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FactSage Steelmaking Consortium Project Overview Department of Materials Science and Engineering Professor In-Ho Jung Tel : 82-2-880-7077 E-mail: [email protected]

FactSage Steelmaking Consortium Project · 2018. 12. 6. · Steelmaking Consortium Project (2017-2020) 6 Project-B: Thermodynamic databases for metallic systems: This is for the development

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  • FactSage Steelmaking Consortium Project

    Overview

    Department of Materials Science and Engineering

    Professor In-Ho Jung

    Tel : 82-2-880-7077

    E-mail: [email protected]

  • Slag/Refractory/

    Inclusions/Flux/

    Steel

    Slag:Viscosity,

    Molar volume,

    Thermal

    Conductivity, etc.

    Thermodynamic

    database

    Physical Property

    database

    Kinetic Process

    Simulation models

    (EERZ Concept)

    - Secondary Refining Units

    - Continuous Casting Process

    Overall Goal of FactSage Steelmaking Consortium Project

    (2009~2020)

    Combining Thermodynamics

    & Mass transfer based on

    numerical analysis and plant

    sampling data2

  • 2017-2

    020

    Steel database

    High alloy steels with all common elements

    (steelmaking, alloy design, metallic coating)R

    E o

    xy-s

    ulfid

    es,

    Hig

    h V

    an

    d T

    io

    xid

    e s

    lag

    s

    Addition of C, H into oxy-fluoride systems

    SF

    CA

    s

    Steelmaking Consortium project (2009 ~ 2020)

    3

    FactSage DatabaseOxide database (FToxid): CaO-

    MgO-FeO-Fe2O3-Al2O3-SiO2-…

    FSStel and FeLq databasae

    P2O5(de-P process)

    Na2O, K2O, Li2O, F, S

    Oxy Fluoride system

    (mold flux & refining slag)

    Na

    2 O-F

    et O

    , Mn

    O,…

    ,

    (refin

    ing

    , refra

    cto

    ry)

    Ti oxides, ZrO2, B2O3

    Tra

    nsie

    nt m

    eta

    l oxid

    es

    (Mn

    , Cr, V

    , Ti

    ox

    ide

    s)

    2014-2

    017

    2009-2

    014

    Steel database

    (high Mn, Al, Si alloys)

  • Steelmaking Consortium project (2009 ~ 2020)

    4

    Physical property database for molten slags

    Process simulation: Steelmaking process

    Viscosity

    Molar volume

    Electric conductivity

    Y 2014

    Solidification of slag

    Continuous casting process: mold flux

    RH degassor Basic Oxygen Furnace

    LF

    Injection Tundish

    VTD

    KR

    Y 2010 Y 2020

    RH degassor EAF

  • Steelmaking Consortium Project (2017-2020)

    5

    Project-A: Thermodynamic database of oxide system:

    (i) Expansion of Ti, V and Cr oxide systems. (continuation from

    previous consortium project)

    - CaO-MgO-Al2O3-SiO2-FeO-Fe2O3-MnO-Na2O + Ti oxide (Ti3+, Ti4+)

    - CaO-MgO-Al2O3-SiO2-FeO-Fe2O3-MnO + Cr oxide (Cr2+, Cr3+, Cr6+)

    - CaO-MgO-Al2O3-SiO2-FeO-Fe2O3 + V oxide (V2+, 3+, 4+, 5+)

    (ii) Development of rare earth oxy-sulfide systems.

    - CaO-MgO-Al2O3-SiO2-RE2O3-RE2S3

    (iii) Development of the database related to the iron ore sintering

    process.

    - CaO-SiO2-FeO-Fe2O3-MgO-Al2O3 system + SFCA and SFCA-I.

    (iv) Development of the database of the Mg-Al-Si-C-N-O system

    (v) Solubility of C and H in liquid slag and mold flux

  • Steelmaking Consortium Project (2017-2020)

    6

    Project-B: Thermodynamic databases for metallic systems:

    This is for the development of new steel database covering all current and

    future steel grades (low C, stainless steel, high alloy steel, etc.) and even ferro-

    alloys. In addition, Galvanizing bath database is going to be expanded.

    (i) Expansion to Stainless steels

    - Ni, Cr, Ti, Mo, … (both 300 and 400 series).

    (ii) Expansion to TRIP steels

    - carbide and nitride ppts: (Ti,Nb,Zr,…)(C,N)

    (iii) Expansion to Super steels

    - BCC and FCC order/disorder phases: Al-Co-Cr-Fe-Ni-Ti

    (iv) Galvanizing bath database

    - Zn-Al-Fe-Si-Mg + Mn, Cr.

  • Steelmaking Consortium Project (2017-2020)

    7

    Project-C: Physical properties database for oxide and

    metallic systems.Molar volume of liquid slag system was completed in 2015.

    (i) Viscosity database for liquid slag- Revision of the viscosity database of the Ti oxide system (Wan-Yi Kim)

    - Addition of P2O5 systems(preliminary study done – insufficient data available)

    (ii) Thermal conductivity database of liquid slag- Silicate system and oxyfluoride system

    (iii) Molar volume and viscosity of liquid metal system- Molar volume and viscosity of liquid metal

    for both high alloy steels and galvanizing bath

    (iv) Surface tension database for liquid metal system (tentative project)

  • Steelmaking Consortium Project (2017-2020)

    8

    Project-D: Development of a simple kinetic process

    simulation model for the secondary steelmaking process

    and continuous casting process.

    Using the same FactSage macro simulation approach we have used for other

    process simulations, we will develop new models for the Electrical Arc Furnace

    (EAF) and Tundish, and we will continuously upgrade the RH degassor and Vacuum

    Tank Degassor (VTD) models. In 2019, we will begin to convert the FactSage macro

    model to a stand-alone software with a user-friendly interface using ChemApp DLL.

    Review and develop slag foaming model.

    Develop and insert simplified ferro-alloy dissolution model in process simulation.

  • Steelmaking consortium project (2009~2020) – 2018 Annual meeting, Seoul, Korea