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Chemistry Chemistry David K. Ryan, Ph.D. Department of Chemistry Department of Chemistry University of Massachusetts Lowell University of Massachusetts Lowell April 12, 2010 April 12, 2010 http:// http:// faculty.uml.edu/david_ryan faculty.uml.edu/david_ryan / / Fundamentals of Engineering (FE) General Exam Review Program March 3 rd ~ April 12 th , 2010

FE Exam Review Chemistry Problems...Fundamentals of Engineering (FE) General Exam Review Program March 3rd ~ April 12 th, 2010. Date: 04/12/10 2 Problems. Date: 04/12/10 3 Problems

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Page 1: FE Exam Review Chemistry Problems...Fundamentals of Engineering (FE) General Exam Review Program March 3rd ~ April 12 th, 2010. Date: 04/12/10 2 Problems. Date: 04/12/10 3 Problems

ChemistryChemistry

David K. Ryan, Ph.D.

Department of ChemistryDepartment of ChemistryUniversity of Massachusetts LowellUniversity of Massachusetts Lowell

April 12, 2010April 12, 2010

http://http://faculty.uml.edu/david_ryanfaculty.uml.edu/david_ryan//

Fundamentals of Engineering (FE) General Exam Review Program

March 3rd ~ April 12th, 2010

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Page 27: FE Exam Review Chemistry Problems...Fundamentals of Engineering (FE) General Exam Review Program March 3rd ~ April 12 th, 2010. Date: 04/12/10 2 Problems. Date: 04/12/10 3 Problems

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Relating Kc and Kp

The ideal gas equation PV = nRT

can be manipulated into a form that reflects a gas concentration term

P = (n/V) RT where n/V = molarity

For any gas, A; P = [A] RT

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Consider the Rxn: N2O4(g) = 2NO2(g)

Kp for this rxn follows as:

As a general expression:

where Δn = (number moles of gaseous product - number moles of gaseous reactant)

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End of Problems Section

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