200 No No 106445 4-Methylphenol 0.35 U N 1022 102200 No No 621647 N-Nitroso-di-n-propylamine 0.35 U 0.8176 81.76 No No 67721 Hexachloioethane 0.35 U 408.8 40880 No No 98953 Nitrobenzene 0.35 U N 102.2 10220 No No 78591 Isophorone 0.35 U 6024 602400 No No 88755 2-Nitrophenol 0.35 U NL NL NL No No

105679 2,4-Dunethylphenol 0.35 U N 4088 408800 No No 111911 bis(2-Chloroethoxy) methane 0.35 U NL NL NL No No 120832 2,4-Dichloiophenol 0.35 U N 613.2 61320 No No 120821 1,2,4-T richlorobemenc N 2044 204400 No No 91203 Naphthalene 0.35 U N 4088 408800 No No 106478 4-Chloroaniline 0.35 U N 817.6 81760 No No 87683 Hexachlorobutadiene 0.35 U 73.37 7337 No No 59507 4-Chloro-3-methylphenol 0.35 U NL NL NL No No 91576 2-Methybaphthalene 0.35 U N 4088 408800 No No 77474 Hexachlorocyclopentadiene 0.35 U N 1431 143100 No No 88062 2,4,6-Trichlorophenol 0.35 U C 520.3 52030 No No 95954 2,4,5-Trichlorophenol 0.88 U N 20440 2044000 No No 91587 2-Chloronaphthalcnc 0.35 U N 16350 1635000 No No 88744 2-Nitroaniline 0.88 U N 12 1200 No No.

131113 Dimethylphthalatc 0.35 U N 2044000 2.04E+08 No No 208968 Acenaphthylcne 0.35 U NL NL NL No No 606202 2,6-Dinitrotoluenc 0.35 U N 204.4 20440 No No 99092 3-Nitroaniline 0.88 U N 610 61000 No No 83329 Acenaphthene 0.35 U N" 12000 1200000 No No

Note: RBCs are based on a cancer risk of 10"4 and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERGs are based on a cancer risk of 10"4 and a hazard quotient of 10.

Cancer risk applies to carcinogens and hazard quoh'cnt applies to non-carcinogens.

AR302429

Industrial Soil - U.S. EPA CLP Volatile Organic Analysis Data Sheet

ite Name: Ffan1flin Slag Pile All units in mg/kg

Sample ID: SP-03

CAS# Compound Results RBC ERG RBC Exceedance ERG Exceedance ' 74873 Chloromethane 0.011 U 440.2 44020 No No

74839 75014 75003 75092 67641 75150

Bromome thane 0.011 U N 286.2 28620 Vinyl chloride 0.011 U 3.012 301.2 Chloroethane 0.011

Methylene chloride 0.011 Acetone 0.016

Carbon disulfide 0.011

U 1974 197400 U 763.1 76310

N 20440 2044000 U N 20440 2044000

No No No No No No

No No No No No No

75354 1,1-Dichlorocthene 0.011 U 9.539 953.9 No No 75343 1,1-Dichloroethanc 0.011 U N 20440 2044000 No No

540590 1,2-Dichlorocthcnc (total) 0.011 U N 1840 184000 No No 67663 Chloroform 0.011 U 938.2 93820 No No 107062 1,2-Dichloroe thane 0.011 U 62.89 6289 No No 78933 2-Butanonc (MEK) 0.011 U N 122600 12260000 No No 71556 1,1; 1 -Trichlorocthane 0.011 U N 4088 408800 No No 56235 Carbon tetrachloride 0.011 U 44.02 4402 No No 75274 Bromodichloromethane 0.011 . U 92.31 9231 No No 78875 1,2-Dichloropropane 0.011 U 84.16 8416 No No

542756 1,3-Dichloropropene 0.011 U 31.8 3180 No No 79016 Trichloroethene 0.011 U 520.3 52030 No No 124481 Dibromochloromethane 0.011 U 68.13 6813 No No 79005 1,1,2-T richloroethane 0.011 U 100.4 10040 No No 71432 Benzene 0.011 U 197.4 19740 No No 75252 Bromofoxro 0.011 U 724.5 72450 No No 108101 4-Mcthyl-2-pentanonc 0.011 U N 16350 1635000 No No 591786 2-Hexanone 0.011 U N 8176 817600 No No

127184 Tetrachloroethene 0.011 U 110.1 11010 No No 79345 1,1,2,2-Tetrachloroethane 0.011 U 28.62 2862 No No

108883 Toluene 0.011 U N 40880 4088000 No No

108907 Chlorobenzene 0.011 U N 4088 408800 No No

100414 Ethylbenzcne 0.011 U N 20440 2044000 No No

100425 Styrene 0.011 U N 40880 4088000 No No

1330207 Xylene (total) 0.011 U N 40880 4088000 No No 1634044 MTBE 0.011 U N NL NI- No No

Note: RBCs art based on a cancer risk of 10 and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERGs art based on a cancer risk of 10"* and a hazard quotient of 10.

Cancer risk applies to carcinogens and hazard quotient applies to non-carcinogens.

A - ^ n

AR302430

Industrial Soil - U.S. EPA CLP Pesticide/Polycblorinated Bipbenyl Analysis Data Sheet

Site Name: Franklin Slag Pile All units in mg/kg

Sample ID: SP-03

CAS# Compound Results RBC ERG RBC Exceedance ERG Exceedance

319846 alpha-HCH 0.0018 u 0.9084 90.84 No No 319857 beta-HCH 0.0018 U 3.18 318 No No

319868 delta-HCH 0.0018 U NL NL NL No No 58899 gamma-HCH (Lindane) 0.0018 U 4.402 440.2 No No 76448 Heptachlor 0.0018 U 1.272 127.2 No No

309002 Aldrin 0.0018 U 0.3367 33.67 No No

1024573 959988

Heptachlor epoxide 0.0018 U 0.6289 62.89

Endosulfan I 0.0018 U NL NL NL No No

No No.

60571 Dieldrin 0.0035 U 0.3577 35.77 No No

72559 4,4'-DDE 0.0035 U 16.83 1683 No No

72208 Endrin 0.0035 U N 61.32 6132 No No

33213659 Endosulfan II 0.0035 U NL NL NL No No

72548 4,4'-DDD 0.0035 U 23.85 2385 No No

1031078 Endosulfan sulfate 0.0035 U NL NL NL No No

50293 4,4'-DDT 0.0035 U 16.83 1683 No No

72435 53494705

Methoxychlor 0.018 U N 1022 102200 Endrin ketone 0.0035 U NL NL NL

No No

No No

7421363 Endrin aldehyde 0.0035 U NL NL NL No No

5103719 alpha-Chlordane 0.0018 U 16.35 1635 No No

5103742 8001352

gamma -Chlordane 0.0018 U 16.35 1635

Toxaphenc 0.18 U 5.203 520.3 No No

No No

12674112 11104282

Aroclor-1016 0.035 U 81.76 8176 Aroclor-1221 0.071 U 2.862 286.2

No No

No No

11141165 Aroclor-1232 0.035 U 2.862 .286.2 No No

53469219 Aroclor-1242 0.035 U 2.862 286.2 No _No _ No 12672296 Aroclor-1248 0.035 U 2.862 286.2 No

11097691 Aroclor-1254 0.035 U 2.862 286.2 No No

11096825 Aroclor-1260 0.06 2.862 286.2 No

Note: RBCs are based on a cancer risk of 10"* and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERGs are based on a cancer risk of 10"* and a hazard quotient of 10.

Cancer risk applies to carcinogens and hazard quotient applies to non-carcinogens.

No

^ - (o - Co

AR302431

» Name: F™nVlin Sla? Pile 1 units in mg/kg

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sheet

Sample ID: SP-03

CAS # 7429905 7440360

Compound Aluminum Antimony

Results 37.100

10.1

Q T

N N

RBC 204400 81.76

ERG 20440000

8176"

RBC Exceedance No No

ERG Exceedance •. No

No 7440382 Arsemc 2.6 3.815 381.5 No No 7440393 7440417

Barium Beryllium

805 N 14310 1431000 129 N 408.8 40880

No No

No No

.7440439 Cadmium 1.9. N 102.2 10220 No No 7440702 Calcium 54,200 NA NA No No 7440473 Chromium 109 N 613.2 61320 No '' No 7440484 Cobalt 204 N 12260 1226000' No No 7440508 Copper 16,600 N 8176 817600 Yes No 7439896 Iron 180,000 N 61320 6132000 Yes No 7439921 Lead 6,370 400 NL Yes No 7439954 Magnesium 13,700 NA NA No No 7439965 Manganese 3,320 N 4088 408800 No No 7439976 Mercury 0.05 U N 61 6100 No No 7440020 Nickel 1,580 N 4088 408800 No No 7440097 Potassium 2,940 NA NA No No 7782492 Selenium 6.1 N 1022 102200 No No 7440224 Silver 0.39 B N 1022 102200 No No ,440235 Sodium 11,800 NA NA No No M40280 Thallium 0.45 U N 14.31 1431 No No 7440622 Vanadium 23.3 N 1431 143100 No No 7440666 Zinc 54,600 N 61320 6132000 No No

74908 Cyanide N 4088 408800 No No

Note: RBCs ore based on a cancer risk of 10"4

GRGs are based on a cancer risk of 10"* and a

Cancer risk applies to carcinogens and hazard

and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

hazard quotient of 10.

quotient applies to non-carcinogens.

ft

AR302432

Site Name: franklin Slay Pile All units in mg/kg

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sheet

Sample ID: SP-03A

CAS# Compound Results RBC ERG RBC Exceedance ERG Exceedance

7429905 Aluminum 37,400 N 204400 20440000 No No 7440360 Antimony N 81.76 8176 No No 7440382 Arsenic 3.7 3.815 381.5 No No 7440393 Barium 839 N 14310 1431000 No No 7440417 Beryllium 1 2 1 N 408.8 40880 No No 7440439 Cadmium 0.06 U N 102.2 10220 No No 7440702 Calcium 55,400 NA NA No No 7440473 Chromium 118 N 613.2 61320 No No

7440484 Cobalt 198 N 12260 1226000 No No

7440508 Copper 13,300 N 8176 817600 Yes No

7439896 Iron 183,000 N 61320 6132000 Yes No

7439921 Lead 5,770 400 NL Yes No

7439954 Magnesium 13,300 NA NA No No

7439965 Manganese 3,310 N 4088 408800 No No

7439976 Mercury 0.05 U N 61 6100 No No

7440020 Nickel 1,440 N 4088 408800 No No

7440097 Potassium 3,010 NA NA" No No

7782492 Selenium 6.2 N 1022 102200 No No

7440224 Silver 0.17 B N 1022 102200 No No

7440235 Sodium 11,900 NA NA No No

7440280 Thallium 0.45 U N 14.31 1431 No No

7440622 Vanadium 24.4 N 1431 143100 No No

7440666 Zinc 52,300 J N 61320 6132000 No No 74908 Cyanide N 4088 408800 No No

lote: RBCs are based on a cancer risk of 10"4 and a hazard quotient of 0.1 and are taken

RGs are based on a cancer risk of 10"* and a hazard quotient of 10.

ancer risk applies to carcinogens and hazard quotient applies to non-carcinogens.

from the 7 (5ctober 1999 RBC table.

AR302433

Site Name: F r a n V l i n Slag Pile A)] units in mg/kg

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sheet

Sample ID: SP-02

CAS# Compound Results RBC ERG RBC Exceedance ERG Exceedance 7429905 Aluminum 34.600 N 204400 20440000 No No 7440360 7440382

Antimony Arsenic

11.7 N 81.76 8176 2.8 3.815 381.5

No No

No. No

7440393 7440417

Barium Beryllium

710 N 14310 1431000 118 N 408.8 40880

No No

No No

7440439 Cadmium 2.1 N 102.2 10220 No No 7440702 Calcium 53,900 NA NA No No 7440473 Chromium 89.8 N 613.2 61320 No No 7440484 Cobalt 208 N 12260 1226000 No No 7440508 Copper 16,500 N 8176 817600 Yes No 7439896 Iron 174,000 N 61320 6132000 Yes No 7439921 Lead 6,050 400 NL Yes No 7439954 Magni esium 12,900 NA NA No No 7439965 Manganese 3,230 N 4088 408800 No No 7439976 Mercury 0.05 U N 61 6100 No No 7440020 Nickel 1,650 N 4088 408800 No No 7440097 Potassium 2,760 NA NA No No 7782492 Selenium N 1022 102200 No No 7440224 Silver 0.17 B N 1022 102200 No No 7440235 Sodium 11,900 NA NA No No 7440280 Thallium 0.44 U N 14.31 1431 No No

7440622 7440666

74908

Vanadium Zinc

Cyanide

22.5 N 1431 143100 53,400 N 61320 6132000 0.11 B N 4088 408800

No No No

No No No

Note: RBCs are based on a cancer risk of 10"4 and a hazard quotient of 0.1 and are taken from the 7 October 1999 RBC table.

ERGs are based on a cancer risk of 10"* and a hazard quotient of 10.

Cancer risk applies 10 carcinogens and hazard quotient applies to non<arcinogens.

AR302434

Site Name: Eranklin Slag Pile All units in mg/kg

Industrial Soil - U.S. EPA CLP Inorganic Analysis Data Sheet

Sample ID: SP-01

CAS# Compound Results RBC ERG RBC Exceedance ERG ExceedaL

7429905 Aluminum 35,000 N 204400 20440000 No No •7440360 Antimony 8.4 N 81.76 8176 No No 7440382 Arsenic 0.7 3.815 381.5 No No 7440393 Barium 772 N 14310 1431000 No No 7440417 Beryllium 129 N 408.8 40880 No No 7440439 Cadmium 0.06 U N 102.2 10220 No No 7440702 Calcium 49.200 NA NA No No 7440473 Chromium •111 N 613.2 61320 No No 7440484 Cobalt 186 N 12260 1226000. No No 7440508 Copper 13,200 N 8176 817600 Yes No 7439896 Iron 172,000 N 61320 6132000 Yes No

7439921 Lead 5,550 400 NL Yes No

7439954 Magnesium 11,500 NA NA No No

7439965 Manganese 3,220 N 4088 408800 No No

7439976 Mercury 0.05 U N 61 6100 No No 7440020 7440097

Nickel Potassium

1,320 N 4088 408800 2,600 NA NA

No No

No No

7782492 Selenium 5.2 N 1022 102200 No No

7440224 7440235

Silver Sodium

0.08 U N 1022 102200 11,500 N A ­ NA

No No

No No

7440280 Thallium 0.42 U N 14.31 1431 No No

7440622 Vanadium 23.2 N 1431 143100 No No

7440666 Zinc 48,400 J N 61320 6132000 No No 74908 Cyanide N 4088 408800 No No

Note: RBCs are based on a cancer risk of 10"* and a hazard quotient of 0.1 and are taken from the ? October 1999 RBC table.

ERGs are based on a cancer risk of 10*4 and a hazard quotient of 10.

Cancer risk applies to carcinogens and hazard quotient applies to non-carcinogena.

\

j

AR302435

LIST OF ACRONYMS

jig microgram

AWQC Ambient water quality criteria

B Chemical not detected substantially above levels reported in blank samples

C Carcinogen

E Essential nutrient ERG Emergency removal guideline Ex. Exceedance

J Estimated values

K Reported values are biased high kg kilogram

L liter (unit of measure) L Reported values are biased low (qualifier)

mJ ... cubic meter MCL Maximum contaminant level mg milligram

N Non-carcinogen NA Not applicable NL Not listed

Q Qualifier

R Unusable data RAL Removal action level RBC Risk-based concentration \

T Toxicity TT Best available treatment technology

U Non-detect

A - 6 - / AR302436

Site Name: All units in

Franklin Slap Pile

mg/kg

Industrial Inorganic

Soil - U.S. EPA CLP Analysis Data Sheet

Sample ID: SP-04

CAS# Compound Results RBC ERG RBC Exceedance ERG Exceedanci.

7429905 Aluminum 1 29,300 N 204400 20440000 No No 7440360 / Antimony 2.1 49.3 N 81.76 8176 No No

7440382 v/ Arsenic 12=- 40.4 3.815 381.5 Yes No

7440393 Barium 830 N 14310 1431000 No No

7440417 Beryllium •$ > 86.1 N 408.8 40880 No No

7440439 Cadmium 3L 250 N 102.2 10220 Yes No

7440702 Calcium 49,400 NA NA No No

7440473 ClV1- Chromium 112 N 613.2 61320 No No

7440484 7440508

• Cobalt 205 N 12260 1226000 v/ 'Copper 9) Zoo 46,400 N 8176 817600

No Yes

No No

7439896 7439921 7439954

Iron | <?u, op" 142,000 N 61320 6132000 Lead 45ft 22,100 400 NL

Magnesium 14,900 NA NA

Yes Yes No

No No No.

7439965 Manganese ,"31 2,440 N 4088 408800 No No

7439976 Mercury 11. 0.33 N' 61 6100 No No

7440020 7440097

Nickel 4,020 N 4088 408800

Potassium 2,140 NA NA No No

No No

7782492 7440224

Selenium 13.7 N 1022 102200 Silver 54 15 N 1022 102200

No No

No No

7440235 Sodium 11,100 NA NA No No

7440280 Thallium 14 0.47 U N 14.31 1431 No No

7440622 Vanadium 15°° 24.8 N 1431 143100 No No

7440666 v/ Zinc 84,100 N 61320 6132000 Yes No

74908 Cyanide j oo N 4088 408800 No No

Note: RBCs arc based on a cancer risk of 10"4 and

ERGs are based on a cancer risk of 10"4 and a hazai'd

Cancer risk applies to carcinogens and hazard quot

hazard quotient of 0.1 and are taken him the 7 October 1999 RBC table,

quotient of 10.

cnt applies to non-carcinogens.

°tu

h

AR302437