FactSheet Anaerobic Digestion

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    AnAerobic digestion

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    1. descriPtion oF tecHnoLogY

    2. cUrrent distribUtion And ProsPectiVe oF tecHnoLogY

    3. LegAL FrAMeWorK

    4. AnAerobic digestion And bioPLAstics: stAndArds, certiFicAtion And LAbeLLing

    5. interActions betWeen bioPLAstics And tecHnoLogY

    6. beneFits And cHALLenges

    6.1 Beets

    6.2 Chaeges

    7. sUccessFUL cAses

    8. Annex - reFerences; LinKs etc.

    index

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    1. descriPtion oF tecHnoLogY

    Withi bioogica soid waste treatmet, a distictio ca be made betwee

    two major categories: one being aerobic composting and the other one being

    aaerobic digestio or biogasicatio.

    I compostig, orgaic matter is degraded b a microbia popatio co-

    sistig o bacteria ad gi cosmig oxge ad prodcig CO2, water,

    compost or humus and a lot o heat (exothermic). Because o the heat

    prodctio, the temperatre i a compostig pie icreases sigicat. I

    aaerobic digestio, orgaic matter is degraded b a microbia popatio

    cosistig o bacteria i the absece o oxge ad prodcig methae

    and carbon dioxide (= biogas) and compost without practically any exother-

    mic heat. The biogas ca be treated i a Combied Heat ad Power Pat

    (CHP), prodcig eectricit ad heat, or ca be pgraded to bio-methae.

    Tpica ot o 1 to o biowaste, 120 m3 o biogas ca be prodced with a

    tota eectricit ied o 250 kWh ad a et eectricit ied o 200 kWh.

    Rather dieret techoogies ca be distigished i aaerobic digestio.

    Oe distictio betwee dieret techoogies is the temperatre at which

    the aaerobic digestio is operated. Temperatre is extera cotroed,

    and digesters are run either at mesophilic temperature (35-40C), or atthermophiic temperatre (50-55C). These are two distict temperatre

    zoes at which dieret tpes o aaerobic bacteria show maximm actii-

    t (respectie mesophiic ad thermophiic bacteria). The rate o actiit is

    higher at thermophiic temperatre. Frther, aaerobic digestio processes

    ca be 1-phase or 2-phase. I 1-phase, the compete digestio is takig

    pace i oe it or digester. I 2-phase ermetatio, the rst hdrosis

    ad acidicatio phase ad the sbseqet methaogeic phase are r

    i separate taks. I dr aaerobic digestio, the process is r at a mois-

    tre cotet 85%.

    Practically all commercial anaerobic digestion systems consist o a frst

    step o aaerobic ermetatio, oowed b a aerobic compostig, sta-

    biisatio secod step. Sice ermetatio is a kid o mixed process, the

    otpt is ot stabiised or ermeted. I order to redce the resida

    biological activity and to obtain complete maturity o the compost end

    product, the residue rom the anaerobic digestion phase is thereore

    aerobica composted.

    Anaerobic digestion is particularly suited or organic waste with a high

    moistre cotet sch as kitche waste ad ood waste, athogh it ca

    be used or various dierent types o waste streams. Anaerobic digesti-

    o pats hae bee bit ad hae bee operatioa or ma ears or

    the treatmet o mixed, micipa soid waste, or biowaste (obtaied ater

    sorce separated waste coectio), or resida waste ad or ma tpes

    o idstria waste.

    Anaerobic digestion is oten the preerred biological waste treatment option

    in densely populated areas such as big cities or countries like Japan or

    Korea. This is de to good odor prodctio cotro ad a redced eed

    or srace area.

    Recet, aaerobic digestio has aso become a importat paer i the

    area o renewable energy production out o energy crops (e.g. corn). The net

    energy yield per hectare is higher compared to the production o bio-diesel or

    bio-ethanol. Also in bio-refneries, anaerobic digestion could play an important

    role with high-value plant parts being used or green chemistry and residual

    egeta matter (ater processig or ow-ae pat parts) beig treated i

    aaerobic digestio or the prodctio o eerg ad compost.

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    2. cUrrent distribUtion And ProsPectiVe oF tecHnoLogY

    Figre 1 beow gies a oeriew o the deeopmet o digestio capacit

    i Erope i the ast two decades. From three pats i Erope with a tota

    capacit o 87,000 tos per ear i 1990, aaerobic digestio capacit i

    Erope has grow to a tota o 171 pats ad a digestio capacit o more

    than 5 million tons per year in 2010. Figure 2 gives an overview o the

    digestio capacit i dieret Eropea cotries. Both the tota capacit

    as we as the aerage capacit per pat i a gie cotr is dispaed.

    As ca be see, some cotries ted to hae smaer pats (e.g. Germa-

    , Switzerad, Astria), whie others hae arger istaatios (e.g. Spai,

    Frace). Figre 3 gies a oeriew o the eotio ad ratio o respec-

    tie mesophiic ad thermophiic digestio capacit i Erope. Abot oe

    third o the capacity is thermophilic, whereas two thirds are mesophilic.

    Figre 4 gies a oeriew o the eotio ad ratio o respectie wet

    ad dr digestio capacit i Erope. The ratio is abot 50/50 with a sight

    dominance or dry systems. Figure 5 gives an overview o the evolution and

    ratio o respectie 1-phase ad 2-phase digestio capacit i Erope. As

    ca be see, the ast majorit is 1-phase.

    Digestion capacity in Europe is increasing rapidly. Many digesters are being

    built in Mediterranean countries such as Spain and France. Most plants are

    dr ad 1-phase, ad r at mesophiic temperatre. The eotio or the

    next years can be deducted rom the various graphs below, the data o which

    are based o the bids or proposas pbished i the Eropea Jora.

    FIGuRE 1. EvOluTIOn OF DIGESTIOn CAPACITy In EuROPE (Eu + EFTA COunTRIES) (WITH TPA = TOnES

    PER AnnuM)

    1.600

    Germa

    ny

    1.400

    1.200

    1.000

    800

    600

    400

    200

    0

    80.000

    70.000

    60.000

    50.000

    40.000

    30.000

    20.000

    10.000

    0

    Spain

    France Ital

    y NL UK

    Switze

    rland

    Belgiu

    mPor

    tugal

    Austria

    Swede

    nMa

    lta

    Luxem

    burg

    Norwa

    y

    Denma

    rkPol

    andFin

    land

    InstalledCapacity(kTon/y)

    Total Capac ity Average Capac ity

    FIGuRE 2. DIGESTIOn CAPACITy In vARIOuS EuROPEAn COunTRIES (2010) In TOnS PER yEAR

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    4.000

    till199

    0

    3.500

    3.000

    2.500

    2.000

    1.500

    1.000

    500

    0

    100%

    90%

    80%

    70%

    60%

    50%

    40%

    30%

    0

    1991

    1992

    1993

    1994

    1995

    1996

    1997

    1998

    1999

    2000

    2001

    2002

    2003

    2004

    2005

    >2009

    Cumulative(kTon/y)

    20%

    10%

    2006

    2007

    2008

    2009

    2010

    2011

    % Meso % ThermoMeso Thermo

    FIGuRE 3. EvOluTIOn AnD RATIO OF MESOPHIlIC AnD THERMOPHIlIC DIGESTIOn CAPACITy

    FIGuRE 4. EvOluTIOn AnD RATIO OF WET AnD DRy DIGESTIOn CAPACITy

    till199

    0

    3.500

    3.000

    2.500

    2.000

    1.500

    1.000

    500

    0

    1991

    1992

    1993

    1994

    1995

    1996

    1997

    1998

    1999

    2000

    2001

    2002

    2003

    2004

    2005

    Cumulative(kTon/y)

    2006

    2007

    2008

    2009

    2010

    70%

    60%

    50%

    40%

    30%

    20%

    10%

    0%

    % Wet % DryWet Dry

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    4.000

    till1

    990

    3.500

    3.000

    2.500

    2.000

    1.500

    1.000

    500

    0

    1991

    1992

    1993

    1994

    1995

    1996

    1997

    1998

    1999

    2000

    2001

    2002

    2003

    2004

    2005

    Cumulativ

    e(kTon/y)

    2006

    2007

    2008

    2009

    2010

    4.500

    5.000

    80%

    70%

    60%

    50%

    40%

    30%

    20%

    10%

    0%

    90%

    100%

    % One % TwoOne Cumulat ive Two Cumulat ive

    FIGuRE 5. EvOluTIOn AnD RATIO OF 1-PHASE AnD 2-PHASE DIGESTIOn CAPACITy

    3. LegAL And PoLiticAL FrAMeWorK

    Iormatio o aaiabiit o techoog i geera ad i dieret co-

    tries ca be od i chapter 2. With regard to aorabe egisatio, the

    sitatio is idetica to that or aerobic compostig ad the acceptace o

    compostabe packagig i biowaste. I most cotries athorities are ot

    aowig the additio o compostabe packagig or prodcts to biowaste

    which is sigicat hiderig the breakthrogh o biopastics. O i The

    netherads the additio is aowed.

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    4. AnAerobic digestion And bioPLAstics:

    stAndArds, certiFicAtion And LAbeLLing

    The ormatie bechmark or the orgaic recoer o packagig ad bio-

    pastics i Erope is represeted b the Eropea harmoized stadard

    En 13432 "Packagig - Reqiremets or packagig recoerabe throgh

    compostig ad biodegradatio - Test scheme ad eaatio criteria or

    the a acceptace o packagig". This stadard aims "to determie the

    compostabiit ad aaerobic treatabiit o packagig ad packagig ma-

    terias".1 Accordig to the En 13432, "compost is ot o the a prod-ct o the aerobic compostig process bt aso the aerobica stabiized

    prodct o the aaerobic biogasicatio process".2 I practice, the ocs

    is o the prodctio o a a compost, ree o cotamiats. This ca be

    obtaied thaks to two steps: a rst aaerobic phase oowed b a aero-

    bic phase, eeded to stabiise the aaerobic sdge. The En 13432 does

    ot ocs o the recoer ied o the packagig as biogas. Howeer, the

    aaerobic biodegradatio ca be estimated with specic stadards (e.g.

    ISO 11734, ISO 14853, ISO 15985, Ecetoc #28, ASTM D.5210-92, ASTM

    D.5511-02, ASTM D.5526-94). I the En 13432, a ote ca be od:

    aaerobic biodegradatio ad disitegratio ca be eried as a optio

    (ot madator). For biodegradatio, 50% is reqired ater 2 moths as

    aaerobic ermetatio is oowed b aerobic compostig, drig which

    biodegradatio ca rther cotie. With regard to disitegratio, the

    stadard reqires that ater 5 weeks o combied aaerobic ad aerobic

    treatmet at most 10% o the origia sampe ma remai ater sieig

    oer 2mm mesh size. no rther detais are specied. I a ote it is rther

    metioed that these reqiremets might chage i the tre, wherther iormatio ad experiece become aaiabe.

    The discssio ad stadardisatio o reqiremets or aaerobic biode-

    gradatio or preerab aaerobic treatabiit is sti i a ear, iitia phase.

    Oe idea, which is aso circatig, is to reqire o disitegratio ater

    aaerobic testig, argig that biodegradatio ca be achieed i sbse-

    qet aerobic compostig ad/or soi appicatio.

    no specic certicates or abes o aaerobic treatabiit exist crret

    (2010), or are oresee or the ear tre.

    5. interActions betWeen bioPLAstics And tecHnoLogY

    I order to be compatibe biopastics shod, rst o a, be biodegraded d-

    rig the treatmet process, jst as with aerobic compostig, sice aaerobic

    digestio is a bioogica waste treatmet process. Whether the biodegrada-

    tio occrs drig the rst aaerobic phase or drig the secod aerobic

    phase has o impact o the qait o a compost, whie it cear has o

    the biogas prodctio. Correct recoer is assred as og as biopastic is

    eeta biodegraded ad o resides are et.

    I this cotext, whether or ot biopastics are prodced rom reewabe

    resorces is ot reeat. The ke eemet is or them to be biodegradabe

    ad compatibe with the aaerobic digestio process.

    Cocerig techica precoditios o treatig biopastics i aaerobic

    digestio pats, a distictio mst be made betwee wet ad dr techo-

    ogies. I most dr sstems, biopastics ca be added i some bodar

    coditios are ed: the shod be redced i partice size beore ete-

    rig the digestio (jst ike biowaste itse), ad sieig shod be ocated

    at the ed o the process i order to eabe as mch biodegradatio ad

    disitegratio as possibe i both the aaerobic digestio ad the aerobic

    compostig step.

    I the case o wet techoogies, pretreatmet o biopastics is reqired

    to make them processabe. Otherwise, the are ote remoed either b

    fotatio or b sedimetatio i the rst ppig ad hdrosis phase ad

    thereore are ot rea eterig the digestio (except whe biopastics

    are qick sobe or dispersibe). Aother sotio cod be to add the

    biopastics direct to the 2d aerobic compostig step (cosiderig the

    retetio time i this 2d step is mch shorter tha the residece time i

    a tpica compostig process).

    The major derig reaso wh seera biopastics show a dieret bio-

    degradatio behaior i aerobic compostig ad i aaerobic digestio

    coditios is de to the ifece o gi. Fgi are abdat aaiabe

    ad er actie i aerobic compostig, whie i aaerobic ermetatio, o

    1EN 13432: Packaging. Requirements or packaging recoverable through composting and biodegradation. Test scheme and evaluation criteria or the fnal acceptance o packaging, Scope, Clause 1.2EN 13432: Packaging. Requirements or packaging recoverable through composting and biodegradation. Test scheme and evaluation criteria or the fnal acceptance o packaging, Scope, Clause 5.

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    gi are actie. Some pomers are mai (or ee o) degraded b -

    gi ad ot b bacteria, ad wi thereore biodegrade o i aerobic

    compostig ad ot, or o mch sower, i aaerobic digestio. As a

    matter o act, this is aso the case or the atra pomer igi, which ca

    be od i wood, straw, shes, etc.

    O the other had, whe biopastics do biodegrade aso i aaerobic er-

    metatio, there is a dobe beet. First o a, eerg is prodced rom

    the biopastics der the orm o biogas to be coerted to eectricit. Se-

    cod, as most biopastics are er rich i carbo ad do ot cotai

    itroge (or er itte), the additio o biopastics to biowaste wi improethe carbo to itroge (C/n) ratio o the mixtre. Biowaste teds to be ow

    i C/n, which is sometimes a probem i aaerobic digestio, b addig a

    carbo-rich sbstrate, the C/n ratio is icreased.

    So ar, itte iormatio o aaerobic biodegradatio o biopastics is

    kow, ad rther research wod be wecome to assess the potetia

    biogas (eerg) prodctio de to the biopastics. Idea, biopastics wod

    biodegrade ad aso disitegrate drig the aaerobic phase i a aaero-

    bic digestio pat, jst as the major part o atra biowaste does. How-

    eer, i the biopastic disitegrates drig the aaerobic phase ad the

    aterwards biodegrades compete drig the aerobic stabiisatio phase

    or drig the se o digestate or compost i soi, it ca aso be cosideredto be compatibe with aaerobic digestio.

    6. beneFits And cHALLenges

    6.1 Benets

    Eerg prodctio. This ca ead to a tripe beet or wi-wi-wisitatio: (1) biopastics cotai reewabe resorces, (2) drig biode-

    gradatio, (reewabe) eerg is prodced i the orm o biogas ad, (3)

    the resida matter ad biomass prodced remais as compost.

    Improemet o C/n ratio. As biowaste, especia whe mai

    kitche waste, is ote rich i proteis, the C/n ratio ca be reatie

    ow (

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    8. Annex - reFerences; LinKs etc

    1. De Baere . ad Matthews B. (2008). State-o-the-art 2008. Waste Maagemet Word, J-Agst 2008

    February 2011

    European Bioplastics e.V.

    Marienstrae 19/20

    10117 Berlin

    Phone: +49 (0) 30 284 82 350

    Fax: +49 (0) 30 284 84 359

    [email protected]

    www.european-bioplastics.org

    not a certied compostabe biopastics wi degrade to the same

    extet i the aaerobic digestio step, ad the ma perorm dieret

    i the dieret techoogies. For this reaso, more iormatio is

    eeded o the behaior o dieret biopastics i dieret aaerobic

    digestio sstems.

    Pretreatmet ca be a critica actor ad determie the processabiit

    o a compostabe biopastic i a aaerobic digestio pat.

    6.2 Challenges

    I some AD pats, o-reccabe paper ad biopastics are added

    to biowaste withot hiderig the good operatio ad ctioig o

    these pats or ma ears aread, e.g. the AD pats i Brecht ad

    Teeie, Begim (both dr 1- stage sstems).

    Compostabe bags are accepted i arios pats, e.g. Skeetea

    Swede (wet oe-stage aaerobic digestio pat); SIS, Passa,

    Germa (dr horizota pg fow pat); ZAW-SR, Eiterhoe, Germa,

    (dr batch aciit); ETRA, Bassao de Grappa, Ita (dr ertica pg

    fow pat),; ACEA Tri, Ita (wet aaerobic 1-stage digestio pat).

    7. Successful Cases